SRI CHAITANYA EDUCATIONAL INSTITUTIONS,INDIA.

A.P,TELANGANA,KARNATAKA,TAMILNADU,MAHARASHTRA,DELHI,RANCHI,CHANDIGARH
CHEMISTRY

STOICHIOMETRY

Topic : Mole concept 5. Suppose 2 elements X and Y combine to form

2 compounds XY2 and X 2Y3 . When 0.05
1. Equal masses of H 2 , N 2 & CH 4 taken in a

container of volume V at temp 27C in moles of XY2 weigh 5g while 3.0111023

identical condition. The ratio of volumes of molecules of X 2Y3 weighs 85 g, the
gases H 2 : N 2 : CH 4 ? atomic masses of X and Y respectively
(1) 56 : 4 : 7 (2) 7 : 4 : 56 (1) 20,30 (2) 30,40
(3) 2: 28:16 (4) 8:14 :1 (3) 40,30 (4) 80,60
2. Which of the following has maximum no.of
6. If Avagadro number would have been 11023
atoms
instead of 6.02 1023 then mass 01 one atom
(1) 18g of H 2O (2) 18g of O2

(3) 18g of CH 4 (4) 18g of CO2 of 16

8 O would be

3. If one mole of carbon atom weighs 12g what is (1) 16 amu (2) 1100 amu
the mass of 1 atom of carbon.
(3) 6  103 amu (4) 1amu
23 23
(1) 6.023 10 (2) 12 10
7. The number of water molecules in 1L of water
(3) 1.9 1023 (4) 9.11023 is
4. Calculate the no.of molecules in a drop of (1) 18 (2) 18 1000
water weighing 0.07 g? (3) N A (4) 55.5 N A

(1) 2.34 1025 molecules of H 2O 8. A gaseous mixture contains O2 & N 2 in the

ratio of 1:4 by weight. The ratio of their no.of
(2) 8.6 1024 molecules of H 2O
molecules is
23
(3) 2.34 10 molecules of H 2O (1) 1: 8 (2) 7 : 32

(4) 2.34 1021 molecules of H 2O (3) 3:16 (4) 1: 4

9. In organic compound on analysis gave
H  6.48% and O  51.42% . Determine its
empirical formula is the compound contains
12 atom of carbon is C  12, H  1, O  16

Sri Chaitanya Page 1

 (1) C12 H12O12 (2) C12 H 20O12 (1) 40 mol (2) 2.8 mol

(3) C12 H 24O12 (4) None (3) 3.2 mol (4) 4.1 mol
15. The density of 3M solution if NaCl is 1.25
10. A sample of lime stone is 20% pure. Find the
g/mL. Calculate molality of the solution?
mass of CO2 produced by decomposing 40g
(1) 1.20 m (2) 2.79 g m
of that sample of lime stone.
(3) 2.56 m (4) 1.67 m
(1) 7.04g (2) 1.76g
16. A mixture of 18g of oxalic acid and 4.6 g of
(3) 3.52g (4) 3g formic acid is treated with excess conc.
11. Calculate the amount of 95% pure H 2 SO4 . The evolved gaseous mixture is
Na2CO3 required to prepare 5 l of 0.5M
passed through excess KOH pellets. Mass of
solution remaining gaseous product obtained at STP
(1) 246 gm (2) 260 gm will be
(3) 278.9 gm (4) 280 gm (1) 8.4 g (2) 2.8 g
12. List – I List –II (3) 8g (4) 4.4 g
P) 16g of CH 4 g  i. weigh 28 g 17. What is the mass of the precipitate formed
w
Q) 1g of H 2 g  ii. 60.2 1023 e when 50 ml of 17.0% solution of AgNO3
v
R) 1 mole of N2  g  iii. Weigh 32g w
is mixed with 50ml of 11.6% NaCl
S) 0.5 mol of SO2 g  iv. Occupies 11.2 L v
solution ?
volume at NTP
(1) 28g (2) ng
(1) P  i, Q  iii, R  ii, S  iv
(3) 3.54 g (4) 7.175g
(2) P  ii, Q  iii, R  iv, S  i
18. 2.5 g of an impure sample of
(3) P  ii, Q  iv, R  iii, S  i
sodium bicarbonate when heated strongly gave
(4) P  ii, Q  iv, R  i, S  iii 300 ml of CO2 measured at 27C and
13. If density of a solution is 3.12 gm/ mL1 , the 760mm pressure. Calculate the percentage
mass of 1.5 mL solution in significant figures purity of the sample?
is (1) 83% (2) 84%
(1) 4.680g (2) 4.7 g (3) 81.9% (4) 79%

(3) 4680 103 g (4) 46.80g 19. In the reaction vessel 100g H 2 and 100g

14. How many moles of nitrogen are needed to Cl2 are mixed and suitable condition are
produce 8.2 moles of ammonia by reaction of provided for the following reaction:
hydrogen?
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 ? 25. In which of the following compounds of Cr,
H 2 g   Cl2 g  
 2HCl g  the actual
the oxidation number of Cr is not +6:
amount of HCl formed in this reaction is
(1) CrO3 (2) Cr2O3
(1) 102.8g (2) 36.5
(3) CrO2Cl2 (4) K 2Cr2O7
(3) 72 g (4) 142 g
20. 1.0 g of Mg is burnt with 0.28g of O2 in a 26. H 2O2  H 2O2  2 H 2O  O2 is an example

closed vessel. Which reactant is left in excess of disproportion because

and how much? (1) Oxidation no of O2 only decreases

(1) Mg, 5.8 g (2) Mg, 0.58g (2) Oxidation no.of O2 only increases
(3) O2 ,0.24 g (4) O2 ,2.4g (3) Oxidation no.of O2 decrease as well as

21. 6.02 1023 molecules of urea are present in increases

100ml of its solution. The conc. of urea (4) Oxidation no.of O2 neither decrease or
solution is increase
(1) 0.001M (2) 0.02 M 27. The oxidation number of ‘N’ in hydrazoic acid
(3) 0.01 M (4) 10 M is = ___  N3H 
22. The atomic weight of metal (M) is 27 and the
(1) 1/ 3 (2) 3
eq.wt is 9, the formula of its chloride will be :-
(3) 3 (4) 2 / 3
(1) MCl (2) MCl2
28. W.O.f compounds are arranged in increasing
(3) M 3Cl (4) MCl3 oxidation no.of S.
TOPIC : Redox Reactions (1) H 2 SO3 , H 2 S , H 2 SO4 , H 2 S2O3

23. Which of the following reaction doesn’t (2) H 2 S2O3 , H 2 SO3 , H 2 S , H 2 SO4
involve oxidation and reduction? (3) H 2 S , H 2 SO3 , H 2 SO4 , H 2 S2O3
(1) 2 Rb  2 H 2O  2 RbOH  H 2
(4) H 2 S , H 2 S2O3 , H 2 SO3 , H 2 SO4
(2) 2CuI 2  2CuI  I 2
29.
(3) NH 4Cl  NaOH  NaCl  NH 3  H 2O

(4) 3Mg  N 2  Mg3 N 2

24. The sum of the oxidation states of all the
carbon atoms present in the compound
C6 H 5CHO is
(1) -4 (2) 3
(3) +5 (4) -4/7

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30. Which reaction represents the oxidizing (4) 2 7 6 1 7
behavior of H 2 SO4 ? 35. Which of the following set all species show

(1) NaCl  H 2 SO4  NaHSO4  HCl disproportionation reaction?

