JEE MAIN 16 March Shift 2

CHEMISTRY
CN
(1) PhMgBr (1 eq.)
1.  
 Product is
(2) H3O
OCH3
OH O O
CN Ph
Ph Ph O
(1) (2) (3) (4)
OCH3 OCH3 Ph OCH3

Ans. (2)
2. Green house gases are

(I) CO2 (II) Methane (III) O2 (IV) Water vapour
(1) I, II, III (2) I, II, IV (3) I, III (4) III, IV
Ans. (2)
3. Which of the following reagent is used for given conversion?

Cl
Cl
(1) Anhydrous AlCl3/Cl2(dark) (2) HCl + ZnCl2
(3) Cl2/h (4) Cl2/CCl4
Ans. (3)
4. Match the column

(A) CuO (I) Halogen
(B) AgNO3 (II) Sulphur
(C) Lassaigne (III) Carbon
(D) Black ppt with (CH3COO)2Pb (IV) Nitrogen
(1) AIII ; BI ; CIV , DII (2) AIV ; BIII ; CII , DI
(3) AIII ; BI ; CII , DIV (4) AIV ; BI ; CIII , DII
Ans. (1)
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O AgNO
5. Compound (X)  3
 Y  3
silver mirror
Which of the following is [X]
(1) (2) CH3–CC–CH3 (3) (4) CH3–CCH
Ans. (4)
6. Wooden laminates are made by

(1) Urea–formaldehyde resin (2) Melamine–formaldehyde resin
(3) Phenol–formaldehyde resin (4) PVC
Ans. (2)
7. Which of the following is least basic among the following compounds?

(1) Et3N (2) (Et)2NH (3) (CH3CO)2NH (4) CH3–C–NH–Et
O
Ans. (3)
CH3 COOH
Reagent
8.
OCH3 OCH3
Reagent is
(1) LiAlH4 (2) NaBH4 (3) ZnHg/HCl (4) KMnO4/H
Ans. (4)
9. Ammonolysis of alkyl halide to prepare primary, secondary and tertiary amines followed by
NaOH is
(1) to remove acidic impurities
(2) to remove basic impurities
(3) to activate halide
(4) to activate ammonia
Ans. (1)
10. Secondary structure of protein in stabilized by

(1) H-bond (2) Vanderwaal force of attraction
(3) Peptide bond (4) Glycosidic linkage
Ans. (1)
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11. Statement-1: NaH can be used as an oxidising agent.
Statement-2: Pyridine is basic due to lone pair of nitrogen.
(1) Both Statement-1 and Statement-2 are correct
(2) Both Statement-1 and Statement-2 are false
(3) Statement-1 is correct and Statement-2 is false
(4) Statement-1 is false and Statement-2 is correct
Ans. (4)
12. Vapour pressure of pure liquid A & B are 21 & 18 mm of Hg respectively. Determine vapour
pressure of a solution (in mm of Hg) obeying Raoult’s law containing 1 mole of A & 2 mole of B.
Ans. (19)
1 1 2
Sol. XA =  XB =
1 2 3 3
PAº = 21 mm of Hg PBº = 18 mm of Hg
Ptotal = PAº XA + PBº XB
1 2
= 21 × + 18 ×
3 3
= 7 + 12 = 19 mm of Hg
13. Two elements A & B have following ionisation energy data:

IE1 IE2
A 400 4000 (in kJ/mol)
B 700 1400 (in kJ/mol)
A & B are respectively :
(1) Na, Mg (2) Mg, Na (3) Na, F (4) Mg, F
Ans. (1)
14. Half life time of two first order reactions

A  Products
B  Products
are 54 & 18 min respectively. Starting with equimolar quantities of A & B, determine the time
after which [A] = 16 [B]
Ans. (108)
[A]0 [B]0
Sol. [A]t = Time [B]t = Time
2 54
2 18
 [A]0 = [B]0 and [A]t = 16 [B]t
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[A]0 [A]0
T
= 16 T
2 54
2 18
T T

16 = 218 54
2T
16 = 2 54
2T
24 = 2 54
2T
4=
54
T = 108 min
15. If both FeX2 & FeY3 are found to exist, X & Y can be :
(1) X = F, Cl, Br, I Y = F, Cl, Br (2) X = Cl, Br, I Y = F, Cl, Br, I
(3) X = F, Cl, Br Y = Cl, Br, I (4) X = F, Cl, Br, I Y = F, Cl, Br, I
Ans. (1)
Sol. FeI3 does not exist because of I¯ being very good reducing agent.
16. Which of the following cannot be reduced by coke?

