(Main) : Computer Based Test (CBT)

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2021
COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 17 March, 2021 (SHIFT-2) | TIME : (3.00 p.m. to 6.00 p.m)
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Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
PART : CHEMISTRY
Single Choice Type
This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its answer,
out of which Only One is correct.
1. For the coagulation of a negative sol, the species below, that has the highest flocculating power is:
(1) PO 34– (2) Na+ (3) Ba2+ (4) SO 24–
Ans. (3)
Sol. For anion coagulation cation is used. Higher the charge on cation greater is its flocculation power.
2. The functional groups that are responsible for the ion-exchange property of cation and anion exchange
resins, respectively, are:
(1) –NH2 and –SO3H (2) –SO3H and –NH2 (3) –SO3H and –COOH (4) –NH2 and –COOH
Ans. (2)
Sol. Cation exchange resin contain RSO3H.
Anion exchange resin contain RNH2.
3. Nitrogen can be estimated by Kjeldahl's method for which of the following compound?
(1) (2) (3) (4)

N NO2 +
CH2–NH2 N N Cl–
Ans. (3)
Sol. Kjeldahl method is not applicable to compound containing nitrogen in nitro & azo group and nitrogen
present in ring (eg. Pyridine).
4. Match List-I with List-II:

List-I List-II
(a) CoNH3 6  Cr(CN)6  (i) Linkage isomerism
(b) CoNH3 3 (NO2 )3  (ii) Solvate isomerism
(c) Cr(H2O)6 Cl3 (iii) Co-ordination isomerism
(d) cis- [CrCl2 (ox)2 ]3 (iv) Optical isomerism

Choose the correct answer from the options givens below :
(1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv) (2) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
(3) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv) (4) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
Ans. (4)
Sol. Theory based.

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5. One of the by-products formed during the recovery of NH3 form Solvay process is:
(1) Ca(OH)2 (2) NaHCO3 (3) CaCl2 (4) NH4Cl
Ans. (3)
Sol. In Solvay process CaCl2 is obtained along with NH3 as by product.
OCH3
6. C7H2N2OCl + C2H5OH  + N2 + "X" + "Y"

(A)
In the above reaction, the structural formula of (A), "X" and "Y" respectively are:
–
N2+Cl– N2+OCH3
O H H
(1) , CH3 — C—H, HCl (2) ,
H O H , HCl
OCH3 Cl
–
N2+Cl– N2+OCH3
H H O
, , CH3 — C—H , H2O
(3) (4)
H O H , H2O
OCH3 Cl
Ans. (1)
+ –
N2Cl OCH3
C2H5OH
Sol. + CH3–CHO + HCl + N2
(A) (B)
OCH3
(C7H7) N2ClO
(P)
7. The set of elements that differ in mutual relationship from those of the other sets is:
(1) Li – Mg (2) B – Si (3) Li – Na (4) Be - Al
Ans. (3)
Li Be B C
Na Mg Al Si
Sol.
Li & Na are alkali metal but Li, Mg & Be, Al & B, Si have diagonal relationship.

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8. The common positive oxidation states for an elements with atomic number 24, are:
(1) +1 and +3 (2) +1 to +6 (3) +1 and +3 to +6 (4) +2 to +6
Ans. (4)
Sol. 24Cr = [Ar]3d54s1
9. Amongst the following, the linear species is:

(1) O3 (2) Cl2O (3) NO2 (4) N 3
Ans. (4)
Sol. N3 (azide ion is linear in shape)
  
N=N=N
sp
10. Fructose is an example of:

(1) Aldohexose (2) Heptose (3) Pyranose (4) Ketohexose
Ans. (4)
Sol. Fructose contains ketone group so it is ketose.
11. Choose the correct statement regarding the formation of carbocations A and B given.
+
CH3 — CH2—CH2—CH2 + Br
"A"
CH3—CH2—CHHBr
+
CH3 — CH2—CH—CH3 + Br–
"B"
(1) Carbocation B is more stable and formed relatively at slow rate

(2) Carbocation A is more stable and formed relatively at slow rate
(3) Carbocation A is more stable and formed relatively at faster rate
(4) Carbocation B is more stable and formed relatively at faster rate
Ans. (4)
+
CH3—CH2—CH2—CH2
Sol. "A" 1° Carocation
(2-H)
(Less stable)
+
CH3 — CH2—CH2—CH3
"B" 2° Carocation
(5-H)
(More stable)
So, Carbocation (B) is more stable and formed relatively at faster rate.

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12. Primary, secondary and tertiary amines can be separated using:

(1) para-Toluene sulphonyl chloride (2) Acetyl amide
(3) Benzene sulphonic acid (4) Chloroform and KOH
Ans. (1)
Sol. Hinsberg reagent (PhSO2Cl) is used to distinguish 1º, 2º and 3º amines.
13. The set that represents the pair of neutral oxides of nitrogen is:
(1) NO and N2O (2) NO and NO2 (3) N2O and NO2 (4) N2O and N2O3
Ans. (1)
Sol. Neutral oxide  NO & N2O
Acidic oxide  N2O3, NO2, N2O4
14. During which of the following processes, does entropy decrease?

