1. If 0.5 moles of BaCl2 are mixed with 0.

2 moles of Na3PO4, the maximum number

of moles of Ba3(PO4)2 that can be formed is

(1) 0.7 (2) 0.5 (3) 0.30 (4) 0.10

2. Assume that the nucleus of the fluorine atom is a sphere of radius 5 x 10 -13 cm.
What is the density of matter in the nucleus?

(1) 6.02 x 1023 g/mL (2) 6.02 x 1013 g/mL

(3) 12.02 x 1023 g/mL (4) 12.02 x 1013 g/mL

3. 1.00 x 10-3 moles of Ag+ and 1.00 x 10-3 moles of CrO42- react together to form
solid Ag2CrO4. Calculate the amount Ag2CrO4 formed (Ag2CrO4 = 331.73 g mol-1)

(1) 0.268 g (2) 0.166 g (3) 0.212 g (4) 1.66 g

4. How many gram of H2SO4 are present in 0.25 mole of H2SO4?

(1) 2.45 (2) 24.5 (3) 0.245 (4) 0.25

5. 5 g of each of the following gases at 87 oC and 750 mm pressure are taken. Which
of them will have the least volume?

(1) HF (2) HCl (3) HBr (4) HI

6. 5.85 g of NaCl is dissolved in 1 L of pure water. The number of ions in 1 mL of this

solution is

(1) 6.02 x 1019 (2) 1.2 x 1022 (3) 1.2 x 1020 (4) 6.02 x 1020

7. The number of molecules of water in 333 g of Al2(SO4)3.18H2O is

(1) 18.0 x 6.023 x 1023 (2) 9.0 x 6.023 x 1023

(3) 18.0 (4) 36.0

8. Equivalent weight of I2 in the reaction,

I2+ 5Cl2 + 6H2O → 2HIO3 + 10HCl is

(1) M (2) M/2 (3) M/5 (4) M/10

9. The vapour density of a mixture containing NO2 and N2O4 is 38.3 at 300 K. The
number of moles of NO2 in 100 g of the mixture is approximately

(1) 0.44 (2) 4.4 (3) 33.4 (4) 3.34

10. The simplest formula of a compound containing 50% of element x (atomic mass
10) and 50% of element y (atomic mass 20) is

(1) XY (2) X2Y (3) XY3 (4) X2Y3

11. The equivalent weight of an element is 4. Its chloride has a vapour density 59.25.
Then the valency of the element is

(1) 4 (2) 3 (3) 2 (4) 1

12. 1.00 g of BaCl2 is treated with excess of aqueous AgNO3 and all chlorine is
recovered as 1.38 g of AgCl. What is the atomic weight of Ba? (Cl = 35.5, Ag =
108)

(1) 137 (2) 172.5 (3) 33 (4) 68.5

13. A metal oxide has the formula Z2O3. It can be reduced by hydrogen to give free
metal and water. 0.1596 g of the metal oxide requires 6 mg of hydrogen for
complete reduction. The atomic weight of the metal is

(1) 27.90 (2) 159.60 (3) 79.80 (4) 55.80

14. Chlorine is prepared in the laboratory by treating manganese dioxide (MnO 2) with
aqueous hydrochloric acid according to the reaction

4HCl(aq) + MnO2(s) → 2H2O(l) + MnCl2(aq) + Cl2(g)

How many grams of HCl will react with 5.0 g of manganese dioxide?

(1) 6.4 g HCl (2) 4.8 g HCl (3) 8.4 g HCl (4) 7.2 g HCl
15. A welding fuel gas contains carbon and hydrogen only. Burning a small sample of
it in oxygen gives 3.38 g of CO2, 0.690 g of water and no other product. A volume
of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g.
Molecular formula of the compound is
(1) C2H4 (2) C2H2 (3) C3H8 (4) C3H6

16. A student prepared a standard solution of sodium oxalate by weighing 3.2 g of

the dry anhydrous salt, dissolving it in distilled water and making the solution
upto 500 ml. Molarity of the sodium oxalate solution is

