Page # 1 VICTORY BATCH

ARP - 4 [VICTORY BATCH]

CHEMISTRY
Duration : 1.15 Hours Max. Marks : 90
SECTION - A
1. Q.1 to Q.10 has four choices (A), (B), (C), (D) out of which only one option is correct & carry 3 marks each.
1 mark will be deducted for each wrong answer.
2. Q.11 to Q.15 has four choices (A), (B), (C), (D) out of which one or More than one option may be correct & carry 3 marks
each. No Negative Marking in this section
2. Q.16 to Q.19 are based upon a Paragraph. Each Question has four choices (A), (B), (C), (D) out of which only one is correct
& carry 4 marks each. No Negative Marking in this section
3. Q.20 contains 4 multiple choice questions. Each question has matching list. The codes of list have choices (A), (B), (C) &
(D) out of which only one is correct & carry 4 marks each. 1 mark will be deducted for each wrong answer.

SECTION - B
1. Q.1 to Q.5 are Numeric value type questions carry 5 marks each. No Negative Marking.

SECTION - A 3. Free expansion of vander waal’s gas takes

[STRAIGHT OBJECTIVE TYPE]
Q.1 to Q.10 has four choices (A), (B), (C), (D) place adiabatically. Select the correct state-
out of which ONLY ONE is correct & carry 3 ments
marks each. -1 Negative marking for each (i) Gas shows heating effect
wrong Answer.
1. The solubility of metal sulphides in (ii) Gas shows cooling effect
saturated solution of H2S {H2S = 0.1 M} (iii) If free expansion is carried out at in-
can be represented by
version temp then heating effect will be ob-
MS + 2H+ M2+ + H2S ;
served
2
[M ][H 2S]
K eq  (iv) Ssystem  0
[H  ]2
The value of Keq is given for few metal
suphide. If conc. of each metal ion in (A) i & iv only (B) ii & iii only
solution is 0.01 M, which metal sulphides (C) ii & iv only (D) ii, iii & iv only
are selectively ppt at total [H+] = 1 M in
saturated H2S solution.
Metal sulphides MnS ZnS CoS PbS
2 4. For a first order reaction : A(g)  2B(g)
Keq  [M ][H 2S] 3 × 1010 3 × 10–2 3 3 × 10–
[H  ]2 occurring at 1 bar pressure and 300 K. If
7
initial volume of container is V0 and vol-
(A) MnS, ZnS, CoS (B) PbS, ZnS, CoS
(C) PbS, ZnS (D) PbS ume after 20 minutes is V 20 then t 1/2

2. For the equilibrium SrCl2 · 6H2O(s) (in minute) will be :

SrCl2 · 2H2O(s) + 4H2O (g) the
equilibrium constant KP = 16 x 1012 atm4 V0 20 ln 2
at 10C. If one litre of air saturated with (A) ln (B)
water vapour at 10C is exposed to a large 2V0  V20 V0
ln
quantity of SrCl2· 2H2O(s), what weight of 2V0  V20
water vapour will be absorbed? Saturated 2V0
vapour pressure of water at 10C = 7.6 20 ln 2
(C) ln (D)
torr. 2V0  V20 V
(A) 6.4 mg (B) 3.25 mg
ln 0
V20
(C) 2.3 mg (D) 8.5 mg

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Page # 2 VICTORY BATCH

5. Which of the following will have three

stereoisomeric forms?
(i) [ Cr ( NO 3 ) 3 ( NH 3 ) 3 ]
(ii) K 3 [ Co (C 2 O 4 ) 3 ] (B) (P)

(iii) K 3 [ CoCl 2 (C 2 O 4 ) 2 ]
(iv) [CoBrCl ( en ) 2 ]
Select the correct option O OH
(A) (iii) and (iv) (B) (i), (iii) and (iv) O
(C) (iv) only (D) all four
(Q) (R)
6. Which of following molecule can show Lewis O
HOOC O
acidity.
(I) CO2 (II) Br2
(III) SnCl2 (IV) HF
(V) NMe3
Select the correct option
(A) III, IV (B) I, II, III (S)
(C) I, III, IV (D) II, III, V

7. Which is the correct sequence in the following

properties. For the correct order, mark (T), and
for the incorrect order mark (F) :
(a) Acidity order :
(C) (P)
SiF4 < SiCl4 < SiBr4 < SiI4
(b) Melting point :
NH3 > SbH3 > AsH3 > PH3
(c) Boiling point :
NH3 > SbH3 > AsH3 > PH3
(d) Dipole moment order :
NH3 > SbH3 > AsH3 > PH3 (Q) (R)
(A) FTFT (B) TFTF
(C) FFTT (D) FFTF

8. Which of the following option are correct : OH

HO

(S)
O
CHO

(D) (P)

(A) (Q)
O
O

(Q) (R)
O
(R) (S) HOOC O

(S)

(P)

