B-136

B.A. / B.SC. / B.COM. (MAJOR/MINOR COURSE)

FIRST SEMESTER EXAMINATION 2023-24
CHEMISTRY
FUNDAMENTALS OF CHEMISTRY
Time: 2:00 Hrs Max. Marks: 75
Note:- Attempt all questions from Section-A (Objective type questions),Three questions from Section–
B (Short answer type questions) and two questions from Section–C (Long/Essay type questions)
[k.M+ &v ¼oLrqfu"B iz’u½ ds lHkh iz’uksa ds] [k.M+&c ¼y?kq mRrjh; iz’u½ ls 3 iz’uksa ds rFkk
[k.M+&l ¼nh?kZ@foLr`r mRrjh; iz’u½ ls 2 iz’uksa ds mRrj nhft,A

([k.M+ &v) Section – A 2*10=20

Q1. Colourless ion is (jaxghu vk;u gS%) :
(a) Mn+2 (b) Co+3 (c) Sc+4 (d) Cu+2
Q2. Which of the following metal does not give flame test:
(a) Radium (b) Beryllium (c) Calcium (d) Barium
dkSu lk /kkrq Tokyk ijh{k.k iznf’kZr ugha djrk \
¼v½ jsfM;e ¼c½ cSjhfy;e ¼l½ dSfY’k;e ¼n½ csfj;e
Q3. Which fluoride of xenon is impossible?
t+hukSu dk dkSu lk ¶yqvksjkbM vlEHko gS \
(a) XeF2 (b) XeF3 (c) XeF4 (d) XeF6
Q4. Inert pair effect relates:
(a) A pair of s electron. (b) A pair of p electron.
(c) A pair of d electron. (d) A pair of f electron
vfØ; ;qXe izHkko lEcfU/kr gS &
¼v½ s bysDVªkWu ;qXe ls ¼c½ p bysDVªkWu ;qXe ls
¼l½ d bysDVªkWu ;qXe ls ¼n½ f bysDVªkWu ;qXe ls
Q5. Banana bond is found in (cukuk ca/k ik;k tkrk gS) :
(a) B2H6 (b) CaCO3 (c) H2O (d) NH3
Q6. White enamel of our teeth is (gekjs nkars dh lQsn irZ gksrh gS) :
(a) CaF2 (b) CaBr2 (c) CaCl2 (d) Ca3(PO4)2
Q7. Bleaching Powder is obtained by action of Cl2 gas and -
(a) Concentrated solution of Ca(OH)2 (b) Dilute solution of Ca(OH)2
(c) Dry stacked lime (d) Dry CaO
Cyhfpax ikmMj Dyksjhu fd fdl ;kSfxd dh izfrfØ;k ls feyrk gS \
¼v½ Ca(OH)2 ds lkUnz foy;u ls ¼c½ Ca(OH)2 ds ruq vEy ls
¼l½ lw[ks cq>s pwus Ca(OH)2 }kjk ¼n½ lw[ks CaO ds }kjk
Q8. When KI and CuSO4 solution are mixed, product obtained is-
KI vkSj CuSO4 foy;u feykus ij izkIr gksrk gS %
(a) K2SO4 + I2 (b) Cu2I2 + K2SO4 (c) CuI2+K2SO4 (d) Na2SO4+I2
Q9. Hypo is used in photography because of its : gkbiks dks QksVksxzkQh esa iz;ksx djrs gSa D;ksafd %
(a) Reducing behavior (b) Oxidizing behavior
(c) Complexing behavior (d) Reaction with light
{Cont…
1 .
 ¼v½ vipk;d ds :i esa ¼c½ vkWDlhdkjd ds :Ik esa
¼l½ ladfjr ;kSfxd ds :Ik esa ¼n½ izdk’k ls fØ;k’khy

Q10. Freon -12 is used as : Ýh;ku&12 dks iz;ksx djrs gS%

(a) Acidic nature vius vEyh; xq.k ds dkj.k
(b) Electron deficient character bysDVªkWu dh deh gksus ds dkj.k
(c) Covalen nature lgla;ksth xq.k ds dkj.k
(d) Refrigerant 'khryd xq.k ds dkj.k

([k.M+ &c) Section – B 3*10=30

1. What is meant by electron affinity? Discuss the factors affecting it.
bysDVªkWu cU/kqrk dk D;k rkRi;Z gS \ bldks izHkkfor djus okys dkjdksa dk mYys[k dhft,A
2. Why the bond strength in a N2 molecule is greater than in F2 molecule? Also mention MO theory.
N2 v.kq dh ca/k {kerk F2 v.kq dh ca/k {kerk ls vf/kd D;ksa gksrh gS \ MO fl)kar dh O;k[;k djsAa
3. Explain VSEPR theory with special reference to shape of NH3 and SF4 molecule.
NH3 vkSj SF4 v.kq dh vkd`fr dk mnkgj.k ysrs gq, VSEPR fl)kUr dh foospuk dhft,A
4- Write short note on Born – Haber cycle.
ckuZ& gScj pØ ij laf{kIr fVIi.kh fyf[k,A
5. Compare the properties of alkali metals and alkaline earth metals?
{kkjh; /kkrqvksa rFkk {kkjh; e`nk /kkrqvksa esa muds xq.kksa dh rqyuk dhft,A

([k.M+ &l) Section – C 2*12.5=25

1. What are interhalogen compounds? Write down their preparation methods, properties and
structure.
vUrjkgSykstu ;kSfxd D;k gksrs gS \ muds cukus dh fof/k;k¡] xq.k vkSj lajpuk fyf[k,A
+ + 2+
2. Describe functions of Na , K , Mg, Ca ions in bio system.
+ + +2
tSo iz.kkyh esa Na , K , Mg, Ca vk;uksa ds dk;ksZ dk o.kZu dhft,A
3. What is Van der Waal’s force? How many types of its? Give characteristic and write the factors
which affect the magnitude of Van der Waal’s forces?
oSuMj okYl cy D;k gksrs gSa \ blds fdrus izdkj gSa \ bldh fo’ks"krk vkSj dkjd fy[ksa tks
oSuMj okYl cyksa ds vkdkj dks izHkkfor djrs gSa \
4. What is Schrodinger wave equation? Derive the equation relating to wave properties of electron.
Discuss the physical significance of 𝜓 aand 𝜓 2 .
JksfMatj rjax lehdj.k D;k gS \ bysDVªkWu ds rjax xq.kksa ls lEcaf/kr lehdj.k dh O;k[;k ,oa 𝜓
vkSj 𝜓 2 ds HkkSfrd egRo ij ppkZ djsa A