Chemistry 100 Days Challenge CPP

68
MOLE CONCEPT (PHYSICAL CHEMISTRY)
1. A metal M forms the sulphate M2(SO4)3. A 0.596 gram sample of the sulphate reacts with
excess BaCl2 to give 1.220 g BaSO4. What is the atomic weight of M(in g/mol)?
(A) 26.9 (B) 69.7 (C) 55.8 (D) 23
2. The mass of CaO obtained by heating 100 kg of 95% pure limestone (CaCO3) is-
(A) 56 kg (B) 28 kg (C) 53.2 kg (D) 50 kg
3. 500 g impure sample of CaCO3 on heating gives 70 g of CaO. Percentage impurities in sample
is
(A) 25% (B) 50% (C) 75% (D) 80%
4. Percentage loss in mass, when NaHCO3(S) is heated in open vessel 2 NaHCO3(S)  Na2
CO3(S) + CO2(g) + H2O (g)
(A) 21.12% (B) 36.9% (C) 30% (D) 32.23%
5. NaCIO3 is used in spacecraft to produce O2. The daily consumption of pure O2by a person is
492 L at 1 atm, 300 K. How much amount of NaCIO3 (in grams) is required to produce O2 for
the dailyconsumption of a person at 1 atm, 300 K ?
NaCIO3 (s) + Fe (s) O2 (g) + NaCI(s) + FeO (s) R = 0.082 L atmmol–1 K–1
(A) 21.3 (B) 1115 (C) 2130 (D) 4260
6. At constant T and P, 5.0 L of SO2 are reacted with 3.0 L of O2 according to the following
equation,
2 SO2(g) + O2(9) 2 SO3(g). The volume of the reaction mixture at the completion of the
reaction is
(A) 0.5 L (B) 8.0 L (C) 5.5 L (D) 5 L
7. 100 mL of 0.3 M acetic acid is shaken with 0.8 g wood charcoal. The final concentration of
acetic acid in the solution after adsorption is 0.125 M. The mass of acetic acid adsorbed per
gram of charcoal is
(A) 1.05 g (B) 0.0131 g (C) 1.31 g (D) 0.131 g
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8. The ratio of the masses of methane and ethane in a gas mixture is 4:5. The ratio of number of
their molecules in the mixture is
(A) 4 : 5 (B) 3 : 2 (C) 2 : 3 (D) 5 : 4
9. According to the equation : 4NH3(g) + 5 O2 (g) 4NO (g) + 6H2O (l) when 1 mole of O2 and 1
mole of ammonia are mixed, then
(A) 0.2 mole of H2O is produced
(B) 0.1 mole of NO is produced
(C) all the oxygen will be consumed
(D) all the ammonia will be consumed in order to form 1 mole NO
10. 1.44 g of Titanium (Ti) reacted with an excess of O2 and produced x g of a non- stoichiometric
compound Ti1.44O1. The value of x in g is :
(A) 1.44 (B) 2 (C) 1.77 (D) None of these
11. The average molar mass of chlorine is 35.5 g mol–1. The ratio of 35Cl to 37
Cl in naturally
occurring chlorine is close to
(A) 4 : 1 (B) 3 : 1 (C) 2 : 1 (D)1 : 1
12. The ammonia (NH3) released on quantitative reaction of 0.6 g urea (NH2CONH2) with sodium
hydroxide (NaOH) can be neutralized by
(A) 100m L of 0.2 N HCl (B) 200 mL of 0.4 N HCl
(C) 200 mL of 0.2 N HCl (D) 100 mL of 0.1 N HCl
13. In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4 and Fe2(SO4)3
in acidic medium, the number of moles of KMnO4 required is.
(A) 2 (B) 1 (C) 3 (D) 1.5

69
IUPAC & GOC (ORGANIC CHEMISTRY)
1. What is the correct order of acidic strength in following compounds ?
(A) x > y > z (B) y > x > z (C) x > z > y (D) z > y > x
2. The ionistation constant of phenol is higher than that of ethanol because

(A) phenoxide ion is bulkier than ethoxide
(B) phenoxide ion is stronger base than ethoxide
(C) phenoxide ion is stabilised through delocalistation
(D) phenoxide ion is less stable than ethoxide
3. Which one is more acidic than Phenol

(A) p-nitrophenol (B) ethanol (C) cresol (D) benzyl alcohol
4. Find the order of Ka of following compounds :
COOH COOH COOH

COOH
NO2
(I) (II) (III) NO2 (IV) (V)
NO2
(A) I < II < III < IV < V (B) IV < I < III < II < V
(C) III < II < I < IV < V (D) II < I < III < IV < V
5. Order of Ka of following acids is :

O O O
C C – OH
OH C – OH
O2N CH3O
I II III
(A) I > II > III (B) II > I > III (C) I > III > II (D) III > I > II

6. Give the acidic strength order for given compounds :
I: II : III : IV :
(A) II > III > I > IV (B) II > IV > III > I (C) III > I > II > IV (D) IV > III > I > II
1 2 3 4
CH2  C  CH  CH3
7. In molecule, the hybridization of carbon 1,2,3 and 4 respectively are :
3 3 3
(A) sp , sp, sp , sp (B) sp2, sp2, sp2, sp3 (C) sp2, sp, sp2, sp3 (D) sp2, sp3, sp2, sp3
8. Mesityl oxide is a common name of :

(A) 2,4-Dimethyl pentan-3-one (B) 3-Methyl cyclohexane carbaldehyde
(C) 2-Methyl cyclohexanone (D) 4-Methyl pent-3-en-2-one
9. In the following molecules,

a
H3C b

C C—O
c
H H
Hybridisation of carbon a, b and c respectively are :
(A) sp3, sp, sp (B) sp3, sp2, sp (C) sp3, sp2, sp2 (D) sp3, sp, sp2
10. Which one of the following compounds is nonaromatic ?


N
(A) (B) O (C)  (D)
11. Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution is/are:
NH2 COOH NH2
O2N NO2
A = H2N NH2 B= C=
OH NO2
(A) B only (B) C only (C) B and C only (D) A and B only
12. The correct order of acid character of the following compounds is :

OH COOH COOH COOH
I II III IV
NO2 CH3
Options :
(A) III > II > I > IV (B) IV > III > II > I (C) I > II > III > IV (D) II > III > IV > I

70
PERIODIC TABLE (INORGANIC CHEMISTRY)
1. The atomic masses of Li and K are 7 and 39, respectively. According to law of triads the
atomic mass of Na will be
(A) 23 (B) 32 (C) 46 (D) 64
2. Three elements X, Y, and Z have atomic numbers 19, 37 and 55 respectively. Then the correct
statements (s) is/are
(A)their ionization potential would increase with increasing atomic numbers
(B) Y would have an ionization potential between those of X and Z
(C) Y would have the highest ionization potential
(D) Z would have the highest ioniztion potential
3. Which of the following oxides are acidic ?

CuO,Mn2O7,CO,SO2,CrO3
(A) CrO3,Mn2O7, and SO2 (B) only SO2
(C) Mn2 O7 and SO2 (D) CO and SO2
4. Which of the following orders is incorrect with respect to the property indicated ?
(A) NH3 < PH3 < AsH3 ( acidic behaviour)
(B) Li < Be < B < C( First ionlsation energy)
(C) Al2O3 < MgO < Na2O < K2O (basic character)
(D) Li+ < Na+ < K+ < Cs+ ( ionic radius)
5. Identify the correct decreasing order of acid strength for the following compounds.
(I) HclO, (II) HbrO, (III) HIO
(A) I > II > III (B) II > I >III (C) III > II > I (D) I > III > II
6. Which among the following elements have lowest value of IE1?

(A) Pb (B) Sn (C) Si (D) C
7. Which among the following species have the same number of electrons in its outermost as well
as pendultimate shell
(A) Mg2+ (B) O2– (C) F– (D) Ca2+

8. The atomic numbers of vanadium (V) chromium (Cr) manganese (Mn) and iron (Fe) are,
respectively 23, 24, 25 and 26. Which one of these may be expected to have the highest
second ionisation enthalpy.
(A) V (B) Cr (C) Mn (D) Fe
9. Which of the following represents the correct order of increasing first ionization enthalpy for Ca,
Ba, S, Se and Ar ?
(A) Ba < Ca < Se < S < Ar (B) Ca < Ba < S < Se < Ar
(C) Ca < S < Ba < Se < Ar (D) S < Se < ca < Ba < Ar
10. How many molecules are acidic oxides among the following:
CO, NO2, SO2, SO3, NO, N2O, SiO2, Cl2O7
(A) 4 (B) 5 (C) 6 (D) 7
11. The correct order of electron gain enthalpy is

(A) S > Se > Te > O (B) Te > Se > S > O
(C) O > S > Se > Te (D) S > O > Se > Te
12. Identify the elements X and Y using the ionisation energy values given below :
Ionization energy (kJ/mol)
1st 2nd
X 495 4563
Y 731 1450
(A) X = Na ; Y = Mg (B) X = Mg ; Y = F
(C) X = Mg ; Y = Na (D) X = F; Y = Mg
13. The absolute value of the electron gain enthalpy of halogens satisfies :
(A) I > Br > Cl > F (B) Cl > Br > F > I (C) Cl > F > Br > I (D) F > Cl > Br > I

71
ATOMIC STRUCTURE (PHYSICAL CHEMISTRY)
1. The vapour of Hg absorb some electrons accelerated by a potential difference of 4.5 volts from
rest as a result of which light is emitted. If the full energy of a single incident electron is
supposed to be converted into light emitted by electron in a single Hg atom, find the wave

 
number    of the light
(A) 3.63 × 106 m–1 (B) 5.93 × 106 m–1 (C) 5.93 × 106 cm–1 (D) 5.62 × 106 m–1
x
2. An electron in an atom jumps in such a way that its kinetic energy changes from x to 9 . The
change in its potential energy (magnitude) will be -
x 16x 9x
(A) 9 (B) 9 (C) 9x (D) 16
3. What electronic transition in Li2+ produces the radiation of same wavelength as the first line in
the Balmer’s series of Hydrogen spectrum
(A) n2 = 3 to n1 = 2 (B) n2 = 6 to n1 = 3
(C) n2 = 9 to n1 = 6 (D) n2 = 9 to n1 = 8
4. An element undergoes a reaction as shown :

X + 2e–  X2– , energy released = 30.87 eV/ atom. If the energy released is used to dissociate
4 gms of H2 molecules, equally into H+ and H*, where H* is excited state of H atoms where the
electron travels in orbit whose circumference equal to four times its de Broglie's wavelength.
Determine the least moles of X that would be required.
Given I.E. of H = 13.6 eV/atom bond energy of H2 = 4.526 eV/ moleule.
(A) 1 (B) 2 (D) 3 (D) 4
5. The de-Broglie wavelength of -particles at a voltage V is (Given that -particle has 2 units
positive charge and 4 units mass)
12.3 0.286 0.101 0.856
 Å  Å  Å  Å
(A) v (B) v (C) v (D) v

6. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes
transition from an energy level with n = 4 to an energy level with (Given: Rydberg constant
1
]
912 Å
(A) 185.2 nm (B) 285.2 nm (C) 385.2 nm (D) 486.4 nm
7. The energy of second Bohr orbit of the hydrogen atom is –328 kJ mol–1. The energy of fourth
Bohr orbit would be:
(A) –41 kJ mol–1 (B) –82 kJ mol–1 (C) –164 kJ mol–1 (D) –1312 kJ mol–1
8. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain

metal (work function = 2.0 eV). The maximum kinetic energy of 1he photoelectrons will be:
(A) 0.55eV (B) 2.55eV (C) 4.45 eV (D) None
9. If the uncertainty in the position of a particle is equal to its de-Broglie wavelength, the minimum
uncertainty in its velocity should be
1 v v mv
(A) 4 (B) 4 (C) 4m (D) 4 
10. The ratio of minimum to maximum wavelengths in Balmer series of H-atom is

(A) 5 : 9 (B)5 : 36 (C) 1 : 4 (D) 3 : 4
11. According to Bohr's atomic theory :-
Z2

(a) Kinetic energy of electron is μ n2
(b) The product of velocity (v) of electron and principal quantum number (n), 'vn'  Z2.
Z2

(c) Frequency of revolution of electron in an orbit is n2 .
Z3

(d) Coulombic force of attraction on the electron is n4 .
Choose the most appropriate answer from the options given below :
(A) (c) Only (B) (a) Only
(C) (a), (c) and (d) only (D) (a) and (d) only

12. The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are
given below:
8 3
4r R n,/(r)
4r R n,/(r)
2
2
2
2
2
4
(a) (b) 1
0 5 10 0 5 10
r(Å)  r(Å) 
2.0
3
4r R n,/(r)
4r R n,/(r)
1.5
2
2
2 1.0
2
2
(c) 1 (d) 0.5
0 5 10 0 5 10
r(Å)  r(Å) 
The correct plot for 3s orbital is:
(A) (b) (B) (a) (C) (d) (D) (c)
13. The figure that is not a direct manifestation of the quantum nature of atoms is
Rb K Na
Kinetic energy of
Increasing wavelength photoelectrons
(A) (B)
Frequency of incident
Absorption spectrum radiation
T2 > T1
Internal Internal
energy of of black body
(C) Ar (D) radiation T1
300 400 500 600
Temperature (K) Wavelength

72
ISOMERISM (ORGANIC CHEMISTRY)
1. Which type of isomerism is present between compound

CH2  CH  CH2  OH & CH3  CH2  C  H
||
O
(A) Tautomers (B) Functional isomers
(C) Position isomers (D) Metamers
2. Which of the following set is not the example of positional isomerism.

CH3  CH2  C  H & CH3  C  CH3 CH2  C  CH3 & CH  CH  CH3
(A) || (B) | |
O OH OH
CH2  CH  CH2  OH& CH2  C  CH3 CH2  CH  CH2  OH & CH  CH  CH3
(C) | (D) |
OH OH
3. Given compound shows following type of isomerism OHCCH2CH2CN and OHCCH(CH3)CN

(A) Chainisomerism (B) Positional isomerism
(C) Metamerism (D) Functional group isomerism
O & O
4. are :
(A) Chain isomer (B) Positional isomers
(C) Metamers (D) Functional group isomers
O O
S—O & S—O
5.
O O
(A) Chain isomer (B) Positional isomers
(C) Metamers (D) Functional group isomers
COOH
|
HOOC  CH  CH2  COOH
6.
What is the relationship of the two compounds.
(A) Chainisomerism (B) Position isomerism
(C) Identical (D) Homologues

7. The pair of functional group isomerism is :
CH2CONH2 ,CH2 CHO
(A) | (B) CH3COOH, HCOOCH3
NH2
(C) CH3—CH2OH, CH3OCH3 (D) All the above
8. Identify the compound having highest enol content ?
OEt
(A) (B) (C) (D) EtO OEt
9. The absolute configuration of the compound is :

CH3
Cl H
Cl H
C2H5
(A) 2S, 3R (B) 2S, 3S (C) 2R, 3S (D) 2R, 3R
10. The correct statement about the compound (A), (B) and (C) is :
COOCH3 COOH COOH
H OH H OH H OH
(A) H OH (B) H OH (C) HO H
COOH COOCH3 COOCH3
(A) (A) and (B) are identical (B) (A) and (B) are diastereomers
(C) (A) and (C) are enantiomers (D) (A) and (B) are enantiomers
11. Assertion A : Enol form of acetone [CH3COCH3] exists in < 0.1% quantity. However, the enol
form of acetyl acetone [CH3COCH2OCCH3] exists in approximately 15% quantity.
Reason R : enol form of acetyl acetone is stabilized by intramolecular hydrogen bonding, which
is not possible in enol form of acetone.
Choose the correct statement :
(A) A is false but R is true
(B) Both A and R are true and R is the correct explanation of A
(C) Both A and R are true but R is not the correct explanation of A
(D) A is true but R is false
12. Compound with molecular formula C3H6O can show :

(A) Positional isomerism (B) Both positional isomerism and metamerism
(C) Metamerism (D) Functional group isomerism

73
METALLURGY (INORGANIC CHEMISTRY)
1. The method of zone refining of metals is based on the principle of

(A) Greater mobility of the pure metal than that of impurity.
(B) Greater solubility of the impurity in the molten state than in the solid.
(C) Higher melting point of the impurity than that of the pure metal.
(D) All above the correct
2. Electrometallurgical process is used to extract

(A) Fe (B) Pb (C) Na (D) Ni
3. Electrolytic reduction of alumina to aluminium by Hall-Heroult process is carried out

(A) in the presence of NaCl
(B) in presence of fluorite
(C) In presence of cryolite which forms a melt with lower melting temperature.
(D) in the presence of cryolite which forms a melt with higher melting temperature.
4. When of the following processes involves smelting
(A) ZnCO3 ZnO + CO2 (B) Fe2O3 + 3C  2Fe + 3CO
(C) 2PbS + 3O2 2PbO + 2SO2 (D) Al2O3.2H2O  Al2O3 + 2H2O
5. Which of the following process involves smelting ?

 Heat
ZnCO3   ZnO  CO2 Fe2O3  3C   2Fe  3CO
(A) (B)
Heat Heat
2PbS  3O2 
 2PbO  2SO2 Al2O3 .2H2O   Al2O3  2H2O
(C) (D)
6. Which one of the following ores is known as Malachite :

(A) Cu2S (B) Cu2O
(C) Cu(OH)2. CuCO3 (D) CuFeS2
7. During the process of electron refining of copper, some metals present as impurity settle down
as anode mud. These are:
(A) Sn and Ag (B) Pb and Zn (C) Ag and Au (D) Fe and Ni

8. Which of the following metals cannot be extracted by carbon reduction process
(A) Pb (B) Al (C) Hg (D) Zn
9. An example of halide ore is

(A)Galena (B) Bauxite (C) Cinnabar (D)Cryolite
10. In the metallurgy of iron, whenlimestone is added to the blast furnace,the calcium ion ends
up in:-
(A) Slag (B) Gangue (C) Metallic Ca (D)CaCO3
11. Which of the following statements incorrect?

(A)In Hall-Heroult process, the electrolyte used is a molten mixture of alumina, sodium
hydroxide and cryolite.
(B)Lead is extracted form its chief ore by both carbon reduction and self reduction.
(C)Tin is extracted from its chief ore by carbon monoxide reduction.
(D)Siderite and cassiterite are carbonate ores.
12. Al2O3 was leached with alkali to get X. The solution of X on passing of gas Y, forms Z. X, Y and
Z respectively are :
(A) X = Na[Al(OH)4], Y = SO2, Z = Al2O3
(B) X = Na[Al(OH)4], Y = CO2, Z = Al2O3.xH2O
(C) X = Al(OH)3, Y = CO2, Z = Al2O3
(D) X = Al(OH)3, Y = SO2, Z = Al2O3.xH2O
13. Which of the following ore is concentrated using group 1 cyanide salt ?
(A) Sphalerite (B) Calamine (C) Siderite (D) Malachite
14. Al2O3 was leached with alkali to get X. The solution of X on passing of gas Y, forms Z. X, Y and
Z respectively are :
(A) X = Na[Al(OH)4], Y = SO2, Z = Al2O3 (B) X = Na[Al(OH)4], Y = CO2, Z = Al2O3.xH2O
(C) X = Al(OH)3, Y = CO2, Z = Al2O3 (D) X = Al(OH)3, Y = SO2, Z = Al2O3.xH2O

74
REDOX REACTION (PHYSICAL CHEMISTRY)
1. Consider the following three halides:

(1) CH3 – CH2 – Cl (2) CH2 = CH – Cl (3) C6H5 – Cl
Arrange C –Cl bond length of these compounds in decreasing order -
(A) 1 > 2 > 3 (B) 1 > 3 > 2 (C) 3 > 2 > 1 (D) 2 > 3 > 1
2. RH2 (ion exchange resin) can replace Ca2+ ions in hard water as :
RH2 + Ca2+RCa + 2H+
If 1 L of hard water after passing through RH2 has pH = 3, then hardness in parts per million of
Ca2+is :
(A)10 ppm (B) 40 ppm (C) 100 ppm (D) 20 ppm
3. 2.56 x 10–3 equivalent of KOH is required to neutralise 0.12544 g H2XO4 The atomic mass of
X(in g/mol ) is:[Given: 1-12 XO 4 is a dibasic acid]
(A) 16 (B) 8 (C) 7 (D) 32
4. 1 mole of equimolar mixture of Fe2(C2O4)3 and FeC2O4 reqires X moles of KMnO4 in acid
medium for complete reaction. The value of X is :
(A) 0.9 (B) 0.6 (C) 1.2 (D) 0.8
5. A redox reaction always involves

(A) A change in oxidation number. (B) A change in phase.
(C) The transfer of protons. (D) The formation of ions.
6. 0.1 M KMnO4 is used for following titration. What volume of the solution in mL will be required
2
3
MnO–4 2
4
to react with 0.158 g of Na2S2O3? Not balanced: S2O + + H2O  MnO2(S) +SO +OH–
(A) 26.7 mL (B) 50 mL (C) 65 mL (D) 75 mL
7. In the mixture of (Na2CO3 + NaHCO3) volume of HCl required is x mL with phenolphthalein

indicator and y mL with methyl orange indicator in the same titration. Hence volume of HCl for
complete reaction of Na2CO3 is-
x
(A) 2x (B) y (C) 2 (D) (y – x)

8. What will be the value of x, y and z in the following equation?
H2C2O4 + xH-2O2 yCO2 + zH2O
(A) 2, 1, 2 (B) 1, 2, 2 (C) 2, 2, 1 (D) 1, 2, 1
9. H2O2 acts as an oxidizing agent in

(A) neutral medium (B) acidic medium
(C) alkaline medium (D) both acidic & alkaline medium
10. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M Kand 10 mL of

4 N acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used to
reach the end point. The molarity of the household bleach solution is
(A) 0.24 M (B) 0.48 M (C) 0.024 M (D) 0.96 M

11. (A) HOCl + H2O2 H3O+ + Cl– + O2

(B) I2 + H2O2 + 2OH– 2I– + 2H2O + O2
Choose the correct option.
(A) H2O2 acts as reducing and oxidising agent respectively in equation (A) and (B)
(B) H2O2 acts as oxidising agent in equation (A) and (B)
(C) H2O2 acts as reducing agent in equation (A) and (B)
(D) H2O2 act as oxidizing and reducing agent respectively in equation (A) and (B)
12. Which of the following equation depicts the oxidizing nature of H2O2?
(A) K I O4 + H 2O2  K IO3 + H 2O + O2
(B) 2I --- + H 2O2 + 2H +  I 2 + 2H 2O + O2
(C) I 2 + H 2O2 + 2OH ---  2I --- + 2H 2O + O2
(D) Cl 2 + H 2O2  2HCI + O2
CBaSO4
13. Ledt CNaCl and be the conductances (in S) measured for saturated aqueous solution of
NaCl and BaSO4. Respectively, at a temperatures T. Which of the following is false ?
(A) Ionic mobiliies of ions from both salts increase with T.
CBaSO4 CBaSO4
(B) (T2), > (T1) for T2 > T1
(C) CNaCl(T2) > CNaCl(T1) for T2 > T1
CBaSO4
(D) CNaCl ≫ at a given T