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Page # 3 VICTORY BATCH

9. Match each of the compounds given in 

H
Column I with the reaction(s), that they (D)  (A)

can undergo, given in column II. 
Column I

(2,4-Di-nitrophenyl hydrazine)
(A)
Column II
(P) Formation of six member ring takes place
(Q) Final product is Ketone
(B)
(R) Final product formed will give positive
Tollen's test
(S) Final product formed will react with 2,4-
DNP.
(C)
In which of the following select the correct
set of option.
(A) (A) P, Q ; (B) Q; (C) P, Q; (D) P, S
(D) (B) (A) P, Q, R; (B) R; (C) P, S; (D) P, R
(C) (A) P, Q, S; (B) P; (C) P, Q, S;
Column II (D) P, Q, S
(p) Nucleophilic substitution (D) (A) P, R; (B) Q; (C) Q, R, S; (D) P
(q) Elimination
(r) Nucleophilic addition [MULTIPLE OBJECTIVE TYPE]
(s) Esterification with acetic anhydride Q.11 to Q.15 has four choices (A), (B), (C), (D)
(t) Dehydrogenation out of which ONE OR MORE THAN ONE is correct
& carry 3 marks each.
In which of the following select the correct
set of option. 11. A 2.5 gm impure sample containing weak
(A) (A) - p, q, t ; (B) - p, s, t ; monoacidic base (Mol. wt. = 45) is dissolved
(C) - r, s ; (D) - p in 100 ml water and titrated with 0.5 M HCl
(B) (A) - p, q, t ; (B) - r, t ; (C) - r, s ; th
(D) - q 1
when   of the base was neutralised the
(C) (A) - p, s, t ; (B) - p, s, t ; (C) - p,q ; 5
(D) - r
pH was found to be 9 and at equivalent point
(D) (A) - r ; (B) - p, s, t ; (C) - r, s, q ;
pH of solution is 4.5. Given: All data at 25º
(D) - s,t
C & log 2 = 0.3.
10. Column I
Select correct statement(s).
(A) Kb of base is less than 10–6
(B) Concentration of salt (C) at equivalent point
(A) HCN
LiAlH 4
 (A)    is 0.25 M
traces of KOH (C) Volume of HCl is used at equavalent point
is 100 ml
NaNO (D) Weight percentage of base in given
2  (C)
(B)   sample is 80%.
HCl
12. Select incorrect statement(s).
(A) Phenolphthalein is suitable indicator for
the titraction of HCl(aq) with NH4OH (aq).
NH OH H
(B)  (A) 
 2 (B) An aci d-base indicator i n a buffer
 solution of pH = pKln + 1 is ionized to the
extent of 90%
(B) LAH
 (C) (C) In the titration of a monoacidic weak
base with a strong acid, the pH at equivalent
1
O O point is always calculated by pH = [pKw –
2
|| || pKb – logC]
(C) CH 3  C  CH 2  CH 2  CH 2  C  H (D) When Na3PO4(aq) is titrated with HCl
(aq.), the pH of solution at second equivalent
–

HO

 (A) 1
point is calculated by [pKa + pKa ]
 2 1 2

Motion Education | 394 - Rajeev Gandhi Nagar | : 1800-212-1799 | url : www.motion.ac.in

Page # 4 VICTORY BATCH

13. Which of the following statements is/are

true NO2
(A) Sul phi d e i ons react with
Na2[Fe(NO)(CN)5] to form a purple coloured
compound Na 4 [Fe(CN) 5 (NOS)]. In the
reaction, the oxidation state of iron changes
(B) In B 2H6 vacant orbital take part in (A) X is
C O
hybridisation
(C) In B2H6, there are only 12 bonding CH3
electrons available
(D) Bond length of NO+ is less than in NO

NH2

(i) HNO3 /H2SO4 (i ) HNO 2

14.   P   
(ii) (NH4 )2 S (ii ) H2 O, 

(B) Y is
(i) NaOH, CO , 6 atm, 
(i ) Sn / HCl C O
Q 
2
 R    S
(ii) HCl (ii ) NaOH
Which of the following statement(s) for the CH3
above sequence of reactions is/are correct
O

NH2 (C) Z is N N C CH3

OH
(A) P =
NH2

(D) Z is N N OH

C O
(B) Q =
CH 3

[COMPREHENSION TYPE]
Q.16 to Q.19 are based upon a paragraph. Each
questions has four choice (A), (B), (C), (D) out of
which ONLY ONE is correct
(C) R =
Paragraph for question nos. 16 to 17
Some substances like water are unique in
their ability of acting both as an acid and a
base. In pure water, one H2O molecule
donates proton and acts as an acid and
another water molecule accept proton and
act as a base at the same time.
(D) S =
H2O(l) + H2O(l) H3O+(aq) + OH–(aq)
The ionic product of water is given as :
Kw = [H3O+] [OH–]
The value of Kw is 1.0 × 10–14 M2 at 298 K.
15. Identify the product in the given reactions Addition of acid or base in pure water will
: affect the equilibrium according to Le-
Chatelier's principle.
The pH of an aqueous solution is defined as
SOCl2 N2O5 (CH3)2CuLi negative logarithm to base 10 of the activ-
ity of hydrogen (or hydronium) ion.

