SRI CHAITANYA EDUCATIONAL INSTITUTIONS,INDIA.

A.P,TELANGANA,KARNATAKA,TAMILNADU,MAHARASHTRA,DELHI,RANCHI,CHANDIGARH

CHEMISTRY CHEMICAL BONDING

01. Which one of the following pairs is iso 3) 5 and 2 4) 2 and 3

structural and having the same 08. St – I : The BCl3 is a planar molecule where
hybridization as NCl3 is pyramidal
1) NH 3 & NO3− 2) BF4− & NH 4+ St – II: BCl3 has no lone pair but NCl3 has a
3) NF3 & BF3 4) BCl3 & BrCl3 lone pair of electrons
02. The correct sequence of increasing covalent 1) S-I is correct and S-II is wrong
character is represented by 2) S-I is wrong and S-II is correct
1) BeCl 2 < NaCl < LiCl 3) Both statements are correct
2) NaCl < LiCl < BeCl2 4) Both statements are wrong
09. Which of the following molecule contains
3) BeCl 2 < LiCl < NaCl
both polar and non polar covalent bonds
4) LiCl < NaCl < BeCl2 1) H2O2 2) S2Cl2
03. The correct order in which the O – O bond 3) O2F2 4) All the above
length increases in the following is 10. If z – axis is the molecular axis, then
1) O3 < O 2 < H 2 O 2 2) O3 < H 2 O 2 < O 2 π - molecular orbitals are formed by the
3) O 2 < O3 < H 2 O 2 4) O 2 < H 2 O 2 < O3 overlap of
04. The correct decreasing order of dipole 1) S + Px 2) Px + Py
moment of the following is 3) Pz + Pz 4) Px + Px
1) NH 3 > H 2 O > NF3 > BF3
11. In which one of the following species the
2) BF3 > NF3 > H 2 O > NH 3 central atom has the type of hybridization
which is not the same as that present in the
3) NF3 > BF3 > NH 3 > H 2O
other three
4) H 2 O > NH 3 > NF3 > BF3
1) SF4 2) I3−
05. During change of N2 to N +2 ion, the electron
3) XeF4 4) PCl5
can be removed from which of the following
12. Which one of the following pairs of species
orbital
have the same bond order
1) σ 2PX orbital 2) σ 2Pz orbital
1) O 2 , NO + 2) CN − , CO
3) π 2Px orbital 4) π 2Py orbital
3) N 2 , O −2 4) N +2 , O 2−2
06. Which of the following molecules does not
possess a permanent dipole moment (1)
O
1) SO2 2) H2S O
( 2)
O
( 3)
3) SO3 4) NH3 13. In molecule, the formal
07. The formula of the compound is A2B5. The charges of oxygen atoms 1, 2, 3 are
number of electrons in the outermost respectively
orbitals of A and B respectively are 1) – 1, 0, + 1 2) 0, – 1, +1
1) 6 and 3 2) 5 and 6 3) 0, +1, – 1 4) +1, 0, –1

