FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Tuesday 28th June, 2022) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A (D) ±1/2 are the two possible orientations of
1. Compound A contains 8.7% Hydrogen, 74% electron spin.
Carbon and 17.3% Nitrogen. The molecular (E) For l = 5, there will be a total of 9 orbital.
formula of the compound is, Which of the above statements are correct?
Given : Atomic masses of C, H and N are 12, 1 and (A) (A), (B) and (C)
14 amu respectively.
(B) (A), (C), (D) and (E)
–1
The molar mass of the compound A is 162 g mol .
(C) (A), (C) and (D)
(A) C4H6N2 (B) C2H3N
(D) (A), (B), (C) and (D)
(C) C5H7N (D) C10H14N2
Official Ans. by NTA (C)
Official Ans. by NTA (D)
Allen Ans. (C)

Sol.
Allen Ans. (D)
EN Sol. (A) Number of values of n = 1, 2, 3 … 
(B) Number of values of  = 0 to (n – 1)
74 6.16
C 74%  6.16 5
12 1.23 (C.) Number of values of m = –  to + 
17.3 1.23
LL
N 17.3%  1.23 1
14 1.23   Total values = 2 + 1
8.7 8.7
H 8.7%  8.7 7 1
1 1.23 (D) Values of spin = 
2
Emperical formula = C5NH7
A

(E) For  = 5 number of orbitals = 2+ 1= 11

Emperical weight = 81
162 3. In the structure of SF4, the lone pair of electrons on
Multiplying factor = 2
81
S is in.
Molecular formula = C10N2H14
(A) equatorial position and there are two lone pair-
2. Consider the following statements : bond pair repulsions at 90°
(A) The principal quantum number „n‟ is a positive
(B) equatorial position and there are three lone
integer with values of „n‟ = 1, 2, 3, ….
pair-bond pair repulsions at 90°
(B) The azimuthal quantum number „l‟ for a given
(C) axial position and there are three lone pair –
„n‟ (principal quantum number) can have values as
bond pair repulsion at 90°.
„l‟ = 0, 1, 2, …. n
(D) axial position and there are two lone pair –
(C) Magnetic orbital quantum number „ml‟ for a
bond pair repulsion at 90°.
particular „l‟ (azimuthal quantum number) has (2l
+ 1) values. Official Ans. by NTA (A)

Allen Ans. (A)

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Sol. Choose the correct answer from the options given
F below :
F
(A) (A) – (II), (B) – (III), (C) – (IV), (D) – (I)
S (B) (A) – (II), (B) – (I), (C) – (III), (D) – (IV)
(C) (A) – (II), (B) – (III), (C) – (I), (D) – (IV)
F
F (D) (A) – (I), (B) – (III), (C) – (II), (D) – (IV)
sp3d, See-Saw Official Ans. by NTA (C)
Allen Ans. (C)
4. A student needs to prepare a buffer solution of
Sol. Negative charged sol = CdS (II)
propanoic acid and its sodium salt with pH 4. The
Macromolecular colloid = starch (III)
[CH3CH 2 COO  ] Positively charged sol = Fe2O3.xH2O (I)
ratio of required to make buffer
[CH3CH 2 COOH] Cheese = gel (IV)
is ………. 6. Match List-I with List-II.

Given : Ka(CH3CH2COOH) = 1.3 × 10–5 List-I (Oxide) List-II (Nature)

(A) Cl2O7 (I) Amphoteric
(A) 0.03 (B) 0.13
EN (B) Na2O (II) Basic
(C) 0.23 (D) 0.33 (C) Al2O3 (III) Neutral

Official Ans. by NTA (B) (D) N2O (IV) Acidic

Choose the correct answer from the options given
Allen Ans. (B)
below :
Salt  (A) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
Sol. pH  pK a  log 
LL

Acid  (B) (A) – (IV), (B) – (II), (C) – (I), (D) – (III)
(C) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
CH3CH2COO 
4  5  log1.3  log  (D) (A) – (I), (B) – (II), (C) – (IIII), (D) – (IV)
CH3CH2COOH Official Ans. by NTA (B)
CH3CH2COO  
A