(2) 2 PCl5  H 2 SO4  2 POCl3  SO2Cl2  2 HCl (1) ClO2 , F2 , MnO4 , Cr2O72

(3) 2 HI  H 2 SO4  I 2  SO2  2 H 2O (2) Cr2O72 , MnO4 , ClO2 , Cl2

(4) 2 NaOH  H 2 SO4  Na2 SO4  2 H 2O
(3) MnO42 , ClO2 , Cl2 , Mn3
In Acidic medium , H 2O2 changes Cr2O72
(4) ClO4 , MnO4 , ClO2 , F2
31.

to CrO5 which has 2  O  O  bonds

36. Which of the following in redox
oxidation state of Cr in CrO5 is decomposition rxn?
(1) +5 (2) +3 
(1) CaCO3 s  
CaO s   CO2 s 
(3) +6 (4) -10

32. H 2O2  O3  H 2O  2O2 in this H 2O2 (2) 2KClO3 s  
 2KCl s   3O2 s 

  2F2 s   4HF aq   O2 s 

acts as (3) 2H 2O
(1) Oxidising agent
(4) 2 Na s   Cl2 s   2 NaCl s 
(2) Reducing agent
(3) Dehydrating agent 37. In the conservation of Br2  BrO3 the
(4) Bleaching agent
oxidation state of bromine changes from
33. The pair of compounds which cannot exist
(1) -1 to -1 (2) 0 to -1
together in aqueous solution is
(3) 0 to +5 (4) 0 to -5
(1) Na2CO3 , NaHCO3 38. Which of the following is true regarding
(2) NaHCO3 , NaOH decomposition redox reaction?
(3) NaOH , NaH 2 PO4 (1) Same element of a single compound

(4) Both 2 and 3 undergoes oxidation and reduction.

(2) Different elements of a single compound
34 . Choose the set of coefficient that correctly
balances the following equation undergoes oxidation and reduction.
(3) Same element of different compound
xCr2O72  YH   Ze  aCr 3  bH 2O
undergoes oxidation and reduction.
X Y Z a b
(4) Both 1 and 2
(1) 2 14 6 2 7
39. The oxidation state of the most electronegative
(2) 1 14 6 2 7
element in the products of reaction between
(3) 2 7 6 2 7
BaO2 & Dil. H 2 SO4 are
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 (1) 0 & -1 (2) -1 & -2 (3) -2 & 0 (4) -2 & +1
KEY

1) 1 2) 3 3) 3 4) 4 5) 3 6) 1 7) 4 8) 2 9) 4 10) 3
11) 3 12) 4 13) 2 14) 4 15) 2 16) 1 17) 4 18) 3 19) 1 20) 2
21) 4 22) 4 23) 3 24) 1 25) 2 26) 3 27) 1 28) 4 29) 1 30) 3
31) 3 32) 2 33) 1 34) 2 35) 3 36) 2 37) 3 38) 2 39) 2 40)
(1) 5744.1 J
THERMODYNAMICS (2) 150 J
1. Which of the following PV curves represents (3) 250 J
workdone is zero ? (4) Zero
4. Which one among the following is the
correct option for right relationship between
(1) C P and C V for one mole of monoatomic

gas ?
CP 5 CP 7
(1)  (2) 
(2) CV 3 CV 5

CP 4 CP 1
(3)  (4) 
CV 3 CV 2
(3) 5. ‘W’ is the amount of workdone by the
system and ‘q’ is the amount of heat supplied
to the system. Choose the change in internal

(4) energy and type of a system from the given

2. The workdone when 1 mole of a gas expands options.

reversibly and isothermally from pressure of (1) ΔE = Wad , adiabatic system

10 atm to 1 atm at 300 K is (2) ΔE =  q , Open system

(1) 150 J (3) ΔE = q  W , Closed system
(2) 401.4 J (4) ΔE = q  W , Open system
(3) 401.4 J
6. Under isothermal conditions, a gas at 300K
(4) 5744.1J expands from 0.1 L to 0.2 L against a
0 constant external pressure of 2 bar. The work
3. One mole of an ideal gas at 27 C is
expanded isothermally from 1 litre to 5 done by the gas is (Given that 1L bar = 100
litres volume. ΔE for this process is J)
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Sec :
Chemistry

(1) – 20 J (2) – 40 J 11. At standard conditions, if the change in

(3) – 50 J (4) – 100 J enthalpy for the following reaction is
7. Reversible expansion of an ideal gas under ‘  x’ KJ/mole
isothermal and adiabetic conditions are as H2g  Br2g 
 2HBrg
shown in the figure
Given that bond energy of H 2 and Br2 is ‘y’
AB → Isothermal expansion
KJ/mole and ‘z’ KJ/mole respectively. What
AC → Adiabatic expansion
is the bond energy (in KJ/mole) of HBr ?
Which of the following option is correct ?
(1) x + y + z (2) -x  y  z

(3) x  y  z (4) x  y  z
12. Three thermochemical equations are given
below :
(i)

(1) ΔS isothermal >ΔS adiabetic C(graphite) +O2 g)   CO2 g)  , ΔHo = 'x'KJ/mole

(ii)
(2) Wisothermal >W adiabetic
C(diamond) +O2 g)   CO2 g)  , ΔHo = 'y'KJ/mole
(3) TA = TB
(iii)
(4) All of these
C(diamond)  C(graphite) , ΔHo = 'z'KJ/mole
8. Two moles of an ideal gas are expanded
spontaneously into a vacuum. Workdone is Based on the above equations, find out which

(1) Zero (2) 2 J of the relationships given below is correct ?

