TEST-2 SOLUTION S

STANDARD ANSWER KEY

Q 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A 1 2 3 4 4 2 1 4 3 1 1 3 2 1 2
Q 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A 4 4 2 1 4 5 3 5 9 2 0 4 3 8 3
Q 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A 3 2 3 1 4 4 1 1 1 3 4 4 3 2 4
Q 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A 3 2 1 3 1 7 3 2 3 7 2 1 3 4 4
Q 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A 4 1 1 3 4 2 4 2 4 2 3 1 1 3 3
Q 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A 3 4 2 3 1 3 4 2 4 0 2 7 1 7 0
(1) (1). For [Ca+2], M1V1 = M2V2 (9) (3). NH4SH(s) NH3 (g) + H2S(g)
0.04 × 50 = M2 × 200
0 0
M2 = 0.01
Similarly, for [SO4–2] 0.1 (–1 – ) 0.1 0.1
= 30% = 0.3
0.0008 × 150 = M2 × 200 So number of moles at equilibrium
M2 = 0.0006 0.1 (1 – 0.3) 0.1 × 0.3 0.1 × 0.3
Ionic product (Q) = [Ca+2] × [SO4–2] = 0.07 = 0.03 = 0.03
Now use PV = nRT at equilibrium
= 6 × 10–6
Ptotal × 3 lit = (0.03 + 0.03) × 0.082 × 600
So, Q < Ksp
Ptotal = 0.984 atm
(2) (2). F for 1 mol combustion of benzene
ng = –1.5 At equilibrium
H = U + ngRT
 –3271 = U –
 U = –3267.25 kJ
for 1.5 mol
(10) (1). I2 + 10HNO3  2HIO3 + 10NO2 + 4H2O
U = –3267.25 × 1.5 = –4900.88 kJ
(3) (3). In HIO3 oxidation state of iodine is +5.
O xidation (11) (1). n = 5; Ti = 100 K; Tf = 200 K;
0 –3
P4
+1
N a H2 P O2 PH 3 CV = 28 J/mol K; Ideal gas
U = nCVT
R eduction
= 5 mol × 28 J/mol K × (200 – 100) K
(4) (4). = 14,000 J = 14 kJ
 Cp = Cv + R = (28 + 8) J/mol K
= 36 J/mol K
 H = nCpT = 5 mol × 36J/mol K×100 K
(5) (4). For equilibrium H2O ()  H2O (g)
= 18000 J = 18 kJ
G = 0, H = U +  (PV)
H > 0 (+ ve) endothermic  (PV) = H – U = (18 – 14) kJ = 4 kJ
S > 0 (+ ve) (12) (3). H = E + ng RT
(6) (2). H° = B.E. (R) – B.E.(P)
= (1 × 433 + 1 × 192) – (2 × 364) E – H = –ng RT
= 625 – 728 = –103 kJ (E – H)  maximum
(7) (1). H4IO6– PCl5(g)  PCl3(g) + Cl2(g) ; ng = 1
+4 + x – 12 = –1 NH4HS(s)  NH3(g) + H2S(g) ; ng = 2
x – 8 = –1 N2 (g) + O2 (g)  2NO(g) + ng = 0
x = +7
(minimum)
(8) (4). CaCO3(s)  CaO + CO2(g) ; ng = 1
(E – H) = maximum for
N2 (g) + O2 (g)  2NO(g)
= 3 [23 (1000 – 300) + (10002 – 3002)] (13) (2). G° = H° – TS°
At equilibrium, G° = 0
= 61950 J  62 kJ H° = T S°

