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FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

Held On Sunday 29th January, 2023
TIME : 03:00 PM to 06:00 PM

SECTION-A [CoF6 ]3  : Co3+ = 3d6 (O < P)

31. Given below are two statements:
Statement I : The decrease in first ionization eg
enthalpy from B to Al is much larger than that
from Al to Ga.
Statement II : The d orbitals in Ga are completely t2g
filled.
In the light of the above statements, choose the Number of unpaired e– = 4    24 BM
most appropriate answer from the options given [Co(C 2O 4 ) 3 ]3 : Co3+ = 3d6 (O > P)
below
(1) Statement I is incorrect but statement II is eg
correct.
(2) Both the statements I and II are correct
(3) Statement I is correct but statement II is t2g
incorrect
Number of unpaired e– = 0   = 0 BM
(4) Both the statements I and II are incorrect
Official Ans. by NTA (2) 33. Match List-I and List-II.
Allen Ans. (1) List-I List-II
Sol. The first ionization energies (as in NCERT) are as A. Osmosis I. Solvent molecules pass
follows: through semi permeable
B : 801 kJ/mol membrane towards solvent
side.
Al : 577 kJ/mol
B. Reverse osmosis II. Movement of charged
Ga : 579 kJ/mol
colloidal particles under the
Ga : [Ar]3d104s24p1
influence of applied electric
potential towards oppositely
32. Correct order of spin only magnetic moment of the charged electrodes.
following complex ions is: C. Electro osmosis III. Solvent molecules pass
(Given At. No. Fe: 26, Co:27) through semi permeable
(1) [FeF6 ]3  [CoF6 ]3  [Co(C 2O 4 ) 3 ]3 membrane towards solution
side.
(2) [Co(C 2O4 ) 3 ]3  [CoF6 ]3  [FeF6 ]3
D. Electrophoresis IV. Dispersion medium
(3) [FeF6 ]3  [Co(C 2O 4 ) 3 ]3  [CoF6 ]3 moves in an electric field.
(4) [CoF6 ]3  [FeF6 ]3  [Co(C 2O 4 ) 3 ]3 Choose the correct answer from the options given
below:
Official Ans. by NTA (1) (1) A-I, B-III, C-IV, D-II
Allen Ans. (1) (2) A-III, B-I, C-IV, D-II
Sol. [FeF6 ]3 : Fe3+ = 3d5 O<P (3) A-III, B-I, C-II, D-IV
(4) A-I, B-III, C-II, D-IV
eg Official Ans. by NTA (2)
Allen Ans. (2)
Sol. A. Osmosis III
t2g B. Reverse osmosis I
C. Electro osmosis IV
Number of unpaired e– = 5    35 BM D. Electrophoresis II

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34. The set of correct statements is: 36. An indicator ‘X’ is used for studying the effect of
(i) Manganese exhibits +7 oxidation state in its variation in concentration of iodide on the rate of
oxide. reaction of iodide ion with H2O2 at room temp. The
(ii) Ruthenium and Osmium exhibit +8 oxidation indicator ‘X’ forms blue colored complex with
in their oxides. compound ‘A’ present in the solution. The
(iii) Sc shows +4 oxidation state which is indicator ‘X’ and compound ‘A’ respectively are
oxidizing in nature.
(1) Starch and iodine
(iv) Cr shows oxidising nature in +6 oxidation
(2) Methyl orange and H2O2
state.
(3) Starch and H2O2
(1) (ii) and (iii) (2) (i), (ii) and (iv)
(3) (i) and (iii) (4) (ii), (iii) and (iv) (4) Methyl orange and iodine
Official Ans. by NTA (2) Official Ans. by NTA (1)
Allen Ans. (2) Allen Ans. (1)
Sol. (i), (ii) and (iv) correct. Sol. I   H 2O 2 
 I 2  H 2O
Manganese exhibits +7 oxidation state in its oxide. (A)
(Mn2O7)
I 2  Starch 
 Blue
Ru & Os from RuO4 & OsO4 oxide in +8 oxidation (Indicator)
state
37. A doctor prescribed the drug Equanil to a patient.
Cr in +6 oxidation act is oxidizing.
The patient was likely to have symptoms of which
Sc does not show +4 oxidation state.
disease?
35. Match List-I and List-II.
(1) Stomach ulcers
List-I List-II (2) Hyperacidity
A. Elastomeric I. Urea formaldehyde (3) Anxiety and stress
polymer resin (4) Depression and hypertension
Official Ans. by NTA (4 )
B. Fibre polymer II. Polystyrene
Allen Ans. (4)
C. Thermosetting III. Polyester Sol. Theory based.
polymer 38. Find out the major product for the following
D. Thermoplastic IV. Neoprene reaction.

