RM

NEET & AIIMS 2018-19

M-CAPS-27 : CHEMISTRY
(Medical-Classroom Assessment Practice Sheet)
Topics covered : Introduction, Double salts vs coordinate complex, Various classification of ligands and IUPAC
nomenclature, Isomerism, Werner’s coordination theory, EAN, V.B.T, C.F.T, Organometallic compounds, Importance
and applications of coordination compounds.
Choose the correct answer :
1. The coordination number of a metal in coordination 8. The IUPAC name of [Ni(NH3)4][NiCl4] is
compound is
(1) Tetrachloridonickel (II) tetraamminenickel (II)
(1) Same as primary valency
(2) Tetraamminenickel (II) tetrachloridonickel (II)
(2) Sum of primary and secondary valencies
(3) Tetraamminenickel (II) tetrachloridonickelate (II)
(3) Same as secondary valency
(4) Twice the primary valency (4) Tetraamminenickel (IV) tetrachloridonickelate (IV)

2. Which of the following complexes has six 9. The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is
coordination number? (1) [Cr(H2O)4(NO2)]Cl2
(1) [Zn(CN)4]2– (2) [Co(en)2Cl2]+ (2) [Cr(H2O)4Cl2]NO2
(3) [Ag(NH3)2]+ (4) [Ni(NH3)4]2+ (3) [Cr(H2O)4Cl(ONO)]Cl
3. Which of the following ligands forms chelate with (4) [Cr(H2O)3Cl2(NO2)]H2O
metal ion?
10. The primary valency of the metal ion in the
(1) Acetate (2) Oxalate
co-ordination compound, K2[Ni(CN)4] is
(3) Cyanide (4) Ammonia
(1) Four (2) Zero
4. An example of ambidentate ligand is
(3) Two (4) Six
(1) H2O (2) NO2– 11. Which among the following is a polydentate ligand?
(3) NH2CH2CH2NH2 (4) NH3 (1) Oxalate (2) Ethane-1, 2-diamine
5. When two moles of [Co(NH3)5Cl]Cl2 is treated with (3) EDTA4– (4) SCN –
excess silver nitrate solution, the number of moles
12. Which one of the following will give a white
of silver chloride formed is
precipitate with AgNO3 in aqueous medium?
(1) 3 (2) 6
(1) [Co(NH3)5Cl](NO2)2
(3) 4 (4) 2
(2) [Pt(NH3)2Cl2]
6. In solution, the complex, [Pt(NH3)6]Cl4 gives
(3) [Pt(en)Cl2]
(1) 4 ions (2) 3 ions
(4) [Pt(NH3)4]Cl2
(3) 2 ions (4) 5 ions
7. As per IUPAC nomenclature, the name of the 13. Which kind of isomerism is exhibited by the
complex, [Co(H2O)4(NH3)2]Cl3 is octahedral complex, [Co(NH3)4Br2]Cl?

(1) Tetraaquadiaminecobalt (III) chloride (1) Geometrical and ionization

(2) Tetraaquadiamminecobalt (III) chloride (2) Geometrical and optical
(3) Diaminetetraaquacobalt (III) chloride (3) Optical and ionization
(4) Diamminetetraaquacobalt (III) chloride (4) Only geometrical