2
 25 × 1000 = 50 × T
= 500K
C = conjugate
(19) (1). S8  (Homo atomic molecule)
(14) (1).
EN = 0 O. N of S = 0
Direction of co-ordinate bond is from S2F2  (O. N of F is always –1)
more EN atom to less EN atom. So there is 2x + (–1) × 2 = 0 2x = 2  x = +1
no development of charge due to this co- So, O. N of S in S2F2 = +1
ordinate bond.
H2S  1 × 2 + x = 0 x = –2
So in HNC 
O·N of H = + 1 So O. N of S in H2S = –2
O·N of N = – 3
O·N of C = + 2
(20) (4).
(15) (2).
...... (1)
= 4 × 200 + 5 × 150 – (100 × 2 + 3 × 120)
= 800 + 750 – 560 = 990 J/k
(16) (4). Due to common ion /reaction will proceed
in backward direction that why solubility
is decreases in the presence of common
ion. = pKa + log 3 ...... (2)
Concentration of common ion increases, pH1 – pH2 = pKa + log 3 – pKa + log 3
solubility decreases. Maximum common
= 2 log 3
ion is obtained from BaCl2.
(21) 5. Since value of equilibrium constant is very
BaCl2  Ba2+ + 2Cl– high, reaction is completely shifted
0.3 0.6 M forward.
+
AgNO3  Ag + NO3 – So total equilibrium pressure is caused by
0.1 0.1 C(g) & D(g) only. So,
+
NaCl  Na + Cl –
0.4 0.4 (22) 3. (90% dissociation)
(17) (4). AB2  A+2 + 2B–
For NaOH  = 100% ; i = 2 0.3 M 0 0
0.3 (1 – 0.9) 0.3 × 0.9 2 × 0.3 × 0.9 M
= 0.54 M
i=2 pOH = 7 – PKa – log C
For K2SO4  2K+ + SO42–  n = 3
i = 1 +  (n – 1) 5.6 = 7 – pKa – log (0.54)
2 = 1 +  (3 – 1)
2 = 1 + 21 = 2 = 1/2 pKa + log 0.54 = 2.8
  = 0.5   = 50% pKa = 3.07  3
(18) (2). H2F+ and H3O+ (23) 5. G° = – 2.303 RT log Kp
– 6.909 = –2.303 × 2 × 10–3 × 300 log Kp
5 = log KP

3
 Kp = 105 × 1 = 1 × 10x
x=5 
(24) 9. rH° = 2 × (– 45 × 103) = –90 × 103 J
When the volume of vessel is doubled,
= – 90 KJ reaction moves in the backward direction.
rS° = 2 × 200 – 190 – 3 × 130 = –180 J Let the decreases in concentration of C be
= –180 × 10–3 KJ yM.
rG° = rH° – TrS° At new equilibrium
A (g) + 2B (g)  C (g)
= – 90 + 300 × 180 × 10–3 = –36
1.5 + y 2+2y
Given that 2 + 2y = 3 y = 1/2 = 0.5
(25) 2. 2H2S (g)  2H2(g) + S2 (g)
Initial conc. 0.1 0 0
Equiv. conc. 0.1 (1 – x) 0.1x 0.1x/2
Molar concentrations are :
On solving x = 4M.
, (28) 3. KCN, K2CO3 and LiCN are the salts of
weak acid and strong base. So, their
aqueous solutions turns red litmus paper
blue.
(NH4)2C2O4 is a salt of weak base
(NH4OH ; Kb = 1.8 × 10–5)
and weak acid
(HOOC.COOH ; = 5.4 × 10–2 and
If x is small, 1 – x 1 = 5.2 × 10–5).
Kc = 1.0 × 10–6 = As a result, the extent of hydrolysis of
NH4+ will be more than that of C2O42–
x3 = 8 × 1 × 10–6 and hence the resulting solution will be
x = 2 × 10–2 acidic.
 % Dissociation = 2 × 10–2 × 100 = 2% (29) 8. The variation of equilibrium constant with
temperature is represented as
(26) 0. In isothermal reversible process
ln K = ln A –

ln K = 4 –
H = 2000 × R = 4000 cal/mol
G = H – TS
= – 9.135 JK–1 mole–1 0 = 4000 – T S
Ssurr. = –Ssystem TS = 4000
Suniverse = 0
= 8 cal/mol
(27) 4. A (g) + 2B (g) C (g)
[A]eq = 3M, [B]eq = 4M
Let [C]eq = xM

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(30) 3. Number of moles of K4[Fe(CN)6] = 0.1 M
 = 50% i.e., 1/2
K4[Fe(CN)6]  4K+ + [Fe(CN)6]4–
Initially 0.1 M 0 0 (35) (4).
After dissociation
0.1 (1 – ) 0.1 (4) 0.1
Total = 0.1 (1 – 0.5) + 0.2 + (0.1 × 0.5) = 0.3
Van't hoff factor,
By parallel axis theorem
I = I0 + MR2
(31) (3).


