CHEMICAL BONDING

WORKSHEETS.
1. The maximum possible number of 8.if the electronegativity difference between
hydrogen bonds is, a H20 molecule two atoms A and B is 2.0 , then the
participates percentage of covalent character in the
1) 1 2) 2 molecule is
3) 3 4) 4 1) 54% 2)46%
3)23% 4) 72%
2.CCl4 is insoluble in water because :
1)CCl4 is nonpolar and water is polar
2)water is Nonpolar and CCl4 polar
3)water and CCl4 both are polar 9.For which of the following hybridisation
4)none of the above the bond angle is maximum
1) sp2 2) sp
3) sp3 4)dsp2
3.The bond angle and % of d character in SF6
are
1) 120°,20% 2) 90°,33%
3) 109° ,25% 4) 90°, 25%
10.the incorrect statement regarding
4.The bond order in NO is 2.5 while that in
bonding molecular orbital is
NO+ is 3.which of the following statements
1)Bonding molecular orbitals posess less
is true for the two species ?
energy than combining atomic orbitals
1)bond length in NO+ is greater than that of
2)Bonding molecular orbitals have low
NO
electron density between the two nuclei
2) bond length in NO is greater than that of
3) Every electron in bonding molecular
NO+
orbitals contributes to attraction between
3) bond length in NO+ is equal to NO
atoms
4) bond length is un predictable .
4)They are formed when the lobes of the
5.the ratio of bonds in benzene is combining atomic orbitals have same sign
1) 2 2) 6
3) 4 4)8
11.Chlorine atom in its third excited state
6.Number of lone pairs in XeOF4 is/are
,reacts with fluorine to form a compound X
1) 0 2) 1
the formula and shape of x are
3) 2 4) 3
1)ClF3, pentagonal
7. H2O boils at higher temperature than H2S 2) ClF4, tetrahedral
because it is capable of forming 3) ClF4, pentagonal bipyramidal
1) ionic bonds 2) covalent bonds 4) ClF7, pentagonal bipyramidal
3) hydrogen bonds 4) metallic bondsis
12.In which of the following componds 18.The compound with maximum dipole
sp2 hybridisation is absent . moment among the following is
1) P-dichlorobenzene
1) CH2= CH-CH=CH2 2) CH C-CH2-CH3
2) m-dichlorobenzene
3) CH2-CH=CH2 4) CH2=CH-CH2-CH3
3) o-dichlorobenzene
4)Carbon tetrachloride

13.Linear molecule among the following is 19.The bond order in O2+ is equal to the bond
1)H2S 2)NO2 order in
3)ClO2 4) CO 1)N2+ 2)CN-
3)CO 4)NO+

20.Which of the following is most covalent ?