(1) Al2O3 (2) ZnO (3) Fe2O3 (4) Cu2O
Ans. (1)
17. Volume of 1 M NaOH solution required to neutralise 50 mL 1M H3PO3 & 100 ml 2M H3PO2
respectively are
(1) 100 ml, 200 ml (2) 200 ml, 100 ml (3) 50 ml, 100 ml (4) 100 ml, 50 ml
Ans. (1)
Sol. (1) 2NaOH + H 3 PO 3  Na2HPO3 + 2H2O
100 m mole 50 m mole
100 m mole = M × Vml

100 m mole = 1 × Vml
Vml = 100 ml
(2) NaOH + H 3 PO 2  NaH2PO2 + H2O
200 m mole 200 m mole
200 m mole = M × Vml

Vml = 200 ml
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18. Elements with atomic number 33, 53 & 83 are respectively
(1) Metalloid, Non-metal, Metal (2) Metal, Non-metal, Metalloid
(3) Non-metal, Metal, Metalloid (4) Metalloid, Metal, Non-metal
Ans. (1)
Sol. Atomic number Element
33  As (Metalloid)
53  I (Non-metal)
83  Bi (Metal)
19. Which of the following are correct for H2O2

(A) Used in pollution control treatment of industrial effluents.
(B) H2O2 can act as both oxidising agent & reducing agent
(C) Miscible in water
(D) two hydroxy groups are in same plane
(1) ABC (2) ACD (3) ABCD (4) BCD
Ans. (1)
Sol. In H2O2–1 oxidation state of oxygen is –1 therefore acts both as oxidising agent & reducing agent.
H2O2 is miscible in water due to intermolecular H-bonding.
H2O2 has open book structure in which both –OH groups are not in same plane
20. Arrange the following compounds (assuming to be high spin) in increasing order of spin magnetic
moment :
(1) (NH4)2[Ce(NO3)6] < Eu(NO3)3 < Gd(NO3)3
(2) (NH4)2[Ce(NO3)6] < Gd(NO3)3 < Eu(NO3)3
(3) Eu(NO3)3 < Gd(NO3)3 < (NH4)2[Ce(NO3)6]
(4) Gd(NO3)3 < (NH4)2[Ce(NO3)6] < Eu(NO3)3
Ans. (1)
Sol. (NH4)2[Ce(NO3)6] (n=0)  = 0 BM
Eu(NO3)3 (n=6)  = 6.93 BM
Gd(NO3)3(n=7)  = 7. 94 BM
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21. Gallium (At. Mass = 70) crystallises in HCP lattice. If the total number of voids in 0.581 gram of
gallium is x × 1021 then determine 'x' :
Ans. 15
0.581
Sol. No. of moles of Ga =
70
0.581
No. of atoms of Ga =  NA
70
0.581
 Total no. of voids =  NA  3
70
= 0.0249 × 6 × 1023
= 15 × 1021
As there are one octahedral void and two tetrahedral voids per atom.
22. Which of the following is incorrect?

(1) Al3+ > Na+ flocculation power
(2) Colloids show Brownian motion
(3) Colloids show colligative property
(4) Colloidal solution can not pass through ordinary filter paper
Ans. (4)
Sol. Colloidal solution can pass through ordinary filter paper but can not pass through special filter
paper.
23. Number of orbitals having m = +2 in n = 5 are:

Ans. (3)
Sol. n=5
 = 0, 1, 2, 3, 4
 = 2  m = –2, –1, 0, +1, +2
 = 3  m = –3, –2, –1, 0, +1, +2, +3
 = 4  m = –4, –3, –2, –1, 0, +1, +2, +3, +4
24. Incorrect statement regarding C60 is:

(1) It has 24 6-membered rings & 12 5-membered rings.
(2) It has 5-membered rings only attached to 6-membered rings.
(3) It has 6-membered rings attached to both 5 & 6-membered rings.
(4) Each Carbon is attached to 3 C-atoms.
Ans. (1)
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25. The number of mol of PbSO4 obtained on reacting 35 ml of 0.15M Pb(NO3)2 with 50 ml, 0.2M
Cr2(SO4)3 is x × 10–5. Find x.
Ans. (525)
Sol. 3Pb(NO3)2 + Cr2(SO4)3  3PbSO4 + 2Cr(NO3)3

m.mol. 5.25 (L.R.) 10
0 5.25 m.mol
formed
 i.e. = 525 × 10–5
 x = 525
26. Determine pH of 0.588 M H2SO3 solution given K a1 = 1.7 × 10–2 K a2 = 10–8

Ans. (1)
0.5882
Sol.  1.7  10 2
1 
2
 0.029 2 + 0.029 – 0.029 = 0
1 
0.029  (0.029) 2  4(1)(0.029)
=
2
= 0.1564
[H+] = 0. 588 × 0.1564 = 0.092 M
pH = 2 – log 9.2 = 2 – 0.964 = 1.036  1
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S E A R C H @ S t u d y T i m e _ C h a n n e l
O N T E L E G R A M T O J O I N O U R T E L E G R A M C H A N N E L
Q U I C K L Y
JEE (MAIN) MARCH-2021 DATE-16/03/2021 (SHIFT-II)
MATHEMATICS
3x 4x
1. Number of solution of the equations sin –1 + sin –1 = sin–1 x ; x Î [–1, 1] is
5 5
(1) 0 (2) 1 (3) 2 (4) 3
Ans. (4)
Sol. Taking sine both sides
3x 16x 2 4x 9x 2
1- + 1- =x
5 25 5 25
Þ 3x 25 - 16x 2 = 25x – 4x 25 - 9x 2
Þ x = 0 or 3 25 - 16x 2 = 25 – 4 25 - 9x 2
Þ 9(25 – 16x2) = 625 – 200 25 - 9x 2 + 16 (25 – 9x2)
Þ 200 25 - 9x 2 = 800
Þ 25 - 9x 2 = 4
Þ x2 = 1
Þx±1
\ Total number of solution = 3
2.
Number of elements Group-1
Group-2
Number of elements 10 n
Mean 2 3
variance 2 1
17
If combined variance of both groups is , then find 'n'
9
Ans. (5)
Sol. For group-1 :