 (36) (4).
vi
vf dm
r
dr

v = 2v sin 20° ( = 40°)

(32) (2). From conservation of momentum,
p1 = p2 = 40 kg m/s
v' sin  = v sin 45° ....... (1)
v' cos  = e v cos 45° ....... (2)
vsin45°
dI = (dm) r2 = ( dA) r2
= = (0 2) r2 dr
v'cos

v  v'
vcos45° v'sin
45°


(1) ÷ (2) :
  = 60° m = 0 2 (b – a)
Radius of gyration
(33) (3).

(37) (1). Gravitational field

= – gravitational potential gradient

Integrating, we get;
(34) (1).

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  V – V0 = k [ln r – ln r0]
 V = V0 + k ln (r/r0)
(38) (1). According to work energy theorem
 {by (1)} 
Work done by force on the particle
= Change in KE (43) (3).
Work done = Area under F-x graph 0


m M
W = KEfinal – KEinitial = 6.5 Before collision After collision
KEinitial = 0 M vm
m M v1 m
KEfinal = 6.5 J
(39) (1). mg – T = ma By momentum conservation
T = m (g – a) ...(1)
 = I  = rT

...(2)

By equation (1) & (2),

(40) (3). V = A = ab Dividing,

By componendo divided

= – 1 (1– 2 × 0.2) 
= –1 (1 – 0.4) = – 0.6 (44) (2). At height r from center of earth. orbital
Volume approximately decreases by 0.6%.
velocity
(41) (4).
By energy conservation
x dx
KE of m + =0+0
(At infinity, PE = KE = 0)

 KE of 'm' =
(42) (4). Kinetic energy KE =
(45) (4).
....(1)
Since mass of the sphere will be same
Differentiate (1) wrt time

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 

In this time angle rotate by rod


 =  t = 0.5 × 1 = 0.5 radian
(46) (3). (50) (1).Consider a strip of radius x & thickness dx.
Torque due to friction on this strip.
vc
v
m
m M = 4m h vc dx
rest
x
Applying linear momentum conservation
mv = (m + M) vc
vc = v / 5
Applying work energy theorem (51) 7. Due to solid sphere,
Gravitational potential,
–mgh = (m + M) vc2 – mv2

Solve, h = Due to spherical shell,

Gravitational potential,
(47) (2). Work Energy theorem from A to B
Net Gravitational potential

2gh = vB2 – vA2

2 × 10 × 10 = vB2 – 52
vB = 15 m/ s
(52) 3.
Angular momentum about O
L0 = mvr = 20 × 10–3 × 20 = 6 kg.m2/s
x dx
(48) (1). The desired moment of inertia is,

(V2 = 0)

OR

KE per unit volume = P.E per unit volume

(53) 2. Apply W-E theorem on block C

(49) (3).Angular impulse
= change in angular momentum
Substituting values
100x2 + 20x – 8 = 0

= 0.5 rad/s
(54) 3.
Time taken by rod to hit the ground

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 (58) 3. Since the rod is in translation so,  = 0
Finally, Poutside = 0 Pinside =
About O,
Now, P1V1 = P2V2
........ (1)

m Also, N = Mg ....... (2)

m
u u So, X = 3
(55) 7. v (59) 4.
Conservation of momentum along
horizontal
mv cos 60° + 2mu v = 4u

xsin60° (60) 4.
x

Conservation of mechanical energy

m [v2 + u2 + 2vu cos 120°] + mu2
= mgx sin 60°
, acceleration relative to pipe T1 = T2 ; n = 4
(61) (4).
; Time =
= 2 [6C0x6 + 6C2x4 (x3 – 1)
(56) 2. If string does not become loose at A + 6C4 x2(x3 – 1)2 + 6C6(x3 – 1)3]
B
mg
A = 2[6C0x6 +6C2x7 – 6C2x4 + 6C4x8 + 6C4x2
mg

A
R /320 ° R /4 R /2 – 26C4x5 + (x9 – 1 – 3x6 + 3x3)]
 Sum of coefficient of even powers of x
R
= 2 [1 – 15 + 15 + 15 – 1 – 3] = 24
(62) (1). Since there are 8 males and 5 females. Out
of these 13, if we select 11 persons, then
there will be at least 6 males and atleast 3
females in the selection.

