Nama : Luky Desyana Putri Ramadhani

NIM : 19/445655/PA/19479

Kelas :A

Self test 6.3

For a particular reaction from A  B + 2H+ in aqueous solution, it was found that ∆𝑟𝐺 θ = +20kJ
mol-1 at 28oC. Estimete the value of ∆𝑟𝐺⊕.
Diket : A  B + 2H+
T = 28oC = 301,15 K
R = 8,3145 J/mol. K
v = -2
Ditanya : ∆𝑟𝐺 ⊕ ?
Jawab : ∆𝑟𝐺⊕ = ∆𝑟𝐺 θ + 7vRT ln 10
∆𝑟𝐺⊕ = +20kJ mol-1 + 16,1 x 1 (8,3145 x 10-3 kJ K-1 mol-1) x (301,15K)
= 61 kJ/mol
Modifikasi Self test 6.3
For a particular reaction from A  B + 2H+ in aqueous solution, it was found that ∆𝑟𝐺 θ = +30kJ
mol-1 at 30oC. Estimete the value of ∆𝑟𝐺⊕.
Diket : A  B + 2H+
T = 30oC = 303,15 K
R = 8,3145 J/mol. K
v = -2
Ditanya : ∆𝑟𝐺 ⊕ ?
Jawab : ∆𝑟𝐺⊕ = ∆𝑟𝐺 θ + 7vRT ln 10
∆𝑟𝐺⊕ = +30kJ mol-1 + 16,1 x 1 x (8,3145 x 10-3 kJ K-1 mol-1) x(303,15K)
=71 kJ/mol
Self test 6.4
Predict the effect of tenfold pressure increase on the equilibrium composition pf the reaction
3N2(g) + H2(g)  2N3H(g).
Diket : 3N2(g) + H2(g)  2N3H(g)
P1 = 1 bar
P2 = 10 x P1 = 10 bar
Ditanya : Pengaruh terhadap komposisi kesetimbangan ?
Jawab :

1
K = Kx
102

Kx = 100 K
Modifikasi Self test 6.4
Predict the effect of thirtyfold pressure increase on the equilibrium composition pf the reaction
3N2(g) + H2(g)  2N3H(g).
Diket : 3N2(g) + H2(g)  2N3H(g)
P1 = 1 bar
P2 =30 x P1 = 30 bar
Ditanya : Pengaruh terhadap komposisi kesetimbangan ?
Jawab :

1
K = Kx
302

Kx = 900 K
Self Test 6.5

The equilibrium constant of the reaction 2SO2 (g)+ O2 (g)↔2SO3 (g) is 4.0 𝑥 1024 300 K,
2.5 𝑥 1010 at 500 K, and 3.0 𝑥 104 at 700 K. Estimate the reaction enthalpy at 500 K.

Answer :

T 300 500 700

K 4.0 𝑥 10 24
2.5 𝑥 10 10
3.0 𝑥 104
Ln K -56,6 -23,94 -10,31
1/T 0,003 0,002 0,0014

Grafik 1/T Vs ln K
0
0 0,0005 0,001 0,0015 0,002 0,0025 0,003 0,0035
-10

-20
ln K

-30

y = -24364x + 24,616
-40
R² = 1

-50

-60
1/T

Slope : -24364
Persaman garis : y = -24364 x + 24,616

∆𝑟 𝐻 0
Slope = 𝑅

∆𝑟 𝐻 0
-24364 K = 𝑅
𝐽
∆𝑟 𝐻 0 = -24364 K x8,3145 𝐾𝑚𝑜𝑙
𝒌𝑱
∆𝒓 𝑯𝟎 = -202 𝑲𝒎𝒐𝒍

Modifikasi Self Test 6.5

The equilibrium constant of the reaction 2SO2 (g)+ O2 (g)↔2SO3 (g) is 4.0 𝑥 1024 250 K,
2.5 𝑥 1010 at 450 K, and 3.0 𝑥 104 at 650 K. Estimate the reaction enthalpy at 500 K.

Answer :

T 250 450 650

K 4.0 𝑥 10 24
2.5 𝑥 1010
3.0 𝑥 104
Ln K -56,6 -23,94 -10,31
1/T 0,004 0,0022 0,0015

Grafik 1/T Vs ln K
0
0 0,0005 0,001 0,0015 0,002 0,0025 0,003 0,0035 0,004 0,0045
-10

-20
ln K

-30

-40

-50
y = -18739x + 18,177
R² = 0,9997
-60
1/T

Slope : -18739
Persaman garis y = -18739x + 18,177
∆𝑟 𝐻 0
Slope = 𝑅

∆𝑟 𝐻 0
-18739K = 𝑅
𝐽
∆𝑟 𝐻 0 = -18739 K x8,3145 𝐾𝑚𝑜𝑙
𝑘𝐽
∆𝑟 𝐻 0 = -155,8 𝐾𝑚𝑜𝑙

Self-test 6.6
The equilibrium constant for N2 O4 (g)↔2NO2 (g) was calculated in Self-test 6.1. Estimate its value
at 100°C

∆𝑟 𝐻 0 = 2∆f H(NO2 g) − ∆f H(N2 O4 g)

kJ kJ
= 2 × (+33,18 mol − (+9,16 mol ))

kJ
= +57,2 mol

J
∆𝑟 𝐻 0 = 57200 mol

Menentukan nilai K

∆𝑟 𝐻 0 1 1
ln K2 - ln K1 = - (𝑇2 − 𝑇1)
𝑅

+57200 𝐽/𝑚𝑜𝑙 1 1
ln K2 - ln 0,15 = -8,3145 𝐽/𝐾𝑚𝑜𝑙 (373𝐾 − 298𝐾)

Ln K2 + 1,8971 = -6.879,55 (0,00268096515-0,0033557047)

ln K2 = 2,744

K = 15,54

Modifikasi Self-test 6.6

The equilibrium constant for N2 O4 (g)↔2NO2 (g) was calculated in Self-test 6.1. Estimate its value
at 100°C.
∆𝑟 𝐻 0 = 2∆f H(NO2 g) − ∆f H(N2 O4 g)
kJ kJ
= 2 × (+33,18 mol − (+9,16 mol ))
kJ
= +57,2 mol
J
∆𝑟 𝐻 0 = 57200 mol

Menentukan nilai K
∆𝑟 𝐻 0 1 1
ln K2 - ln K1 = - 𝑅
(𝑇2 − 𝑇1)
 +57200 𝐽/𝑚𝑜𝑙 1 1
ln K2 - ln 0,15 = -8,3145 𝐽/𝐾𝑚𝑜𝑙 (373𝐾 − 473𝐾)

Ln K2 + 1,8971 = -6.879,55 (0,00268096515-0,0021141649)

ln K2 = -5,796
K = 0,003