(3) 3 J (4) 10 J (1) z = x-y (2) z= y-x

9. Heat capacity (C V ) of an ideal gas is (3) z = x+y (4) z = -x-y

10 KJ/mole/K , To rise its temperature from 13. Consider the following reaction :

295 K to 315 K, heat to be supplied per 10 g

N2(g) +3H2(g)  2NH3(g) , ΔH =  92KJ/mole

gas will be (in KJ) (Molecular weight = 16) What is the enthalpy change for
(1) 160 (2) 62.5 decomposition of one mole of ammonia ?
(3) 320 (4) 125 (1) 92 KJ/mole (2)  92 KJ/mole
10. Which amongst the following options is the
(3) 46 KJ/mole (4)  46 KJ/mole
correct relation between change in enthalpy
14. The bond dissociation energies of A 2 , B2
and change in internal energy ?
and AB are in the ratio of 1 : 0.5 : 1 . ΔH for
(1) ΔH +ΔU=ΔW (2) ΔH  ΔU-ΔW
the formation of AB is  200 KJ/mole . The
(3) ΔH  ΔU+ΔW (4) ΔH+ΔW=ΔU
bond dissociation energy of AB will be
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Chemistry

(1) 200 KJ/mole (2) 100 KJ/mole 19. When 11.2 litres of a gas mixture of methane

(3) 800 KJ/mole (4) 400 KJ/mole and propane is perfectly combusted at 00 C

15. Of the following, the largest value of entropy and 1 atmosphere, 44.8 litres of oxygen at the
same temperature and pressure is consumed.
at 250 C and 1 atm is that of
The amount of heat released from this
(1) H 2(g) (2) O 2(g)
combustion in KJ (Heat of combustion
(3) H2O(l ) of CH 4 = 890 KJ/mole and heat of
(4) Graphite Carbon(s) combustion of C3H8 = 2220 KJ/mole ) is
16. The electrical energy supplied decomposes (1) 884 (2) 442
water into H 2 and O 2 is (3) 221 (4) 150

(1) non useful work 20. For irreversible expansion of an ideal gas

(2) useful work under isothermal condition, the correct

(3) non expansion work option is

(4) zero work (1) ΔE = 0 (2) ΔE  0

17. Consider the following reaction for which the (3)  Stotal  0 (4)  Stotal  0
change in enthalpy is negative. 21. For the reaction Cl2(g)  2Cl(g) , the correct
A(g) +B(g) C(g) +D(g) .
option is
Which of the following will not affect the (1) ΔH > 0,ΔS>0 (2) ΔH > 0,ΔS< 0
equilibrium ?
(3) ΔH  0,ΔS  0 (4) ΔH  0,ΔS  0
(1) Change in temperature
22. If for a certain reaction ΔH is 20KJ/mole at
(2) Change in pressure
400 K, the value of ΔS ( in J/K/mole) for
(3) Change in concentration
which the same reaction will be spontaneous
(4) All of these
at the same temperature is
18. The heat of combustion of carbon to CO 2 is
(1) – 50 K (2) 60 K
- 393 KJ/mole. The heat released upon
(3) 40 K (4) 10 K
formation of 44 g of CO 2 from carbon and
23. In which case change in entropy is positive
oxygen gas is (KJ/mole ) ?
(1) – 393 (2) + 393
(1) 2H(g)  H 2(g)
(3) 196.5 (4) – 196.5
(2) Evaporation of water
(3) N2(g)  3H2  g   2 NH3(g)

(4) 2SO2(g) +O 2  2SO3(g)

(g)

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Chemistry

24. For a given reaction , ΔH =30KJ/mole and d log P  ΔH Vap

(2) =
ΔS=90 J/K/mole . The reaction is dT RT 2
d log P ΔH Vap
spontaneous at [Assume the ΔH and ΔS do (3) =
dT 2.303RT 2
not vary with temperature]
(1) T > 200K (2) T > 333K d log P ΔH Vap
(4) =
dT RT 2
(3) T  333K (4) T  200K
28. Which of the following statements is correct
25. For a same of perfect gas, when its volume is
for the spontaneous reaction ?
changed isothermally from V1 to V2 . The
(1) 3O2(g)  2O3(g) at hight temperature
entropy change is given by
(2) N2(g)  3H2(g)  2NH3(g) at low
V 
(1) ΔS  nR ln  2  temperature
 V1 
(3) 2SO 2(g)  O2(g)  2SO3(g) at high
V 
(2) ΔS= nR ln  1 
 V2  temperature
(4) N2(g) +O2(g)  2NO(g) at low
V 
(3) ΔS  nRT ln  2 
 V1  temperature
29. For the reaction,
V 
(4) ΔS  nRT ln  1  N2O4(g)  2NO2(g) , ΔH =14K cal and
 V2 
26. The correct thermodynamic conditions for ΔS=100 cal/K at 300 K. Hence ΔG is
the spontaneous reaction at low temperature (1) – 16 Kcal (2) 16 K cal
is (3) 20 K cal (4) – 50 K cal
(1) ΔH < 0 and ΔS<0 30. The activation energies of forward and

(2) ΔH  0 and ΔS<0 reverse reactions depends on

(1) ΔH (2) ΔS
(3) ΔH  0 and ΔS>0
(3) ΔS and ΔG (4) ΔG
(4) ΔH  0 and ΔS>0
27. Consider the following liquid – vapour
equilibrium, liquid Vapour . Which of the
following relations is correct ?
d log P  ΔH Vap
(1) =
dT 2 T2

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Chemistry

KEY

1) 3 2) 4 3) 4 4) 1 5) 3 6) 1 7) 4 8) 1 9) 4 10) 3
11) 1 12) 2 13) 3 14) 3 15) 2 16) 1 17) 2 18) 2 19) 1 20) 1
21) 1 22) 2 23) 2 24) 2 25) 1 26) 1 27) 3 28) 2 29) 1 30) 1
(4) CH3CH2MgBr + CH3CHO
ALCOHOLS PHENOLS & ETHERS 5. Which one/ones of the following reactions
1. An industrial method for the preparation of will yield 2-propanol?

methanol is (I) CH2  CH  CH3  H2O 
H

(1) by reacting CH4 with steam at 900oC
(II) CH3  CHO 
(i) CH3MgI
(ii) H2O

with nickel catalyst.
(III) CH2O 
(i) C2 H5MgI
(2) by reduction of HCHO with LiAlΗ4. (ii) H2O

