Chemistry

SHIFT-1
27th January 2024 & Saturday
SUBJECT: CHEMISTRY
| JEE(Main) 2024 | DATE : 27-01-2024 (SHIFT-1) | PAPER-1 | OFFICAL PAPER | CHEMISTRY
PART : CHEMISTRY
61. NaCl reacts with conc. H2SO4 and K2Cr2O7 to give reddish fumes (B), which react with NaOH to give
yellow solution (C). (B) and (C) respectively are :
(1) CrO2Cl2, Na2Cr2O7 (2) Na2CrO4, CrO2Cl2 (3) CrO2Cl2, KHSO4 (4) CrO2Cl2, Na2CrO4
Ans. (4)
Sol. These are reactions of chromyl chloride test for acid react Cl–.
NaCl(s) + K2Cr2O7(s) + H2SO4 (conc.)  CrO2Cl2 + Na2SO4 + K2SO4 + H2O
CrO2Cl2 + NaOH  Na2CrO4 + NaCl + H2O
62. Given below are two statements :

Statements (I) : Aqueous solution of ammonium carbonate basic.
Statements (II) : Acidic/basic nature of salt solution of a slat of weak acid and weak base depends on Ka
and Kb value of acid and the base forming it.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Statements I is correct but Statements II is incorrect.
(2) Both Statements I and Statements II are correct.
(3) Statements I is incorrect but Statements II is correct.
(4) Both Statements I and Statements II are incorrect.
Ans. (2)
1 1
Sol. pH(WBWA) = 7  pK a  pK b
2 2
The above equation shows that pH depends on Ka & Kb value.
63. Which of the following electronic configuration would be associated with the highest magnetic moment ?
(1) [Ar] 3d7 (2) [Ar] 3d6 (3) [Ar] 3d8 (4) [Ar] 3d3
Ans. (2)
Sol.
Electronic configuration No. of unpaired electron
1. 3
[Ar]3d  3
2. [Ar]3d6 4
3. [Ar]3d8 2
4. [Ar]3d7 3
More are the no. of unpaired electron, more is the magnetic moment (spin only)
64. The ascending order of acidity of –OH group in the following compounds is :
(A) Bu – OH (B) O2N OH
(C) MeO OH (D) OH
(E) O2N OH
NO2
Choose the correct answer from the options given below :
(1) (C) < (A) < (D) < (B) < (E) (2) (A) < (C) < (D) < (B) < (E)
(3) (A) < (D) < (C) < (B) < (E) (4) (C) < (D) < (B) < (A) < (E)
Ans. (2)
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OH OH OH OH
NO2
Sol. > > > > Bu–OH
NO2 NO2 OCH3

–M –M +M
65. Two nucleoptides are joined together by a linkage known as :

(1) Disulphide linkage (2) Peptide linkage
(3) Glycosidic linkage (4) Phosphodiester linkage
Ans. (4)

Statements (I) : p-nitrophenol is more acidic than m-nitrophenol and o-nitrophenol.
Statements (II) : Ethanol will give immediate turbidity with Lucas reagent.
In the light of the above statements, choose the correct answer from the options given below :
(1) Statements I is true but Statements II is false.
(2) Both Statements I and Statements II are true.
(3) Statements I is false but Statements II is true.
(4) Both Statements I and Statements II are false.
Ans. (1)
67. Yellow compound of lead chromate gets dissolved on treatment with hot NaOH solution. The product of
lead formed is a :
(1) Tetraanionic complex with coordination number six.
(2) Neutral complex with coordination number four.
(3) Dianionic complex with coordination number six.
(4) Dianionic complex with coordination number four.
Ans. (4)
Sol. Yellow ppt. of PbCrO4  is soluble in hot NaOH, forming [Pb(OH)4]2– as Pb2+ is amphoteric in nature.
68. Consider the following complex ions

P = [FeF6]3– Q = [V(H2O)6]2+ R = [Fe(H2O)6]2+
The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is :
(1) R < P < Q (2) R < Q < P (3) Q < R < P (4) Q < P < R
Ans. (3)
Sol.
Species Electronic configuration No. of unpaired electron
(P) [FeF6]3– [Ar]3d5  5
(Q) [V(H2O)6]2+ [Ar]3d3 3
(R) [Fe(H2O)6]2+ [Ar]3d6 4
More are the no. of unpaired electrons more is the magnetic moment (spin only). H2O is weak field ligand
therefore magnetic properties of central metal ion and complex will be same.
69. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Melting point of Boron (2453 K) is unsually high in group 13 elements.
Reason (R) : Solid Boron has very strong crystalline lattice.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) (A) is true but (R) is false
(2) (A) is false but (R) is true
(3) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(4) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
Ans. (3)

