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[Physics]
1.(3) Potential difference between two faces perpendicular to x-axis will be
l (V B) = 12 mV
N2 = N0e – t
1 N1
= = e−9t
e N2
9t = 1 t = 1/9
v = 960 40 10–2
4.(1) P = I 2 R
4.4 = 4 10–6 R
R = 1.1 106
112 112
P = = 10−6 = 1110−5W
R 1.1
12500
5.(4) Energy of photon = = 12.75 eV
980
Electron will excite to n = 4
Since, ‘R’ n
2
–1
6.(2) For adiabatic process : TV = constant
7
For diatomic process : –1 = −1
5
x = 2/5
u 2 2sin cos
R=
g
R2
= 16
h1h2
0.61
8.(1) Numerical aperture of the microscope is given as, N A =
d
Where d = minimum separation between two points to be seen as distinct.
1 sin60 = sin30
= 3
Optical path = AO +(OB)
a b
+ 3 = 2a + 2b
cos60 cos30
f f f
10.(4) Energy = nRT = PV = (3106 ) (2)
2 2 2
= f 3106
f=3
E = 9 106 J
I Magnetic moment
11.(3) = ; I=
H Volume
20 10−6
I= −6
= 20 N / m2
10
20 1
= +3
= 10−3
60 10 3
12.(1) = 6 1014 2
f = 6 1014
C = f
C 3 108
= = = 5000 Å
f 6 1014
12375
Energy of photon = = 2.475 eV
5000
KEmax = E –
eVs = E –
eVs = 2.475 – 2
eVs = 0.475 eV
13.(1)
v + v0
f = f
v − vs 0
340 + (−20)
2000 = f ; f = 2250 Hz
340 − (−20) 0 0
14.(4) Since height of water column is constant.
h = (1/20) m = 5 cm
GMe
15.(3) Orbital velocity, V =
r
1 1
TA = mAVA2 , TB = mBVB2
2 2
Gm
TA m R
= =1
TB 2m Gm
2R
16.(4) Q = 2 (BE of He) – (BE of Li)
= 2 × (4 × 7.06) – (7 × 5.60)
By Snell’s law,
1 3
1 sin i = 3 = ; i = 60
2 2
18.(4) Since unpolarised light falls on P1
P1 = I0 /2
I0 3I
P2 = cos2 30 = 0
2 32
Pass axis of P3 is at an angle of 60º with P2
3I0 3I
P3 = cos2 60 = 0
8 8
I0 32
= = 10.67
I 3
19.(2)
v v
2v0 = 2 0 + mv 2v0 = 0 + mv
4 2
3v0
= mv … (i)
2
Since collision is elastic
Vseparation = vapproch
v0
v− = v0
4
5v0
=v … (ii)
4
Equation (ii) and (i)
3v0 5v
= m 0
2 4
6
m= = 1.2 kg
5
20.(4) Suppose M is mass and a is side of larger triangle, then M/4 and a/2 will be mass and side length of
smaller triangle.
2
M a
2
2 ; I removed = 0
I removed I
= 4
Ioriginal M (a) 16
I0 15I0
I = I0 − =
16 16
= 10sin 3t +
3
Amplitude = 10 cm
2 2 2
T= = = sec
3 3
22.(3) At saturation state, VCE becomes zero
10V
ic = = 10mA
1000
i
Now current gain factor = C
iB
10mA
iB = = 40A
250
23.(2) Since mass of the object remains same.
