TEST-4 SOLUTION S

STANDARD ANSWER KEY

Q 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A 2 3 3 1 1 1 3 4 2 1 3 3 1 1 3
Q 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A 2 3 1 3 1 2 7 8 3 4 6 5 8 3 4
Q 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A 3 1 1 1 2 3 1 1 4 2 3 4 1 1 2
Q 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A 2 3 3 1 4 5 3 2 4 2 5 5 6 4 3
Q 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A 3 4 3 2 3 4 2 4 4 4 1 2 1 2 3
Q 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A 3 2 4 1 2 3 2 4 3 6 4 7 7 4 3
(1) (2).
CH3 CH3 (11) (3).
C H 3 C –C H =C – C H 3
5 4 3 2 1
CH3
(12) (3). (O2N) – CH – COOH
2, 4,4-Trimethylpent-2-ene
(2) (3). Anti-form is most stable due to minimum EWG increases Acidic strength strong –I
torrisional & steric repulsion. effect
(3) (3). (13) (1). Rate of NAR
Depends on magnitude of positive charge
at carbonyl carbon and steric hinderene

(4) (1). Both the –OH groups are on same side. Rate of NAR
COOH
 + ve charge at carbonyl carbon.
HO H R
C C
HO H R H
(14) (1).
CH3 R R [O]
No POS i.e. why optically active. C O O C 

R H
(5) (1). R – C C – H A ld . R – COOH
(15) (3). n = 2, S.I. = 2n = 22 = 4
(16) (2).
O
2 1
COOH
(6) (1). The upper stratosphere consists of ozone 3 6
(O3), which protect us from harmful
CHO 4 5
ultraviolet (UV) radiations coming from 4-Formyl-2-Oxo cyclohexane carboxylic
sun. acid.
(7) (3). Freons (CFC's) are not common
components of photo chemical smog. or
(8) (4). Acidic strength is inversely proportional to (17) (3).
pKa. give some carbocation.
OH OH OH OH
(18) (1). Alkene having lesser number of ''
hydrogen will show highest heat of
> > > hydrogenation.
NO2 (19) (3). Ketone are very less reactive towards
OM e NO2 NAR, due to steric crowding and +I effect.
O
(9) (2). CH3 – CH = CH2
C
.. Cl C H 2C H 3
 | C H 3 C H2
Cl H2 O
..
C H 3–C H –C H 2
| (20) (1). Chemical method using NaHCO3 solution.
CH – CH – CH2 OH
(10) (1). The common component of photochemical
smog are ozone, nitric oxide, acrolein,
formaldehyde & peroxyacetyl nitrate
(PAN).

2
 O NH2

(21) 2. and are more reactive then (24) 3. b, c, f structures have +H, +M, +M
respectively.
OH (25) 4. Molecular weight of compound = 122 amu
Molecular weight of acetyl derivative
towards electrophilic = 290 amu
substitution reaction.  Increase in mass due to acetylation
(22) 7. = 290 – 122 = 168 amu
(i) Compound which are aromatic
..
(P = 5) Increase in mass due to acetylation of one
..
NH2 – OH group = 42amu (CH3CO – H)
N N  Hence, no. of – OH groups present in
 ..
N O
:N N:
 .N.
original molecule = .
H
(a) (d) (e) (i) (j) (26) 6.
(ii) Compounds which are antiaromatic(Q = 1) Br Br Br Br
Br
(l)
, , ,
(iii) Compounds which are non-aromatic (R=6) Br  
 Br
Br Br Br

(b) (c) (f) , Br

Br

(g) (h) (k) (27) 5.

(iv) Anti-aromatic compounds are unstable at
room temperature that’s why they will
dimerise at room temperature (S = 1)

(v) Number of compounds unstable at room

temp. (T = 1)

Sum of P + Q + R + S + T
 = 5 + 1 + 6 + 1 + 1 = 14 Product = 5
(23) 8. x=3
Possible structures of X are (28) 8.