14.When O2 is converted to O2+ 1) SiCl4 2) MgCl2
1)Both para magnetic character and bond 3)NaCl 4)AlCl3
order increases
2)Bond order decrease 21.Consider the following compounds
3) Para magnetic character increases i) chloroethene ii) benzene iii)1,3-butadiene
4) Para magnetic character decreases and the iv)1,3,5-hexatriene .
bond order increases All the carbon atoms are sp2 hybridised in
1) i,iii,iv only 2) i,ii only
15.Dipolemoment is shown by 3) ii,iii,iv only 4) i,ii,iii,iv only
1)Cis -1,2 –dichloro ethane
2) trans-1,2 –dichloro ethane 22.Which of the compound has zero dipole
3) trans-1,2 –dichloro -2-pentene moment.
4)none 1) 1,1-dichloroehene
2) cis1,2-dichloroehene
16.The molecule which has T-shaped 3) trans1,2-dichloroehene
structure is 4) none of the above
1)PCl3 2)ClF3
3)NH3 4)BCl3 23.The bond order in O2-2 is
1)3 2)2
17.Accordingto VSEPR theory the repulsion 3) 3/2 4)1
between different pair (lone or bond)of
electrons obey the order 24.The number of unpaired electrons in O2
1) lp-bp lp-lp bp-bp molecule is
2) lp-bp bp-bp lp-lp 1) Zero 2) 1
3)lp-lp lp-bp bp-bp 3) 2 4) 3
4) bp-bp lp-lp lp-bp
25.Carbon atoms in C2(CN)4 are
1) sp-Hybridised
2)sp2- Hybridised
3) sp- and sp2- Hybridised
4) sp ,sp2 and sp3 Hybridised
26.In polar molecule ,the ionic charge is 4.38
X 10-10 esu.If the inter ionic distance is 1A°
unit, then the dipole moment is
1) 41.8D 2) 4.18D
3)4.8D 4)0.48D
27. N2 and O2 are converted into N2+and O2+
respectively .which of the following is not
correct
1) In N2+ ,the N-N bond weakens
2) In O2+ ,O-O bond order increases
3) In O2+ ,paramagnetism decreases
4) N2+ becomes diamagnetic
28. Na+, Mg+2, Al+3, Si+4 are iso electronics
.their ionic size follows the order
1) Na+ < Mg+2 < Al+3 < Si+4
2) Na+ > Mg+2 < Al+3 <Si+4
3) Na+ < Mg+2 > Al+3 >Si+4
4) Na+ > Mg+2 > Al+3 >Si+4
29.According to Fajan’s rules polarization is
more when
1) Small cation and large anion
2) Small cation and small anion
3)Large cationand large anion
4)Large cation and small anion
30.Which of the following is a favourable
factor for cation formation
1)Low ionisation potential
2)High electron affinity
3) High electropositivity
4)Small atomic size
31.Elements whose electronegativities are
1.2 and 3.0 fprm :
1) Ionic bond
2) Covalent bond
3) Coordinate bond
4) Metallic bond
32.Intra molecular hydrogen bonding is
found in
1)Salicylaldehye 2) Water
3) Acetaldehyde 4) Phenol
33.In which of the following molecules /ions
BF3 , NO2-, NH2-, H2O the central atom is sp2
hybridised
1) BF3 and NO2-,
2) NO2- and NH2-
3) NH2- and H2O
4) NO2- and H2O
34.sp3d hybridisation results in
1) A squareplanar molecule
2) An octahedron molecule
3) A trigonal bipyramidal molecule
4) A tetrahedron molecule
35.The example of p-p orbital overlapping is
the formati
1) H2molecule
2)Cl2molecule
3) HCl molecule
4) HBr molecule
36.which of the following has odd electron
and shows paramagnetic character
1)NO 2)SO2
3)CO2 4)H2O
37.Among LiCl BeCl2 BCl3 CCl4 the covalent
bond character follows the order
1) LiCl > BeCl2 > BCl3 > CCl4
2) LiCl < BeCl2 < BCl3 < CCl4
3) LiCl > BeCl2 > CCl4 > BCl3
4) LiCl < BeCl2 < BCl3 > CCl4
38.The lattice energy order for lithium halide
is
1) LiF > LiCl > LiBr > LiI
2) LiCl > LiF > LiBr > LiI
3) LiBr > LiCl > LiF > LiI
4) LiI > LiBr > LiCl > LiF
39.Covalaency of nitrogen in HNO3 is
1)Zero 2) 3 3) 4 4) 5
40.Which ion has a higher polarising power
1) Mg+2 2)Al+3 3)Ca+2 4)Na+
41.Among the following , the compound 46.Which one of the following sets of ions
that contains ionic, covalent and coordinate represent a collection of isoelectronicseries
linkage 1)K+ Cl- Ca+2 SC+3
1) NH3 2) NH4Cl 2) Ba+2 Sr+2 K+ Ca+2
3) NaCl 4) CaO 3) N-3 O-2 F-2 S-2
4)Li+ Na+ Mg+2 Ca+2
42.In which of the following arrangements
the sequence is not strictly according to the 47.In which of the following
properity written against it ? bonding is observed
1) HF < HCl < HBr < HI : 1)NO3- 2)SO3-2
3)BO3-3 4)CO3-2
increasing acid strength
48.In which of the following bond angle is
2) NH3 < PH3 < AsH3 <SbH3 :
maximum
Increasing basic strength 1)NH3 2)NH4+
3) PCl5 4)SCl2
3) B < C < O < N :
49.The correct order of bond angles is
Increasing first ionisation enthalpy
1)H2S <NH3<BF3<SiH4
4)CO2 < SiO2 < SnO2 < PbO2 : 2)NH3<H2S<SiH4<BF3
3)H2S<NH3<SiH4<BF3
Increasing oxidising power. 4)H2S<SiH4<NH3<BF3

43.The d orbital invoved in sp3d hybridisation 50.The hydration of of ionic compounds

is involves
1) d x2y2 2) dxy 1)Evolution of heat
3) dz2 4) dzx 2)Weakening of attractive forces
3) Dissociation into ions
44.In the case of alkali meal halides, covalent
4) all of these
character decreases in the order
1) MI>MBr>MCI>MF
2)MCl>MI>MBr>MF
3) MF>MCl>MBr>MI
4) MF>MCl>MI>MBr

45.The correct order of decreasing

polarisaility of ion is
1) Cl- Br- I- F-
2) F- I- Br- Cl-
3) I- Cl- Br- F-
4) F- Cl- Br- I-