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FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

Held On Wednesday 01st February, 2023
TIME : 03:00 PM to 06:00 PM

SECTION-A 34. The graph which represents the following reaction

31. In a reaction, is :
OH OH OCOCH 3
OH 
COOCH 3 COOH COOH (C6 H 5 )3 C  Cl 
Pyridine (C 6 H 5 )3 C  OH
‘Y’ ‘X’

rate rate
reagents ‘X’ and ‘Y’ respectively are :
(1) (2)
(1) (CH3CO)2O/H+ and CH3OH/H+, 

(2) (CH3CO)2O/H+ and (CH3CO)2O/H+ [(C6 H5) 3C–Cl] –

[OH ]

(3) CH3OH/H+,  and CH3OH/H+, 

rate rate
+ +
(4) CH3OH/H  and (CH3CO)2O/H (3) (4)
Official Ans. by NTA (1)
[(C6 H5) 3C–Cl] [Pyridine]
Allen Ans. (1)
Official Ans. by NTA (3)
32. The correct order of bond enthalpy (kJ mol–1) is :
Allen Ans. (3)
(1) Si – Si > C – C > Sn – Sn > Ge – Ge
35. ‘X’ is : HF
(2) Si – Si > C – C > Ge – Ge > Sn – Sn + X
 Major product
(3) C – C > Si – Si > Sn – Sn > Ge – Ge

(4) C – C > Si – Si > Ge – Ge > Sn – Sn

Official Ans. by NTA (4) (1) (2)

Allen Ans. (4)

33. All structures given below are of vitamin C. Most

stable of them is :
OH (3) (4)
(1) HO O
O
(2)
H
OH OH
Official Ans. by NTA (1)
Allen Ans. (1)
(3) (4) 36. The complex cation which has two isomers is :
(1) [Co(H2O)6]3+ (2) [Co(NH3)5Cl]2+
(3) [Co(NH3)5NO2]2+ (4) [Co(NH3)5Cl]+
Official Ans. by NTA (1) Official Ans. by NTA (3)
Allen Ans. (1) Allen Ans. (3)

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37. Given below are two statements : 40. Given below are two statements : one is labelled
Statement I : Sulphanilic acid gives esterification
as Assertion (A) and the other is labelled as
test for carboxyl group.
Reason (R).
Statement II : Sulphanilic acid gives red colour in
Lassigne’s test for extra element detection. Assertion (A) : -halocarboxylic acid on reaction
In the light of the above statements, choose the
with dil. NH3 gives good yield of -amino
most appropriate answer from the options given
below : carboxylic acid whereas the yield of amines is very
(1) Statement I is correct but Statement II is low when prepared from alkyl halides.
incorrect.
Reason (R) : Amino acids exist in zwitter ion form
(2) Both Statement I and Statement II are incorrect.
(3) Both Statement I and Statement II are correct. in aqueous medium.

(4) Statement I is incorrect but Statement II is In the light of the above statements, choose the
correct.
correct answer from the options given below :
Official Ans. by NTA (4)
Allen Ans. (4) (1) Both (A) and (R) are correct and (R) is the

38. Given below are two statements : one is labelled correct explanation of (A).
as Assertion (A) and the other is labelled as
(2) Both (A) and (R) are correct but (R) is not the
Reason (R).
Assertion (A) : Gypsum is used for making correct explanation of (A).

fireproof wall boards. (3) (A) is correct but (R) is not correct.
Reason (R) : Gypsum is unstable at high
(4) (A) is not correct but (R) is correct.
temperatures.
In the light of the above statements, choose the Official Ans. by NTA (1)

correct answer from the options given below : Allen Ans. (2)
(1) Both (A) and (R) are correct but (R) is not the
41. The industrial activity held least responsible for
correct explanation of (A).
(2) (A) is correct but (R) is not correct. global warming is :

(3) (A) is not correct but (R) is correct. (1) manufacturing of cement
(4) Both (A) and (R) are correct and (R) is the
(2) steel manufacturing
correct explanation of (A).
Official Ans. by NTA (1) (3) Electricity generation in thermal power plants.

