(Main) : Computer Based Test (CBT)

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2021
COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 26 August, 2021 (SHIFT-1) | TIME : (9.00 a.m. to 12.00 p.m)
w
Duration: 3 Hours | Max. Marks: 300
SUBJECT : CHEMISTRY
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| JEE MAIN-2021 | DATE : 26-08-2021 (SHIFT-1) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
PART : CHEMISTRY
Section : Chemistry Section A
1. The major products formed in the following reaction sequence A and B are :
fuEufyf[kr vfHkfØ;k Øe esa fojfpr eq[; mRikn A rFkk B gS :
O
Br2
CH3  A + B
KOH
O
(1) A = C CBr3 ; B= CHO
O O
(2) A = C CH2–Br ; B= C CH2–OH
Br Br
O
(3) A = C OK ; B = CHBr3
Br O HO O
(4) A = C CH3 ; B= C CH3
Br HO
Ans. (3)
Sol. It is Haloform reaction.
O
O
Br2
CH3  C OK + CHBr3
KOH
2. Given below are two statements.

Statement-I : The choice of reducing agents for metals extraction can be made by using Ellingham
diagram, a plot of G vs temperature.
Statement-II : The value of S increases from left to right in Ellingham diagram.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Statement-I is false but Statement-II is true.
(2) Both Statement-I and Statement-II are false.
(3) Statement-I is true but Statement-II is false.
(4) Both Statement-I and Statement-II are true.
uhps nks dFku fn;k gSA
dFku-I : ,fya?ke vkys[k] (G dk rki ds fo:) ,d vkjs[k), dk mi;ksx dj /kkrq fu"d"kZ.k ds fy,] vip;u deZd
pquk tk ldrk gSA
dFku-II : S dk eku ,fya?ke vkys[k esa ck¡, ls nkfgus vkSj c<+rk gSA
mijksDr dFkuksa ds lanHkZ esa uhps fn, fodYiksa esa ls lgh mÙkj pqfu,A
(1) dFku-I vlR; gSa ijUrq dFku-II lR; gSA
(2) dFku-I rFkk dFku-II vlR; gSA
(3) dFku-I lR; gS ijUrq dFku-II vlR; gSA
(4) nksuksa dFku-I rFkk dFku-II lR; gSA
Ans. (3)
Sol. Ellingham diagram is used to check which metal oxide is reduced by which compound.

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3. Given below are two statements :

Statement-I : In the titration between strong acid and weak base methyl orange is suitable as an
indicator.
Statement-II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.
(1) Statement-I is false but Statement-II is true
(2) Both Statement-I and Statement-II are false
(3) Statement-I is true but Statement-II is false
(4) Both Statement-I and Statement-II are true
uhps nks dFku fn;k gSA
dFku-I : izcy vEy rFkk nqcZy {kkj ds e/; vuqekiu ds fy, esfFky vkWjsUt lwpd ds :i esa mi;qDr gSA
dFku-II : ,slhfVd vEy ds NaOH ls vuqekiu ds fy, QhukWy¶Fksfyu ,d mi;qDr lwpd ugha gSA
(1) dFku-I vlR; gS ijUrq dFku-II lR; gSA
Ans. (3)
Sol. (1) MeOH is suitable indicator for titration of strong acid and weak base.
(2) Hph is suitable indicator for titration of weak acid and strong base.
4. What the products formed in sequence when excess of CO 2 is passed in slaked lime ?
CO2 ds vkf/kD; dks cq>s pwuk esa izokfgr djus ij dkSu ls mRikn Øekuqlkj fojfpr gksrs gSA
(1) CaCO3, Ca(HCO3)2 (2) Ca(HCO3)2, CaCO3
(3) CaO, Ca(HCO3)2 (4) CaO, CaCO3
Ans. (1)
Pass Prolong
Sol. Slaked lime CaCO3 Ca(HCO3)2
CO2 Passage of CO2
5. Which one of the following methods is most suitable for preparing deionized water ?
(1) Permutit method (2) Synthetic resin method
(3) Calgon’s method (4) Clark’s method
fuEufyf[kr esa ls dkSulh ,d fof/k fovk;fur ty rS;’kj djus ds fy, lokZf/kd mi;qdr gS \
(1) ijE;wfVV fof/k (2) la'ysf"kr jsftu fof/k
(3) dsyxku fof/k (4) DykdZ fof/k
Ans. (2)
Sol. Pure de-mineralised (de-ionised) water free from all soluble mineral salt is obtained by passing water
successively through a cation exchange and an anion exchange resins.
2RH(S) + M2+ (aq) MR2 (S) + 2H+ (aq)
6. Which one of the following when dissolved in water gives coloured solution in nitrogen atmosphere ?
fuEufyf[kr esa ls dkSu lk ukbVªkstu ds ok;qeaMy esa ty esa ?kksyus ij jaxhu fofy;u nsrk gS ?
(1) Cu2Cl2 (2) CuCl2 (3) ZnCl2 (4) AgCl
Ans. (2)
Sol. CuCl2 dissolve in water & give coloured solutions.
AgCl not soluble in water.
Cu2Cl2 is not soluble in water.
ZnCl2 is soluble but colourless.

