Bharti Vidya Mandir High School,Barwala

1st Semester Exam Sep,2023

Class-12th
Sub:-Chemistry
Time:-3.00Min M.M70

Q:-1. (i) which one is coloured . a) [ Ti(H2O)6 ]3+ b) Cu2I2

3+ 2+
c) [ Sc (H2O)6] d) [ Zn(NH3)6 ]
(ii) If rate of reaction is independent concentration of
reactonts then reaction is a) zero order
b) first order c) second order d) none
iii) SI unit of molar conductance
a) Sm-1 mole-1 b) Sm3mole-1 c) Sm-2mole d) Sm2mole-1
iv) A primary Alkyle Holide would prefer to undergo
a) Sn 1 b) Sn2 c) elimination d) none
V) The oxidation number of cobalt in K [Co(Co)4 ] is
a) +1 b) -1 c) +3 d) -3
Vi) which element does not show variable oxidation state
a) Sc b) V c) Fe d) Hg
Vii) Which of the following oxidation state is most common
among the Lanthanoids ?
a) +4 b) +3 c) +2 d) +5
-4 -1 -1
Viii) K= 2.6 x 10 L mol Sec order of reaction is
a) First b) zero c) second d) none
2+ 2+
Ix) For the given cell reaction Mg Mg Cu Cu
a) Mg as cathode b) Cu as cathode
C) Cu is oxidizing agent d) none of the above.
X) Which is strongest legand
a) - OH b) NCS- c) CN- d) CO
Xi) In the following complexes which metal has zero oxidation
number ?
a) . [ Fe(CN)6 ]3- b) [ CuCl4 ]2- c) [ Ni(CO)4] Q:-10. Explain [Co(NH3)6]3+ is an inner orbutal complex
d) K4 [Fe(CN)6] whereas [ Ni(NH3)6]2+ is an outer orbutal complex ?
Xii) Vant hoff factor (i) for K4[Fe(CN)6] (3)
a) 6 b) 5 c) 4 c) zero Q:-11. Write ionic equations for the reaction of acidfied
xiii) Magnetic moment of 5c ion 3+ KMnO4 with following :-
a) 1.73 BM b) 0 BM c) 5.92 BM d) 2.83 BM i) Oxalic Acid ii) H2S iii) Sulphate ion (SO32-) (3)
Xiv) Coordination number of cr in [ Cr(NH3 )4 Cl2 ]Cl is Q:-12. Give mechonism CH3 -- CH -- CH -- CH3HBr→
a) +6 b) +1 c) +3 d) zero CH3 OH
Xv) Which is Amludentate ligand (3)
a) Co32- b) NO-3 c) CN- d) Br- Q:-13. How will you bring about following conversations ?
Q:- 2. The rate constant of a reaction at 500 K 700 K are 0.02 sec - a) Tolune to Benzyl Alcohal
1
and 0.07 sec-1. Calculate the value of Ea ? (2) b) But -1 - ene to But - 2 - ene
Q:-3. Complete the following chemical equation :- c) Tort - Butyl BRomide to Isolwtyl Bromide (3)
i) MnO4- + I- + H+ → Q:-14. (a) A first order reaction takes 40 minute for 30%
ii) Cr2O72- +Sn2+ + H+→ (2) decomposition. Calculate T1/2 (2)
Q:-4. Silver atom has completely filled d orlutals (4d ) in its 10 (b) What is meant by Collision frequency ? (1)
ground state . How can you say that it is a tronsition Q:-15. The Hexaquamanganese (II) ion contain five
element ? (2) UnPaiRed electron . Explain using CFSE . (3)
Q:-5. Transition metals generally form coloured Q:-16. Write the following reactions :-
compounds . a) Swarts reaction b) Sondmeyer reaction
Give reasons ? (2) c.) Wurtz - fittig reaction (3)
Q:-6. 4g NaOH ( molar mass=40) dissolved in 500 ml of Q:-17. Explain Henry’s Law . Write one Application (3)
solution ? Calculate molarity ? (2) Q:-18. What is Lonthanoid Contraction . Explain its reasons
Q:-7. Number of faradays required to reduce 5 mole of and consequences ?
Mno-4 into Mn2+ ? (2) (5)
Q:- 8. Calculate E cell :- Cu Cu Ag Ag
0 2+ + Q:-19. Explain SN1 SN2 reactions with example . (5)
Q:-20. (a) IUPAC name :- [ Co (NH3)5Br ]So4
Given :- Cu2+ Cu = 0.34 V (2) K3[ Cr(C2O4)3 ] K3 [ Fe (CN)6 ] (3)
Ag Ag+ = -0.80 V
Q:-9. Write electron configuration of (b) The boling point of benzene is 353.23K . When
a) Fe2+ b) Cr (2) 1.80g of non - volatile solute was dissolved in 90g of
benzene the boiling point is raised to 354.11K .
Calculate the molar mass of solute . Kb Benzene is
2.53K Kg mole-1 .