å x i = 2 Þ å x = 20
i
10
å x2i – (2)2 = 2 Þ x 2 = 60
10
å i
for group-2 :
å y i = 3 Þ å y = 3n
i
n
å y2i – 32 = 1 Þ y 2 = 10n
n
å i
Now, combined variance
å (x2i + y2i ) – æç å (x i + y i ) ö÷
2
2
s = ç 10 + n ÷
10 + n è ø
2
17 60 + 10n (20 + 3n)
Þ = –
9 10 + n (10 + n)2
Þ 17(n2 + 20n + 100) = 9(n2 + 40n + 200)
Þ 8n2 – 20n – 100 = 0
Þ 2n2 – 5n – 25 = 0 Þ n = 5
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ì cos-1 (1 - {x}2 ) sin -1 (1 - {x})

ï , x¹0
3. If f(x) = í {x} - {x}3
ï a , x=0
î
then find a if f(x) is continuous at x = 0 (Here {x} denotes fractional part of x)
p p
(1) (2) (3) p (4) no value of a
4 2
Ans. (4)
cos -1 (1 - x 2 ) sin1 (1 - x) p cos -1 (1 - x 2 )
Sol. RHL = lim+ = lim
x®0 x(1 - x 2 ) 2 x®0+ x
p -1
= lim+ (–2x) (L¢Hospital Rule)
2 x®0 1 - (1 - x 2 )2
x 1 p
= p lim+ = p lim+ =
x®0
2x 2 - x 4 x®0
2 - x2 2
-1
cos (1 - (1 + x) )sin ( -x)
2 1
p sin -1 x p sin -1 x
LHL = lim- = lim = lim
x®0 (1 + x) - (1 + x) 3 2 x ® 0 - (1 + x)[(1 + x) 2 - 1] 2 x ® 0 - x 2 + 2x
p æ1ö p
= ç ÷=
2 è2ø 4
As LHL ¹ RHL so f(x) is not continuous at x = 0
4. Let the circle x2 + y2 – 9x – 2ay + c = 0 has x–intercept and y–intercept respectively 2 2 and
2 5 . Find distance of farthest tangent from origin which is perpendicular to 2y + x = 0
(1) 6 (2) 30 (3) 10 (4) 2 6
Ans. (1)
a2
Sol. 2 -c = 2 2 , 2 a2 - c =2 5
4
a2
-c = 2 a2 - c = 5
4
a2
c = -2
4
a2 = 4c + 8
3c + 8 = 5
c = –1, a2 = 4
Equation of tangent
y = 2x + c'
c'
D= =r
5
c a2
= + a2 - c
5 4
c
= 1 + 5 = 30
5
D= 6
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5. Let image of y2 = 4x in y = x is a parabola. The equation of tangent from (2, 1) to new parabola is
x
(1) y = x + 1 (2) x = y + 1 (3) y = 2x – 3 (4) y = +1
2
Ans. (2)
y=x
Sol.
Image of y2 = 4x w.r.t. y = x is x2 = 4y
tangent from (2, 1)
xx1 = 2 (y + y1)
2x = 2(y + 1)
x=y+1
x2 y2
6. If point of intersection of the curves + 2 = 1 and x 2 + y 2 = 4b , where b > 4 , lies on the curve
16 b
y2 = 3x2 then find 'b'
(1) 4 (2) 12 (3) 10 (4) 6
Ans. (2)
x2 y2
Sol. + =1 ......(1)
16 b2
x 2 + y 2 = 4b ......(2)
2 2
y = 3x ......(3)
From eq (2) and (3) x = b and y2 = 3b
2
b 3b
from equation (1) + =1
16 b2
Þ b2 + 48 = 16b
Þ b = 12
7. Find the area bounded between the curve whose differential equation are given by
dy y 2 - x 2 dx x 2 - y 2
= and =
dx 2xy dy 2xy
Given that both the curve passes through the point (1, 1)
æp ö æp ö
(1) (p + 1) (2) (p – 1) (3) ç – 1 ÷ (4) ç + 1 ÷
è2 ø è2 ø
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Ans. (3)
dy y 2 - x 2
Sol. =
dx 2xy
Put y = vx
dv v2 x2 – x2 v 2 – 1
v+x = =
dx 2vx 2 2v
dv v 2 – 1 – 2v 2 (v 2 + 1)
x = =-
dx 2v 2v
2v dx
Þ 2
dv = -
v +1 x
c
ln(v2 + 1) = –lnx + lnc Þ v2 + 1 =
x
y2 c
Þ 2
+ 1 = Þ x2 + y2 = cx
x x
If pass through (1, 1)
\ x2 + y2 – 2x = 0
dx x 2 - y2
similarly for second differential equation =
dy 2xy
equation of curve is x2 + y2 – 2y = 0
Now required area is
y
(1, 1)
(0, 1)
x
O C(1, 0)
æ1 1 ö
= ç ´ p´ 12 – ´ 1 ´ 1 ÷ × 2
è4 2 ø
æp ö
= ç – 1 ÷ sq. units
è2 ø
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éæ (| z | +3)(| z | -1) ö ù
8. If exp êç ÷ loge 2 ú ³ log | 5 7 + 9i | , then find the minimum value of |z|
ëè | z | +1 ø û
2
(1) 3 (2) 2 (3) 5 (4) 6

