TEST-1 SOLUTION S

STANDARD ANSWER KEY

Q 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A 2 1 2 2 4 2 4 3 1 1 2 1 2 3 2
Q 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A 3 1 2 2 3 5 1 2 5 4 9 6 6 1 4
Q 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A 2 3 2 1 3 2 4 3 3 1 1 2 4 3 2
Q 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A 2 2 4 2 3 2 1 4 9 2 3 3 8 2 5
Q 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A 3 3 1 4 1 1 3 4 1 3 4 4 4 4 2
Q 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A 2 3 1 3 4 7 2 1 6 3 1 5 8 6 5
 = 250 – 160 = 90 gm/mole
(1) (2).
So value of n =
Weight of solvent
= Weight of solution – weight of NaC1 (9) (1). s-character increases, Bond angle increases
= 1.0585 × 1000 – 58.5 p-character increases, Bond angel
= 1058.5 – 58.5 = 1000 g = 1 kg decreases
(2) (1). 3Mg + 2NH3  Mg3N2 + 3H2 Hence, p-character order : PH3 > : NH3
3mol 2mol 1mol Bond angle order PH3 < : NH3
(72 g) (34 g) (100 g)
(L. R.) (10) (1).
72 g Mg will produce Mg3N2 = 100 g
Greater value of Higher is Tc
48 g Mg will produce Mg3N2 =
Gas Ar Ne Kr Xe
= 200/3 g 1.3 0.2 5.1 4.1
a
(3) (2). For third transition of balmer series b
3.2 1.7 1 5
 0.406  0.118  5.1  0.82
E = (E5 – E2) × Z2
= (–0.54 + 3.4) × 4 = 11.44 eV  Tc has order : Kr > Xe > Ar > Ne
For He+(E.P.)I = E2 – E1 = 10.2 × 4 (11) (2). P (x) = 4x2 × [(x)]2
= 40.8 eV Probability will be maximum at a and c.
For Li+2(SE)III = E – E4 = 0.85 × 9 (12) (1). o– nitrophenol < p – nitrophenol
Intra Molecular Inter. molecular
= 7.65 eV H. Bonding H – Bonding
For H (E.P.)IV = E4 – E1 = 12.75 eV
For Be3+(I.P.) = 13.6 × 16 = 217.6 eV (13) (2).
(4) (2). 1 mol N–3 ion  1 × 10 mol e–
1 mol O–2 ion  1 × 10 mol e–
= 6.023 × 1024 e–
1 mol CH4  1 × 10 mol protons
1 mol H2O  1 × 10 mol protons
(5) (4). Polarity of Bond EN.
(6) (2). Cr – 1s2 2s2 2p6 3s2 3p6 3d5 4s1 Formula = CnH2n–2 = C4H2×4–2 = C4H6
m = +1 will be for 2py, 3py Mw of C4H6 = 4 × 12 + 6 × 1 = 54
and 3dxz orbitals (14) (3).
 Minimum 2 electrons will be with Be 3  All are single electron species
anticlockwise spin & maximum will be 3. 
Li 2  Bohr's atomic theory is applicable.
(7) (4). H  Only for single electron species

C O C O O C O He2+  no electron
O O (15) (2). CO2(g) + C(s)  2CO(g)
1.33 2L 0
B.O. = 3 2
(8) (3). Mass of anhydrous MSO4 salt 2–x 2x
2 – x + 2x = 3
= 250 × = 160 gm/mole 2 + x = 3 ; x = 1 litre
Volume of CO = 2 × 1 = 2 litre
Total Mass of H2O is MSO4. nH2O

2
 0.31 gm loss from 0.01 mole of NaHCO3
Moles of CO (at STP) =
Moles of Na2CO3 produced= = 0.005
(16) (3). According to Pauli's rule an orbital contain
maximum 2 electron with opposite spin. Total moles of carbonate reacted with
BaCl2