(a) C2, C3, C4 are asymmetric carbons

n = 3 odd and a = 2n = 23 = 8, the
(b) molecule cannot be divided into two
identical halves.
(c) (29) 3.
CH3
8 9 1
y=5 7 2
So, x + y = 8 6 3
5 10 4

3
 CH3
2

CH3
9

(35) (2). f = 480 =

(30) 4. All carboxylic acids and phenols are
soluble in aqueous NaOH. Four
compounds are soluble in aqueous NaOH.
(31) (3). Displacement from mean position
; 1590 = 1500 + 5v2
5v2 = 90 v2 = 18 m/s
So phase of the particle which is going (36) (3).
5 0 m /s
towards
+ x is 1 = /4 O S
and for other particle 2 = 2 – /4 = 7/4
Phase difference

(32) (1). In second resonance x = 3L1 = 54 but

during summer temp. increases so velocity
of sound 5 0 m /s
increases.
 x > 3L1
S O  
(33) (1). Angular frequency of pendulum

; = 750 Hz

(37) (1). For a simple pendulum

[s = angular frequency of support] Situation 1: When pendulum is in air

 geff = g
Situation 2 : When pendulum is in liquid

(34) (1).  geff =

x = 2


So,

 (38) (1). y = a sin (t + kx)

Kx
 Wave is moving along –ve x-axis with
speed

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 T = 4.41°C
= 25 m/sec.
(39) (4).
µ µ2
(42) (4). Time of fall =
L L
rad iu s = r rad iu s = 2 r In this time number of oscillations are
Let mass per unit length of wires are µ1 and eight.
µ2 respectively.
So time for 1 oscillation
Materials are same, so density  is same.
Frequency = Hz = 56 Hz
 and
(43) 2
(1). amax =    A =  ...(1)
Tension in both are same = T. Vmax =  A =  ...(2)
Let speed of wave in wires are V1 and V2
Dividing,

So fundamental frequencies in both wires are (44) (1).

(45) (2). Vmax = 4V

Frequency at which both resonate is L.C.M 2f y0 = 4f  or
of both frequencies i.e. V / 2L.
Hence no. of loops in wires are 1 and 2 (46) (2). After removal of 700 g mass
respectively.
A A ..(1)
N
N After removal of 500 g mass
N N
A
So, ratio of no. of antinodes is 1 : 2.
T' = 2s
(40) (2). x = a sin t
2 = 4 sin t1 (47) (3).
Mass per unit length =  . A
and
,

where m = mass per unit length

(41) (3). Speed of wave from wave equation (48) (3). The force that is responsible for restoring
the liquid levels in the two arms of the
tube is –A = – (h1 + h2) gA where 
Since speed of wave is the pressure difference and A is the area
of cross section of the tube, h1 and h2
So, T = 277.41 K being the rise and fall of liquid levels in
the two arms in vertical direction
respectively. Note that the change in

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 length of the liquid thread along the tube So, min. frequency at which both agree is
will be same, say x. Using this is force can 300.
furtherer be written as
{– (x sin 1 + x sin 2) gA}. (53) 2.
Writing force as mass times acceleration, Both are at same point and same phase.
we get expression for period and then for
frequency.  ...... (1)
(49) (1).
rest
t0 , h
and ...... (2)
x=0
Solving,
E q u ilib riu m v = 2gh
x 0 = m g/k
= 2 .5m
A (54) 4. = (83.2 + e) = (83.2 + 0.6r)
= (83.2 + 1.8) = 85cm.
 = 3.4 m

T/6 T/6 ; f3 = 700 Hz

6 0 ° A /2 f1 = 300 Hz ; f4 = 1000 Hz ; f2 = 500 Hz
 A = 5m v/
A Ans : 4 overtones
 Time = 2t0 +

(55) 2. = 0.4 m

L= ....... = 10 cm, 30cm, 50cm etc.

