Final JEE-Main Exam June, 2022/25-06-2022/Morning Session

FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Saturday 25th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 4. Leaching of gold with dilute aqueous solution of
1. Bonding in which of the following diatomic NaCN in presence of oxygen gives complex [A],
molecule(s) become(s) stronger, on the basis of which on reaction with zinc forms the elemental
MO Theory, by removal of an electron ?
gold and another complex [B]. [A] and [B],
(A) NO (B) N2 respectively are :-
(C) O2 (D) C2
(A) [Au(CN)4]– and [Zn(CN)2(OH)2]2–
(E) B2
(B) [Au(CN)2]– and [Zn(OH)4]2–
Choose the most appropriate answer from the
options given below :- (C) [Au(CN)2]– and [Zn(CN)4]2–
(A) (A), (B), (C) only (B) (B), (C), (E) only (D) [Au(CN)4]2– and [Zn(CN)6]4–
(C) (A), (C) only (D) (D) only Official Ans. by NTA (C)

Allen Ans. (C)

EN
Official Ans. by NTA (C)

Sol. Bond strength µ Bond order

removal of electron from antibonding MO
increases B.O.
NO & O2 has valence e_ in p *orbital.
5.
Allen Ans. (C)
Sol. Au + NaCN ® Na[Au(CN)2]
Zn + Na[Au(CN)2] ® Na2[Zn(CN)4] + Au
Number of electron deficient molecules among
the following
PH3, B2H6, CCl4, NH3, LiH and BCl3 is
2. Incorrect statement for Tyndall effect is :-
(A) The refractive indices of the dispersed phase (A) 0 (B) 1
LL
and the dispersion medium differ greatly in (C) 2 (D) 3
magnitude. Official Ans. by NTA (C)
(B) The diameter of the dispersed particles is much
Allen Ans. (C)
smaller than the wavelength of the light used.
Sol. Electron deficient species have less than 8 electrons
(C) During projection of movies in the cinemas
hall, Tyndall effect is noticed. (or two electrons for H) in their valence
(incomplete octet)
(D) It is used to distinguish a true solution from a
A

colloidal solution. B2H6, BCl3 have incomplete octet.

Official Ans. by NTA (B) 6. Which one of the following alkaline earth metal
Allen Ans. (B) ions has the highest ionic mobility in its aqueous
Sol. The diameter of dispersed particle should be solution?
somewhat below or near the wavelength of light. (A) Be2+ (B) Mg2+
3. The pair, in which ions are isoelectronic with Al3+ (C) Ca2+ (D) Sr2+
is :-
Official Ans. by NTA (D)
(A) Br– and Be2+ (B) Cl– and Li+
Allen Ans. (D)
(C) S2– and K+ (D) O2– and Mg2+
Official Ans. by NTA (D) Sol. Highest ionic mobility corresponds to lowest extent
of hydration and highest size of gaseous ion.
Allen Ans. (D)
Sol. Isoelectronic species have same no. of electrons Hence Sr2+ has the highest ionic mobility in its
aqueous solution
Al+3, O2-, Mg+2 all have 10 electrons.

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Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
7. White precipitate of AgCl dissolves in aqueous Sol. Eutrophication of water body results in loss of
ammonia solution due to formation of : Biodiversity.
(A) [Ag(NH3)4]Cl2 (B) [Ag(Cl)2(NH3)2 ] 11. Phenol on reaction with dilute nitric acid, gives
two products. Which method will be most effective
(C) [Ag(NH3)2]Cl (D) [Ag(NH3)Cl]Cl
for large scale separation ?
Official Ans. by NTA (C) (A) Chromatographic separation
Allen Ans. (C) (B) Fractional Crystallisation
Sol. AgCl + 2NH3 ® [Ag(NH3)2]+Cl– (C) Steam distillation
soluble (D) Sublimation
8. Cerium (IV) has a noble gas configuration. Which Official Ans. by NTA (C)
of the following is correct statement about it? Allen Ans. (C)
(A) It will not prefer to undergo redox reactions. Sol.
(B) It will prefer to gain electron and act as an : :
OH :
OH
oxidizing agent OH NO2
(C) It will prefer to give away an electron and dil +
behave as reducing agent HNO3

Official Ans. by NTA (B)

Allen Ans. (B) EN
(D) It acts as both, oxidizing and reducing agent.

