Class 11ChemistryTest Mole Concept www.AhaGuru.

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S. Santhanam
TS19.C11.04 2019-20
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1. Thermal decomposition of a Mn compound (X) at 513K results in Y, MnO2

and a gaseous product (Z). Z is also obtained as one of the products on
heating solid potassium chlorate. X, Y and Z are
(A) K2 MnO4 , KMnO4 , Cl2 (B) KMnO4 , K2 MnO4 , O2
(C) K2 MnO4 , KMnO4 , SO3 (D) KMnO4 , K2 MnO4 ,SO2

2. Which among the following is/are comproportionation reaction? (not

balanced)
(i) 2H 2O2 ⎯⎯

→ 2H 2O + O2
+
(ii) IO3− + I − ⎯⎯→
H
I 2 + I 2 + H 2O
(iii) 2CuBr → CuBr2 + Cu
(iv) P4 + OH − → PH3 + H 2 PO2−
(v) MnO4− + I − ⎯⎯→
+
H
Mn 2 + + I 2 + H 2O
(vi) Cr2O72− + H 2O → 2CrO42− + 2H +

(A) (i), (iii), (v) (B) (ii) only (C) (ii), (iv), (vi) (D) (i), (vi)

3. Which among the following is/are thermally unstable?

(A) NH 4Cl , NH 4 NO3 , KClO3 (B) K2Cr2O7 , Na2CO3 ,( NH 4 )2 Cr2O7

(C) Pb( N3 )2 , KCl , NaHCO3 (D) Ba3 N2 , Pb( N3 )2 , K2CO3
(E) FeSO4 .7 H2 O, NaCl , NH 4 NO2

4. Which among the following solids on heating leaves no residue?

(A) NH 4Cl ,( NH )2 Cr2O7 (B) NH 4 NO3 , NH 4Cl , NH 4 NO2

(C) KNO3 , NaHCO3 ,lead azide (D) FeSO4 .7H 2O, KMnO4 , KClO3
 Class 11ChemistryTest www.AhaGuru.com
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TS19.C11.04

5. In which among the following the equivalent mass of solute is

1
 formula weight?
8
(i) S2O32− in S 2O32− → SO42− (ii) ClO4− in Cl − + ClO4− + H + → Cl2 + H 2O
(iii) Cl − → ClO4−
(iv) H 2C2O4 .K2C2O4 .NaHC2O4 .RbHC2O4 as reducing agent (at 70- 80 C )
(A) (i), (iii) (B) (ii), (iv) (C) all four (D) (ii), (iii)

6. Which among the following is/are true peroxides?

(i) KO2 (ii) BaO2 (iii) Pb3O4 (iv) MnO2 (v) Na2O2 (vi) PbO2
(A) (i), (iii), (v) (B) (ii), (iv) (C) (ii), (iv), (vi) (D) (ii), (v)

7. Among the following the number of oxygen atoms present is maximum in

(A) 1g O2 (B) 4g O (C) 1g O3 (D) 1.7g H 2O

8. ________moles of KClO3 needed to produce 1lit O2 ( g ) at STP on heating

1 1 1 1 2 1 3 1
(A)  (B)  (C)  (D) 
3 22.4 2 22.4 3 22.4 2 22.4

9. Which among the following is/are redox reactions?

(i) Cr2O72− + 2OH − → 2CrO42− + H 2O (ii) SiCl4 + 2Mg → 2MgCl2 + Si
(iii) 6Cl2 + 12KOH → 2KClO3 + 10KCl + 6H 2O (iv) 2H 2O2 → 2H 2O + O2
(A) (ii), (iii), (iv) (B) (ii), (iv) (C) (i), (iii), (iv) (D) (iv) only

10. Penicillamine is used in the treatment of arthritis. 1 molecule of it contains

one atom of sulphur and the mass% of sulphur in the medicine is 21.49%.
The molecular mass of penicillamine in g/mol is _______
(A) 85.4 (B) 68.76 (C) 125.2 (D) 149
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S. Santhanam
TS19.C11.04

11. A common method to clean acid spills is to use Na2CO3 (molar mass: 106g).

If 50ml of 0.75M HCl is on a wooden surface the amount of Na2CO3

needed is _______g
(A) 3.75 (B) 7.5 (C) 2.0 (D) 4.0

12. The analysis of three different binary oxides of Br and oxygen gives the following results

Compound Mass of oxygen combined

with 1g of Br2 in gram
X 0.101
Y 0.303
Z 0.503

Which of the following is correct?

