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hc
6.63 10 34 3 10 8
E=
=
45 10 9
w
2
n O2
50.
Ans.
Sol.
51.
Ans.
Sol.
52.
Ans.
Sol.
53.
w
32
n CH 4
So, ratio is
49.
E = 4.42 10 18 J
48.
Equal masses of H 2 ,O 2 and methane have been
taken in a container of volume V at temeprature
27C in identical conditions. The ratio of the
volumes of gases H 2 : O 2 : methane would be :
(1) 8 : 16 : 1
(2) 16 : 8 : 1
(3) 16 : 1 : 2
(4) 8 : 1 : 2
Ans. (3)
Sol. According to Avogadro's hypothesis volume moles
n H2
Ans. (4)
Sol. The distance between the body centred atom and
3a
2
46.
w
16
w
w
w
:
:
2
32
16
= 16 : 1 : 2
If a is the length of the side of a cube, the distance
between the body centered atom and one corner
atom in the cube will be :
(1)
2
a
3
4
a
(2)
3
(3)
3
a
4
3
a
(4)
2
Ans.
Sol.
n H2 =
n Cl2
initially
after reaction
V(L)
22.4
=1
22.4L 22.4
11.2
= 0.5 mole
22.4
= 1 mole
AIPMT-2014
54.
MnO24
55.
(2) 2 96500 C
(4) 96.50 C
Mn O 42
Mn O 4 + e
0.1 mole
0.1 mole
charge required = 0.1 F = 0.1 96500
= 9650 C
Using the Gibbs energy change, G = + 63.3kJ,
for the following raction,
Ag2 CO 3 2Ag+ (aq) + CO23 (aq)
Ans.
Sol.
w Ag
EAg
57.
59.
wO2
and KP are
e
(1) Kp > KP
(2) Kp < KP
(3) Kp = KP
(4) Kp =
1
K P
Ans. (2)
Sol. X2 O 4 () 2 XO 2 (g); n g = 2 0 = 2
H = U + n gRT
EO 2
600
w Ag 22400 32
108
8
wAg = 108g
Which of the following statements is correct for the
spontaneous adsorption of a gas ?
(1) S is negative and, therefore, H should be
highly positive
(2) S is negative and therefore, H should be
highly negative
(3) S is positive and, therefore, H should be
negative
(4) S is positive and, therefore, H should also
be highly positive
56.
Ans.
Sol.
Ans. (2)
Sol. During adsorption entropy decreases, so
S < 0.
G = H T S
For spontaneous adsorption G < 0 so H should
be highly negative.
58.
For the reaction :
X2 O 4 () 2XO 2 (g)
U = 2.1 k cal, S = 20 cal K 1 at 300 K
Hence G is :(1) 2.7 k cal
(2) 2.7 k cal
(3) 9.3 k cal
(4) 9.3 k cal
Ans. (4)
Sol. According to Le-Chatelier's Principle
In exothermic reactions low temperature
favours the forward reaction
On increasing pressure equilibrium shifts
towards less number of moles.
= 2.1 + 2
2
1000
300
H = 3.3 kcal
G = H T. S
= 3.3 300
60.
20
; G = 2.7 Kcal
1000
CODE-P
61.
1
mole,
24
Mg(s)
Initially
1
mole
24
n O2 =
67.
shape.
Acidity of diprotic acids in aqueous solutions
increases in the order :(1) H 2 S < H 2 Se < H 2 Te
(2) H 2 Se < H 2 S < H 2 Te
(3) H 2 Te < H 2 S < H 2 Se
(4) H 2 Se < H 2 Te < H 2 S
Sol.
68.
(a) H2 O 2 + O 3 H 2 O + 2O
H
H
= 1.4 D
F
0.23 D
(b) H2 O 2 + Ag 2 O 2Ag + H 2 O + O
Ans. (3)
69.
(2) Sucralose
(3) Aspartame
(4) Alitame
Ans. (3)
70.
N
F
(4) CO 2
(3) NO2
Ans. (1)
0.56
mole
32
>
(2) NO3
Sol.
MgO(s)
0.0416 mole
0.0175 mole
0
after (0.0416 2 0.0175) 0
2 0.0175 mole
reaction 0.0066 mole
mass of Mg = 0.0066 24g = 0.16 g
63.
The pair of compounds that can exist together is:(2) HgCl 2 , SnCl 2
(1) FeCl3 , SnCl 2
(3) FeCl2 , SnCl 2
(4) FeCl3 , Kl
Ans. (3)
Sol. Both are reducing agent
64.
Be 2+ is isoelectronic with which of the following
ions ?
(1) H +
(2) Li+
(3) Na +
(4) Mg2+
Ans. (2)
Sol. Li+ , Be +2 & Li + both have 2 electron.
65.
Which of the following molecules has the maximum
dipolement ?
(1) CO 2
(2) CH 4
(3) NH3
(4) NF3
Ans. (3)
Sol.
(1) N3
Ans. (2)
0.56
moles
32
1
O 2 (g)
2
Sol.
66.
(1) + 5
(2) + 3
(3) + 6
(4) 10
Ans. (3)
O
Sol.
O
Cr
O
3
AIPMT-2014
Ans.