Ans. (1)
(|z| +3)(|z|-1)
(| z | +3)(| z | -1)
Sol. 2 (|z|+1)
³ 23 Þ ³3
| z | +1
Þ |z|2 + 2|z| – 3 ³ 3|z| + 3
Þ |z|2 – |z| – 6 ³ 0
(|z| – 3) (|z| + 2) ³ 0
|z|min = 3
9. Let f(x) ; (0, ¥) ® R is defined f(x + 1) = xf(x) & g(x) ; R ® R is defined as
g(x) = log (f(x)), then the value of |g¢¢(5) – g¢¢(1)| is
205 144 144
(1) (2) (3) (4) none of these
144 205 113
Ans. (1)
Sol. g(x + 1) = ln (f(x + 1)) = ln (x f(x)) = lnx + ln(f(x))
Þ g(x + 1) – g(x) = lnx
1
g¢(x + 1) – g¢(x) =
x
1
Þ g¢¢(x + 1) – g¢¢(x) = – …..(i)
32
putting x = 1, 2, 3, 4 in (i), we get
Þ g¢¢(2) – g¢¢(1) = – 1
1
g¢¢(3) – g¢¢(2) = –
4
1
g¢¢(4) – g¢¢(3) = –
9
1
g¢¢(5) – g¢¢(4) = –
16
Adding,
1 1 1 205
g¢¢(5) – g¢¢(1) = – 1 – – – =–
4 9 16 144
205
\ |g¢¢(5) – g¢¢(1)| =
144
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dy æpö
10. If y = y(x) the solution of the differential equation + y tan x = sin x and y(0) = 0, then y ç 4 ÷ is
dx è ø
equal to
1 1 1
(1) ln2 (2) ln2 (3) ln2 (4) ln2
2 2 2 2
Ans. (2)
Integrating factor = e ò
tan x dx
Sol. = sec x
\ solution of the equation is
y sec x = ò sin x ´ sec x dx
y
Þ = ln(sec x) + c
cos x
put x = 0, c = 0
\ y = cos x ln (sec x)
p
put x =
4
1 1
y= ln 2 = ln2
2 2 2
1 + cos2 x sin 2 x cos 2x
11. If (x) = 2
cos x 1 + sin x cos 2x , then maximum value of f(x)
2
cos2 x sin 2 x sin 2x

(1) 5 (2) 5 (3) 3 (4) 2 5
Ans. (1)
Sol. C1 ® C1 + C2
2 sin 2 x cos 2x
f(x) = 2 1 + sin x cos 2x
2
1 sin 2 x sin 2x
R2 ® R2 – R1
2 sin 2 x cos 2x
f(x) = 0 1 0
2
1 sin x sin 2x
f(x) = 2 sin 2x – cos 2x
f(x)max = 5
10
[x].e[x]
12. The value of integral ò e x -1
dx is equal to
0
(1) 45 (1 – e) (2) 55 (e – 1) (3) 45 (e – 1) (4) 45 (e + 1)
Ans. (3)
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10
Sol. I = ò [x].e[x]+1-x dx
0
2 3 4 10
= òe 2 -x
dx + ò 2.e 3-x
dx + ò 3.e 4-x
dx + .... + ò 9e10 - x dx
1 2 3 9
= –{(1 – e) +2 (1 – e) + 3 (1 – e) + ...... + 9 (1 – e)}
= 45(e – 1)
13. If S = {0,1,2,....6} and a six digit and number is formed from it, find the probability it is divisible
by '3'.
4 4 1 2
(1) (2) (3) (4)
5 9 3 3
Ans. (2)
Sol. 6×6×5×4×3×2
n(5) = 6 × 6!
0,1,2,3,4,5,6
6!+ 2 ´ 5 ´ 5!
n(Î) =
6 ´ 6!
6 + 10
=
36
4
=
9
éa ù éb ù 1 é 1 -1ù
14. If two matrices A and B are A = ê 1 ú and B = ê 1 ú such that A = XB, where X = ê ú,
ëa 2 û ë b2 û 3 ëk 1 û
2
( )
then find k such that a12 + a22 = b12 + b 22 and (1 + k2) b22 ¹ 2b1b2 .
3
Ans. 1
Sol. \ A = XB
é a ù 1 é 1 -1ù é b1 ù
\ê 1 ú = ê úê ú
ëa2 û 3 ë k 1 û ë b2 û
1 1
Þ a1 = (b1 - b 2 ) and a 2 = (kb1 + b2 )
3 3
Given that
2
(
a12 + a22 = b12 + b 22
3
)
1 2 1 2
Þ ( b1 - b2 ) + ( kb1 + b2 ) = b12 + b22
3 3
2
3
( )
Þ (1 + k ) b1 + 2b2 + 2 (k –1) b1b2 = 2b12 + 2b22
2 2 2
Þ (1 + k2) b12 + 2(k – 1) b1b2 = 2b12