Wearth 9 gearth
Given, = =
Wplanet 4 g planet
GM
Also, g surface = (M is mass planet, G is universal gravitational constant, R is radius of planet)
R2
2
9 GM earth R planet
= 2
4 GM planet Rearth
2 2
M R R
= earth planet
2
= 9 planet
2
M planet Rearth Rearth
Rearth R
Rplanet = =
2 2
1 1 1 20
24.(4) For first lens, − = ;V=
V −20 5 3
For second lens,
20 14 1 1 1
V= −2 = ; − =
3 3 V 14 / 3 −5
V = 70 cm
25.(3) Given initial velocity u = 0 and acceleration is constant
At time t, v = 0 + at
v = at
1 2
Also x = 0 (t ) + at
2
1
x = at 2
2
T 8
V= = 1000 = 40 m/s
5
v 40
Now, wavelength of wave = = m
n 100
Separation between successive nodes,
20
= m = 20 cm
2 100
27.(2)
40 + f = m (R) … (i)
40 R – f R = mR2
40 – f = mR … (ii)
40
= = 16
mR
28.(2)
29.(2) Fthrust − mg = ma
Fthrust = 150000 N
dm
Fthrust = Urel
dt
dm
(−800) = 150000
dt
dm
−187.5 kg /s
dt
amount of gas ejected per second = 187.5 kg/s
30.(3)
/3 1
t= = = sec = 3.3 ms
100 300
31.(2) Path difference = d sin d
(from n = 4)
12F 2 1
cos = − 2
=−
24F 2
33.(1) K.E. = qV
2mqV m rp 1
r= ;r ; =
qB q r 2
x
34.(4) i = ; i 12r =
13r L 2
x 13L
12r = x =
13r L 2 24
qE 5 10−6 2000
35.(3) tan = =
mg 2 10−3 10
1
tan = = tan −1 (0.5)
2
36.(3)
1 3
0 + 150 iˆ + ˆj + 100 iˆ
rcm = 2 2
300
7ˆ 3ˆ
rcm = i+ j
12 4
7 3
Co-ordinate =
12 , 4 m
37.(4) Magnetic field at ‘O’ will be because of ‘PS’ and ‘QN’ only
0i 0i
B0 = +
4d 4d
0i 2 10−7 i
or 10−4 = =
2d 4 10−2
i = 20 A
38.(4) Electric field of equitorial plane of dipole
KP
=−
r3
KP KPQ
At P, F = − Q; P, F = − = 27 F
r3 (r / 3)3
1 2
KE 2 mv
39.(3) P = =
t t
dx
v t ; t
dt
x t 3/2
P hg
40.(4) = =
(−V / V ) (−V / V )
C = /
C = [ML2T –2 ]
42.(3) Q = T 4
4
Q1 T1 273 + 27
4
= =
Q2 T2 273 + 177
4 4
300 2 16
= = =
450 3 81
43.(1)
Various forces acting on the system are shown in the figure. For vertical equilibrium of the system,
f B = 100 N + 20 N = 120 N
h h
44.(4) = =
p 2mK
K
→ 2 K →
4
45.(3)
2T sin = Tdl
2T = T (2 R)
Tension T = RT
Q2 Q2
46.(4) The coefficient of performance of a refrigerator is given by = =
W Q1 − Q2
Where,
Q2
=
Q1 − Q2
1 Q2
Substituting the given values, we get =
3 200 − Q2
200 − Q2 = 3Q2
200
4Q2 = 200 Q2 = J = 50J
4
W = Q1 − Q2 = 200 J − 50 J = 150 J
ms A (t − t A ) = msB (tB − t )
4s A = 3sB
IInd Case
4sB = 5sC
15
3sB = s
4 C
15
4sA = 3sB = s
4 C
1 1 1
sA : sB : sC = : :
16 12 15
k k
sA = , sC =
16 15
When A and C are mixed
ms A (t − t A ) = msC (tC − t )
k k
(t −12) = (28 − t )
16 15
15t −180 = 448 −16t
31t = 628
t = 20.2C
3RT
48.(1) vrms =
M
v2 T
= 2 =
( 273 + 90) = 1.1
v1 T1 ( 273 + 27 )
v
= 2 − 1 100 = 0.1100 = 10%
v1
49.(2) Capacitance of two capacitors each of area A/2, plate separation 𝑑 but dielectric constants
K1 and K2 respectively joined in parallel.
A A
K10 K20
C1 = 2+ 2
d /2 d /2
=
( K1 + K2 ) 0 A
d
It is in series with a capacitor of plate area A, plate separation d/2 and dielectric constant K3 ie,
K30 A
C2 =
d /2
K 0 A
If resultant capacitance be taken as C =
d
1 1 1
= +
C C1 C2
d d d /2
= +
K 0 A ( K1 + K2 ) 0 A K30 A
1 1 1
= +
K K1 + K2 2K3
v2
50.(1) Acceleration = r = = v = 2v/T
2
r
[Chemistry]
51.(2) Strength of H2O2 = N × eq. wt.
= 1.5 × 17 = 25.5
2H2O2 → 2H2O + O2
(2 34 = 68 gm) (22.4 lit.)
22.4
25.5 gm produce 25.5
68
= 8.4 litres of oxygen
52.(4) Sublimation is the best method for those organic compound which pass directly from solid to vapour
state on heating and vice-versa on cooling.
