JEE Main 2022 June Session 1 Shift-2 (DT 27-06-2022) Chemistry

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2022
COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 27 June, 2022 (SHIFT-2) | TIME : (3.00 a.m. to 6.00 p.m)
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Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2022 | DATE : 27-06-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
PART : CHEMISTRY
1. Identify correct order of increasing ionic radii.
(1) Mg2+, Na+, F–, O2–, N3– (2) N3– , O2– , F– , Na+ , Mg2+
(3) F–, O2–, N3–, Na+, Mg2+ (4) Mg2+, F–, Na+, O2–, N3–
Ans. (1)
Sol. Species N3– O2– F– Na+ Mg2+
No. of e– 10 10 10 10 10
Z 7 8 9 11 12
For isoelectronic specie greater is Z smaller is size of ion.
2. Which of the following lanthanide have half-filled and full filled ƒ-orbital respectively.
(1) Eu2+, Tb3+ (2) Yb3+, Tb2+ (3) Gd3+, Dy2+ (4) Sm2+, Dy2+
Ans. (3)
Sol. Ion Electronic configuration
Eu2+ 4f7
Tb2+ 4f9
Tb3+ 4f8
Gd3+ 4f7
Dy2+ 4f10
Sm2+ 4f6
3. Statement-I : Fluorine form only one oxoacid.

Statement-II : Due to high electronegativity and small size.
(1) Both Statement-I & Statement-II are true (2) Both Statement-I & Statement-II are false
(3) Statement-I is true & Statement-II is false (4) Statement-I is false & Statement-II is true
Ans. (1)
Sol. Due to small size & high electronegativity F can not act as central atom in higher oxidation state so F
form only one oxy acid HOF.
4. Which of the following statement is incorrect regarding PCl5.

(1) In PCl5 axial bonds are longer than equatorial bonds
(2) It has trigonal by pyramidal structure
(3) 3Cl atoms are in same plane
(4) Hybridisation of 'P' is sp3d2
Ans. (4)

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Cl
Cl
Sol. P Cl
Cl
Cl
Hybridisation = sp3d
5. Identify correct increasing strength of intermolecular H-bonding.

(1) HCN < H2O < NH3 (2) NH3 < HCN < H2O (3) CH4 < HCN < NH3 (4) CH4 < NH3 < H2O
Ans. (3)
Sol. Correct order of H-bond strength is :
CH4 < HCN < NH3
6. Identify correct set which represent increasing order of magnetic moment.

(a) [FeF6]3– (b) [Fe(CN)6]3–
(c) [Mn(CN)6]2– (d) [Mn(Cl)6]2– (high spin)
(1) b < c < d < a (2) a < b < c < d (3) a < d < c < b (4) d < c < b < a
Ans. (1)
Sol. Complex Electronic configuration No. of unpaired electron
1,1,1 1,1
(a) [FeF6]3– Fe3+  3d5 𝑡2𝑔 , 𝑒𝑔 5
2,2,1 0,0
(b) [Fe(CN)6]3– Fe3+  3d5 𝑡2𝑔 , 𝑒𝑔 1
2,1,1 0,0
(c) [Mn(CN)6]2– Mn4+  3d4 𝑡2𝑔 , 𝑒𝑔 2
1,1,1 1,1
(d) [Mn(Cl)6]2– (high spin) Mn4+  3d5 𝑡2𝑔 , 𝑒𝑔 4
7. Which of the following have high value of reduction potential (𝐸°𝑀2+ | 𝑀 )

(1) Zn (2) Cr (3) Cu (4) Fe
Ans. (3)
Sol. 𝐸°𝑍𝑛2+|𝑍𝑛 = – 0.76 V
𝐸°𝐶𝑟 2+|𝐶𝑟 = – 0.91 V
𝐸°𝐶𝑢2+|𝐶𝑢 = 0.34 V
𝐸°𝐹𝑒 2+ |𝐹𝑒 = – 0.44 V
8. Which gas is produced during following reaction :

∆
NH4Cl + NaNO2 → Product
(1) NH3 (2) N2 (3) Cl2 (4) N2O
Ans. (2)

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∆
Sol. NH4Cl + NaNO2 → NaCl + NH4NO2
∆
NH4NO2 → N2(g) + 2H2O
9. Match athe acid radicals present in Column I with their characteristic observation in Column II
Column I Column II
(i) CO32– (P) Brisk effervescence
(ii) NO3– (Q) White PPT
(iii) SO42– (R) Brown Ring
(iv) S2– (S) Rotten egg smell
(1) (i) – (P) ; (ii) – (R) ; (iii) – (Q) ; (iv) – (S) (2) (i) – (S) ; (ii) – (R) ; (iii) – (Q) ; (iv) – (P)
(3) (i) – (P) ; (ii) – (R) ; (iii) – (S) ; (iv) – (Q) (4) (i) – (P) ; (ii) – (Q) ; (iii) – (R) ; (iv) – (S)
Ans. (1)
– 𝐻+
Sol. (i) CO32 → CO2
–
(i) NO3 + FeSO4 + H2SO4  [Fe(H2O)5(NO+)]SO4
Brown ring
𝐵𝑎𝐶𝑙2
(iii) SO42– → BaSO4
White PPT
𝐻+
(iv) S2– → H2S
Rotten egg smell
10. How many set of quantum numbers are possible.