Allen Ans. (1) (4) Industrial production of urea

39. Which element is not present in Nessler’s reagent ?
Official Ans. by NTA (4)
(1) Mercury (2) Potassium
(3) Iodine (4) Oxygen Allen Ans. (4)

Official Ans. by NTA (4)

Allen Ans. (4)

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42. The structures of major products A, B and C in the In the light of the above statements, choose the
following reaction are sequence. correct answer from the options given below :
O (1) Both (A) and (R) are correct and (R) is the
NaHSO3, dil. HCl LiAlH4
H [A] [B] correct explanation of (A).
NaCN, H2O
(2) (A) is correct but (R) is not correct.
HCl/H2O
[C] (3) (1) is not correct but (R) is correct.

OH CN (4) Both (A) and (R) are correct but (R) is not the
(1) A = ,
H correct explanation of (A).
HO CHO Official Ans. by NTA (1)
B= Allen Ans. (1)
H
, 44. The starting material for convenient preparation of
HO CO2H
C= deuterated hydrogen peroxide (D2O2) in laboratory
H is:
OSO3Na (1) K2S2O8 (2) 2-ethylanthraquinol
(2) A = , (3) BaO2 (4) BaO
H
Official Ans. by NTA (1)
OH
Allen Ans. (1)
B=
H 45. In figure, a straight line is given for Freundrich
,
Cl 1
Adsorption (y = 3x + 2.505). The value of and
C= n
H log K are respectively.
HO SO3H Y
(3) A = , x
log m
H I
n
B= OH
,
log K
HO SO2Cl
C=
H log P X
HO CN (1) 0.3 and log 2.505 (2) 0.3 and 0.7033
(4) A = ,
(3) 3 and 2.505 (4) 3 and 0.7033
H
Official Ans. by NTA (3)
HO NH2
B= Allen Ans. (3)
H 46. Given below are two statements : one is labelled as
,
HO CO2H Assertion (A) and the other is labelled as Reason
C=
H (R).
Official Ans. by NTA (4) Assertion (A) : An aqueous solution of KOH
Allen Ans. (4) when for volumetric analysis, its concentration
43. Given below are two statements : one is labelled
should be checked before the use.
as Assertion (A) and the other is labelled as
Reason (R) : On aging, KOH solution absorbs
Reason (R).
atmospheric CO2.
Assertion (A) : Cu2+ in water is more stable than
Cu+. In the light of the above statements, choose the
Reason (R) : Enthalpy of hydration for Cu2+ is correct answer from the options given below.
much less than that of Cu+.