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14. The optically active co-ordination complex ion 23. The magnetic moment of a transition metal of 3d
among the following is series is 48 B.M. It's electronic configuration is
(1) Trans-[Co(en)2Cl2]+ (2) Cis-[Co(en)(NH3)2Cl2]+ (1) 3d14s2 (2) 3d54s1
(3) [Co(NH3)6]3+ (4) [Co(NH3)4Cl2]+ (3) 3d64s2 (4) 3d54s2
15. The number of possible isomers of a square planar 24. Crystal field stabilization energy for high spin d4
complex, [Mabcd] is/are octahedral complex is
(1) 4 (2) 3 (1) –0.6Δ0 (2) –1.8Δ0
(3) 2 (4) 1 (3) –1.6Δ0 + P (4) –1.2Δ0
16. The complex ion having minimum magnitude of 25. High spin complex of d 6 configuration in an
Δo (CFSE) in octahedral field is
octahedral field will have the CFSE equal to
(1) [CoCl6]3– (2) [Co(CN)6]3–
(3) [Co(H2O)6]3+ (4) [Co(NH3)6]3+ −12 −14
(1) Δ0 (2) Δ0
5 5
17. The number of unpaired electrons in central metal
of cobalt ferrocyanide, Co2[Fe(CN)6] is
−41 −2
(1) 0 (2) 2 (3) Δ0 (4) Δ0
5 5
(3) 1 (4) 3
26. The hybridized state of Al3+ in the complex ion
18. Geometrical shapes of the complexes formed by formed when AlCl3 is treated with aqueous acid is
the reaction of Ni 2+ with Cl – , NH 3 and CN – ,
(1) sp3 (2) dsp2
respectively are
(3) sp3d2 (4) sp2d
(1) Octahedral, tetrahedral and square planar
27. Which of the following complexes is an inner
(2) Tetrahedral, octahedral and square planar
orbtial complex?
(3) Square planar, tetrahedral and octahedral
(1) [FeF6]3– (2) [NiCl4]2–
(4) Octahedral, square planar and tetrahedral
(3) [Ni(H2O)6]2+ (4) [Mn(CN)6]3–
19. The compound which does not show
paramagnetism is 28. Which of the following pairs does not exhibit colour
in solution?
(1) [Cu(NH3)4]Cl2 (2) [Ag(NH3)2]Cl
(1) ZnCl2, HgCl2 (2) CuCl2, VOCl2
(3) [NiCl4]2– (4) [CoF6]3–
(3) VOCl2, FeCl2 (4) MnCl2, FeCl3
20. The shape of [Cu(NH3)4]2+ is square planar, Cu2+ in
this complex is 29. Which of the following complexes will show Jahn-
Teller distortion?
(1) sp3 hybridised
(1) [Cu(H2O)6]2+ (2) [Cr(H2O)6]3+
(2) dsp2 hybridised
(3) [Mn(H2O)6]2+ (4) [Co(H2O)6]3+
(3) sp3d hybridised
30. Out of the following, choose a correct expression
(4) sp3d2 hybridised
for finding out the cystal field stabilization energy
21. What is the geometrical shape of complex and in tetrahedral coordination entities.
hybridisation of central metal in [Fe(CO)5]?
(1) Tetrahedral, sp3 ⎡⎛ ⎞ ⎛ ⎞⎤
(1) CFSE = ⎢⎜ + 4 × ne−( t ) ⎟ + ⎜ + 6 × ne –(e) ⎟ ⎥ Dq
(2) Square planar, dsp2 ⎣⎝ 2 ⎠ ⎝ ⎠⎦
(3) Trigonal bipyramidal, dsp3
⎡⎛ ⎞ ⎛ ⎞⎤
(4) Trigonal bipyramidal, sp3d (2) CFSE = ⎢⎜ + 4 × ne−( t ) ⎟ − ⎜ − 6 × ne–(e) ⎟ ⎥ Dq
⎣ ⎝ 2 ⎠ ⎝ ⎠⎦
22. Out of the following, choose a correct statement.
(1) [Cu(NH3)6]2+ is a colourless ion
⎡⎛ ⎞ ⎛ ⎞⎤
(2) [Zn(H2O)6]2+ ion is blue coloured (3) CFSE = ⎢⎜ + 4 × ne−( t ) ⎟ + ⎜ − 6 × ne–(e) ⎟ ⎥ Dq
⎣⎝ 2 ⎠ ⎝ ⎠⎦
(3) [Ni(CO)4] ion has a square planar shape
(4) If [CoCl(NH3)5]2+ absorbs yellow colour of light, ⎡⎛ ⎞ ⎛ ⎞⎤
then the colour of this coordination entity is violet. (4) CFSE = ⎢⎜ + 6 × ne−( t ) ⎟ + ⎜ − 4 × ne–(e) ⎟ ⎥ Dq
⎣⎝ 2 ⎠ ⎝ ⎠⎦

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Regular Medical 2018-19 M-CAPS : 27 (Medical-Classroom Assessment Practice Sheet)

31. The homoleptic complex is 39. Major product of the given reaction is
(1) [Co(NH3)4Cl2]+
(2) [Co(NH3)6]3+ + HBr → Product

(3) [Ni(NH3)4Cl2]
(4) [Fe(NH3)4Cl2]+ Br
(1) (2)
32. Which of the following is not a metal carbonyl?
Br
(1) Ni(CO)4
(2) [Co(CN)6]3–
(3) (4)
(3) Mn2(CO)10
Br Br
(4) Fe(CO)5
40. Which of the following will not lead to the formation
33. In which of the following carbonyls, the bond length of an alkyl halide?
of CO is the highest?
(1) [V(CO)6]– (2) [Cr(CO)6] CH2OH
(3) [Mn(CO)6]+ (4) [Fe(CO)4]2– OH
(1) (2) Δ
34. The number of bridging CO groups in [Co2(CO)8] + HCl
and [Fe(CO)5] are respectively + PCl5
(1) 2, 0 (2) 1, 1 OH

