JEE (Main + Advanced) 2024

JEE (Main + Advanced) 2024

ENTHUSIAST COURSE
ENTHUSIAST COURSE
RACE # 16 PHYSICAL CHEMISTRY
M.M. : 32 TIME : 35 Min.
Single correct :
1. In the presence of a catalyst, the heat evolved or absorbed during the reaction ___________. [3]
(A) increases. (B) decreases.
(C) remains unchanged. (D) may increase or decrease.
2. For a complex reaction ______________. [3]
(A) order of overall reaction is same as molecularity of the slowest step (provided slowest step having no
reaction intermediate)
(B) order of overall reaction is less than the molecularity of the slowest step.
(C) order of overall reaction is greater than molecularity of the slowest step.
(D) molecularity of the slowest step is never zero or non interger.
3. Mark the incorrect statements. [3]

®
(A) Catalyst provides an alternative pathway to reaction mechanism.
(B) Catalyst raises the activation energy.
(C) Catalyst lowers the activation energy.
(D) Catalyst alters enthalpy change of the reaction.
4. A gas is taken isochorically from state A to state C as shown in the graph. Choose the correct statement-

B C
P
A
T
(A)Moles of gas first remains constant and then increases [3]
(B) Moles of gas first increases and then remains constant.
(C) Moles of gas first remains constant and then decreases
(D) Moles of gas first decreases and then remains constant.
5. A closed vessel contains helium and ozone at a pressure of P atm. The ratio of He and oxygen atoms
is 1 : 1. If helium is removed from the vessel, the pressure of the system will reduce to:

(A) 0.5 P atm (B) 0.75 P atm (C) 0.25 P atm (D) 0.33 P atm [3]
6. Consider Figure and mark the correct option. [3]
Activated complex

E1
Energy

Products
E2
Reactants
(A) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(B) Activation energy of forward reaction is E1+E2 and product is more stable than reactant.
(C) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
than product.
(D) Activation energy of backward reaction is E1 and product is more stable than reactant.

E-26 /37 Physical / R # 01-20 (Booklet)

 JEE (Main + Advanced) 2024

ENTHUSIAST COURSE

7. For a gas reaction A P at T (K) the rate is given by [3]

rate = k1 pA2 atm/hr
rate = k2CA2 mol/litre/hr
the relation between k1 and k2 is
(A) k2 = k1 (B) k2 = k1 RT (C) k2 = k1/RT (D) k2 = k1(RT)2
8. For the reactions (i) A 
KI
 P. [3]

& (ii) B 

K II Q, following observation is made.

1M
Concentration

1M
Concentration

®
0.5
[A] 0.5
0.25
[B]
0 30 60
Time (min) 60 Time (min)

KI
Calculate K , where K1 and KII are rate constants for the respective reaction.
II

(A) 2.772 (B) 1 (C) 0.36 (D) None of these

Multiple correct :
9. Consider the Arrhenius equation given below and mark the correct option. k = A e–Ea / RT [3]
(A) Rate constant increases exponentially with increasing activation energy and decreasing temperature.
(B) Rate constant decreases exponentially with increasing activation energy and decreasing temperature.
(C) Rate constant increases exponentially with decreasing activation energy and decreasing temperature.
(D) Rate constant increases exponentially with decreasing activation energy and increasing temperature.
10. tx/y= time in which x/y fraction of reactant converts into product. [5]
ColumnI Column II
(A) t5/9 (P) Equal to 54 sec. if t1/3 is 18 sec. in case of first order reaction.
(B) t19/27 (Q) Equal to 32 sec. if t1/4 is 16 sec. in case of first order reaction.
(C) t7/8 (R) Equal to 56 sec. if t1/3 is 4 sec. in case of second order reaction.
(D) t7/16 (S) Equal to 30 sec. if t1/3 is 18 sec. in case of zero order reaction.
(T) Equal to 28 sec. if t1/2 is 16 sec. in case of zero order reaction.

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