II YR OUT GOING KCET GT -3 Date: 07.04.

2024
Time:1HRS K-CET Max. Marks: 60M
CHEMISTRY

1. The velocity of an electron with de Broglie wavelength of 1.0 102 nm is

1 ) 7.2  105 cm / sec 2) 72  105 cm / sec

3) 7.2  10 4 cm / sec 4) 3.6  105 cm / sec

2. Which one of the following set of quantum numbers is not possible for a 4p electron

1 1
1) n  4, l  1, m  1, ms   2) n  4, l  1, m  0, ms  
2 2

1 1
3) n  4, l  1, m  2, ms   4) n  4, l  1, m  1, ms  
2 2

3. Successive ionization potentials of an element M are 8.3, 25.1, 37.9, 259.3 and 340.1 ev. The
molecular weight of the oxide of the element A is (x is atomic weight)

1) MBr5 2) MBr4 3) MBr3 4) MBr2

4. Oxide that is most acidic

1) Cl2O7 2) SO3 3) P4O10 4) N 2O5

5. Octet rule is not valid for the following molecule

1) CO2 2) N 2 3) O2 4) BF3

6. Shape of hydronium ion is  H 3O  

1) Tetrahedron 2) Square Planar 3) Planar triangle 4) Pyramidal

7. The structural formula of a compound is CH 3  CH  C  CH 2 the type of hybridization at the four

carbons from left to right are

1) sp 3 , sp, sp 2 , sp 3 2) sp 2 , sp3 , sp 2 , sp

3) sp 3 , sp 2 , sp, sp 2 4) sp 2 , sp 2 , sp 3 , sp 2

8. The vapour density of ethyl alcohol vapour is

1) 46 2) 23 3) 92 4) 69
9. When equal masses of methane and sulphur dioxide are taken , than the ratio of their molecules is

1) 1 : 1 2 )1 : 2 3) 2 : 1 4) 4 : 1

10. If 1.26 grams of oxalic acid (MW =126) is dissolved in 250 ml of solution then its normality

1) 0.05 2) 0.04 3) 0.02 4) 0.08

11. Oxidation number of carbon in CO2 & CCl4

1) +4, -4 2) +4, +4 3) -4 , -4 4) -4, +4

12. Decreasing order of oxidation number of iodine (form left to right )

1) I 2 , ICl , HI , HIO4 2) HIO4 , ICl , I 2 HI

3) I 2 HI , ICl , HIO4 4) HI , I 2 , ICl , HIO4

33. If K1 and K2 are the equilibrium constants of the equilibrium (A) and (B) respectively.What is the
relationship between the two constants

A) SO2  g   1 / 2O2  g   SO3  g  K1

B) 2 SO3  g   2 SO2  g   O2  g  K 2

1 1
1) K1  K 2 2) K1  3) K 2  K12 4) K12 
K2 K2

14. The equilibrium constant for the reaction H 2O( l )  CO g   H 2 g   CO2 g  is 64 . If the rate constant
for the forward reaction is 160, the rate constant for the backward reaction is

1) 0.4 2) 2.5 3) 6.2 4) 10.24  103

15. From the reaction equilibrium, N 4O4  g   2 NO2  g  the concentration of N 4O4 and NO2 at
equilibrium are 4.8  102 and1.2  102 moL1 , respectively.The velue of K c for the reaction is \

1) 3.3  10 2 molL1 2) 3.3  10 1 molL1

3) 3.3  10 3 molL1 4) 3.3  103 molL1

76. Which of the following is not Lewis acid

1) AlCl3 2) BaCl2 3) BCl3 4) SnCl4

17. The PH of 0.005 MH2SO4 is

1) 2.5 2) 4.5 3) 2.0 4) 1.0

18. K sp of salt A 3B2 ,for solubility x mol L1 is

1) 36x 2) 36x 6 3) 108x 5 4) 108x 6

19. The relationship between H and E for the reaction PCl3  g   Cl2  g   PCl5  g  is given as

1) H   E  RT 2)  H  E  RT

3) H  E  2 RT 4)  H  E  2 RT

20. The heat of combustion of C2 H 4 , C2 H 6 and H 2 gases are 1409.5kJ , 1558.3kJ and  258.6 kJ
respectively. The heat of hydrogenation of ethene is

1) -136.8kJ 2) -13.68kJ 3) 273.6 kJ 4) 1.368 kJ

21. Enthalpy of vapourisation for water is 186.5kJ mole-1 . The entropy change during vapouriusation
is___kJmole-1

1) 0.5 2) 1.0 3) 1.5 4) 2.0

22. The IUPAC name of the compound shown below is

1) 2 – bromo – 6 – chloro cyclohex – 1 – ene

2) 6 – bromo – 2 – chloro cyclohexene

3) 3 – bromo – 1 – chloro cyclohexene

4) 1 – bromo – 3 – chloro cyclohexene

23. CH 3CH 2CH 2OH is a functional isomer of ketone to show position isomerism

1) C2 H 5OCH 3 2) CH 3OC3 H 7

3) CH 3CH 2CH 2OCH 2CH 3 4) CH 3CHOHCH 3

24. Hyperconjugation involves overlap of the following orbitals

1)    2)    3)    4)both 1 and 3

25. 0.12 g of an organic compound gave 0.22 g of Mg 2 P2O7 by the usual analysis.The percentage of
phosphorus in the compound is