75
HYDROCARBON (ORGANIC CHEMISTRY)
1. Which statement is incorrect about photochemical chlorination of the following compound,
Ph  CH2  CH2  CH3
(A) The major product will be chiral and a racemic mixture

(B) The intermediate free radial of the major product is resonance stabilized (benzylic
secondary free radical) .
(C) This intermediate free radical will be optically inactive
(D) This intermediate free radical is also stabilized by hyperconjugation due to five -H atoms.
2. Reactivity order of halogens towards free radical substitution reaction is

(A) Br2 > F2 > Cl2 > I2 (B) F2 > I2 > Br2 > Cl2
(C) I2 > Br2 > Cl2 > F2 (D) F2 > Cl2 > Br2 > I2
Cl /h

2

3. CH3 –CH2 –CH2 –CH3 major product.
(A) CH3 –CH2 –CH2 –Cl (B)

Cl
(C) (D)
Cl Cl
4. In given compound during chlorination most reactive hydrogen atom is :
(A) Ha (B) Hb (C) Hc (D) All are equally reactive
CH3 – CH – CH  CH2 Br / CCl

5. | 2 4
X (major)
CH3
X will be
Br Br Br Br
| | | |
CH3 – C – CH – CH3 CH3 – CH – CH – CH2
(A) | (B) |
CH3 CH3

Br Br Br Br
| | | |
CH3 – C – CH2 – CH2 CH2 – CH – CH – CH2
(C) | (D) |
CH3 CH3
6. The correct order of alkene reactivity towards an electrophile is mentioned in-

(A) CH2=CH–Cl > CH2=CH–OCH3 (B) CH2=CHCl < CH2=CCl2
(C) ethene > propene (D) CH2 = CH – OCH3 > CH2=CH–
H O
7. 3 
 P (major), P is :
(A) (B)
(C) (D)
8. P (major), P is :
CH2—CH—CH3 CH—CH2CH3
(A) (B)
OH OH
CH CH—CH3 HO CH CH—CH3
(C) (D)
OH
9. An alkene on oxidative ozonolysis gives only methyl propanoic acid. The alkene is :
(A) 3, 4-Dimethyl-3-hexene (B) 2, 5-Dimethyl-3-hexene
(C) 3-Methyl-1-pentene (D) 2, 3-Dimethyl-2-butene
10. An open-chain hydrocarbon C7H12 on ozonolysis produces propanone, methanal and 2-

oxopropanal. The hydrocarbon could be :
CH3 CH3
(A) (CH3)2C = CHC = CH2 (B) (CH 3)2C = C – CH = CH2
(C) Both (A) and (B) (D) None of these

11. An unsaturated hydrocarbon X on ozonolysis gives A. Compound A when warmed with
ammonical silver nitrate form a bright silver mirror along the sides of the test tube. The
unsaturated hydrocarbon X is :
CH3 — C
|
 C — CH3
|
CH3—C 
(A) (B)
CH3 CH3
 
(C) HC C—CH2—CH3 (D) CH3—C C—CH3
Br A
CH3 CCl4 (Major product)
12.
Br Br CH Br
3
Br CH3
CH3 CH3
(A) (B) CH3 (C) (D)
CH3 CH3
13. Choose the correct statement regarding the formation of carbocations A and B give :-
+
CH3—CH2—CH2—CH2+Br–
"A"

CH3—CH2—CH CH2+HBr—
+
CH3—CH2—CH—CH3+Br–
"A"
(A) Carbocation B is more stable and formed relatively at faster rate
(B) Carbocation A is more stable and formed relatively at show rate
(C) Carbocation B is more stable and formed relatively at slow rate
(D) Carbocaion A is more stable and formed relatively at faster rate

76
CHEMICAL BONDING (INORGANIC CHEMISTRY)
1. The gas which has similar shape and bond order as that of azide ion is:
(A) Sulphur dioxide (B) Ozone

(C) Sulphur trioxide (D) Carbon dioxide
2. The correct shape and I–I–I bond angles respectively in I3– ion are :
(A) Distorted trigonal planar; 135° and 90° (B) T-shaped; 180° and 90°
(C) Trigonal planar; 120° (D) Linear; 180°
3. A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The
shape of this molecule is :
(A) see-saw (B) planar triangular
(C) T-shaped (D) trigonal pyramidal
4. Which of the following compound CANNOT act as a Lewis base ?
(A) NF3 (B) PCl5
(C) SF4 (D) ClF3
5. A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The
shape of this molecule is :
(A) see-saw (B) planar triangular
(C) T-shaped (D) trigonal pyramidal
6. Which of the following compound CANNOT act as a Lewis base ?
(A) NF3 (B) PCl5
(C) SF4 (D) ClF3


77
CHEMICAL KINETICS (PHYSICAL CHEMISTRY)
1. Four thousand active nuclei of a radioactive material are present at t = 0. After 60 minutes 500
active nuclei are left in the sample. The decay constant of the sample is
ln  2  ln  2 
(A) 60 per minute (B) 20 per minute
(C) 20 ln (2) per minute (D) 60 ln (2) per minute
2. At 500 K, the half life period of a gaseous reaction at an initial pressure of 80 kPa is 350 s.
When the pressure is 40 kPa, the half life period is 175 sec; the order of the reaction is:
(A) zero (B) one (C) two (D) three
t1
3. Following is the graph between log and log 2 a(a = initial concentration of reactant) for a given
reaction at 27ºC. Hence, order of the reaction is
=45º
logt1/2
O loga
(A) 0 (B) 1 (C) 2 (D) 3
234
90 Th
4. The radioactive isotope undergoes two successive -decay followed by -decay. The
atomic number and the mass number respectively of the resulting isotope are :
(A) 92 and 237 (B) 94 and 230 (C) 90 and 230 (D) 92 and 230
5. The rate of decomposition for methyl nitrite and ethyl nitrite can be given in terms of rate
constant k1 and k2 respectively. The energy of activation for the two reactions are 152.30 kJ
mol–1 and mol–1 and 157.7 kJ mol–1 as well as frequency factors are 1013 and 1014 respectively

for the decomposition of methyl and ethyl nitrite. Calculate the temperature at which rate
constant will be same for the two reactions.
(A) 256 K (B) 354 K (C) 282 K (D) 674 K
6. At the point of intersection of the two curves shown, the concentration of B is given by
.............., for the first reaction AnB.
A0
[B]
Conc.
Time
nA0 A0 nA0  n –1

 
(A) 2 (B) n – 1 (C) n  1 (D)  n  1  A0
7. The half-life period for catalytic decomposition of AB3 at 50 mm is found to be 4 hrs and at 100
mm it is 2 hrs. The correct of the reaction is :
(A) 3 (B) 1 (C) 2 (D) 0
8. Decomposition of H2O2 follows a first order reaction. In fifty minutes the concentration of H2O2
decreases from 0.5 to 0.125 M in one such decomposition. When the concentration of H2O2
reaches 0.05 M, the rate of formation of O2 will be :
(A) 2.66 Lmin–1 at STP (B) 1.34 × 10–2 mol min–1
(C) 6.93 × 10–2 mol min–1 (D) 6.93 × 10–4 mol min–1
   
A  t 1  10min  & B  t 1  20min 
9. Two substance  2   2  follows I order kinetics in such a way that
[A]i = 8 [B]i. Time when [B] = 2[A] in min is:
(A) 20 (B) 40 (C) 60 (D) 80
10. Consider the following gaseous reaction where initial pressure of A(g) is 200 torr
A(g)  3B(g) + C(g)
After time t, the pressure of system increased to 650 torr. Calculate the value of t (in seconds)
(Given : rate constant of reaction, k = 4.606 × 10–3 sec–1, log 2 = 0.3)
(A) 600 (B) 300 (C) 50 (D) 5

11. Simplified absorption spectra of three complex [(i), (ii) and (iii)] of Mn+ ion are provided below;
their max values are marked as A, B and C respectively. The correct match between the
complexes and their max values is
Absorption
B
max max max

Wavelength (nm)
(i) [M(NCS)6](–6 + n) (ii) [MF6](–6 + n) (iii) [M(NH3)6]n+
(A) A-(iii), B-(i), (C)-(ii) (B) A-(ii), B-(i), (C)-(iii)
(C) A-(ii), B-(iii), (C)-(i) (D) A-(i), B-(ii), (C)-(iii)
12. Amongst the following statements regarding adsorption, those that are valid are:
(a) DH becomes less negative as adsorption proceeds.
(b) On a given adsorbent, ammonia is adsorbed more than nitrogen
(c) On adsorption, the residual force acting along the surface of the adsorbent increases
(d) With increase in temperature, the equilibrium concentration of adsorbate increases.
(A) (d) and (a) (B) (b) and (c) (C) (a) and (b) (D) (c) and (d)
13. It is true that

(A) a second order reaction is always a multistep reaction
(B) a zero order reaction is a multistep reaction
(C) a first order reaction is always a single step reaction
(D) a zero order reaction is a single step reaction

78
ALKYL HALIDE & HALOGEN DERIVATIVE (ORGANIC CHEMISTRY)
1. Which of the following reaction is/are feasible?

CH3 CH3
+ –
CH3CH2Br + NaO – C – CH 3 CH3CH2O – C – CH3
(A)
CH3 CH3
CH3 CH3
+ –
CH3 – C – Cl + Na O CH2CH3 CH3CH2 – O – C – CH3
(B)
CH3 CH3
(C) Both (A) and (B)
(D) None of the above
2. When the concentration of alkyl halide is tripled and concentration of nucleophile is reduced to
half, the rate of SN2 reaction is increased by
(A) 3 times (B) 1.5 times (C) 2 times (D) 6 times
3. The reaction
Me
NaH Me-I
OH O Na O
can be classified as:
(A) Williamson ether synthesis reaction
(B) Alcohol formation reaction
(C) Dehydration reaction
(D) Williamson alcohol synthesis reaction

4. The major product of the following reaction is
O
C
NH (i) KOH
C (ii) Br CH2Cl
O
O O
C C
N CH2 Br N CH2Cl
(A) C (B) C
O O
O O
C C
N N
(C) (D) C
O CH2 Br
O CH2Cl
OH
AgNO3
Product

5. CH2–Cl
O O O O
(A) (B) (C) (D)
Cl Cl
6. Which of following compound will not undergo acid catalysed hydrolysis ?

O–CH3 O–Ph O–CH2CH3
(A) (B) (C) (D)
OCH3
(x) conc. HI
7. OCH3
x = moles of HI consumed.
value of x is
(A) 2 (B) 4 (C) 5 (D) 6

alc. KOH
CH3  CH2  CH  CH3 

8. | X (major)
Br
(A) (B) (C) (D) None of these

H


9. (X).
Major product (X) is
(A) (B) (C) (D)
10. Which of following halides gives fastest elimination reaction when it is treated with alcoholic
KOH.
Br
Br Br
Br
(A) (B) (C) (D)
11. What is the final product (Major) 'A' in the given reaction ?
CH3 OH
CH
CH3 
HCl
 'A'
(major product)
CH3 CH3 CH3 CH3 Cl

Cl CH Cl CH
CH3 CH3
CH2–CH3 CH2–CH3
(A) (B) (C) (D)

12. Identify A and B in the chemical reaction.
OCH3
HCl NaI
[A] [B]
(major) dry acetone (major)
NO2
OCH3 OCH3 OCH3 I
Cl
Cl Cl Cl
(A) A = NO2 B= NO2 (B) A = NO2 B= NO2
OCH3 I OCH3 OCH3

Cl Cl Cl I
(C) A = NO2 B= NO2 (D) A = NO2 B= NO2
13. Identify A in the given reaction.

OH
SOCl2
A (Major Product)
HO CH2OH
OH OH Cl Cl
(A) (B) (C) (D)

HO CH2Cl Cl CH2Cl Cl CH2Cl OH CH2OH

79
COORDINATION COMPOUNDS (INORGANIC CHEMISTRY)
1. How many EDTA (ethylenediamineteraacetate) unit(s) are required to make an octahedral

2+
complex with a Ca ion ?

(A) Six (B) Three (C) One (D) Two
2. The total number of possible isomers for the complex compound [Cu(NH3)4][PtCl4]
(A) 4 (B) 5 (C) 6 (D) 3
3. The -bounded organometallic compound which has ethylene as one of its component is
(A) Dibenzene chromium (B) Zeise salt
(C) Ferrocene (D)Tetraethyl tin
Pt Py NH3  BrCl  ?

4. How many geometrical isomers are formed by the complex
(A) 3 (B) 4 (C) 0 (D) 2
5. The correct statement on the isomerism associated with the following complex ions.
(a) [Ni(H2O)5NH3]2+ (b) [Ni(H2O)4 (NH3)2]2+ and (c) [Ni(H2O)3 (NH3)3]2+ is
(A) (a) and (b) show only geometrical isomerism
(B) (a) and (b) show geometrical and optical isomerism
(C) (b) amd (c) show geometrical and optical isomerism
(D) (b) and (c) show only geometrical isomerism
6. Which of the complexes is expected to have lowest 0 value? [consider only magnitude]
Co(NH3 )6 3  Rh(NH3 )6 3  lr (NH3 )6 3  [CoF6 ]3
(A) (B) (C) (D)
7. Nickel (Z = 28) combines with a uninegative monodentate ligand to form a diamagnetic

2–
complex [NiL4] . The hybridization involved and the number of unpaired electrons present in
the complex are respectively.
(A) dsp2, zero (B) sp2, zero (C) dsp2, one (D) sp2, two

8. Which of the following coordination compounds has maximum number of isomers?
2 2
Pt  NH3 4 Cl2  Pt  gly 3 
(A) (B)
4
Pt  en3  Pt  NH3 3 Cl2 
(C) (D)
9. Which of the following complex has the highest value of t.

(A) [CoCl4]2 –
(B) [CoBr4]2– (C) [CoI4]2– (D) [Co(NCS)4]2–
10. [NiCl4]2–, [PtCl4]2– and [PdCl4]2– are respectively :-

(A) high spin, low spin, high spin (B) low spin, low spin, low spin
(C) high spin, low spin, low spin (D) low spin, high spin, high spin
11. Types(s) of isomerism shown by [Co(en))2Cl2]Br :-

(A) Geometrical (B) Optical (C) Ionisation (D) All of these
12. Which of the following statement is wrong

2– 4
(A) RuCl6  has a t 2g configuration
3–
(B) Fe  Ox 3  is a low spin complex
(C) Pairing energy of 4d and 5d series metal tend to be lower than the 3d series metals.
3–
(D) Number of unpaired electrons in Mn  CN6  is 2.
13. Incorrect match among the following is:

(A) Vitamin B12– Cu (B) Cis-platin -Pt
(C) Wilkinson catalyst – Rh (D) Chlorophyll - Mg

80
LIQUID SOLUTION (PHYSICAL CHEMISTRY)
Tb
1. Ratio K b of 10 g AB2 and 14 g A2 B per 100 g of solvent in their respective, solution (AB2 and
A2 B both are non-electroytes) is 1 mol/kg in both cases. Hence, atomic wt. of A and B are
respectively:
(A) 100, 40 (B) 60, 20 (C) 20, 60 (D) None of these
2. The amount (in grams) of sucrose (mol wt. = 342 g) that should be dissolved in 100 g water in
order to produce a solution with a 105.0 °C difference between the freezing point and boiling
point is (given that Kf = 1.86 K kg mol–1 and kb = 0.51 k kg mol–1 for water)
(A) 34.2 g (B) 72.2 g (C) 342 g (D) 460 g
3. Urea (NH2 – CO – NH2) needs to be dissolved in 100 g of water, in order to decrease the
vapour pressure of water by 25% ? What will be the molality of the solution ?
(A)18.52 (B) 62.45 (C) 28.52 (D)35.64
4. A 5.25% solution of a substance is isotonic with a 1.5% solution of urea (molar mass = 60 g
mol–1) in the same solvent. If the densities of both the solutions are assumed to be equal to 1.0
g cm–3, molar mass of the substance will be
(A) 210 g mol–1 (B) 90.0 g mol–1 (C) 115.0 mol–1 (D) 105.0 g mol–1
5. The solubility of N2 in water at 300 K and 500 torr partial pressure 0.01 g L–1. The solubility
(in g L–1) at 750 torr partial pressure is:
(A) 0.0075 (B) 0.005 (C) 0.02 (D) 0.015
6. 2.0 molal aqueous solution of an electrolyte X2Y3 is 75% ionised. The boiling point of the
solution a 1 atm is (Kb(H2O) = 0.52 K kg mol–1)
(A) 274.76K (B) 377K (C) 376.4K (D) 377.16K
7. The vapour pressure of pure liquid A is 10 torr and at the same temperature when 9 g of B
solid dissolved in 20 g of A, its Vapour pressure is reduced to 5 torr. If the molecular mass of
A is 200 amu, then the molecular mass of B is
(A) 100 amu (B) 90 amu (C) 75 amu (D) 120 amu

8. K2HgI4 is 55% onized in aqueous solution. The value of Van't Hoff factor is
(A) 2.1 (B) 4.3 (C) 1.9 (D) 3.7
9. The concentration in g/L of a solution of cane sugar (Molecular weight = 342) which is isotonic
with a solution containing 6 g of urea (Molecular weight = 60) per litre is
(A) 3.42 (B) 34.2 (C) 5.7 (D) 19
10. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water
changes the freezing point of the solution. Use the freezing point depression constant of water as
2 K kg mol–1. The figures shown below represent plots of vapour pressure (V.P.) versus
temperature (T). [molecular weight of ethanol is 46 g mol–1.
Among the following, the option representing change in the freezing point is
Water Water
V.P./bar
V.P./bar
1 1
Ice Ice
(A) Water+Ethanol (B) Water+Ethanol
270 273 T/K 271 273 T/K
Water Water
V.P./bar
V.P./bar
Ice Ice
1 1
Water+Ethanol Water+Ethanol
(C) (D)
270 273 T/K 271 273 T/K
11. The size of raw mango shrinks to a much smaller size when kept in a concentrated salt
solution. Which one of the following processes can explain this?
(A) Osmosis (B) Dialysis (C) Diffusion (D) Reverse osmosis
12. An acidic buffer is obtained on mixing

(A) 100 mL of 0.1 CH3COOH and 100 mL of 0.1 M NaOH
(B) 100 mL of 0.1 HCl and 200 mL of 0.1 M NaCl
(C) 100 mL of 0.1 CH3COOH and 200 mL of 0.1 M NaOH
(D) 100 mL of 0.1 HCl and 200 mL of 0.1 M CH3COONa
13. A solution of two components containing n1 moles of the 1st component and n2 moles of the 2nd
component is prepared. M1 and M2 are the molecular weights of component 1 and 2
respectively. If d is the density of the solution in g mL–1, C2 is the molarity and 2 is the mole-
fraction of the 2nd component, then C2 can be expressed as
1000 2 d 2
C2  C2 
(A) M1   2 (M2  M1 ) (B) M2  2 (M2  M1 )
1000d 2 d1
C2  C2 
(C) M2  2 (M2  M1 ) (D) M2  2 (M2  M1 )

81
GRIGNARD REAGENT (ORGANIC CHEMISTRY)
1.
The product B is
(A) Benzyl alcohol (B) 2-Phenylethanol
(C)1-Phenylethanol (D) Quinol
2. In the reaction,
The compound (C) is ?
(A) (B)
(C) (D)
3. Choose the product of the following reaction :
(A) (B) (C) (D)

4. Which reaction produce 1-methylcyclohexene
Br
( i ) aq. KOH ( i) HBr
Br     

(A) ( ii ) CH3MgBr , ether (B) ( ii) alcoholic KOH, 
( iii ) H , H2O
Br
( i) Mg, ether ( i ) HI
   
  
(C) ( ii) CH 2 O (D) ( ii ) aq . NaOH
( iii ) H  , H 2 O
5. Identify (A) in the following reaction sequence

O
C
(i) CH3MgBr O3/Zn2H2O H
(A) (A)
(ii) H+,H2O CH3
Give Positive
(iii) Conc. H2SO4/ H3C C O
iodoform test
CH3
CH3
(A) O CH3 (B) O CH3
CH3 CH3
CH3
(C) O CH3 (D) O CH3
OH CHO
+ CH3MgBr P +Q
COOH (Excess) (Gas)
6. HO
1 mole
How many litres of gas ‘P’ is formed in above reaction at NTP. (molar volume of gas at NTP is
22.4 L)
(A) 22.4 L (B) 33.6 L
(C) 44.8 L (D) 66 L
7. In which of the following reactions, alcohol is formed as product gives positive iodoform test?
O
Ph–MgBr
(A) CH3—C—CH3 HOH/H+

(I)CH3 MgBr (excess)(II) H2O/H
 
(B) CH3–CH2–CH=O
O
(C) (i) PhMgBr(excess)
H—C—OEt
(ii) HOH/H+
O
(i) PhMgBr(excess)
(D) CH3—C—OEt (ii) HOH/H+

8. The product formed in the first step of the reaction of
Br
CH3–CH2–CH–CH2–CH–CH3
with excess Mg/Et2O(Et = C2H5) is:
Br
CH3–CH2–CH–CH2–CH–CH3 CH3–CH2–CH–CH2–CH–CH3
(A) (B)
CH3–CH–CH2–CH–CH2–CH3 CH3–CH2–CH–CH2–CH–CH3
MgBr
CH2
CH3–CH CH3CH2–CH–CH2–CH–CH3
(C) CH–CH3 (D)
MgBr
CN
(i) C 6 H5 MgBr Ether (1.0 equivalent ), dry
    (ii) H O
 
3
9. X Major Product
OCH3
The structure of X is :
O O
C6H5 C6H5
NH2 NH2
(A) (B) (C) C6H5 (D)
C6H5 OCH3 C6H5 OCH3
10. Reaction of Grignard reagent, C2H5MgBrwith C8H8O followed by hydrolysis gives compound "A"
which reacts instantly with Lucas reagent to give compound B, C10H13Cl. The Compound B is :
Cl
CH3 Cl CH3
CH 3
Cl
CH3 CH3 CH3
(A) (B) Cl (C) (D)

82
BLOCK (S, P, D & F) CHEMISTRY (INORGANIC CHEMISTRY)
1. Which of the following are not more basic than Al(OH)3 ?

(A)Ca(OH)2, Ce(OH)3 (B)Yb(OH)3, Lu(OH)3
(C)B(OH)3, Be(OH)2 (D)Ce(OH)3, Lu(OH)3
2. Number of sigma bonds in P4O10 is

(A) 6 (B) 7 (C) 17 (D) 16
3. The geometry of XeOF4 by VSEPR theory is:

(A) Trigonal bipyramidal (B) Square pyramidal
(C) Pentagonal planar (D) Octahedral
4. In which of the following species, each atom carries same number of lone pair of electrons on it?
XeO2–
4 XeO64– O3
(A) (B) XeF2 (C) (D)
5. Which of the following is a cyclic oxoacid ?