(3) by catalytic reduction of CO in (IV) CH2  CH  CH3 

Neutral KMnO4

presence of ZnO – Cr2O3. (1) I and II (2) II and III
(4) by reaction of HCHO with NaOH(aq). (3) I and III (4) II and IV
2. Identify (Z) in the following reaction 6. Phenyl magnesium bromide reacts with
series: methanol to give
Ethanol 
(X) 
PBr3
(Y) 
(Z)
Alc.KOH H2SO4 , room temp.
H2O, heat (1) a mixture of anisole and Mg(OH)Br
(1) CH2 = CH2 (2) CH3CH2OH (2) a mixture of benzene and Mg(OMe)Br
(3) CH3CH2OSO3H (4) C2H5OC2H5 (3) a mixture of toluene and Mg(OH)Br
3. The compound which reacts fastest with (4) a mixture of phenol and Mg(Me)Br
Lucas reagent at room temperature is 7. Which of the following exhibit highest
(1) butan – l – ol B.P.?
(2) butan – 2 – ol
(1) (2)
(3) 2 – methylpropan – 1 – ol
(4) 2 – methylpropan – 2 – ol (3) (4)
4. Which of the following are the starting 8. An organic compound (A) reacts with
materials for the synthesis of tert-butyl sodium metal and forms (B). One heating
alcohol? with conc. H2SO4, (A) gives diethyl ether.
(1) CH3MgI + CH3COCH3 (A) and (B) are respectively.
(2) CH3MgI + CH3CHOHCH3 (1) C2H5OH and C2H5ONa
(3) CH3CH2MgBr + CH3COCH3 (2) C3H7OH and CH3ONa
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Chemistry

(3) CH3OH and CH3ONa (3) HCHO (4) C3H7CHO

(4) C4H9OH and C4H9ONa 14.
9. 3 moles of ethanol react with one mole of
phosphorus tribromide to form 3 moles of
bromoethane and one mole of X. Which of
The electrophile involved in the above
the following is X?
reaction is
(1) H3PO4 (2) H3PO2
(1) Dichloromethyl cation  CHCl2 

(3) HPO3 (4) H3PO3
 
10. (CH3 )2 CHOH 
Mild oxid.
 X 
(i) CH3MgBr
(ii) HOH
Y .
(2) dichlorocarbene (:CCl2)
Here Y is
 () 
(3) trichloromethyl anion  C Cl3 
(1) iso-butyl alcohol  
(2) tert-butyl alcohol  
(4) formyl cation  C HO 
(3) iso-butylene  
(4) sec-butyl alcohol 15. The major product obtained on interaction
11. To prepare 3-ethylpentan-3-ol, the reagents of phenol with sodium hydroxide and
needed are carbon dioxide is
(1) CH3CH2MgBr + CH3COCH2CH3 (1) benzoic acid (2) salicylaldehyde
(2) CH3MgBr + CH3CH2CH2COCH2CH3 (3) salicylic acid (4) phthalic acid
(3) CH3CH2MgBr + CH3CH2COCH2CH3 16. Dow’s reaction involves
(4) CH3CH2CH2MgBr + CH3COCH2CH3 (1) electrophilic addition
12. Which of the following will not give CHI3 (2) electrophilic substitution
on treatment with I2 and NaOH? (3) nucleophilic addition
(1) CH3 – OH (4) nucleophilic substitution
(2) CH3 – CH2 – OH 17. Which one of the following compounds
(3) CH3  CH CH3 will be most readily attacked by an
|
OH
electrophile?
(4) CH3  C CH 2  CH3
|| (1) Chlorobenzene (2) Benzene
O
(3) Phenol (4) Toluene
13. Primary alcohols can be prepared by the
18. Which represents Reimer-Tiemann
reaction of RMgX with
reaction?
(1) C2H5CHO (2) CH3CHO

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Chemistry

(1)
(3)

(2)

(4)
(3) 21. Identify Z in the sequence.
CH3CH2CH  CH2 
HBr/H2O2
Y 
C2H5ONa
z

(4) (1) (CH3)2CHOCH2CH3

19. Which of the following statements (2) CH3CH2CH(CH3)-O-CH2CH3
regarding phenols is not correct? (3) CH3(CH2)3-O-CH2CH3
(1) Phenols are stronger acids than water (4) CH3(CH2)4-O-CH3
and alcohols. 22. HBr reacts with CH2=CH – OCH3 under
(2) Phenols are weaker acids than anhydrous conditions at room temperature
carboxylic acids. to give
(3) Phenols are soluble in both aqueous (1) CH3CHO and CH3Br
NaOH and aqueous NaHCO3. (2) BrCH2CHO and CH3OH
(4) Phenoxide ions are more stable than the (3) BrCH2 – CH2 – OCH3
corresponding phenols. (4) H3C – CHBr – OCH3
20. In the reaction, 23. An organic compound of molecular
formula C4H10O docs not react with
sodium. With excess of HI, it gives only
the products
two types of alkyl halide. The compound is
are
(1) ethoxyethane
(2) 2-methylpropan-2-ol
(3) 1-methoxypropane
(1)
(4) 1-butanol
24. tert-Butyl methyl ether on heating with HI
(2) gives a mixture of
(1) tert-butyl alcohol and methyl iodide

Sri Chaitanya
Page 11
Sec :
Chemistry

(2) tert-butyl iodide and methanol

(3) iso-butylene and methyl iodide
(1)
(4) iso-butylene and methanol
25. Which one of the following ethers cannot
be prepared by Williamson's synthesis? (2)
(1) Diphenyl ether
(2) Diethyl ether
(3)
(3) Phenyl ethyl ether
(4) Tertiary butyl ether
26. Which one of the following is not cleaved (4)
by HI? 30. Tert-butyl bromide on treatment with
(1) Divinyl ether sodrum methoxide yields
(2) Diethyl ether (1) Sodium tertiary butoxide
(3) Methyl ethyl ether (2) Methyl tertiary butyl ether
(4) Phenetole (3) tert-butyl alcohol
27. Allyl phenyl ether can be prepared by (4) iso-butylene
(1) CH2 = CH – CH2 – ONa + C6H5CH2 – 31. Which of the following reaction(s) can be
Br used for the preparation of alkyl halides?
(2) C6H5 – CH = CH – Br + CH3 – ONa (I) CH3CH2OH  HCl 
anh. ZnCl2