1.3 Allen Ans. (B)

log   log1.3  1  log
CH3CH2COOH 10 Sol. Cl2O7 Acidic
Na2O Basic
CH3CH2COO  Al2O3 Amphoteric
 0.13
CH3CH2COOH N2O Neutral
7. In the metallurgical extraction of copper, following
5. Match List-I with List-II.
reaction is used :
List-I List-II FeO + SiO2  FeSiO3
(A) Negatively (I) Fe2O3·xH2O FeO and FeSiO3 respectively are.
charged sol (A) gangue and flux (B) flux and slag
(B) Macromolecular (II) CdS sol (C) slag and flux (D) gangue and slag
colloid Official Ans. by NTA (D)
(C) Positively (III) Starch Allen Ans. (D)
charged sol Sol. FeO = Gangue

(D) Cheese (IV) a gel FeSiO3 = Slag

2
8. Hydrogen has three isotopes : protium (1H), Sol.
deuterium (2H or D) and tritium (3H or T). They S (–2) O O
have nearly same chemical properties but different +6
O S OH HO S+5 S +5 OH
physical properties. They differ in
(A) number of protons OH O O
H2S2O3 H2S2O6
(B) atomic number
(C) electronic configuration O O O O
(D) atomic mass HO S
+6
O S+6 OH HO S
+6
O O S+6 OH
Official Ans. by NTA (D)
O O O O
Allen Ans. (D) H2S2O7 H2S2O8
Sol. They have different neutrons and mass number
9. Among the following basic oxide is : 12. Correct statement about photo-chemical smog is :
(A) SO3 (B) SiO2 (A) It occurs in humid climate.
(C) CaO (D) Al2O3
(B) It is a mixture of smoke, fog and SO2
Official Ans. by NTA (C)
Allen Ans. (C) (C) It is reducing smog.
Sol. SO3, SiO2 = Acidic (D) It results from reaction of unsaturated
CaO = Basic
Al2O3 = Amphoteric
EN hydrocarbons.

Official Ans. by NTA (D)

10. Among the given oxides of nitrogen; N2O, N2O3,
N2O4 and N2O5, the number of compound/(s) Allen Ans. (D)
having N–N bond is : Sol. Photo chemical smog results from the action of
LL
(A) 1 (B) 2 sunlight on unsaturated hydro carbons and nitrogen

(C) 3 (D) 4 oxide

Official Ans. by NTA (C) 13. The correct IUPAC name of the following
compound is :
Allen Ans. (C)
A

Sol.
O O O O
+
N  N– O –
N–N N–N
O O O (A) 4-methyl-2-nitro-5-oxohept-3-enal
N2O N2O3 N2O4
(B) 4-methyl-5-oxo-2-nitrohept-3-enal
O O
N –O– N (C) 4-methyl-6-nitro-3-oxohept-4-enal
O O (D) 6-formyl-4-methyl-2-nitrohex-3-enal
N2O5
Official Ans. by NTA (C)
11. Which of the following oxoacids of sulphur
contains “S” in two different oxidation states? Allen Ans. (C)

(A) H2S2O3 (B) H2S2O6 Sol.

(C) H2S2O7 (D) H2S2O8

Official Ans. by NTA (A)
Allen Ans. (A)
4-Methyl-6-nitro-3-oxohept-4-enal

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14. The major product (P) of the given reaction is CH3 CH2–Cl
(where, Me is –CH3) Cl2 / CN

Br Br

CH2–CN CH2–COOH
H3O+
(A)
Br Br
16. Isobutyraldehyde on reaction with formaldehyde
(B)
and K2CO3 gives compound „A‟. Compound „A‟
reacts with KCN and yields compound „B‟, which
(C) on hydrolysis gives a stable compound „C‟. The
compound „C‟ is :

(D)
Official Ans. by NTA (C) EN (A)
Allen Ans. (C)
Sol.
(B)

Me OH Me OH2
Me H
+
LL
Me
Me Me H2 O
(C)
Me Me Me Me Me O
H3 C
Me
1,2-Methyl shift H
+

Me Me
Me H3 C O
A

(i) Cl2 , 
15. A    4-Bromophenyl acetic acid. (D) HO
(ii) CN
(iii) H 2O/H  Official Ans. by NTA (C)
In the above reaction „A‟ is Allen Ans. (C)
Sol.