(i) the compound Y is Br2O3
(ii) this data illustrates the law of multiple proportions
(iii) the compound Z is Br2O5
(iv) the compound X is BrO2
(v) Z is Br2O7

(A) (i), (iii), (v) (B) (ii), (iv) (C) (i), (ii), (iii) (D) none of these

13. 0.1M KMnO4 acts as oxidising agent in (i) acidic (ii) basic (iii) neutral
medium. The normalities are ________, _______ and _________ respectively

(A) 0.1, 0.3, 0.5 (B) 0.5, 0.1, 0.3

(C) 0.1, 0.1, 0.1 (D) 0.5, 0.5, 0.3

14. 2.68 10−3 mol of a solution containing An+ required 1.6110−3 mol of MnO4−
for the oxidation of An+ to AO3− in acid medium. The value of n is _______
(A) 0 (B) 5 (C) 3 (D) 2
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TS19.C11.04

15. xCe( IO3 )4 + yH 2C2O4 → pCe2 (C2O4 )3 + qI 2 + rCO2 + tH 2O , which is correctly matched?

x y p
(A) 2 3 1
(B) 2 24 1
(C) 1 42 1
(D) 2 21 4

16. The oxidation of C in HCHO and Cu in [Cu (CN ) 4 ]3− are _______ and ________
respectively
(A) 4, 1 (B) 0, 2 (C) -1, 2 (D) 0, 1

17. A metal (M) forms an alum with ( NH 4 )2 SO4 . The molecular formula of the
alum is
(A) MSO4 .( NH 4 )2 .6H 2O (B) M 2 (SO4 )3.( NH 4 )2 SO4 .24H 2O

(C) M 3 (SO4 )2 .( NH 4 )2 SO4 .6H 2O (D) M 3 (SO4 )2 .( NH 4 )2 SO4 .24H 2O

18. Which among the following concentration units are dependent on

temperature?
(A) molality, molarity, normality
(B) molefraction, normality, molality
(C) normality, molarity, weight/volume
(D) ppm, molality, molefraction, w/w

19. 0.5mol of bismuth (III) chloride is mixed with 1 mol of Potassium

phosphate. The number of moles of bismuth (III) phosphate formed is ______
(A) 0.5 (B) 1 (C) 0.3 (D) 1.5

20. The molefraction of 3 molal ethanolic solution of KCl is _______

(Molecular weight of KCl: 74.5, Molecular weight of C2 H5OH : 46)

3
3 3 74.5 3
(A) (B) (C) (D)
1000 1000 3 1000 1000
3+ 3+ + 3+
18 74.5 74.5 40 46
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21. The normality of H 2O2 solution as reducing agent labelled as

“10 volume H 2O2 ” is __________

(A) 8.4 (B) 44.8 (C)4.2 (D) none of these

22. 20ml of 1M BaCl2 (aq) , 50ml 0.2M CaCl2 (aq) and 100ml 1M FeCl3 (aq )

are mixed. The molality of Cl − in the final solution is _________

17 36
(A) (B) (C) 0.17 (D) 0.30
36 17

23. The normality of 0.1M KBrO3 (aq) in the net redox reaction

(unbalanced) is _______ BrO3− + Br − + H + → Br2 + Br2 + H 2O

(A) 0.5 (B) 0.8 (C) 0.6 (D) 0.4

24. Which among the following is expected to react with acidified KMnO4
solution under suitable conditions
(i) K 2 SO3 (ii) H 2O2 (iii) FeSO4 (iv) H 2 S (v) H 2C2O4

(vi) NO2− (vii) K 2 SO4 (viii) KNO3

(A) (i), (iii), (v), (vii) (B) (ii), (iv), (vi), (viii)
(C) (i), (ii), (iii), (iv), (v), (vi) (D) (viii), (vii)

