KARNATAKA

KCET-2020 CRASH COURSE

CHEMISTRY ASSIGNMENT
SOME BASIC CONCEPTS OF CHEMISTRY & REDOX REACTION - DAY - 1 (10-06-2020)

1. According to Lanes process of manufacture of H 2 gas, 3Fe  4 H 2O  Fe3O4  4 H 2 the equivalent weight
of Fe is ( At. wt. of Fe = 56 )
1) 3 2) 21 3) 42 4) 84
2. 2.4 g Mg gets converted to 9.5 g of MgCl2 . The Eq. wt. of Mg is :
1) 1.2 2) 2.4 3) 12 4) 7.1
3. 0.3269 g of a metal ‘A’ displaces 0.3177 g another metal ‘B; of equivalent wegith 31.77 g. What is the gram
equivalent weight of ‘A’?
1) 3.177 2) 31.77 3) 3.260 4) 32.69
4. 0.24 g of Ca metal burns in air to give 0.335 g of calcium oxide. The eq. wt. of Ca is :
1) 18.8 2) 19.9 3)20.2 4) 23.0
5. Passage of the same quantity of electric charge through ZnSO4 and CuSO4 solutions connected in series
produces 1.308 g Zn and 1.271 g Cu at electrodes. If the equivalent weight of Cu is 31.77 g, what is the
equivalent weight of Zn ?
1) 63.54 g 2) 2.579 g 3) 65.4 g 4) 32.7 g
6. B1 g of an element gives B2 g of its chloride, the equivalent mass of the element is

B1 B2 B2  B1 B2  B1
1) B  B  35.5 2) B  B  35.5 3) B1
 35.5 4) B2
 35.5
2 1 2 1

7. A metal M of equivalent mass E forms an oxide of molecular formula M x Oy . The atomic mass of the metal is
the given by the correct equation
1) 2E  y / x  2) E / 2  x / y  3) xy / E 4) E / y
8. The equivalent mass of Fe in FeO is
1) 56 2) 28 3) 36 4) 18.66
9. Find the equivalent mass of zinc if 1.98 g of zinc displaced 1.92 g of copper from CuSO4 solution. ( equiva-
lent mass of Cu = 31.8 )
1) 32.79 2) 32.3 3) 65.5 4) 63.5
10. 1.520 g of a certain metal hydroxide on ignition gave 0.995 g of metal oxide. The equivalent mass ofthe metal
is
1) 3 2) 18 3) 12 4) 9
11. The equivalent mass of an element is 4. Its chloride has a vapour density 59.25. The valency of the element
is
1) 4 2) 3 3) 2 4) 1
12. 1.575 g of CdCl 2 was found to contain 0.9367 g of Cd. What is the atomic weight of Cd ?
1) 48 2) 56.26 3) 96 4) 104
13. 1.4 g of iron displaced 1.6 g of Cu from a solution of CuSO4 . If the equivalent mass of Fe is 28, then that of
Cu is
1) 16 2) 32 3) 48 4) 64
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14. The equivalent mass of a metal is 12. The oxide of the metal contains
1) 12 % metal 2) 60 % oxygen 3) 40 % oxygen 4) 8 % metal
15. Molecular weight of KMnO4 is 158 g mol 1 . In acidic medium its equivalent weight is :
1) 15.8 g 2) 158 g 3) 79 g 4) 31.6 g
16. Phosphorous forms two chlorides which have different compositions. The equivalent of which element re-
mains constant ?
1) neither element 2) both elements 3) phosphorous 4) chlorine
17. The equivalent of chromium in CrCl3 and Cr2  SO4  are