n  m n  m
(a) 2 2 1 (b) 3 2 –2
(c) 3 2 –1 (d) 2 1 –1
Ans. (3)
Sol. For possible set of quantum number.
n > , m = – to + (including zero).
Correct set are b, c, d.
11. Find pH of 0.001 M NaOH solution.

Ans. (11)
Sol. NaOH  Na+ + OH–
10–3 M 10–3 M 10–3 M
[OH–] = 10–3 pOH = 3
pH = 11

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12. Which of the following graph is correct for an ideal gas

T1 T1
T2 T2
P P
(1) T3 T1 > T2 > T3 (2) T3 T3 > T2 > T1
d d
P T3 P T3
(3) T2 T3 > T2 > T1 (4) T2 T1 > T2 > T3
T1 T1
d d
Ans. (1)
Sol. PV = nRT
𝑤 𝑅𝑇
P=[ ]
𝑉 𝑀
𝑑𝑅𝑇 𝑅𝑇
P= so P  d Slope =
𝑀 𝑀
Greater is slope greater is Temperature.
𝑥
13. At 1.003 atm pressure value of ( ) will be
𝑚
Slope=1
log(x/m) 45ºC
0.602
log P
Report your answer to nearest integer.
Ans. (4)
𝑥
Sol. ( ) = K P1/n
𝑚
𝑥 1
log ( ) = log K + log P
𝑚 𝑛
Intercept log K = 0.602 = log 4

K=4
1
Slope  =1 so n=1
𝑛
𝑥
so ( ) = 4(1.003) = 4.012
𝑚
14. 2.5 × 10–3 kg of a non-volatile & non electrolyte solute dissolve in 75 × 10–3 kg of water. If Boiling point of
solution is 373.67 K, then molar mass of solute in gram is :
[Given (𝑇º𝑏 )𝐻2𝑂 = 373.15 K and Kb(H2O) = 0.52 K.Kg/mole]
(Report your answer to nearest integer)
Ans. (333)

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Sol. Boiling point of solution (Tb) = 373.67 K

Boiling point of solvent (Tºb) = 373.15 K
Tb = (Tb – Tºb)
Tb = 0.52
Tb = (Kb)m
2.5×1000
0.52 = 0.52[ ]
𝑀𝑠𝑜𝑙𝑢𝑡𝑒 ×75
Msolute = 333.33 g/mol
15. 5 mole of an ideal gas change it's volume from 10 L to 20 Lit. reversible isothermally at 300 K then work
done by gas is……..KCal. [Given R = 2 Cal]
Ans. (2)
Sol. For isothermal reversible process
𝑉
W = –2.303 nRT log ( 2)
𝑉1
20
= –2.303 × 5 × 2 × 300 log ( )
10
= –2072.7 Cal = –2.0727 × 103 Cal = –2 K Cal = |W| = 2 K Cal
16. 0.25 gram of an organic compound containing chlorine treated with excess of AgNO3, which gives 0.4
gram of AgCl as precipate out in carius method, then % of chlorine in organic compound is …………. .
[Report your answer to nearest integer]
Ans. (40)
𝐴𝑔𝑁𝑂3
Sol. Organic compound → AgCl
(Containing chlorine) 0.4 gram
0.25 gram
0.4
Mole of AgCl = ( )
143.5
0.4
wCl = ( ) × 35.5
143.5
0.4 100
% of Cl = [ × 35.5] × = 39.58  40
143.5 0.25
n2
17. Statement-I : h = (E2 – E1) absorb photon.
n1
n2
Statement-II : h = E2 – E1 = emitted photon.
n1
(1) Both Statement-I & Statement-II are true (2) Both Statement-I & Statement-II are false
(3) Statement-I is true & Statement-II is false (4) Statement-I is false & Statement-II is true
Ans. (1)
Sol. In this process absorbed & emitted photon have equal energy.