this is only possible when k = 1
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15. Consider 3 points A(–1, 1), B(3, 4) and C (2, 0). The line y = mx cuts line AC and BC at points P
and Q respectively. If area of DABC = A1, and area of DPQC = A2 and A1 = 3A2, then positive
value of m is
4 15
(1) 1 (2) (3) 2 (4)
15 4
Ans. (1)
A(–1,1)
P
Sol.
B(3,4) C(2,0)
Q
y=mx
-1 1 1
1
A1 = DABC = 2 0 1
2
3 4 1
13
A1 =
2
1
Equation of line AC is y – 1 = (x + 1)
3
æ 2 2m ö
solve it with line y = mx, we get P ç , ÷
è 3m + 1 3m + 1 ø
Equation of line BC is y – 0 = 4 (x – 2)
æ –8 –8m ö
Solve it with line y = mx, we get Q ç , ÷
è m –1 m – 4 ø
2 0 1
1 2 2m A 13
A2 = Area of DPQC = 1 = 1=
2 3m + 1 3m + 1 3 6
–8 –8m
1
m -4 m -4
2 0 1
1 2 13
m0 1 =
2 3m + 1 6
–8
0 1
m -4
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1 æ 2 8 ö 13
m(2) ç + ÷=
2 è 3m + 1 m - 4 ø 6
æ m - 4 + 12m + 4 ö 13
2m ç ÷ =±
è (3m + 1)(m - 4) ø 6
26m 2 13
=±
(3m + 1)(m - 4) 6
16. If Sn(x) = loga1/ 2 x + log a1/ 3 x + loga1/ 6 x + loga1/11 x + ........ Also, S24(x) = 1093 and S12(2x) = 265.
then find a.
Ans. (16)
Sol. + 3 +4
Sn(x) = (logax) 2144 + 11 + ......
62444 3
7
2
tn = an + bn + c
a+b+c=2 ...... (i)
4a + 2b + c = 3 ...... (ii)
9a + 3b + c = 6 ...... (iii)
Þ a = 1; b = – 2; c = 3
Tn = n2 – 2n + 3 = (n – 1)2 + 2
\ S24(x) = 1093 = logax.(4372)
Þ x = a1/4 ...... (i)
Also, S12(2x) = 265 = (loga2x).(530)
Þ 2x = a1/2 ...... (ii)
from (i) and (2)
a1/2 = 2a1/4
Þ a2 = 16a Þ a = 16
1 1 1
17. If , a, b are in GP and , , 6 are in AP, then
16 a b
72 (a + b) =
Ans. 14
b 2 1
Sol. a2 = and = + 6
16 b a
1 -1
Solving, we get a = or a = [rejected]
12 4
1 1
If a = Þb=
12 9
æ 1 1ö
\ 72 (a + b) = 72 ç + ÷ = 14
è 12 9 ø
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18. The number of points lying in the interior of line segments AB, BC, CD, DA of rectangle ABCD
are 5, 6, 7 and 9. If a is the number of triangle made from the points by selecting each vertex from
different line segments and b is the number of such quadrilaterals then the value of |a – b| is
(1) 711 (2) 717 (3) 919 (4) 926
Ans. (2)
Sol. a = 6C1 7C19C1 + 5C1 7C19C1 + 5C1 6C19C1 + 5C1 6C17C1 = 378 + 315 + 270 + 210 = 1173
b = 5C1 6C17C1 9C1 = 1890
Þ b – a = 1890 – 1173 = 717
19. Let a, b are sides of triangle where a = 5, b = 12 and area of triangle is 30, then value of 2R + r
(1) 13 (2) 15 (3) 20 (4) 17
Ans. (2)
Sol. ÐC = 90º
A
13
12
C B
5
13 12 + 5 + 13
R= ,S= = 15
2 2
D 30
r= = =2
S 15
2R + r = 13 + 2 = 15
x -1 2
20. Find the interval in which f(x) = loge – is increasing
x +1 x -1
(1) (–¥, –1) È [0, 1) È (1, ¥) (2) (–1, –0) È [0, 1) È (1, ¥)
(3) (–1, –¥) (4) (–¥, –1) È (–1, 1)
Ans. (1)
x + 1 x + 1 - (x - 1) 2 2 2
Sol. f¢(x) = × + = +
x -1 (x + 1) 2
(x - 1) 2
(x - 1)(x + 1) (x - 1) 2
2 æ 1 1 ö 2
= ç + ÷ = (2x)
(x - 1) è x + 1 x - 1 ø (x - 1) 2 (x + 1)
4x
=
(x - 1) 2 (x + 1)
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for increasing, y¢(x) ³ 0
–1 0 1
x
Þ ³0
(x - 1) 2 (x + 1)
Þ x Î (–¥, –1) È [0, 1) È (1, ¥)
21. Consider the set A = {2, 3, 4, ......, 30}. A relation R defined on A × A is an equivalence relation
such that (a, b) R (c, d) Þ ad = bc. If (c, d) = (3, 4). then find the number of ordered pair of (a, b)
Ans. (7)
Sol. (a, b) R (c, d) Þ ad = bc
3
\ (a, b) R (3, 4) Þ 4a = 3b Þ a = b
4
Þ b is a multiple of 4
\ (a, b) = (3, 4), (6, 8), (9, 12), (12, 16), (15, 20)(18, 24), (21, 28)
i.e., 7 ordered pairs
® ® ® ® ®
22. If a = î + ĵ + 2 k̂ and b = î + 2 ĵ + k̂ and a vector c perpendicular to both a and b and
® ® ® ®
c . ( î – ĵ + 3 k̂ ) = 8 then the value of c . ( a × b )
(1) 90 (2) –88 (3) 80 (4) 78
Ans. (2)
® ® ®
Sol. c = l( a × b )
î ˆj kˆ
®
c = l 1 1 2 = l[i(1 – 4) – j(1 – 2) + k(2 – 1)]
1 2 1
®
c = l(–3 î + ĵ + k̂ )
®
c .( î – ĵ + 3 k̂ ) = 8
l(–3 î + ĵ + k̂ ).( î – ĵ + 3 k̂ ) = 8
l(–3 –1 + 3) = 8
–l = 8
l=–8
® ® ®
c = – 8( a × b )
® ® ® ® ®
c .( a × b ) = –8| a × b |2 = – 8 ( 9 + 1 + 1) 2 = – 88
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23. Point (1, –1, 2) is the foot of perpendicular drawn from point (0, 3, 1) on the line
x-a y -2 z-b
= = . find the shortest distance between this line and the line
l 3 4
x -1 y - 2 z - 3
= = .
3 4 5
61 71 91 31
(1) (2) (3) (4)
1314 1314 1314 1314
Ans. (1)
Sol. Let A(0, 3, 1) and B(1, –1, 2)
d·r's of AB are 1, – 4, 1
l(1) + 3(–4) + 4(1) = 0 Þ l = 8
1- a 2-b
B line on L1 Þ =–1=
8 4
Þ a = 9, b = 6
x-9 y-2 z-6
Þ L1 is = =
8 3 4
x -1 y - 2 z - 3
L2 is = =
3 4 5
8 0 3
8 3 4
3 4 5
Shortest distance =
( )(
8i$ + 3j$ + 4k$ ´ 3i$ + 4$j + 5k$ )
61 61 61
= = =
–i$ – 28j$ + 23k$ 1 + 784 + 529 1314
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JEE-MAIN 2021 (16 MARCH ATTEMPT) SHIFT-2
PHYSICS
1. A bullet of mass 0.01 kg collides with a stick hanging with string and sticks to it as shown in figure.
Stick rises to 9.8 cm. If gravitational acceleration is 9.8 m/s2. Find initial velocity of bullet (in m/s).
g = 9.8 m/s2
h = 9.8 cm
u 5.99 kg
0.01 kg
(1) 490 2 m/s (2) 588 2 m/s (3) 294 2 m/s (4) 98 2 m/s
Ans. (2)
Sol. Pi = 0.01 × u + 0 = Pf = 6 × v
0.01u
v
6
using energy conservation
2
1  u 
6   6  9.8  9.8  102
2  600 
u = 6 × 98 × 2 = 588 2 m/s
2. A particle of mass 2kg is placed at rest at origin. A force F  2iˆ  3ˆj  5kˆ is acting on particle.
At t = 4sec the position vector of particle is found to be 8iˆ  bjˆ  20kˆ . Find b.
(1) 12 (2) –6 (3) 2 (4) 10
Ans. (1)
F 2iˆ  3ˆj  5kˆ
Sol. a 
m 2
1
rf  ri  ut  at 2
2
ˆ ˆ ˆ
(xiˆ  yjˆ  2k) ˆ  1   2i  3j  5k  (4)2
ˆ  (0iˆ  0jˆ  0k)
2   2 