O
CH3 O H3C O
K 2CO3 H–C –H
(A) (B) CH3–CH–C–H Base CH3 – C – C – H

H3C O H3C O–
(C) (D) CH3 – C – C – H
KCN
CH3 – C – CH – CN
Official Ans. by NTA (C) CH2–OH CH2–OH
Allen Ans. (C) O
HO H3C OH
Sol. H3C H3 O+
O CH3 – C – CH – COOH
H3C CH2–OH
Stable product

4
17. With respect to the following reaction, consider the 19. When sugar „X‟ is boiled with dilute H2SO4 in
given statements : alcoholic solution, two isomers „A‟ and „B‟ are
formed. „A‟ on oxidation with HNO3 yields
HNO saccharic acid where as „B‟ is laevorotatory. The
 3
H SO , 288k
 products compound „X‟ is :
2 4

(A) o-Nitroaniline and p-nitroaniline are the (A) Maltose (B) Sucrose
predominant products
(C) Lactose (D) Strach
(B) p-Nitroaniline and m-nitroaniline are the
predominant products Official Ans. by NTA (B)
(C) HNO3 acts as an acid Allen Ans. (B)
(D) H2SO4 acts as an acid H
Sol. C12H22O11  H2O  
+
C6H12O6  C6H12O6
(A) (A) and (C) are correct statements. [] = 66.6° D-Glucose D-Fructose
(B) (A) and (D) are correct statements. [] = +52.7° [] = –92.2°
(C) (B) and (D) are correct statements. (A) (B)
(D) (B) and (C) are correct statements. CHO COOH
Official Ans. by NTA (C) H OH H OH
Allen Ans. (C) HO H HO H
HNO
NH2 NH2 NH2 H OH H OH
3

NH2 NO2 H OH H OH
HNO3 EN
+ +
H 2SO4
CH2OH COOH
NO2
NO2 Sachharic acid
Sol. 2% 47% 51%
20. The drug tegamet is :

HNO3  H2SO4  NO 2
Base Acid

18. Given below are two statements, one is Assertion

LL
(A) and other is Reason (R).
Assertion (A) : Natural rubber is a linear polymer (A)
of isoprene called cis-polyisoprene with elastic CH(NO2 )
properties. NMe2 S
Reason (R) : The cis-polyisoprene molecules O N NHMe
(B) H
consist of various chains held together by strong
A

polar interactions with coiled structure.

In the light of the above statements, choose the
correct one from the options given below :
(A) Both (A) and (R) are true and (R) is the correct (C)
explanation of (A)
(B) Both (A) and (R) are true but (R) is not the
correct explanation of (A).
(C) (A) is true but (R) is false.
(D) (A) is false but (R) is true.
Official Ans. by NTA (C)
(D)
Allen Ans. (C)
Official Ans. by NTA (C)
Sol. Natural rubber is linear polymer of isoprene (2-
methyl-1,3-butadiene) and is also called cis-1,4- Allen Ans. (C)
polyisoprene. The cis-polyisoprene molecules Sol. Tegamet is the brand name of Cimetidine
consists of various chains held together by weak N CH3 CN
Vander Waal‟s interactions and has a coiled N
structure
N S N
H NHCH3

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 SECTION-B 4. For the given reactions
1. 100 g of an ideal gas is kept in a cylinder of 416 L Sn2+ + 2e–  Sn
volume at 27°C under 1.5 bar pressure. The molar
mass of the gas is ______ g mol–1. (Nearest Sn4+ + 4e–  Sn
integer) (Given : R = 0.083 L bar K–1 mol–1)
o
The electrode potentials are; ESn 2 = –0.140 V
Official Ans. by NTA (4) /Sn
o
Allen Ans. (4) and ESn 4
/Sn
= 0.010 V. The magnitude of
100 standard electrode potential for Sn4+/Sn2+ i.e.
Sol. 1.5  416   0.083  300
M o
ESn is ______ × 10–2 V. (Nearest integer)
4
M = 3.99 /Sn 2 

Ans. 4 Official Ans. by NTA (16)

2. For combustion of one mole of magnesium in an Allen Ans. (16)
open container at 300 K and 1 bar pressure, C HΘ
= –601.70 kJ mol–1, the magnitude of change in Sol. Sn2  2e  Sn G10  2  0.140  F
internal energy for the reaction is _____ kJ. Sn4  4e  Sn G02  4  0.01  F
(Nearest integer)
_____________________________________
(Given : R = 8.3 J K–1 mol–1)
Sn4  2e  Sn2 G30  2  E0Sn 4 /Sn 2  F
Official Ans. by NTA (600)
Allen Ans. (600) EN G30  G02  G10