 
(63) (1). 10 Identical 21 Distinct 1 0
For string to not be loose at B. Object
0 10 21C ×1
 10
1 9 21C ×1
9
4mgR = mu2 
10 0 21C ×1
(57) 1. 0
21C + ...+ 21C 21C ...... + 21C0= 221
0 10 + 1+
(21C0 + .... + 21C )
10 = 220

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(64) (3). Total cases = number of diagonals  x = 10, 10–4  x = 10 (As x > 1)
= 20C2 – 20 = 170
(65) (4). (70) (2). (4 + x + 7x2)
(1) The number of four-digit numbers Starting
with 5 is equal to 63 = 216 
(2) Starting with 44 and 55 is equal to
36 × 2 = 72 term independent of x in above will be
(3) Starting with 433,434 and 435 is equal to
6 × 3 = 18 4 × coefficient of x0 in expansion of
(4) Remaining numbers are
4322,4323,4324,4325is equal to 4.
So total numbers are + 1 × coefficient of x–1 in expansion of
216 + 72 + 18 + 4 = 310
(66) (2). (1 + x) (1 – x)10 (1 + x + x2)9
+ 7 × coefficient of x–2 in expansion of
(1 – x2) (1 – x3)9
9C = 84
6
 xr in expansion of
(67) (4).

Its general term =  11Cr . x11–2r . (–3)r

x0 will not exist in expansion of

For term independent of x, r for Ist
expression is 3 and r for second expression for integral r.
is 5 x–1 will occur at r = 6
 Term independent of x = – 36  Coefficient of x–1 = 11C6(–3)6 = 36 . 11C6
(68) (2). Sum of given digits 0, 1, 2, 5, 7, 9 is 24. Also x2 will not exist in expansion of
Let the six digit number be abcdef and to
be divisible by 11. for integral r.
|(a + c + e) – (b + d + f)| is multiple of 11.
Hence only possibility is  Term independent of x in expansion will
a + c + e = 12 = b + d + f be = 36. 11C6
Case-I : {a, c, e} = {9, 2, 1} & {b, d, f}
= {7, 5, 0} (71) (3). Let
So, Number of numbers = 3! × 3! = 36 R – R' =
Case-II : {a,c,e} = {7,5,0}  R – R' = Integer I + f – R' = Integer
and {b,d,f} = {9,2,1}  f – R' is an Integer but –1 < f – R' < 1
So, Number of numbers 2 ×2! × 3! = 24
so f – R' = 0 f = R'
Total = 60
so R. f = R.R' =
(69) (4). = 431 = 262
(72) (1). Total possible words – words do not begin
or terminate with vowel
 Total words = 5! = 120
Words which do not begin and terminate
where t = log10x with vowel = 3 × 3 × 2 × 1 × 2 = 36
 t2 + 3t – 4 = 0  t = 1, – 4 Desired words : 180 – 36 = 84