(A) H4P2O7 (B) H2P2O6 (C) H3P3O9 (D) H5P5O15
6. Identify the correct order of increasing number of -bonds in structures of the following
molecules.
(i) H2S2O6 (ii) H2SO3 (iii) H2S2O5
(A)I < II < III (B) II < III < I (C) II < I < III (D) I < III < II
7. The polarity of (i) (CH3)2P(CF3)3 and (ii) (CH3)3 P(CF3)2 respectively are ?
(A) (i) Non Polar (ii) Polar (B) (i) Polar (ii) Non Polar
(C) (i) Non Polar (ii) Non Polar (D) (i) Polar (ii) Polar
8. The carbon-carbon bond distance in benzene is

(A)Longer than a C–C single bond (B) Longer than a C–C double bond
(C)Shorter than a C=C double bond (D) Shorter than a C=C triple bond

9. Which type of silicate compound, Beryl (Be3Al2Si6O18) is ?
(A) Chain silicate (B) Cyclic silicate (C) Planar silicate (D) Disilicate
10. Least stable peroxide among the following:

(A) MgO2 (B) CaO2 (C) SrO2 (D) BaO2
11. Select which type of overlapping is responsible for -character in Si–N bond of H3SiNCO
(A) 3p  2p (B) 2p  2p (C) 3d  2p (D) 3d  2d
*2p and 1s

*
12. What is the ratio of number of nodal planes present in molecular orbitals?
(A) 0 (B)   (C) 2 (D) 1
13. Which of the following does not illustrate the anomalous properties of lithium ?
(A) Li is much softer than the other group first metals
(B) The melting point and boilling point of Li are comparatively high
3
(C) Li forms a nitride Li N unlike group first metals
(D) The ions of Li and its compounds are more heavily hydrated than those of the rest of the
group first elements
– –
3
14. When an inorganic compound X having 3c – 2e as well as 2c – 2e bounds react with NH gas
at a certain temperature, gives a compounds Y, isostructural with benzene. Compound X with
ammonia at a high temperature produces a substance Z, then
3 2 2 3
(A) X is BH , Y is B N H , Z is inorganic Benzene
2 6 3 3 6
(B) X is B H , Y is B N H , Z is Boron nitride
2 3
(C) X is borax, Y is B O , Z is inorganic Benzene
(D) Reactions insufficient to predict
15. Referring to the following reactions the missing products A, B, C, and D respectively are
4 2 2
NH Cl(aq) + NaNO (aq)  [A] + H O(l) + NaCl(aq)

4 2 2 7   2 2 3
(NH ) Cr O [B] + H O(l) + Cr O (s)
3 3 2 2
Cu + HNO (dilute)  Cu(NO ) + [C] + H O(l)
3 3 2 2
Cu + HNO (concentrate) Cu(NO ) + [D] + H O(l)
2 2 2 2 3 2
(A) N , N , NO, NO (B) N , NH , N , NO
2 2 2 2 2 3 2 2 4
(C) N , N , NO , NO (D) N , NH , NO , N O

83
CHEMICAL EQUILIBRIUM (PHYSICAL CHEMISTRY)
1. In a saturated solution of the sparingly soluble strong electrolyte AgIO3 (molecular mass = 283)
the equilibrium which sets in is
IO 3
+
AgIO3(s) Ag (aq) + (aq)
If the solubility product constant, Ksp of AgIO3 at a given temperature is 1.0 × 10–8, what is the
mass of AgIO3 contained in 100 mL of its saturated solution.
(A) 28.3 × 10–2 g (B) 2.83 × 10–3 g (C) 1.8 × 10–7 g (D) 1.0 × 10–4 g
2. The first and second dissociation constants of an acid H2A are 1.0 × 10–5 and 5.0 × 10–10,
respectively. The overall dissociation constant of the acid will be
(A) 5.0 × 10–5 (B) 5.0 × 1015 (C) 5.0 × 10–15 (D) 0.2 × 105
3. The equilibrium constant Kc for the reaction

1
SO3(g) SO2(g) + 2 O2(g)
is 4.9 × 10–2. The value of Kc for the reaction
2SO2(g) + O2(g) 2SO3(g) will be

(A) 416 (B) 2.40 × 10–3 (C) 9.8 × 10–2 (D) 4.9 × 10–2
4. Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,
PCl5(g) PCl3(g) + Cl2(g)

If total pressure, at equilibrium, of the reaction mixture is p and degree of dissociation of PCl5 is
x, the partial pressure of PCl3 will be
 x   2x   x   x 
 p  p  p  p
(A)  x  1  (B)  1  x  (C)  x  1  (D)  1  x 

5. An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain
temperature and 0.50 atm pressure. Ammonium hydrogen sulphide decomposes to yield NH3
and H2S gases in the flask. When the decomposition reaction reaches equilibrium, the total
pressure in the flask rises to 0.84 atm. The equilibrium of NH4HS at this temperature is
(A) 0.11 (B) 0.17 (C) 0.18 (D) 0.30
6. For the reaction,
2NO2(g) 2NO(g) + O2(g)

[Kc = 1.8 × 10–6 at 184°C, R = 0.00831 kJ/(mol K)]
When Kp and Kc are compared at 184°C it is found that
(A) whether Kp is greater than, less than or equal to Kc depends upon the total gas pressure
(B) Kp = Kc
(C) Kp is less than Kc
(D) Kp is greater than Kc
7. The exothermic formation of ClF3 is represented by the equation
Cl2(g) + 3F2(g) ClF3(g); Hr = –329 kJ

Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and
ClF3?
(A) Adding F2 (B) Increasing the volume of the container
(C) Removing Cl2 (D) Increasing the temperature
8. What is the conjugate base of HO–?

(A) O2– (B) O– (C) H2Os (D) O2
9. The solubility product of a salt having general formula MX2, in water is 4 × 10–12. The
concentration of M2+ ions in the aqueous solution of the salt is
(A) 4.0 × 10–10 M (B) 1.6 × 10–4 M (C) 1.0 × 10–4 M (D) 2.0 × 10–6 M

10. Consider the reaction equilibrium
2SO2(g) + O2(g) 2SO3(g)

H° = –198 kJ
On the basis of Le-Chatelier's principle, the condition favourable for the forward reaction is
(A) lowering of temperature as well as pressure
(B) increasing temperature as well as pressure
(C) lowering the temperature and increasing the pressure
(D) any value of temperature and pressure
11. For the equilibrium A , the variation of the rate of the forward (a) and reverse (b) reaction with
time is given by
Rate of reaction
Rate of reaction
a
a
Equilibrium Equilibrium
(a) b (b) b
Time Time
Rate of reaction
Rate of reaction
a a
Equilibrium Equilibrium
b
(c) b (d)
Time Time
K (1)
eq K (2)
eq
12. If the equilibrium constant for A B + C is and that of B + C P is , the equilibrium
constant for A P is
K (1) (2)
eq / K eq K (1) (2)
eq  K eq K (1) (2)
eqK eq K (2) (1)
eq  K eq
(A) (B) (C) (D)
13. Consider the following reaction :

N2O4(g) 2NO2(g) ; Hº = + 58 kJ
For each of the following cases (A, B), the direction in which the equilibrium shifts is
(A) temperature is decreased.
(B) pressure is increased by adding N2 at constant T.
(a) (A) towards product, (B) towards reactant
(b) (A) towards reactant, (B) no change
(c) (A) towards reactant, (B) towards product
(d) (A) towards product, (B) no change

84
OXIDATION REDUCTION (ORGANIC CHEMISTRY)
1. Which of the following statements is true for the reaction given below ?
H H
alkalineKMnO4
—
—
C—
—C P
—
—
H3 C CH3
(A) P is a the meso compound 2, 3-butanediol formed by syn-addition
(B) P is a the meso compound 2, 3-butanediol formed by anti-addition
(C) P is a racemic mixture of (d) and (l) 2, 3- butanediol formed by anti-addition
(D) P is a racemic mixture of (d) and (l) 2, 3-butanediol formed by syn-addition
2. Which of the following compound gives red colour with ceric ammonium nitrate.
OH NH
2
COOH O
(A) (B) Cl (C) (*D)

OH

3. What are A, B and C in the following
O
NaBH 4
A PCC CH3OH B
OH
Raney Ni, H2
C
O OH
in all case in all case

(A) (B)
O O
O O O
A; ,B ,C
(C)
O O OH
O OH OH
A; ,B ,C
(D)
O OH OH
4. The end products of the following sequences of reactions are

O
(1) I2 + NaOH, 
(2) H+
C–CH3
(3) 
O
O O
(A) yellow precipitate of CHI3 (B) yellow precipitate of CHI3 COOH

O O
OH
(C) yellow precipitate of CHI3 OH (D) yellow precipitate of CHI3
O
5. In the given transformation. which of the following is the most appropriate reagent ?
CH CHCOCH3 CH CHCH2CH3
Reagent
HO HO
(A) Zn-Hg/HCl (B)Na, liq, NH3 (C)NaBH4 (D)NH2-NH2, OH–

6. What is the final product of following reactions ?
(i) NaBH4
Hex  3  ynal 
(i)PBr3
(ii) Mg/ ether
(iii) CO 2 /H3 O 
COOH COOH
(A)
(B)
COOH
COOH
(C) (D)
KMnO /OH
RCH2 OH 
4
 P.
7. What is the compound P ?
(A) RCOOH (B)RCHO (C) RCH2OH (D)None of these
8. Which of the following gives ketone on oxidation ?

(A) (CH3)3COH (B) CH3CH2CH2OH
(C) (CH3)2CHCH2OH (D) CH3CHOHCH3
9. Which of the following reagent is used for the following reaction ?

?
 
CH3CH2CH3 CH3CH2CHO
(A) Manganese acetate (B) Copper at high temperature and pressure
(C) Molybdenum oxide (D) Potassium permanganate
10. Identify products A and B :

CH3 CH3
OH
(A) A : B:
OH O
CH3 CH3
OH OH
(B) A : B:
OH O
O O
OHC–CH2CH2CH2–C–CH3 HOOC–CH2CH2CH2–C–CH3
(C) A : B:
CH3 CH3
(D) A : B:
OH O
?
11. O O
Which of the following reagent is suitable for the preparation of the product in the above
reaction ?
 
C2H5 ONa
(A) NaBH4 (B) NH2–NH2/
(C) Ni/H2 (D) Red P + Cl2

85
IONIC EQUILIBRIUM (PHYSICAL CHEMISTRY)
1. Solid Na2SO4 is slowly added to a solution which is 0.020 M in Ba(NO3)2and 0.020 M in

Pb(NO3)2. Assume that there is no increase in volume on adding Na2SO4. There preferential
precipitation takes place. What is the concentration of Ba2+ when PbSO4. Startsto precipitate?
[Ksp (BaSO4) = 1.0 × 10–10 and Ksp(PbSO4) = 1.6 × 10–8]
(A) 5.0 × 10–9 M (B) 8.0 × 10–7 M
(C) 1.25 × 10–11 M (D) 1.95 × 10–8 M
2. For two weak acids A and B, the ratio of their percent ionization is 4:9. The ratio of their Ka
would be –
(A) 4:9 (B) 2:3
(C) 16 : 81 (D) 3:2
3. Which one of the following mixture does not act as a buffer solution-
(A) Boric acid and borax
(B) Sodium Phosphate & disodium hydrogen phosphate
(C) Sodium propionate and propionic acid
(D) O Sodium acetate and sodium propionate
4. pH of 0.005 M calcium acetate (pKa of CH3COOH = 4.74) is

(A) 7.04 (B) 9.37
(C) 9.26 (D) 8.37
5. If pKb for CN– at 25°C is 4.7, the pH of 0.5 M aqueous NaCN solution is
(A) 10 (B) 11.5
(C) 11 (D) 12
6. An acid base indicator has Ka = 3 × 10–5. The acid form of the indicator is red and the basic
form is blue. By how much must the pH change in order to change the indicator from 75% red
to 75% blue (log 3 = 0.4770)
(A) 0 0.95 (B) 2.3
(C) 0.75 (D) 5

7. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a
correct combination?
Base Acid End point Base Acid End point
(A) (B)
Strong Strong Pink to colorless Weak Strong Colorless to pink
Base Acid End point Base Acid End point
(C) (D)
Strong Strong Pinkish red to yellow Weak Strong Yellow to pinkish red
8. The pH of 0.1 M solution of the following salts increases in the order

(A)NaCl< NH4CI <NaCN<HCl (B)HCl< NH4CI <NaCl<NaCN
(C)NaCN< NH4CI <NaCl<HCl (D)HCl<NaCl<NaCN< NH4Cl
9. 20 ml of 0.1 M NaOh is added to 30 ml 0.1 M NaOH 30 ml 0.2 M CH3COOH, (pKa = 4.74)

calculate the pH of the resulting solution ?
[given : log 2 = 0.3]
(A) 3.44 (B) 4.01 (C) 4.44 (D) 4.71
10. The table below gives the results of three titrations carried out with 0.200 M HCI to determine
the molarity of a given NaOH solution using phenolphthalein as indicator. NaOH was taken in
the burette and HCI was taken in a conical flask for the titrations
Titration No. VHCl(mL) VNaOH(mL) MNaOH mol/dm3
I 21.4 19.3 0.222
II 18.6 16.8 0.221
III 22.2 21.1 0.210
The actual molarity of the prepared NaOH solution was 0.220 mol dm–3. Which among the
following could be the reason for the wrong value obtained in titration III?
(A) Number of drops of phenolphthalein added to the titration flask was more in this titration
(B) The concentration of HCl was wrongly used as 0.250 M for the calculation of M NaOH
(C) A few drops of NaOH solution were spilled outside the titration flask during titration
(D) A few drops of the neutralized solution from titration II were left behind in the flask
11. The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is:

[Assume : No cyano complex is formed; Ksp(AgCN) = 2.2 × 10–16 and Ka(HCN) = 6.2 × 10–10]
(A) 0.625 × 10–6 (B) 1.9 × 10–5 (C) 2.2 × 10–16 (D) 1.6 × 10–6
12. The solubility of Ca(OH)2 in water is :

[Given: The solubility product of Ca(OH)2 in water = 5.5 × 10–6]
(A) 1.77 × 10–6 (B) 1.11 × 10–6 (C) 1.11 × 10–2 (D) 1.77 × 10–2
13. Amongst the following, the form of water with the lowest ionic conductance at 298 K is
(A) saline water used for intravenous injection
(B) distilled water
(C) water from a well
(D) sea water

86
ALDEHYDE & KETONE (ORGANIC CHEMISTRY)
1. An organic compound X is oxidized by using acidified K2Cr2O7. The product obtained reacts
with phenyl hydrazine, but does not answer silver mirror test. The possible structure of X is
(A) CH3COCH3 (B) (CH3)2CHOH (C) CH3CHO (D) CH3CH2OH
2. Which of the following is not formed iniodoformreaction?

(A) CH3COCH2I (B) ICH2COCH2I (C) CH3COCHI2 (D) CH3COCI3
3. The formation of cyanohydrin from acetone is which type of reaction?

(A) Electrophilic addition reaction (B) Electrophilic substitution reaction
(C) Nucleophilic substitution reaction (D) Nucleophilic addition reaction
O
conc. NaOH
CHO 
4. Product should
OH
COCHO
COCH CHOHCOONa
(A) (B)
COCH2OH COONa COCH2OH
(C) + (D) + CH3OH
PCl5 ,0C 2 
(i)NaNH excess
NaNH2 CH3 H2 /Pd,
P   Q 
2HCl
 R   S 
 T  
5. (ii)H
P is
O
CH=0 O Cl CH=0
(A) (B) (C) (D)

6. Which of the following will show cannnizzaro reaction:
CHO
CHO O = CH
(A) (B) (C) O = CH (D) All of these

NO2
2,4-DNP
Positive
test
Organic
compound
7. Fehling’s
Positive
test
How many among the following compounds will give the above result?
i. Cyclohexanone ii. Acetone iii. Propionaldehyde
iv. Acetophenone v. Acetaldehyde vi. Benzophenone
vii. Benzaldehyde
(A) 2 (B) 3 (C) 4 (D) 5
OH O
CH–C–OH
8.
Identify the product of above higher esterification reaction.

OEt O
| PH–CH–C=O
(A) PH – CH – COOH (B)
O
||
(C) PH – CH – CO 2Et (D) PH – CH – C – Et
| |
OH OH
(i) O3 (2) Zn|H 2 O Cannizzaro reaction

     
9. (A) + (B) (C) + (D) (alcohol)
Idntity at the possible product
H–C–ONa CH3–C–ONa
(A) (B) (C) CH3–OH (D) none of these
O O

OCH3 OCH3
EtOOC COOEt H2NOH (i) ConH2 SO4
A E C
10. (ii)  pH 5/6 (ii) H3O+, 
Compound C in above reaction sequence is

O NOH
O
O
NH H2N
(A) (B) (C) (D) OH
11. What represents the best method for converting a carboxylic acid to an aldehyde?
(A) Convert the acid to an acid chloride, and react the acid chloride with water.
. (B) Reduce the acid with LiAlH4.
(C) Convert the acid to an acid chloride, and reduce the acid chloride with lithium aluminium
tri(t-butoxy) hydride.
(D) Convert the acid to an acid chloride, react the acid chloride with a Grignard reagent, and
reduce the product with LiAIH4
12. What is 'X' in the given reaction?

CH2OH
210°C
+ oxalic acid X
CH2OH (major product)
CH2 CH–OH CHO CH2OH
(A) CH2 (B) CH2 (C) CHO (D) CHO
13. For the given reaction :

1.NaNH2
HC CHBr A
2.Red hot iron tube, 873 K
(major product)
CH3
H3C CH3
CH=CH–NH2
(A) CH3CH2CH2NH2 (B) (C) (D)
CH3
CH3

87
GASEOUS STATE (PHYSICAL CHEMISTRY)
N2  3H2 
2NH3
1. 1 mole N2 and 4 moles H2 are taken in 15L flask at 27º C. After complete
conversion of N2 into NH3, 5L of H2O is added. Pressure set up in the flast is (assume water
dissolves NH3)
3  0.0821 300 2  0.0821 300
atm atm
(A) 15 (B) 10
1  0.0821  300 1  0.0821  300
atm atm
(C) 15 (D) 10
T
2. The reduced temperature =  = TC
P
The reduced pressure =  = PC
V
The reduced volume =  = VC
Hence, it can be said that the reduced equation of state may be given as
 1  8 n 1 8
  2   
(A)  3   (3 – 1) = 3    (B)  3   ( – 1) = 3 
 1 8  1 8
     
(C)  4   (3 – 1) = 3  (D)  3   (3 – 1) = 3 
3. For one mole of a van der Waals when b = 0 and T = 300 K, the PV vs. 1/V plot is shown
below. The value of the van der Waals constant a (atmlitre2 mole–2) is:
24.6
PV(litre-atm mol–1)
[Graph not to scale]

23.1
21.6
20.1
0 2.0 3.0
(mol littre–1)
(A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0

4. An open manometer attached to a flask containing ammonia gas have no difference in mercury
level initially as shown in diagram. After sparking into the flask, ammonia is partially
dissociated as 2NH3(g)  N2(g) + 3H2(g). Now it have difference of 18 cm in mercury level in
two columns, what is partial pressure of H2(g) at equilibrium?
p (atm)
(A) 9 cm of Hg (B)18 cm of Hg (C) 27 cm of Hg (D)None of these
5. The Van der Waal's constant 'b' of a gas is 4× 10–4 L/mol. How near can the centres of the to
molecules approach each other ? [ Use NA = 6 × 1023]
(A) 10–7 m (B) 10–10m (C) 5 × 10–11m (D) 5 × 10–9m
F2 (g) 2F(g)
6. At 800º C, the following equilibrium is established as
The composition of equilibrium may be determined by measuring the rate of effusion of the mixture
through a pin hole. It is found that 800°C and 1 atm mixture effuses 1.6 times as fast as SO2
effuses under the similar conditions. (At. wt. of F =19). What is the value of Kp (in atm) ?
(A) 0.315 (B) 0.685 (C) 0.46 (D) 1.49
7. For a given one mole of ideal gas ket at 6.5 atmin a container of capacity 2.463 L, the
Avogadro proportionality constant for the hypothesis is (see figure)
(A) 0.406 (B)2.46 (C) 22.4 (D) none of these
8. An open vessel at 27ºC is heated until 3/8th of the air in it has been expelled. Assuming that the
volume remains constant, calculate the temperature at which the vessel was heated
(A) 307ºC (B) 107ºC (C) 480ºC (D) 207ºC

10. Which of the following graph represent Boyles law?
(A) (B)
(C) log P (D) All of these
log V
11. An air column closed in a tube sealed at one end by a Hg column having height h. When the
tube is placed with open end down, the height of the air column is l1. If the tube is turned so
that its open end is at the top, the height of the air column is I2. What is the atmospheric
pressure (P0)
(I) (II)
h
1
1
h
h(11  12 ) h(11  12 )
P0  cm P0  cm
(A) (12  11 ) ofHg (B) (11  12 ) ofHg
h(11  12 )
P0  cm
(C) 76cm of Hg (D) (11  12 ) ofHg
12. Which one of the following graphs is not correct for ideal gas ?
d d
(I) T (II) T
d d
1/T (IV) p
(III)
d = density, p = pressure, T = Temperature

(A) III (B) I (C) IV (D) II

13. A mixture of one mole each of H2, He and O2 each are enclosed in a cylinder of volume, V at
temperature T. If the partial pressure of H2 is 2 atm, the total pressure of the gases in the
cylinder is
(A) 14 atm (B) 38 atm
(C) 22 atm (D) 6 atm
14. An element crystallises in a face-centred cubic (fcc) unit cell with cell edge a. The distance
between the centres of two nearest octahedral voids in the crystal lattice is
a
(A) 2 (B) a
a
2a
(C) (D) 2

88
AROMATIC COMPOUND (ORGANIC CHEMISTRY)
1. The product of the following reaction is

(i) HNO2, 0.5°C
NH2
(ii) dil. H2SO4, heat
(iii) HI,heat
NH2
OH OH I I
I I
I I OH
(A) (B) (C) (D)
I
2. In the following reaction sequence the major product B is
NH2
Ac 2O Br2
  A 
AcOH
B
CH3
NHCOCH3 NHCOCH3 NHCOCH3 NHCOCH3
Br COCH3 Br
(A) (B) (C) Br (D)

CH2Br CH3 CH3 CH3
3. Consider the following reaction

Anhyd.AlCl3
+ Cl  
(a)
Cl Cl
+ Cl2 Anhyd.AlCl3
  Cl Cl
(excess) dark
(b)
Cl Cl
AlCl3
+ CH2=CH–Cl   CH=CH2