1) the same 2) that in Cr2  SO4  is half that of CrCl3

3) that in Cr2  SO4  is twice than in CrCl3 4) cannot be predicted

18. The equivalent mass of anhydrous sodium carbonate is equal to
1
1)  formula mass 2) 2  formula mass 3) 5  formula mass 4) 3  formula mass
2
19. The equivalent mass of Na2 S 2 O3 .5 H 2 O
1) 248 2) 24.8 3) 124 4) 12.4
20. A sample of chlorine contains Cl  35 and Cl  37 isotopes in the ratio 3 :1 . The average atomic mass of
chlorine is :
1) 36 2) 18 3) 35.5 4) uncertain
21. H 2 SO4 has 32.653% sulphur in it. The atomic weight of sulphur is :
1) 32.653 2) 32 3) 16 4) cannot be calculated
22. Number of C-atoms present in 600 mg of graphite is :
1) 6.023  1023 2) 3.612  1024 3) 3.01 1022 4) none of these
23. Oxygen contains 90% 16 O and 10% 18 O ( very close approximation ). Its atomic mass is :
1) 16.2 2) 17.4 3) 17.0 4) 16.5
24. C p , Cv and vapour density of an elementary gas respectively are 0.125 and 0.094. The atomic weight of
element is :
1) 12 2) 15 3) 16 4) 56.1
25. 6.4 g of which of the following gas will occupy 2.24 L volume at STP ?
1) N 2 2) CO2 3) C2 H 6 4) SO2
26. A protein contains 0.16% sulphur in it. The minimum molecular weight of protein is :
1) 2  10 4 g 2) 1.6  104 g 3) 3.2  104 g 4) none of these
27. 0.24 g of a volatile substance displaced 53.78 mL of air at STP. The molecular weight of the substance is :
1) 24 g 2) 53.78 g 3) 50 g 4) 100 g
28. In Victor Meyer’s method 0.46 g of a volatile compound displaced 86.23 cm3 of air. The V.D. of the
compound is :
1) 46 2) 86.23 3) 59.75 4) 46.43
29. The mass of an atom of silver ( At. Wt. = 108 g ) is :
108 108
1) 108 g 2) N 3) 108 N A 4)
A 12
30. Total number of molecules of H 2 SO4 in its 2.45 g is :
1) 1.05  1023 2) 1.5  1022 3) 1.25  1023 4) none of these
31. 10 L of each of H 2 ( molar mass = 2 g ) O2 ( molar mass = 32 g ) and C4 H10 ( molar mass = 58 ) are
separately taken in three flasks at 00 C and 1 atm. The ratio of the number of their molecules will be :
1) 1:16 : 29 2) 29 :16 :1 3) 1:1:14 4) 1:1:1

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32. Vapour density of ammonia is 8.5. 85 g of NH 3 at STP occupies a volume of
1) 224 L 2) 1120 L 3) 112 L 4) 22.4 L
33. The molecular mass and atomic mass of sulphur are 256 and 32 respectively. The molecular formula of
sulphur is
1) S 6 2) S 3) S8 4) S 2
34. Volume in dm3 occupied by 1 mole of a gas at STP is
1) 12.0 2) 22.4 3) 24.0 4) 100
35. The mass of 1dm of oxygen compared with the mass of 1dm of hydrogen under same condition
3 3

1) 2 2) 4 3) 8 4) 16
36. The volume in dm3 occupied by 7.3 g of hydrogen chloride at STP
1) 22.4 2) 4.48 3) 2.8 4) 11.2
37. The number of molecules (approxmately) of HCl present in 3.64 g is
1) 2.7  1022 2) 3.7  10 22 3) 4.7  1022 4) 6.02  10 22
38. The molecular mass of  NH 4 2 SO4 is
1) 114 2) 146 3) 132 4) 70
39. Which of the following contains least number of molecules ?
1) 16 g of CO2 2) 8 g of CO2 3) 4 g of N 2 4) 2 g of H 2
40. Which of the following is the heaviest ?
1) 25 g of Hg 2) 2 moles of H 2O 3) 2 moles of CO2 4) 4 g atoms of oxygen
41. Avogadro number of helium atoms weigh
1) 1.00 g 2) 4.00 g 3) 8.00 g 4) 6.022 10 23 g
42. Which of the following contains largest number of atoms ?
1) 2.0 mol of H 2) 8.22  1024 H atoms 3) 18.0 g H 2 4) 10.0 g Cl2
43. 60 g carbon contains as many atoms as
1) 190 g F 2) 100 g Ca 3) 60 g Co 4) 20 g He
44. Which of the following contains 6.02  10 molecules
23

1) 12 g CH 4 2) 6 g H 2O 3) 5 g C2 H 6 4) 17 g NH 3
45. The number of moles of nitric acid present in 28.5 g of the sample is
1) 0.452 mol 2) 4.25 mol 3) 2.125 mol 4) 0.2125 mol
46. Number of kilograms of oxygen present in 10 kg of water is
1) 32 2) 8.89 3) 16.6 4) 15.5
47. 6  1023 molecules of CaCO3 gives
1) 6.023  1023 molecules of carbon dioxide 2) 3.011 1023 molecules of carbon dioxide
3) 2  6.023  10 23 molecules of caron dioxide 4) 3.011 1011 molecules of carbon dioxide
48. The mass in grams of magnesium oxide MgO, formed when 6 g Mg is burnt in oxygen.
1) 24 2) 16 3) 10 4) 12
49. In Victor-Meyer’s method, 0.2 g of an organic compound displaced 56 mL of air at STP. The molecular
weight of the compound is
1) 56 2) 112 3) 80 4) 28
50. The element whose atom has a mass of 6.642  10 kg is
26

1) Silver 2) Zinc 3) Calcium 4) Boron

51. The weight of 1 1022 molecules of CuSO4 .5H2O is
1) 42.42 g 2) 41.42 g 3) 44.44 g 4) 48.94 g
52. The number of molecules in 16 g of methane is
16 23 16 23
1) 3.0  1023 2) 6.022  1023 3) 60.22  10 4) 3.0  10

