Sample Calculations:

Case I:
1
87.88

Time (s)

a=

( 0.10 M ) (10 mL)

100 mL

c=

( 0.01 M ) (2 mL)
100 mL

a-

c
2

3
51.03

4
38.95

5
36.54

= 0.01 M

= 0.0002 M

0.002 M
2

0.01 M

= 9.9 x 1 0

c
3
2 ) = log (9.9 x 1 0 ) = -2.0044

log (a -

c
2t

2
63.49

log ( 2 t

0.0002
2( 87.88)

)=

= 1.1379 x 1 0

log (1.1379 x 1 0

) = -5.9439

Linear Regression:
x [ log (a -2.0044
-1.8268
-1.7011
-1.6038
-1.5243
Slope = m = 0.8242

c
2 )]

y [log ( 2 t )]
-5.9439
-5.8027
-5.7078
-5.5905
-5.5628

y-intercept = log

r2

k'
k'

y-intercept = log

-4.2939 = log
'

k'

= -4.2939

= 0.99

k from

'

= -4.2939

k'
5

= 5.0828 x 1 0
n

= k[b

5.0828 x 1 0

= k[0.02

k = 0.1270747891

Case II:
Time (s)

a=

b=

c=

1
169.97

( 0.10 M ) (10 mL)

100 mL
( 0.10 M ) (10 mL)
100 mL
( 0.01 M ) (2 mL)
100 mL

2
114.01

= 0.01 M

= 0.01 M

log (b) = log(0.01) = -2

2x1 0

3
90.97

4
75.72

5
61.87

c
2t

2 x 10
2(169.97)

= 5.8832 x 1 0

log( 2 t ) = log (5.8832 x 1 0

log

k' '

) = -6.2304

= -4.4296

c m

k' '

= k[a -

k' '

= 3.7188 x 1 0
5

3.7188 x 1 0

= k [0.01 -

K = 3.7563 x 1 0

2 x 1 04 1

Linear Regression:
x [ log (b)]

y [log ( 2 t )]
-2
-1.8239
-1.6990
-1.6021
-1.5229
Slope = m = 0.8937
y-intercept = -4.4296

r2

= 0.9987

-6.2304
-6.0569
-5.9589
-5.8792
-5.7915

Effect of Temperature:
1
213.08

Time (s)

a=

( 10 mL ) (0.1 M )
100 mL

= 0.01 M

b=

( 20 mL ) (0.1 M )
100mL

= 0.02 M

c=

( 0.010 M ) (2 mL)
100mL

a-

c
2t

c
2

0.0002
2

= 0.01

= k [b

= 0.0002 M

[a - 2

= 0.009

; n=2, m =1

k = 0.1185
ln(k) = ln(0.1185) = -2.1328

1
T

ln(k) =

1
288.15
Ea
R

= 3.47 x 1 0

( T

) + In(A)

y-intercept = ln(A)
15.6275 = ln(A)
A = 6122615.913
Slope =

Ea
R

= -5132.4689 =

Ea = 42671.346

E a
8.314

3
90.97

4
75.72

5
61.87

Linear Regression:
x[

1
T ]

y [ln(k)]

3.47 x 1 0

-2.1337

3.35 x 1 0

-1.7142

3.30 x 1 0

-1.2455

3.25 x 1 0

-1.0689