polymer
Major Product
Choose the correct answer from the options given
below:
(1)
(1) A-II, B-III, C-I, D-IV
(2) A-II, B-I, C-IV, D-III
(2)
(3) A-IV, B-III, C-I, D-II
(4) A-IV, B-I, C-III, D-II
(3)
Official Ans. by NTA (3)
Allen Ans. (3) (4)
Sol. Neoprene : Elastomer
Official Ans. by NTA (2)
Polyester : Fibre Allen Ans. (2)
Polystyrene : Thermoplastic
Urea–Formaldhyde Resin: Thermosetting polymer Sol.

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39. The one giving maximum number of isomeric 41. Find out the major products from the following
alkenes on dehydrohalogenation reaction is reaction sequence.
(excluding rearrangement)
(1) 1-Bromo-2-methylbutane
(2) 2-Bromopropane
(3) 2-Bromopentane
(4) 2-Bromo-3,3-dimethylpentane
Official Ans. by NTA (3)
Allen Ans. (3)
CH 3 (1)
|
Sol. CH 3  CH 2  CH  CH 2  Br 


C
| (1)
CCC  C
Br
|
CH 3  CH  CH 3 
 CH3CH=CH2 (1)
(2)
Br
|
CH 3  CH 2  CH 2  CH  CH3 


C-C-C-C=C + C-C-C=C-C, cis & trans (3)

CH3 C
| |
C  C  C  C  C 
 C  C  C  C  C (1)
| | |
(3)
CH3 Br C

40. When a hydrocarbon A undergoes combustion in

the presence of air, it requires 9.5 equivalents of
oxygen and produces 3 equivalents of water. What
is the molecular formula of A?
(1) C8H6 (2) C9H9 (4)
(3) C6H6 (4) C9H6
Official Ans. by NTA (1)
Allen Ans. (1)
 y y
Sol. Cx Hy   x   O2  xCO2  H2O
 4 2
y Official Ans. by NTA (2 )
x  9.5
4 Allen Ans. (2)
y
3
2
 x = 8, y = 6

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O –O 45. Reaction of propanamide with Br2 / KOH (aq)

Sol.
NaCN produces :
CN
Cl Cl (1) Ethylnitrile (2) Propylamine
EtOH, H3O+ (3) Propanenitrile (4) Ethylamine
Official Ans. by NTA (4)
HO HO
O– O Allen Ans. (4)
MeMgBr C–O–Et
C OEt O
Me Cl Br2/KOH
Cl Sol. NH2 Hoffmann NH2
HO
OH
O– Bromamide Ethylamine
O
MeMgBr C
C Me Me
Me
Cl 46. Following tetrapeptide can be represented as
Cl

OH
OH
C
Me
Me
Cl
42. According to MO theory the bond orders for O22–,
CO and NO+ respectively, are
(1) 1, 3 and 3 (2) 1, 3 and 2
(3) 1, 2 and 3 (4) 2, 3 and 3
Official Ans. by NTA (1)
Allen Ans. (1)
Sol. Theory based. (F, L, D, Y, I, Q, P are one letter codes for amino
43. A solution of CrO5 in amyl alcohol has a….colour acids)
(1) Green (2) Orange–Red
(1) FIQY (2) FLDY
(3) Yellow (4) Blue
Official Ans. by NTA (4) (3) YQLF (4) PLDY
Allen Ans. (4) Official Ans. by NTA (2)
Sol. A solution of CrO5 in amyl alcohol has a blue Allen Ans. (2)
colour. So, option (4) is correct.
Sol. Hydrolysis of the given tetrapeptide will give the
44. The concentration of dissolved Oxygen in water
for growth of fish should be more than X ppm and following:
Biochemical Oxygen Demand in clean water O
should be less than Y ppm. X and Y in ppm are, Ph–CH2–CH–COOH OH
respectively.
NH2 NH2
X Y X Y
(1) (2) (F) (L)
6 5 4 8
(Phenylalanine) (Leucine)
X Y X Y O
(3) (4) O
4 15 6 12
HO OH
Official Ans. by NTA (1 ) OH
Allen Ans. (1) NH2
O NH2 HO
Sol. The growth of fish gets inhibited if the
(D) (Y)
concentration of dissolved Oxygen in water is less
(Aspartic acid) (Tyrosine)
than 6 ppm and Biochemical Oxygen demand in
clean water should be less than 5 ppm.

