JEE | NEET | Class 8 - 10 Download eSaral APP

FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

Held On Tuesday 31th January, 2023
TIME : 09:00 AM to 12:00 PM

SECTION-A Sol. CH3 CH2 CHO +HCHO 

OH




31. Nd 2  _______
(1) 4f26s2 (2) 4f4
(3) 4f3 (4) 4f46s2
Official Ans. by NTA (2)
Allen Ans. (2)
Sol Nd(60) = [Xe] 4f4 5d0 6s2
Nd2+ = [Xe] 4f4 5d0 5s0
32. The methods NOT involved in concentration of ore Carboxylic acid will give CO2 gas, with NaHCO3
are solution
(A) Liquation 34. The correct order of basicity of oxides of vanadium
(B) Leaching is
(C) Electrolysis (1) V2O3 > V2O4 > V2O5
(D) Hydraulic washing (2) V2O3 > V2O5 > V2O4
(E) Froth floatation (3) V2O5 > V2O4 > V2O3
Choose the correct answer from the options given (4) V2O4 > V2O3 > V2O5
below : Official Ans. by NTA (1)
(1) B, D and C only Allen Ans. (1)
(2) C, D and E only Sol. With increase in % of oxygen acidic nature of oxide
(3) A and C only of an element increase and basic nature decreases
(4) B, D and E only 35. When Cu2+ ion is treated with KI, a white
Official Ans. by NTA (3) precipitate, X appears in solution. The solution is
Allen Ans. (3) titrated with sodium thiosulphate, the compound Y
Sol. Methods involved in concentration of one are is formed. X and Y respectively are
(i) Hydraulic Washing (1) X = Cu2I2 Y=Na2S4O5
(ii) Froth Flotation (2) X=Cu2I2 Y=Na2S4O6
(iii) Magnetic Separation (3) X=CuI2 Y=Na2S4O3
(iv) Leaching (4) X=CuI2 Y=Na2S4O6
Official Ans. by NTA (2)
33. Consider the following reaction
Allen Ans. (2)
Propanal  Methanal  
(i)dil.NaOH
(ii) 
Product B Sol.
(iii)NaCN (C5 H8O3 )

(iv)H3O  CuI 2  2K 
Cu 2+  2KI 
Unstable
The correct statement for product B is. It is
I is strong R.A it reduces Cu2+ to Cu+
–

(1) optically active and adds one mole of bromine

2CuI2 
 Cu 2 I2   I2
(2) racemic mixture and is neutral (White) ' X '
(3) racemic mixture and gives a gas with saturated
NaHCO3 solution  K  I3– (Brown solution)
KI  I2 
(4) optically active alcohol and is neutrall I3 I2  I –
Official Ans. by NTA (3) KI3  Na 2S2 O3  KI  Na 2S4 O6
Allen Ans. (3) (Y)

JEE Exam Solution www.esaral.com 1

 JEE | NEET | Class 8 - 10 Download eSaral APP

38. Identify X, Y and Z in the following reaction.

(Equation not balanced)
36. 
Cl O NO2  X 
H2 O
Y  Z
O
(1) X=ClONO2, Y=HOCl, Z = NO2
(2) X=ClNO2, Y=HCl, Z=HNO3
C (3) X=ClONO2, Y=HOCl, Z=HNO3
(4) X=ClNO3, Y=Cl2, Z=NO2
(1) Official Ans. by NTA (3)
Allen Ans. (3)
 H2O
O Sol. ClO NO 2 
 ClO NO 2   HOCl HNO3
(X) (Y) (Z)
C 39. The correct order of melting point of
CH 2NH 2
(2) dichlorobenzenes is
Cl Cl Cl
Cl
O
(1) > >
C Cl
NHCH2 OH
Cl
(3) Cl Cl Cl
Cl
O (2) > >
C Cl
NH CH 3
Cl
(4) Cl Cl Cl
Cl
(3)
Official Ans. by NTA (4) > >
Allen Ans. (4) Cl
NH 2 NHCOCH 3
Sol. NO2
Cl
Cl Cl Cl
H2/Pd (CH3CO)2O
C2H5OH Pyridine
Cl
(4) > >
37. Cobalt chloride when dissolved in water forms
pink colored complex X which has octahedral Cl
geometry. This solution on treating with cone HCl Cl
forms deep blue complex, Y which has a Z Official Ans. by NTA (4)
geometry. X, Y and Z, respectively, are Allen Ans. (4)
Sol.
(1) X=[Co(H2O)6]2+, Y=[CoCl4]2-, Z=Tetrahedral Cl Cl Cl
(2) X=[Co(H2O6)]2+, Y=[CoCl6]3-, Z=Octahedral Cl
(3) X=[Co(H2O)6]3+, Y=[CoCl6]3-, Z=Octahedral
(4)X=[Co(H2O)4Cl2]+, Y=[CoCl4]2-, Z=Tetrahedral Cl
Cl
Official Ans. by NTA (1)
b.p / K 453 446 448
Allen Ans. (1)
m.p / K 256 249 323
Sol.
Cl
 Co(H 2 O) 6  Cl 2
CoCl2  6H 2 O 
Pink(X) More Symmetrical & better
Crystal fitting
octahedral Cl
  HCl(conc.) M.P a Packing efficiency
[CoCl 4 ]2  Cl
Cl
(Y)Blue solution
max
(Z)Tetrahedral