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18. For following cell

Pt(s)|H2(g)|H+(aq)||Ag+|Ag(s) Eocell= 0.302 V
Value of G° is [–X] × 103 J then value of X is :
[Report your answer to nearest integer]
Ans. (29)
1
Sol. Anode  H2(g)  H+(aq) + e–
2
Cathode  Ag+ + e–  Ag(s)

______________________________
1 𝑛=1
H2(g) + Ag+(aq) → H+(aq) + Ag(s)
2
G° = –nFE°cell = –1 × 96500 × 0.302

= –29143 J = –29.143 × 103J
19. The correct match of the product given in Column-II with the reaction in Column-I is.
Column-I Column-II
O
OH
(A) Na2S2O8 (i)

H2SO4
O
OH
OH
CHO
(B) CHCl3,KOH (ii)
OH
OH
(C) Br2,CS2 (iii)
Br
OH
(D) Zn (iv)
(1) (A)-(i), (B)-(ii), (C)-(iii), (D)-(iv) (2) (A)-(ii), (B)-(i), (C)-(iv), (D)-(iii)
(3) (A)-(iv), (B)-(ii), (C)-(iii), (D)-(i) (4) (A)-(iii), (B)-(i), (C)-(iv), (D)-(ii)
Ans. (1)

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20. Which is most stable.
 
(1) (2)

(3) (4)
Ans. (4)
(i) Fe, Br2

21. major product.
(ii) Cl2/
(iii) alc.KOH
Major product is:
CCH Cl CH2 CCH–Cl
(1) (2) (3) (4)
Br Br Br Br
Ans. (1)
22. The correct match of the effects given in Column-II with the drug type given in Column-I.
Column-I Column-II
(A) Tranquiliser (1) Pan reliever
(B) Antipyretic (2) Reduce acidity
(C) Analgesic (3) Reduce stress
(D) Antacid (4) Reduce fever
(1) (A)-(3), (B)-(4), (C)-(1), (D)-(2) (2) (A)-(2), (B)-(3), (C)-(4), (D)-(1)
(3) (A)-(3), (B)-(1), (C)-(1), (D)-(1) (4) (A)-(1), (B)-(3), (C)-(2), (D)-(4)
Ans. (1)
23. Which of the following is incorrect about Buna-N?

(1) N stands for acrylonitrile (2) Buna-N is formed by butadiene & styrene
(3) Buna-N is a addition polymer (4) Buna-N is a copolymer
Ans. (1)

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24. Statement-I : Maltose is formed by C1–C4 glycosidic linkage between two D(+) glucose units that are
reducing sugar.
Statement-II : Maltose is formed by C1–C6 glycosidic linkage between two D(+) glucose & D(+)
glucose.
(1) Statement-I is true & Statement-II is false (2) Statement-I & Statement-II both are true
(3) Statement-I & II both are false (4) Statement-I is false & Statement is true
Ans. (1)
1. nBuLi
25. nBu–CCH Major product
2. nC5H11Cl
3. H2–Pd, BaSO4
n-Bu n-Bu C5H11 n-Bu C5H11

n-Bu C5H11
(1) (2) (3) (4)
C5H11 n-Bu n-Bu
Ans. (1)
26. A compound has molecular formula C6H3(NH2)2COOH has six structural isomers, on decarboxylation out
of six, three compounds give same product (A), another two isomers give same product (B) & remaining
isomer give one product (C). Find melting point of (C).
(1) 143ºC (2) 104ºC (3) 73ºC (4) 47ºC
Ans. (1)
NH2 NH2 NH2 NH2
COOH COOH
Sol. , & give (A) on
NH2 H2N COOH H2N NH2
decarboxylation.
NH2
NH2 NH2 NH2
NH2 NH2
& give (B) .
COOH COOH
NH2
NH2
COOH
& give (C)

NH2
NH2
(C) has highest melting point.

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JEE Main 2022 June Session 1 Shift-2 (DT 27-06-2022) Chemistry

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JEE Main 2022 June Session 1 Shift-2 (DT 27-06-2022) Chemistry

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Duration: 3 Hours | Max. Marks: 300

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3. Statement-I : Fluorine form only one oxoacid.

4. Which of the following statement is incorrect regarding PCl5.

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5. Identify correct increasing strength of intermolecular H-bonding.

6. Identify correct set which represent increasing order of magnetic moment.

7. Which of the following have high value of reduction potential (𝐸°𝑀2+ | 𝑀 )

8. Which gas is produced during following reaction :

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10. How many set of quantum numbers are possible.

11. Find pH of 0.001 M NaOH solution.

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12. Which of the following graph is correct for an ideal gas

Greater is slope greater is Temperature.

Intercept log K = 0.602 = log 4

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Sol. Boiling point of solution (Tb) = 373.67 K

Msolute = 333.33 g/mol

= –2072.7 Cal = –2.0727 × 103 Cal = –2 K Cal = |W| = 2 K Cal

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18. For following cell

Cathode  Ag+ + e–  Ag(s)

G° = –nFE°cell = –1 × 96500 × 0.302

(A) Na2S2O8 (i)

(C) Br2,CS2 (iii)

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20. Which is most stable.

(i) Fe, Br2

Major product is:

CCH Cl CH2 CCH–Cl

(1) (2) (3) (4)

23. Which of the following is incorrect about Buna-N?

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n-Bu n-Bu C5H11 n-Bu C5H11

& give (C)

(C) has highest melting point.

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