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7. Excess of isobutene on reaction with Br2 in presence of light at 125ºC gives which one of the following,
as the major product ?
125ºC ij izdk'k dh mifLFkfr esa vkblksC;wVsu ds vkf/kD; dh Br2 esa vfHkfØ;k fuEufyf[kr esa ls dkSu lk ,d eq[;
mRikn ds :i esa nsrh gS ?
CH3 Br
(1) CH3–C–Br (2) CH3–CH–CH2Br (3) CH3–C–CH2–Br (4) CH3–CH–CH2Br
CH3 CH2Br CH3 CH3
Ans. (1)
CH3 CH3 CH3
Br2 Br 
Sol. CH3–C–CH3  CH3–C  CH3–C–Br
h
CH3 CH3 CH3
3º radical Major product
(stable)
8. Which one of the following, is correct for the adsorption of a gas at a given temperature on a solid
surface ?
,d fn, rki ij ds Bksl dh lrg ij xSl ds vf/k'kks"k.k ds fy, fuEufyf[kr esa ls dkS u lk ,d lgh gS ?
(1) H < 0, S < 0 (2)H > 0, S < 0 (3)H > 0, S > 0 (4)H < 0, S > 0
Ans. (1)
Sol. Adsorption of gas on solid surface is exothermic process & entropy is decrease in this process so
H < 0, S < 0

Statement-I : Frekel defects are vacancy as well as interstitial defects.
Statement-II : Frenkel defect leads to colour in ionic solids due to presence of F-centres.
Choose the most appropriate answer for the statements from the options given below :
uhps nks dFku fn, gSaA
dFku-I : Ýsadsy nks"k fjfDrrk rFkk vUrjkdk'kh nks"k gSA
dFku-II : Ýsadsy nks"k] F-dsUnzksa dh mifLFkr ds dkj.k] vk;fud Bkslksa esa jx mRiUu djrk gSA
(1) nksuksa dFku-I rFkk dFku-II vlR; gSA
Ans. (2)
Sol. Frenkel defect is dislocation defect, it is not interstitial defect and it is not responsible for colour of solid.
Note : NTA ans. is (2), But Reso ans. Is (1).

Statement-I : The limiting molar conductivity of KCl (strong electrolyte) is higher compared to that of
CH3COOH (weak electrolyte).
Statement-II : Molar conductivity decreases with decrease in concentration of electrolyte.

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uhps nks dFku fn;k gS&

dFku-I : KCl (izcy oS|qr vi?kV~;) dh lhekar eksyj pkydrk CH3COOH (nqcZy oS|qr vi?kV~;) ds eku dh rqyuk
esa vf/kd gSA
dFku-II : fo|qr vi?kV~; dh lkUnzrk ?kVus ij eksyj pkydrk ?kV tkrh gSA
mijksDr dFkuksa ds lanHkZ esa uhps fn, fodYiksa esa lg lgh mÙkj pqfu,A
(1) dFku-I lR; gSa ijUrq dFku-II vlR; gSA
Ans. (4)
Sol.
Ion K+ Cl– CH3COO– H+
º/(S cm2mol–1) 73.5 76.3 40.9 349.6
ºM(CH3COOH) = ºM(H+) + ºM(CH3COO–)

= 349.6 + 40.9 = 390.5 S cm 2mol–1
ºM(KCl) = ºM(K+) + ºM(Cl–)
= 73.5 + 76.3 = 149.8 S cm2mol–1
So, statement-I is false.
For an electrolyte the dilution increases (or) decrease in
concentration, the number of ions increases due to increase
of degree of dissociation. So, the molar conductance
increases. Hence Statement-II is false.
11. The incorrect statement is :