Sol.
73.
Ans.
Sol.
74.
Ans.
Sol.
75.
Ans.
Sol.
76.
N N.Cl+ H
H
NNCl
77.
salt RN +2 X ?
+
(1) CH 3 N 2 X
78.
Salt
N = N:
N = N:
N = N:
CH = NOH
CH = NOH
H C OH
is :-
N=NNH
N=N
HO C H
HO C H
HO C H
(2)
HO C H
H C OH
H C OH
H C OH
CH 2OH
CH 2OH
CH = NOH
CH = NOH
HO C H
H C OH
H C OH
N=N
NH2
(A)
(4) C6 H 5 CH 2 N 2 X
(1)
N=N
N N
(3)
(4)
(2) C6 H 5 N 2 X
Ans. (2)
Sol. Primary aliphatic amines form highly unstable
alkyldiazonium salts. Primary aromatic amines form
arene diazonium salts which are stable for a short
time in solution at low temperature (273 278 K).
The stability of arenediazonium can be explained
on the basis of resonance.
NH2
(3)
(3) CH 3 CH 2 N 2 X
NH 2
(2)
NH 2
Yellow dye
(1)
p-Aninoazobenzene
(yellow dye)
+Cl + H O
2
NH2
NH 2
N=N
72.
Ans. (4)
Sol. This is an example of electrophilic substritituion
reaction [coupling reaction]
Ans.
Sol.
71.
HO C H
H C OH
CH 2OH
HO C H
(4)
H C OH
H C OH
CH 2OH
CODE-P
Ans. (4)
Sol. Glucose reacts with hydroxyl amine to form an
oxime.
CH=NOH
OH
H
CHO
H
OH
H
OH
OH
CH2OH
HO
H
H
HO
H
H
NH-OH
OH
OH
CH2OH
D(+)glucose
79.
(3) Adrenaline
Ans.
Sol.
Cl
83.
( CH 2 CH )n
Cl
OH
(4)
82.
( CH 2 C = CH CH 2 ) n
(3)
nHOCH2 CH2OH +
Ethylene glycol
[Ethane-1,2-diol]
Ans. (3)
Sol. Adrenaline commonly known as fight or flight
hormone, it is produced by the adrenal glands after
receving a message from the brain that a stressful
situation has presented itself.
80.
Which one of the following is an example of a
thermosetting polymer?
(2)
CH 2
OH
Ans.
Sol.
CH 2
n
Ans. (4)
Sol. Thermosetting polymers are cross linked or heavily
branched molecules, which on heating undergo
extensive cross linking in moulds and again become
in fusible. Most common examples are bakelite.
COOH
Terephthalic acid
[Benzene-1,4-di
carboxylic acid]
O
OCH2CH2OC
(4) Estradiol
(1)
(2) Insulin
81.
Terylene or Dacron
O
C
O
n
14 20 10 3
100 = 37.33%
0.75
5
AIPMT-2014
84.
CH 3
CH3
CH 3
CH3
b
CH 3
Br
(1)
CH 3
CH 3
and
CH 3
Br
b & c results in
and
CH 3
CH 3
85.
Br
CH 3
CH 3
Br
CH 3
Br
(ii) CH3 CH 2 CH 2 Cl
(4)
and
Br
CH 3
CH 3
CH 3
CH 3
Br
CH 2Cl
(i)
and
(3)
CH 3
(2)
CH 3
Br
CH 3
(iii) H 3C CH CH 2Cl
CH 3
(iv) H
Cl
C2H 5
CH 3
Ans. (1,2)
CH3
CH3
CH3
CH3
Br
Br2
FeBr 3
Sol.
CH3
CH 3
Br
(major)
CH 3
(minor)
Sol.
Cl results in
C 2H 5
formation of racemic product due to chirality.
CODE-P
86.
3I
Ans. (4)
Sol. Reactivity of carbonyl compounds towards NAR
depends on steric and electronic effects.
NAR reactivity :
CHO
CHO
>
CHO
>
COCH 3
>
Ans. (2)
NO 2
OH
Sol.
O Na
NaOH
H 2O
M of NO 2
OCH 3
CH 3I
(SN2 )
89.
CH 3 CH 2 CH = CH
(1)
COCH 3
(2)
CHO
(3)
CHO
(4)
CH 3
HBr/H 2 O2
C 2 H 5 ONa
Y
Z
(1) CH 3 (CH 2 )3 O CH 2 CH 3
(2) (CH3 )2 )CH 2 O CH 2 CH 3
(3) CH 3 (CH 2 )4 O CH
(4) CH 3 CH 2 CH(CH 3 ) O CH 2 CH 3
+ H 2 Co 3 carbonic acid
88.
Ans. (1)
O Na
NO 2
c of
Sol.
87.
OH
CH 3
NO 2
Sol.
HBr/H O
2 2
CH 3 CH 2 CH=CH 2
(Peroxide effect)
CH 3CH 2CH CH
2
2
(y)
Br
CH 3(CH 2)3 OCH 2CH 3
(z)
90.
5
C 2 H 2 + O 2
2CO 2+ H O
2
2
Both HC CH & CO
carbon atom. (sp).