(c)
Anhyd.AlCl3
+ CH2=CH–CH2Cl   CH2–CH=CH2
(d)
Which of these reactions are possible?
(A) (b), (c) and (d) (B) (b) and (d) (C) (a) and (d) (D) (a) and (b)

4. Amongst the compound given, the one that would form a brilliant colored dye on treatment with
NaNO2 in dil. HClfollowed by addition to an alkaline solution of
-naphthol is
NH2
NHCH3 N(CH3)2 CH2NH2
(A) (B) (C) (D) H3C
5. The major product obtained when Br2/Fe is treated with

O
HN
H3 C CH3
O O
HN HN
H3C CH3 H3C CH3
(A) (B)
Br Br
O O
HN HN
H3C CH3 H3C CH3
(C) (D)
Br Br
NH2
6. Major product C is :
CH3
OH OH OH OH
CHO CO2H
(A) CHO (B) (C) (D) CO2H

CH3 CH3 CH3 CH3
7. Which of the following compounds will be most easily attacked by an electrophile ?
NO2 CI NH2 CH3
(A) (B) (C) (D)

8. The major product U in the following reactions is
O H3C CH3
O
O
CH3 O H
(A) (B)
H
O O CH2
CH2 O H
O
(C) (D)
9. The product(s) of the following reaction sequence is(are)

NH2
i) Acetic anhydride / pyridine

ii ) KBrO3 / HBr
  
iii) H3O  , heat
iv ) NaNO 2 / HCl, 273 278 K
iv ) Cu / HBr
Br Br Br Br
Br Br Br
(A) Br (B) (C) (D)

Br
10. The major product of the following is

OH
(i) NaNO2, HCl, 0ºC
(ii) aq. NaOH
NH2
–
OH ONa+
(A) (B)
N=N N2Cl
N=N OH OH
(C) (D)
Cl

11. Which of the following reaction/s will not give p-aminoazobenzene?
NO2 NO2 NH2
(i) Sn/HCl (i) NaBH4 (i) HNO2
(ii) HNO (ii) NaOH (ii) Aniline, HCl
(A) (iii) Aniline
(B) (iii) Aniline
(C) NaOH
(A) A only (B) B only (C) C only (D) A and B
12. The major product of the following reaction is:

NO2
H2SO4
NO2 NO2
NO2 NO2
(A) (B) (C) (D)
13. The correct sequence of reagents used in the preparation of 4-bromo-2-nitroethyl benzene
from benzene is :
(A) HNO3/H2SO4, Br2/AlCl3, CH3COCl/AlCl3, Zn-Hg/HCl
(B) Br2/AlBr3, CH3COCl/AlCl3, HNO3/H2SO4, Zn/HCl
(C) CH3COCl/AlCl3, Br2/AlBr3, HNO3/H2SO4, Zn/HCl
(D) CH3COCl/AlCl3, Zn-Hg/HCl, Br2/AlBr3, HNO3/H2SO4

89
THERMODYNAMICS (PHYSICAL CHEMISTRY)
1. The enthalpy of neutralisation of NH4OH and CH3COOH is –10.5 kcal mol–1 andenthalpy of
neutralisation of CH3COOH with strong base is –12.5 kcal mol–1.The enthalpy of ionisation of
NH4OH will be
(A) 4.0 kcal mol–1 (B) 3.0 kcal mol–1 (C) 2.0 kcal mol–1 (D) 3.2 kcal mol–1
2. Hydrogen peroxide (H2O2) decomposes according to the equation

2H2 O2 2H2 O I  O2  g
From the following data at 250 C Calculate the value of Kp at 400 K for the above reaction,
H0  196.0KJ s0  125.65
J/K
0.15
[Given : 10 = 1.41]
32
(A) 0.14  0 (B) 0.14  10-32 (C) 0.14  103 (D) 1.3  1015
3. What is the true regarding complete combustion of gaseous isobutane-

(A) H = E (B) H > E (C) H = E = 0 (D) H < E
4. Two moles of an ideal gas is expanded isothermally and reversibly from 1 litre to 10 litre at 300
K. The enthalpy change (in kJ) for the process is
(A) 11.4 kJ (B) – 11.4 kJ (C) 0 kJ (D) 4.8 kJ
5. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is
shown in the figure. Which of the following statement is incorrect?
(P1, V1, T1)
P
(P2, V2, T2)
adiabatic
(P3, V3, T3)
(A) T3> T1 (B) T2 = T2

(C) Uisothermal>Uadiabatic (D) W isothermal>W adiabatic

6. A sample of gas is compressed by an average pressure of 0.50 atmosphere so as to decrease
its volume from 400 cm3 to 200cn3. During the process 8.00 J of heat flows out to
surroundings. The change in internal energy of the system is
(A) +2.13 J (B) +10.13 J (C) –2.13 J (D) –10.13 J
7. When the following reaction was carried out in a bomb calorimeter, U is found to be
–740.0 kJ/mol of NH2 CN(s) (s) at 300k.
3
NH2CN(s) + 2 CO2(g) N2(g)+ CO2(g) + H2O(A) Calculate AH300K for the reaction.
(A) –738.75 kJ (B) +738.75 kJ (C) –824.75 kJ (D) –919.57 kJ
8. The entropy change when an ideal gas under atmospheric condition at room temperature is
allowed to expand from 0.5 L to 1.0 L and also is simultaneously heated to 373 K will be
(Given: Cv, m = 12.50 J K–1mol–1 and log 1.25 = 0.1)
(A) 0.18 J K–1 (B) 0.36 JK–1 (C) 0.90 JK–1 (D) 0.72 JK–1
9. A fixed mass m of a gas is subjected to transformation of states from K to L to M to N and back

to K as shown in the Figure.
K L
N M
The succeeding operation that enable this tansformation of state are
(A) heating, cooling, heating, cooling (B) cooling, heating, cooling, heating
(C) heating, cooling, cooling, heating (D)cooling, cooling, heating eating,
10. Three samples of 100 g of water (samples I, Il and Ill), initially kept at 1 atm pressure and
298 K were given 1he following treatments.
Sample I was heated to 320 K and cooled to 298 K
Sample lI was heated to 300 K, cooled to 273 K and heated to 298 K
Sample Ill was heated to 373 K and cooled to 298 K
At the end of these processes, the internal energy of
(A) III is the highest
(B) II is the highest
(C) I and III are the same, II is lower than that of I and II
(D) I, II and III are the same

11. For silver, Cp(J K–1 mol–1) = 23 + 0.01 T. If the temperature (T) of 3 moles of silver is raised
from 300 K to 1000 K at 1 atm pressure, the value of H will be close to
(A) 62 kJ (B) 16 kJ (C) 21 kJ (D) 13 kJ
12. A process will be spontaneous at all temperature if

(A) H > 0 and S < 0 (B) H < 0 and S > 0
(C) H < 0 and S < 0 (D) H > 0 and S > 0
13. Consider the reversible isothermal expansion of an ideal gas in a closed system at two
different temperatures T1 and T2 (T1 < T2). The correct graphical depiction of the dependence
of work done (W) on the final volume (V) is
|W| T2 |W| T2 |W| T2 |W| T2
T1 T1
T1 T1
(A) (B) (C) (D)

O ln V O ln V O ln V O ln V

90
BIOMOLECULE (ORGANIC CHEMISTRY)
1. Consider the following reactions :

Dry HCl x eq. of
Glu cos e  ROH  Acetal   Acetyl derivative
(CH 3CO ) 2 O
(i)
Ni/H 2 y eq. of
Glu cos e   A    Acetyl derivative
(CH 3 CO ) 2 O
(ii)
z eq. of
Glu cos e   Acetyl derivative
(CH 3CO ) 2 O
(iii)
x’, y’ and z’ in these reactions are respectively
(A) 5, 4 and 5 (B) 4, 5 and 5 (C) 5, 6 and 5 (D) 4, 6 and 5
2. Which of the following statements is correct ?

(A) Gluconic acid is obtained by oxidation of glucose with HNO3
(B) Gluconic acid is a dicarboxylic acid
(C) Gluconic acid can form (acetal/hemiacetal) structure
(D) Gluconic acid is a partial oxidation product of glucose
3. Which of the following statement is not true for glucose ?

(A) The pentaacetate of glucose does not react with hydroxylamine to give oxime
(B) Glucose exists in two crystalline forms  and 
(C) Glucose gives Schiff’s test for aldehyde
(D) Glucose reacts with hydroxylamine to form oxime
4. Glucose on prolonged heating with HI gives

(A) n-hexane (B) 1-hexene (C) Hexanoic acid (D) 6-iodohexanal
5. The change in the optical rotation of freshly prepared solution of glucose is known as
(A) tautomerism (B) racemization (C) specific rotation (D) mutarotation

6. The term anomers of glucose refers to
(A) isomers of glucose that differ in configurations at carbons one and four (C-1 and C-4)
(B) a mixture of (D)-glucose and (L)-glucose
(C) enantiomers of glucose
(D) isomers of glucose that differ in configuration at carbon one (C-1)
7. -D-(+)-glucose and -D-(+)-glucose are

(A) anomers (B) epimers (C) enantiomers (D) geometrical isomers
8. Which one of the following statements is not true ?

(A) Lactose contains -glycosidic linkage between C1of galactose and C4 of glucose
(B) Lactose is a reducing sugar and it gives Fehling’s test.
(C) Lactose (C11H22O11) is a disaccharide and it contains 8 hydroxyl groups.
(D) On acid hydrolysis, lactose gives one molecule of D(+) - glucose and one molecule of D (+)
- galactose
9. Two monomers in maltose are

(A) -D-glucose and -D-glucose
(B) -D-glucose and -D-galactose
(C) -D-glucose and -D-glucose
(D) -D-glucose and -D-fructose
10. Which of the given statements is incorrect about glycogen ?

(A) It is straight chain polymer similar to amylose
(B) Only -linkage are present in the molecule
(C) It is present in animal cells
(D) It is present in some yeast and fungi
11. Indicate whether each is a reducing sugar or not

CH2OH HO
O CH2OH
HO O
OCH2CH2CH3 HO
OH OH
(A) (B) OCH3
HO
HO HOCH2
CH2OH O OCH2CH3
O
OH
HO CH2OH
(C) (D)
OH OH OH
12. Which one given below is a non-reducing sugar?

(A) Lactose (B) Glucose (C) Sucrose (D) Maltose

13. Which of the glycosidic linkage between galactose and glucose is present in lactose?
(A) C-1 of galactose and C-4 of glucose
(B) C-1 of glucose and C-6 of galactose
(C) C-1 of glucose and C-4 of galactose
(D) C-1 of galactose and C-6 of glucose
14. Which of the following is correct structure of -anomer of maltose?

CH2OH CH2OH CH2OH CH2OH
O O O O
H H H H OH H H H H OH
H H
(A) HO H H O OH H H (B) HO OH H O OH H H
OH OH H OH H OH H OH
CH2OH CH2OH CH2OH CH2OH
O O O O
H H H H H H H H H H
H H
(C) HO H H O H H OH (D) HO OH H O OH H OH
HO OH HO OH H OH H OH
15. Which of the following is correct structure of tyrosin ?

COOH
H2N H COOH
OH
H2N H
(A) OH (B)
COOH
H2N H COOH
OH
H2N H
(C) (D) OH

91
ELECTROCHEMISTRY (PHYSICAL CHEMISTRY)
1. Consider the following cell reaction

2Fe  s   O 2  g   4H   aq   2Fe2   aq   2H 2 O  l 
E ºcell  Fe 2   10 3 M,
If Ecell = at 25º C and = 0.01 atm and pH = x
value of x is
(A) 1 (B) 2 (C) 3 (D) 4
2+
2. The standard reduction potential for Cu /Cu is +0.34 V. Calculate the reduction potential at pH
–19
sp 2
= 14 for the above couple. (k of Cu(OH) = 1 × 10 )
(A) –0.22 V (B) +0.22 V (C) –0.44 V (D) +0.44 V
3. The equivalent conductivity of 0.1 M weak acid is 100 times lesser than that at infinite dilution.
The degree of dissociation of weak electrolyte at 0.1 M is-
(A) 100 (B) 10 (C) 0.01 (D) 0.001
4. For sparingly soluble salt [M(NH3)4Br2]H2PO2, what will be the solubility product constant in
2
 mol 
 
 litre  ?
 0M( NH  0H2 PO2
3 )4 Br2 2 –1
[Given = 100 Sm mol , = 50 Sm2mol–1]
Take specific resistance as 200 cm
(A) 1.11 × 10–11 (B)1.11 × 10–3 (C) 3.33 × 10–6 (D) None of these
5. Calculate G° for the following cell reaction Zn(s) + Ag2O(s) + H2O(l)  Zn2 (aq) + 2Ag(s) +
E 0Ag / Ag  0.80 V E0Zn2 / Zn  0.76 V
–
2OH (aq) and ,F = 96500. (Given :Ksp of AgOH = 2 × 10–8)
(A)– 305 kJ/mol (B) 212 kJ/mol (C) 305 kJ/mol (D) 301 kJ/mol

6. The resistance of 0.01 N solution of an electrolyte was found to be 220 ohm at 298 K using a
conductivity cell with a cell constant of 0.88 cm–1. The value of equivalent conductivity of
solution is .
(A) 400 mho cm2 eq–1 (B) 295 mho cm2 eq–1
(C) 419 mho cm2 eq–1 (D) 425 mho cm2 eq–1
7. In a Cu-voltmeter, mass deposited in 30 s in ‘m’ g. If the time-current graph is shown in the

following figure :
200 mA
current
100 mA
10s 20s 30s

time
What is the electrochemical equivalent of Cu?
m m
(A) 2 (B) 3
m m
(C) 4 (D) 63.5
8. A current of 1.93 ampere is passed through 200 mL of 0.5 M Zinc sulphate (aq.) solution for 50
 Zn2 
min. with a current efficiency of 80%. If volume of solution remain constant, then after
deposition of Zn2+.
(A) 0.38 M (B) 0.26 M
(C) 0.35 M (D) 0.076 M
EoAl3 / Al
–35
9. Ksp of Al(OH)3 = 10 and = – 1.66 V
3+
Reduction potential of Al /Al couple at pH = 12 and 298 K is
(A) 1.07 V (B) 2.25 V
(C) –1.07 V (D) –2.25 V
[Sn2 ]
2
|| Pb2 (a q, 1M | Pb(s)
10. For a electrochemical cell, SN(s)|SN2+ (aq, 1M). the ratio [Pb ] when the cell
2.303
E0Sn2 |Sn  0.14V, EPb
0
2
|Pb
 0.13V,  0.06
attains equilibrium is (Given F ).
(A) 4.3 (B)1
(C) –2.15 (D)2.14

m C
11. Which one of the following graphs between molar conductivity ( ) versus is correct?
NaCl
KCl
m m NaCl
(A) (B) KCl
C C
KCl
m KCl m
(C) NaCl (D)
NaCl
C C
12. An example of a disproportionation reaction is

2MnO4
(A) + 10 I– + 16H+2Mn2+ + 5I2 + 8H2O
(B) 2NaBr + Cl2  2NaCl + Br2
(C) 2KMnO4 K2MnO4 + MnO2 + O2
(D) 2CuBr CuBr2 + Cu
13. The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The
amount of PbSO4 electrolysed in g during the process is (Molar mass of PbSO4 = 303 g mol–1)
(A) 11.4 (B) 7.6
(C) 15.2 (D) 22.8

92
POLYMER (ORGANIC CHEMISTRY)
1. Adipic acid reacts with hexamethylene diamine to form

(A) Bakelite (B) Nylon-6,6
(C) Terylene (D) Nylon-6, 10
2. Ethylene glycol reacts with dimethyl terephthalate to form

(A) Nylon-6, 6 (B) Teflon
(C) Dacron (D) Orlon
3. Neoprene is a polymer of the following monomer:

(A) Chloroprene (B) Isoprene
(C) Isobutene (D) Isopentene
4. Which of the following is an example of a condensation polymer?

(A) Nylon-6, 6 (B) Teflon
(C) Polypropylene (D) Orlon
5. Which of the following is a thermosetting polymer?

(A) Bakelite (B) Nylon-6, 6
(C) Polyethylene (D) Teflon
6. Choose copolymer
(A) Buna–S and Buna–N (B) polythene
(C) polypropene (D) None
7. Which of the following statements about low density polythene is FALSE ?

(A) Its synthesis requires high pressure.
(B) It is a poor conductor of electricity.
(C) Its synthesis requires dioxygen or a peroxide initiator as a catalyst.
(D) It is used in the manufacture of buckets, dust-bins etc.
8. Nylon-66 is made by using

(A) Phenol (B) Benzaldehyde
(C) Adipic acid (D) Succinic acid

9. Polymer which has amide linkage is
(A) Nylon-66 (B) Terylene
(C) Teflon (D) Bakelite
10. Terylene is a condensation polymer of ethylene glycol and

(A) Benzoic acid (B) Phthalic acid
(C) Salicylic acid (D) Terephthalic acid
11. In polymer Buna-S: ‘S’ stands for :

(A) Sulphonation (B) Strength
(C) Sulphur (D) Styrene
12. Which statement is correct ?

(A) Synthesis of Buna-S needs nascent oxygen.
(B) Neoprene is an addition copolymer used in plastic bucket manufacturing.
(C) Buna-S is a synthetic and linear thermosetting polymer.
(D) Buna-N is a natural polymer.
13. The structure of Neoprene is -

—CH2CH=CH—CH2–CH2–CH— —CH2–CH—
(A) (B)
CN n CN n
Cl
—CH2–C=CH–CH2— —NH N NHCN2—
n
(C) (D)
N N n
NH

93
SOLID STATE (PHYSICAL CHEMISTRY)
1. One mole crystal of a metal halide of the type MX with molecular weight 119 g having face
centered cubic structure with unit cell length 6.58 Å was recrystallized. The density of the
recrystallized crystal was found to be 2.44 gcm–3. The type of defect introduced during the
recrystalization may be
(A) Additional M+ and X– ions at interstitial sites

(B) Schottky defect
(C) F-centre
(D) Frenkel defect
2. The arrangement of X- ions around A+ ion in solid AX is given in the figure (not drawn to scale).
If the radius of X- is 250 pm, the radius of A+ is
x–
+ +
OHA A
(A) 104 PM (B) 125 (C)183 PM (D) 57PM
3. The shortest distance between two Na+ ions in rock-salt arrangement having edge length equal
a 2
to picometers is-
a
2a 2
(A) 2a (B) (C) 2 (D) a
4. The crystal system of a compound with unit cell dimensions a = 0.387, b = 0.387 and
c = 0.504 nm and  = = 90° and  = 120° is
(A) Hexagonal (B) Cubic
(C) Rhombohedral (D)Orthorhombic

5. A solid is formed and it has three types of atoms X, Y and Z. X forms a fcc lattice with Y atoms
occupying all tetrahedral voids and Z atoms occupying half of octahedral voids.
The formula of solid is
(A) X4YZ2 (B) X4Y2Z (C)XY2Z4 (D) X2Y4Z
6. CsBr has bcc structure with edge length 4.3 Å. The shortest inter ionic distance in between Cs+
and Br– is -
(A) 4.3 Å (B) 7.44 Å (C) 1.86 Å (D) 3.72 Å
7. If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction
of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied
bymagnesium ions, m and n, respectively, are
1 1 1 1 1 1 1
, 1, , ,
(A) 8
2 (B) 4 (C) 2
2 (D) 8
4
8. The density of KBr is 2.75 g cm–3, length of the unit cell is 654 pm. K = 39, Br = 80, then what
can be true about the predicted nature of the solid ? (Given: NA = 6.023 × 1023)
(A)Solid has face centred cubic system with co-ordination number = 6
(B)Solid has simple cubic system with co-ordination number = 8
(C)Solid has face centred cubic system with co-ordination number =12
(D)None of the above
9. A crystalline solid of a pure substance has a face-centred cubic structure with a cell edge of
400 pm. If the density of the substance in the crystal is 8 g cm–3 then the number of atoms
present in 256 g of the crystal is N x 1024. The value of N is
10. CsCl crystallises in body centred cubic lattice. If ‘a’ is its edge length then which of the
following expressions is correct?
3a
rCs  rCl  3a rCs  rCl 
(A) (B) 2
3
rCs  rCl  a rCs  rCl   3a
(C) 2 (D)
11. In a binary compound, atoms of element A form a hcp structure and those of element M occupy
2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound is :
(A) M2A3 (B) M4A3 (C) M4A (D) MA3
12. A hard substance melts at high temperature and is an insulator in both solid and in molten
state. This solid is most likely to be a / an :
(A) Ionic acid (B) Molecular solid (C) Metallic solid (D) Covalent solid

94
PRACTICAL ORGANIC CHEMISTRY (ORGANIC CHEMISTRY)
1. In a Lassaignes’s test for sulphur in the organic compound with sodium nitroprusside solution
the purple colour formed is due to-
(A) Na4 [Fe(CN)5 NOS] (B) Na3 [Fe(CN)5 S]
(C) Na2 [Fe(CN)5 NOS] (D) Na3 [Fe(CN)6 ]
2. An organic compound (A) (molecular formula C6H12O2) was hydrolysed with dil. H2SO4 to give
a carboxylic acid (B) and an alcohol (C). ‘C’ gives white turbidity immediately when treated with
anhydrous ZnCl2 and conc. HCl. The organic compound (A) is
(A) (B)
(C) (D)
3. An organic compound neither reacts with neutral ferric chloride solution nor with Fehling
solution. It however, reacts with Grignard reagent and gives positive iodoform test. The
compound is
(A) (B)
(C) (D)

4. Two compounds A and B with same molecular formula (C3H6O) undergo Grignard’s reaction
with methylmagnesium bromide to give products C and D. Products C and D show following
chemical tests.
Test C D
Caric ammonium nitrate test Positive Positive
Lucas test Turbidity obtained Turbidity obtained
after five minutes immediately
Iodoform test Positive Negative
C and D respectively are
(A)
(B)
(C)
(D)
5. Compound A(C9H10O) shows positive iodoform test. Oxidation of A with KMnO4/KOH gives
acid B(C8H6O4). Anhydride of B is used for the preparation of phenolphthalein. Compound A is
(A) (B) (C) (D)
6. Consider the following reactions,
A is
(A) CHCH (B) CH3CCCH3 (C) CH3—CCH (D) CH2CH2

The compound [P] is
(A) (B) (C) (D)

Ozonolysis
(A)  (B)  (C)
(C 7H14 )
(A) is
(A) (B)
(C) (D)
9. A flask contains a mixture of isohexane and 3-methylpentane. One of the liquids boils at 63ºC
while the other boils at 60ºC. What is the best way to separate the two liquids and which one
will be distilled out first ?
(A) Fractional distillation 3-methyllpentane
(B) Fractional distillation, isohexane
(C) Simple distillation, 3-methylpentane
(D) Simple distillation, isohexane
10. In chromatography, which of the following statements is incorrect for Rf ?