1) 15.23 2) 38.75 3) 51.20 4) 60.92

26. An alkane cannot be chlorinated by using which of the following reagents?

1) Cl2 / hv 2) HCl 3) SO2Cl2 4) t  Bu  O  Cl


27. C2 H 6 
1000 C
 A 
S 2Cl2
 B . Here ‘B’ is

1)  C2 H 5 2 S 2)  C2 H 4Cl 2 S 3)  CH 3Cl 2 S 4)  CH 3 3 S

HgSO4  dill . H 2 SO4

28. CaC2 
Hydrolysis
 A   B .B is

1 ) Acetylene 2) Acetaldehyde 3) Acetone 4) Acetic acid

29. A mong the following the aromatic compound is

30. The major organic product form the reaction C6 H 6  CH 3COCI / AlCl3 is

1) C6 H 5Cl 2) C6 H 5COCl

3) C6 H 5COCH 3 4)

31. The volume of 0.025M H 2 SO4 required for the complete neutralisation of 25 ml of 0.3M Ca(OH )2
solution is

1) 20ml 2) 30ml 3) 25 ml 4) 35 ml

32. 18 g of glucose C6 H12O6 is dissolved in I kg of water in a saucepan. At what temperature will water
boil at 1.013 bar? For water 0.52 K Kg mol-1

1) 186. 101 2) 93.090 3) 280.292 4) 373.202

33. For a very dilute aqueous solution of K 4  Fe  CN 6  ,van ‘t Hoff factor is

1
1) i  11 2) i  5 3) i  4) i  10
11
34. The molar conductance’s of HCl , NaCl and CH 3COONa are 426 , 126 and 91 1cm 2 mol 1
respectively .The molar conductance for CH 3COOH is

1) 561  1cm2 mol 1 2) 391 1cm 2 mol 1

3) 261  1cm 2 mol 1 4) 612 1cm 2 mol 1

35. One ampere of current is passed for 9650seconds through molten AlCl3 .What is the weight in grams
of Al deposited at cathode? (Atomic weight of Al =27)

1) 0.9 2) 9.0 3) 0.09 4) 90.0

36. The EMF of the cell Ni / Ni 2  0.01M   Cl 1 (0.01M ) / Cl2 , pt is ______V if the SRP of nickel and
chlorine electrodes are -0.25V and +1.36V respectively

1) +1.61 2) -1.61 3) +1.79 4) -1.79

37. The rate of the reaction at 400C is 5 units then the rate of same reaction at 800C is (nearly)

1) 10 units 2) 40 units 3) 20 units 4) 80 units

38. Half-life of a zero order reaction is 250sec. t75% , t100% of the reaction respectively in sec.are

1) 500,375 2) 375,500 3) 300 , 575 4) 575, 300

39. The decomposition of ozone proceeds as

O3  O2  O ( fast )

O  O3  2O2 ( slow)

The rate expression should be

1) Rete = k O3  2) Rate  k  O3  O2 

2 2 1

3 ) Rate = k O3 O2  4) Rate = k O3 O2 

1

40. Which of the following statement is not correct

1) Copper liberates hydrogen from acids

2) In higher oxidation states, manganese forms stable compounds with oxygen and fourine

3) Mn3 and CO 3 are oxidizing agents in aqueous solutions

4) Tn 2 and Cr 2 are reducing agents in aqueous solutions

41. The ‘spin – only’ magnetic moment [in units of Bohr magneton ,     of Ni 2 in aqueous solution
would be (atomic number of Ni =28)
 1) 2.48 2) 4.90 3) 0 4) 1.73