Sol. Cerium exists in two different oxidation state +3,

+4
Ce+4 + e– ® Ce3+ E0 = + 1.61 V
(ortho)
NO2
(para)

Para product has higher boiling point than ortho

as intermolecular H-bond is possible in former,
where as intramolecular H-bond is possible in ortho
product.
Ce+3 + 3e– ® Ce E0 = –2.336 V
Steam distillation can separate them as ortho
LL
It shows Ce+4 acts as a strong oxidising agent &
product is steam volatile.
accepts electron.
9. Among the following, which is the strongest 12. In the following structures, which one is having
oxidizing agent ?
staggered conformation with maximum dihedral
(A) Mn3+ (B) Fe3+
angle?
(C) Ti3+ (D) Cr3+
Official Ans. by NTA (A) CH3
A

CH3H
Allen Ans. (A) H CH3
Sol. Strongest oxidising agent have highest reduction
potential value (A) H H (B)
H H
E 0
= 1.51V (highest) H CH3
Mn +3 / Mn +2 H
10. The eutrophication of water body results in :
CH3
(A) loss of Biodiversity CH3 CH
H H 3
(B) breakdown of organic matter
(C) increase in biodiversity
(C) H H (D)
(D) decrease in BOD. H H
Official Ans. by NTA (A) CH3 H H
Allen Ans. (A)
Official Ans. by NTA (C)
Allen Ans. (C)

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 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
Sol. Dihedral angle : It’s the angle b/w 2 specified Cl
groups (–CH3 here) Sol.
Cl
Staggered form is Given in option (C) & the angle
“1, 1-Dichloroethane is Ethylidene chloride”
is 1800
15. The major product in the reaction
13. The products formed in the following reaction.
CH3
CH 3 H CH3 CH3
– –

CH 3 C=CH2+H–C –CH3 ? is :
–
+ –
CH3– C – Cl + K O – C – CH3 ? is
–
CH3
CH3 CH3
(A) CH3 CH–CH –CH –CH CH3
CH3 2 2
CH3 (A) t-Butyl ethyl ether
(B) 2,2-Dimethyl butane
CH3 (C) 2-Methyl pent-1-ene
(B) CH 3 (D) 2-Methyl prop-1-ene
CH 3 C –CH2–C–CH3 Official Ans. by NTA (D)
H CH3
Allen Ans. (D)

(C) CH3–CH–CH–CH
CH3 CH3EN
CH3 CH3
(D) CH3– C – C – CH3
CH3
CH3
Sol. We have been given a bulky base, hence
elimination will take place & not substitution.

CH 3 C
CH 3

CH 2 H
Cl + t-BuO
_
CH 3 C
CH3

2-methyl
CH2

CH3 CH3 prop-1-ene

LL
Official Ans. by NTA (B) [D]
16. The intermediate X, in the reaction
Allen Ans. (B)
OH

Sol. + H+ ¾¾
® +
CHCl3+Aq.NaOH + [X]
(1) NaOH
+
(2) H
+
+
A

+ OH
CHO is :

+ H +
+ +
OH OH
14. The IUPAC name of ethylidene chloride is :- CCl3 CHCl2
(A) (B)
(A) 1-Chloroethene
(B) 1-Chloroethyne
(C) 1,2-Dichloroethane – + – +
O Na O Na
(D) 1,1-Dichloroethane CHCl2 CCl3
Official Ans. by NTA (D) (C) (D)
Allen Ans. (D)
Official Ans. by NTA (C)
Allen Ans. (C)
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Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
Sol. It’s a classic Reimer-Tiemann reaction. 18. The reaction of R–C– NH2 with bromine and KOH
_ +
O Na
O
CHCl2
gives RNH2 as the end product. Which one of the
following is the intermediate product formed in
this reaction ?
Will be the intermediate formed.
(A) R–C– NH–Br (B) R–NH–Br
17. In the following reaction :
CH3 CH3 H3C CH3 O
CH C–O–O–H (C) R–N=C=O (D) R–C– NBr2
+
H O
+ O2
H2O
A and B
Official Ans. by NTA (C)
The compounds A and B respectively are :-
CH3 Allen Ans. (A & C)
Sol. The given reaction is Hoffmann-Bromide
(A) , CH3COOH degradation method.
OH

(B)