(A) Rf value depends on the type of chromatography
(B) Higher Rf value means higher adsorption
(C) Rf value is dependent on the mobile phase
(D) The value of Rf can not be more than one

11. Which of the following compound gives pink colour on reaction with phthalic anhydride in conc.
H2SO4 followed by treatment with NaOH ?
CH3 HO CH3
(A) OH (B) HO CH3

H3C CH3 CH3
(C) HO OH (D) HO
12. The diazonium salt of which of the following compounds will form a coloured dye on reaction
with b-Naphthol in NaOH ?
CH3
CH2NH2 N–CH3 NH2 NH–CH3
(A) (B) (C) (D)
Hydrolysis
A    B
( C 4H8Cl2 ) 373 K ( C 4H8O )
13.
B reacts with Hydroxyl amine but does not give Tollen's test. Identify A and B
(A) 1,1-Dichlorobutane and 2-Butanone (B) 2,2-Dichlorobutane and Butanal
(C) 1,1-Dichlorobutane and Butanal (D) 2,2-Dichlorobutane and 2-butan-one

95
SURFACE CHEMISTRY (PHYSICAL CHEMISTRY)
1. 10 mL of 1 mM surfactant solution forms a monolayer covering 0. 24 cm2 on a polar substrate.

If the polar head is approximated as cube, what is its edge length?
(A) 2.0 pm (B) 2.0 nm (C) 1.0 pm (D) 0.1 nm
2. The coagulation values in millimoles per litre of the electrolytes used for coagulation of As2S2
are given below.
I. NaCl = 52 II. BaCl2 = 0.69 III. MgSO4 = 0.22]
The correct order of their coagulation is:
(A) III > I > II (B) I > II > III (C) II > I > III (D) III > II > I
3. Which of the following statements about physical adsorption is not correct?

(A) It is usually monolayer
(B) It is reversible in nature
(C) It involves van der Waals interactions between adsorbent and adsorbate
(D) It involves small value of adsorption
T1
IV T2
4. The plots of the extent of adsorption (x/m) Vs pressure at different X/m
T3
temperature are as follows;
T4
The correct order of increasing temp for curves I, II, III, IV are : PA(cm of hg)
(A) T1> T2> T3> T4 (B) T4> T3> T2> T1 (C) T3> T2> T1> T4 (D) can't be predicted
5. Among the following, the surface that will form micelles in aqueous solution at the lowest molar
concentration at ambient condition is:
(A) CH3(CH2)15 N+(CH3)3 Br– (B) CH3(CH3)11 OSO3– Na+
(C) CH3 (CH2)= COO– Na+ (D)CH3(CH2) 11N+(CH3)3Br–
6. Which of the following statements is correct for a lyophilic sol?

(A) It is not easily solvated
(B) The coagulation of this sol is irreversidble in nature
(C) It is unstable
(D) It is quite stable in a solvent

7. For coagulation of Arsenioussulphide sol, which one of the following salt solution will be most
effective?
(A) AICI3 (B) NaCI (C) BaCI2 (D) Na3P04
8. As2S3 and TiO2sol example of

(A) Negativity charge sols
(B) Positively charged sols
(C) Positively and negatively charged sols respectively
(D) Negatively and positively charged sols respectively.
9. In Freundlich adsorption isotherm, slope of AB line is :

B
N
A
log P
(A) log n with (n > 1) (B) n with (n, 0.1 to 0.5)

1 1 1 
log with   0 to 1
(C) n with (n < 1) (D) n n 
10. Most suitable salt which can be used for efficient clotting of blood will be :-
(A) NaHCO3 (B) FeSO4 (C) Mg(HCO3)2 (D) FeCl3
x
 
11. In Freundlich adsorption isotherm at moderate pressure, the extent of adsorption  m  directly
proportional to Px. The value of x is
1
(A) zero (B) n (C) 1 (D) 
12. Which one of the following statements is FALSE for hydrophilic sols ?
(A) Their viscosity is of the order of that of H2O.
(B) The sols cannot be easily coagulated.
(C) They do not require electrolytes for stability.
(D) These sols are reversible in nature.
13. The nature of charge on resulting colloidal particles when FeCl3 is added to excess of hot
water is :
(A) Positive (B) Sometimes positive and sometimes negative
(C) Neutral (D) Negative

96
CHEMISTRY IN EVERYDAY LIFE (ORGANIC CHEMISTRY)
1. A substance which can act both as an analgesic and antipyretic is

(A) Quinine (B) Aspirin (C) Penicillin (D) Insulin.
2. Treatment of acidity is done by

(A) Antacids (B) Antihistaines (C) Analgestics (D) None
3. The drug given during hypertension is

(A) Streptomycin (B) Chloroxylenol (C) Equanil (D) Aspirin
4. Tranquilizer are used for treatment of

(i) Pain (ii) Stress
(iii) Mild or mental diseases (iv) Anxiety
(v) use in sleeping pills
(A) (i), (ii), (iii), (v) only (B) (i), (ii), (iv), (v) only
(C) (i), (ii), (v) only (D) (ii), (iii), (iv), (v) only
5. Drug which helps to reduce anxiety and brings calmness is

(A) Tranquilizer (B) Diuretic (C) Analgesic (D) Antihistamine
6. Tranquilizers are/is
(A) chlordiazepoxide (B) meprobamate (C) equanil (D) All of these
6. Streptomycin is an example of
(A) Antibiotic (B) Analgesic (C) Antipyretic (D) Anaesthetic.
7. Chloroxylenol is an important component of

(A) Soap (B) Antibiotics (C) Dettol (D) Pain killing ointments

8. Those Antibiotics which kill or inhibit a wide range of gram-positive and gram-negative bacteria
are said to
(A) Narrow spectrum antibiotics (B) Broad spectrum antibiotics
(C) Both (A) and (B) (D) None
9. Which are synthesis of penicillins :

(A) Ampicillin (B) Amoxycillin (C) Both (A) and (B) (D) None
10. Vancomycin and ofloxacin are

(A) Limited-spectrum antibiotics (B) Narrow-spectrum antibiotics
(C) Broad-spectrum antibiotics (D) None
11. Match List-I and List-II.

List-I List-II
(a) Valium (i) Antifertility drug
(b) Morphine (ii) Pernicious anaemia
(c) Norethindrone (iii) Analgesic
(d) Vitamin B12 (iv) Tranquilizer
(1 ) (a)–(iv), (b)–(iii), (c)–(ii), (d)–(i) (B) (a)–(iv), (b)–(iii), (c)–(i), (d)–(ii)
(C) (a)–(ii), (b)–(iv), (c)–(iii), (d)–(i) (D) (a)–(i), (b)–(iii), (c)–(iv), (d)–(ii)
12. The functions of antihistamine are :

(A) Antiallergic and Analgesic (B) Antacid and antiallergic
(C) Analgesic and antacid (D) Antiallergic and antidepressant
13. With respect to drug-enzyme interaction, identify the wrong statement :

(A) Non-Competitive inhibitor binds to the allosteric site
(B) Allosteric inhibitor changes the enzyme’s active site
(C) Allosteric inhibitor competes with the enzyme’s active site
(D) Competitive inhibitor binds to the enzyme’s active site

SOLUTION & ANSWER KEY
PHYSICAL CHEMISTRY
MOLE CONCEPT
1. (A)
1.22
Mole of BaSO4 
Sol. 233.3
1.22 1
Moles of M2  SO4 3  
233.3 3
 1.743  103
Wt. of M2  SO 4 3  0.596
1.743  103 (2M  96  3)

= 0.596
= M = 26.9
2. (C)
Sol. CaCO3(s)  CaO(s) + CO2(g)
105  95
 56 gm
mass = 100  100
= 53.2 kg
3. (C)
Sol. CaCO3  CaO + CO2
Let the % purity is x
500  x
Mol : 100  100 mol
500  x
 56  70
100  100
X = 25
% Impurities = 100 – 25 = 75%
4. (B)
Sol. Let the number of moles of NaHCO3 is x.
x x
 44   18
Wt. loss = 2 2
x
 62
2  100  36.9%
% Weight loss = x  84
5. (C)
PV 1 492
O2    20
Sol. Moles of NaClO3 = moles of O2, moles of RT 0.082  300 moles
As molecular of NaClO3 = 106.5
NaClO3 = 20 × 106.5 = 2130 g

6. (C)
Sol. 2SO2 (g) + O2 (g)  2SO3 (g)
initial volume: 5 3 0
volumeafterrxn: 0 (3 – 2.5) 5
= 0.5
Total volume of reaction mixture
= 0.5 + 5 = 5.5 L
7. (C)
100(0.3  0.125)60
Sol. Mass adsorbed =  1.05g
1000
(0.3  0.125)6
Mass adsorbed per gram of charcoal =  1.3125
0.8
8. (B)
nCH4 mCH4 (MC2H6 )
Sol.  3:2
nC2H6 (mCH4 )(MCH4 )
9. (C)
4NH3 (g) 5O 2 (g)  4NO(g) 6H2 O(g) (l)
Sol. 4 moles 5 moles 4 moles 46moles
 4 moles of NH3 5 moles of O2

5
1 moles of NH3  4 moles of O2 1.25 moles of O2
Thus, all volume of oxygen will be consumed.
10. (C)
Ti  O2 
 Ti1.44O
Sol. (1.44 g) ( x )g
Apply POAC to Ti
 1.44g   xg 
 48   1   (1.44  48)  16  1.44
   
48  1.44  16
x
48
16
1.44   1.44  0.33  1.77 g
= 48
11. (B)
Sol. Given,
Average molar mass of chlorine is 35.5 g mol–1.
Naturally occurring chorine are
35 37
Cl Cl
Mass ratio x 1–x

Total molar ratio = x + 1 – x = 1
Mass average = 35 × x + 37 × (1 – x)
35.5 = 35x + 37 – 37x
1.5 3
2x = 37 – 35.5; x = 2 = 0.75 = 4
35 3
Cl
For , x= 4
37 3
Cl
For , 1– 4
35 37
Cl Cl
;
3  3 3 1
 1– 
4 ;  4  4 : 4
On simplify this ratio, we get 3 : 1
12. (A)
NH 2CONH2
Sol. (M=60) + 2 NaOH  2 NH3 + Na2CO3
No. of moles of urea = Given mass / molar mass
0.6
= 60 = 0.1 mol NH2CONH2
 It gives 0.02 mol NH3 as per the equation.
To neutralize it, 0.02 equivalents of HCl needed.
As we know, no. of equivalents of HCl = Normally × Volume
13. (A)
The oxidation of a mixture of one mole of each of
FeC2O4, Fe2(C2O4)3FeSO4 and
Fe2(SO4)3 in acidic medium with KMnO4 is as follows
FeC2O4 + KMnO4 → Fe3++CO2 + Mn2+ …… (i)
3+ 2+
Fe2(C2O4)3 + KMnO4 → Fe +CO2 + Mn …… (ii)
3+ 2- 2+
FeSO4+ KMnO4 → Fe + SO 4+ Mn …… (iii)
Change in oxidation number of Mn is 5. Change in oxidation number of Fe in (i), (ii) and (iii) are
+3,+6,+1, respectively
neqKMnO4 = neq[FeC2O4 + Fe2(C2O4)3 + FeSO4]
n×5 = 1×3+1×6+1×1
n=2

ATOMIC STRUCTURE
1. (A) 2. (B) 3. (C) 4. (B)

5. (C) 6. (D) 7. (B) 8. (A)
9. (B) 10. (A)
11. (C)
Sol. According to Bohr’s theory :
z 2 eV z2
2
 2
(A) KE = 13.6 n atom  KE n
z

(B) speed of e– n
v n z

v
e 
(C) Frequency of revolution of 2r
z2
frequency 
 n3 
kq1q2 kze2  n2
F  2 r
(D) r2 r  z
z
F 2
  n2 
 
 z 
z3
F
 n4 
12. (C)
Sol. Number of radial nodes = n – – 1
=3–0–1=2
Therefore corresponding graph is (D)
Hence answer is (3)
13. C
Sol. Quantum nature of atoms are associated with following phenomena or process :
(i) Absorption spectrum
(ii) Emission spectrum
(iii) Black body radiation
(iv) Photo-electricity
Internal energy (U) of particles like atoms depends upon the thermodynamics variables (p, V,
T) of the system. Thus, U = f(p, T)
or U = f1(TV)
or U = f2(p, V)
So, quantum nature of atom is not associated with its internal energy.
Graph (c) is not a direct manifestation of the quantum nature of atoms.

REDOX REACTION
1. (A)
3 2
Sol. (1) CH – CH – Cl
R.S. = 0
2
(2) CH = CH – Cl
R.S = 2
6 5
(3) C H – Cl
R.S. = 4
1
R.S . 
Bond length of sin gle bond
2. (D)
Sol. [H+] = 10–3 M [pH = 3 = –log[H+] = 10–3 moles per litre
[Ca2+] = 5 × 10–4 moles of per litre = 5 × 10–1 moles of Ca2+ per 103 L = 5 × 10–1 × 40 g Ca2+ per
106 g of H2O
Ca2+ = 20 ppm = (H).
3. (D)
Sol. Let the atomic weight of X = y
No. of equivalents of KOH = No. of equivalents of H2XO4
0.12544
 0.12544
i.e.= 66  y 
2
 y = 32
4. (A)
Sol. Fe2(C2O4)3  2Fe3+ + 6CO2 + 6e– (n Factor = 6)
Fe(C2O4)  Fe3+ + 2CO2 + 3e– (n Factor = 3)
Meqs of [Fe2(C2O4)3 + Fe(C2O4)] = 0.5 × 6 + 0.5 × 3
= 4.5 Eqs.
= 4.5 Eqs. of KMnO4
4.5
= 5 = 0.9 moles of KMnO4
5. (A)
Sol. It is a fact that a redox reaction always involves change in oxidation number.
6. (A)
2 6
S 2 O 32  MnO4 S O24
Sol. + + H2O  MnO2(s) + + OH–
'n' factor of Na2S2O3 = 8
'n' factor of KMnO4 = 3
0.158
 8  1000
m.eq of Na2S2O3 = m.eq of KMnO4 158 = 0.1 ×V × 3
V = 26.7 mL

7. (A)
Sol. If x mL is with phenolphthalein the rxn occurring is
Na2CO3 + HCl  NaHCO3 + NaCl
Sol the volume of HCI for complete reaction of Na2CO3 would be double of 'x' because the
reaction will be
Na2CO3 + 2HCl  Na2CO3 + 2NaCl
So, 2x
8. (B)
Sol. (i) The half reaction for oxidation is, H2C2O4 2CO2
Balancing carbon atoms on both sides, H2C2O4 2CO2
Balancing hydrogen atoms on both sides, H2C2O4 2CO2 + 2H+
Balancing the charge on both sides, H2C2O4 2CO2 + 2H+ + 2e– ....(i)
(ii) The half reaction for reduction is H2O2 H2O
Balancing oxygen atoms on both sides, H2O2 2H2O
Balancing hydrogen atoms, H2O2 + 2H+ 2H2O
Balancing eh charge, H2O2 + 2H+ + e– 2H2O .......(ii)
Now, adding both equation,
H2C2O4 + H2O2 2CO2 + 2H2O
This is balanced equation so x, y, z are 1, 2, 2 respectively.
9. (D)
Sol. H2O2 acts as an oxidizing agent in both acidic and alkaline medium.
10. (A)
H2O 2  2l  2H  2
0.5M (from CH3 COOH)
Sol. Bleach
25 ml
30 ml 4N(10 ml ) ……(i)
+ 2H2O
 2  2Na2S 2O3  Na2S 4O6  2Nal
0.25 N( 48 ml) …….(ii)
1
2 
m. mol of 2 (m. mole of Na2S2O3)
1
 (0.25  48)  6 m.mol
= 2
Using equation (i)
1m. mol of 2 1m.Mol of H2O2
m. mol of H2O2 = 6 m. mol
6
 0.24M
Molarity of H2O2 = 25
11. (C)

Sol. (A) HOCl + H2O2 H3O+ + Cl– + O2
In this equation, H2O2 is reducing chlorine from +1 to –1.

(B) I2 + H2O2 + 2OH– 2I– + 2H2O + O2
In this equation, H2O2 is reducing iodine from 0 to –1.

Sol. In (A) reduction of HOCl occurs so it will be a oxidising agent hence H2O2 will be a reducing
agent.
In(B) reduction of I2 occurs so it will be a oxidising agent and H2O2 will be a reducing agent.
12. (B)
Sol. I– is oxidised to I2 by H2O2. Hence answer is (2)
13. (C)
Sol. NaCl is a strong electrolyte, whereas BaSO4 is a sparingly soluble (weaker) electrolyte. So,
even in saturated solution, NaCl will almost remain in dissociated form to give free Na+ and Cl–.
SO24
2+
But availability of Ba and in water will be very poor. But degree of dissociation of BaSO4
will increase with a temperature to give more ions.
SO24
BaSO4(s) Ba2+(aq) + (aq)
Again, with increase in temperature ionic mobility alos increases. So options(a), (b) and (d) are
true but (c) is false.
Solubility of NaCl in water remains almost constant with increase in temperature. So, option ©
is false.
Solubility
NaCl
Temperature (ºC)
(Solubility curve)
CHEMICAL KINETICS
1. (B)
Sol. 60 minutes = 3 half lives
T1
 2 = 20 min
ln 2 ln 2
 
 t1/ 2 20 per min
2. (A)
1 n
 T1 / 2   C1 
  
Sol.  T1 / 2   C2 
1 n
 350   80 
   
  175   40 
1–n
= 2 = (2) 1 – n = 1
n = 0

3. (A)
n–1
1
t1   
Sol. 2 a for nth order reaction
1– n
t 1  k(a)
2
log t 1
2 = (1 – n) loga + logk
log t 1
Thus, graph between 2 and log a is linear slope
(1 – n) = tan45º
n–0
4. (C)
2 
90 Th 234   92 X 234  90 Th
230
Sol.
Elimination of 1 and 2 particles give isotope.
5. (C)
–Ea
k  Ae RT
Sol.
For methyl nitrite k1 = 1013e[–152300/(8.314 × T)]
For ethyl nitrite k2 = 1014e[–157700/(8.314 × T)]
If k1 = k2 then
1013e[–152300/(8.314 × T)] =1014 e[–157700/(8.314 × T)]
157700 – 152300

Or 2.303 log 10 8.314  T
T = 282 K
6. (C)
Sol.
A0
[B]
Conc.
Time
A nB
At t = 0 A0 –
At t = t A0–x nx
According to question, at presentation point
 A0 – x = nx
 A0 = (n + 1)x
A0
x = n  1
 n  A0 
 
[B] = nx =  n  1 

7. (C)
t 1  a1n
Sol. 2
1n
t 1  1 
 
t2  2 
1n
4  50 

2  100 
n=2
Therefore, the order of reaction is 2.
8. (D)
1
H2O2  H2O  O2
Sol. 2
d H2O2  d H2O d O2 
  2
dt dt dt
t 1/2
0.5 0.25 0.125
t3/4 = 50 minute
t 1  25
2
0.69314
t1 
2
k
0.69314
k
25
k H 2 O 2 
rate of reaction =
d O2 
1
  k H 2O2 

dt 2
1 0.69314
   0.05
2 25
 6.93  10 –4 molmin–1
9. (D)
Sol. For A:
10 10 10 10 10 10 10 10 a
8a            
32
For B:
20 20 20 20 a
a    
16

10. (B)
Sol. A(g)  3B(g) + C(g)
at t = 0 200 torr – –
at t = t 200 – p 3p p
p = 150 torr
1 200 1  2.303  log 4
 2.303  log 
t= k 200 – p 4.606  10 –3 = 300 sec
11. (A)
Sol. Here, same metal ion, Mn+ from three homoleptic octahedral complexes (i), (ii) and (iii) on
 
NCS,F
separate combination with three mono-dentate ligands- and NH3 respectively.
So we have to compare their CFSE(0) as well as wavelength () values, where
hc 1
E(CFSE) =  or, 0  
Again, 0 value will depend on power of lignad as placed in spectrochemical series.
1
F  NCS  NH3
Power of ligand  0   , F– < NCS– < NH3,
 Power of Ligand 
 0
So, for the given complexes, it is evidented from the plot (Absorption vs )
(ii) (i) (iii)
max  max  max
(C) (B) (A )
[F ] [NCS ] [NH3 ]
12. (C)
Sol. On adsorption (both physical and chemical), the residual force acting along the surface of
absorbent decreases. So, H of the adsorption becomes less negative as adsorption
proceeds. So, statement (a) is correct but statement (c) is incorrect. Ammonia molecules
(NH3) is larger in size and dipolar in nature. Nitrogen is smaller in size and it is a non-polar
molecule. So, degree of adsorption : NH3 > N2. So, Statement (b) is correct. With increase in
temperature, kinetic energy of adsorbate molecules will increase and hence, its equilibrium
concentration will decreases. So, statement (d) is not correct.
13. (B)
Sol. Only statement (b) is true whereas all other statements are incorrect. A zero order reaction is a
multistep reaction because in most of the zero order reactions, free radical is the intermediate
which follow chain-initiation, chain-propagation and chain-termination like steps, e.g., free
radical substitution reaction.
(a) A second order reaction is always a single step reaction, e.g., SN2 and E2 reactions.
(c) A first order reaction may be a multi-step reaction when intermediate of the reaction, like
carbocation (l1) gets rearranged into its most stable form (l2).
Same is the case with (d). So, options (a), (c) and (d) are not true .