1 –2 × E0 × F = –(0.04 + 0.28) × F
Sol. Mg(s)  O2 (g)  MgO(s) E0 = 0.16 volt = 16 × 10–2 V
2
H  U  ng RT Ans 16
1 5. A radioactive element has a half life of 200 days.
601.70  103  U   8.3  300
2 The percentage of original activity remaining after
601.70kJ  U  1.245kJ
LL
83 days is ______. (Nearest integer)
U  600.455kJ
(Given : antilog 0.125 = 1.333, antilog 0.693 =
Ans. 600 4.93)
3. 2.5 g of protein containing only glycine (C2H5NO2)
is dissolved in water to make 500 mL of solution. Official Ans. by NTA (75)
The osmotic pressure of this solution at 300 K is
A

Allen Ans. (75)

found to be 5.03 × 10–3 bar. The total number of
glycine units present in the protein is ____ t1/2 A 0
–1 –1 Sol. t log
(Given : R = 0.083 L bar K mol ) 0.3 A t
Official Ans. by NTA (330)
200 A 0
Allen Ans. (330) 83  log
0.3 A t
Sol.   CRT
A 0
5.03 103  C  0.083  300 0.125  log
A t
C  0.202 103 M
A 0 4
Moles of protein = 0.202 × 10–3 × 0.5  1.333 
A
 t 3
= 10–4 × 1.01
2.5 A t 3
1.01  104    100   100  75%
M A 0 4
M(molar mass of protein) = 24752
Ans. 75
24752
 No. of glycine units =  330.03
75

6
6. [Fe(CN)6]4– Official Ans. by NTA (46)
3–
[Fe(CN)6] Allen Ans. (46)
[Ti(CN)6]3– 0.793
Sol. Mole of CO2 = Moles of C =
[Ni(CN)4]2– 44

[Co(CN)6]3– 0.793
Weight of „C‟ =  12  0.216 gm
44
Among the given complexes, number of
paramagnetic complexes is _____. 0.442
Moles of „H‟ = 2
18
Official Ans. by NTA (2)
0.442
Allen Ans. (2) Weight of „H‟ =  2  1  0.049 gm
18
Sol. [Fe(CN)6]4– Diamagnetic
 Weight of „O‟=0.492–0.216–0.049= 0.227 gm
[Fe(CN)6]3– Paramagnetic (1 unpaired electron)
0.227
[Ti(CN)6]3– Paramagnetic (1 unpaired electron) % of ' O'   100  46.13%
0.492
[Ni(CN)4]2– Diamagnetic Ans. 46
3–
[Co(CN)6] Diamagnetic 9. The major product of the following reaction
Ans. 2 contains _______ bromine atom(s).
7. (a) CoCl3·4 NH3
(b) CoCl3·5NH3
EN
(c) CoCl3·.6NH3 and
(d) CoCl(NO3)2·5NH3
Number of complex(es) which will exist in cis- Official Ans. by NTA (1)
LL

trans is/are Allen Ans. (1)

Sol.
Official Ans. by NTA (1)
Br
Allen Ans. (1)
Sol. (a) CoCl3·4 NH3 = [Co(NH3)4 Cl2]Cl
A

Can exhibit G.I. cc

(b) CoCl3·5NH3 = [Co(NH3)5 Cl]Cl2
O
Can‟t exhibit G.I.
No. of Br atoms = 1
(c) CoCl3·.6NH3 = [Co(NH3)6]Cl3 10. 0.01 M KMnO4 solution was added to 20.0 mL of
Can‟t exhibit G.I. 0.05 M Mohr‟s salt solution through a burette. The
(d) CoCl(NO3)2·5NH3 = [Co(NH3)5 Cl](NO3)2 initial reading of 50 mL burette is zero. The
OR volume of KMnO4 solution left in the burette after
the end point is _______ mL. (nearest integer)
= [Co(NH3)5 (NO3)]Cl(NO3)
Official Ans. by NTA (30)
Both can‟t exhibit G.I.
Allen Ans. (30)
8. The complete combustion of 0.492 g of an organic
Sol. N1 V1  N2 V2
compound containing „C‟, „H‟ and „O‟ gives
0.01 × 5 × V1 = 0.05 × 1 × 20
0.793g of CO2 and 0.442 g of H2O. The percentage
V1 = 20 ml used
of oxygen composition in the organic compound is
 Volume left = 50 – 20 = 30 ml
____________. (nearest integer)