(3) 1, 0 (4) 2, 1
NBS/hν
35. The addition of four amine groups to a metal ion (3) (4) Toluene + Cl2 Fe
⎯⎯⎯ →
dark
(X 2+ ) shows a stability constants of 2 × 10 4 ,
1.5 × 103, 1.2 × 102 and 1.4 × 101 respectively.
HBr NaI
Then, the overall complex dissociation equilibrium 41. F3C – CH = CH2 ⎯⎯⎯ → (A) ⎯⎯⎯⎯⎯
dry acetone
→ (B)
constant for [X(NH3)4]2+ ion is
Compounds (A) and (B) are respectively
(1) 5.04 × 10–10 (2) 19.8 × 10–10
(1) F3C – CH(Br) – CH3 and F3C – CH(I) – CH3
(3) 1.98 × 10–11 (4) 50.4 × 10–9
(2) F3C – CH2 – CH2Br and F3C – CH2 – CH2I
36. Excess of copper and iron are removed mainly by
which of the following chelating ligands via (3) BrF2C – CH = CH2 and IF2C – CH = CH2
formation of coordination compounds? (4) BrF2C – CH2 – CH2Br and IF2C – CH2 – CH2I
(1) Desferrioxime–B and EDTA respectively ZnCl
42. In the reaction C2H5OH + HX ⎯⎯⎯⎯ 2
→ C2H5X +
(2) EDTA and D-Penicillamine respectively H2O. The order of reactivity of HX is
(3) Desferrioxime–B and D-Penicillamine (1) HI > HBr > HCl
respectively
(2) HCl > HBr > HI
(4) D-Penicillamine and Desferrioxime B-respectively
(3) HCl > HI > HBr
37. Ethylidene chloride is a/an
(4) HBr > HI > HCl
(1) Gem-dihalide (2) Allylic halide
CCl4
(3) Vinylic halide (4) Vic-dihalide 43. CH3 – C ≡ CH + Br2 ⎯⎯⎯ → (A)

CH2Cl The product (A) is

38. IUPAC nomenclature of is
Br Cl Br Br

(1) Benzylchloride (1) CH3 – C = CH (2) CH3 – C – CH

(2) Chlorophenylmethane Br Br

(3) 1-chloro-2-methylbenzene (3) CH3 – C = CH2 (4) CH 3 – CH2 – CHBr2

(4) Benzoylchloride Br
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M-CAPS : 27 (Medical-Classroom Assessment Practice Sheet) Regular Medical 2018-19

44. Among the following halide ions (X –) reaction, 45. The number of all possible products excluding
which is feasible is?
stereoisomers obtained on monochlorination of
(1) X– + CH3 – CH2 – H CH3 – CH2 – X + H–
n-butane and iso-butane are respectively
–
⊕
(2) X + CH3 – OH CH3 – X + H2O (1) 2 and 3
H (2) 3 and 2
–
(3) X + CH3 – CH3 CH3 – X + CH3 (3) 2 and 1
–
(4) X + CH3 – OH CH3 – X + OH (4) 2 and 2

  

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 RM

NEET & AIIMS 2018-19

M-CAPS-27 : CHEMISTRY
(Medical-Classroom Assessment Practice Sheet)

ANSWERS
1. (3) (E) 2. (2) (E) 3. (2) (M) 4. (2) (E) 5. (3) (M)
6. (4) (M) 7. (4) (E) 8. (3) (M) 9. (2) (E) 10. (3) (E)
11. (3) (M) 12. (4) (D) 13. (1) (D) 14. (2) (VD) 15. (2) (M)
16. (1) (E) 17. (1) (M) 18. (2) (E) 19. (2) (E) 20. (2) (E)
21. (3) (M) 22. (4) (D) 23. (2) (M) 24. (1) (D) 25. (4) (VD)
26. (3) (M) 27. (4) (E) 28. (1) (M) 29. (1) (M) 30. (3) (E)
31. (2) (E) 32. (2) (E) 33. (4) (M) 34. (1) (E) 35. (3) (D)
36. (4) (M) 37. (1) (E) 38. (2) (E) 39. (3) (VD) 40. (4) (M)
41. (2) (D) 42. (1) (M) 43. (2) (E) 44. (2) (M) 45. (4) (M)

Question Level Questions Number

Easy (E) – 18 1, 2, 4, 7, 9, 10, 16, 18, 19, 20,
27, 30, 31, 32, 34, 37, 38, 43
Medium (M) – 18 3, 5, 6, 8, 11, 15, 17, 21, 23, 26,
28, 29, 33, 36, 40, 42, 44, 45
Difficult (D) – 06 12, 13, 22, 24, 35, 41

Very Difficult (VD) – 03 14, 25, 39

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