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Chemistry - Part Syllabus Test # Contact Number:

16 - Full Class 12 (10 Chapters) [ 9667591930 /


50 MCQ] 8527521718

Section A 5 Which of the following shows the least reactivity


towards nucleophilic substitution reaction?
1 Mark the complex among the following that can
exist as a pair of enantiomers:
1. [Co(H2NCH2CH2NH2)3]3+
2. Trans-[Co(H2NCH2CH2NH2)2Cl2]+
3. [Co(NH3)4Cl2]+ 1. 2.
4. [Co{P(C2H5)3}2ClBr]

2 What amount of urea should be dissolved in 400 g


of water to attain a solution with a
vapor pressure 2% lower than pure water?
1. 32.4 g
2. 27.2 g
3. 21.4 g
4. 24. 5 g 3. 4.

3
1 M solution of KCl has greater osmotic
Assertion: pressure than 1 M solution of glucose at the
same temperature
In solution, KCl dissociates to produce more 6 The major product of the following reaction is :
Reason:
number of particles CH3 CH = CHCO2 CH3 −−−−→
LiAlH4

1.CH 3 CH2 CH2 CO2 CH3

Both (A) and (R) are True and (R) is the correct 2.CH
1. 3 CH2 CH2 CH2 OH

explanation of (A). 3.CH 3 CH = CHCH2 OH

Both (A) and (R) are True but (R) is not the correct 4.CH 3 CH2 CH2 CHO
2.
explanation of (A).
3. (A) is True but (R) is False. 7 Choose the correct statement among the following
4. Both (A) and (R) are false about freons.
1. They are used as a cancer medicine.
4 Consider a zero-order reaction. The rate equation 2. They are chlorofluorocarbon compounds.
3. These are toxic organic compounds.
for the given expression 2X + Y → Z is:
4. These are flammable compounds.
1. Rate = k[X][Y ]
2. Rate = k[X] [Y ]
0 0

3. Rate = k[X] [Y ]
0

4. Rate = k[X][Y ]0

Page: 1
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

8 Match the complexes (given in column I) with their 11


corresponding hybridisation (given in column II) and Isopropyl chloride is more reactive than
mark the appropriate choice. Assertion (A): CH Br in S 2 reactions.
3 N
Column I Column II
SN2 reactions are always accompanied
(A) [Ag(NH3 ) ]
+
(i) 2
d sp
3
, octahedral Reason (R):
2
by inversion of configuration.
(B) [Ni(CN)4 ]
2−
(ii) dsp ,
2
square planar
(C) [Ni(CO)4 ] (iii) sp , linear Both (A) and (R) are True and (R) is the correct
1.
(D) [Fe(CN)6 ]
3−
(iv) sp
3
, tetrahedral explanation of (A).
Both (A) and (R) are True but (R) is not the correct
2.
explanation of (A).
1. (A) → (i), (B) → (ii), (C) → (iii), (D) → (iv)
2. (A) → (iii), (B) → (ii), (C) → (iv), (D) → (i) 3. (A) is True but (R) is False.
3. (A) → (iv), (B) → (iii), (C) → (ii), (D) → (i) 4. (A) is False but (R) is True.
4. (A) → (ii), (B) → (i), (C) → (iii), (D) → (iv)
12 In the electrolysis of dilute sulfuric acid employing
9 Electronic configuration of nickel in K2[NiCl4] is: a Platinum (Pt) electrode, the resulting product obtained
(Atomic number of Ni is 28)is: at the anode would be:
1. e t3 5

2. e t3
g
5 1. Oxygen gas
2g
2. H S gas
3. e t3 4 2

2
3. SO gas 2

4. e t4 4

2 4. Hydrogen gas

10 13 The actinoid that can show oxidation states up to +7


Assertion EDTA forms complex with divalent is:
(A): metals of 3d-series in the ratio of 1:1. 1. Am
Reason 2. Th
EDTA has 4 − COOH groups. 3. U
(R):
4. Np
Both (A) and (R) are True and (R) is the correct
1.
explanation of (A). 14
Both (A) and (R) are True but (R) is not the correct Ln oxides are used as phosphors in
2. Statement
explanation of (A) television screens and similar fluorescing
I:
3. (A) is True but (R) is False. surfaces.
4. Both (A) and (R) are False. Statement TiO is used in the pigment industry and
II: MnO2 is used in dry battery cells.