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53. 4.4 g of an unknown gas occupies 2.24 L of volume under NTP conditions. The gas may be
1) CO2 2) CO 3) O2 4) SO2
54. The weight of 2.8 L of a gas at NTP is 3.50 g. Its vapour density is
1) 14 2) 28 3) 32 4) 20
55 The density of air is 0.001293 g mL . Its vapour density is
 1

1) 143 2) 14.3 3) 1.43 4) 0.143

56. Boron has two isotopes 10 B and 11 B . If the atomic mass of boron is 10.81, then the ratio of 10 B and 11 B in
nature is
1) 19/81 2) 15/16 3) 10/11 4) 100/110
57. The number of gram molecules of oxygen in 6.02  10 CO molecules is
24

1) 10 g molecules 2) 5 g molecules 3) 1 molecules 4) 0.5 molecules

58. The total number of valence electrons in 42gm of nitride ion  N 3   are
1) 2.4 N A 2) 4.2 N A 3) 3.2 N A 4) 1.6 N A
59. 0.075 g of a liquid on vaporisation gave 1.5 cm3 of vapour at STP. The molecular mass of the liquid is
1) 96 2) 56 3) 112 4) 5.6
60. When methane is burnt in excess of oxygen, the products formed are carbon dioxide and water. In equation
for the combustion, CH 4  O2  CO2  2 H 2O , the coefficient of O2 should be
1) 1 2) 2 3) 3 4) 4

KEY

01) 2 02) 3 03) 4 04) 3 05) 4 06) 1 07) 1 08) 2 09) 1 10) 4
11) 2 12) 4 13) 2 14) 3 15) 4 16) 4 17) 1 18) 1 19) 3 20) 3
21) 2 22) 3 23) 1 24) 3 25) 4 26) 1 27) 4 28) 3 29) 2 30) 2
31) 4 32) 3 33) 3 34) 2 35) 4 36) 2 37) 4 38) 3 39) 3 40) 3
41) 2 42) 3 43) 4 44) 4 45) 1 46) 2 47) 1 48) 3 49) 3 50) 3
51) 2 52) 2 53) 1 54) 1 55) 2 56) 1 57) 2 58) 1 59) 3 60) 3

HINTS

1. 8g hydrogen  3  56g Fe
3  56
1 g hydrogen   21g Fe = Eq. wt
8
weight  35.5
2. Eq. wt of Mg  weight of chlorine

2.4  35.5 2.4  35.5

   12
 9.5  2.4 7.1

weight of metal ' B ' Eq. wt. of metal ' B '

3. 
weight of metal ' A ' Eq. wt. of metal ' A '
0.3177 31.77 31.77  0.3269
   Eq wt. of ‘a’  32.69
0.3269 Eq.wt of ' A ' 0.3177
weight  8
4. Eq. wt of Ca  Re lated Wt. of oxygen  g 

0.24  8 0.24  8
   20.21g
 0.335  .024 0.095
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 Eq.wt.of Zn Weight of Zn deposited
5. 
Eq.wt.of Cu Weight of Cu deposited
1.308
Eq. wt. of Zn =  31.77  32.69 g
1.271
Weight of the metal
6.  35.5
wt.of the Chlorine
7. Conceptual
8. Equivalent mass of Fe in
Atomic mass 56
FeO    28
Positive valency 2
9. Use the formula
Mass of Zn Eq. mass Zn

Mass of Cu Eq.mass of Cu

1.98 E
 
1.92 31.8

1.98
or E  31.8  32.79
1.92
Mass of metal hydroxide
10. Mass of metal oxide

E  Eq.mass of OH  ion

E  Eq.mass of O 2  ion

1.520 E  17
 
0.995 E8
 E  17  0.995   E  8 1.520
on solving E = 9
11. Mol. wt. of MCl x  59.25  2  119
Mol. wt of MCl x = At. wt. of
 M  x  35.5
 E  x  35.5 x
 x  E  35.5 

119 119
 x  E  35.5  39.5  3

12. Mass of CdCl 2  1.575g

Mass of Cd = 0.9367 g
Mass of chlorine = 1.575  0.9367  0.6383g
Eq. mass of Cd
Mass of Cd 0.9367
  Eq.wt . of chlorine   35.5
Mass of chlorine 0.6383