(C)
OH

OH
OH
EN
, CH3COCH3
, CH3COOH R
O

N
H

O
_
+ OH ƒ R
O
_
NH

Br

O
Br

OH _
(D) .. Br
, CH3COCH3 Br ƒ
ƒ R N
LL
R N
H _
Official Ans. by NTA (C)
OH
Allen Ans. (C)
Sol. Given reaction is cumene-Peroxide method for the _
preparation of phenol. OH _ +
In this reaction R-N=C-OH R-N=C=O R-N-C=O
_
A

+
O-O-H O-OH 2 O :+ O

¾¾
H
®
+
¾¾
®

Proton transfer

H2O O
H _
H + H R N C O RNH2+ CO2
O: O
OH
O
+

Acetone Phenol

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 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session
19. Using very little soap while washing clothes, does Sol. Unit cell formula – Na4Cl4
not serve the purpose of cleaning of clothes
because Z ´ M.M.
Mass per unit cell = g
NA
(A) soap particles remain floating in water as ions
(B) the hydrophobic part of soap is not able to
4 ´ 58.5
take away grease = g
NA
(C) the micelles are not formed due to
concentration of soap, below its CMC value m m
d unit cell = =
(D) colloidal structure of soap in water is V a3
completely disturbed. 4 ´ 58.5
Þ = 43.1
Official Ans. by NTA (C) NA × a 3
Allen Ans. (C)
Sol. Micelle formation only takes place above CMC. Þ a 3 = 9.02 ´10-24 cm3
20. Which one of the following is an example of
artificial sweetner ? Þ a = 2.08 ´10-8 cm
(A) Bithional
(C) Salvarsan

Allen Ans. (B)

EN
Official Ans. by NTA (B)
(B) Alitame
(D) Lactose

Sol. Alitame is a second generation dipeptide sweetner

that is 200 times sweeter than sucrose.
Þ a = 2.08 ´ 10-10 m

Also a = 2 ( rNa + rCl

\ The answer is 1
-
+ -

Þ rNa + rCl = 1.04 ´ 10 -10 m

)

3. The longest wavelength of light that can be used

SECTION-B for the ionisation of lithium atom (Li) in its ground
LL
1. The number of N atoms is 681 g of C7H5N3O6 is state is x × 10 –8 m. The value of x is
x × 1021. The value of x is _____ (NA = 6.02 × ____________. (Nearest Integer)
1023 mol–1) (Nearest Integer) (Given : Energy of the electron in the first
Official Ans. by NTA (5418) shell of the hydrogen atom is –2.2 × 10–18 J;
Allen Ans. (5418) h = 6.63 × 10–34 Js and c = 3 × 108 ms–1)
Sol. M.M. of C7H5N3O6 is 84 + 5 + 42 + 96 = 227 Official Ans. by NTA (4)
A

681 Allen Ans. (Bonus)

nC H N O = =3
7 5 3 6
227 Sol. We can not calculate I.E. of lithium atom.
681 4. The standard entropy change for the reaction
nN = ´ 3 = 9 mol
227 4Fe(s) + 3O2(g) ® 2Fe2 O3(s) is –550 JK–1 at
298 K.
no. of N atoms = 9 ´ 6.02 ´ 1023
[Given : The standard enthalpy change for the
= 5418 ´ 1021 reaction is –165 kJ mol–1]. The temperature in K
\ The answer is 5418. at which the reaction attains equilibrium is
2. The distance between Na+ and Cl– ions in solid _________. (Nearest Integer)
NaCl of density 43.1 g cm–3 is ________ × Official Ans. by NTA (300)
10–10m. (Nearest Integer) Allen Ans. (300)
(Given : NA = 6.02 × 10 mol )23 –1

Official Ans. by NTA (1)

Allen Ans. (1)
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Final JEE-Main Exam June, 2022/25-06-2022/Morning Session

Sol. DG = DH - TDS = 0 at equilibrium 7. In a cell, the following reactions take place

Þ -165 ´ 103 - T ´ ( -505) = 0

Fe2+ ® Fe3+ e - E oFe3+ /Fe2+ = 0.77 V
Þ T = 300K
The answer is 300 2I - ® I 2 + 2e - E oI /I - = 0.54 V
2
5. 1 L aqueous solution of H2SO4 contains 0.02
m mol H2SO4. 50% of this solution is diluted The standard electrode potential for the
with deionized water to give 1 L solution (A). spontaneous reaction in the cell is x × 10–2V 298
In solution (A), 0.01 m mol of H 2 SO 4 are
K. The value of x is __________ (Nearest
added. Total m mols of H 2 SO 4 in the final
Integer)
solution is ____________ × 103 m mols.
Official Ans. by NTA (0) Official Ans. by NTA (23)

Allen Ans. (0) Allen Ans. (23)

Sol. n H SO in Soln A = 50% of original solution

2 4 Sol. Fe +3 + I - ¾¾
® I2 + Fe +2
Cathode anode

= 0.01 m mol.