1. Only Statement I is correct.


2. Only Statement II is correct.
3. Both Statements I and II are correct.
4. Both Statements I and II are false.

15 The oxidation state of nickel in K4[Ni(CN)4] is:


1. -1
2. 0
3. +1
4. +2

Page: 2
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

16 The ratio of the number of electrons gained by 1. Both (A) and (R) are True and (R) is the correct
acidified KMnO4 and acidified K2Cr2O7 respectively in explanation of (A).
the given reaction is: Both (A) and (R) are True but (R) is not the correct
2.
H
+ explanation of (A).
KMnO4 −−→ Mn2+ 3. (A) is True but (R) is False.
+

K2Cr2O7 −−→ Cr3+ 4. (A) is False but (R) is True.


H

1. 5:6
2. 6:5 21 This reaction is a zero-order with respect to N2O.
3. 3:5 2 N O(g) ⟶ 2 N ( g) + O ( g)
2 2 2

4. 5:3 If the half-life for this reaction is 19.0 minutes and the
initial concentration of N2O is 1.39 M, then the value of
17 One mole of propyl acetate on treatment with an rate constant k, is:
excess of LiAlH in dry diethyl ether followed by 1. 0.0158 mol L–1min–1
4
2. 0.0263 mol L–1 min–1
acidification gives:
1. 1 mole acetic acid + 1 mole ethyl alcohol 3. 0.0366 mol L–1 min–1 4. 0.0526 mol L–1 min–1
2. 1 mole ethyl alcohol + 1 mole methyl alcohol
3. 2 moles of ethyl alcohol 22 Which of the following is classified as secondary
4. 1 mole of propyl alcohol + 1 mole of ethyl alcohol benzylic alcohol?

18 Which of the following complex is/are homoleptic:


1. 2.
3+
a. [Co(NH 3
) ]
6
2+
b. [Co(NH ) Cl]
3 5

c. [Ni(CN) ]
2−
4

d. [Ni(NH ) Cl ]
3 4 2

Choose the correct option. 3. 4.


1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
23 Given that a certain electric current generates 0.504
19 Calculate the molarity of the KI solution, provided grams of hydrogen in 2 hours, How many gram of mass
of copper can be liberated by the same current when
its density is 1.202 g mL-1 and it consists of a 20% applied for the same duration in a solution of CuSO ?
4
(mass/mass) concentration.
1. 1.25 M 1. 12.7
2. 1.95 M 2. 16
3. 1.45 M 3. 31.8
4. 2.15 M 4. 63.5

20 24 Mixing 20 g of naphthoic acid (C 11 H8 O2 ) with 50


grams of benzene results in a freezing point depression
Acetic acid does not undergo haloform
Assertion (A): of 2K.(K = 1.72K kg mol ) −1

reaction. f

The Van't Hoff factor (i) is:


Reason (R): Acetic acid has no alpha hydrogens. 1. 0.5
2. 1
3. 2
4. 3

Page: 3
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

25 Match the column I with the column II and mark


the appropriate choice. 1.
Column I Column II
(Process) (Reagent)
(A) Analytical chemistry (i) EDTA
(B) Volumetric estimation (ii) Silver complexes 2.
(C) Catalyst (iii) Cu , Fe , Ni
2+ 3+ 2+

(D) Electroplating (iv) (Ph P) RhCl


3 3

1. (A) → (ii), (B) → (iii), (C) → (i), (D) → (iv)


2. (A) → (i), (B) → (iii), (C) → (ii), (D) → (iv) 3.
3. (A) → (iii), (B) → (i), (C) → (iv), (D) → (ii)
4. (A) → (i), (B) → (iv), (C) → (ii), (D) → (iii)

26 The equilibrium constant value for the given


4.
reaction is:
Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)
(Given: EƟ(cell) = 0.46 V)
1. 3.92 × 1014 28 Identify X in the following sequence of reactions :
(i) CH
2. 3.92 × 1015 X−−−−−−−
3 MgX

→ C5 H12 O −−−→ C5 H10


Cu

3. 3.92 × 1016 (ii) H +


/H2 O 573 K

4. 3.92 × 1017 1. CH3 COCH2 CH3

2. CH3 CH2 CH2 CHO

27 The structure of A and B respectively in the 3. CH3 CH2 CHO

following reaction is: 4. CH3 CH2 CH2 CH2 OH

29 The following reaction is first order,


A(g) ⟶ B(g) + C(g)

Given that the initial pressure of A is 100 torr and the


total pressure of the mixture
is increased by 50 torr in 8 min. Calculate the half-life of
the reaction.
1. 4 min
2. 8 min
3. 16 min
4. 32 min

Page: 4
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

30 Which of the following reactions is correct? 34 IUPAC name of the following compound is:
CH3 − CH − OCH3

1. |

CH3

1. 1-Methoxy-1-methylethane
2. 2. 2-Methoxy-2-methylethane
3. 2-Methoxypropane
4. Isopropylmethyl ether

3. 35 The following reaction is given for reference.

4.