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14. The types of bonds present in 3) NO +2 4) NO3−
CuSO4 . 5 H2O are
22. An atom with atomic number 20 is most
1) Covalent and co-ordinate covalent
likely to combine chemically with the atom
2) Only electrovalent whose atomic number is
3) Electrovalent, Covalent, Co-ordinate and
1) 11 2) 16
Hydrogen bond
3) 18 4) 40
4) Covalent, electrovalent only
23. Octet rule is not valid for the molecule
15. The ratio of hybrid and un-hybrid orbitals
involved in the bonding of a benzene 1) H 2 O 2) NH 3
molecule is 3) ClF3 4) CCl 4
1) 3 : 2 2) 1 : 1
24. The central atom in a molecule has three
3) 3 : 1 4) 1 : 3
bond pairs and one lone pair of electrons.
16. Among the following, which compound will The shape of the molecule is
show the highest lattice energy
1) Triangular 2) Pyramidal
1) KF 2) NaF
3) Linear 4) Tetrahedral
3) CsF 4) RbF
25. The hybridization of carbon in diamond,
17. St – I : O – Nitro phenol is more volatile
graphite and acetylene is
than P – Nitro phenol
St – II : Boiling point of O – Nitro phenol is 1) sp3 , sp 2 , sp 2) sp3 , sp, sp 2
greater than that of P – Nitro phenol 3) sp 2 , sp3 , sp 4) sp, sp 2 , sp3
1) S-I is correct and S-II is wrong
26. The heat of formation of CH4 is 360 K Cal.
2) S-I is wrong and S-II is correct The heat of formation of C2H6 is 620 K Cal.
3) Both statements are correct The C – C bond energy is
4) Both statements are wrong 1) 80 K Cal 2) 90 K Cal
18. Which of the following hydrogen bonds is 3) 100 K Cal 4) 120 K Cal
relatively weaker 27. If a molecule of MX3 has zero dipole
1) N − − − H − N 2) F − − − − H − F moment, the sigma bonding orbitals used
3) N − − − − H − O 4) O − − − H − O by M (At. no. < 21) is
19. The correct order of increasing C - O bond 1) Pure p 2) sp hybrid
length of CO, CO2 and CO3−2 is 3) sp2 hybrid 4) sp3 hybrid
1) CO3−2 < CO 2 < CO 2) CO 2 < CO3−2 < CO 28. Which one of the following compound has
the smallest bond angle
3) CO < CO 3−2 < CO 2 4) CO < CO 2 < CO 3−2
1) H2O 2) H2S
20. The difference of electro negativity between 3) NH3 4) SO2
X and Y is 2, if X and Y form covalent 29. Statement – I : Bond energy of F2 is greater
bond, the percentage of ionic character in than Cl2
X – Y bond is
Statement – II : F atom is smaller in size
1) 40 % 2) 42 % than Cl
3) 25 % 4) 46 % 1) S-I is correct and S-II is wrong
21. Which of the following has largest bond 2) S-I is wrong and S-II is correct
angle
3) Both statements are correct
1) NO2 2) NO −2 4) Both statements are wrong
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30. A diatomic molecule has dipole moment of 36. The incorrect statement is
1.2 D. If its bond distance is 1.0 A0, What 1) The boiling of H2O is less than HF
fraction of electric charge “e” exist on each 2) The density of ice is less than H2O
atom
3) HF exists as polymer ( HF )6 in vapour state
1) 12 % 2) 18 %
3) 20 % 4) 30 % 4) The O – H bond length is same in
H 2 O, H 2 O 2 and C 2 H 5OH
31. The correct statement regarding the
following reaction is 37. A square planar complex is formed by
H 3 N : + BF3 → H 3 N → BF3 hybridization of which atomic orbitals

1) The hybridization of nitrogen remains same 1) s, p x , p y d z2 2) s, p x , p y d x 2 − y2

2) The shape of NH3 changes from pyramidal 3) s, p x , p y d yz 4) s, p x , p z d yz
to tetrahedral
3) The hybridization of Boron changes from
38. The number of sigma (σ ) and pi (π )
sp2 to sp3 bonds present in tetracyano ethylene
4) All are correct ( C ( CN ) ) are respectively
2 4

32. The most polar bond among the following is 1) 9, 9 2) 9, 10

1) C – F 2) C – O 3) 10, 9 4) 6, 9
3) C – Br 4) C – S 39. Which of the following molecular orbital
33. The correct order of stability of Li 2 , has one nodal plane
Li +2 and Li 2− is 1) σ 2p z 2) π x 2p x

1) Li 2 > Li 2− > Li 2+ 2) Li +2 > Li 2− > Li 2 3) σ 2s 4) π 2p y

3) Li 2 > Li 2+ > Li 2− 4) Li −2 > Li 2+ > Li 2 40. All the following molecules are linear except
one
34. The incorrect statement regarding PCl5 is
1) XeF2 2) CO 2
1) It has trigonal bipyramidal structure
2) ‘P’ is sp3d hybridized 3) SO 2 4) C2 H 2
3) All P – Cl bonds are identical
4) In solid state it exists as PCl+4 and PCl6−
35. Which of the following is not paramagnetic
1) O 2 2) O +2
3) O −2 2 4) O −2
CHEMISTRY

1) 2 2) 2 3) 3 4) 4 5) 2 6) 3 7) 2 8) 1 9) 4 10) 4
11) 3 12) 2 13) 4 14) 3 15) 1 16) 2 17) 3 18) 1 19) 4 20) 4
21) 3 22) 2 23) 3 24) 2 25) 1 26) 1 27) 3 28) 2 29) 4 30) 3
31) 4 32) 1 33) 3 34) 3 35) 3 36) 1 37) 2 38) 1 39) 4 40) 3

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