JEE Exam Solution www.esaral.com 2

 JEE | NEET | Class 8 - 10 Download eSaral APP

40. A protein ‘X’ with molecular weight of 70,000 u, 42. Match items of column I and II
on hydrolysis gives amino acids. One of these
amino acid is Column I (Mixture of compounds) Column II (Separation Technique)

(1) NH2  CH2  CH  CH2 CH2 COOH A. H2O/CH2Cl2 Crystallization

|
CH3 O OH

B. ii. Differential solvent extraction

CH3
| NO2
(2) CH3  CH  CH 2  CH  COOH
| C. Kerosene/Naphthalene iii. Column chromatography
NH 2
D. C6 H12O6 /NaCl iv. Fractional Distillation
CH3 Correct match is :
|
(3) CH  CH  CH  CH COOH (1) A-(iii), B-(iv), C-(ii), D-(i)
3 2
|
NH2 (2) A-(i), B-(iii), C-(ii), D-(iv)

(3) A-(ii), B-(iii), C-(iv), D-(i)

CH3
| (4) A-(ii), B-(iv), C-(i), D-(iii)
(4) CH  C  CH  CH COOH
3 2 2
| Official Ans. by NTA (3)
NH2
Official Ans. by NTA (2) Allen Ans. (3)
Allen Ans. (2) Sol. A. H2O/CH2Cl2  ii, CH2Cl2 > H2O (density) so they
Sol. Only in option (2) -Amino acid is given all the
other options are not -Amino acids. can be separated by differential solvent extraction.
41. Which transition in the hydrogen spectrum would B.
have the same wavelength as the Balmer type
O OH
transition from n=4 to n = 2 of He+ spectrum
(1) n = 2 to n = 1 iii. column
(2) n = 1 to n = 3 chromatography
(3) n = 1 to n = 2 NO2
(4) n = 3 to n = 4
Official Ans. by NTA (1) OH
Allen Ans. (1)
Due to H-bonding in it can be separated
Sol. He+ ion :
1 1 1
 R(1)2  2  2  NO2
(H)  n1 n 2 
O
1 1 1

 R(2) 2  2  2 
(He ) 2 4  from by column chromatography.
Given (H)  (He  )
1 C. Kerosene / Naphthalene
1 1 1 iv. Fractional distillation.
R(1)2  2  2   R(4)  2  2 
 n1 n 2  2 4  Due to different B.P. of kerosene and Naphthalene
1 1 1 1 it can be separated by fractional distillation.
2
 2  2 2
n1 n 2 1 2
D. C6H12O6/NaCl  i. Crystallization.
On comparing n1=1 & n2=2
Ans. 1 NaCl (ionic compound) can be crystallized.

JEE Exam Solution www.esaral.com 3

 JEE | NEET | Class 8 - 10 Download eSaral APP

43. The correct increasing order of the ionic radii is 46. Match List I with List II

(1) Cl  Ca 2   K  S2 List I List II

(2) K  S2   Ca 2  Cl
A. XeF4 I.See  saw
B.SF4 II. Square planar
(3) S2  Cl  Ca2  K
C.NH 4 III. Bent T  shaped
(4) Ca2  K  Cl  S2  D.BrF3 IV. Tetrahedral
Official Ans. by NTA (4) Choose the correct answer from the options given
Allen Ans. (4) below :
1 (1) A-IV, B-III, C-II, D-I
Sol. In isoelectronic species size 
Z (2) A-II, B-I, C-III, D-IV
Ca 2  K  Cl  S2 : Size (3) A-IV, B-I, C-II, D-III