S am e spin = 0.015
(17) (1). Moles of carbonate in original sample
q = 0.015 – 0.005 = 0.01
NH3 = 107°, OCl2 = > 109.5°
100 q = 1.
(18) (2). (23) 2. No. of  bonds
Total e = 18 B .O . = 1 N o un pa ired e
(a) P4O6  12
Y Y ..
P
X Y X O O
Y
x :P O P:
=0 = =x
2 O
(19) (2). PV = nRT O O

P= nRT .P.
T1 > T2 > T3 (b) K2Cr2O7  8
O– O–
(20) (3). Moles of urea =
+ Cr Cr
2K
O O O
Molarity of urea = O O
(c) KMnO4  4
(21) 5. 26Fe (normal configuration)
O–
= 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d6
+
K Mn
3d O O
(n + ) for each unpaired electron = 5 O
Total (n + ) for 4 unpaired electrons = 20 (d) I2Cl6  8
26Fe (abnormal configuration)
Cl Cl Cl
= 1s2, 2s2, 2p6, 3s2, 3p6, 3d8
I I
3d Cl Cl Cl
Total (n + ) for 2 unpaired electrons = 10
(e) K2MnO4  4
% change =
O–
x=5 +
(22) 1. Loss in wt. due to heating 2K Mn
–
O O
= 6.2 × = 0.31 g O

1mole NaHCO3 31 gm loss due to

heating

3
 (f) K2CrO4  4
Volume of ozone =
O–
(28) 6. Binding energy of electron = 250 kJ mol–1
+
2K Cr  Binding energy of one electron
–
O O
O = = 4.15 × 10–19 J
(g) C5H8  12
Along binding energy = h0
H
| Where 0 is the threshold frequency
HC  CC  CCH
| | | | |  4.15 × 10–19 = 6.625 × 10–34 × 0
H H H H H 0 = 6 × 1014 sec–1
(24) 5. (29) 1. Bond order
(a) PCl3F2 : µ=0
(b) P(CH3)3(CF3)2 : µ=0 =
– –
(c) BF3 : µ=0 O O O
– –
(d) CHCl3 : µ0 – C=O – C–O C=O
O O O
(e) P(CH3)2(CF3)3 : µ0
Bond order =
(f) PF3Cl2 : µ0
–
(g) CH4 : µ=0 O O O
– O=N –
O –N O –N
(h) CCl4 : µ=0 O O O

(25) 4. Bond order =

Ratio =

In H-atom electron excited to 2nd orbit by (30) 4. Electronic configuration of the element
absorbing this photon. with atomic number 24 is
1s2 2s2 2p6 3s2 3p6 4s1 3d5
2r = n  The electronic configuration for its
dipositive ion is 1s2 2s2 2p6 3s2 3p6 3d4
Hence, no. of unpaired electrons = 4
(31) (2).
(26) 9.
= Acceleration

So, kinetic energy increases by 8%.

(27) 6.
20ml d + t  t d  time

20 – x
 c  distance
;

4
 Vertical component of speed of ball is
(32) (3). = u sin 30° = 20 × (1/2) = 10 m/s
upward –ive and downward +ive
Acceleration along wedge = g sin 
h = ut + gt2
= 5 m/s2
(33) (2). N = F sin 37° – mg 5t2 – 10t – 40 = 0
as per given condition t2 – 2t – 8 = 0
When N = 0, F sin 37° – mg = 0 t2 – 4t + 2t – 8 = 0
t (t – 4) + 2 (t – 4) = 0
 Fsin 37º = mg  (t + 2) (t – 4) = 0
 t = 50/3 s  t = –2 not possible, so t – 4 = 0 ; t = 4s
(34) (1). (38) (3). F.B.D. of block A
N °
s 45
F co