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 II-Method  words which begin with
vowel
(A/I) = 4! × 2 = 48 ways  say = n(A)
Similarly words terminating with vowel
= 4! × 2 = 48 ways  say = n(B)
Now exclude words which begin as well
as terminates with vowel
2 × 3 × 2 × 1 × 1 = 12 ways  n(A  B)
Desired number of words :-
48 + 48 – 12 = 84 ways
( n(A B) = n(A) + n(B) – n(A  B))
(73) (1). (1 – 2x + 5x2)n
For sum of coefficients put x = 1
 a = (1 – 2 + 5)n = 4n
(1 + x)2n
For sum of coefficients put x = 1;
b = (1 + x)2n = 22n = (22)n = 4n
 a=b
(74) (3). Make cases when all 5 boxes are filled by:
Case 1 : Identical 5 red balls
5C 1 way
5
Case 2 : 4 identical red balls and 1 blue ball
5C = 5 ways
1
Case 3 : 3 blue and 2 red balls i.e. xRxRx
 4 gaps, for 2 blue balls
 4C2 = 6 ways
Case 4:2 red and 3 blue balls i.e. x R x R x
 3 gaps, 3 blue balls
 3C3 = 1 way
 Total number of ways are
1 + 5 + 6 + 1 = 13 ways
Words starting with QE 
next word will be QUEEU  1
and finally QUEUE  1
Rank is 12 + 3 + 1 + 1 = 17th
(77) (4). Let three consecutive natural numbers are
n, n + 1, n + 2,
P(n) = (n)3 + (n + 1)3 + (n + 2)3
P (1) = 13 + 23 + 33 = 36,
which is divisible by 2 and 9
P(2) = (2)3 + (3)3 + (4)3 = 99,
which is divisible by 9 (not by 2).
Hence P(n) is divisible 9  n  N.
(78) (2). For a number to be divisible by 5,5 or 0
should be at units place.
Unit place can be filled by 2 ways
Remaining digits can be filled in
ways.
 Total ways =
But these arrangements also include cases
where 0 is at millions place and 5 at units
place, which are undesirable cases
 ways (undesirable)
Subtract it from total ways.
 Desired ways = 2 × = 110
(79) (3).

(75) (3). Calculate as in (a + b)n



 100 = k

m is not integer so greatest term is T[m]+1 (80) (1). Given sum = coefficient of xr in the
expansion of (1 + x)20 (1 + x)20, which is
T5 = 13C4(2x)9.(5y)4
equal to 40Cr
= 13C4 . 209 . 104 [ x = 10, y = 2]
It is maximum when r = 20
(76) (3). EEQUU (81) 3. Given expression can be rewritten as
Words starting with E 

10
  m + n = 5!5!
p = 5!.5!.2!

 Last term becomes (4x + 1)3 (87) 7.
Hence degree is 3. Single element subsets 7C1 (1 cannot be taken)
(82) 4. Two element subsets 7C2 (2 cannot be taken)
Three element subsets 7C3 (3 cannot be taken)
Four element subsets 7C4 (4 cannot be taken)
 
Five element subsets 7C5 (5 cannot be taken)
 2 (log2 x)2 =8
Six element subsets 7C6 (6 cannot be taken)
 (log2x)2
= 4 log2x = 2 or –2
Seven element subsets 7C7 (7 cannot be taken)
 x = 4 or 1/4
 Total number of non-empty subsets are
7C + 7C + 7C + .......+ 7C = 127
(83) 2. 1 2 3 7
(88) 1. (1– x)2 (1+ x)–2
 (1– 2x + x2) (1– 2x + x2+ ....)
 so term independent of x = 1.

(89) 7.

= 2 [x5 + 5C2.x3 (x3–1) + 5C4 x(x3–1)2 ]

= 2 [x5 + 10 x3 (x3–1) + 5x(x6 – 2 x3 + 1)]
= 10x7 + 20 x6 + 2x5 – 20 x4 – 20 x3 +10 x
 polynomial has order of 7.
K = 225
(90) 0.
(101)202 + (202)101 – (107)99
(84) 4.
(101)202 = (100 + 1)202
= 202C0 100202 + ....... + 202C201 100 + 1
 Unit digit is 1
(202)101 = (200 + 2)101
= 101C0 200101 + 101C100 (200) 2100
r=2 + 2101M (100) + 2101
2101=2 (24)25 =2 [(24) (24) .... (2)4 25 times]
Hence, 10C2 2 = 720 . 2 [6 . 6 ........... 6) 25 times
 Unit digit is 2
2 = 16 ;  = ± 4
 Unit digit in 2 (24)25 is 2.
(85) 0. Also, (107)99 = (100 + 7)99
= 99C0 10099 + .......... 99C98(100)798 + 799
 70x8 = 5670 Now, 799 = 73 (74)24.
 = 73 (74 . 74 ............. 24 times)
(86) 2. m = 4!.5!  Unit digit is 3
n = 4C3 × 5C2 × 2! × 3! × 4! = 4. 4!.5!  Unit digit in (101)202 + (202)101 – (107)99
=1+2–3=0

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