(1) On hydrolysis CIF forms HOCl and HF.
(2) Cl2 is more reactive than CIF.
(3) F2 is more reactive than CIF.
(4) F2 is a stronger oxidizing agent than Cl2 in aqueous solution.
xyr dFku gS&
(1) CIF ty vi?kVu ls HOCl rFkk HF cukrh gSA
(2) CIF dh vis{kk Cl2 vf/kd vfHkfØ;k'khy gSA
(3) CIF dh vis{kk F2 vf/kd vfHkfØ;k'khy gSA
(4) tyh; foy;u esa Cl2 dh vis{kk F2 ,d izcy vkWDlhdj.k deZd gSA
Ans. (2)
Sol. In general, interhalogen compounds are more reactive than halogens (except fluorine). This is because
X–X′ bond in interhalogens is weaker than X–X bond in halogens except F–F bond. All these undergo
hydrolysis giving halide ion derived from the smaller halogen and a hypohalite (when XX′), halite (when
XX′3), halate (when XX′5) and perhalate (when XX′7) anion derived from the larger halogen.
XX’ + H2O  HX’ + HOX
12. The conversion of hydroxyapatite occurs due to presence of F – ions in water. The correct formula of
hydroxyapatite is :
ty esa F– vk;u dh mifLFkfr ds dkj.k gkbMªkWDlh,isVkbV esa ifjorZu gks tkrk gSA gkbMªkWDlh,isVkbV dk lgh lw=k
gS:
(1) [3Ca3(PO4)2.CaF2] (2) [3Ca(OH)2.CaF2]
(3) [Ca3(PO4)2.CaF2] (4) [3Ca3(PO4)2.Ca(OH)2]
Ans. (4)
Sol. Hydroxyapatite  [3Ca3(PO4)2.Ca(OH)2]
Hydroxyapatite in presence of F– ions converts to fluorapatite [3Ca3(PO4)2.CaF2].

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Statement-I : According to Bohr’s model of an atom, qualitatively the magnitude of velocity of electron
increases with decrease in positive charges on the nucleus as there is no strong hold on the electron by
the nucleus.
Statement-II : According to Bohr’s model of an atom, qualitatively the magnitude of velocity of electron
increases with decrease in principal quantum number.
In the light of the above statements, choose the most appropriate answer from the options gien below :
uhps nks dFku fn, gSaA
dFku-I : ijek.kq ds cksj ds ekWMy ds vuqlkj bysDVªkWu ds osx dk ifjek.k xq.kkRed :i ls ukfHkd ij /kukos'k ?kVus
ds lkFk] c<+rk gS D;ksafd bysDVªkWu ij ukfHkd dk dksbZ izcy ca/ku ugha jgrk gSA
dFku-II : ijek.kq ds cksj ds ekWMy ds vuqlkj bysDVªkWu ds osx dk ifjek.k xq.kkRed :i ls eq[; DokUVe la[;k ?kVus
ds lkFk c<+rk gSA
Ans. (2)
Z
Sol. Vn = (2.18 × 106) × m/sec ; Vn  1 ; n, Vn
n n
14. Which one of the following complexes is violet in colour ?

fuEufyf[kr ladqyksa esa ls fdl ,d dk jax cSaxuh gS \
(1) Fe4[Fe(CN)6]3.H2O (2) [Fe(CN)5NOS]4–
(3) [Fe(CN)6]4– (4) [Fe(SCN)6]4–
Ans. (2)
Sol. S2– + Na2[Fe(CN)5(NO)+]  Na4[Fe(CN)5(NOS)]
Sodium nitroprusside Violet colour
15. The correct sequential addition of reagents in the preparation of 3-nitrobenzoic acid from benzene is :
csUthu ls 3-ukbVªkscsUtksbd vEy rS;kj djus ds fy,] vfHkdeZdksa ds ladyu dk lgh Øe gS&
(1) Br2/AlBr3, HNO3/H2SO4, Mg/ether, CO2, H3O+
(2) Br2/AlBr3, NaCN, H3O+, HNO3/H2SO4
(3) HNO3/H2SO4, Br2/AlBr3, Mg/ether, CO2, H3O+
(4) Br2/AlBr3, HNO3/H2SO4, NaCN, H3O+
Ans. (3)
NO2 NO2 NO2 NO2
Sol.
HNO3 Br2 Mg/ether CO2/H3O+
H2SO4 AlBr3
Br MgBr COOH