xiˆ  yjˆ  zkˆ  8iˆ  12jˆ  20kˆ
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3. Heat produced in a resistance if 1.5A current is passed through it is 500J in 20 sec. If the current
is 3A, the heat produced in the same resistor in the same duration will be :
(1) 500 J (2) 1000 J (3) 1500 J (4) 2000 J
Ans. (4)
Sol. I2RT = H
2
H1  I1 
 
H2  I2 
2
 3 
 H2 = 500 ×   = 2000 J
3/2
4. Half life for a radioactive sample is 20 min. Find the time interval in between decaying from 33%
to 66 % occurs:
(1) 40 min. (2) 60 min (3) 20 min (4) 10 min
Ans. (3)
ln 2
Sol. T1/2 = 20 min  = 20 min

ln2
=
20(min)
 Nt = N0 e  t
Nt
 e 1  0.67 = et1
N0
 ln(0.67) = –t1
 100 
ln    20(min)
 100   67 
 ln   = t1  t1 =
 67  (ln 2)
 100 
ln    20(min)
Similarly t2 =  34 
ln( 2)
t2 – t1 = 19.57 min  20 min.
5. In the line of sight communication maximum separation between two antennas is 45 km. Find the
height of each antenna assuming they are of same height and radius of earth is 6400 km.
(1) 20.65 m (2) 39.55 m (3) 18.45 m (4) 64.39 m
Ans. (2)
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Sol. D = 2 2Rh
D2 452
H= = km = 39.55 m
8R 8  6400
xGMe 2
6. If the energy required to dissemble particles of earth upto infinite distance is
5Re
Where Me = Mass of earth