(3) CH2 = CH – ONa + C6H5Br (II) CH3CH2OH  HCl 

(4) CH2 = CH – CH2 – Br + C6H5ONa
(III)  CH3 3 COH  HCl 

28. In the reaction,
CH3CHCH3 
alc.
 A HBr
  B 
CH3ONa
C
(IV)  CH3 2 CHOH  HCl 
anh. ZnCl
2

KOH Peroxide
|
Br (1) (I) and (II) only
, C is
(2) (IV) only
(1) diethyl ether
(3) (III) and (IV) only
(2) 1-methoxy propane
(4) (I), (III) and (IV) only
(3) isopropyl alcohol
32. The reaction,
(4) propylene glycol
29. Which of the following is most suitable
method for the preparation of methyl
cyclopentyl ether?
Sri Chaitanya
Page 12
Sec :
Chemistry

(1) (2)
can be classified as
(1) Dehydration reaction
(2) Williamson alcohol synthesis reaction
(3) Williamson ether synthesis reaction (3) (4)
(4) Alcohol formation reaction 36. Given below are two statements:
33. Which one is the most acidic compound? Statement-1: The acidic strength of
monosubstituted nitrophenol is higher than
phenol because of electron withdrawing
nitro group.
(1) (2)
Statement-II: o-Nitrophenol, m-nitrophenol
and p-nitrophenol will have same acidic
strength as they have one nitro group
attached to the phenolic ring.
(3) (4)
In the light of the above statements, choose
34. The compound that is most difficult to
the most appropriate answer from the
protonate is
options given below:
(1) (2) (1) Both statement-I and statement-II are
correct.
(3) (4)
(2) Both statement-1 and statement-11 are
35. The structure of intermediate A in the
incorrect.
following reaction is
(3) Statement-I is correct but statement-Il
is incorrect.
(4) Statement-I is incorrect but statement-Il
is correct.
37. Given below are two statements:
Statement I: In Lucas test, primary,
secondary and tertiary alcohols are
distinguished on the basis of their
Sri Chaitanya
Page 13
Sec :
Chemistry

reactivity with conc. HCl + ZnCl2, known 39. Which amongst the following will be most
as Lucas Reagent. readily dehydrated under acidic
Statement II: Primary alcohols are most conditions?
reactive and immediately produced
turbidity at room temperature on reaction
with Lucas Reagent. (1)
In the light of the above statements, choose
the most appropriate answer from the
options given below. (2)
(1) Both statement-I and statement-II are
correct.
(2) Both statement-1 and statement-11 are (3)

incorrect.
(3) Statement-I is correct but statement-Il
(4)
is incorrect.
40. Consider the following reaction:
(4) Statement-I is incorrect but statement-Il
is correct.
38. Consider the following reaction and
Identify products A and B.
identify the product (P).
 Product  P 
CH3  CH  CH  CH3 HBr (1)
| |
CH3 OH

3  Methylbutan  2  ol
(2)
(1) CH3  CH  CH  CH 3
| |
CH3 Br
(3)
CH 3
|
(2) CH 3  C  CH 2 Br (4)
|
CH 3

Br
|
(3) CH3  C  CH 2  CH3
|
CH3

(4) CH3CH  CH  CH3

KEY

Sri Chaitanya
Page 14
Sec :
Chemistry

1) 3 2) 2 3) 4 4) 1 5) 1 6) 2 7) 2 8) 1 9) 4 10) 2
11) 3 12) 1 13) 3 14) 2 15) 3 16) 4 17) 3 18) 1 19) 3 20) 4
21) 3 22) 4 23) 3 24) 2 25) 1 26) 1 27) 4 28) 2 29) 2 30) 1
31) 4 32) 3 33) 3 34) 1 35) 3 36) 3 37) 3 38) 3 39) 4 40) 1

ARYL AND ALKYL HALIDES CH 3

H 3C  C  CH  CH 3
1) The organic compound, C  CH  CH 3

CH 2  CH  C  CH 2  CH 3  
HBr
 A; 
 C6 H 5CO  O  B;
HBr
2

Br
‘A’ and ‘B’ are respectively
is classified as
1)
1) Vinylic halide 2) Benzylic halide
BrH 2 C  C  C H  C H 3 H 3C  C H  C H B r  C H 3

3) Allylic halide 4) Aryl halide

;

I 2)

2) I) I II) CH 2 Br
H 3 C  C  Br   CH 2  CH 3 C  CH  CH 3

I I
III) IV) ;
Correct order of reactivity towards SN 1 3)
reaction is _______and H 3 C  C  Br   CH 2  CH 3 H 3C  C  Br   CH 2  CH 3

Correct order of reactivity towards  ,  -

;
dehydrohalogenation is ______.
4)
1) II>I>III>IV ; IV>III>I>II
H 3C  C  Br   CH 2  CH 3 H 3C  CH  CH  Br   CH 3
2) II>I>III>IV ; II>I>III>IV
3) IV>III>I>II ; IV>III>I>II ;
4) IV>III>I>II ; II>I>III>IV
5) Chloro benzene cannot be obtained in the
3) CH 3  I  CH 3  Br  CH 3  Cl  CH 3  F
following process
represents the correct decreasing order of
   
Cl2 / FeCl3 Cl2
A) Boiling point B) Reactivity dark sunlight
A) B)
C) Bond enthalpy D) Dipole moment
1) A, B and D only 2) A only
3) A and B only 4) A,B and C only
4)
Sri Chaitanya
Page 15
Sec :
Chemistry

+
N 2 Cl  + Cl COCl
N 2 Cl 
1) 2)

 Cu
HCl
C u C l2
 H2C
l  
C) D)
3) 4)
Cl2  excess 
 / 
AlCl   9)
3 dark
E)
a ) Mg / dry ether

Br  b )     X .
D2 O
1) B only 2) E only c ) Conc . HNO3  Conc . H 2 SO4

3) B and D only 4) B and E only

6) Identify correct reaction I ’X’ is
1) NO2
Cl OH
O2 N Br D


a ) aq. NaOH

b) H  1) D 2) I

2) O2 N Br I NO2
3) 4)
Cl CH 3
10 Choose correct statements from the following
CH 3Cl   CH 3  CH  Br   CH 2  CH3 
an. AlCL 

3 OH
A) SN 1

3) Racemic mixture of 2-butanol

CH 3  CH  Br   CH 2  CH3 

Cl Cl B) OH
SN 2

COCH 3  major 
CH 3COCl 
 an. AlCL3
Inverted product


4) Cl  
OH

CH 2  CH 2  CH 2  Br CH 2  CH  CH 2 C) same product is
obtained either by S N 1 (or) S N 2

alc . KOH
 D) Compound with ‘R’ configuration must

7) Major product is not properly represented in always show dextro rotation

1) CH 3CH 2 Br 
LiAlH 4
 CH 3  CH 3 E) 20 alkyl halides prefer S N 2 (or) elimination
reactions based on strength of base /
2) CH 3  CH 2  Br 
AgNO2
 CH 3  CH 2  NO2
nuecliophile
3) CH3 3 CBr  
CH ONa
CH3 3 C  O  CH3
3