Mass of iron Equivalent mass of iron

13. 
Mass of copper Equivalent mass of copper

1.4 28
 or ECu  32
1.6 ECu

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14. 12 g of the metal combines with 8 g of oxygen to form the oxide.
Hence mass of the oxide = 12  8  20
12  100
 % age of the metal of the oxide =  60
20
 %age of oxygen = 40
15. Conceptual
16. Conceptual
17. Conceptual
18. Conceptual
19. Conceptual
 35  3   37  1 
105  37
 35.5
20. Av. At. wt of Cl 
4 4
21. Conceptual
0.6 0.6
22. 600 mg = 0.6 g  mol   6.02  1023 C  atoms
12 12
3.01 1022 C  atoms
16  90  10 18
23. Atomic mass = 100

CP 0.125
24.   1.33 i.e., the gas is triatomic
CV 0.094
Molar mass 2  V .D 2  24
At. wt    16
3 3 3
25. 2.24 L = 64 g
6.4  22.4
22.4 L   64 g  SO2 gas
2.24
1 32  100
26. 0.1 
MW
W
27. Molar mass V  22400  0.24  22400  5376  100 g
STP  mL  53.78 5378
Weight  11200 0.46  11200
28. V .D.  =  59.75 g
Vol. of air displaced at STP 86.23
29. The mass of one atom
Gram At.wt 108

Avogadro ' s number N A
2.45
30. 2.45 g H 2 SO4 mol = 0.025 mol H 2 SO4
98
= 0.025  7 kt 6.02  1023 molecules of H 2 SO4
 1.5 10 22 molecules of H 2 SO4
31. Equal volumes of all the gases under the same conditions of temperature and pressure contain equal number
of molecules, 1:1:1
32. Molecular mass = 2  vap density  2  8.5  17
22.4  85
17 g of ammonia at STP=22.4 L; 85 g of ammonia at STP  112 L
17
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33. Number of atoms in the molecule
mol mass 256
=  8;
at.mass 32
Molecular formula  S8
34. Conceptual
mass of 22.4 dm3 of oxygen 32
35. 3
  16
mass of 22.4 dm of hydrogen 2
36. Molecular mass of HCl = 36.5
36.5 of HCl occupies 22.4 L;
22.4  7.3
73 g of HCl occupies  4.48 L
36.5
37. 36.45 g of HCl  6.02 1023 molecules;
6.02  1023  3.64
3.64 g   6.02  1022
36.45
molecules.
38. Conceptual
4 1
39. Number of moles of nitrogen  
28 7
40. 2 mol of CO2  2  44   88 g
41. Conceptual
6.02  1023  18
42. 18 g of hydrogen = atoms
1
 108.36  1023 atoms
60
43. 60 g of carbon =  5mol
12
 5  6.02  1023 atoms;
20
20 g = He   5mol
4
44. 17 g ammonia=1 mol= 6.02  10 23 molecules
45. Molecular mass of HNO3  63 ; 63 g = 1mol;
1 28.5
28.5 g   0.452 mol
63
46. 18 g of water contains 16 g of oxygen;
16  10
10 kg of water contains  8.89
18
47. CaCO3  CaO  CO2
1 molecule of CaCO3 gives 1 molecule of CO2
48. Molecular weight of MgO  24  16  40
24 g of Mg gives 40 g of MgO;
40  6
6 g of Mg gives  10 g
24

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 W 0.2
49. Mol. mass =  22400   22400  80
V 56
50. Gram atomic mass of the element
 6.642  10 26  6.022  10 23  0.040kg  40 g
Hence atomic mass is 40 amu, so the elemnt is calcium.
51. 6.022  1023 molecules of CuSO4 .5H2O ( 1mol) have weight = 249.5 g
 1 1022 molecules of CuSO4 .5H2O
249.5  1 1022
have weight =  41.42g
6.022  1023

52. 16 g of methane i.e., 1 mol contains Avodadro’s number of molecules

53. 2.24 L of gas corresponds to mass = 4.4 g
4.4
2.24 L of gas corresponds to mass   22.4  44.0g
2.24
The gas is CO2 3
54. 2.8 L of gas at NTP has mass = 3.50 g
3.50
2.24 L (1 mole ) of gas at NTP has mass   22.4  28g
2.8
Thus, molecular weight of the gas = 28
Mol .wt 28
vapour density =   14
2 2
Density of air 0.001293
55. Vapour density = density of H  0.00009  14.3
2

56. If B and B is x : y , then

10 11

10 x  11y x 19
 10.81g or 0.81x  0.19y or 
xy y 81
57. 6.022  1023 CO molecules = 1 gram molecule
1 6.02  1024
 6.022  10 CO molecules = 6.02  1023  10g molecule of CO
24

10
Now, 10 g molecules of CO contains oxygen = 10 g atoms = g molecules
2
58. N 3 has valence e   5  3   8NA
 8
 4.2 g has valence e   4.2N A  2.4NA
14
59. 0.075 g - 15 cm3
? 22,400 cm3
0.075  22400
 Mol. mass   112
15
60. Conceptual

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