F
4 5°
s in Applying Newton's second law for block
mg F sin 45° A in vertical direction
 = 45 ° m gcos 45°
mAg – N cos  = mAg
mg where  is the angle of the wedge
N = F sin 45°+ mg cos 45°  N cos  = 0
as  < 90º N=0
(39) 
(3). Let G = c g p 
(35) (3). Let v be the velocity at the time of Substitute the dimensional formula on both
collision sides of equation and compare the powers
of L, M, T on both sides. Then solve for ,
vsin60° , and .
60°
(40) (1).
vcos60°
60°
Then



(36) (2). Velocity,

(41) (1).
or

or 2x1/2 =  t or x t2
(37) (4). (42) (2).
u

30° B

h = 40 m
C

5
(43) (4). If we take the position of ship 'A' as origin
then positions and velocities of both ships
can be given as :
^j
1 0 k m /h r
B

(45) (2). [Impulse] = [MLT–1]

1 5 0 km
5 0 k m /h r
(46) (2).
A 3 0 k m /h r ^i
(0 ,0 ) O 80 k m = 1 m/s2

(47) (2).

Time after which distance between them will

be minimum Acceleration =

= 2 m/s2, which is constant.

where,
Hence Net force at any instant will be
F = ma = 1 × 2 = 2N
(48) (4). 
so when v = 0 we get a = 0
OR
v = x2 – 5x + 4

(44) (3).
1 0m /s
 Acceleration 'a' = (2x – 5) v
 5
g
v
 When v = 0, a = 0
60° g co s  (49) (2). In velocity-time graph, the total distance
(1 0 – 5 3 ) covered is equal to the area of the curve
vx = 10 cos 60° = 5 m/s under the time-axis.
 Distance covered in last 2 s
vy = 10 cos 30° = 5 m/s
Velocity after t = 1 sec.
vx = 5 m/s
Total distance covered in 7s = Area ABCD

The ratio is therefore, 20 : 80 or 1 : 4

(50) (3). A : 5g – T = 5 (2a)
B : 2T – 8g = 8 (a)
Where 'a' is acceleration of block B
upwards
 2g = 28 (a)

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 On solving, we get u = v/2
 v = 40 km/hr {u = 20 km/hr (given)}

(51) 2. Speed =  40 km/hr = 6 km/T

a
2  T = 9 min.
2T
(55) 2. amax = µsg = 0.2 × 10 = 2 m/s2
A

2T
(56) 3.
T T
T T
v21 = v2 – v1 = 90 km/hr
B a .
2g s21 = v21t =

Block A :
(57) 3.
2T = 5 (a/2) a = ___(1)
Block B : 2g – T = 2 (a) ___(2)
 2g – T = 2 ×  = 2g 

 2 = 3  
Reading = T =
(58) 8.
(52) 1. L= MaTb (ML2T–2)c (i) Since the lift is moving down with an
a+c=0 acceleration of 3 m/sec2, then the inertial
2c = 1 force F = ma, acts upwards on the body
c = 1/2., a = –1/2 R
F=ma
a = 3 m /s 2

b – 2c = 0 b = 1
(53) 4. Here, V = | t – 2 | = 2 – t for t  2
 t – 2 for 4 t > 2
mg

or Now, R + F = mg
or R = mg – F = mg – ma
= m (g – a) = 60 (9.8 – 3) = 408 N
(ii) When the lift is moving down with
constant velocity a = 0 and hence,
R = mg = 60 × 9.8 = 588 N
(54) 9. Let distance between the buses be L.
(iii) The lift is now moving down with a
Velocity of man relative to bus moving in
same direction = v – u retardation of 3 m/sec2.
and Velocity of man’s relative to bus The retardation is 3 m/sec2 in the
moving in opposite direction = v + u downward direction is equivalent to an
 v – u = L/(18min) & v + u = L/(6min) acceleration of
3 m/sec2 upwards.