1) A and B only 2) A,B and E only

4) CH 3CH 2 Br  CH 3COOCH 2CH 3
CH 3COOAg
3) A,B,C,D,E 4) A,B,C and E only
A)  C6 H5 2 CHBr
a ) KCN
b ) H 3O /   11.
Br  c   
) Cl2  Re dp
 X.
d ) Zn / HCl
e ) NaOH  CaO / 
8) ’X’ is
Sri Chaitanya
Page 16
Sec :
Chemistry

B)  C6 H5 2 C  Br  CH3 4)

C) C6 H5 3 CBr  OH 
 
Con . HI
O I

D) C6 H 5CH 2 Br …….. S N 2 mechanism

Correct increasing order of reactivity towards 14) I) 2-bromobutane 
 2-butene ; II) 2-fluoro
S N 1 mechanism is butane 
 1-butene ;
1) D,B,A,C 2) D,A,B,C Incorrect statement is
3) C,B,A,D 4) C,A,B,D 1) Mechanism in both cases is  -elimination
12. Statement-I : Reactivity towards 2) ‘I’ gives a Zaitsev product
S N 1 …… 3) II gives a Hoffmann’s product
CH3 2 CHCH2 Br  CH3CH2CH2CH2 Br 4) Mechanism in I and II is E1
15)
Statement-II : Reactivity towards
a ) Conc . HBr  excess  a ) PCl3

H 3CO CH  CH 2      A 
b ) KCN
c ) H O / OH  
 
b ) C 2 H 5 NH 2
c ) LiAlH 4
I CH 2  I
2

< . A and B are respectively

S N 2 …..
1)
(1) I & II are correct
COOH
(2) I is correct, II is incorrect
(3) I is incorrect, II is correct H 3CO ; H 3CO
(4) I and II are incorrect
13. Identify incorrect match NH
2)
1)
COOH ; NH
Br HO ; HO

  
alc. KOH
 major 
……..Saytzeff product 3)
2) COOH
;
Cl 
KCN CN HO ; HO
HCON  CH 3  2  major 
…….. S N 2 mechanism NH

3) 4)
COOH
C H Br  C H 3 CH OH   CH 3
; H 3CO ;
H 3CO NH


H 2O
  major 
Br Br Cl
CH 3 CH 3 Cl

…… S N 1 mechanism 16) A) B)

Sri Chaitanya
Page 17
Sec :
Chemistry

Cl 2) 3-bromo-1-ethyl benzene

Cl 3) 4-bromo-1,2-dimethyl benzene
C) D)
4) 3-bromo-1,4-dimethyl benzene
Cl
19) Identify correct combination

Cl Cl  S
 
base
HS
A) can
CH 3 be considered as nucleophilic substitution
E) F)
B)
How many are non reactive towards alkaline
OCH 3 OCH 3
hydrolysis ?
1) 6 2) 5  NaNH
  2

3) 4 4) 3 Br NH 2
…….follows
17) benzyne mechanism i.e elimination followed
CH 2  CH 2 
 CH 3CH 2 Br 
A
 CH 3CH 2OH B
by addition.
.

 CH 2  CH 2 
C
 CH 3CH 2`OH D
C)
A,B,C and D are respectively. Br Br

S. A B C D CH 3  CH  CH 2  CH 2OH 
  CH 3  CH  CH 2  CH 2Cl
HCl

n ……involves retention in configuration

o 1) A, B and C 2) B and C only

1) HBr / Ag 2O Al2O3 / dil.H 2 SO4 3) A and C only 4) A and B only

peroxide
 moist  533K 20) Most reactive towards S N 1 reaction is

Cl
2) HBr aq.NaOH Conc.H 2 SO4 /
H 3O 
413K
CH 2Cl
3) HBr / alc.KOH Conc.H 2 SO4Conc
/ .H 2 SO4 /
peroxide 443K H 2O CH 3
1) 2)
CH 2 I Cl
4) HBr aq.KOH Conc.H 2 SO4 / H 3O 
443K

CH 3
CH 3 NO2
3) 4)

 A 
 B.
Br2 /773 K
3 moles
a ) Br2 / Fe , dark
b ) Zn / HCl
c ) NBS / hv
d ) CH 3 MgBr
21) Identify incorrect statement
18)
1) Reactivity of C3 H 6  C2 H 6 towards
Compound ‘B’ is
bromine gas
1) 4-bromo-1-ethyl benzene

Sri Chaitanya
Page 18
Sec :
Chemistry

2) n-propyl chloride 
 n-propyl cyanide, N 2 Cl  I
the solvent used is DMF

KI

3) Reactivity of methyl bromide is 30 times
II) ……..Nucleophilic
that of isopropyl bromide towards S N 2
substitution
4) Energy required for C-X bond cleavage III)
during S N 1 reaction is obtained by the Br
solvation of halide ion with the proton of 
Br2
H 2O

protic solvent OH
…….Electro
22) philic addition
Conc. HI / 
X Y  X  allyl iodide 'X' is
b ) Na
a ) aq. KOH
excess Br
c )CH 2 CH CH 2  I

I 
Br2

773 K
CH 2OH IV) …….Free radical

1) 2) substitution
V)
I I
 
HBr

C 6 H 5 CO  O
 H
2
Br ……
3) 4)
..Free radical addition
23) How many of the following compounds are Identify the correct combination from the
optically active above reactions
1) All of them 2) I, IV & V only
CH 3 COOH
3) I, II and V only 4) II, IV and V only
H Cl HO H
25) Statement-I : Enantiomers are super imposable
H 3C H H H
mirror images of each other.
Cl CH 3
A) B) Statement-II : Racemic mixture can be

Cl Cl separated either by crystallization (or) by

Cl
fractional distillation.