LIQUID SOLUTION
1. (B)
 w 1 
Tb  K b  solute    1000
Sol.  Wsolvent M solute 
1000  10
 M AB2  100
1 = 100  M AB2
Similarly
A B
100 + M + 2  M
A B
and 140 = 2  M + M ;
A B
M = 60 and M = 20
Alternative solution
Tb 10
1
Kb M A  2M B
0.1
A B
M + 2M = 100 ...(1)
Tb 14
1
Kb 2M A  MB
0.1
A B
2M + M = 140 ...(1)
A B
M = 60, M = 20
2. (B)
Sol. Boiling point (Tb) = 100 + Tb = 100 + Kbm
Freezing point (Tf) = 0 – Tf = kfm
Tb – Tf = (100 + kbm) – (– kfm)
105 = 100 + 0.51 m + 1.86 m
5
m  2.11
2.37 m = 5 or 2.37
 Weight of sucrose to be dissolved in 100 g water
2.11 342
  100  72.2g
1000
3. (A)
p0  pS
 x solutes
Sol. p0
Wsolutes
Msolutes
= Wsolutes  Wsolvent
Msolutes Msolvent
p0  pS w A mB
 
p0 mA WB (A stands for solute and B for solvent)

75
xx
100  w  18
75 60 100
x
100
[Let the vapour pressure of pure water P0 = x]
0.25x w 18
 
0.75x 60 100
 w = 111.118
111.11 1000
  18.52
Molality = 60 100
4. (A)
Sol. Isotonic solution have same osmotic pressure
1  C1RT, 2  C2RT
For isotonic solution, 1 = 2
 5.25 / M   1.5 / 60 
  10  RT    10  RT
 100   100 
5.25 1.5

M 60
60  5.25
M  210 g / mole
1.5
5. (D)
Sol. P2 = KHX2 where P2 partial presence of gas
X2mole fraction of gas in solution
KH = Henry's law constant
So, P  solubility
p1 s1 500 750
  
p2 s2 0.01 x
x = 0.01 5 g/L
6. (D)
X2 Y2  aq  2X3  aq  3Y 2  aq
Sol.
n=5
Tb = i Kb .m = 11 (1+4) Kbm
= (1 + 4 × 0.75) × 0.52 × 2
= 4.16; Tb = 373 + 4.16 = 374.76

7. (B)
P0  Ps n
Sol. 
Ps N
10  5 9  200

5 M  20
M = 90 amu
8. (A)
Sol. K2Hgl4 2K+ +HgI42+
  i = 1 + (n – 1) a
  i = 1 + (0.55) (3.1) ( n = 3)
  I = 21
9. (B)
Sol. The two solution should have same molar concentration for being isotonic.
Molar concentration of cabe sugar = Molar
6
Concentration of urea = 60 = 0.1 mol/L
Concentration of cane sugar in g/L
= molar concentration × molecular weight
= 0.1 × 342 = 34.2
10. (A)
Sol. As when temperature increase, vapour pressure increases so C and D options get rejected.
 Tf = Kf × m
34.5
273 – Tf' = 2 × 46
0.5
So, Tf' = 270 K
11. (A)
Sol. When a raw mango is kept in a concentrated salt solution, the mango will shrink because of
exo-osmosis. Mango cell membrane acts as semi-permeable membrane and its cell cytoplasm
is considered as a solution of concentration, C1M (say). Let the concentration of salt solution is
C2M, where C1 < C2 (mentioned).
So, osmotic pressure developed at salt solution, 2 will be greater than that at cell cytoplasm,
1 at a given temperature.
1 = C1RT and 2 = C2RT
So, solvent molecules (water) will flow out from mango cells to salt solution resulting shrinking
of mango. This state is also known as plasmolysis.

12. (D)
Sol. An acidic buffer is a mixture of weak and its salt with strong base. Now, let us study the
composition of each mixture obtained by mixing of two solutions.

CH3COONa
(a) CH3COOH + NaOH  + H2O
t  0 100  0.1 100  0.1 0 0
milimol
ta 0 0 10 10
So, it is not a buffer.
NaCl, a salt of strong acid (HCl) and strong base (NaOH) is not hydrolysable by HCl also. So, it
is not a buffer.

CH3COONa
CH3COOH + NaOH  + H2O
t  0 100  0.1 200  0.1 0 0
(Limiting)
milimol
ta 0 20  10  10 10 10
After mixing, the solution contains equimolar amounts by NaOH(a strong base) and

CH3COONa
(salt). So, it is also not a buffer.

CH3COONa
+ HCl  + CH3COOH + NaO
t0 200  0.1 100  0.1 0 0
(Limiting)
milimol
t  a 20  10  10 0 10 10
Now, the resultant solution contains equimolar amount of CH3COOH (an week acid) and
CH3COONa (a salt of CH3COOH with strong base, NaOH).
So, it is an acid buffer.
13. (C)
Sol. In first component,
Mass = number of mole × molecular weight = n1M1
In second component, Mass = n2M2
Mass of solution = n1M1 + n2M2 ……….(i)
n2
Mole-fraction (2) = n1  n2
n2 (1   2 )
n1 
 2 ……….(ii)
Place the value of n1 in eq. (i)
n (1  2 )M1
n1  2  n2M2
 2
n2
 2 (M22 – M12 + M1)
Volume of solution,

n2 (M2 2  M1 2  M1 )
L
= 1000  d   2
1000  n2  d 2
C2 
n2 (M2 2  M1 2  M1 )
1000d2
C2 
 M1  2 (M2  M1 )
Hence, the correct option is (c).
CHEMICAL EQUILIBRIUM
1. (B)
+
IO 3
Sol. AgIO3(s) Ag (aq) + (aq)
Let the solubility of AgIO3 be S
IO3 
+
Ksp = [Ag ]
1.0 × 10–8 = S2 or S = 1 × 10–4 mol/L
In 1000 mL moles of AgIO3 dissolved
= 1 × 10–4 moles
In 100 mL moles of AgIO3 dissolved
= 1 × 10–5 moles
Mass of AgIO3 in 100 mL
= 1 × 10–5 mol × 283 g mol–1
= 2.83 × 10–3 g
2. (C)
Sol. The overall dissociation constant of the acid is
K = K1 × K2
= 1.0 × 10–5 × 5.0 × 10–10 = 5 × 10–15
3. (A)
Sol. Equilibrium constant for the reaction,
1
SO2(g) + 2 O2(g) SO3(g)
1
2
Kc = 4.9  10
and for 2SO2(g) + O2(g) 2SO3(g)

2
 1  10 4
 2 

Kc =  4.9  10  (4.9)2

= 416.490 416

4. (A)
Sol. PCl5(g) PCl3(g) + Cl2(g)

Initially 1 0 0
At equilibrium (1 – x) x x
Total number of moles at equilibrium
= (1 – x) + x + x = 1 + x
 x 
pPCl3   p
1 x 
5. (A)
Sol. NH4HS(s) NH3(g) + H2S(g)

Initially 1 0.5 0
At equilibrium (1 – x) (0.5 + x) x
Total pressure at equilibrium
pNH3  pH2S
=
= 0.5 + x + x = 0.84
 x = 0.17 atm
pNH3
 = 0.50 + 0.17 = 0.67 atm
pH2S
= 0.17 atm
pNH3 pH2S
 Kp = 
= 0.67 × 0.17 = 0.114 atm 
6. (D)
Sol. 2NO2(g) 2NO(g) + O2(g)

–6
Kc = 1.8 × 10 at 184°C (= 457 K)
R = 0.00831 kJ mol–1 K–1
ng
RT 
Kp = Kc
where,
ng = (gaseous products – gaseous reactants)
=3–2=1
 Kp = 1.8 × 10–6 × 0.00831 × 457
= 6.836 × 10–6 > 1.8 × 10–6
Thus, Kp > Kc.
7. (A)
Sol. Reaction is exothermic. By Le–Chatelier principle, a reaction is spontaneous in forward side (in
the direction of formation of more ClF3). If F2 is added, temperature is lowered and ClF3 is
removed.


8. (A)
Sol. conjugate base is formed by loss of H+
O 2
OH–  Conjugate + H+
base
O2– is the conjugate base of OH–.


9. (C)
Sol. MX2 M2+ + 2X–

S 2S
Ksp = [M ] [X–]2
2+
If solubility be S, then
Ksp = (S) (2S)2 = 4S3
4S3 = 4 × 10–12
 S = 1 × 10–4 M
 [M2+] = S = 1 × 10–4 M
10. (C)
Sol.
Dng = – ve H° = – ve
Takes place with decrease Takes place with evolution of heat
in number of moles of of increase in temperature, hence
pressure, hence increase in decrease in temperature shifts this
pressure shifts equilibrium equilibrium in forward side.
in forward side.
11. (A)
Sol. From the equilibrium, A B
At equilibrium, ra rb
Equilibrium is the condition when a forward chemical reaction and its reverse reaction proceed
at equal rates. It can be illustrated by following graph.
Rate of reaction
a
Equilibrium
b
Time
12. (C)
[B][C]
A B  C;K (1)
eq 
Sol. [A]
[P]
BC P;K(eq2) 
[B][C]
Equilibrium equation (i) and (ii)
[P]
K (1) (2)
(eq)  K (eq)   K eq
[A]

13. (B)
Sol. N2O4(s) 2NO2(s) ; DHº = + 58 kJ
Because in case of an endothermic reaction (H = + ve), the equilibrium constant increases with
rise in temperature and hence, the reaction moves in forward direction. On adding N2, pressure
is increases at constant T, and volume would also be constant, so no change is observed.
IONIC EQUILIBRIUM
1. (C)
Sol. When BaSO4 begins to precipitate
K sp [BaSO 4 ] 1.0  10 10
[SO24 ]  
[Ba2 ] 0.020 = 5.0 × 10–9M
When PbSO4 begins to precipitate
K sp [PbSO 4 ] 1.6  10 8
[SO24 ]  2

[Pb ] 0.020 = 8.0 × 10–7 M
[SO42–] is less for BaSO4 precipitation
So BaSO4precipitates first when PbSO4 begins to precipitate
[SO42–] = 8.0 × 10–7M at that point concentration of
K sp [BaSO 4 ] 1.0  1010
Ba2    1.25  104 M
[SO24 ] 8.0  107
2. (C)
K a  ca 2
Sol.
K a1 a12
 
K a2 a22
42 16
2

= g 81
3. [D]
Sol. Sodium acetate and sodium propionate are not conjugate acid base pairs
4. (A)
Sol. Calcium acetate is a salt of weak acid and weak base.
0.005 M calcium acetate, (CH3COO)2Ca
(CH3COO)2Ca  Ca2+ + 2CH3COO–
0.005 M (2 × 0.005 = 0.01)
–
 [CH3COO ] = 0.01M
–
OH
Alkaline
CH3COO + H2O CH3COOH +
pK a logC

pH = 7 + 2 2
log0.01
= 7 + 2.37 + 2
= 7 + 2.37 – 2.30 = 7.06

5. (B)
Sol. pkb of CN– = 4.7
pka of HCN = 4.7
NaCN is salt of weak acid (HCN) and strong base (NaOH) so
1 1
pH = 7 + 2 pka + 2 logC
1 1
= 7 + 2 x 9.3 + 2 log(0.5)
pH = 11.5
6. (A)
Sol. pH change = pH of 75 % blue 75% red
75
= [pKa + loglog ]
25
25
= [pKa + loglog ]
75
= log3 + log3
pH = 0.954
7. (D)
Sol. Methyl orange is weak organic base. It is used in the titration of weak base vs strong acid.
MeOH Me+ + OH-

Unionized form Ionized form
(Yellow) (Red)
In basic medium, equilibrium lies in backward direction and therefore it shows yellow colour.
In acidic medlum, equilibrium shifts in forward direction and therefore, colour changes from
yellow to red.
8. (B)
Sol. HCI: Strong acid (low pH)
NH4CI : Salt of weak base + strong acid it gives acidic solution. (pH less than 7)
NaCl: Salt of strong base + strong base  it gives neutral solution with pH = 7.
NaCl: Salt of strong base + weak acid  it gives basic solution with pH > 7.
Thus the increasing order of pH is HCI < NH4CI <NaCl<NaCN
9. (C)
Sol. NaOH + CH3COOH  CH3COONa + H2O
2 6
m mol LR
– 4 2
The resulting solution is an acidic buffer.

[Salt]
so pH = pKa + log [Acid]
2
log
= 4.71 + 4
= 4.44
10. (C)
Sol.
NaOH
HCl
n  n [HCl] VHCl
OH   OH  acid 
  V – V VNaOH = 0.21 M < 0.220
OH NaOH
11. (B)
K sp s2 K sp 
 
s (H )
Sol. Ka (H ) ; Ka
2.2  1016
s 10
 103
6.2  10
s = 1.9 × 10–5
Hence answer is (2)
12. (C)
Sol. Ca(OH)2 Ca2+(aq) + 2OH–(aq)

s 2s
2 –6 3
ksp = s(2s)  5.5 × 10 = 4S
1
 5.5  3 2
s   10
  4  = 1.11 × 10–2
13. (B)
Sol. Among the given options, distilled water has the lowest ionic conductance at 298 K.
Water from well or sea contains mineral ions,
 they have ionic conductance.
Saline water is an electrolyte and contain ions
 It also has ionic conductance.

GASEOUS STATE
1. (D)
N 2  3H 2 
 2NH3
Initial mole 1 4 0
Sol. Reacted mole 1 3
Left mod e 0 4  3 1 2
2
H Left = 1 mole
3
NH formed = 2 mol
3 4 2
But NH (g) dissolves in water forming NH OH. Residual gas only H which exerts pressure.
2
Volume = 15 – 5 = 10 L (5L occupied by H O added)
n 1  0.821  300
RT atm
p = V 10
2. (A)
 a 
c  2 
Sol. P = P  =  27b  
c
V – V  = (3b)
 8a 
  c
T = T  =  27Rb  
Hence substituting in the van der Waal’s equation
 a 
P  2 
 v  (V – b) = RT
 3 
 2 
    (3 – 1) = 8
This is reduced state equation
 3   3 1   1  8
   2  –    2
    8 8  = 1   3   (3 – 1) = 3 
3. (C)
Sol.
24.6
PV(litre-atm mol–1)
[Graph not to scale]

23.1
21.6

20.1
0 2.0 3.0
(mol littre–1)
van der Waals equation for 1 mol of real gas is

 a 
 P  v 2   V  b   RT

Given that b = 0
 a 
 P   [V – b]  RT
 V2 
a
 PV  RT –
V .....(i)
1
Following y = mx + c for the curve PV vs v
Slope = –a
21.6 – 20.1
  1.5
Slope 2–3
 a = 1.5
4. (C)
Sol. 2NH3(g) N2(g) + 3H2
76–2x
76 + 2x = 76 + 18
2x = 18
 x=9
p H2
 =3×9
= 27 cm of Hg
5. (B)
4
b  4  r 3  N A
Sol. 3 ;
we know that,1L = 1000cm3
4
4    10 4  1000  4     r 3  6  1023
3
r = 5 × 10–9 cm
6. (D)
Sol. According to Graham's law of effusion.
1
r
M
rmix MSO2

rso2 Mmix
64
 2.56 
Mmix
 Mmixture  25
Let mole fraction of F2 is x. Therefore, mole fraction of F will be (1– x)

38  x  1  x   19
25 
1
x = 0.315 ;
PF2 (0.685P)2
 Kp   1.49 atm
PF2 (0.315P)
7. (B)
Sol. According to Avogadro hypothesis
Vn
(RT)
V n
P
RT
Proportionality constant = P
Using PV = nRT
RT V 2.463
 
 P n 1
8. (D)
3 th 5
Sol. If 8 of the air is expelled out then remaining air = 8
In the open vessel volume and pressure are both constant but moles are decreasing
 n1T1 = n2T2
5 
 n1  T2
 n1 × 300 =  8 
8 8
 T1 
 T2 = 5 5 × 300 = 480 K
= 480 – 273 = 207ºC

9. (D)
Sol. As per Boyles law
PV = constant
P  1 
 cons tan t  2 
V V 
logP = – log V + log(constant)

10. (D)
Sol. Let P0 be the value at atmospheric pressure
(I) (II)
h
1
1
h
In case I:
Pgas + hcm of Hg = P0cm of Hg
In case ii Pgas = P0cm of Hg + hcm of Hg
By applying Boyle's law between (I) & (II)
(P0 – h)× l1 = (P0 + h) × I2
orP011 – h11 = P012 + h12
orP0(11 – 12) = h(11 + 12)
h(11  12 )
P0 
or (11  12 )
11. (D)
Sol. Graph (II) is not correct for ideal gas.
For n mole of an ideal gas,
W
pV = nRT = M RT
W RT RT  W 
p 
V M
 d
M  M  d
  
p·M
d
 RT
Where, p = pressure, V = volume,
T = temperature in K, R = molar gas constant,
w = mass of the gas in g,
M = gram molar mass of the gas and
W
d
V = density of the gas.
1
d
(i) When, p = constant  T
So, nature of the plot, d vs T is rectangular hyperbolic (I) but not linear (II). Again,
1
nature of the plot, d vs T will be linear in (III).
(ii) When, T = constant  d  p
Here, nature of the plot, d vs p will be linear as (IV).

12. (D)
Sol. Volume of cylinder = V, Temperature = T,
Partial pressure of H2 = 2 atm
According to law of partial pressure
pi = i × pT
pi = partial pressure of the ith component,
i = mole fraction, pr = total pressure
 nH2 
2atm     pr
  nH2  nHe  nO2 
3
Then, pr = 2 × 1 = 6 atm
13. (A)
Sol.
OV
OV
a/2
OV a/2
In fcc octahedral voids are present at the edge centrers at body center.
Minimum distance between centres of two octahedral at voids.
2 2
a  a a 2 a2 a
x        
 2  2 4 4 2
THERMODYNAMICS
1. (C)
Sol. Hneutr.for strong acid with strong base = –13.7 kcal equiv–1
Enthalpy of ionisation of acetic acid &NH4OH together
=–10.5 – (–13.7) = +3.2 kcal mol–1
Enthalpy of ionisation of only acetic acid
= –12.5 – (–13.7) = +1.2 kcal mol–1
Enthalpy of ionisation of only NH4OH
= 3.2 – 1.2 = 2 kcal mol–1
2. (A)
Gº  Hº TSº
Sol.
= –196000 –400 (125.65)
=– 196000 –50260
= – 246260= –2.303 x 8.314 x 400 log Kp
246260
logKp = 7658 = 32.15
Kp = Antilog (32.15)
= 0.4 x 1032

3. (D)
Sol. C4H10(g) + 6.5O2(g)  4CO2(g) + 5H2O(l)
n = [4 – 7.5] = –3.5
H = E + ngRT
 H < E
4. (C)
Sol. H = ( E + PV) = E + (RT) = E + RT
For isothermal expansion of ideal gas, E = 0
(E = Cv T)
So H = 0 + 0 = 0 (T = 0)
putting
E = CvT, H = CvT + RT for = (Cv + R) T = Cp T
1 mole
for n moles, H = nCpT = 0
5. (A)
Sol. In an isothermal process, temperature is constant T2 = T1
Area under P - V graph is more is isothermal
W isothermal>W adiabatic
Now Ulsothermal = 0
In adiabatic T1V1–1 = T3V3–1
1
T3  V1 
 
T1  V3 
T3< T1 Hence internal energy decreases
Uisothermal>Uadiabatic
6. (A)
Sol. Here, V = 200 – 400 = –200 cm3
A we know 1 litre = 1000 cm3V = –0.2 litre
External Pressure(P) = 0.50 then work done = –PV = +0.50(0.2) = +0.1b atmlitre and 1 litre
atmosphere = 101.3 joule
 W = + 10.13 joule
According to first law of thermodynamics
q = E – W
thenE = q + W
Given q = –8.00 J
E = –8 + 10.13 = 2.13 Joule
7. (A)
Sol. H = U + ng RT
H = –740000 + 0.5 × 8.3 × 300 = – 738755 J

8. (A)
PV
 0.02moles
Sol. n = RT
v2 T
 nC v,m ln 2
S = nRln v1 T1
S = 0.12 +0.06
S =0.18 JK–1
9. (C)
 TL   PL 
Sol. K L : Isochoric process with increasing in pressure so by   
 TK   PK 
PL> PK so TL> TK so it is a case of heating.
 TM   VM 
L M : Isochoric process with increasing in pressure so by   
 TL   VL 
VM< VL so TM< TL so it is a case of cooling
Similarly for
 TN   PN 
M N : Isochoric process with increasing in pressure so by   
 M   PM 
T
PN< PM so TN< TM so it is a case of cooling.
10. (D)
Sol. As Internal energy change is a state function so it depends only on the initial and final
temperature and does not depends on the path taken.
11. (A)
Sol. According to Kirchoff’s relation,
T2
H  n  Cp dT
T1 …(i)
Where H = Change in enthalpy
Cp = Heat capacity at constant pressure.
Give, n = 3 moles, T1 = 300 K, T2 = 1000 K,
Cp = 23 + 0.01 T
On substituting the given values in Eq. (i), we get
1000 1000
H  3  (23  0.01T)dT  3  23dT  0.01T dT
300 300

1000
 0.01T 2 
 3  23T 
 2 300
 0.01 
 3  23(1000  300)  (1000 2  300 2 ) 
 2 
= 3[16100 + 4550] = 61950 J  62 kJ
12. (B)
Sol. A process will be spontaneous when its free energy (Gibb’s energy) change will be negative,
i.e. G < 0. Spontaneity of a process is decided by the value of G, which can be predicted
from the Gibb’s equation, G = H – TS for positive/negative signs of H and S at
any/higher/lower temperature as :
H S Comment on temperature (T) G Comment on the process

  at any temp.  Spontaneous
  At any temp.  Non-spontaneous
  At lower temp.  Spontaneous
  at higher temp.  spontaneous
13. (C)
Sol. For isothermal reversible expansion.
Vf V
| W | nRT ln  nRT ln
Vi Vi
Where, V = final volume, Vi = initial final.
Or |W| = nRt ln V – nRT ln Vi
On comparing with equation of straight line,
Y = mx + c, we get
slope = m = + nRT
intercept = – nRT ln Vi
Thus, plot of |W| with ln V will give straight line in which slope of 2(T2) is greater than slope of
1(T1) which is given in all options.
Now, it Vi < 1 then y intercept (–nRT Vi) becomes positive and if it is positive for one case then
it is positive for other case also. Thus, it is not possible that one y-intercept goes above and
other y-intercept goes below. Thus, option (b) and 9d) are incorrect.
If we extent plot given in option (a) it seems to be merging which is not possible because if
they are merging they give same +ve y-intercept. But they cannot give same y-intercept
because value of T is different.
Now, if we extent the line of T1 and T2 given in option (c) it seems to be touching the origin. If
they touch the origin then y-intercept becomes zero which is not possible. Thus, it is not the
exactly correct answer but among the given options it is the most appropriate one.