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16. The major product formed in the following reaction is :

H Br Major product
(excess)
fuEufyf[kr vfHkfØ;k esa fojfpr eq[; mRikn gS&
H Br
eq[; mRikn
(vkf/kD;)
Br
Br Br Br
(1) (2) (3) (4)
Br Br
Br
Ans. (2)
Sol. H Br 

Br –
Br
Major product
Br (More stable alkene)
At 25ºC thermodynamicaly controlled Product is formed as major product.
17. The correct options for the products A and B of the following reactions are :
fuEufyf[kr vfHkfØ;k esa mRikn A rFkk B ds fy, lgh fodYi gS :
OH
Br (Excess ) Br
A 2   
2
 B
H2O CS2 , 5 º C
OH OH OH OH
Br Br Br
(1) A = , B= (2) A = , B=
Br
Br Br Br
OH OH OH OH
Br Br Br Br Br
(3) A = ,B= (4) A = ,B=
Br Br Br Br
Ans. (4)
OH OH OH
Br
Sol. Br2
+
CS2
Br
(Major)
OH OH
Br Br
Br2
H2O
Br

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18. The polymer formed on heating Novolac with formaldehyde is :

(1) Bakelite (2) Polyester (3) Melamine (4) Nylon 6, 6
uksoksysd dks QkWesZYMhgkbV ds lkFk xeZ djus ij tks cgqyd curk gSa] og gS&
(1) cSdkykbV (2) ikWfy,LVj (3) esySehu (4) ukbyku 6, 6
Ans. (1)
Sol. Note Novalac on heating with formaldehyde undergoes cross linking to form infusible solid mass
called Bakelite.
19. Among the following compounds I-IV, which one forms a yellow precipitate on reacting sequentially with
(i) NaOH (ii) dil. HNO3 (iii) AgNO3 ?
fuEufyf[kr ;kSfxdksa I-IV esa ls dkSu&lk ,d (i) NaOH (ii) dil. HNO3 rFkk (iii) AgNO3 ls bl Øe esa vfHkfØ;k djds
ihyk vo{ksi cukrk gS ?
Cl Br Cl
Cl
CH3 CH2
H3 C
CH3
   V
(1) I (2) III (3) II (4) IV
Ans. (4)
Cl
Sol. Only in , I– can be substituted by OH–, I– combine with Ag+ to form yellow ppt of AgI. While
CH2
in I, II and III substitution reaction is not possible due to partial double bond character.
20. The major product formed in the following reaction is :
COOH SOCl , CH OH
2 3
Major Product
N NH 2
H
fuEufyfpjr vfHkfØ;k esa fojfpr eq[; mRikn gS&
COOH SOCl , CH OH
2 3
eq[; mRikn
N NH2
H
CO2CH3 Cl CO2Me
(1) (2)
N NH2.HCl N NH2
H H
COCl CO2CH3
(3) (4)
N NH2 N NH2.HCl
H H.HCl
Ans. (1)
COOH COCl
SOCl2
Sol.
N NH2 N NH2
H H
CH3OH
CO2CH3 COOCH3
NH2.HCl + HCl
N N NH2
H H

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Section : Chemistry Section B