Cl (1) I & II are correct

C) D) E)
(2) I is correct, II is incorrect
1) 4 2) 3 (3) I is incorrect, II is correct
3) 5 4) 2 (4) I and II are incorrect
Cl 26) Regarding S N 1 reaction, incorrect statement is


Cl2 / Fe
dark
 1) Rearranged products are possible
24) I) …..Electrophilic 2) Polar protic solvent is used
substitution
Sri Chaitanya
Page 19
Sec :
Chemistry

3) Rate of reaction is doubled when 1) A pair of enantiomers

concentration of nucleophile is doubled 2) A pair of diastereomers
4) Order of reactivity- 30 `RX  20 RX  10 RX 3) A pair of identical compounds

CH 3 4) A pair of constitutional isomers

CH 2 CH s

H Br H Br
Br and are
H H 3C Br
CH 2 CH s H
27)
KEY

1) 1 2) 2 3) 3 4) 4 5) 6) 4 7) 3 8) 3 9) 1 10) 4

11) 2 12) 1 13) 4 14) 4 15) 16) 1 17) 4 18) 2 19) 1 20) 3

21) 3 22) 2 23) 2 24) 1 25) 4 26) 3 27) 3 28) 29) 30)
(3) CH 4 (4) C4 H10
HYDROCARBONS
5. CH3  Br  2H 
X
 CH 4  HBr . Here
ALKANES
‘X’ is
1. 2.84 grams of methyl iodide is completely
(1) Zn HCl (2) NaOH + CaO
converted into methyl magnesium iodide and
the product was decomposed by excess of (3) Na dE (4) Zinc alc
ethanol. The volume of the gaseous 6. CH3  Br 
Na dE
 X  NaBr . Here ‘X’ is
hydrocarbons produced at NTP will be
(1) CH 4
(1) 22.4 ml (2) 22400 ml
(3) 0.448 lit (4) 0.224 lit (2) CH 3  CH 3

2. The number of possible theoretical rotamers (3) CH3  CH 2  CH3

of ethane are CH 3  CH  CH 3
(1) 2 (2) 3
CH 3
(3) 4 (4) infinite (4)

3. Which of the following has highest boiling 7. Conversion of methane to methyl chloride is

point an example of

(1) C3 H 8 (2) C4 H10 (1) Free radical addition

(2) Free radical substitution
(3) C5H12 (4) C10 H 22
(3) Electrophillic addition
4. The alkane with least melting point
(4) Nucleophillic substituent
(1) C2 H 6 (2) C3 H 8

Sri Chaitanya
Page
20
Sec :
Chemistry

8. The alkane that gives two monochloro (4) 16 K Cal mole

products on chlorination with Cl 2 in 13. Assertion (A) : For C2 H 6 staggered
presence of diffused sunlight is conformation is more stable than eclipsed
(1) Neopentane Reason (R) : In staggered conformation, the
(2) Isopentane bonded electrons have minimum repulsions
(3) Propane (1) Both (A) and (R) are true and (R) is the
(4) 2, 2 dimethyl butane correct explanation of (A)
9. CH4  Br2 
1mole
 A 
Na
B . (2) Both (A) and (R) are true but (R) is not
 organic
compound  dE
the correct explanation of (A)
Here ‘A’ is (3) (A) is true but (R) is false
(1) CH 3  CH 3 (2) CH 3Br (4) Both (A) and (R) are false
(3) C2 H 4 (4) C2 H 2 ALKENES

10. With respect to the conformers of ethane, 14. Which of the following compound can show

which of the following are true geometrical isomerism

(1) Both bond angle and bod length remain Br Cl

same CC
I Cl
(2) Rotation around carbon – carbon bond (1)
in ethane molecule is possible, because of CH 3
cylindrical symmetry of  bond between C
carbon – carbon atoms CH 3
(2)
(3) Both 1 and 2
F Et
(4) Bond angle changes but bond length
CC
remains same Cl Et
(3)
11. Tetrachloroethane on treatment with excess
CH 3 CH 3
alcoholic zinc finally forms
C
(1) Ethene (2) Ethane
CH 3 CH 3
(3) Ethyne (4) Butane (4)
12. Energy barrier between staggered and 15. 2 butene on reduced ozonolysis gives
eclipsed forms of ethane is (1) 2 moles of HCHO
(1) 0.6 K Cal mole (2) 2 moles of CH 3CHO
(2) 2.9 K Cal mole (3) 1 mole CH 3COCH 3 and 1 mole
(3) 12 K Cal mole HCHO

Sri Chaitanya
Page 21
Sec :
Chemistry

(4) 1 mole CH 3CHO and 1 mole of 19. An alkene on ozonolysis gives ethanol as one

HCHO of the products. Its structure is

16. CH3  CH 2  CH 2  CH  CH 2 CH  CH  CH3


1.HBr, benzoyl peroxide,Δ
2. alcoholic KOH
 A . Here ‘A’ is (1)

(1) CH3  CH  CH 2 CH  C  CH 2

(2) CH3  CH 2  CH 2  CH  CH 2 (2)

(3) CH3  CH  CH  CH 2  CH3 CH 2  CH  CH 2

CH 3  C  CH  CH 3 (3)

CH 3 CH 2  CH 2  CH 3
(4)
17. Incorrect statement in the synthesis of (4)
alkenes is 20. CH 3  CH 2  CH  CH 2 
B2 H 6
 Z.
H 2O H 2O2 , OH
(1) treatment of alkynes with Lindlar’s
This reaction follows
catalyst
(1) Anti Markownikov’s rule
(2) treatment of alkyl halides with alcoholic
(2) Markownikov’s rule
KOH
(3) Saytzeff’s rule
(3) treating germinal dihalides with Zn
(4) Hoffmann’s rule
metal
21. An alkene (A) on reaction with O3 and
(4) treating alkyl halide with
Zn Conc.HCl Zn  H 2O gives 2 moles of acetaldehyde in

18. The major product in the following chemical equimolar ratio. Addition of HCl to alkene

reaction gives (B) as the major product. The structure

C H CO  O
of product ‘B’ is
CH3  CH  CH 2  HBr 
6 5 2 2
(1)
CH 3  CH  CH 3 CH 2  CH 2  CH 2  CH3

(1) Br Cl
CH3  CH  CH 2 (2)

(2) Br Br CH3  CH  CH 2  CH3

CH 2  CH  CH 2 Cl

Br
(3)
(3)
(4) CH3  CH 2  CH 2  Br

Sri Chaitanya
Page
22
Sec :
Chemistry

Cl C6 H5  CH 2  CH  CH3
CH 3  C  CH 3 Br

CH 3 (2)