42. Which of the following pairs is coloured in aqueous solutions

1) Sc3 , Co2 2) Ni 2 , Cu  3) Ni 2 , Ti 3 4) Sc 3 , Ti 3

43. Which of the following isomeric pairs shows ionization isomerism

1) Co  NH 3 6  Cr  CN 6  and Cr  NH 3 6  Co  CN 6 

2) Cr  H 2O 6  Cl3and Cr  H 2O 5 Cl  Cl2 .H 2O

3)  Pt  NH 3  2 Cl2  and  Pt  NH 3 4   PtCl4 

4) Co  NH 3 5 Br  SO4 and Co  NH 3 5 SO4  Br

44. IUPAC name of

[ Pt ( NH3 )3 Br ( NO2 ) Cl ] Cl is

1 ) Triammine chloro bromo nitroplatinum ( IV ) chloride

2 ) Triammine bromo nitro chloroplatinum ( IV ) chloride

3 ) Triammine bromo chloronitroplatinum ( IV ) chloride

4 ) Triammine nitro chloro bromoplatinum ( IV ) chloride

45. Ziegler - Natta catalyst is

1 ) Solution of SnCl4 + trialkylaluminium

2 ) Solution of Ti Cl4 + trialkylaluminium

3 ) Solution of Ti Cl4 + trialkylchromium

4 ) Solution of Sn Cl4 + Tollen's reagent

46. IUPAC name of

1 ) 2 - bromo - 3 - methyl pentane

2 ) 2 - bromo - 3,3 - dimethyl butane

3 ) 4 - bromo - 3,3 - dimethyl butane

4 ) 2 - bromo - 3,3 - dimethyl pentane

47. C2 H 5OH  SOCl2 

Pyridine
x y z

This reaction x, y and z respectively are

 1) C2 H 5Cl2 , SO2 , HCl 2) C2 H 5Cl , SO2 , HCl

3) C2 H 5Cl , SOCl , HCl 4) C2 H 4Cl , SO2 , Cl2

48. Which of the following alkyl halide is hydrolysed SN1 mechanism

1) CH 3Cl 2) CH 3  CH 2  Cl

3) CH 3  CH 2  CH 2  Cl 4)  CH 3 3 C Cl

 2  H 2O / Zn   A    B  PRODUCT ((B) is

 31O
49. RCH  CH 2  LiAlH 4

1)RCHO+HCHO 2) RCHO+HCOOH

2) RCOOH+HCOOH 4) RCH2OH+CH3OH
Pd  BaSO4 / Quinoline
50. H  C  CH  H 2   A  
HCl
 B 
KOHaq
 C Here the ' C ' is

1) Propane 2) Ethanol 3) Ethyne 4) Ethylene

51. Which order is correct about acidity

1) CH 3COOH  C6 H 5COOH  C6 H 5OH

2) C6 H 5COOH  CH 3COOH  C6 H 5OH

3) C6 H 5OH  C6 H 5COOH  CH 3COOH

4) C6 H 5OH  CH 3COOH  C6 H 5COOH

52. Tollens reagent is :

1 ) alkaline mercuric chloride 2 ) alkaline potassium permanganate

3) ammoniacal silver nitrate 4 ) ammonium citrate

53. Match the following

Column – 1 Column -1

A ) Grignard reagent 1) H/Pd – BaSO4

B) Clemmeson reductio 2) N2H4/KOH/CH2OH- CH2OH

C) Rosenmund ‘s reduction 3) CH3MgX

D) Wolf – Kishner reduction 4) Zn – Hg /Conc.HCl

5) H2/Ni

A B C D

1) 3 4 2 1
 2) 3 4 1 2

3) 2 1 4 5

4) 5 3 2 1

54. 1. The correct order of reactivity of acyl compounds is

1 ) acid chloride > amide > anhydride > ester

2 ) acid chloride > anhydride > ester > amide

3 ) ester > acid chloride > anhydride > amide

4 ) ester > anhydride > acid chloride > amide

55. Bromine water reacts with aniline to give

1) o - bromoaniline 2 ) p - bromoaniline

3) m - bromoaniline 4)symmetric tribromoaniline

56. In gaseous state , the correct basic strength among the following is

1) ( C2 H5 )3 N > ( C2 H5 )2 NH > C2 H5 NH2 > NH3

2 ) ( C2 H5 )2 NH > ( C2 H5 )3 N > C2 H5 NH2 > NH3

3 ) ( C2 H5 )2NH > C2 H5 NH2 > ( C2 H5 )3 N > NH3

4 ) ( C2 H5 )3 N > C2 H5 NH2 >( C2 H5 )2 NH> NH₂

57. Statement - I : Alkyl isocyanide can be prepared by carbyl amine reaction .

Statement - II : Ethyl amine when heated with chloroform in presence of alcoholic KOH ,
alkanamide is formed

1) Statement - I is True , Statement - II is True ;

Statement - II is a correct explanation for Statement - I

` 2 ) Statement - I is True , Statement - II is True ;

Statement - II is NOT a correct explanation for Statement - I

3 ) Statement - I is True , Statement - II is False .

4 ) Statement - I is False , Statement - II is True

58. Which of the following compound will not show mutarotation

1) Methyl –  – D – glucopyanoiside 2)  – D(+) glucospyanose

3)   D (+) glucospyanose 4)  – D(+) – galactopyranose

59. The number of polypeptide chains present in haemoglobin is

1) Two 2) Four 3) Nine 4) 50

60. Match the following

List -1 List – 11

A) Vitamin A 1) Calcfierol
B) Vitamin D 2) Tocopherol derivative
C) Vitamin C 3) Retinol
D) Vitamin K 4) Anti haemorrhagic
5) Thiamin

1) A – 3, B – 1 ,C – 2 , D – 4 2) A – 3, B – 1 ,C – 2 , D – 5

3) A – 3, B – 1 ,C – 4 , D – 2 4) A – 1, B – 3 ,C – 2 , D – 4