(A) Freezing of water to ice at 0°C
(B) Freezing of water to ice at –10°C
(C) N2(g) + 3H2(g)  2NH3(g)
(D) Adsorption of CO(g) on lead surface.
(E) Dissolution of NaCl in water
Choose the correct answer from the options given below:
(1) (A), (B), (C) and (D) only (2) (B) and (C) only
(3) (A), (C) and (E) only (4) (A) and (E) only
Ans. (1)
Sol. In process I, II, III & IV entropy is decreases while is in process V entropy is increases.
15. Match List-I with List-II:

List-I List-II
(a) Haematite (i) Al2O3xH2O
(b) Bauxite (ii) Fe2O3
(c) Magnetite (iii) CuCO3Cu(OH)2
(d) Malachite (iv) Fe3O4
Choose the correct answer from the options given below:
(1) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) (2) (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
(3) (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv) (4) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
Ans. (1)
Sol. Ore Formula
(a) Haematite Fe2O3
(b) Magnetite Fe3O4
(c) Bauxite Al2O3.xH2O
(d) Malachite CuCO3.Cu(OH)2

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16. The correct pair(s) of the ambident nucleophilies is (are):

(A) AgCN/KCN (B) RCOOAg/RCOOK
(C) AgNO2/KNO2 (D) AgI/Kl
(1) (A) and (C) only (2) (A) only (3) (B) only (4) (B) and (C) only
Ans. (1)
Sol. Ambident ligands are those which have two donor sites but at once it has ability to donate either site.
Hence in AgCN/KCN, AgNO2/KNO2, CN, NO2 have two donar sites act as ambident Nu.
Enzyme A
17. C12H22 O11  H2O   C2H12 O6  C6H12 O6
Sucrose Glu cos e Fru cos e
Enzyme B
C 6H12 O 6    2C 2H5 OH  2CO2
Glu cos e
In the above reactions, the enzyme A and enzyme B respectively are:
(1) Amylase and Invertase (2) Zymase and Invertase
(3) Invertase and Amylase (4) Invertase and Zymase
Ans. (4)
Invertase
Sol. (a) Sugar    Glucose + Fructose
Zymase
(b) C6H12O6   2C2H5OH + 2CO2
18. Given below are two statements:

Statement I : 2-methylbutane on oxidation with KMnO4 gives 2-methylbutan-2-ol.
Statement II: n-alkanes can be easily oxidised to corresponding alcohols with KMnO 4
(1) Statement I is incorrect but statement II is correct
(2) Both Statement I and Statement II are correct
(3) Both Statement I and Statement II are incorrect
(4) Statement I is correct but Statement II is incorrect
Ans. (4)
Sol. Only tertiary hydrogen containing alkanes are oxidised by KMnO 4 to 3º alcohols.
19. Match List-II with List-II

List-I List-II
Chemical Compound Used as
(a) Sucralose (i) Synthetic detergent
(b) Gylceryl ester of stearic acid (ii) Artificial sweetener
(c) Sodium benzoate (iii) Antiseptic
(d) Bithionol (iv) Food preservative
Choose the correct match:
(1) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) (2) (a)-(i), (b)-(i), (c)-(iv), (d)-(iii)
(3) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i) (4) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

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Ans. (1)
Sol. (a) Sucrolose - Artificial sweetner
(b) Gylceryl ester of stearic acid - Synthetic detergent
(c) Sodium benzoate - Food preservative
(d) Bithionol - Antiseptic
20. Which of the following statement(s) is (are) incorrect reason for eutrophication?
(A) excess usage of fertilisers
(B) excess usage of detergents
(C) dense plant population in water bodies
(D) lack of nutrients in water bodies that prevent plat growth
Choose the most appropriate answer from the options given below:
(1) (C) only (2) (D) only (3) (A) only (4) (B) and (D) only
Ans. (2)
Sol. Theory based
Numerical Value Type

This section contains 10 Numerical value type questions.
21. On complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in the
formation of product A. The secondary valency of Fe in the produce A. The secondary valency of Fe in
the product A is________. (Round off to the Nearest Integer).
Ans. (6)
KOH
Sol. FeCl3 + oxalate   [Fe(C2O4)3]3–
Secondary valency = 6
O
C O
22. Cl
+ C6H5NHC6H5 C6H5 —C—N—(C6H5)2
0.140 g 0.388 g 0.210 g
Consider the above reaction. The percentage yield of amide product is____________(Round off to the
Nearest Integer). (Given: Atomic mass : C : 12.0 u, H : 1.0 u, N : 14.0 u, O : 16.0 u, Cl : 25.5 u)
Ans. (77)

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O
Sol. O
C
Cl
+ C6H5NHC6H5 C6H5 —C—N—(C6H5)2
0.140 0.388
0.210 g
140.5 169
1 0.210
= 0.001 = 0.002 
0.001 273
= 0.769
% yield = 76.9 %
 77%
23. The total number of C–C sigma bond/s in mesityl oxide (C6H10O) is (Round off to the Nearest Integer)
Ans. (5)
O
Sol. mesityl oxide
Number of C–C bond  bond in mesityl oxide is 5.
24. Consider the reaction N2O4(g) 2NO2(g). The temperature at which KC = 20.4 and KP = 600.1,
is______K (Round off to the Nearest Integer)