+
16. The pH at which water is maximum dissoci-
+ -
Fe / H NaNO2 / H PhOH / OH ated at 298K is
X Y Z
(A) 2 (B) 7
(C) 10 (D) 14

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Page # 5 VICTORY BATCH

17. What is the ratio of pH of a solution con- [MATCH THE COLUMN TYPE ]
taining 1 mole of CH3COONa and 1 mole of Q.20 contains 4 multiple choice questions. Each
question has matching list. The codes of list
HCl per litre and the other solution contain- have choices (A), (B), (C) & (D) out of which
ing 1 mole of CH3COONa and 1 mole of only & carry 4 marks each. -1 negative
CH3COOH per litre? [pKa = 5] marking for each wrong Answer.
(A) 1 : 2 (B) 2 : 1 20. Column-I Column-II
(C) 5 : 2 (D) 1 : 1 (A) B2H6 (P) Planar shape
(B) I2Cl6 (Q) Non- planar shape
(C) Al2Br6 (R) Contains 3c - 4e– bond
Paragraph for question nos. 18 to 19 (D) [Pt2Br6]2– (S) Contains 2c - 2e– bond
An optical inactive compound (A), which
gives (+) iodoform test and gives coloured Select the correct option
compound with braddy's reagent. When it (A) (A) Q,S (B) P, R, S (C) Q, R, S (D) P, R, S
is treated with hydroxyl amine in mild acidic (B) (A) P,S (B) P, Q, R (C) P, Q, R (D) Q, R,S
(C) (A) Q,S (B) P, Q (C) P, Q, R (D) P, S
me di um . It p roduce s tw o di fferent
(D) (A) Q,S (B) P, S (C) Q, R (D) P, Q
compounds (B) & (C). Each when further
heated with conc.H2SO4 produces (D) & (E) SECTION - B
respectively. Further hydrolysis of (D) & (E) [NUMERIC VALUE TYPE]
both produces mixture of a carboxylic acid Q.1 to Q.5 are NUMERIC VALUE TYPE Questions.
and an amine. Acid produce by hydrolysis (The answer of each of the questions is
carry 5 marks each.
of (D) is most acidic among its isomers and 9
Keq.=2×10
the amine produce by hydrolysis of (E) is 1. 2A(g) + B(g) 3C(g)
least basic among its positional isomers. Initially only A & B are present in the
container & moles of A and B at t = 0 are 4
18. Identify (A) among the following.
& 2 respectively. If the concentration of A
O at equilibrium is p × 10–q then find p + q – 2
C–CH3 OH Given : Volume of container is 100 lit.

CH–CH3 2. Ammoni um carbamate di ssoc i ates as

(A) (B) CH3 NH2COONH4 (s) 2NH3 (g) + CO2(g). In
a closed vessel containing ammonium
CH3 carbamate in equil ibrium, ammonia is
added such that partial pressure of NH3 now
equals to the ori ginal total pressure.
OH
Calculate the ratio of total pressure now to
O CH–CH3 the original pressure as P/Q and give P + Q.
C–CH3
(C) CH3 (D) 3. How many of the following reagents would
cause symmetrical cleavage in diborane?
CH3
(CH3)3N, (CH3)3P, , , CH3NH2 ,
O S
19. Select incorrect statement.
(A) Acid produced by hydrolysis of D will (CH3)2NH, (C2H5)3N,
give effervescence of CO2 with NaHCO3 N
[If your answer is 2 then write the
faster than the acid produced by hydrolysis
answer as 0002.]
of E
(B) Base produced by hydrolysis of D will 4. Find the number of reagents which would
be more basic than the base produced by lead to unsymmetrical cleavage of diborane.
hydrolysis of E CH3NH2,NH3,(CH3)2NH, (CH3)3N, ,NaH
(C) Reaction involves formation B & C can O
also be carried out with NH2NH2.
(D) Reaction involves formation D & E can
also be carried out with PCl5.

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Page # 6 VICTORY BATCH

5. An organic compound (A) consists of C, H

and O gives a characteristic colour with ceric
ammonium nitrate. Treatment of (A) with
PCl5 gives (B) which reacts with KCN to from
(C). The re duct i on of (C) w i t h
Na/C2H5OH produces (D) which on heating

gives piperidine with the evolution

of ammonia. Identify The number of

carbon atoms in compound D is x and the
number of carbon atoms in compound A is
y, what is the value of x + y ?

Motion Education | 394 - Rajeev Gandhi Nagar | : 1800-212-1799 | url : www.motion.ac.in