Naphthalene is volatile and Benzoic acid is Non-volatile, due to formation of dimer via
H-bonding (Intermolecular).
54.(4)
A = Na,B = H2 ,C = NaOH,D = Zn
Zn + 2NaOH → Na 2ZNO2 + H2
(D) (C) (B)
56.(1) In case of IA and IIA group compounds, the thermal stability of carbonates increases down the
group as the ionic radius of cation increases and polarizing power decrease.
57.(2)
− bonds = 10
− bonds = 3
58.(3)
1-chloro-1-methyl chycloxane
59.(1)
OR
OR
● Ph − Ph → Biphenyl
3a
(r + ) + (r − ) =
2
r + = Radius of cation
r − = Radius of Anion
a = Edge length
3 387
r + r = = 335.15 pm 335 pm
2
62.(1) For isotonic solution
C1RT = C2RT
w1 w 2
n1 = n 2 =
m1 m2
5 1
=
342 m2
342
m2 = = 68.4 gm
5
63.(3) Tf = i k f m
Salt i
● KCl 2
● C6H12O6 1
● Al2 (SO4 )3 5
● K2SO4 3
64.(1) Less positive the value of reduction potential, stronger will be the R.A. thus I is strongest R.A.
More positive the value of reduction potential shows good oxidizing property thus strongest O.A. is
F2 .
M
MnO4− → Mn 2+ ; n.f. = 5 ; E =
5
Basic medium:
M
MnO4− → MnO24− ; n.f. = 1; E =
1
66.(1) ● Molar conductance of NH4OH
● Molar conductance of NH4OH at infinite dilution ( ) = 238 −1 cm2 mol−1 of NH4OH
So degree of dissociation ( )
c 9.54
%=
100 = 100 = 4.008%
238
0.059 [Zn 2+ ]
67.(2) Ecell = Ecell − log
n [Cu 2+ ]
0.059 0.01
E1 = E − log
2 1
0.059
E1 = E − log 10−2
2
E1 = E + 0.059
0.059 1
E2 = E − log = E − 0.059
2 0.01
E2 = E − 0.059 E1 E2
r = K[A]a [B]b
[A] = constant
a = 1, b = 2
So r = K[A]1 [B]2
P
70.(4) x/m correct relation
T
= 24 B.M
= 15 B.M
= 35 B.M
= 8 B.M
72.(1) K2Cr2O7 + 4H2SO4 → K2SO4
74.(4)
75.(4)
m-Bromoanisole gives only the respective meta substituted aniline. This is a substitution reaction
which goes by an elimination addition pathway.
76.(1) There are two non-super impossible mirror images of each other, so they are enantiomers.
77.(3)
78.(3)
79.(3)
80.(3) As the compound is giving yellow ppt with NaOI that shows it is undergoing haloform reaction.
Haloform reaction is shown by the compounds having.
Hence compound A -
82.(3)
84.(3)
Ease of hydrolysis depends upon the magnitude of the charge on the carbonyl group. EWG es
the magnitude of the charge and ERG ee magnitude of the charge.
85.(3)
HVZ in this reaction, acids containing − H reacts with X2 | Red P giving product in which the
-hydrogen are substituted by X.
+ POCl3 + HCl
87.(3)
88.(1) →
CH3NH2 + 2KBr + K2CO3 + 2H2O
89.(1)
+− D − Fructose
91.(3) In the lipid metabolism, a molecule of palmitic acid (C15H31 − COOH) produces 130 adenosine
triphosphate molecules.
92.(3) Aspirin is acetyl salicylic acid, which is formed by acetylation of o-hydroxybenzoic acid.
94.(4)
1 1 1
= R H Z2 2 − 2
n1 n 2
[In − ]
pH = pK a + log
[HIn]
3 / 4
pH = 7 + log
1/ 4
3 4
pH = 7 + log
4 1
pH = 7 + log3
pH = 7 + 0.47
pH = 7.47
97.(3) Phenyl – methyl ether
Methyl phenyl oxonium ion
– O — CH3 bond weaker than O — C6H5 bond as O — C6H5 has partial double bond character.
Step – I
Step – II
98.(3) Adrenaline hormone helps to release fatty acids from fat and glucose from liver glycogen under the
condition of stress also called 3F hormone.
100.(4)
In this defect, equal number of cation and anions are missing from the lattice, so the crystal remains
neutral.