ELECTROCHEMISTRY
1. (A)
cell
E ºcell
Sol. For E =
log Q must be zero
Q =1
2
 Fe 2  106
 1
Q =  H    Po2  10   0.01
4 4x
–4 –4x
10 = 10
x=1
2. (A)
+ –14 –
Sol. When pH = 14, [H ] = 10 and [OH ] = 1 M
2+ – 2 –19
sp
K = [Cu ] [OH ] = 10
2+
10–19 –19
– 2
 [Cu ] = [OH ] = 10
The half cell reaction
2+ –
Cu + 2e  Cu
0.059 0
1
log
E=E – 2 [Cu 2  ]
0.059 1
log –19
= 0.34 – 2 10 = –0.22 V
3. (C)
Sol. The equivalent conductivity of 0.1 M weak acid is 100 time lesser thn that at infinite dilution.
0
v 
100
Degree of dissociation
 0
 v  0v 
() =  100 0 = 0.01
4. (A)
Sol. Saturated solution corresponding to infinite dilution
0m
for salt
 0M( NH ) Br    H0 PO –
= 3 4 2 2 2
= 100 S m2 mole–1 + 50 Sm2mol–1 = 150 Sm2mol–1
1 1 1

K =  200 –1 cm–1 = 2 –1m–1

1 –1 –1
 m
k 2
0m  –3
(salt) = s s moles m
1 1

S (moles m ) = 2  150 300 = 333 × 10–3
–3
S (moles L–1) = 333 × 10–6

Ksp = (333 × 10–6)2
= 1.11 × 10–11 M2
5. (B)

EOH
|Ag O|Ag
2
Sol. Calculation for
 2Ag  2e   2Ag s, G1  –2  F  E  
 Ag / Ag 
Reduction
 Ag2O  H2O(l)  2Ag  2OH G2  2.303RT logk 2 
 sp 
Lonisation
 Ag2O  H2O(l)  2e  2Ag(s)  2OH , G3  2  F  EOH |Ag O|Ag 
Net  2 
2.303RT logk sp2
G3  G1  G2  2  F  EOH |Ag O|Ag  2  F  E Ag / Ag 
2
2F
0.06
EOH |Ag O|Ag  EAg /Ag   2logk sp
2
2
= 0.8 + 0.06 log [2 × 10–8]
= 0.8 + 0.06 [–8 + 0.3]
= 0.8 + 0.06 × (–7.7)
= 0.8 – 0.462
= 0.338 Volt 0.34 V
G° = –nFE°ceu
–nF(E°c – EA)Red
2  (EOH |Ag O|Ag  EZn2 /Zn )
2
=
= –2 × 96500 × (0.34 + 0.76)
= 212300 J
= 212.3 kJ
6. (A)
100 1 1 1000
 eq  k    
Sol. N R a N
1 1000
 cell cons tan t 
R N
1 1000
 0.88 
= 220 0.01
= 400 mho cm2 eq–1

7. (B)
Sol. Total current passed in 30 sec = Area of current–time curve
1  1 
 2  100  10   100  10   100  10    2  100  10 
=   
= 3 × 100 × 10 mA × s
= 3000 × 10–3 amp s = 3C
EQ W E m
W or  Z
F Q F 3
8. (A)
1.93  50  60
Sol. No. faraday = 96500 = 0.06
80 0.06

 Moles of Zn deposited = 100
2+ 2 = 0.024
0.5  2 – 0.024
 Zn2    0.38M
  0.2 
9. (D)
Sol. Al3+ + 3e–  Al
0.059 1
3 3
E = E° – log [ Al ]
at pH = 12  pOH = 14 – 12 = 2  [OH–] = 0.01 M
10 36 10 36
 3 3
[Al+3] = [OH ] = (0 .01) = 10–30
0.059  1 
 30 
 E = –1.55 – 3 log  10 
0.059
= – 1.66 – 3 × 30 = – 1.66 – 0.59 = – 2.25 V
10. (D)
Sol. At equilibrium
Ecell = 0
E0cell = 0.01 V
Sn + Pb2+ Sn2+ + Pb
0.06
Ecell  E0cell  logQ
n
0.06 [Sn2  ]
0  0.01  log
2 [Pb2  ]
0.06 [Sn2  ]
0.01  log
2 [Pb2  ]
1 [Sn2  ]
 log
3 [Pb2  ]
1
[Sn2 ]
 10 3  2.14
[Pb2  ]

11. (C)
Sol. NaCl and KCl are strong electrolytes. So, the study of their molar conductances (m) can be
experimentally verified by Debye-Huckel
c 0
m  m B C
cm
= molar conductance at concentration.
0m
= molar conductance at infinite diution.
i.e. C  0
B = Debye-Hukel Onsgar constant.
m C
For (both NaCl and KCl) a strong binary electrolyte like AB, the nature of the plot of vs
will be
m
C
Na will remain in more hydrated state, i.e. larger sized in aqueous solution. As a result, ionic
mobility as well as ionic conductance of Na.
(or NaCl as Cl is common to NaCl and KCl) will be lower than K (or KCl). Thus, the plot of
m C
vs for NaCl and KCl is as follows :
KCl
NaCl
m
C
12. (D)
Sol. In disproportionation reactions, same element undergoes oxidation as well as reduction.
e.g.
Reduction
+1
2CuBr +2 + Cu
CuBr 0
2
Oxidation
Here, CuBr get oxidised to CuBr2 and also it get reduced to Cu. other given reactions and their
types are given below.
Reduction
+7 
MnO 2Mn+2 + 5I2 + 8H2O
4 – +
2 + 10I + 16H
Oxidation
MnO4
In the given reaction, get oxidised to Mn2+ and I– get reduced to I2. It is an example of
redox reaction. The reaction takes place in acidic medium.
2KMnO4 K2MnO4 + MnO2 + O2

The given reaction is an example of decomposition reaction, Here, one compound split into two
or more simpler compounds, atleast one of which must be in elemental form.
2NaBr + Cl2  2NaCl + Br2
The given reaction is an example of displacement reaction. In this reaction, an atom (or ion)
replaces the ion (or atom) of another element from a compound.
13. (B)
Sol. Key Idea This question is based upon Faraday’s first law which states that “Mass of any
substance deposited of liberated at any electrode is directly proportional to the quantity of
electricity passed.”
During charging :
SO24
Pb + PbSO4 + 2e–
 1 F 1 g-equiv. of PbSO4
1 303
= 2 mol of PbSO4  2 g PbSO4
303
 0.05 F  2 × 0.05 g PbSO4
= 7.575 g of PbSO4
SOLID STATE
1. (B)
molar mass 4  119

Sol. Calculated density d = z × = 23 8 3
= 2.78 g cm–3
NA  volume 6.023  10  (6.58  10 )
Is greater then actual density 2.44 gcm–3 therefore density decreases and defect is Schottky
defect.
2. (A)
rA rA
 0.414 
Sol. rx 250
rA  0.414  250 pm  104 pm
3. (D)
1
+
Sol. Distance between two Na is 2 times of edge length
4. (A)
Sol. For the given crystal, a = b  c,  =  = 90°,  = 120°
These are the characteristic of hexagonal system.

5. (D)
Sol. X is in f.c.c. lattice
1 1
8
Number of atoms= atom at corner × + atoms at faces × 2
1 1
X  8  6  4
8 2
Total tetrahedral voids = 8
As y are at T.V.
So Y = 8
Number of Octahedra voids = 4
1
Z 4  2
2
So X = 4, Y = 8, Z = 2
Hence the formula of solid is X4Y8Z2
or X2Y4Z.
6. (D)
Sol. In BCC structure the cations and anions touch along the body diagonal
 
2 rcs  rBr   3  4.3 3a
(Body diagonal = )
1.72  4.3
rcs  rBr    3.72Å
2
2rc  rBr 
s
rBr 
7. (A)
Sol. No. of oxygen atoms per unit cell in ccp = 4(O2–)
No. of octahedral voids per unit cell = 4 (Al3+)
No. of Tetrahedral voids per unit cell = 8 (Mg2+)
Total negative charge due to oxygen atoms = 8
Net charge must be zero.
m4 (3) + 2n (8) + 4 (–2) = 0
3m + 4n = 2

3 4
 2
(A) 2 8 is correct
4
3  1 4  42
(B) 4
1 1
3  4  4  2
(C) 2 4
1 1 3 2 5
3  4     2
(D) 4 8 4 4 4
8. (A)
Sol. Given that  = 2.75 g cm–3
We need to find type of unit cell
Z M

 NA a3
  NA  a3
Z
 M
2.75  6.023  10 23  (654  1010 )3

= 119
 Z = 4 so FCC unit cell
In FCC 1 atm surrounded by 6 atoms so coordination number is 6.
9. (B)
M0
z
NA
d
Sol. a3(d = density)
M0
4
8 6  1023
3

4  10 10 
1
M0 
8  6  1.6
256 10
 
Number of moles in 256 g 8  6  1.6 3
10
  6  1023  2  1024
Number of atoms 3
10. (C)
Sol. 8chloride ions at 8 corners Cs+ cation at body centre along body diagonal there will be one Cs+
cation and 2Cl– ions at ends of body diagonal.
2rCs  2rCl  3a
a is edge length

11. (B)
M 2 A6
12
Sol. 3
M8A6
M4A3
12. (D)
Sol. Covalent or network sold have very high melting point and they are insulators in their slid and
molten form.
SURFACE CHEMISTRY
1. (A)
Sol. Millimoles = 10 × 10–3 = 10–2
moles = 10–5
No. of molecules = 6 × 1023 × 10–5 = 6 × 1018
0.24
18
Suface area ocupied by one molecule = 6  10 = 0.04 × 10–18 cm2
–20 2
4 × 10 = x [ x = edge length]
x = 2 × 10–10 cm = 2 pm
2. (D)
1
Sol. Coagulation value  coagulating power
Coagulating power As2S3 is
MgSO4 > BaCl2 > NaCl
III > II > I
3. (A)
Sol. Physical adsorption is a multilayer phenomenon. Rest all are correct features of physical
adsorption.
4. (B)
Sol. Physisorption is exothermic in nature. Therefore, in accordance with Le-Chatliers principle, it
decreases with increase in temperature. This means physisorption occurs at low temperature
more readily. So, The correct order of temperature for curves I, II, III, IV are :
T4> T3> T2> T1
5. (A)
Sol. Larger the hydrophobic fragment of surfactant molecule easier will be micellization, smaller the
CMC value i.e., CH3(CH2)15 N+(CH3)3 Br– will have lowest CMC due to longest hydrophobic
chain.
6. (D)
Sol. In lyophilic sols, the dispersed phase particles have great affinity for the dispersion medium.
These sols are reversible. These are quite stable. Examples include gum, gelatin, starch,
proteins and rubber etc.
7. (A)
Sol. Arsenioussulphide is –ve charged colloid. Hence cation having maximum positive charge will
be nost effective for coagulation, (Hardy Schulz rule)
Al3+> Ba2+> Na+ (coagulating power)

8. (D)
Sol. As2S3 and TiO2solare examples of negatively and positively charged sols respectively.
9. (D)
x
 K(P)1/n
Sol. m
x 1
log    logK  logP
m n
y = c + mx
m = 1/n so slope will be equal to 1/n.
x/m
1<n< n=
n<1
P
N
1
0 1
Hence n
10. (4)
Sol. Blood : negatively charged sol
According to Hardly-schulz rule, for the negatively charged sol, most (+) ve ion is needed for its
efficient coagulation.
11. (B)
1
x 1
   KP n  x 
Sol. m
As per Freundlich adsorption isotherm   n
Hence answer is (2)
12. (A)
Sol.  Viscosity of hydrophilic sol > viscosity of H2O
 Hydrophilic sol is more stable so can't be easily coagulated.
 Hydrophilic sols are reversible sols.
 No electrolytes are required to stabilize hydrophilic sol.
13. (A)
Sol. If FeCl3 is added to hot water, a positively charged sol, hydrated ferric oxide is formed due to
adsorption of Fe3+ ions.
Fe2O3. xH2O/Fe3+ Positively charged.

ORGANIC CHEMISTRY
IUPAC & GOC
1. (B) 2. (C) 3. (A) 4. (D) 5. (C)
6. (C)
7. (C)
1 2 3 4
CH2  C  CH  CH3
Sol. [ ]
H
2 2 3
H sp sp sp sp
C=C=C—C—H
H
H H
8. (D)
O
4
1 2 3 5
Sol.
Mesityloxide
IUPAC [4-Methylpent-3-en-2-one]
9. (C)
3
a(sp )
H3C b(sp2) (sp )
2

C C—O
c
Sol. H H
10. (A)
Sol. For the following ion/compounds
N
(A) - Non aromatic (B) O - Aromatic

(C)  - Aromatic (D) - Aromatic
11. (C)
Sol. COOH COONa
+ NaHCO3 + H2CO3
Weaker acid
CO2 H2O
Equilibrium favours forward direction and CO2 is librated.

OH ONa
O2N NO2 O2N NO2
+ NaHCO3 + H2CO3
Weaker acid
NO2 NO2
Stronger acid
CO2 H2O
Equilibrium favours forward direction and CO2is librated.
NH2 NH2
+ NaHCO3 H2CO3 +
O2N NH2 Strong H2N NH2
OH acid ONa
Weak acid
Equilibrium favours back word direction and CO2is not librated.
12. (D)
OH COOH COOH COOH
Sol.
Non eq. NO2 eq. CH3
Reso –I/–M Reso –I/+H.C.
2>3>4>1
ISOMERISM
1. (B) 2. (A) 3. (A) 4. (B) 5. (C)
6. (C) 7. (D) 8. (A) 9. (C) 10. (D)
11. (B)
CH3 — C — CH3
||
CH2  C — CH3
|
Sol.
O OH
(keto form) (enol form)
enol from of acetone is very less (< 0.1 %)
H-bonding
H…..
O O
CH3—C—CH2—C—CH3 CH3—C C
CH CH3
O O
enol from (more than 50%)
12. (D)
 CH3 — C— CH3
||
Sol. C3H6O  CH3—CH2—CH O&
O

HYDROCARBON
1. (D) 2. (D) 3. (D) 4. (A) 5. (B)

6. (D) 7. (C) 8. (B) 9. (B) 10. (C)
11. (C)
Ozonolysis Ammonical
(X)  (A) 
AgNO3
 Ag 
Sol.
Unsaturated (Tollne’s silver
Hydrocarbon regent) mirror
As (A) compound given positive tollen’s test hence it may consist—CHO (aldehyde group).
or it can be HCOOH
So for the given option :
 Ozonolysis

(C) CH3—CH2—C CH CH3CH2COOH + HCOOH (A) +ve tollen’s test and for
other compounds (options) :
CH3 CH3 Ozonolysis CH3
C=C C=O (Does not
CH3 CH3 CH3 show tollen’s
(A) Test
CH3 Ozonolysis CH3
C= C=O + O
CH3 CH3
(Both do not show
tollen’s test)
(B)
 Ozonolysis

(C) CH3—C C–CH3 2CH3–COOH
(Does not show
tollen’s test)
12. (D)
Sol.
 
HBr Methyl
CH3 CH3 shift
Br••
Br
13. (A)
+ HBr + Br–
Sol. +
(B) –
+ + Br
(A)
This is more stable due to secondary cation formation and formed with faster rate due to low
activation energy.

ALKYL HALIDE & HALOGEN DERIVATIVE
1. (A) 2. (B) 3. (A) 4. (A) 5. (C)

6. (B) 7. (B) 8. (A) 9. (A) 10. (A)
11. (A)
+
OH OH2
+ +
1,2-shift of H– Cl– Cl
H–Cl H–Cl
Sol.
12. (D)
OMe OMe OCH3
Cl Cl I
HCl NaI
Marcovnikov’s dry acetone
Sol. Addition
NO2 NO2 NO2
 Ist reaction marcovnikov's addition of HCl on double bond while 2nd reaction is halide
substitution by finkelstein reaction.
13. (B)
OH OH
SOCl2
Sol.
HO CH2OH Cl CH2Cl
GRIGNARD REAGENT
1. (B)
+ + –+
PhMgBr + CH2 – CH2 Ph – CH2 – CH 2 – OMgBr
(A)
O
Sol. H2O/H+
Ph – CH2 – CH 2 – OH
2-phenylethanol
2. (B)
Sol. (C – Br) bond is weaker than (C-Cl) bond. Grignard’s reagent is formed more predominantly
with (C-Br).

3. (D)
Sol.
4. (B)
OH
Sol. In (A) product is In (B) product is
OH
OH
In (C) product is In (D) product is
5. (B)
Sol. Here the reaction proceeds as follow
(i) CH3MgBr H+

+
(ii) H3O+
O HO
CH2 ZnH2O O3
(A) CH=O
O
C
C CH3
CH3 CH3
6. (C)
Sol. Grignard's reagent reacts with acidic-H to release methane

 
CH3  CH  OM gBr
CHO
+ CH3MgBr   +2CH4(g)
COOH CO OMgBr (p)
HO BrMgO
(1 mole) (1 mole)
Volume of CH4 at NTP = 2 × molar volume = 2 × 22.4 = 44.8 L

7. (B)
O Ph
Ph–MgBr
CH3—C—CH3 CH3—C—CH3 I2 | KOH –ve test
HOH/H+
Sol. OH
(tertiary alcohol)
MeMgBr I2 | KOH
CH3—CH2—CH–O + CH3—CH2—CH—CH3 +ve test
HOH/H
OH
(Secondary alcohol)
H—C—O—Et Ph–MgBr Ph—CH=O Ph–MgBr Ph—CH—Ph I2 | KOH –ve test

HOH/H+ HOH/H+
OH
O Ph
Ph–MgBr I2 | KOH
CH3—C—O—Et CH3—C—Ph –ve test
HOH/H+
OH
8. (D)
Br Br Mg(Excess)
MgBr MgBr
  
(dry ether )

Sol.
9. (D)
Ph
+
CN – + C=N–MgBr
PhMgBr
Dry ether
Sol.
OCH3 OCH3
H 3O +
Ph Ph
C=N C=NH Br
H3O+
+Mg
OH
OCH3 OCH3
10. (C)

OXIDATION REDUCTION
1. (A)
Sol. Cis-2-butene undergoes hydroxylation by syn-addition forming meso product.
CH3
—
C—C—H H — C — OH
Alk.KMnO 4
—
—
—
(cold) H — C — OH
H3 C — C — H
—
cis-2-butene
CH3
(Meso)
2. (D)
Sol. Alcohols give red colour with ceric ammonium nitrate.
3. (D)
Sol.
O O OH
PCC NaBH4
CH 3OH
O Raney OH OH
(A) Ni, H 2
OH
4. (D)
O (1) I2 + NaOH, 
O

+
CHI3 + O + CO2
CH3 (2) H
Sol. COOH
O
5. (D)
CH CHCOCH3 CH CH–CH2CH3
–
NH2-NH2/OH
Sol. Wolff-Kishner
reduction
HO HO
-OH group and alkene are acid- sensitive groups so Clemmensen reduction cannot be used
C O to –CHOH
and NaBH4 reduces only.

6. (D)
Sol. Here the final product formed is Hept-4-yn-1-oic acid as follows
O
NaBH4
CH3–CH2–C  C–CH2–C–H CH3–CH2–C C–CH2
CH2–OH
PBr3
Mg
CH3–CH2–C C–CH2 CH3–CH2–C C–CH2
Ether
CH2–MgBr CH2–Br
CH2/H3O O
CH3–CH2–C  C–CH2–CH2–C–OH
7. (A)
KMnO /OH KMnO
RCH2 OH 
4
 R  CH  O 
4
 R  COOH
Sol.
Primary alcohols are oxidized to carboxylic acids with KMnO4 in neutral, acidic or basic
medium.
8. (D)
Sol. CH3CHOHCH3 gives ketone on oxidation
[O]
CH3–CH–CH3 — CH3–C–CH3
OH O
9. (C)
MO2O3
 
Sol. CH3–CH2–CH3 CH3–CH2–CH=O
The r eagent used will be M O2O3
10. (B)
HO
O
dil.KMnO4 CrO3
273 K (A)
Sol. OH OH
11. (B)
(i) NH2–NH2
– +
(ii) EtO Na /
Sol. O
To reduce the carbonyl groups into alkane wolf – kischner reduction is used, without affecting
the double bond.

ALDEHYDE & KETONE
1. (B)
Sol. The oxidation product of X reacts with phenyl hydrazine, thus it contains > C = 0 group. The
same product does not give silver mirror test. Thus, it is a ketone, because only aldehydes
give silver mirror test.
Thus, the compound X must be 2° alcohol, as only secondary alcohols give ketones on
oxidation an hence, X is (CH3)2CHOH.
2. (B)
Sol. Halogenation of ketones of aldehydes takes placed in -position. Further presence of
halogen on a carbon atom increases acidity of that particular carbon atom, hence further
halogenations takes place on the carbon having halogen and not on other carbon atoms.
O O O
X2,OH '  X2,OH
–
CH3–C–CH3 CH3–C–CH2X CH3–C–CHX2
-H more acidic than ’–H’
3. (D)
Sol. Cyanohydrin formation:
O
NC OH
H–C–N + R–C–R' C
R R'
This reaction is nucleophilic addition reaction.

Step (i): The nucleophilic carbon in the cyanide adds to the electrophilic carbon in the polar
carbonyl group, electrons from the C=O move to the electronegative O creating
anintermediate alkoxide.
Step (ii): An acid/ base reaction protonation of the alkoxide oxygen creates the cyanohydrin
product.
4. (B)
Sol. It is an example of internal Cannizzaro reaction; where –CHO is oxidized while ketonic group
of the same molecule is reduced. Since keto group can’t be oxidized, alcohol corresponding to
–CHO group will not be formed.

5. (B)
Sol.
O Cl
Cl
C  C  CH3
(P)  
(P)
H2 /Pd,  l CH3 C  CNa(R)


Pr ess
6. (D)
Sol. Carbonyl which does not have  – H
can exhibit canizzaro reaction.
7. (A)
Sol. Positive 2,4-DNP test  Carbonyl group,
Positive Fehling’s test  Aliphatic aldehyde group.
Aromatic aldehydes and ketones do not give Fehling’s test.
Hence, among the given options, compounds (iii) and (v) will give positive 2.4-DNP and
Fehling’s test.
8. (C)
Sol.
OH O OH
O
CH–C–OH CH–C–OH
+ O
+
H
NO2
OH O
CH–C–OEt
H
H2O
9. (A)
O
O3
+ H–C–H
Sol. Zn
O
cannizarro
2H–C–H + OH– H–C–O – + CH3–OH
O O
Which compound reaction (aldehyde) doesn't contain – H give Cannizarro reaction.

10. (D)
Sol.
OCH3 OCH3 OH OH
+
EtOOC COOEt (i) H3O HOOC COOH
(ii) 
O NOH
H2N (i) ConH2 SO4
– 
 pH 
O
NH H2O O
H2N
OH
11. (C)
Sol. (i) This method will not work
SOCl2 /PCl3 /PCl5 H2O
 
  
RCOOH RCOCl RCOOH
Aldehyde will not form
(ii) carboxylic acid are not reduced by LiAlH4.
(iii) This method is best
SOCl2 /PCl3 /PCl5 lithium aluminiumtri(t butoxy)hydride.
 
  
RCOOH RCOCl RCHO (aldehyde)
(iv) This method will produce alcohol rather than aldehyde :
SOCl2 /PCl3 /PCl5 (I)R'MgBr LiAlH4
 
    

RCOOH RCOCl RCOR' 3° Alcohol
12. (A)
O
CH2OH COOH CH2 C=O
110°C 
+ CH2=CH2 + 2CO2
Sol. CH2OH COOH CH2 C=O
O
13. (D)
NaNH2
CH CHBr CCH
–HBr
Sol.
CH3 CH3
Red hot iron

tube 873 K
H3C CH3
CH3

AROMATIC COMPOUND
1. (A)
Sol.
 