(1) 0.04776 (2) 0.07446 (3) 0.06447 (4) 0.07644

17. The hydrated salt Na2CO3.xH2O undergoes 63% loss in mass on heating and
becomes anhydrous. The value of x is

(1) 3 (2) 5 (3) 7 (4) 10

18. The oxides of two metals A and B are isomorphous. The metal A (atomic weight =
52.9) forms chloride whose vapour density is 79. The oxide of B contains 47.1% of
oxygen. Thus, atomic weight of B is

(1) 27 (2) 13 (3) 42 (4) 54

19. 50.0 kg of N2(g) and 10.0 kg of H2(g) are mixed to produce NH3(g). Identify the
limiting reagent in the production of NH3 in this situation

(1) Nitrogen (2) Hydrogen

(3) Can’t be predicted (4) None of these

20. A cylinder contains 100 g of an ideal gas (mol. wt. 40 g mol -1) at 27 oC and 2 atm
pressure. In transference process, the cylinder fell and a dent was created, i.e.,
there was a decrease in the volume of cylinder. But valve attached to the cylinder
cannot keep the pressure greater than 2 atm, so 10 g of gas leaked out. Calculate
volume of the cylinder after dent.

(1) 3.08 (2) 30.8 (3) 2.77 (4) 27.7

21. The mixture of CO and CO2 contains 60% CO and rest is CO2, Two litres of this
mixture is passed over hot charcoal. What is the volume of the mixture after the
reaction?

(1) 3.6 L (2) 2.4 L (3) 2.8 L (4) 4.0 L

22. A compound has a haemoglobin like structure. It has one Fe. It contains 4.6% of
Fe. The approximate molecular mass is

(1) 100 g mol-1 (2) 1200 g mol-1 (3) 1400 g mol-1 (4) 1600 g mol-1

23. A metal M of equivalent mass E forms an oxide of molecular formula M xOy. The
atomic mass of the metal is given by the correct equation.

(1) 2E(y/x) (2) xy/E (3) E/y (4) y/E

24. If an iodized salt contains 1% of KI and a person takes 2 g of the salt everyday, the
iodide ions going into his body everyday would be approximately

(1) 7.2 x 1021 (2) 7.2 x1019 (3) 3.6 x 1021 (4) 9.5 x 1019

25. 25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL
of solution. If sodium carbonate dissociates completely, molar concentration of
sodium ion, Na+ and carbonate ions, CO32- are respectively (Molar mas of Na2CO3
= 106 g mol-1 )

(1) 0.955 M and 1.910 M (2) 1.910 M and 0.955 M

(3) 1.90 M and 1.910 M (4) 0.477 M and 0.477 M

26. Two students X and Y report the weight of the same substance as 4.0 g and 4.00 g
respectively. Which of the following statement is correct?

(1) Both are equally accurate (2) X is more accurate than Y

(3) Y is more accurate than X (4) Both are inaccurate scientifically

27. The total number of electrons present in 18 mL of water (density of water is 1 g

ml-1) is

(1) 6.02 x 1023 (2) 6.02 x 1022 (3) 6.02 x 1024 (4) 6.02 x 1025
28. A 400 mg iron capsule contains 100 mg of ferrous fumarate, (HCOO) 2Fe . The
percentage of iron present in it is approximately

(1) 33% (2) 25% (3) 14% (4) 10%

29. 2.5 g of the carbonate of a metal was treated with 100 mL of 1 N H 2SO4. After the
completion of the reaction, the solution was boiled off to expel CO 2 and was then
titrated against 1 N NaOH solution, the volume of alkali that would be consumed
if the equivalent weight of the metal is 20

(1) 50 (2) 25 (3) 75 (4) 100

30. Common salt obtained from sea water contains 95% NaCl by mass. The
approximate number of molecules present in 10.0 g of the salt is

(1) 1021 (2) 1022 (3) 1023 (4) 1024

Answer key :

1. (4) 2. (2) 3. (2) 4. (2) 5.(4) 6. (3)

7. (2) 8. (3) 9. (2) 10.(2) 11. (1) 12. (1)

13. (4) 14. (3) 15. (2) 16. (1) 17. (4) 18. (1)

19. (2) 20. (4) 21. (3) 22. (2) 23. (1) 24. (2)

25. (2) 26. (3) 27. (3) 28. (4) 29. (1) 30. (3)