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(1) (A) is not correct but (R) is correct 50. O–O bond length in H2O2 is X than the O–O bond
(2) Both (A) and (R) are correct but (R) is not the length in F2O2. The O – H bond length in H2O2 is
correct explanation of (A) Y than that of the O–F bond in F2O2.
Choose the correct option for X and Y from the
(3) Both (A) and (R) are correct and (R) is the
given below.
correct explanation of (A)
(1) X – shorter, Y – shorter
(4) (A) is correct but (R) is not correct
(2) X – shorter, Y – longer
Official Ans. by NTA (3) (3) X – longer, Y – longer
Allen Ans. (3) (4) X – longer, Y - shorter
47. Which one of the following sets of ions represents Official Ans. by NTA (4)
a collection of isoelectronic species? Allen Ans. (4)
(Given : Atomic Number : F :9 , Cl : 17, Na = 11,
Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21) SECTION-B
(1) (Li+ , Na+ , Mg2+ , Ca2+ 51. 0.3 g of ethane undergoes combustion at 27°C in a
(2) (Ba2+ , Sr2+ , K+ , Ca2+ bomb calorimeter. The temperature of calorimeter
system (including the water) is found to rise by
(3) (N3– , O2– , F– , S2–
0.5°C. The heat evolved during combustion of
(4) (K+ , Cl– , Ca2+ , Sc3+
ethane at constant pressure is ________kJ mol–1.
Official Ans. by NTA (4)
(Nearest integer)
Allen Ans. (4)
[Given : The heat capacity of the calorimeter
48. The effect of addition of helium gas to the
system is 20 kJ K–1, R = 8.3 JK–1 mol–1.
following reaction in equilibrium state, is :
Assume ideal gas behaviour.
PCI5 (g) PCl3 (g)  Cl2 (g)
Atomic mass of C and H are 12 and 1 g mol–1
(1) the equilibrium will shift in the forward respectively]
direction and more of Cl2 and PCl3 gases will be Official Ans. by NTA (1006)
produced.
Allen Ans. (1006)
(2) the equilibrium will go backward due to
52. Among following compounds, the number of those
suppression of dissociation of PCl5. present in copper matte is_________.
(3) helium will deactivate PCl5 and reaction will
A. CuCO3
stop.
B. Cu2S
(4) addition of helium will not affect the
C. Cu2O
equilibrium.
D. FeO
Official Ans. by NTA (1 & 4)
Official Ans. by NTA (1)
Allen Ans. (1 & 4)
Allen Ans. (1)
49. For electron gain enthalpies of the elements
53. Among the following, the number of tranquilizer/s
denoted as egH, the incorrect option is :
is/are_________.
(1) egH (Cl) <egH (F)
A. Chloroliazepoxide
(2) egH (Se) <egH (S)
B. Veronal
(3) egH (I) <egH (At)
C. Valium
(4) egH (Te) <egH (Po)
D. Salvarsan
Official Ans. by NTA (2)
Official Ans. by NTA (3)
Allen Ans. (2)
Allen Ans. (3)

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54. A B 58. Testosterone, which is a steroidal hormone, has the

The above reaction is of zero order. Half life of following structure.
this reaction is 50 min. The time taken for the OH
concentration of A to reduce to one-fourth of its CH3
initial value is________min.
CH3
(Nearest integer)
Official Ans. by NTA (75)
O Testosterone
Allen Ans. (75)
The total number of asymmetric carbon atom/s in
55. 20% of acetic acid is dissociated when its 5 g is
added to 500 mL of water. The depression in testosterone is ______
freezing point of such water is _______ × 10–3 °C. Official Ans. by NTA (6)
Atomic mass of C, H and O are 12, 1 and 16 a.m.u.
Allen Ans. (6)
respectively.
[Given : Molal depression constant and density of 59. The spin only magnetic moment of [Mn(H2O)6]2+

water are 1.86 K kg mol–1 and 1 g cm–3 complexes is _______B.M. (Nearest integer)
respectively. (Given : Atomic no. of Mn is 25)
Official Ans. by NTA (372)
Official Ans. by NTA (6)
Allen Ans. (372)
Allen Ans. (6)
56. The molality of a 10% (v/v) solution of di-bromine
solution in CCl4 (carbon tetrachloride) is 'x'. x = 60. A metal M crystallizes into two lattices :- face
________ × 10–2 M. (Nearest integer) centred cubic (fcc) and body centred cubic (bcc)
[Given : molar mass of Br2 = 160 g mol–1 with unit cell edge length of 2.0 and 2.5 Å
atomic mass of C = 12 g mol–1 respectively. The ratio of densities of lattices fcc to
atomic mass of Cl = 35.5 g mol–1 bcc for the metal M is _______.
density of dibromine = 3.2 g cm–3 (Nearest integer)
–3
density of CCl4 = 1.6 g cm ]
Official Ans. by NTA (4)
Official Ans. by NTA (139)
Allen Ans. (4)
Allen Ans. (139)
57. 1×10–5 M AgNO3 is added to 1 L of saturated
solution of AgBr. The conductivity of this solution
at 298 K is ______×10–8 S m–1.
[Given : Ksp(AgBr) = 4.9×10–13 at 298K

0Ag  6  103 Sm 2 mol –1

 0Br   8  103 Sm2 mol –1

 0NO  7  103 Sm2 mol –1 ]

3

Official Ans. by NTA (14)

Allen Ans. (Bonus)

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