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Sol. Boron is non-metallic in nature. It is extremely hard and black coloured solid. Due to very strong crystalline
lattice, boron has unusually high melting point. Rest of the members are soft metals with low melting point
and high electrical conductivity. (NCERT Boron family/Reso sheet)
Property B Al Ga In Tl
Melting point / K 2453 933 303 430 576
70. Which of the following has highly acidic hydrogen ?

H 3C CH2 CH2 CH3
H3C
(1) C C CH3 (2)
O O O
O O
H 3C CH2 C C CH3
(3) C CH2 CH3 (4) H3C C
O O
Ans. (1)
Sol. Active methelene group have more acidic hydrogen atom.

Statements (I) : The 4f and 5f-series of elements are placed separately in the Periodic table to preserve
the principle of classification.
Statements (II) : s-block elements can be found in pure form in nature.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Both Statements I and Statements II are true.
(2) Both Statements I and Statements II are false.
(3) Statements I is true but Statements II is false.
(4) Statements I is false but Statements II is true.
Ans. (3)
Sol. Statement I is correct while Statement II is incorrect as s-block elements are found in combined form as
they are highly reactive.
72. Which of the following is strongest Bronsted base?

NH2
(1) (2) NH
H H
N

N
(3) (4)
Ans. (4)
Sol. Lone pair of N is being used in aromatic ring, whereas in A and B, lone pair is being delocalised in
aromatic ring, whereas in ‘B’ lone pair is localised.
73. Choose the polar molecule from the following :

(1) CCl4 (2) CH2 = CH2 (3) CHCl3 (4) CO2
Ans. (3)
Sol. CHCl3 is having permanent dipole moment, therefore it is polar molecules whereas all other given
molecules have dipole moment = 0.

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74. IUPAC name of following compound (P) is :
(P)
(1) 1-Ethyl-5,5-dimethylcyclohexane (2) 1-Ethyl-3,3-dimethylcyclohexane
(3) 3-Ethyl-1,1-dimethylcyclohexane (4) 1,1-Dimethyl-3-ethylcyclohexane
Ans. (3)
1
2
Sol. 6
5 3
4
3-Ethyl-1, 1-dimethylcyclohexane
75. Highest enol content will be shown by :

O O O
O O O O
(1) (2) (3) (4)
O O
O
Ans. (3)
O OH
Sol.
O O HO OH
Aromatic
76. The electronic configuration for Neodymium is :

[Atomic Number for Neodymium 60]
(1) [Xe] 4f 4 6s2 (2) [Xe] 4f 6 6s2 (3) [Xe] 5f 7 7s2 (4) [Xe] 4f 4' 5d' 6s2
Ans. (1)
144
Sol. 60Nd = [Xe]4f 4 6s2
77. Cyclohexene is ________ type of an organic compound.

(1) Benzenoid non-aromatic (2) Acyclic
(3) Alicyclic (4) Benzenoid aromatic
Ans. (3)
Sol. Given compound is cyclic as well as aliphatic, hence it is alicylic.
78. Element not showing variable oxidation state is :

(1) Chlorine (2) Bromine (3) Fluorine (4) Iodine
Ans. (3)
Sol. Fluorine in it's compound shows only –1 oxidation state. As it's electronegativity is highest and It has no
vacant d-orbital.

