FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Wednesday 29th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH ANSWER

SECTION-A 3. Arrange the following in the decreasing order of
1. Production of iron in blast furnace follows the their covalent character :
following equation (A) LiCl (B) NaCl
Fe3O4(s) + 4CO(g) 3Fe(l) + 4CO2(g) (C) KCl (D) CsCl
when 4.640 kg of Fe3O4 and 2.520 kg of CO are Question: Choose the most appropriate answer
allowed to react then the amount of iron (in g) from the options given below :
produced is : (A) (A)> (C) > (B)> (D)
[Given : Molar Atomic mass (g mol –1): Fe = 56 (B) (B) > (A) > (C) > (D)
Molar Atomic mass (g mol –1) : 0 = 16 (C) (A) > (B) > (C) > (D)
Molar Atomic mass (g mol –1): = C = 12 EN (D) (A) > (B) > (D) > (C)
(A) 1400 (B) 2200 Official Ans. by NTA (C)
(C) 3360 (D) 4200 Allen Ans. (C)
Official Ans. by NTA (C) 4. The solubility of AgCl will be maximum in which
Allen Ans. (C) of the following ?
LL
2. Which of the following statements are correct ? (A) 0.01 M KCl
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(A) The electronic configuration of Cr is [Ar] 3d (B) 0.01 M HC1
4s1. (C) 0.01 M AgNO3
(B) The magnetic quantum number may have a (D) Deionised water
A

negative value. Official Ans. by NTA (D)

(C) In the ground state of an atom, the orbitals are Allen Ans. (D)
filled in order of their increasing energies. 5. Which of the following is a correct statement ?
(D) The total number of nodes are given by n – 2 . (A) Brownian motion destabilises sols.
Choose the most appropriate answer from the (B) Any amount of dispersed phase can be added
options given below : to emulsion without destabilising it.
(A) (A), (C) and (D) only (C) Mixing two oppositely charged sols in equal
(B) (A) and (B) only amount neutralises charges and stabilises colloids.
(C) (A) and (C) only (D) Presence of equal and similar charges on
(D) (A), (B) and (C) only colloidal particles provides stability to the colloidal
Official Ans. by NTA (D) solution.
Allen Ans. (D) Official Ans. by NTA (D)
Allen Ans. (D)
1
6. The electronic configuration of Pt (atomic number 10. Match the List-I with List- II.
78) is: List-I List-II
14 9 1
(A) [Xe] 4f 5d 6s (Metal) Application
14 10
(B) [Kr] 4f 5d (A) Cs (I) High temperature
(C) [Xe] 4f14 5d10
thermometer
(D) [Xe] 4f14 5d8 6s2
(B) Ga (II) Water repellent
Official Ans. by NTA (A)
sprays
Allen Ans. (A)
(C) B (III) Photoelectric cells
7. In isolation of which one of the following metals
from their ores, the use of cyanide salt is not (D) Si (IV) Bullet proof vest

commonly involved ? Choose the most appropriate answer from the

(A) Zinc (B) Gold option given below:
(C) Silver (D) Copper (A) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
Official Ans. by NTA (D) (B) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
Allen Ans. (D) (C) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
8. Which one of the following reactions indicates theEN (D) (A)-(I), (B)-(IV), (C)-(II), (D)-(III)
reducing ability of hydrogen peroxide in basic Official Ans. by NTA (A)
medium ?
Allen Ans. (A)
(A) HOCl + H2O2  H3O+ + Cl– + O2
11. The oxoacid of phosphorus that is easily obtained
(B) PbS + 4H2O2 PbSO4 + 4H2O from a reaction of alkali and white phosphorus and
(C) 2MnO4  3H2O2  2MnO2  3O2  2H2O  2OH has two P-H bonds, is :
LL

(D) Mn2 + + H2O2 Mn4+ + 2OH– (A) Phosphonic acid

Official Ans. by NTA (C) (B) Phosphinic acid
Allen Ans. (C) (C) Pyrophosphorus acid
9. Match the List-I with List- II. (D) Hypophosphoric acid
A

List-I List-II Official Ans. by NTA (B)

(Metal) (Emitted light Allen Ans. (B)
wavelength (nm)) 12. The acid that is believed to be mainly responsible
(A) Li (I) 670.8 for the damage of Taj Mahal is
(A) Sulfuric acid (B) Hydrofluoric acid
(B) Na (II) 589.2
(C) Phosphoric acid (D) Hydrochloric acid
(C) Rb (III) 780.0
Official Ans. by NTA (A)
(D) Cs (IV) 455.5 Allen Ans. (A)
Choose the most appropriate answer from the 13. Two isomers 'A' and 'B' with molecular formula
options given below: C4H8 give different products on oxidation with
(A) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) KMnO4 in acidic medium. Isomer 'A' on reaction
with KMnO4/H+ results in effervescence of a gas
(B) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
and gives ketone. The compound 'A' is
(C) (A)-(III), (B)-( I), (C)-(II), (D)-(IV)
(A) But-1-ene (B) cis-But-2-ene
(D) (A)-(IV), (B)-(II), (C)-(I), (D)-(III) (C) trans-But-2ene (D) 2-methyl propene
Official Ans. by NTA (A) Official Ans. by NTA (D)
Allen Ans. (A) Allen Ans. (D)
2
 OH COOH NH2 NH2

14. (CH3)3CLi
(A)
(i) CO2
(ii) H3O+ 16. Br2(excess)
A
(i) (CH3CO)2O
B
OH OH H2O
Major Product (ii) Br2, CH3COOH
Major Product
(ii) HCl
In the given conversion the compound A is:
Consider the above reaction, the product A and
Li
product B respectively are
(A) NH2 NH2

OH
(A) and
Li
(B) Br Br
NH2 NH2
OLi Br Br Br Br
(B) and
(C)
Br Br
NH2 NH2
C(CH3)3 EN Br Br

(D) (C) and

OH
Br Br
NH2 NH2
Official Ans. by NTA (B) Br Br
LL

Allen Ans. (B) (D) and

15. Given below are two statements : Br Br

Statement I : The esterification of carboxylic acid Official Ans. by NTA (C)

Allen Ans. (C)
A

with an alcohol is a nucleophilic acyl substitution.