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47. Which of the following relations are correct? 49. Given below are two statements:
(A) U  q  pV (B) G  H  TS Statement I : Nickel is being used as the catalyst
for producing syn gas and edible fats.
q rev Statement II : Silicon forms both electron rich and
(C) S  (D) H  U  nRT
T electron deficient hydrides.
Choose the most appropriate answer from the In the light of the above statements, choose the
most appropriate answer from the options given
options given below :
below:
(1) C and D only (2) B and C only (1) Both the statements I and II are correct
(3) A and B only (4) B and D only (2) Statement I is incorrect but statement II is
Official Ans. by NTA (2) correct
(3) Both the statements I and II are incorrect
Allen Ans. (2)
(4) Statement I is correct but statement II is
Sol. Only (B) and (C) are correct. incorrect
(B) G = H – TS Official Ans. by NTA (4)
At constant T Allen Ans. (4)
Sol. Statement–I is correct.
G = H – TS
Ni is used in Hydrogenation of unsaturated fat to
(A) First law is given by make edible fats.
U = Q + W Statements–II is false as hydride of Silicon is
electron precise & neither electron deficient nor
If we apply constant P and reversible work.
electron rich.
U = Q – PV
50. Match List I with List II.
(C)By definition of entropy change
List I List II
dq rev A. van’t Hoff I. Cryoscopic constant
dS 
T factor, i
At constant T B. kf II. Isotonic solutions
q rev C. Solutions with III. Normal molar mass
S  same osmotic Abnormal molar mass
T
pressure
(D) H = U + PV
D. Azeotropes IV.
Solutions with same
For ideal gas composition of vapour
H = U + nRT above it
At constant T Choose the correct answer from the options given
below :
H = U + nRT
(A) A-III, B-I, C-II, D-IV
48. The major component of which of the following (B) A-III, B-II, C-I, D-IV
ore is sulphide based mineral? (C) A-III, B-I, C-IV, D-II
(D) A-I, B-III, C-II, D-IV
(1) Calamine (2) Siderite
Official Ans. by NTA (1)
(3) Sphalerite (4) Malachite Allen Ans. (1)
Official Ans. by NTA (3) Sol. (A) van’t Hoff factor, i
Allen Ans. (3) Normal molar mass
i
Sol. Calamine : ZnCO3 Abnormal molar mass
(B) kf = Cryoscopic constant
Siderite : FeCO3
(C) Solutions with same osmotic pressure are
Sphalerite : ZnS known as isotonic solutions.
Malachite : CuCO3.Cu(OH)2 (D) Solutions with same composition of vapour
over them are called Azeotrope.‘

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54. Total number of acidic oxides among

51. On heating, LiNO3 gives how many compounds N2O3, NO2, N2O, Cl2O7, SO2, CO, CaO, Na2O and
NO is _________ .
among the following?
Li2O, N2, O2, LiNO2, NO2 Official Ans. by NTA (4 )
Official Ans. by NTA (3) Allen Ans. (4)
Allen Ans. (3) Sol. Acidic oxides are N2O3, NO2, Cl2O7, SO2
 1
Sol. 2 Li NO3   Li2O + 2NO2 + O2
2 55. When 0.01 mol of an organic compound containing
Hence three products Li2O, NO2 and O2 60% carbon was burnt completely, 4.4 g of CO2
52. At 298 K
was produced. The molar mass of compound is
N2 (g)  3H 2 (g) 2NH3 (g), K1  4  10 5
__________ g mol–1 (Nearest integer)
N2 (g)  O2 (g) 2NO (g), K2  1.6  1012 Official Ans. by NTA (200)
1
H 2 (g)  O2 (g) H 2 O (g), K 3  1.0  10 13 Allen Ans. (200)
2
Sol. Let M is the molar mass of the compound (g/mol)
Based on above equilibria, the equilibrium
constant of the reaction, mass of compound = 0.01 M gm
5 60
2NH3 (g)  O2 (g) 2NO (g)  3H 2 O (g) mass of carbon = 0.01 M ×
2 100
is ___  10 33 (Nearest integer) 0.01M 60
moles of carbon = 
Official Ans. by NTA (4) 12 100
Allen Ans. (4) 4.4
moles of CO2 from combustion = = moles of
Sol. N2 (g)  3H 2 (g) 2NH3 (g), K1  4  10 5 ...(i) 44
carbon
N2 (g)  O2 (g) 2NO(g), K 2  1.6  1012 ...(ii)
0.01M 60 4.4
1 13  
H 2 (g)  O2 (g) H 2 O(g), K 3  1.0  10 ...(iii) 12 100 44
2
(ii) + 3×(iii) – (i) 4.4 100 12
M=    200gm / mol
5 44 60 0.01
2NH3 (g)  O2 (g) 2NO(g)  3H 2 O(g)
2 56. The denticity of the ligand present in the Fehling’s
k2  k3
1.6  10  (10
12 13 3
) reagent is _______ .
k eq  3

