UT-5A_Paper-1 (Code-A) JEE (Advanced) CoE (XII)-2022-23

10. Answer (25) 1  

I E B
di d 0
VB  i  2   1  2  3i   VA … (i)
dt dt B 2c

i= 5e–t … (ii) 0
11. Answer (02) 15. Answer (A)
iAR = iB(2R) 16. Answer (C)
 iA = 2iB Solutions for Q 15 and Q 16
1 2 q
Li A BlV – iR – 0 … (i)
UA 2
  2 C
UB 1
 2L  iB
2
–ilB = Ma … (ii)
2
12. Answer (08) Differentiate (i) and combine with (ii)

di 1  1 B2l 2 
    i
dt R C M 

17. Answer (C)

18. Answer (A)
Solutions for Q 17 and Q 18

 Vnet  400 2 Inet

13. Answer (02)
After shorting the battery
Reff = 5R/3
L 3L
 
Reff 5R

14. Answer (75)

19. Answer (A, D)
CaCO3 and MgC2O4 dissolve in dilute HCl
BaCrO4 dissolves in HCl to form an orange
coloured solution.
BaSO4 can only dissolve in conc. H2SO4.
[Because acidic strength of H2SO4 > acidic
strength of HCl] (aqueous medium)
20. Answer (A, D)
Cr2 O 72 (acidified) + H2O2
PART – II : CHEMISTRY
Oxidation state of Cr in CrO5 is ‘+6’
It has two peroxy linkages
Magnetic moment of Cr2O3
 3  3  2
 3.87 B.M
21. Answer (C)
Stereoisomers of [CrBr(NO2)(en)2]+
 CrO5(A)


decomposes in aquous solution
 Cr2O3(B) + O2
Structure of CrO5

Total 3 stereoisomers (2 geometrical isomers)

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JEE (Advanced) CoE (XII)-2022-23 UT-5A_Paper-1 (Code-A)

Similarly, 3 stereoisomers will be shown by [Cr X=4

Br(ONO)(en)2]+, which is a linkage isomer of the Representing (gly) as (XY), the stereoisomers

complex containing NO ligand
2 are :
22. Answer (C, D)
The possible formulae of complexes could be
[CoCl2(H2O)4]Cl. H2O (I)
and (CoCl(H2O)5]Cl2 (II)
2 m mol of complex (I) gives 2 m mol of Cl– ions
in solution
As both the isomers are optically active total 4
 Volume of 0.2 N AgNO3 needed
stereoisomers can be obtained
2
=  10 mL Y=4
0.2
(X + Y) = (4 + 4) = 8
For complex (II), volume of 0.2 N AgNO3 needed
2 2
=  20 mL 26. Answer (02)
0.2
X = 5(BaCO3, PbSO4, CaC2O4, Mg(OH)2,
23. Answer (A, C)
CH3COOAg)
White Solid ‘X’ is NaHCO3
Y = 3(BaCO3, CaC2O4 and CsHCO3 liberate a

2NaHCO3   Na2CO3 + H2O + CO2
non-polar acidic gas (CO2) on complete thermal
33.6
 0.4 moles 0.2 moles 0.2 moles 0.2 moles decomposition)
84
x – y = 5 – 3 = 2
= 21.2 g = 3.6 g = 8.8 g
27. Answer (04)
(Q) (P)
X=4
Na2 CO3 + BaCl2  2NaCl + BaCO3   
white ppt
(SrCl2, BaCl2, CaCl2 and Pb(CH3COO)2 form
 Z
white precipitate with aqueous Na2CO3)
The gas ‘P’ cannot be oxidised further. Y=7
Therefore, no change is observed in the orange 28. Answer (02)
coloured acidified dichromate solution. Fe+2 is green in colour
24. Answer (A, B, D) 4
[Fe(H2O)6]2+ = 3d6 = t 2g eg2
All elements of lanthanoid series except Pm are
H2O is a weak field ligand
not radioactive. All other statements are based
 CFSE = –0.40 (no contribution of pairing
on theory and are correct.
energy)
25. Answer (08)
m = 0.4
As in complex (I) a chiral ligand is present, total
n=0
4 stereoisomers will be formed. If the ligand is
29. Answer (33)
considered to be of (AB) type, the geometrical
[Co(Br)(Cl)(NH3)4]Cl + AgNO3
isomers are:
(P)
 AgCl() (white ppt. which dissolves in aq.
ammonia)
27.8
Moles of P taken =  0.1
[Where M represents the central atom and (AB) 278
represents a chiral bidentate ligand]  Mass of AgCl formed = 0.1 × 143.5
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UT-5A_Paper-1 (Code-A) JEE (Advanced) CoE (XII)-2022-23

= 14.35 g Number of possible linkage isomers of ‘X’ is ‘3’

Similarly, mass of AgBr formed This is because ‘C’ has the three possible donor
= 0.1 × 188 sites. Considering CN– as a monodentate ligand.
= 18.80 g c=3
 X + Y = 14.35 + 18.80 a+b+c=5
= 33.15 g 33. Answer (B)
30. Answer (15) 34. Answer (B)
Solutions of Q. 33 and Q. 34

Maximum number of atoms is one plane = 9 = x

Number of geometrical isomers of
{Cr(en) (Pn) (NO2)2] = 6 = y

(E) must contain CuSO4 as CuSO4 + BaCl2 (aq)

gives white ppt. of BaSO4 (insoluble in
HNO3)
x + y = 15
35. Answer (B)
31. Answer (50.00)

36. Answer (C)
FeSO4 .7H2O   FeSO4  7H2O
P  Q Solutions of Q. 35 and Q. 36

 Fe H2 O 5 NO  SO 4
FeSO 4  NO  H2O   acceptance tendency:
 Q R  PF3 > CO (given)
2FeSO4 
 Fe2O3   SO2  SO3   CO bond order will be higher in [Ni(CO)3(PF3)]
Q S  A B 
due to lesser magnitude of back bonding of
Sum of molar masses = 278 + 152 + 160 + 64 +
central metal with C.
80 = 734 g
Also -acceptor tendency of
32. Answer (05.00)
PF3 > PCl3 > PMe3
‘X’ is Na4[Fe(CN)5NOS]
 The order of stretching frequency of CO bond is:
Oxidation state of Fe is (+2)
[Mo(CO)3(PMe3)] < [Mo(CO)3PCl3] <
 Magnetic moment of X = 0 BM
[Mo(CO)3(PF3)]
a=0
[Fe(CO)4]–2 has the lowest CO bond order
Number of d-orbitals involved in hybridisation of
among the complexes given in Q 36 as the
central atom of ‘X’ is 2
oxidation state of central metal is (–2) resulting
b=2
in greater extent of back bonding with C.

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