(4)
C6 H5  CH 2  CH 2  CH 2

CH 3  CH  CH 2  CH 2 Br
(3)
Cl Cl
C6 H5  CH  CH 2  CH 3
22.
H CH 3 Br
CH3  C  C  CH3 
 (4)
CH3 H , C6 H 4 Br  CH 2  CH 2  CH3
the most suitable reagent in the above CH 3
conversion is
CH3  C  CH 2 
HCl
A
(1) Hg+2 H+ , H2O 26. . Here ‘A’ is
(1)
(2) Na liq.NH 2
CH 3
(3) H 2 , Pd C, quinoline
CH 3  C  CH 3
(4) Zn HCl
Cl
23. CH3  C  C  CH3 
 A . Here ‘A’ is
(2)
(1) CH3  CH 2  CH  CH 2
CH 2  Cl
(2) CH 3  CH 2  C  CH 2
CH 3  CH  CH 3
(3) CH3  CH  CH  CH3
(3)
CH3  C  CH 2
CH 2  CH 2  CH 2  CH3
CH 3
(4) Cl
24. The compound that can most readily react (4)
with gaseous bromine is CH 2  Cl
(1) C2 H 2 (2) C4 H10
CH3  CH  CH 2  Cl
(3) C2 H 6 (4) C4 H8
27.
H+
25. C6 H5  CH 2  CH  CH 2 
HBr
A . Here

‘A’ is
(1)
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Chemistry

CH 3 CH 3
CC
CH 3 CH 3 (3) (4)
(A)
30. CH3  CH 2  C  CH 
1% HgSO4
40% H SO , 60°C
A.
2 4
CH 3 CH 3
Here ‘A’ is
CC
CH 3 (1) CH3  CH 2  CH 2  CHO
H
(B) (2) CH3  CH  CH  CH3
H H
CH3  CH 2  C  CH3
CC
H H (3) O
(C)
(4) CH3  CH 2  CH 2  COOH
The enthalpy of hydrogenation of these
31. In the following reaction
compounds will be in the order as
(1) C > A > B (2) B>A>C CH  CH 
red hot Fe tube
873K
 A . The number of
(3) C > B > A (4) C>B=A  and  bonds present in A
CH 3 (1) 6, 3 (2) 8, 4
(3) 12, 3 (4) 12, 2

O3 Zn H 2O
Z
28. . Here ‘Z’ is 32. Which of the following is more acidic
CH 3 CH 3 (1) CH  CH
CHO (2) CH3  C  CH
CHO
CHO (3) CH3  C  C  CH3
(1) (2)
(4) CH3  CH 2  C  CH
CH 3 CH 3
COOH 33.
COOH
O
COOH (4) COOH
(3) CH3  C  CH 
1% HgSO4
 CH 3  C  CH 3
40% H SO 60°C
2 4,
29. Which of the following is not product of
The type of isomerism exhibited during the
OH
intermediate stage of the reaction is
(1) Positional (2) Chain
dehydration of
(3) Metamerism (4) Tautomerism
34. The pair of electrons in the given carbanion

(1) (2)
CH3  CH  C is present in which of the
following orbitals
Sri Chaitanya
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Chemistry

(1) sp 2 (2) sp NO2

(3) 3p (4) sp3

35. CH3  C  CH 

1.NaNH 2 liq.NH3
2.CH Br
X . Here (1) (2)
3
OH Cl
‘X’ is
(1) CH3  C  C  Na
(2) CH3  C  C  CH 2  CH3 (3) (4)
40. Which of the following reaction is an
NH 2
nucleophillic substitution reaction
h
CH3  C  CH 2 (1) CH4  Cl2   CH3Cl  HCl
(3)
CH3  C  C  CH3 (2) CH3Br  KOH  aq  
 CH3OH  KBr
(4)
 CH3CH  OH  CN
(3) CH3CHO  HCN 
36. During the combustion of ethene, the type of
hybridization on carbon changes as Cl

(1) sp  sp2 (2) sp2  sp

 Cl2 
FeCl3
  HCl
(3) sp  sp
2 2
(4) sp  sp
3 (4)
41. Among the following, the one which is easily
AROMATIC HYDROCARBONS nitrated is
37. The number of aromatic species among the (1) Benzene (2) Benzaldehyde
following (3) Phenol (4) Chlorobenzene
42.
CH  CH3
 CH3  CH 2  CH 2  Cl 
anhy.AlCl3

CH3
   During this reaction the intermediate formed
(1) 3 (2) 5 is
(1) Carbanion
(3) 4 (4) 2
(2) Carbon free radical
38. Which of the following is an aromatic (3) Benzyne
compound ? (4) Carbocation
43. Which of the following molecule contain all
atoms in coplanar
(1) (2) (1) Ethyne (2) Ethane
 (3) Ethene (4) Ethanal
44. In Thiophene, the electron density is
(3) (4) maximum on
39. Which of the following is least reactive in
electrophillic aromatic substitution ?

Sri Chaitanya
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Chemistry

4 3 46. Consider the nitration of benzene using

mixed Conc. H 2SO 4 and HNO 3 . If a large
5 2
S 1 amount of KCl is added to the mixture the
rate of nitration will be
H
(1) unchanged (2) doubled
(1) 2 and 3 (2) 3 and 4
(3) faster (4) slower
(3) 2 and 4 (4) 2 and 5
47. The oxidation of benzene by V2O5 in the
45. In the given reaction product ‘P’ is
presence of air produces the compound ‘X’.
CH 3 The number of lone pairs present in the
compound ‘X’ is
+ 
HF
0C
 (1) 5 (2) 2
(3) 6 (4) 7
CH 3 48. What is the major product formed when the
following compound is treated with Br2 in
presence of FeBr3
NO2

OH
(1) F
(1)
CH 3 NO2

OH
Br
(2) (2)
CH 3 NO2
Br

OH
(3)
(3)
NO2
CH 3
Br

CH 3 OH
(4)
(4)

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Chemistry

NO2 NH 2 CH 3

Br OH (3) (4)
49. The one with most negative inductive effect 51. Aromatic species among the following is
is
(1) – CN (2) Br
 N NH N
(3)  N H3 (4) – COOH
O
(1) (2)
50. Which of the following compounds will
undergo Friedel – Crafts reaction easily
NO2 COOH S
(3) (4) All the above

(1) (2)
KEY

1) 3 2) 4 3) 4 4) 2 5) 1 6) 2 7) 2 8) 3 9) 2 10) 3
11) 3 12) 2 13) 1 14) 4 15) 2 16) 2 17) 4 18) 4 19) 1 20) 1
21) 2 22) 2 23) 1 24) 3 25) 3 26) 1 27) 3 28) 1 29) 3 30) 3
31) 3 32) 1 33) 4 34) 1 35) 4 36) 2 37) 1 38) 4 39) 1 40) 2
41) 3 42) 4 43) 3 44) 4 45) 2 46) 1 47) 3 48) 2 49) 3 50) 4
51) 4 52) 53) 54) 55) 56) 57) 58) 59) 60)

Sri Chaitanya
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