6.
= 0.02 mmol EN
n H SO in Final solution = 0.01 + 0.01
2 4

= 0.00002 ´ 103 mmol

The answer 0
The standard free energy change (DG°) for 50%
E 0Cell = E cathode

=0.77–0.54

=0.23
0

= 23 ´ 10-2 V
- E anode
0

dissociation of N2O4 into NO2 at 27°C and 1

8. For a given chemical reaction
atm pressure is –x J mol–1. The value of x is
LL
_________. (Nearest Integer) g1A + g 2B ® g 3C + g 4 D
[Given : R = 8.31 J K–1 mol–1, log 1.33 = 0.1239
ln 10 = 2.3] Concentration of C changes from 10 mmol
Official Ans. by NTA (710) dm–3 to 20 mmol dm–3 in 10 seconds. Rate of
Allen Ans. (710) appearance of D is 1.5 times the rate of
Sol. N 2O4 ƒ 2NO 2 disappearance of B which is twice the rate of
disappearance A. The rate of appearance of D
A

t=0 1 mol
has been experimentally determined to be 9 mmol
t=t (1-0.5) mol 0.5 ´ 2 mol
dm –3 s –1 . Therefore the rate of reaction is
= 0.5 mol 1 mol ________mmol dm–3 s–1 . (Nearest Integer)
2
æ 1 ö Official Ans. by NTA (1)
ç 1.5 ´ 1÷
kP = è ø = 1 = 100 Allen Ans. (1)
æ 0.5 ö 0.75 75
ç ´ 1÷ Sol. g1A + g 2 B ¾¾
® g3C + g 4 D
è 1. 5 ø
= 1.33
d [D] -3 d [ B ]
Given : + =
DG = - RTlnk P
0
dt 2 dt

= -8.31´ 300 ´ ln (1.33) = -710.45 J / mol -1 d [ B ] +1 d [ D ]

Þ =
2 dt 3 dt
= –710 J/mol.

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 Final JEE-Main Exam June, 2022/25-06-2022/Morning Session

d [ B] d [A] 1 d [ B] -d ( A ) = 340.34 ´ 10-21 J

- = -2 Þ- =
dt dt 2 dt dt
9
D0 = Dt
d [ B] 4
+ = 9 mmoldm -3s -1
dt
9
= ´ 340.34 ´ 10-21
4
+d [C] 20 - 10
= = 1mmol dm -3s -1
dt 10 = 765.765 ´ 10-21 J

+d [C] 1 +d [ D] » 766 ´ 10-21 J

= ´
dt 9 dt Answer = 766

1 10. Number of grams of bromine that will completely

1A + 2B ¾¾
® C + 3D react with 5.0g of pent-1-ene is _______ ×
3
10–2g. (Atomic mass of Br = 80 g/mol) [Nearest
Þ 3A + 6B ¾¾
® C + 9D Integer)

9.
Rate of reaction = EN +d [C]
dt
= 1 mmol dm -3 s -1

If [Cu(H2O)4] absorbs a light of wavelength 600

2+

nm for d–d transition, then the value of octahedral

crystal field splitting energy for [Cu(H2O)6]2+ will
Sol.
Official Ans. by NTA (1143)
Allen Ans. (1143)

(C5 H10 )
+Br2 ¾¾
®
Br
Br

(C5H 10Br2)

be___________× 10–21 J. (Nearest Integer)

moles of Br2 = moles of C5H10
LL
(Given : h = 6.63 × 10–34Js
and c = 3.08 × 108 ms–1) w 5
Þ =
Official Ans. by NTA (746) 160 70
Allen Ans. (766)
5 ´ 160
Þw= g
hc 6.63 ´ 10-34 ´ 3.08 ´ 108 70
Sol. Dt = =
l 600 ´ 10-9 = 11.428 g
A

6.63 ´ 3.08 ´ 10-17 = 1142.8 ´10-2 g » 1143 ´10-2 g

=
600

= 0.034034 ´ 10-17