Z: 20 19 17 18 (4) A-II, B-I, C-IV, D-III

44. H2O2 acts as a reducing agent in Official Ans. by NTA (4)

Allen Ans. (4)
(1) 2NaOCl  H 2 O2  2NaCl  H 2 O  O2
Sol.
(2) 2Fe 2   2H   H 2 O2  2Fe 3  2H 2 O
F F
(3) Mn 2   2H 2 O2  MnO2  2H 2 O Xe
(A)
F F
(4) Na 2S  4H2 O2  Na 2SO4  4H 2 O
Square planer
Official Ans. by NTA (1)
Allen Ans. (1) F
F
–1 0
Sol. NaOCl + H2O2 S
2NaCl + H2O + O2 (B) SF4
1 (–1) F
F
See-Saw
45. Which of the following artificial sweeteners has
+
the highest sweetness value in comparison to cane H

sugar? N
(C) NH4 H
H
(1) Aspartame H
(2) Sucralose
Tetrahedral
(3) Alitame
(4) Saccharin
Official Ans. by NTA (3) F Br F
(D) Br F3
Allen Ans. (3) F
Sol. Sweetness value order wrt cane sugar Bent T- Shaped

Alitame > Sucralose > Saccharin > Aspartame

JEE Exam Solution www.esaral.com 4

 JEE | NEET | Class 8 - 10 Download eSaral APP

47. Choose the correct set of reagents for the following
conversion
trans (Ph-CH=CH–CH3)  cis (Ph-CH=CH–CH3)
(1) Br2 , alc KOH, NaNH2 , Na(Liq NH3 )
(2) Br2 , alc KOH, NaNH 2 , H 2 Lindlar Catalyst
(3) Br2 , aq KOH, NaNH2 , H2 Lindlar Catalyst
49. An organic compound ‘A’ with empirical formula
C6H6O gives sooty flame on burning. Its reaction
with bromine solution in low polarity solvent
results in high yield of B. B is
OH
(1)

(4) Br2 , aq KOH, NaNH2 , Na(Liq NH3 )

Br
Official Ans. by NTA (2) CH2 CH2Br
Allen Ans. (2)
Sol. (2)
Ph H Br Br
O
C C Br2
Ph CH CH CH3 Br CH 2CH 3
H CH3
(3)
Br
(1) Alc. KOH O
(2) NaNH2 Br
OH
Ph CH3 H2
C C Ph C C CH3 (4)
H H Lindlar’s
Catalyst Official Ans. by NTA (1)
48. Adding surfactants in non polar solvent, the Allen Ans. (1)
micelles structure will look like Sol. Aromatic compounds burns with sooty flame
OH OH
polar (Surfactant structure) CS2
non-polar + Br2
head tail
(a) Non Polar Solvent (b) Non Polar Solvent Br
(Major)
50. Which one of the following statements is correct
for electrolysis of brine solution?
(1) Cl2 is formed at cathode
Non Polar Solvent (d) Non Polar Solvent (2) O2 is formed at cathode
(3) H2 is formed at anode
(4) OH– is formed at cathode
Official Ans. by NTA (4)
Allen Ans. (4)
(1) b Sol. Electrolysis of brine solution
(2) c NaCl  aq.  
 Na (aq) 
 Cl(aq)
(3) a 
At anode : 2Cl(aq.)  Cl2 (g)  2e 

(4) d (Major )

Official Ans. by NTA (3) 2H 2O( )  

 O 2(g)  4H (aq)  4e 
Allen Ans. (3) Minor

Sol. Non-Polar tail towards non-polar solvent At Cathode : 2H 2O( )  2e   

 H 2(g)  2OH (aq)
Ans. 3
2Na   2OH 
2NaOH

JEE Exam Solution www.esaral.com 5

 JEE | NEET | Class 8 - 10 Download eSaral APP

SECTION-B 53. The enthalpy change for the conversion of

51. The logarithm of equilibrium constant for the 1
2  2 Cl 2 (g) to Cl– (aq) is (-) _____________
reaction Pd  4Cl PdCl 4 is ______ 2
(Nearest integer) kJ mol–1 (Nearest integer)
2.303RT 1
Given : dis HCl2( g)  240kJmol .
o
Given :  0.06V
F
2  eg HCl
o
 350kJmol 1 ,
Pd (aq)  2e Pd(s) E  0.83V
o ( g)

PdCl 24 (aq)  2e  Pd(s)  4Cl  (aq)  hyd HoCl  380kJmol 1

( g)