7
 Hence the direction of fictitious force is a + a + 6d + a + 15d = 40
downwards. Now, 3a + 21d = 40
R = mg + ma = m (g + a) = 60 (12.8)
= 768 N
(59) 2. By substituting the dimension of given
quantities S15 = (2a + 14d) = 15 (a + 7d)

By comparing the power of M, L, T in

both sides (64) (4). A = x2 + y2  9  –3  x  3
x+y=0 .....(i)
–3  y  3
–x+z=0 .....(ii) 2 2
–2x – 3y – z = 0 …(iii) | x – 1 – x |  | x – 3x + 4 |
The only values of x, y, z satisfying (i),  – (x2 – 3x + 4)  (x – 1 – x2)  (x2 – 3x + 4)
(ii) and (iii) corresponds to x = 1, y = – 1,  3x – 4  x – 1 and 2x2 – 4x + 5  0
z=1  2x  3 ; x  3/2
(60) 5. Now, uplane – uair = So possible integral x are –3, –2, –1, 0, 1
If uair = N +y at x = 1 , y = –2, –1, 0, 1, 2
at x = 0, y = –3, –2, –1, 0, 1, 2, 3
uplane W E
+x at x = –1, y = –2, –1, 0, 1, 2
= S at x = –2, y = –2, –1, 0, 1, 2
at x = –3, y = 0
S = ut  and (65) (1). a – d + a + a + d = 33  a = 11
 x = – 3 kmph and y = – 4 kmph a (a2 – d2) = 1155
Ans. 5 kmph 121 – d2 = 105
(61) (3). a, b, c in G.P. d2 = 16  d = ±4
say a, ar, ar2 If d = 4 then Ist term = 7
Satisfies ax2 + 2bx + c = 0  x = –r If d = –4 then Ist term = 15
x = –r is the common root, satisfies second T11 = 7 + 40 = 47
equation d (–r)2 + 2e (–r) + f = 0 OR T11 = 15 – 40 = –25

(66) (1).
(62) (3). Let population = 100
A B

17 8 12


n (A) = 25
 S10 = 660
n (B) = 20
n (A  B) = 8 (67) (3). 4 – x2  0 ; x3 – x > 0
n (A  ) = 17 x = ± 2 ; x(x – 1) (x + 1) > 0
n ( B) = 12
–1 0 1
 Df  (–1, 0)  (1, 2)  (2, )
(68) (4). For (a, b), (c, d)  N × N
5.1 + 4.8 + 4 = 13.9
(63) (1). a1 + a7 + a16 = 40 (a, b) R(c, d)  ad (b + c) = bc (a + d)
Reflexive :

8
 Since ab (b + a) = ba (a + b)  ab  N, (73) (4).
 (a, b) R (a, b),  R is reflexive. Period of sin x = 2
Symmetric : For (a, b), (c, d)  N × N,
Let (a, b) R (c, d)  Period of f(x) = =
 ad (b + c) = bc (a + d)
 bc (a + d) = ad (b + c)  = 2  [a] = 4  a  [4, 5)
 cb (d + a) = da (c + b)  (c, d) R (a, b) (74) (4). |z – 4 – 3i| = 2 represents a circle with
 R is symmetric centre (4, 3) and radius 2.
Transitive :
(4 , 3 )
For (a, b), (c, d), (e, f)  N × N, P
Let (a, b) R (c, d), (c, d) R (e, f)
ad (b + c) = bc (a + d), cf (d + e) = de(c + f) O
 adb + adc = bca + bcd ... (i)
so minimum and maximum distances from
and cfd + cfe = dec + def ... (ii)
origin will be OP – r and OP + r
(i) × ef + (ii) × ab gives,
respectively.
adbef + adcef + cfdab + cefab
|z|min = 5 – 2 = 3
= bcaef + bcdef + decab + defab
 adcf (b + e) = bcde(a + f) |z|max = 5 + 2 = 7
 af (b + e) = be (a + f) (75) (2). nth term of the given series
 (a, b) R (e, f).
 R is transitive.
Hence R is an equivalence relation.
(69) (1). S= i + 2i2 + 3i3 + .... + 100 i100
iS = i2 + 2i3 + .... + 100 i101
S (1 – i)= i + i2 + i3 + .... + i100 – 100 i101

