UT-5A_Paper-1 (Code-A) JEE (Advanced) CoE (XII)-2021-22

19. Answer A(R); B(Q, R); C(P, S, T); D(P, S, T)

1 (A)
Eind = BL2res
2

1
 
2
V0  VB  B L 2  BL2
2
V
I 2
(A) VO  VB  BL2 , VO  VA  2BL2 5

 VA  VB  BL2 V 5
Z 
I 2
1
(B) V0  VB  BL2 , V0  VA  BL2 50
2 I 2  10 2
5
1
 VA  VB  BL2 (B) Z = 5
2
V 50 2
1 L2 BL2 I   10 2
(C) V0  VA  B  Z 5
2 4 8
1 3
V0  VB  B L2  VA  VB  BL2
2 8
(C)
1
(D) V0  VA  BL2
8

BL2 I V 2
V0  VB 
2
V 1
3 Z 
VA  VB  B L2 I 2
8
20. Answer A(P, S); B(Q, S); C(R, T); D(R, T) 100  2
I  100 2 A
1
PART – II : CHEMISTRY
21. Answer (3) [Fe(H2O)6]2+ = 3d6 = t 42g e2g
EAN of [Mn(CO5] = 35 (paramagnetic)
H2O is a weak field ligand
Hence to make EAN = 36, it has to gain an
 CFSE = –0.40 (no contribution of pairing
electron can behave as an oxidising agent.
energy)
Both [Mn2(CO)10] & [Co2(CO)8] have M–M bond
m = 0.4
22. Answer (1)
n=0
Cu2+ + K4[Fe(CN)6]  Cu2[Fe(CN)6]
27. Answer (3)
   Chocolate brown ppt 4 6
23. Answer (3) 2MnO2  4KOH  O2  K 2MnO4  2H2O

d, e, g show John-Teller Distortion Equivalent wt of MnO2 =

87
 43.5
2
24. Answer (4)
 43.5 × 2.3 × 10–2  1
Na2C2 O 4  Na2 CO3 + CO2 + CO + C
MnO2 is amphoteric

Ag2C2 O 4  2Ag + CO 2 28. Answer (1)
25. Answer (4) (i) (v) (vi) are optically active
Zn(OH)2, Al(OH)3, Pb(OH)2 and Sn(OH)2 are 29. Answer (A, D)
soluble in excess of NaOH. [Co(H2O)6]3+ & K2(NiF6] both have d2sp3
26. Answer (2) hybridisation)
Fe+2 is green in colour

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JEE (Advanced) CoE (XII)-2021-22 UT-5A_Paper-1 (Code-A)

30. Answer (B, C) Linkage isomers may have different physical

Metal X is Zinc properties but have same colligative properties
31. Answer (A) 36. Answer (A, B, C, D)
PbO2 is a powerful oxidising agent, hence can
oxidise Mn2+ to MnO 4 .

H2O2 + Mn2+  Mn+4 + OH–

32. Answer (A, B, D)
Compound X is H2S 37. Answer (A, B, C)

H+


 Ba  OH2  Ba  SH2
BaS  H2O  CO32 
 CO2
  
both are water soluble
H+
SO32 
 SO2
Cl2  H2S  S   2HCl
 White ppt  H+
S2O32 
 SO2  S 
CdS is yellow in colour
38. Answer (A, B)
33. Answer (B, C)
Greater is the strength of ligand, greater will be
Eu+2 = 4f7
0, light of greater frequency is absorbed
Gd+2 = 4f75d1
39. Answer A(S); B(R, T); C(Q); D(P)
34. Answer (A, C, D)
A is [Co(NH3)4(H2O)2]Cl3
X is [Cr(Py)2(H2O)Cl3].H2O
Cis-trans isomerism is shown by ‘A’
On reaction with Conc. H2SO4 only one H2O
molecule will be dehydrate Cr+3 has d3 Co3+ = 3d6 = t 62g eg

configuration. NH3 will behave as strong field ligand

35. Answer (A, C) Complex B is [Co(NH3)4Cl2]Cl
Ma5b type of complex cannot show geometrical 40. Answer A(R, S); B(R); C(T); D(P, Q, S, T)
isomerism. If ligand is opticalty active, two G
More negative the value of , greater will be
enantiomers will have same physical properties. F
the stability of that oxidation state.

PART – III : MATHEMATICS

41. Answer (5)
 f' (0) = 0, we get c = 0
 1  x 100 100 x 99 
I =  e x
  dx  1 
 1 x
100
1  x100  1  x 200  Thus, f(x) =  f '( x ) dx =   tan x  3 tan
3
x  4 x  dx


d  1  x100  100 x 99 = log |sec x| +

1
 tan x (sec2x – 1)dx + 2x2 + k
Now   
dx  1  x100
3
 1  x100  1  x 200 2
1 tan x 1
= log |sec x| + – log|sec x| + 2x2 + k
1 3 2 3
We get k = 100 and m = –
2 Hence from f(0) = 0, we get k = 0
42. Answer (5) 2 1
f(x) = log |secx| + tan2x + 2x2
3 6
f '(x) =  f ''( x ) dx =  (sec x  4) dx
4

  1 2 1
f   = log 2 + 
4 3 8 6
=  [sec2x(1 + tan2x) + 4] dx
a = 3, b = 8, c=6
tan3 x
= tan x + + 4x + c
3

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