Re = Radius of earth
Evaluate x
Ans. 3
Sol. E = Uf – Ui
 3 GM 2  3 GM 2
E = 0 e

e
 5 Re  5 Re
So x = 3
7. If electron and proton are accelerated by same potential difference 100 V, then find the ratio of
their de-Broglie wavelength
Me = 9.1 × 10–31 kg
Mp = 1.6825 × 10–27 kg
1 40 1
(1) 43 (2) (3) (4)
43 1 40
Ans. (1)
12.27 e 12.27
Sol. e = A   43
V p 0.286
0.286
p = A
V
8. Find the magnitude of torque produced by a force F  4iˆ  3jˆ  kˆ about point (2,3,5).
Ans. 22.44
Sol.   r F
î ˆj kˆ
2 3 5
4 3 1
  î(3  15)  ˆj(2  20)  k(6

ˆ  12)
  12iˆ  18jˆ  6kˆ

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  (12)2  (18)2  (6)2  504
= 22.44
9. A particle moves with a velocity depends on time as
v  0.5t 2 .iˆ  3tjˆ  9kˆ
Find the position vector at t = 2 sec.
2
(1) tan–1   with x-axis (2) tan–1(3) with y-axis
3
1 3
(2) tan–1   with x-axis (3) tan–1   with y-axis
3  5
Ans. (2)
dx
Sol.  0.5t 2 î  3tjˆ  9kˆ
dt
2 2 2
x   0.5t 2 îdt   3t.jdt
ˆ  9kdt
 ˆ
0 0 0
8
x = 0.5  î  6ˆj  18kˆ
3
Dot product of x with unit vector of y-direction gives angle tan–1(3) with y-axis
10. In carnot engine temperature of source is 127°C with efficiency 60%. Find out temperature of
sink (°C).
(1) 143 (2) –105 (3) –113 (4) 113
Ans. (3)
 T  T
Sol.  = 1  2   0.6  1  2
 T1  400
T2
= 0.4
400
T2 = 160k
T2 = 160 – 273
T2 = –113°C
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11. A disc having radius "a" is rising on an inclined plane as shown in figure. If the acceleration of disc
2
is .gsin  , then find the value of "b" ?
b
a
Fixed wedge

Ans. 3
N
 F
a
Sol.
mg sin
mg cos 
mg sin– f = nacm _____(1)
ma2
f.a  . _______(3)
2
aam = a ___________(4)
on solving
2
acm  gsin  b = 3
3
12. In a transformer primary voltage is 220V and secondary current is 0.11A with output power 60W.
0.11A
220V ~ P S 60 watt
(1) Transformer is step up. (2) Transformer is step down

(3) Transformer is auxiliary (4) None of these
Ans. (1)
Sol. Ps = Vs × Is
60 = Vs × 0.11
60 6000
Vs =  , Vp = 220 volt
0.11 11
Vs > Vp so it is step up transformer
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13. A conducting square loop of side length ‘d’ with its edges parallel to x-axis and y-axis move with
B0 x ˆ
velocity v 0 î in a region having magnetic field B  k . Find the induced emf.
a
y
d x
Bd 2v0 Bd 2v0 Bd 2v02 Bd 2v02

(1) (2) (3) (4)
2a a 2a a
Ans. (2)
Sol.
y
2 1
x x+d x
B0 (x  d)
1 = v0 d
a
B0 x
2 = vd
a 0
B0 v0 d2
net = 1 – 2 =
a
14. Statement-1  A cyclist can move on a horizontal road with speed 7 km/hr in a circle of radius
2 m and coefficient of static friction is 0.2.
Statement-2  maximum speed with which a cyclist can move in a circle on same banked road
having inclination of 45° is 18.5 km/hr.
(1) Statement-1 is true, statement 2 is false
(2) Statement-1 is true, statement 2 is true
(3) Statement-1 is false, statement 2 is true
(4) Statement-1 is false, statement 2 is false
Ans. (2)
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Sol. On a horizontal ground,
vmax = Rg  0.2  2  9.8 = 1.97 m/s
18
1.97 ×
5
= 7.12 km/hr = 7.2 km/hr
Statement-2
 tan     1.2
vmax = gr   = 2  9.8  = 19.5 km/hr
 1   tan   0.8
 tan     0.8
vmin = rg    2  9.8  = 13.01 km/hr
 1   tan   1.2
15. A swimmer can swim with speed 12 m/s in still water. Speed of river is 6 m/s. Find the angle at
which he should swim with downstream so that he reaches directly opposite point on the other
side
(1) 90° (2) 150° (3) 60° (4) 120°
Ans. (4)
6 1
Sol. Cos = =
12 2
 = 60°
16. In a damped oscillation, damping constant is 20 gm/sec and mass of an object is 500 gm. Find out
time when amplitude of oscillation becomes half.
(1) 34.6 sec. (2) 44.6 sec. (3) 65.1 sec. (4) 55.6 sec.
Ans. (1)
bt

Sol. A = A0 e 2m
bt
 ln 2  0.693
2m
2m
t= × 0.693
b
500
t = 2  0.693
20
t = 50 × 0.693 = 34.6 sec.
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17. Radioactive substance A has half life 54 min and B has half life 18 min. Initially both have same
number of nuclei. Find time (min) when A will become 16 times of B.
Ans. 108
Sol. NA = N0 and NB = N0 initially
NA
NB =
16
N0 1t
N0e2t  e
16
16  e1t2t
24  e( 12 )t
 n2 n2 
 18  54  t = 4n2
 