E  0.65V Official Ans. by NTA (610)
Official Ans. by NTA (6) Allen Ans. (610)
Allen Ans. (6) 1  
Sol. Go  RT n K Sol. Cl 2(g)  Cl(g)  Cl(g)  Cl(aq.)
2
 nFE ocell  RT  2.303(log10 K) 1
Hº   240  ( 350)  ( 380)
E oCell 2
 n  log K …(1)
0.06 = – 610 ans.
2 
Pd (aq.)  2 e Pd(s) , E o
ca t,red n
 0.83 54. On complete combustion, 0.492 g of an organic
Pd(s)  4Cl  (aq.) PdCl24 ,(aq)  2e  , E oAnode,Oxid n  0.65 compound gave 0.792 g of CO2.
The % of carbon in the organic compound is _____
Net Reaction  Pd2+ (aq.) + 4Cl– (aq.) PdCl42–(aq.)
(Nearest integer)
E ocell  E o ca t,red n  E oAnode,Oxidn
Official Ans. by NTA (44)
E o
cell  0.83 – 0.65 Allen Ans. (44)
E ocell  0.18 …(2) Sol. weight of C in 0.792 gm CO2
Also n = 2 …(3) 12
Using equation (1), (2) & (3) 0.792 0.216
44
logK = 6
52. AB 0.216
The rate constants of the above reaction at 200 K % of C in compound = 100
0.492
and 300K are 0.03 min–1 and 0.05 min–1
respectively. The activation energy for the reaction = 43.90%
is _______ J (Nearest integer)
(Given : In 10 = 2.3 Ans : 44
R = 8.3 J K-1 mol-1
55. At 27oC, a solution containing 2.5 g of solute in
log5 = 0.70
250.0 mL of solution exerts an osmotic pressure of
log3=0.48
400 Pa. The molar mass of the solute is ____ g
log2 = 0.30
mol-1 (Nearest integer)
Official Ans. by NTA (2520)
(Given : R = 0.083 L bar K–1 mol–1)
Allen Ans. (2520)
Sol. Official Ans. by NTA (62250)
Allen Ans. (62250)
K300 Ea 1 1 
log     Sol. :  = CRT
K 200 2.3  8.314  T1 T2 
2.5g
0.05 Ea  1 1  400Pa Mo L  bar
log    =  0.83  300K
0.03 2.305  8.314  200 300  10 5
250 / 1000L K.mol
Ea = 2519.88 J Ea = 2520 J Mo = 62250

JEE Exam Solution www.esaral.com 6

 JEE | NEET | Class 8 - 10 Download eSaral APP

56. Zinc reacts with hydrochloric acid to give 1

hydrogen and zinc chloride. The volume of 58. For reaction : SO 2 (g)  O 2 (g) SO3 (g)
2
hydrogen gas produced at STP from the reaction of
KP = 2 × 1012 at 27oC and 1 atm pressure. The Kc
11.5 g of zinc with excess HCl is ______ L
(Nearest integer) for the same reaction is _______ × 1013. (Nearest
(Given : Molar mass of Zn is 65.4g mol-1 and integer)
Molar volume of H2 at STP = 22.7L) (Given R = 0.082 L atm K–1 mol–1)
Official Ans. by NTA (4) Official Ans. by NTA (1)
Allen Ans. ( 4) Allen Ans. (1)
Sol. Zn 2HCl ZnCl2 H2 1
11.5 Sol. SO 2(g)  O 2(g) SO3(g)
Moles of Zn used = = Moles of H2 evolved 2
65.4
K P  2  1012 at 300 K
11.5
Volume of H2 = 22.7L 3.99L n g
65.4 K P  KC  (RT)
Ans : 4 2 × 1012 = Kc × (0.082 × 300)-1/2
57. How many of the transformation given below KC = 9.92 × 1012
would result in aromatic amines?
O KC = 0.992 × 1013
Ans. 1
NH2+Br2 +NaOH
(1) 59. The oxidation sate of phosphorus in
Cl hypophosphoric acid is + ________ .
O Official Ans. by NTA (4)
(2) NK
Allen Ans. (4)
Sol. H4P2O6
O
NO2 O O
H2 || ||
(3) HO – P – P – OH
Pd/C | |
NH COCH3 O O
H H
dil H2 SO 4
(4)
 O.S. of P is +4
Official Ans. by NTA (3) 60. The total pressure of a mixture of non-reacting
Allen Ans. (3)
Sol. Product in the given reactions are as follow- gases X (0.6 g) and Y (0.45 g) in a vessel is 740
mm of Hg. The partial pressure of the gas X is
1. _________ mm of Hg. (Nearest Integer)

2. No reactions will be observed as in Gabriel (Given : molar mass X = 20 and Y = 45 g mol-1)

Cl
Official Ans. by NTA (555)
phthalimide synthesis is poor
Allen Ans. (555)
2
substrate for SN
NH2
Sol. Px  x PT

3. 0.6
 20  740
NH2
0.6 0.45

4. + CH3COOH 20 45
Aromatic amines will he formed in 1, 3 & 4 Px = 555 mm Hg
Ans : 3

JEE Exam Solution www.esaral.com 7