JEE (MAIN + ADVANCED) 2024

ENTHUSE COURSE
PHASE :
ORGANIC CHEMISTRY QU IZ #0 1 TIME : 30 Min.
SECTION-I(i) : One or More than one
This section contains 12 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)

1. Which of the following can’t act as electrophile ?

+ +
(A) NO2 (B) NO (C) K (D) Cl
2. What is the donor atom in hydroxyl amine during the reaction with carbonyl compound ?
(A) N (B) O (C) C (D) Halogen
4 3 2
3. H2N– NH NO2 2,4-DNP (Brady’s reagent)

NO2
1

Which is the donor atom in 2,4-DNP ?

(A) N 1 (B) N2 (C) N3 (D) N4
4. Which of the following is example of source of hydride ion & acts as elelctrophilic central atom :
(A) B2H 6 (B) LiAlH4
(C) NaBH4 (D) DIBALH (Diisobutylhidride)

5. C=O + NaHSO3

This reaction is example of

(A) Nucleophilic substitution (B) Nucleophilic addition
(C) Electrophilic substitution (D) Electrophilic addition
6. Which of the following are the examples of ambidentate nucleophile ?
(A) CN – (B) NH2– (C) SO42– (D) NO2–
7. What is the correct order of e– density in following compounds ?
CH3 CMe3 CHMe2 CH2CH3
(A) > > >

CMe3 CHMe2 CH2Me CH3

(B) > > >

CH3 CH3
CH3 CH2CH3 CH C CH3
CH3
(C) > > > CH3

CMe3 CH2Me CHMe2 CH3

(D) > > >

1/2 ORGANIC CHEM. / QUIZ # 01

 JEE (Main + Advanced) 2024
ENTHUSIAST COURSE
PHASE -

8. What is correct order of reactivity towards methyl magnesium halide ?

(A) HCHO > CH3CH=O > CH3–COCH3 > PhCOCH3

(B) CH3COCl > (CH3CO)2O > CH3– C –OR > CH3– C –NR2
O O
(C) CH3COCH3 > PhCOCH3 > PhCOPh
CH=O CH=O CH=O CH=O

(D) > > >

NO2 Br CH 3

9. What is the correct order of nucleophilicity of following compounds ?

– – – –
(A) HOO > OH (B) OH > t-BuO
NH2
–
(C) NH2 > LDA (Lithiumdiisopropylamide) (D) RNH2 >

(N donor atom)

10. Which of the following are example of electrophile ?

(A) PCl3 (B) PCl5 (C) SOCl2 (D) NOCl

11. Which of the following are example of nucleophile ?

CH3
: :

(A) EtOH (B) O (C) R2NH (D)

12. In which reaction Ist compound acts as elelctrophile ?

(A) CH2=CH2 + Br2 / CCl4 CH2—CH2 (B) COCl2 + NH3 CO(NH2)2

Br Br

(C) EtOH + CH3–C–OH CH3CO2Et + H2O (D) SO2Cl2 + H2O H2SO4

O

2 /2 ORGANIC CHEM. / QUIZ # 01