FINAL SOLUTION

MASTER FOR
JEE MAIN

BY
JITENDRA HIRWANI

SAMPLE MOCK TEST

PAPER - 1

ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING

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Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA FINAL SOLUTION MASTER FOR JEE MAIN BY J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

1. The composition of a sample in Sn4.44O8. Calculate the ratio of Sn+4 to Sn+2.

(A) 2 (B) 4 (C) 6 (D) 1

2. The ratio of the energy of the electron in ground state of hydrogen atom to that of the electron in the first excited
state of Be3+ is
(A) 1 : 4 (B) 1 : 8 (C) 1 : 16 (D) 4 : 1

3. In the following reaction :

B(OH)3 + H2O  [B(OH)4]– + H+
(A) B(OH)3 is a Lewis acid (B) B(OH)3 is a Lewis base
(C) B(OH)3 is amphoteric (D) None is correct

4.

I A
Two samples A and B of an ideal gas, initially at same temperature and pressure, are compressed from volume V to
V/2, isothermally for A and adiabatically for B. The final pressure of A will be :

D
(A) Greater than that of B (B) Less than that of B
(C) Twice that of B (D) Equal to that of B

N
5. The pair of amphoteric hydroxide in :

I
(A) Al(OH)3, LiOH (B) Be(OH)2, Mg(OH)2 (C) B(OH)3, Be(OH)2 (D) Be(OH)2, Zn(OH)2

Given at 150ºC for the reaction PCl5(g)  PCl3 (g) + Cl2(g) equilibrium moles for PCl5 , PCl3 and Cl2 respectively are

S
6.
a, b & c mol. At same temperature volume is increased then at new equilibrium select correct option(s) :
[ increases decreases ]
PCl5 PCl3 Cl2

O
(A) Concentration   
(B) Partial pressure   
(C) Concentration   

O
(D) Partial pressure   

T
7. Four rubber tubes are filled with H2, O2, N2 & He respectively. The tube which will require to be reinflated (refilled)
firstly is -
(A) H2 filled tube (B) O2 filled tube (C) N2 filled tube (D) He filled tube

8.

E
Select correct statement(s).
(A) Li2CO3 decomposes into oxides while other alkali carbonates are thermally stable.
(B) LiCl is predominantly convalent
(C) Li3N is stable
(D) All of the above

9. Assuming 2s-2p mixing is not operative, the no. of paramagnetic species among the following are Be2, B2, C2, N2, O2,
O2+, NO:
(A) 1 (B) 2 (C) 3 (D) 4

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ETOOSINDIA FINAL SOLUTION MASTER FOR JEE MAIN BY J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

10. Calculate the density of NaCl type ionic solid AB (MW = 60) in gm/cm3 if shortest distance between two nearest
neighbours is 100 pm & solid having 20% schottky defect (NA = 6 × 1023)
(A) 10 (B) 20 (C) 30 (D) 40

11. The kinetic data recorded at 278 K for the reaction

NH4+(aq) + NO2– (aq)  N2(g) + 2H2O(l) is

+ -
Rate of
Set no. [NH4 ]/M [NO2 ]/M -1
reaction MS
-6
1 0.24 0.10 7.2×10
-6
2 0.12 0.10 3.6×10

A
-6
3 0.12 0.15 5.4×10

12.
The kinetic rate expression and the unit of rate constant (k) of the above reaction are respectively :
(A) k[NH4+] [NO2–] and Ms–1
( C) k[NH4+] [NO2–] and M–1s–1
(B) k[NH4+] and s–1
(D) k[NO2–] and s–1

D I
Which of the following graph correctly illustrate the dependence of the cell voltage, Ecell, on the pH for the reaction,

N
2Ag+(aq) + H2(g)  2Ag(s) + 2H+(aq)

I
Assume the silver ion remains constant at, [Ag+] = 1.0 M and the H2 pressure remains constant at 1 atm

S
E cell

E cell

O
(A) (B)

TO
E cell
E cell

E
(C) (D)

13. Which of the following will have two stereoisomeric forms ?

(I) [Cr(NO3)3(NH3)3] (II) K3[Fe(C2O4)3] (III) [CoCl2(en)2]+ (iv) [CoBrCl(Ox)2]3–
(A) I only (B) I and II (C) III and IV (D) All of these

14. 2 g of an organic compound is burnt completely in a bomb calorimeter at 298 K. The final temperature of calorimeter
was found to be 298.5 K. Calorimeter constant is 200 JK–1 and molar mass of the compound is 50g. What is the
enthalpy of combustion per mol of the compound in kJ unit ?
(A) 2.5 kJ (B) 10 kJ (C) 15 kJ (D) 20 kJ

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Kota, Rajasthan – 324005 Mob. : 9214233303
 ETOOSINDIA FINAL SOLUTION MASTER FOR JEE MAIN BY J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

15. When H2O2 is added to an acidified solution of K2Cr2O7 then :

(A) solution turns green due to formation of Cr2O3
(B) solution turns yellow due to formation of K2CrO4
(C) a blue coloured compound CrO(O2)2 is formed
(D) solution gives green ppt of Cr(OH)3

16. The solubility of AgBr in water and in 0.01M CaBr2, 0.01M KBr, and 0.05M AgNO3 be S1, S2, S3 and S4 respectively,
give the relation of solubilities.
(A) S1 > S2 > S3 > S4 (B) S1 > S3 > S2 > S4 (C) S2 > S1 > S3 > S4 (D) S4 > S3 > S1 > S2

A
17. Na 2CrO 4   Na 2SO4  B  C  NaCl
(Orange) (Orange red)

I
A, B and C respectively are :
(A) K2SO4 , K2CrO4 and K2Cr2O7 (B) K2SO4 , Na2CrO4 and Na2Cr2O7
(C) H2SO4 , NaCrO2 and K2Cr2O7 (D) H2SO4 , Na2Cr2O7 and K2Cr2O7

18.
94 respectively. The %degree of association of compound X will be

N D
A compound X dimerises in water, if its observed molecular weight and theoretical molecular weight are 161.84 and

I
(A) 84 (B) 60 (C) 80 (D) 45

19. Which is INCORRECT statement ?

S
(A) Polling process is used to remove Cu2O from Cu
(B) Cupellation process is used to remove traces of lead from silver

O
(C) Liquation process is used for purification of metals whose melting point are higher than those of impurities
(D) Extraction of lead from galena involves roasting at moderate temperature followed by self reduction at high
temperature

20.

O
The incorrect statement pertaining to the adsorption of a gas on a solid surface is :
(A) Adsorption is always exothermic

T
(B) Physisorption may transform into chemisorption at high temperature
(C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature

E
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of
activation.

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