25. A gas (X) turns lime water milky and the milkiness disappears on
prolonged reaction. X could be ________ among the following pairs
(A) SO2 , SO3 (B) CO2 , CO

(C) H2 S , CO2 (D) SO2 , CO2

26. Which among the following reducing agents is equivalent to 25ml of 0.1M
KMnO4 ( MnO42− is formed)

(A) 25ml 0.1M Fe2+ ( Fe2+ is formed)

(B) 50ml 0.2N Sn2+ ( Sn2+ is formed)
(C) 25ml 0.2M C2O42− ( CO2 is formed)

(D) 125ml 0.05M NO2− ( NO3− is formed)

Class 11ChemistryTest www.AhaGuru.com
S. Santhanam
TS19.C11.04

27. Which of the following is/are correct?

(i) the number of significant figures in 2345.100 is 3
(ii) 0.00787 rounded to two significant figures is written as 0.787 10−2
(iii) 340 rounded to two significant figures is written as 0.34 103
(iv) the number of significant figures in 0.020 is two
(A) (ii), (iii) (B) (iii), (iv) (C) (i), (ii), (iv) (D) (iii) only

28. A 4molar aq. NaCl is prepared and 500ml of this solution is electrolysed
using Hg cathode. The product at the anode is Cl2 and at the cathode Na(Hg)
is formed initially which reacts with H 2O to form NaOH, H 2 and Hg. Which
is/are true?
(i) the total number of moles of Cl2 ( g ) evolved at anode is 1
(ii) the reaction is non-spontaneous, redox
(iii) the total charge needed to complete electrolysis is 193000C
(iv) the reactions at cathode are Na+ + e− ⎯⎯
Hg
→ Na( Hg ) and
2 Na( Hg ) + 2 H 2O → 2 NaOH + H 2  +2 Hg
(A) (i), (iii) (B) (ii), (iv) (C) (ii) only (D) all four

29. Sodium azide ( NaN3 ) is used in the airbag of cars as a safety device that
inflates on impact as per the reaction 2 NaN3 → 2 Na + 3N2 . An airbag of a

car is filled with 44.8 10−3 m3 of the gas at STP. The mass of NaN3 to fill
this airbag fully at 298K, 1atm pressure is ______kg
(A) 130 (B) 0.087 (C) 0.84 (D) 0.13

30. Which of the following mixtures of water and H 2 SO4 would have mass%

H 2 SO4 nearly equal to 30

H 2 SO4 H 2O
(A) 30g 100g
(B) 1mol 2mol
(C) 1mol 200g
(D) 0.3mol 0.7mol
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31. Which is incorrect about glucose C6 H12O6

(A) an aq. 0.25M solution of it is prepared by dissolving 45g of it in water
to give 1000 cm3 of solution
(B) 1mmol of glucose  180mg
(C) 90g glucose contains 1.8 1022 atoms of carbon
(D) 100cc of 0.1M solution of it contains 1.8g glucose

32. At constant T and P, 5lit of SO2 mixed with 3lit of O2 .

2SO2 ( g ) + O2 ( g ) → 2SO2 ( g ) . The volume of the reaction mixture at the
completion of the reaction is ______lit
(A) 0.5 (B) 8 (C) 5.5 (D) 5

33. A fuel oxidant system consists of (CH3 )2 NNH 2 and N2O4 (both liquids).
They are mixed stoichiometrically so that N2 , CO2 and H 2O are the only
products. If all gases are under the same reaction conditions the number of
moles of gases produced from 1mol of (CH3 )2 NNH 2 is________
(A) 3 (B) 6 (C) 9 (D) 4.5

34. Identify the compound (s) that on heating normally gives NO2 ( g ) as one of
the products.
(i) Ba( NO3 )2 (ii) NH 4 NO3 (iii) KNO3 (iv) ( NH 4 )2 Cr2O7

(v) Cu( NO3 )2 (vi) Pb( N3 )2 (vii) Pb( NO3 )2 (viii) Ba3 N 2
(A) (i), (iii), (v) (B) (ii), (iv), (vi), (viii) (C) (i), (v), (vii) (D) (vii) only