1. The number of 4f electrons in the ground state electronic configuration of Gd 2+ is.……….
[Atomic number of Gd = 64]
Gd2+ ds fuEure voLFkk bysDVªkWfud foU;kl esa 4f bysDVªkWuksa dh la[;k gS.……….
[Gd dh ijek.kq la[;k = 64]
Ans. (7)
Sol. Gd = [Xe] 4f7 5d1 6s2
Gd2+ = [Xe] 4f8 [due to orbital contraction]
2. An aqueous KCl solution of density 1.20 g mL–1 has a molality of 3.30 mol kg–1. The molarity of the
solution in mol L–1 is…………. (Nearest integer)
KCl ds ,d tyh; foy;u dk ?kuRo 1.20 g mL–1 rFkk eksyyrk 3.30 mol kg–1 gSA bl foy;u dh eksyjrk
mol L–1 gS…………. (fudVre iw.kkZd esa)
Ans. (3)
 M  1000 
Sol. Molality (m) =  
1000 d  M  Msolute 
M  1000
3.3 =
1000 1.20  M  74.5
3960 – 245.85 M = 1000 M
1245.85 M = 3960
3960
M= = 3.17  3 M
1245.85
3. AB3 is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is………
(Integer answer)
AB3 ,d T-vkd`fr dk varjk&gSykstu v.kq gSA A ij bysDVªkWu ;qXeksa dh la[;k gS………
(fudVre iw.kkZd esa)
Ans. (2)
Sol. In interhalogen compound AB3
Central atom A is halogen so it contain 7 electrons in its outer most shell.
so its structure is
B
A B T-shape
B
So central atom A contain 2 lone pairs of electrons.
4. Of the following four aqueous solutions, total number of those solutions whose freezing point is lower
than that of 0.10 M C2H5OH……….. (Integer answer)
(i) 0.10 M Ba3(PO4)2 (ii) 0.10 M Na2SO4 (iii) 0.10 M KCl (iv) 0.10 M Li3PO4
uhps fn, pkj tyh; foy;uksa esa ls mu foy;uksa dh dqy la[;k ftudk fgekad 0.10 M C2H5OH ds fgekad ls uhps
gS……….. (fudVre iw.kkZd esa)
(i) 0.10 M Ba3(PO4)2 (ii) 0.10 M Na2SO4 (iii) 0.10 M KCl (iv) 0.10 M Li3PO4
Ans. (4)

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Sol. Tf = ikfm

As m is same for all solution so Tf depends on vantHoff factor (i).
Greater is i small is freezing point.
Compound i
C2H5OH 1
Ba3(PO4)2 5
Na2SO4 3
KCl 2
Li3PO4 4
So the given solutions have lower freezing point than ethanol.
5. The Born-Haber cycle for KCl is evaluated with the following data :
ƒH for KCl = – 436.7 kJ mol–1 ; subH for K = 89.2 kJ mol–1 ;
ionizationH for K = 419 kJ mol–1 ; electron gainH for Cl(g) = –348.6 kJ mol–1 ;
bondH for Cl2 = 243.0 kJ mol–1
The magnitude of lattice enthalpy of KCl in kJ mol–1 is…………. (Nearest integer)
KCl ds fy, ckWuZ gkcj pØ dk ewY;kadu fuEufyf[kr vk¡dM+ks ds vk/kkj ij fd;k x;k gS&
KCl ds fy,ƒH = – 436.7 kJ mol–1 ; K ds fy, subH = 89.2 kJ mol–1 ;
K ds fy, ionizationH = 419 kJ mol–1 ; Cl(g) ds fy, electron gainH = –348.6 kJ mol–1 ;
Cl2 ds fy, bondH = 243.0 kJ mol–1
KCl dh tkyd ,UFkSYih dk ifjek.k kJ mol–1 esa gS…………. (fudVre iw.kkZd esa)
Ans. (718)
Sol. K(s) + ½Cl2(g)  KCl(s); ƒHº = –436.7 kJ mol–1
sub.Hº=89.2 bondHº=243/2
K(g) Cl(g) latticeHº

ionHº=419
ele. gainHº=–348.6
K+(g) Cl–(g)
so, ƒH = ƒH (KCl) = subH + 1st ionisationH(K) + ½bondH(Cl2(g)) + electron gainH + latticeH
 
– 436.7 = 89.2 + 419 + ½(243) + (–348.6) + latticeH

latticeH = – 717.8 kJ mole–1  – 718 kJ mole–1
6. These are physical properties of an element

(A) Sublimation enthalpy (B) Ionisation enthalpy
(C) Hydration enthalpy (D) Electron gain enthalpy
The total number of above properties that affect the reduction potential is………
(integer answer)
;g rRo ds HkkSfrd xq.k gS&
(A) m/oZikru ,sUFkSYih (B) vk;uu ,sUFksYih
(C) ty;kstu ,UFkSYih (D) bysDVªkWu yC/kh ,sUFksYih
mijksDr xq.kksa esa ls mudh dqy la[;k tks vip;u foHko dks izHkkfor djrs gS………
Ans. (3)