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79. The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is:
(1) Racemisation occurs in SN1 reaction and retention occurs in SN2 reaction.
(2) Racemisation occurs in SN1 reaction and inversion occurs in SN2 reaction.
(3) Racemisation occurs in both SN1 and SN2 reaction.
(4) Racemisation occurs in SN1 reaction and inversion occurs in SN2 reaction.
Ans. (4)
Sol. Since SN1 reaction occurs via carbocation intermediate hence racemization takes place, whereas in SN2,
due to basic side back side attack inversion of configuration takes place.
80. A solution of two miscible liquids showing negative deviatin from Raoult's law will have :
(1) increased vapour pressure, increased boiling point
(2) increased vapour pressure, decreased boiling point
(3) decreased vapour pressure, increased boiling point
(4) decreased vapour pressure, decreased boiling point
Ans. (3)
Sol. For solution showing negative deviation VP decreases & BP increases. Because, interparticle attraction
increases due to mixing.
81. 3-Methylkex-2-ene on reaction with HBr in presence of peroxide forms an addition product (A).
The number of possible stereoisomers for 'A' is _____________.
Ans. (4)
HBr
Sol. * *
H2O2 H
Br H
Since the product has two chiral carbon, hence overall 4 stereoisomers [RR, RS, SR and SS] will be
formed.
82. Mass of methane required to produce 22 g of CO2 after complete combustion is _______ g.
Ans. (8)
Sol. CH4 + 2O2  CO2(g) + 2H2O()
 22 
 
 44 
0.5 mole 0.5 mole
mass of CH4 = 0.5 × 16 = 8 gram.
83. Among the given organic compounds, the total number of aromatic compound is _________.
(A) (B)
(C) (D)
–
Ans. (3)
Sol. For Aromatic compound, sp3 hybridised carbon atom should not be present.
84. If three moles of an ideal gas at 300 K expand isothermally from 30 dm3 to 45 dm3 against a constant
opposing pressure of 80 kPa, then the amount of heat transferred is _______ J.
Ans. (12)
Sol. As process is isothermal ir-reversible expansion of an ideal gas so (U = 0) & (q = –w)
pressure = 80 kPa = 0.8 bar
q = – w = PV
= 0.8 × [45–30]
= 0.8 × 15
= 12 J.

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85. Sum of bond order of CO and NO+ is ________.

Ans. (6)
Sol. Species Total number of electrons Bond order
NO+ 14 3
CO 14 3
1
86. The number of electrons present in all the completely filled subshells having n = 4 and S = + is _______
2
(Where n = principal quantum number and s = spin quantum number)
Ans. (16)
Sol.
4s 4p 4d 4f
Subshell
No. of electrons with +½ 1 3 5 7
87. Among the following, total number of meta directing functional group is ________. (Integer based)
–OHCH3, –NO2, –CN, –CH3, –NHCOOH3, –COR, –OH, –COOH, –Cl
Ans. (4)
Sol. (II), (III), (VI) and (VIII) are classified as meta directing group.
88. Consider the following data for the given reaction

2H(g)  H2(g) + 2(g)
1 2 3
H (mol L–1) 0.005 0.01 0.02
Rate (mol L–1s–1) 7.5 × 10–4 3.0 × 10–3 1.2 × 10–2
The order of the reaction is ________.
Ans. (2)
Sol. As we see, on doubling the concentration, rate becomes four times therefore n = 2.
89. The mass of silver (Molar mass of Ag : 108 gmol–1) displaced by a quantity of electricity which displaces
5600 mL of O2 at S.T.P. will be ______ g.
Ans. (108)
5600 1
Sol. nO 2   mole
22400 4
Anode : 2H2O()  O2(g) + 4H+ + 4e–
1
mole 1F
4
Cathode : Ag+ + e–  Ag(s)
1F 1 mole (108g)
90. From the given list, the number of compounds with +4 oxidation state of Sulphur is ________ .
SO3, H2SO3, SOCl2, SF4, BaSO4, H2S2O7
Ans. (3)
Sol
Species SO3 SF4 H2SO4 BaSO4 H2S2O7 SO2 SOCl2
Oxidation state of sulphur +6 +4 +6 +6 +6 +4 +4

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SHIFT-1

27th January 2024 & Saturday

62. Given below are two statements :

(C) MeO OH (D) OH

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NO2 NO2 OCH3

65. Two nucleoptides are joined together by a linkage known as :

66. Given below are two statements :

68. Consider the following complex ions

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70. Which of the following has highly acidic hydrogen ?

71. Given below are two statements :

72. Which of the following is strongest Bronsted base?

73. Choose the polar molecule from the following :

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74. IUPAC name of following compound (P) is :

75. Highest enol content will be shown by :

76. The electronic configuration for Neodymium is :

77. Cyclohexene is ________ type of an organic compound.

78. Element not showing variable oxidation state is :

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85. Sum of bond order of CO and NO+ is ________.

88. Consider the following data for the given reaction

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