35. A salt when heating with NaOH gives a gas that gives dense white fumes with
HCl and also the gas turns red litmus blue. The resulting solution of the salt
after its reaction with alkali on warming with Zinc granules in basic medium
forms the same gas. Which would be the probable identity of the salt?
(i) KNO3 (ii) ( NH 4 )2 SO4 (iii) NH 4 NO3 (iv) NH 4Cl

(v) NH 4 NO2 (vi) ( NH 4 )2 CO3

(A) (i), (iii) (B) (iii), (v) (C) all six (D) (i) only
Class 11ChemistryTest www.AhaGuru.com
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TS19.C11.04

36. Nitrobenzene C6 H 5 NO2 (molecular mass: 123) in acidic medium is

reduced electrolytically to form C6 H5 NHOH and H 2O at the cathode. A
H 2 − O2 coulometer in series with this cell liberated 168ml of gases

( H 2 + O2 ) at the electrodes at STP. C6 H 5 NO2 + 4 H + + 4e − → C6 H 5 NHOH + H 2O .

Which is/are true?
(i) the number of Faradays needed is 10−2
(ii) the reaction is non-spontaneous and the number of coulombs needed is 965
(iii) the equivalent mass of nitrobenzene is =12.3/4
(iv) the mass of nitrobenzene originally present is 1.23/6 g
(A) (i), (iii) (B) (ii), (iv) (C) (i), (ii), (iii) (D) all four

37. V1M 1 = V2 M 2 is true

(i) for Ca(OH )2 + H 2 SO4 (ii) always for any two reacting solutions
(iii) when N=M for both reacting substances
(iv) when the same solution is getting diluted
(A) (i), (ii) (B) (iii), (iv) (C) (i), (iii), (iv) (D) (ii) only

38. 2.81ppm of sodium ferricyanide Na3[ Fe(CN )6 ] solution is available

(Molecular mass: 281). Which is/are false?
(i) [ Na+ ] = 3 10−4 M (ii) the charge on the central ion is +1

(iii) the total analytical concentration of the complex is 10−5 F

(iv) ppm is a concentration unit that depends on temperature
(A) (ii), (iii) (B) (i), (ii) (C) (i), (ii), (iii) (D) all four

39. The oxidation state of the most electronegative atom in the products of the
reaction of BaO2 with dil. H 2 SO4 are _______, ________

(A) 0, -1 (B) -1, -2 (C) 0, -2 (D) 1, -2

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TS19.C11.04

40. The reaction MnO4− + Mn 2+ + H + → Mn3+ + H 2O (unbalanced) is _________

(A) redox only (B) redox, disproportionation
(C) redox, comproportionation (D) non-redox

41. In the following reaction, p,q,r respectively are ____, _____, _____
p F2 ( g ) + q OH − (aq ) → r F− (aq) + s OF2 ( g ) + t H 2 O(l )
(A) 3, 2, 4 (B) 3, 4, 2 (C) 2, 2, 4 (D) 2, 2, 2

42. A sample of river water was analysed for the presence of metal ions and the
observations are as follows:
Reagent added observation
dil. HCl No change
aq. Na2CO3 White precipitate
aq. Na2 SO4 No change

The water sample is likely to contain ____________

(A) Ba 2+ (B) Cu 2+ (C) Mg 2+ (D) Li +

43. The molefraction of a solvent in aq. Solution of a solute is 0.5. The molality of the
solution is_________
(A) 1.388 (B) 13.88 10−2 (C) 13.88 (D) 13.88 10−3

44. The molefraction of urea in 0.9 kg of water is 0.05. The density of the solution is
1.2g/cc. The molarity of the solution is nearly = ________
(molecular mass of solute: 60)
(A) 0.05 (B) 1.9 (C) 3 (D) 2.4

45. 100ml of 0.1M AgNO3 is mixed with 400ml 0.1M K2CrO4 . In the final solution
after filtering off the precipitate [CrO42 − ] = _________M
35 30 40
(A) (B) (C) (D) none of these
500 500 500
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TS19.C11.04