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M(s) Mn+(aq) ; Hrnx

Hsublimation HHyd
Sol.
M(g) Mn+(g) + ne–
HIE
So reduction potential depends of sublimation, ionization and Hydration energy.
7. The ratio of number of water molecules in Mohr’s salt and potash alum is……… × 10 –1.
(integer answer)
eksj yo.k rFkk iksVs'k fQVdjh esa ty ds v.kqvksa dh la[;k dk vuqikr gS ……… × 10–1.
Ans. (5)
Sol. Mohr's salt = FeSO4(NH4)2SO4·6H2O
Potashalum = K2SO4·Al2(SO4)3 · 24H2O
So water molecule ratio = 
6  1
 = = 0.25 = 2.5 × 10–1.
 24  4
Note : NTA ans. is 5, but Reso ans. is 2.5.
8. The following data was obtained for chemical reaction given below at 975 K.
2NO(g) + 2H2(g)  N2(g) + 2H2O(g)
[NO] [H2] Rate
mol L–1 mol L–1 mol L–1 s–1
(A) 8 × 10–5 8 × 10–5 7 × 10–9
(B) 24 × 10 –5 8 × 10 –5 2.1 × 10–8
(C) 24 × 10 –5 32 × 10 –5 8.4 × 10–8
The order of the reaction with respect to NO is………… [Integer answer]
uhps nh x;h jklk;fud vfHkfØ;k ds fy, 975 K ij fuEufyf[kr vk¡dM+s izkIr gq, :
2NO(g) + 2H2(g)  N2(g) + 2H2O(g)
[NO] [H2] nj
mol L –1 mol L –1 mol L–1 s–1
(A) 8 × 10 –5 8 × 10 –5 7 × 10–9
(B) 24 × 10–5 8 × 10–5 2.1 × 10–8
(C) 24 × 10–5 32 × 10–5 8.4 × 10–8
NO ds izfr vfHkfØ;k dh dksfV gSa………… [fudVre iw.kkZd esa]
Ans. (1)
Sol. rate = K[NO]x [H2]y
From (A) 7 × 10–9 = K(8 × 10–5)x (8 × 10–5)y …………. (1)
From (B) 2.1 × 10–8 = K(24 × 10–5)x (8 × 10–5)y …………. (2)
7  109 K(8  105 ) x (8  105 ) y
(1)/(2)  =
2.1 108 K(24  105 ) x (8  105 ) y
x
 1  1
  =  
3 3
 x=1
Order of reaction w.r.t. NO is x = 1.

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9. The OH– concentration in a mixture of 5.0 mL of 0.0504 M NH4Cl and 2 mL of 0.0210 M NH3 solution is
x × 10–6 M. The value of x is…………. (Nearest integer)
[Given Kw = 1 × 10–14 and kb = 1.8 × 10–5]
0.0504 M NH4Cl ds 5.0 mL rFkk 0.0210 M NH3 foy;u ds 2 mL ds feJ.k esa OH– dh lkUnzrk x × 10–6 M gSA x
dk eku gS…………. (fudVre iw.kkZd esa)
[fn;k gS : Kw = 1 × 10–14 and kb = 1.8 × 10–5]
Ans. (3)
Sol. [NH4Cl] = [NH4+] = 0.0504 M V = 5.0 mL
[NH3] = 0.0210 M V = 2.0 mL
[NH4 ][OH ]
Kb =
[NH3 ]
K b  [NH3 ] 1.8  10 5  0.0210  2
[OH–] = = = 3 × 10–6 M
[NH4 ] 0.0504  5
10. The total number of negative charge in the tetrapeptide, Gly-Glu-Asp-Tyr, at pH 12.5 will be……….
(Integer answer)
pH 12.5 ij VsVªkisIVkbM Gly-Glu-Asp-Tyr esa _.k vkos'k dh dqy la[;k gksxh……….
(Integer answer)
Ans. (4)
O O
CH2–C–OH COOH CH2–C– O– COO–
pH 12.5
Sol. NH2–CH2–C–NH–CH–C–NH–CH–C—NH—CH2 
 NH2–CH2–C–NH–CH–C–NH–CH–C—NH—CH2
O O O O O O
CH2–CH2–C–OH CH2–CH2–C– O–
O O
OH O–

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7340010333
Ph. No.: +91-744-2777777, 2777700 | FAX No. : +91-022-39167222
7340010333
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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Duration: 3 Hours | Max. Marks: 300

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2. Given below are two statements.

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uhps nks dFku fn;k gS&

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Section : Chemistry Section B

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– 436.7 = 89.2 + 419 + ½(243) + (–348.6) + latticeH

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