NH2 NN NN
HNO2
CH2 CH2

NH2
NN

OH
OH OH
dil. HI(heat)
I–
H2SO4, heat 
CH2–OH CH2–OH2 CH2 –I
2. (D)
Sol. Here the major product is formed as follows
O O
NH2 NH–C–CH3 NH–C–CH3
Br
Ac 2O Br2
  
AcOH

A
CH3 CH3 CH3
3. (B)
Sol. Vinyl halides and Aryl halides do not give Friedel Craft Reaction due to partial double bond
character which is resostabilised.
4. (D)
H3C NH2 H3C N N Cl
HO HO
H3C N N Cl + H H3C N=N

Sol.
Brilliant colour dye

5. (B)
Sol. The benzene ring to which >NH group is directly attached is activated for the attack of Br+as –
NH group is highly ringh activating due to +R effect, the ring to which ’fC= O group is directly
attached is deactivated towards electrophillie substitution. As,fC = O group is ring deactivating
due to –R effect in addition the, fNH group is ortho-para directing but para position is
favourable for the attach of Br+. Hence the product formed is as follows
O O
HN HN
H3C CH3 H3C CH3
Br
6. (C)
 
NH2 N2Cl OH OH
COOH
Sol.
CH3 CH3 CH3 CH3
7. (C)
Sol. Strong Electron releasing group favours ESR effectively.
8. (B)
CH3 CH3
Sol.
CH–CH3 CH3–C–O–O–H
Cumene Cumene
hydroperoxide
9. (B)
O
NH2 NH–C–CH3
O O
Pyridine Br  Acidic medium
CH3–C–O–C–CH3   2    
Sol. + – CH3 COOH
O
NH–C–CH3 NH2 N2Cl Br
 NaNO2 / HCl Cu / HBr

H3O
      
 273  278 K
Br Br Br Br

10. (A)
O–
OH
OH
(i)NaNO 2 ,HCl,0ºC (ii)aqNaOH
   
Sol. NN
NN +
N2Cl + Cl– Cl–
O– OH
(ii)aqNaOH

 
N=N N=N
11. (B)
Sol. In basic or neutral medium N–N coupling favourable while in slightly acidic medium C–N
coupling favourable.
NO2 NH2 N2
(i) Sn/HCl (ii) HNO
(A)
Diazonium
1 H
NH2
NH2 N=N
NO2 NO2
NaBH4 NaOH
No reaction
No reaction
(B)
Product not
formed
NH2 N2
HNO2
(C)
NH2 HCl
N=N NH2

12. (C)
NO2 –
H+/HSO4
+ (i) Sn/HCl
Sol. Products
(ii) HNO

+
NO2
NO2
13. (D)
O O
NO2
CH3–C–Cl/AlCl3 CH3 Zn–Hg
HCl
Sol.
Br Br
Br2/AlBr3
NO2  More active

HNO3
H
Br Br
BIOMOLECULE
1. (D) 2. (D) 3. (C) 4. (A) 5. (D)
6. (D) 7. (A) 8. (A) 9. (A) 10. (A)
11. (A) 12. (C)
13. (A)
HO 6
5 O OH Lactose
HO 6 4 1
OH
HO 5 O O 2 Glucose
4 OH 3
OH
Sol. 2
3
OH 1
In lactose linkage is formed between C1 of galactose and C4 of gluocse.
14. (D)
Sol. -ANOMER OF MALTOSE
maltose is disaccharides of -D-glucopyranose by C1–C4 glycosidic linkage
CH2OH CH2OH
O O
H H H H H
H
HO OH H O OH H OH
H OH H OH

15. (D)
Sol. The structure of Tyrosine amino acid is
COOH
H2N H
CH2 OH
POLYMER
1. (B) 2. (C) 3. (D) 4. (A) 5. (A)

6. (A) 7. (D) 8. (C) 9. (A) 10. (D)
11. (D)
Sol. BUN-S, ‘S’ stand for styrene.
Polymerisation
+ (Ph–CH=CH2)  
Buta Buna-S
-1,3-diene styrene
12. (A)
Nascent
+ —CH2 CH2–CH2–CH—
Sol. Oxygen
Ph BuNa-S Ph
13. (C)
Polymerization
CH2=C–CH=CH2 —CH2–C=CH–CH2—
Sol.
Cl Cl n
Chloroprene Neoprene
2-Chloro-1, 3-Butadiene
PRACTICAL ORGANIC CHEMISTRY
1. (A) 2. (B) 3. (D) 4. (A) 5. (C)
6. (C) 7. (A) 8. (D) 9. (B) 10. (B)

11. (A)
Sol.
O O
OH
C C
O + O
C C
O
OH
+ (Pink colour)
(i) H
(ii) –H2O
OH
O
C OH
O + OH
C+
HO
EAS
EAS
O O
C C
H+ H+
O O –H O
–H2O 2
C C
HO
OH
OH
12. (C)
+
NN Cl–
NH2
NaNO2
+HCl
Sol.
1° aromatic
OH –
amine OH
N=N
OH
Organge-Red.dye
13. (D)
Cl OH O
Hydrolysis
373 K H2O
Sol. Cl OH
(C4H8Cl2) (C4H8O)
(A) (B)

CHEMISTRY IN EVERYDAY LIFE
1. (B) 2. (A) 3. (C) 4. (D) 5. (A)

6. (D) 7. (A) 8. (C) 9. (B) 10. (C)
11. (C)
12. (B)
Sol. (a) Valium – Tranquilizer (a)-(iv)
(b) Morphine – Analgesic (b)-(iii)
(c) Norethindrone – Antifertility Drug (c)-(i)
(d) Vitamin B12 – Pernicious anaemia (d)-(ii)
13. (B)
14. (C)
Sol. Some durg do not bind to the Enzyme’s active site. These bind to a different site of enzyme
which called allosteric site.
This binding of inhibitor at allosteric site changes the shape of the active site in such a way h
substrate can not recognise it.
Such inhibitor is known as Non-competitive inhibitor.
Active site with
Active shape change
site
Enzyme Allosteri Inhibitor

site Occupying allosteric
Inhibitor site
(non-competitive)

INORGANIC CHEMISTRY
PERIODIC TABLE
1. (A)
Sol. Atomic mass of middle element of triad is equal to average of masses of terminal elements.
Li Na K
7  39
7 23 39 2 = 23
2. (B)
Sol. The elements X(19), Y(37) and Z(55) are the elements of same group (IA). As atomic number,
increases, the ionization potential decrease down the group. Since, the position of Y is in
between X and Z. Thus, the ionization potential of Y will also be in between X and Z.
3. (A)
Sol. CuO is basic oxide an CO is neutral oxide
CrO3  H2O  H2CrO4
Acid
SO2  H2O  H2SO3 (acid)
Mn2O7  H2O  2HMnO4 (acid)
4. (B)
Sol. (i) Bond angle of NH3 = 107°
PH3 > AsH3 = 90°
According to bond angle the %s character of Ip in NH3 = 22% while in PH3 & AsH3 having
approximately 100%, so the donation of Ip in PH3 & AsH3 are difficult. Hence, the acidic
character increases and the order of acidic character is NH3 < PH3 < AsH3 is correct.
(ii) On moving left to right in a period ionisation energy increases. Li < Be < B < C but the first
ionisation potential of Be is higher than that of B because Be has fulfilled configuration.
(iii) Metallic character increases hence the basic character of oxide increases.
(iv) In a group form top to the bottom, the number of the shell increases hence radius
increases.
5. (A)
Sol. The acidic character of hypohalous acid depends on the electronegativity of halogen. As the
electronegativity value of halogen increases the acidic strength of hypohalous acid increases.
Here, Electronegativity of atom X (Cl, Br or I) attached to O decreases down the group, polarity
of OH bond decreases, acid strength decreases. It means more the electronegativity of the
halogen atom, more the tendency to pull electron and weaker the O–H bond and hence proton
(H+) can easily be removed.

6. (B)
Sol. Ionisation energy of carbon group follows the order C > Si > Ge > Pb > Sn. IEPb > IESn because
of poor shielding effect of electrons resulting in lanthanide contraction.
7. (D)
Sol. 20Ca = 2, 8, 8, 2
2+
Ca = 2,8,8
Hence, Ca2+ has 8 electrons each in outermost and penultimate shell.
8. (D)
Sol. Fe+ (26 ) = [Ar] 3d6, 4s1
Mn+(25 ) =[Ar] 3d5, 4s1
V+ (23) = [ Ar] 3d2 , 4s2
Cr+ (24)= [Ar] 3d5 [ By first IP]
The electronic configuration of Cr+ is most stable hence formation of Cr2+ by second IP
requires maximum enthalpy.
9. (A)
Sol. Ba < Ca < Se < S < Ar
Ba, Ca belong to gr llA ( alkaline earth metals)
Se and S belong to gr VI A (Chalcogens) and as we go down the group ionaization enthalpy
decreases with increasing atomic size. So, Ba < Ca and Se < S
Ar has stable completely filled electronic configuration and, therefore,has higest ionization
enthalpy.Hence,the correct order is
Ba < Ca < Se < S < Ar
–1
In kJ mol 503 590 941 999 1520
10. (B)
Sol. Acidic oxides:
SO2, NO2, SO3, SiO2, Cl2O7
11. (A)
Sol. Correct order of electron gain enthalpy is :
O < S > Se > Te
 S > Se > Te > O
(Oxygen shows least electron gain enthalpy due to small size of atom)
12. (A)
Sol. Na [Ne] 3s1 IE1 is very low but IE2 is very high due to stable noble gas configuration of Na+.
Mg  [Ne] 3s2 IE1 & IE2  Low
IE3 is very high.
13. (C)
Sol. Order of electron gain enthalpy (Absolute value)
Cl > F > Br > I

METALLURGY
1. (B)
Sol. A movable heater is fitted around a rod of impure metal. As heater is moved from one end to
another pure metal crystallises while impurities pass on to adjacent melted zone.
2. (C)
Sol. Because Na is very reactive and can not be extracted by means of the reduction by C, CO etc.
So, it is extracted by electrolysis of molten NaCl Solution
3. (C)
Sol. Cryolite is used to lower the meeting point of alumina (Al2O3) as well as to make it good
conductor of electric current.
4. (B)
Sol. Reduction with carbon is called smelting
Fe2O3 + 3C  2Fe + 3CO
5. (B)
Sol. We know that smelting is reduction with carbon, Here Fe2O3 with the help of carbon.
6. (C)
Sol. Basic copper carbonate
Cu(OH)2 CuCO3 is Malachite green
[ CuFeS2- copper pyrite]
[ Cu2S- copper glance]
7. (C)
Sol. In anode mud, less electropositve elements are present. Ag and Au are less electropositive
than Cu.
8. (B)
Sol. Al is highly electropositive. It can be obtained by electrolytic reduction.
9. (D)
Sol. Cryolite (Na3AlF6)  Halide ore
Galena (PbS) 
 Sulphide ore
Cinnabar(HgS)
Bauxite Al2O3. 2H2O  Oxide ore
10. (A)
Sol. Lime stone acts as flux in this process.
CaCO3CaO+ CO2
CaO + SiO2CaSiO3(slag)

11. (D)
Sol. (i) Molten mixture of alumina and cryolite
(ii) 2PbS + 3O22Pb + 2SO2 (self-reduction)
PbS + 2PbO  3Pb + SO2 (Self reduction)
PbO + C  Pb + CO (carbon reduction)
(iii) SnO2 + C  Sn + CO (carbon reduction
(iv) siderite = FeCO3, cassiterite = SnO2 and argentite = Ag2S.
12. (B)
Al2O3(s) + 2NaOH(aq.) + 3H2O()
Sol.
2Na[Al(OH)4](aq.) X
CO2 Y
Al2O3.xH2O(s) + 2NaHCO3(aq.)
Z
So
X : Na[Al(OH)4]
Y : CO2
Z : Al2O3.xH2O
13. (A)
Sol. Sphalerite ore : ZnS
Calamine ore : ZnCO3
Siderite ore : FeCO3
Malachite ore : Cu(OH)2.CuCO3
It is possible to separate two sulphide ores by adjusting proportion of oil to water or by
using 'depressants'. In case of an ore containing ZnS and PbS, the depressant used is
NaCN.
14. (B)
Al2O3(s) + 2NaOH(aq.) + 3H2O()
Sol.
2Na[Al(OH)4](aq.) X
CO2 Y
Al2O3.xH2O(s) + 2NaHCO3(aq.)
Z
So
X : Na[Al(OH)4]
Y : CO2
Z : Al2O3.xH2O

CHEMICAL BONDING
1. (D)

Sol. Azide ion N3 has linear shape and bond order = 2, same as CO2
2. (D)
I

I
Sol.
I
Shape : Linear, I–I–I Bond angle  180°
3. (C)
X
A X
Sol.
X
3
sp d hybridised
t-shaped
4. (B)
Sol. Lewis base : Chemical species which has capability to donate electron pair.
In NF3, SF4, ClF3 central atom (i.e. N, S, Cl) having lone pair therefore act as lewis base.
In PCl5 central; atom (P) does not have lone pair therefore does not act as lewis base.
5. (C)
X
A X
Sol.
X
3
sp d hybridised
t-shaped
6. (B)
Sol. Lewis base : Chemical species which has capability to donate electron pair.
In NF3, SF4, ClF3 central atom (i.e. N, S, Cl) having lone pair therefore act as lewis base.
In PCl5 central; atom (P) does not have lone pair therefore does not act as lewis base.

COORDINATION COMPOUNDS
1. (C)
Sol. As EDTA is hexadentate ligand. Hence, only one EDTA (ethylenediaminetetraacetate molecule
2+
is required to make an octahedral complex with Ca .
2. (A)
Sol. 1. [Cu(NH3)4][PtCl4]
2. [Cu(NH3)3Cl][PtCl3(NH3)]
3*. [Cu(NH3)2Cl2][PtCl2(NH3)2] – cis isomer
4*. [Cu(NH3)2Cl2][PtCl2(NH3)2] – trans isomer
5. [Cu(NH3)Cl3][Pt(Cl)(NH3)3]
6. [Pt(NH3)4][CuCl4]
* These isomers would not exist as charge on the cation& anion would be zero.
3. (B)
Sol. Zeisesalt : K[PtCl3 (2 – C2H4)]
 - electrons of ethylene bond by way of  - bonding ot Pt.
4. (A)
Pt Py NH3  BrCl
Sol. can have three isomers.
Py NH3 Py Br Py NH3
Pt Pt Pt
Cl Br Cl NH3 Br Cl
(i) (ii) (iii)
5. (D)
Sol. [Ni(H2O)5NH3]2+ does not show any isomerism
[Ni(H2O)4(NH3)2]2+ shows cis-trans (geometrical isomerism)
6. (D)
Sol. The magnitude of 0 varies from stronger to weaker ligand. According to spectrochemical
series, F– is a weaker ligand while NH3 is a stronger ligand.Stronger ligand gives a larger value
[CoF6 ]3
ofHence, among the given complexes is expected to have lowest value of 0 value.

7. (A)
Sol. 28Ni has +2 oxidation state and since the complex is Diamagnetic, all electrons are paired in
inner 3d, orbital to provide the electronic configuration as under:
28Ni  18[Ar] 3d
8 4s 4p
dsp2
hybridisation
L might have been a strong field like CN.
Hybridisation is dsp2. Number of unpaired electron = 0.
8. (B)
2
Pt  NH3 4 Cl2 
Sol. has 2 geometrical isomers.
2
Pt  gly 3 
will have 2 geometrical isomers, both of which will be optical active, giving a total
of 4 isomers.
4
Pt  en3 
Will have no geometrical isomers, but the compound will be optically, hence total
two isomers.
Pt  NH3 3 Cl2 
will have two geometrical isomers
9. (D)
Sol. NCS is the strongest ligand among Cl–, Br– and I–.
10. (C)
Sol. [NiCl4]2– Ni is 3d series element
Cl– weak ligand
 High spin
[PtCl4]2– Pd is 4d series element
Low spin
[PdCl4]2– Pt is 5d series element
Cl– act as strong field ligand for Pt and Pd as they are 5d, 4d elements respectively with
high effective nuclear charge.
11. (D)
Ionisation
  
Sol. [Co(en)2Cl2]Br [Co(en)2ClBr]Cl
en Cl
Cl
Co Br en Co en Br
Cl
en Cl
cis trans
Cis-isomer is optically active.


12. (B)
3–
Sol. Mn  Ox 3  is a high spin complex.
13. (A)
Sol. Vitamin B12 contains Co.
BLOCK (S, P, D & F) CHEMISTRY

1. (C)
Sol. The basic strength of the hydroxides decreases as we move from cerium to lutetium Also the
lanthanoid hydroxides are more basic than Al(OH)3 but less basic than Ca(OH)2. B(OH)3 is
more covalent than Al(OH)3. Be(OH)2 is as covalent as Al(OH)3. B(OH)3 is acidic while Be(OH)2
and AI(OH)3 are amphoteric while all others are more basic than AI(OH)3. Hence choice (B) is
correct while (A),(B) and (D) are incorrect.
2. (D)
Sol.
O
O O
O
O O
O P P
O O
3. (B)
1
V  M  C  A
Sol. H= 2
1
8  4   6
= 2
3 2
sp d hybridiztion
4 B.P + 1 B.P (Doubly bounded) + 1L.P Square pyramidal
F F
Xe
F F
O
Oxygen atom doubly bounded to Xe lone pair of electrons on axial position.

4. (B)
Sol. (a) (sp3d)
O –
O
Xe
–
O
O
  
(b) (sp3d) F – Xe – F
   
all atoms carry 3 long pair each.
(c)(sp3d2)
O –
– O
O
Xe
– –
O O
O
(d)(Lewisstructure)
+
O
–
O O
5. (C)
Sol. H3P3O9 is a cyclic trimetaphosphoric acid.
O OH
P
O O
O
O
O P
O OH
OH
P
Structure of H3P3O9
6. (B)
O O
H2 S2O6 , H – O – S – S – OH
Sol. O O 4-bonds ;
O
H2 SO3, HO – S – OH one p-bond ;
O
H2 S2O5 , HO – S – S – OH
O O 3-bonds ;

7. (B)
CF3 CH3 CF3 CH3
Sol.
P P
CF3 CH3 H3C CH3
CF3 CF3
µ0 µ= 0
8. (B)
Sol. The bond order of carbon-carbon bond is 1.5 in benzene.
Hence, carbon-carbon bond distance
(1.397 Å) is less than C = C single bond
(1.33 Å) and more than C = C double bond (1.33 Å)
9. (B)
Sol. Beryl is a mineral composed of beryllium aluminum cyclic silicate with the cemical formula
Be3Al2(SiO3)6.
10. (A)
Sol. Stability of peroxides of group-2 elements increases down the group.
11. (C)
Sol. -character is due to 3d  2p back bonding between 3d orbital of Si and 2p orbital of N.
12. (C)
*2p  2, 1s
*
1
Sol. Number of Nodal planes in
13. (A)
Sol. Li is much softer than the other group first metals. Actually, Li is harder than other alkali
metals.
14. (B)
Sol. This problem is based on preparation of inorganic benzene and structural charactristics of
diborane. Student must be familiar with concept of bonding in diborane to solve this problem.
Identify the compounds and complete the chemical reaction using information supplied in the
question.
Low temperature 473K
B2 H 6  2NH 3  excess   
B2 H 6  2NH 3 
 B3 N 3 H 6
x borozole( y )
Y has structure similar to benzence (inorganic benzene)

High temperature
B2 H6  NH3  excess   
   BN  X
boron nitride  Z

15. (A)
Sol. (i) In the laboratory, dinitrogen is prepared by treating an aqueous solution of ammonium
chloride with sodium nitrite.
4 2 2 2
NH Cl(aq) + NaNO (aq)  N (g) + 2H O(l) + NaCl(aq)
3
Small amounts of NO and HNO are also formed as impurities, which can be removed by
passing the gas through aqueous sulphuric acid containing potassium dichromate.
(ii) Dinitrogen can also be prepared by heating ammonium dichromate

4 2 2 7   2 2 2 3
(NH ) Cr O (s) N (g) + 4H O(l) + Cr O (s)
3
(iii) Copper metal reacts with dilute HNO to form nitrogen (ii) oxide (NO)
3 3 2 2
3Cu(s) + 8HNO (dilute)  3Cu(NO ) (aq) + 2NO(g) + 4H O(l)
3 2
(iv) Copper metal reacts with conc. HNO to form nitrogen (IV) oxide or nitrogen dioxide (NO ).
3
Cu(s) + 4HNO (conc.)
3 2 2 2
Cu(NO ) (aq) + 2NO (g) + 2H O(l)

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68

MOLE CONCEPT (PHYSICAL CHEMISTRY)

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IUPAC & GOC (ORGANIC CHEMISTRY)

1. What is the correct order of acidic strength in following compounds ?

2. The ionistation constant of phenol is higher than that of ethanol because

3. Which one is more acidic than Phenol

4. Find the order of Ka of following compounds :

COOH COOH COOH

5. Order of Ka of following acids is :

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8. Mesityl oxide is a common name of :

9. In the following molecules,

10. Which one of the following compounds is nonaromatic ?

12. The correct order of acid character of the following compounds is :

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PERIODIC TABLE (INORGANIC CHEMISTRY)

3. Which of the following oxides are acidic ?

6. Which among the following elements have lowest value of IE1?

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11. The correct order of electron gain enthalpy is

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ATOMIC STRUCTURE (PHYSICAL CHEMISTRY)

4. An element undergoes a reaction as shown :

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8. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain

10. The ratio of minimum to maximum wavelengths in Balmer series of H-atom is

11. According to Bohr's atomic theory :-

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Temperature (K) Wavelength

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ISOMERISM (ORGANIC CHEMISTRY)

1. Which type of isomerism is present between compound

2. Which of the following set is not the example of positional isomerism.

3. Given compound shows following type of isomerism OHCCH2CH2CN and OHCCH(CH3)CN

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8. Identify the compound having highest enol content ?

9. The absolute configuration of the compound is :

12. Compound with molecular formula C3H6O can show :

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METALLURGY (INORGANIC CHEMISTRY)

1. The method of zone refining of metals is based on the principle of

2. Electrometallurgical process is used to extract

3. Electrolytic reduction of alumina to aluminium by Hall-Heroult process is carried out

5. Which of the following process involves smelting ?

6. Which one of the following ores is known as Malachite :

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9. An example of halide ore is

11. Which of the following statements incorrect?

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REDOX REACTION (PHYSICAL CHEMISTRY)

1. Consider the following three halides:

5. A redox reaction always involves

7. In the mixture of (Na2CO3 + NaHCO3) volume of HCl required is x mL with phenolphthalein

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9. H2O2 acts as an oxidizing agent in

10. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M Kand 10 mL of

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HYDROCARBON (ORGANIC CHEMISTRY)

1. Which statement is incorrect about photochemical chlorination of the following compound,

Ph  CH2  CH2  CH3

(A) The major product will be chiral and a racemic mixture