46. The number of meq. Of KHC2O4 .NaHC2O4 .H 2C2O4 as reducing agent in

100ml 0.1M solution at 70 − 80 C (with acidified KMnO4 ) is __________
(A) 60 (B) 10 (C) 10−2 (D) 0.06

47. Among ClO4− , F − , CH 3COO − the weakest base is _______ and ______ is the
strongest conjugate acid
(A) ClO4− , CH 3COOH (B) ClO4− , HClO4
(C) F − , HClO4 (D) HClO4 , ClO4−

48. Which is/are false?

(i) PbO2 when warmed with con.HCl forms H 2O2 as one of the products
(ii) KO2 is used to remove CO2 in submarines and airships
(iii) pH of aq. Solution of the same concentration at 25 C follow the
order, NaCN  NaCl  NH 4Cl  HCl
(iv) pH of water >7 at 80 C

(A) (i), (iii), (iv) (B) (ii), (iv) (C) all four (D) (iv) only

49. Which is correctly matched?

Gas Test
(A) H2S Lime water

(B) SO2 Lead acetate

(C) Cl2 Starch+KI solution

(D) CO2 Acidified KMnO4

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TS19.C11.04

50. A solution of KH ( IO3 )2 is used in various reactions. Which is correctly matched

regarding its equivalent weight?
(i) when it reacts with NaOH = Molecular weight /2
(ii) as salt = Molecular weight /2
(iii) as reducing agent in the reaction
KH ( IO3 )2 + 4KMnO4 + 5KOH → 2KIO4 + 4K2 MnO4 + 3H 2O = Molecular weight /4
(A) (i), (iii) (B) (ii), (iii) (C) (i) only (D) all three

51. Formality of a solution is identical to molarity for aq.____________

(i) HClO4 (ii) CH 3COOH (iii) sucrose
(iv) HCl (v) glucose

(A) (i), (iv) (B) (ii) only (C) (iii), (iv) (D) (iii), (v)

52. Which of the following will react with both dil. acids + alkalis
(i) Al (ii) Mg (iii) Zn (iv) K
(A) (i), (ii) (B) (ii), (iii) (C) (i), (iii) (D) (iii) only

53. The molarity of H 2O in pure water is ___________

18
(A) 18 (B) 1 (C) 55.6 (D)
1000

54. Zn + 2 AgNO3 → Zn( NO3 )2 + 2 Ag is an example of _________reaction

(i) displacement (ii) spontaneous (iii) non-redox
(iv) non-spontaneous (v) redox
(A) (i), (ii), (v) (B) (ii), (iii) (C) (i), (v) (D) (i) only

55. The number of electrons in 1.6g CH 4 is

(A) 6 1023 (B) 6 1024 (C) 6 1022 (D) 30 1023

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56. The mass of CaO got by heating 200kg of limestone ( CaCO3 ) that is 95%
pure is ________kg (molecular mass of CaCO3 : 100, CaO: 56)

(D) 106.4 10

3
(A) 0.19 (B) 190 (C) 106.4

57. P4 reacts with aq. NaOH forming PH 3 and NaH 2 PO4 . It is _____

(A) oxidation (B) reduction

(C) neutralisation (D) redox

58. An inorganic substance (X) has the following % N: 35, H: 5 and O: 60. X on
heating gave a gaseous compound (Y) with N: 63.63, O: 36.37 and water. X
and Y are ________, _________

(A) NH 4 NO2 , N2 (B) NH 4 NO3 , N2O

(C) NH 4 NO3 , NO (D) NH 4 NO2 , N2O

59. 20CC of a solution containing 0.2g of an impure sample of H 2O2 reacts with
0.316g KMnO4 in acidic medium. The % purity of H 2O2 is ________
(molecular mass of KMnO4 : 158, H 2O2 : 34)

(A) 95 (B) 50 (C) 31.6 (D) 85

60. The volume occupied by 1molecule of H 2O is nearly ________ cc if d= 1g/cc for

H 2O

(A) 6 10−23 (B) 3 10−23 (C) 18 10−26 (D) 6 10−26