31 Which of the following compounds can yield only


one monochlorinated product upon free radical
chlorination?
1. 2, 2‐Dimethylpropane
2. 2‐Methylpropane 'A' (Major product) is:
3. 2‐Methylbutane
4. n‐Butane

32 The IUPAC name for the following compound is:


1. 2.

1. 4-Hexen-3-one 2. 3-Hexenone
3. 2-Hexene-4-one 4. Hex-3-on-4-ene

33 The correct cell representation for the reaction


given below is: 3. 4.
+ −
H2 + 2AgCl → 2H + 2Ag + 2Cl

1. Pt |H | HCl||AgCl ∣ Ag
2

2. Pt |H | HCl||AgCl ∣ Pt
2

3. Ag|AgCl|HCl |H | Pt
2

4. Pt|AgCl|HC||H ∣ Pt
2
Section B
36 Identify the compound that on Aldol condensation
followed by dehydration gives methyl vinyl ketone
1. Methanal and ethanal
2. Two moles of formaldehyde
3. Methanal and propanone
4. Two moles of ethanal

Page: 5
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

37 The product yield from the reaction of a ketone and 42 The amine that reacts with Hinsberg's reagent to
1° amine is: give an alkali insoluble product is:-
1. Amides
2. Oximes
3. Urea 1.
4. Imines

38 Which one of the following bases is not present in


2.
DNA?
1. Quinoline
2. Adenine
3. Cystosine 3.
4. Thymine

39 The correct statement(s) among the following is or


are:
2+ 3+ 4.
I: Cr and Mn have the same electronic
configuration.
2+ 3+
II: Cr is a reducing agent, while Mn is an
oxidising agent.
2+ 3+
III: Cr is an oxidising agent, while Mn is a 43 Which of the following is more basic than aniline?
reducing agent. 1. Diphenylamine
IV: Both Cr and Mn are oxidising agents. 2. Triphenylamine
3. p-nitroaniline
1. I,III,IV 4. Benzylamine
2. I,II
3. I,II,IV 44
4. I,IV Assertion
Boron is the hardest element in group-13.
(A):
40 Which of the following hormones contains iodine? High lattice enthalpy is due to the strong
1. Insulin Reason (R):
crystalline lattice.
2. Testosterone
3. Adrenaline
Both (A) and (R) are correct and (R) is the correct
4. Thyroxine 1.
explanation of the (A)
41 α-helix structure of proteins is stabilized by : Both (A) and (R) are correct but (R) is not the correct
2.
explanation of the (A)
1. H-bonds formed between the −SH and C=O group.
3. (A) is correct but (R) is incorrect
2. H-bonds formed between the −NH and C=O group.
4. Both (A) and (R) are correct
Ionic bonds formed between the −SH and C=O
3.
group.
45 For an ideal solution, the correct option is:
Ionic bonds formed between the −NH and C=O
4. 1. Δmix G = 0 at constant T and P
group.
2. Δmix S = 0 at constant T and P
3. Δmix V ≠ 0 at constant T and P

4. Δmix H = 0 at constant T and P

Page: 6
Chemistry - Part Syllabus Test # Contact Number:
16 - Full Class 12 (10 Chapters) [ 9667591930 /
50 MCQ] 8527521718

46 49 An organic compound X on treatment with


acidified K Cr O gives compound Y which reacts
2 2 7

with I and NaOH to form CHI . The compound X can


2 3

be:
1. CH OH
3

2. CH CHO
3

3. CH COCH
3 3

4. CH CH(OH)CH
3 3

50 Fructose can cyclize into a five-membered ring


The final product P in the above-mentioned reaction is: known as a furanose. The hydroxyl group attached to
that carbon of fructose which behaves as nucleophilic
during the formation of a furan is:

1. 2.

3. 4.
1. Carbon 1
2. Carbon 3
3. Carbon 5
4. Carbon 6

47 Fill OMR Sheet*


Statement
SO2 is a sp3 hybridised molecule. *If above link doesn't work, please go to test link from
1:
where you got the pdf and fill OMR from there. After
Statement Two S−O bonds in SO2 are not equal in filling the OMR, you would get answers and explanations
2: length. for the questions in the test.
1. Statement 1 is True, Statement 2 is False.
2. Statement 1 is False, Statement 2 is True.
3. Both Statements are True.
4. Both Statements are False.
CLICK HERE to get
48
Assertion Formic acid can be oxidized to carbonic FREE ACCESS for 2
(A): acid.
Formic acid does not give brisk days of ANY
Reason (R): effervescence with NaHCO .
3
1. Both (A) and (R) are True and (R) is the correct
NEETprep course
explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct
explanation of (A).
3. (A) is a True but (R) is False.
4. Both (A) and (R) are False.

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