k1 4  10 5
Official Ans. by NTA (4)
.6
  10 32  4  10 33 Allen Ans. (4)
4
Sol.
53. For conversion of compound A  B, the rate
O C O O C O
constant of the reaction was found to be 4.6 × 10–5
L mol–1 s–1. The order of the reaction is ______ . H Cu H

Official Ans. by NTA (2) H C O O C H

Allen Ans. (2)

H C O O C H
Sol. As unit of rate constant is (conc.)1–n time–1
H Cu H
 (L mol–1)  1–n = –1
n=2 O C O O C O
Copper tartarate complex
Denticity = 2

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57. A metal M forms hexagonal close-packed Sol. Zn(s)  Sn 2 (aq) Zn 2 (aq)  Sn(s)
structure. The total number of voids in 0.02 mol of
G   2.303RT log10 Keq
it is __________ × 1021 (Nearest integer)
(Given NA = 6.02 × 1023)  
 nF E0cell   2.303RT log10 Keq

Official Ans. by NTA (36) 0.059

E 0Zn / Zn 2  ESn
0
2  log10 Keq
/Sn
2
Allen Ans. (36)
0.059
Sol. One unit cell of hcp contains = 18 voids 0.76  ESn
0
2  log10 10 20
/Sn
2
No. of voids in 0.02 mol of hcp
0.059  20
0.76  E Sn
0

18 2
/Sn
2
=  6.02  10 23  0.02
6 0
E Sn 2
/Sn
 0.59  0.76 = –0.17
 3.6 ×10 22
0
E Sn  17  10 2 V
 36 ×1021 /Sn 2

58. Assume that the radius of the first Bohr orbit of Ans. = 17
hydrogen atom is 0.6 Å. The radius of the third
Bohr orbit of He+ is ________ picometer. (Nearest 60. The volume of HCl, containing 73 g L–1, required
Integer) to completely neutralise NaOH obtained by

Official Ans. by NTA (270) reacting 0.69 g of metallic sodium with water, is
_______ mL. (Nearest Integer)
Allen Ans. (270)
(Given : molar Masses of Na, Cl, O, H are 23,
n2
Sol. r 35.5, 16 and 1 g mol–1 respectively)
Z
Official Ans. by NTA (15)
n2
rHe   rH 
Z Allen Ans. (15 )
(3)2 0.69
rHe  0.6  Sol. Mole of Na =  3  10 2
2 23
= 2.7 Å 1
Na  H 2 O 
 NaOH + H2
rHe  270pm 2
By using POAC
59. The equilibrium constant for the reaction
Moles of NaOH = 3 × 10–2
Zn(s)  Sn 2 (aq) Zn 2 (aq)  Sn(s) is 1 × 1020
NaOH reacts with HCl
at 298 K. The magnitude of standard electrode
No. of equivalent of NaOH = No. of equivalent of
2+ o
potential of Sn/Sn if E Zn2 / Zn
= –0.76 V is HCl
_______ × 10–2 V. (Nearest integer) 73
3  10 2  1   V(in L)  1
2.303RT 36.5
Given :  0.059V
F V = 1.5 × 10–2 L

Official Ans. by NTA (17) Volume of HCl = 15 ml.

Allen Ans. (17)

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