MAJOR TEST - 1 (MAIN) CHEMISTRY (MAIN) CODE: 1

PART (B) : CHEMISTRY

SECTION-I : (SINGLE ANSWER CORRECT TYPE)

This section contains 30 multiple choice questions. Each question has four choices (1), (2), (3)
and (4) out of which ONLY ONE is correct.

31. An alkane has a C/H ratio (by mass) of 5.1428 : 1. Its molecular formula is :
(1) C6 H14 (2) C5 H12 (3) C7 H16 (4) C8 H 18

32. One litre of CO2 is passed over hot coke. After one hour volume becomes 1.4 litre. The percent
composition of products is
(1) 0.6 litre CO (2) 0.8 litre CO2
(3) 0.6 litre CO2 and 0.8 litre CO (4) None of these

33. The pair of species having same percentage of carbon is

(1) CH 3COOH and C6 H12O6 (2) CH 3COOH and C2 H 5OH
(3) HCOOCH 3 and C12 H 22O11 (4) C6 H12O6 and C12 H 22O11

34. The percent loss in weight after heating a pure sample of potassium chlorate (mol. Mass = 122.5)
will be
(1) 12.25 (2) 24.50 (3) 39.18 (4) 49.0

35. The mass of 112 cm3 of CH 4 gas at STP is

(1) 0.08 g (2) 1.6 g (3) 0.16 g (4) 0.8 g

36. If half mole of oxygen combine with Al to form Al2O3 , the weight of Al used in the reaction is
(1) 27 g (2) 40.5 g (3) 54 g (4) 18 g

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37. On repeated sparking 10 mL of mixture of carbon monoxide and nitrogen required 7 mL of oxygen
for combustion of CO and N 2 to CO2 and NO . The volume of nitrogen in mixture is (All volumes
are measured under identical conditions)
7 17
(1) mL (2) 4 mL (3) 7 mL (4) mL
2 2

38. For a given mass of a gas, if pressure is reduced to half and temperature is increased two times, then
the volume would become
V
(1) (2) 2V 2 (3) 6V (4) 4V
4

39. The compressibility factor for H 2 and He is usually

(1) > 1 (2) = 1 (3) < 1 (4) Either of these

40. The four quantum numbers of the valence electron of potassium are
1 1 1 1
(1) 4, 1, 0 and (2) 4, 0, 1 and (3) 4, 0, 0 and (4) 4, 1, 1 and
2 2 2 2

41. The ratio of rate of diffusion of SO2 (M = 64) and oxygen (M = 32) is ……
(1) 1:1 (2) 2:1 (3) 1:2 (4) 1:1.414

42. The volume occupied by 7g of nitrogen gas at 27ºC and 750.9 mm Hg pressure is
(1) 8.24 L (2) 6.14 L (3) 6.22 L (4) 5.24 L

43. The average kinetic energy of an ideal gas, per molecule at 25ºC will be
(1) 61.7 1021 J (2) 6.17 1020 J (3) 6.17 1021 J (4) 7.16 1020 J

44. Two separate bulbs contain ideal gases A and B. The density of gas A is twice that of B. The
molecular mass of A is half that of B. The two gases are at the same temperature. The ratio of the
pressure of A to that of B gas is
(1) 2 (2) 1/2 (3) 4 (4) 1/4

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45. Consider 1cm3 sample of air at absolute temperature T0 at sea level and another 1cm3 sample of air
(same number of moles) at a height where the pressure is one third atmosphere. The absolute
temperature T of the sample at the height is
T
(1) Equal to 0
3
(2) Equal to T0
(3) Equal to 3T0
(4) Cannot be determined in terms of T0 from the above data

46. Which one is the electron deficient compound?

(1) ICl (2) NH 3 (3) BCl3 (4) PCl3

47. Octet rule is not valid for the molecule

(1) CO2 (2) NO (3) CO (4) O2

48. The correct sequence of increasing electron affinity is

(1) F  Cl  Br  I (2) S  Se  Te  O (3) F  O  N  C (4) Cl  S  P  Si

49. Which one of the following is having zero dipole moment?

(1) CCl4 (2) CH 3Cl (3) CH 3 F (4) CHCl3

50. Which of the following have both polar and non-polar bonds?
(1) C2 H 6 (2) NH 4 Cl (3) HCl (4) AlCl3

51. Which of the following has p  d bonding?

(1) NO3 (2) CO32 (3) BO33 (4) SO32

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52. A 3p-orbital has

(1) Two non-spherical nodes
(2) Two spherical nodes
(3) One spherical and one non-spherical node
(4) One spherical and two non-spherical nodes

53. The linear structure is not formed by

(1) SnCl2 (2) NCO (3) CS2 (4) NO2

54. Which one of the following species is diamagnetic in nature?

(1) Fe 2 (2) Cu  (3) Mn 2 (4) Ni 2

55. Which one of the following oxides is expected exhibit paramagnetic behaviour?
(1) CO2 (2) SO2 (3) ClO2 (4) SiO2

56. The number of d-electrons in Fe 2  (Z  26) is not equal to that of

(1) p-electrons in Ne(Z = 10) (2) s-electrons in Mg(Z = 12)
(3) d-electrons in Fe(Z = 26) (4) p-electrons in Cl(Z = 17)

57. If each hydrogen atom is excited by giving 8.4 eV of energy, then the number of spectral lines
emitted is equal to
(1) None (2) Two (3) Three (4) Four

58. The tenth element in the periodic table resembles the element with atomic number
(1) 2 and 30 (2) 8 and 18 (3) 2 and 54 (4) 8 and 54

59. Which of the following gas has highest critical temperature?

(1) NH 3 (2) Co2 (3) O2 (4) N 2

60. The first, second and third ionization potentials ( E1 , E2 and E3 ) for an element are 7 eV, 12.5 eV
and 42.3 eV respectively. The most stable oxidation state of the element will be
(1) +1 (2) +2 (3) +3 (4) +4

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