(50) (4). When source is at origin, the observer
receives the sound emitted by the source, l+e=  e = 2 cm
when it was at P. Such that P 50t
(56) 5. T sin  = Mg ;  cos  = L
cos  = 2 00t

O
;

(57) 5. The waves can be added using a phasor

(51) 5. Fundamental frequency, diagram.
Resultant amplitude is
and (58) 6. Time to go from P to A and back from A
to P = 0.50
Solving f = 30 Hz A B
P O
And time to go from P to B and back from
Also,
B to P = 1.5s
| f ' – f | = 5 Hz T = Time period = 0.5 + 1.5 = 2.0
(52) 3. The Fundamental frequency of wires are Time from O to P =
and f2 = 60 Hz
Let equation of SHM be

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 Let
Equation of normal is


Slope = 
(59) 4. , where v is velocity
Equation of tangent is
It passes through (4, 4) 2
3
, where x is the number of
1
beats heard.
gives,

Hence point P is (2 cos 120°, sin 120°)

P (–1, 3/2), Q (4, 4)
 x = 0.02 × 200 = 4 PQ =
 Number of beats heard = 4
(60) 3. The arrangement is equivalent to three (63) (3).
springs in parallel.
 Equivalent spring constant = k' = 3k a = 3, b = 4 & e =
If angular frequency of displacement is '
Corresponding focus will be (–ae, 0) i.e.,
then (–5, 0).
(64) (2). x1 + ... + x4 = 44
x5 + ... + x10 = 96

(61) (3). Let equation of ellipse

Variance =
2a – 2b = 10 ...(1)
...(2) Standard deviation = 2

(65) (3).

Parametric normal :
b2 = a2 (1 – e2)
b2 = a2 – a2e2
b2 = a2 – 25 × 3 b = 5 and a = 10 At x = 0 :
 Length of L.R. = (from given equation)
(62) (4). 3x2 + 4y2 = 12

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 Slope of parametric normal Tautology
p q pq p pq
T T T T
T F T T
F T T T
F F F T
(3)
Tautology
(66) (4). Mean (µ) = (p  q)
p q p  q ~ p p ~ q  p  (~ q)
Standard deviation () T T T F F F
T F T F T T
= F T T T F T
F F F T F T
(4)
(70) (4). Given that be = 2 and a = 2
(Here a < b)
New mean a2 = b2 (1 – e2)
b2 = 8
=
Equation of ellipse
= (256) × 2 + 16 – 8 × 16 = 400
(67) (2). The contrapositive of statement (71) (1). Let x be the 6th observation
p  q is ~q  ~p  45 + 54 + 41 + 57 + 43 + x = 48 × 6 = 288
Here, p : you are born in India.  x = 48
q : you are citizen of India.
So, contrapositive of above statement is
Variance =
“If you are not a citizen of India, then you
are not born in India”.
(68) (4). Tangent to the parabola y2 = 16x is
y = mx + , solve it by curve xy = – 4
 Standard deviation =
i.e. mx2 + x+4=0 (72) (2). Focus of parabola y2 = 8x is (2, 0).
A
Condition of common tangent is D = 0
 m3 = 1 m = 1 Q S
O (2,0)
 Equation of common tangent is y = x + 4
(69) (4). Tautology B
p q p  q (p  q)  p Equation of circle with centre (2, 0) is
T T T T (x – 2)2 + y2 = r2
T F F T AB is common chord.
F T F T Q is mid point i.e. (1, 0).
(1) F F F T AQ2 = y2 where y2 = 8 × 1 = 8
Tautology  r2 = AQ2 + QS2 = 8 + 1 = 9
(p  q) so circle is (x – 2)2 + y2 = 9
p q pq ~ pq  (~ p)  q (73) (1). Let any tangent of ellipse is
T T T T T
T F F F T
F T F T T
F F F T T
(2)

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 Let it meets axes at
A= |2at1 – 2at2| [t1t2 = – 1]
A &B
(77) (2). Given series a, a + d, a + 2d, .... , a + 2nd
Let mid point of AB is (h, k) then
2h = , 2k =

Since cos2+ sin2= 1 (xi – )2 = n2d2 + (1 – n)2d2 + ....