[Assume all gases are ideal and R = 0.0831 L bar K–1 mol–1]
Ans. (354)
Sol. Kp = KC (RT)n
600.1 = 20.4 [0.0831 × T]1
29.41
=T
0.0831
T = 353.99 K  354 K
25. KBr is doped with 10–5 mole percent of SrBr2. The number of cationic vacancies in 1 g of KBr crystal
is______ 1014. (Round off to the Nearest Integer).
[Atomic Mass : K : 39.1 u, Br : 79.9 u NA = 6.023 × 1023]
Ans. (5)
Sol. For every Sr2+ ion, 1 cationic vacancy is created. Hence number of Sr 2+ ion = number of cationic
vacancies. Since mole percentage of SrBr2 doped is 10–5 to that of total moles of KBr. Hence number of
10 –5 1
cationic vacancies = × × NA
100 119
1
× 10–7 × 6.023 × 1023 = 5.06 × 1014
119

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26. In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is________ × 10–1 BM. (Round
off to the Nearest Integer).
[Given : 3 = 1.73, 2 = 1.41]
Ans. (49)
Sol. 26Fe = [Ar]3d64s2
No. of unpaired electrons = 4
µ= n(n  2) BM
= 4( 4  2) = 24
= 2 3  2 = 2[1.73 × 1.41]
= 4.8786 BM
= 48.78 × 10–1 BM
27. The number of chlorine atoms in 20 mL of chlorine gas at STP is _____10 21. (Round off to the Nearest
Integer). [Assume chlorine is an ideal gas at STP R = 0.083 L bar mol–1 K–1, NA = 6.023 × 1023]
Ans. (1)
Sol. No. of moles of Cl2(g) =  20 


 22400 
No. of Cl2(g) molecules =  20 

 NA
 22400 
No. of Cl atoms are = 2  20 

 × 6.023 × 1023
 22400 
= 1.0755 × 1021
Ans. 1
28. The reaction 2A + B2  2AB is an elementary reaction. For a certain quantity of reactants, if the volume
of the reaction vessel is reduced by a factor of 3, the rate of the reaction by a factor of ______ (Round
off to the Nearest Integer).
Ans. (27)
Sol. Let initial concentration of A & B is a & b
Rate = K[A]2 [B2]1
2 1
a b
r1 = K    
V V
2 1
 3a   3b 
r2 = K    
V V
 r2 
  = 27
 r1 

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29. A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of
another solution which contains 18.1 weight percent of a non-electrolytic solute A. The molar mass of A
is______u. (Round off to the Nearest Integer). [Density of water = 1.0 g cm–3]
Ans. (85)
= 1+ [5–1]0.4 = 2.6
18.1 1000
Molality of unknown compound solution =
Msolute  81.9
(Tb )K 4 [Fe(CN)6 ] = (Tb )compound
iKb × m1 = kb × m2
18.1 1000
 2.6 × 1 =
Msolute  81.9
Msolute = 85
30. A KCl solution of conductivity 0.14 S m –1 shows a resistance of 4.19  in a conductivity cell. If the same
cell is filled with an HCl solution, the resistance drops to 1.03 . The conductivity of the HCl solution is
______ × 10–2 S m–1. (Round off to the Nearest Integer).
Ans. (57)
Sol. For KCl solution
KKCl =    1 = 0.14
 a  R KCl
   = 0.14 × 4.19
 
a
For HCl solution
KHCl =    1
 a  R HCl
1
= [0.14 × 4.19]
1.03
1
= 0.5866 × = 0.569
1.03
= 56.9 × 10–2 S m–1
 57 × 10–2 S m–1

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Duration: 3 Hours | Max. Marks: 300

Resonance Eduventures Ltd.

(1) (2) (3) (4)

4. Match List-I with List-II:

(c) Cr(H2O)6 Cl3 (iii) Co-ordination isomerism

(d) cis- [CrCl2 (ox)2 ]3 (iv) Optical isomerism

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6. C7H2N2OCl + C2H5OH  + N2 + "X" + "Y"

Resonance Eduventures Ltd.

9. Amongst the following, the linear species is:

10. Fructose is an example of:

(1) Carbocation B is more stable and formed relatively at slow rate

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12. Primary, secondary and tertiary amines can be separated using:

14. During which of the following processes, does entropy decrease?

15. Match List-I with List-II:

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16. The correct pair(s) of the ambident nucleophilies is (are):

18. Given below are two statements:

19. Match List-II with List-II

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Numerical Value Type

0.140 g 0.388 g 0.210 g

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is______K (Round off to the Nearest Integer)

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Sol. No. of moles of Cl2(g) =  20 

No. of Cl2(g) molecules =  20 

No. of Cl atoms are = 2  20 

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(Tb )K 4 [Fe(CN)6 ] = (Tb )compound

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