Question number 24 to 26 carry three marks each.

Student ID 2020-21
24. (a) The reaction, 2A + B + C  D + E is found to be first order in A, (3) CLASS 12
second order in B and zero order in C. S.S. Tutorials
(i) Give the differential rate law for above reaction. UNIT TEST: 03 – A SET – B
(ii) What is the effect on the when concentratiob of A, B and C, each CHEMISTRY – CH 402
is increased two times?
CH 3: Electrochemistry
(b) Identify the reaction order, if the unit of rate cosntant is s -1.
25. For the reaction, 2A + B + C  Product, (3) Max. Marks: 40………………………………..Time: 1.20 hours
Excess
(i) What is rate law for the reaction? Question number 1 to 20 carry one mark each including multiple choice questions,
(ii) What are units of rate and rate constant of reaction? fill in the blanks, true-false etc.
(iii) On increasing the concentration of A two times, of B three times
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and C four times, what is the effect on the rate of reaction?
26. The rate law equation for the reaction A  B is found to be: (3) 1. (1)
−d [ A ] (a) 10-5 (b) 10-3 (c) 10-2 (d) 10
=k [ A ].
dt 2. (1)
If [A]0 were the initial concnetration of A, derive the expressions for
1+ K 1 [ A ]3
For a reaction rate law is rate =
(i) rate constant in the integrated form. K 2[ A ]
(ii) half-life period of the reaction. Here A is reactant and value of K1 and K2 > 1
Select the correct statement
(a) When concentration of A is very large as compared to 1, unit of rate
Question number 27 carry five marks. constant is Ms-1
(b) When concentration of A is very large as compared to 1, unit of rate
27. What is half life? Derive an expression for the half life of a (5) constant is s-1
(a) (c) When concentration of A is very large as compared to 1, unit of rate
first order reaction. ( ½ + 1 + 3 ½) constant is M-1s-1
(d) When concentration of A is very large as compared to 1, unit of rate
The following rate data were obtained for the thermal constant is M
(b)
decomposition of N2O5 (g) 3. Consider the reaction (1)
KClO3 + 6 FeSO4 + 3 H2SO4  KCl + 3 Fe2(SO4)3 + 3 H2O
2 N2O5 (g)  2 N2O4 (g) + O2 (g) If concentration of FeSO4 decreases from 0.9 to 0.3 M in 10 second, the rate
of formation of KCl is in the above reaction would be (in M sec -1).
Time (sec) 0 50
(a) 0.06 (b) 0.6 (c) 0.01 (d) 0.1
Total pressure (atm) 0.2 0.25 4. P  Q; K = 693 x 10-3 s-1 (1)
The time in which concentration of P change from 2 M to 0.25 M is [Given
Calculate the reaction rate when the total pressure is 0.28 atm. loge 2 = 0.693]
(a) 1 second (b) 2 second (c) 3 second (d) 4 second
5. Half life of a chemical reaction at a particular concentration is 50 minutes. (1)
When the concentration of the reactant is doubled, the half life becomes
 100 minutes, then the order of reaction is : kinetically of first order.
(a) 0 (b) 1st (c) 2nd (d) 3rd
14. Radioactive disintegration is which type of reaction? Give reason. (1)
6. Given (1)
15. The rate of decomposition of ammonia is found to depend upon the (1)
A (g)  B (g) (Zero order reaction with rate constant K 1)
C (g)  D (g) (Zero order reaction with rate constant K 2) −d [ NH 3 ] k1
=
If both reactions start at the same time and initially concnetration of A is 10 concentration of NH3 according to the equation dt 1
times of C. If half life of both reactions is same then which statement is
+k
NH 3 2
correct?
What will be the order of reaction when concentration of NH3 is very
(a) K2 = 10 K1 (b) K1 = 10 K2
low?
(c) K1 = K2 (d) Completion time of both reactions is different.
16. For (1)
7. For a reaction A + B  C + D, the rate = k [A]-1/2 [B]3/2. On doubling the (1)
concentration of A and B, the rate will be
(a) 4 times (b) 3 times (c) 2 times (d) same
What is the order of reaction? Write down unit of rate constant?
8. (1)
17. How does the value of rate constant vary with concentration of reactant? (1)
represents the conversion of 18. The rate law for the following reaction: (1)
reactants into products in 5 minutes time in a first order reaction is given
above. [Concentration of reactant and product are represented in
mole/L]. What is time taken to convert 99.9 % of reactants to products?
(a) 15 minute (b) 25 minute (c) 50 minute (d) 75 minute
9. A gas phase reaction R  A + B + C + D is of first order. The initial pressure (1)
was x0 where pressure after 10 minutes was y. The correct expression for
rate constant k is 19. What is meant by rate controlling step in a reaction? (1)
20. How is order different from molecularity? (1)

Question number 21 to 23 carry two marks each.

21. In a first order reaction, X  Y; the concentration of ‘X’ changes from (2)
10. For a reaction 2 N2O5  4 NO2 + O2, the rate and rate constant are 1.02 x (1) 0.1 M to 0.025 M in 40 minutes. What will be the rate of reaction
10-4 mol L-1s-1 and 3.4 x 10-5 s-1 respectively. The concentration of N 2O5 at (mol/L/min) when concentration of ‘X’ is 0.01 M?
this time will be
22. For a reaction N2O5  2 NO2 + ½ O2 it is given that (2)
(a) 1.732 mol/L (b) 3 mol/L (c) 1.02 x 10-4 mol/L (d) 3.2 x 105 mol/L
11. The reactant A + 2B + C  2 D + E is found to be 1, 2 and zero order with (1)
respect to A, B and C respectively. What will be the final rate, if What is the relation between k1, k2 and k3?
concentration of each reactant is doubled? 23. Write the rate law expression and find the rate constant for (2)
12. Define specific reaction rate. (1)
13. State any one condition under which a bimolecular reaction may be (1)