 + d2 + 0 + d2 + .... + n2d2

= 2 [n2d2 + (n – 1)2d2 + .... + d2]
 16k2 + 9h2 = 4h2k2 = 2d2 [n2 + (n – 1)2 + ...... + 12]
Hence locus is 16y2 + 9x2 = 4x2y2.
(74) (2). Let S (p, q)  (p  ~q)  ~p
 S (~p, ~q)  (~p  q)  p
S*(~p, ~q)  (~p  q)  p
and ~S(p, q)  ~[(p  ~q)  ~p]
 ~(p  ~q)  p 
 (~p  q)  p
Hence S* (~p, ~q)  ~S (p, q) (78) (4). Normal at ,  are
(75) (3). S  (2, 0), S'  (–2, 0)
A(–2 ,3 )

S'(–2 ,0 ) S(2 ,0 )
where = –  and these passes through
(h, k).
Using reflection property of hyperbola,  ah cos + bk cot = a2 + b2 ......(i)
2
ah sin  + bk tan  = a + b 2 ......(ii)
S'A is incident ray.
Equation of incident ray S'A is x = –2 Multiply (i) by sin & (ii) by cos&
Equation of reflected ray SP is 3x+4y = 6. subtract them, we get
2ae = 4  ae = 2 ....(i) (bk + a2 + b2) (sin – cos) = 0
Point (–2, 3) lies on hyperbola, k = – (a2 + b2)/b
(79) (1). (~p  ~q)  (p  ~q)
 (~p  ~q)  (~q  p) (by commutative law)
On solving it we get  ~p  [~q  (~q  p)] (by Associative law)
a = 4 (reject), a = 1 .....(ii)  ~p  [(~q  ~q)  p] (by Associative law)
 Using (i) & (ii), we get e = 2  ~p  (~q  p) ( p  p = p)
Length of latusrectum = 2a (e2 – 1) = 6  ~p  (p  ~q) (by commutative law)
(76) (3). Since QR is focal chord so vertex of Q is  (~p  p)  ~q (by Associative law)
(at , 2at1) and R is (at , 2at2)  t  ~q  t t is a tautology
Hence (~p  ~q)  (p  ~q) is a tautology.

Area of PQR = (80) (2).

A= |2a2t t2 – 2a2t1t |

9
 x1 + x2 = ;
Variance =
Similarly,
2y2 + 32 – 16y = 4y  y1  y 2  10
= 507.5
2y2 – 20y + 32 = 0 
 y1y 2  16
(81) 3.

 S1 = ( , 0), S2 = (– , 0)
A B (x2 , y 2 )
(x 1 , y 1 )
Equation of tangent is y = mx +

S1 F1 =

S2 F2 = (85) 6. 2b = 5 and 2ae = 13

b2 = a2 (e2 – 1) 
Now (S1F1) (S2F2) = . a = 6 e = 13 / 12
(86) 4.
(82) 2. y 2 =4 ax
B
|xi – |=2+1+3=6
y
(90 – )
A 
Mean deviation = | xi – |= ×6=2 x L C

(83) 4. Let two observations are x1 & x2

Mean =
 1 + 3 + 8 + x1 + x2 = 25
 x1 + x2 = 13 ....(1) (87) 7. Let p (4 (1 + cos )), 3 (1 + sin ) is any
point on the curve its reflection about the line
Variance (2) = x – y – 2 = 0.

 x12 + x22 = 97 .....(2)

By (1) & (2)
(x1 + x2)2 – 2x1x2 = 97 or x1x2 = 36
 x1 : x2 = 4 : 9 h = 5 + 3 sin , k = 2 + 4 cos .
(84) 3. x2 = 4y ;
Solving together we get
16h2 + 9k2 – 160h – 36k + 292 = 0
 k1 = – 160, k2 = 292
 |2k1 + k2| = 28

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(88) 7. (90) 3.
(i). p  ~ (p  ~q)
= ~ p  ~ (p  ~ q)
=~p~pq
= ~ (p  q)  q = ~ p  q
(89) (4). Variance is independent of shifting of
(ii)
origin
p p  (p  (q  p))
 xi : 15 25 35 or –10 0 10 p q qp
(q  p)
pq
p  q  (p  (p  q)
fi : 2 x 2 2 x 2 T T T T T T T
T F T T T T T
 Variance (2) = F T F T T T T
F F T T F T T

(iii) Contrapositive of (p  q) is ~q  ~p
For an integer n, if n is even then (n3 – 1)
 200 + 50x = 200 + 200 is odd.
 x=4

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