= – 50 (i – 1) = 50 (1 – i) 
(70) (3). f (x) = x – [x] + (x + 1) – [x + 1] + .........
(x + 99) – [x + 99]
= x – [x] + x – [x] + ..........+ x – [x]
= 100(x – [x]) = 100 {x}
= 100{ } = 41
(76) (2). f (x) = 2 x (x–1)
(71) (4). Let z = r (cos  + i sin ) = r ei It is one-one onto function
= [cos ( – /2) + i sin ( – /2)] log2y = x (x–1)
 x2 – x – log2y = 0
= ei ( – /2)

So  = r e–i × ei( – /2)= e–i /2 = –i

f–1(x) =
(72) (4).
(77) (3). If in a complex number a + ib, the ratio a :
– + – + b is 1 : is then always try to convert
–7 2 5 that complex number in .
Smallest integer is – 6

9
  |z1||z2||z3| = 12
Here,  =
 |z1 + z2 + z3| = 2
Therefore,

4+5

= 4 + 5334 + 3365
= 4 + 5 + 32 ( 3 = 1)
= 1 + 3 + 2 + 3 + 32
= 1 + 2 + 3 (1 +  + 2) = 1 + 2 + 3× 0
( 1 +  + 2 = 0)
= 1 + (– 1 + i) = i.
(78) (1).  +  =  – 3
 = 2 – 
2 + 2 = ( + )2 – 2 
= ( – 3)2 – 2 (2 – )
= 2 + 9 – 6 – 4 + 2= 2 – 4 + 5
= ( – 2)2 + 1
 =2
(79) (3). a1, a2, ....., a10 are in G.P.,
Let the common ratio be r

(80) (4).

Hence, y – x = 198 – 107 = 91

(81) 7. q2 – 4p  0
q = 2  p = 1
q = 3 p = 1, 2
q = 4  p = 1, 2, 3, 4
Hence 7 values of (p, q)
7 equations are possible.
(82) 2. |z1| = 1, |z2| = 2, |z3| = 3
|9z1z2 + 4z1z3 + z2z3| = 12
 ||z3|2 z1z2 + |z2|2 z1z3 + |z1|2 z2z3| = 12
 |z1z2z33 + z1z2z32 + z1z2z31| = 12
 |z1z2z3||1 + 2 + 3| = 12

10
  (4x2 – 2x + 1) (4x2 + 2x + 1) = 0
(83) 1.


i.e., the roots are


(84) 6. f4(x) – f6(x)

(89) 6. z11 + 2z10 + 3z9 + ........... + 2z2 + z = 0

(85) 3. 81x2 + kx + 256 = 0 ; x = , 3
 z (z10 + 2z9 + 3z8 + ........... + 2z + 1) = 0
  z (1 + z + z2 + z3 + z4 + z5)2 = 0

Now,  (z 1)
 k = ± 300
(86) 1. Given, 2x2 + x +  = 0 ....... (1)
x2 + 2x + 2 = 0 ....... (2)
2 × (2) 2x2 + 4x + 4 = 0 ....... (3)
 (1) – (3) ( – 4) x = 3 
On putting the above value in eq. (2), we get

  = 0

(87) 5. 


 Least value of b is 5.
(88) 8. 16x4 + 4x2 + 1 = (2x)4 + (2x)2 + 1
= [(2x)2 – 2x + 1) (4x2 + 2x + 1)
= (4x2 – 2x + 1) (4x2 + 2x + 1)
 16x4 + 4x2 + 1 = 0

11
  z (1 – z6)2 = 0
 z = 0 and every root of the equation
z6 – 1 = 0 (except z = 1) two times
repeated are the 11 roots of the given
equation.

(90) 5. If a is the first term and d the common

difference of the associated A.P. then
a + 9d = and a + 14 d = giving

d=

6th term of A.P. = a + 5d =

6th term of H.P. = 25

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