17. The polymer, which can be stretched and retains its
Statement II : Electron withdrawing groups in the original status on releasing the force is

carboxylic acid will increase the rate of (A) Bakelite (B) Nylon 6,6
(C) Buna-N (D) Terylene
esterification reaction.
Official Ans. by NTA (C)
Choose the most appropriate option : Allen Ans. (C)

(A) Both Statement I and Statement II are correct. 18. Sugar moiety in DNA and RNA molecules
respectively are
(B) Both Statement I and Statement II are incorrect.
(A) -D-2-deoxyribose,  -D-deoxyribose
(C) Statement I is correct but Statement II is incorrect. (B) -D-2-deoxyribose,  -D-ribose

(D) Statement I is incorrect but Statement II is correct. (C) -D-ribose,  -D-2-deoxyribose

(D) -D-deoxyribose,  -D-2-deoxyribose
Official Ans. by NTA (A)
Official Ans. by NTA (B)
Allen Ans. (A)
Allen Ans. (B)

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19. Which of the following compound does not 3. 1.2 mL of acetic acid is dissolved in water to make
contain sulfur atom ? 2.0 L of solution. The depression in freezing point
(A) Cimetidine (B) Ranitidine observed for this strength of acid is 0.0198°C. The
(C) Histamine (D) Saccharin percentage of dissociation of the acid is ________ .
Official Ans. by NTA (C) (Nearest integer)
Allen Ans. (C)
[Given : Density of acetic acid is 1.02 g mL–1
20. Given below are two statements.
Molar mass of acetic acid is 60 g mol–1
Statement I : Phenols are weakly acidic.
Statement II : Therefore they are freely soluble in Kf (H2O) =1.85 K kg mo1–1]

NaOH solution and are weaker acids than alcohols Official Ans. by NTA (5)
and water. Allen Ans. (5)
Choose the most appropriate option:
4. A dilute solution of sulphuric acid is electrolysed
(A) Both Statement I and Statement II are correct.
using a current of 0.10 A for 2 hours to produce
(B) Both Statement I and Statement II are incorrect.
hydrogen and oxygen gas. The total volume of
(C) Statement I is correct but Statement II is
gases produced at STP is ________ cm3. (Nearest
incorrect.
(D) Statement I is incorrect but Statement II is
EN integer) [Given : Faraday constant F = 96500 C

correct. mo1–1 at STP, molar volume of an ideal gas is

Official Ans. by NTA (C) 22.7 L mo1–1]

Allen Ans. (C) Official Ans. by NTA (127)

LL

Allen Ans. (127)

SECTION-B
5. The activation energy of one of the reactions in a
1. Geraniol, a volatile organic compound, is a biochemical process is 532611 J mo1–1. When the
component of rose oil. The density of the vapour is
A

temperature falls from 310 K to 300 K, the change

–1
0.46 gL at 257°C and 100 mm Hg. The molar in rate constant observed is k300 = x  10–3 k310. The
mass of geraniol is ___________ (Nearest Integer) value of x is _________.
–1 –1
[Given R = 0.082 L atm K mol ] [Given: 1n10 = 2.3 , R=8.3 J K–1 mo1–1]
Official Ans. by NTA (152)
Official Ans. by NTA (1)
Allen Ans. (152)
Allen Ans. (1)
2. 17.0 g of NH3 completely vapourises at – 33.42°C 6. The number of terminal oxygen atoms present in the
and 1 bar pressure and the enthalpy change in the
product B obtained from the following reaction is
–1
process is 23.4 kJ mol . The enthalpy change for ________.
the vapourisation of 85 g of NH3 under the same
FeCr2O4 + Na2CO3+ O2 A + Fe2O3 + CO2
conditions is ________ kJ.
A + H+ B+ H2O + Na+
Official Ans. by NTA (117)
Official Ans. by NTA (6)
Allen Ans. (117)
Allen Ans. (6)
4
7. An acidified manganate solution undergoes 9. Observe structures of the following compounds
disproportionation reaction. The spin-only
NH2
OH
magnetic moment value of the product having Cl
H2N
OH
OH
manganese in higher oxidation state is _________ O
O

B.M. (Nearest integer)

The total number of structures/compounds which
Official Ans. by NTA (0) possess asymmetric carbon atoms is __________.
Allen Ans. (0) Official Ans. by NTA (3)
8. Kjeldahl's method was used for the estimation of Allen Ans. (3)
nitrogen in an organic compound. The ammonia
10. C6 H12 O6 
Zymase
 A 
NaOI

 B  CHI3
evolved from 0.55 g of the compound neutralised
12.5 mL of 1 M H2SO4 solution. The percentage of The number of carbon atoms present in the product

nitrogen in the compound is _________. (Nearest B is __________.

integer) Official Ans. by NTA (1)

Official Ans. by NTA (64) Allen Ans. (1)

Allen Ans. (64)

EN
LL
A