5.The reaction below was studied at 250°C.

PCls(g) :;;;:= PCh(g) + Cb(g)

At equilibrium, the partial pressures of the gases are as follows: PCls = 2.0 x 10-2 atm, PCh = 4.2 x 10-2 atm,
and Cb = 4.2 x 10-4 atm. What is the value of Kp for the reaction?

@) -:=_ ['-1/~. '/-I~>.. Ci./,').. V.)D -'f

"J...,o ";. I () -?..

6.At 2010 K, the equilibrium constant, Kc, for the following reaction is 4.0 x 10-4.

If the equilibrium concentrations ofN2 and 02 are 0.25 mol/L and 0.33 mol/L, what is the equilibrium
concen(ration otKCl?' [IVOJ ~.
N>- + O,. -:;t; 'J..NO )~'- =. [rv1-] [p.._J
:r 1,
C,
E o, 'lS 4·0 1'10_.., ::c [o~S] fp.3jj
7.We place 0.064 mol N2O4(g) in a 4.00 L flask at 200. After reaching equilibrium, the concentration ofNO2(g) is 0.0030
M. What is Kc for the reaction below? [ C). 0 0 3 0 1- J
cl_)( ::. 0 I OO 3 M
0
N2O4(g) :;;;:= 2 NO2(g) kc.. : :.
0. 0 I Li ,;
o, o I b f'I' o )< ~ O . 0 O \ ~ fl\ ,,~--·---------~~..- ~
-x +ix o.01G-0,oo\S-=-O.o\Y~ r<c.,.,=- G,~XID- ·
E o,o\G- X a__ X ·-~--------

8.A mixture of 0.200 mol NO and 0.200 mol CO2 is placed in a 1.00 L flask and allowed to reach equilibrium at a given
temperature. Analysis of the equilibrium mixture indicates that 0.067 mol of CO is present. Calculate Kc for
the reaction.

NO(g) + CO2(g) :;;;:= NO2(g) + CO(g)

[O~OG 7] ~
0,100 0,'J-0() 0 0 t< =Cr [o, 13 3]~
-x
-x .fX +.x
X X
. 100 -.:x o. 'l_Otr }(
E o. r-,
X= 0, 0 b ,,

o , 'l,D O - o; o{; 7 =- 0, 13 J
111111

CHM152 Quiz 3a Spring 2019 25 Pts ~:1-J:.-----

Name:. _ _.....:.k----=.....:e=.
Show all work to receive credit. lf

1. Write the expression for Kc for the reaction below.

2.Write a balanced chemical reaction which corresponds to the following equilibrium constant expression.

JV. o Br [J)

3 .For the following reaction, p~ 'T)

k ~ __:~2.L-
2 S03(g) ~ 2 S02(g) + 02(g) pt ? Sor
1 the equilibrium constant, Kp, is 1.32 at 627°C. What is the equilibrium constant for the reaction below?

v _ P~o:t it\
7\p - - - ~
,, ~ f~o)

::::@
4.The oxidation of sulfur dioxide produces sulfur trioxide.

2 S02(g) + 02(g) ~ 2 S03(g)

Calculate the value of Kp, given that Kc for the reaction is 2.3 x l 04 at 999 K. (R = 0.08206 L·atm/mol ·K)
An
l<r~l(_(RT) -\
~ ~
J,.,3 )(/ o ( 0, 0 S ~) ' 'I'! °I/