T = 27 × 4 = 108 min
18. 1.5 miligram of gold (molar mass 198 gram/mole) is undergoing radioactive decay having half
life of 2.7 days. Find initial activity of substance.
(1) 366 curie (2) 466 curie (3) 536 curie (4) 636 curie
Ans. (1)
Sol. Initial activity = A0 = N0.
ln 2 1.5 103
=  × 6.023 × 1023
T1/ 2 198
ln 2 1.5 103 6.0231023

=   Ci
2.7  3600 24 198 3.7 1010
= 366 Ci
19. Heat produced per second is 10 m J through a resistor if current 2 mA passes by it. Find its
resistance.
Ans. 2500
Sol. H = i2 R t
10 × 10–3 = 4 × 10–6 R
103
10  R
4
 R = 2500 
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20. If converging lens is placed in the same medium, from which lens is made. If Radius of curvature
is R1 and R2 then focal length of lens will be inside it.
R1R2
(1) Infinite (2) Zero (3) 1 (4)
R1  R2
Ans. (1)
1  n2   1 1
Sol.    1   
f  n5   R1 R2 
1
0
f
f = infinite.
21. A thin bimetallic strip is rigidly attached on its bottom surface as shown. Coefficient of linear
expansion of strip A is more than strip B. If temperature of system is decreased, find correct
option among the following.
A > B
(1) Bends towards left (2) Bends towards right
(3) Neither bends nor shrinks (4) Shrinks but does not bends
Ans. (1)
22. A charge q is moved in magnetic field by distance dl. Find the work done by magnetic field.
(1) zero (2) infinity (3) 1 (4) –1
Ans. (1)
  
Sol. F  qV  B
 
P = FV  0 W=0
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A
23.
identifly the given logic gater

(1) NAND (2) NOR (3) OR (4) AND
Ans. (2)
Sol. Y  A.B  A.B

So given logic gates circuit is a Nor gate
24. A parallel plate capacitor has area of plates 2m2 and distance between plates 1m. It is half filled
with dielectric of dielectric constant K = 3.2 as shown in figure. Its capacitance is _____0.
K=32
d/2 d/2
Ans. 3.04
K0 A A
Sol. C1 = ; C2 = 0
d/2 d/2
1 1 1 d d
  = 
C C1 C2 2K0 A 20 A
1 d  K 1
=  
C 20 A  K 
20AK 2  2  3.2
C= = 0  3.040
d(K  1) 1 4.2
25. In a vessel containing an ideal gas the pressure is 1.1 × 105 pa, temperature is 27ºc & diameter of
molecules is 0.8 nm. Find the mean free path of the molecules if Boltzman constant is 1.38 × 10–23.
(1) 13.2 nm (2) 132 nm (3) 32 nm (4) 1.32 nm
Ans. (1)
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1
Sol. mean = & PV = NKB T
2N
2d  
V
KBT
mean 
2d2p
1.38  1023  300

=
2  3.14  0.64  1018  1.1 105
= 132 × 10–10 m
= 132 Aº
13.2 nm
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JEE MAIN 16 March Shift 2

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JEE MAIN 16 March Shift 2

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CHEMISTRY

OCH3 OCH3 Ph OCH3

2. Green house gases are

3. Which of the following reagent is used for given conversion?

4. Match the column

(1) (2) CH3–CC–CH3 (3) (4) CH3–CCH

6. Wooden laminates are made by

7. Which of the following is least basic among the following compounds?

10. Secondary structure of protein in stabilized by

13. Two elements A & B have following ionisation energy data:

14. Half life time of two first order reactions

 [A]0 = [B]0 and [A]t = 16 [B]t

16. Which of the following cannot be reduced by coke?

100 m mole = M × Vml

200 m mole = M × Vml

19. Which of the following are correct for H2O2

22. Which of the following is incorrect?

23. Number of orbitals having m = +2 in n = 5 are:

 = 2  m = –2, –1, 0, +1, +2

 = 3  m = –3, –2, –1, 0, +1, +2, +3

 = 4  m = –4, –3, –2, –1, 0, +1, +2, +3, +4

24. Incorrect statement regarding C60 is:

Sol. 3Pb(NO3)2 + Cr2(SO4)3  3PbSO4 + 2Cr(NO3)3

26. Determine pH of 0.588 M H2SO3 solution given K a1 = 1.7 × 10–2 K a2 = 10–8

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Sol. For group-1 :

ì cos-1 (1 - {x}2 ) sin -1 (1 - {x})

(1) 3 (2) 2 (3) 5 (4) 6

Þ g(x + 1) – g(x) = lnx

cos2 x sin 2 x sin 2x

Þ (1 + k2) b12 + 2(k – 1) b1b2 = 2b12

for increasing, y¢(x) ³ 0

xiˆ  yjˆ  zkˆ  8iˆ  12jˆ  20kˆ

Where Me = Mass of earth

  ˆi(3  15)  ˆj(2  20)  k(6

  12iˆ  18jˆ  6kˆ

(1) Transformer is step up. (2) Transformer is step down

Bd 2v0 Bd 2v0 Bd 2v02 Bd 2v02

t = 50 × 0.693 = 34.6 sec.

ln 2 1.5 103 6.0231023

is R1 and R2 then focal length of lens will be inside it.

option among the following.

(1) Bends towards left (2) Bends towards right

(1) zero (2) infinity (3) 1 (4) –1

identifly the given logic gater

Sol. Y  A.B  A.B

1.38  1023  300

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