B a i 13: Cho 1,35 gam hon hop gom Cu, Mg, A l tac dung het vdi dung

dich HNO3 thu duac h5n hdp k h i gom 0,01 mol NO va 0,04

Tinh khoi laang muoi tao ra trong dung dich.

A. 10,08 gam.

B. 6,59 gam.

C. 5,69 gam.

Hit&ng dan

mol NO2.

B a i 14: Cho 1,35 gam hon hap A gom Cu, Mg, A l tac dung vdi HNO3 du
dirac 1,12 l i t hon hop X gom NO va NO2 (dktc) c6 khoi lucfng mol
trung binh la 42,8. Tong khoi lUcJng muoi nitrat sinh ra la:
A. 9,65 gam

D. 5,96 gam.

Cdch 1: n^=

Dat X, y, z Ian lifcft la so mol Cu, Mg, A l .

Cu'^ + 2e

Mg ^

x ^ x - ^ 2 x
Thu e: N + 3e ^

Mg'^ + 2e

y - > y - > 2 y

N (NO)

N + le ^

0,03 <- 0,01

0,04

Al

C. 4,24 gam

Hit&ng dan

gidi

Cdch 1:
Nhi/dng e: Cu ^

B. 7,28 gam

22,4

D. 5,69 gam

gidi

= 0,05mol

Lap scf do dtfdng cheo nhiT bai tren ta tinh di/ac so mol NO va NO2
Ian Itrat la 0,01 va 0,04 mol.

A l ' " + 3e

z->z->3z

Ta CO cac ban phan ufng:

NO3" + 4H^ + 3e

N (NO2)

> NO + 2H2O

0,03

0,04

NO3- + 2H* + le

Ta c6: 2x + 2y + 3z = 0,03 + 0,04 = 0,07 va 0,07 cung chinh la so mol NO3"

0,04

Khoi luong muoi nitrat la: 1,35 + 62. 0,07 = 5,69 gam.

0,01mol
>

NO2 + H2O

0,04 mol

Chon dap an C.

Nhir vay, tong electron nhan la 0,07 mol.

Cdch 2:

Goi X, y, z Ian luat la so mol Cu, Mg, A l c6 trong 1,35 gam hon hop
kim loai. Ta c6 cac ban phan ting:

Khi cho kim loai hoSc hon hop kim loai tac dung vdi dung dich axit

Cu -> Cu^' + 2e

HNO3 tao hon hdp 2 khi NO va NO2 t h i

nj^o, = 2nNo, + 4nNo

nHNo,

=>

x\^^Q -

m = mcu(No,), +

Ap dung dinh luat bao toan khoi luang:

=> niu6i = 5,69

>

2y

>

3z

Khoi liidng muoi nitrat sinh ra la:

0,06 mol

m,u6i

2x

A l ^ Al^^ + 3e

=> 2x + 2y + 3z = 0,07.

= 2.0,04 + 4.0,01 = 0,12 mol

1,35 + 0,12.63 =

>

Mg ^> Mg2^ + 2e

mMg(NO,), +

= 1.35 + 62.(2x + 2y + 3z)

^Aum,),

= 1,35 + 62.0,07 = 5,69 gam. Chon dap an D.

Cdch 2: Ap dung cong thiJc:

+ 0,01.30 + 0,04.46 + 0,06.18

gam.

muoi nitrat = " 1 kim loai

+ molgpk.so

nhan.62

Chon dap an C.

I.

Cdch 3: Dung cho trSc nghiem

fiai 15: Nung m gam bot sat trong oxi, thu dugc 3 gam h6n hcJp chat rSn
X. Hoa tan het hon hdp X trong dung dich HNO3 (dtf), thoat ra 0,56
lit id dktc) NO (la san pham khuf duy nhat). Gia t r i cua m la

nimudi

= mu +

Hspk.so

e nhan.62

= 1,35 + (0,04.1+ 0,01.3).62 = 5,69 gam

Chon dap an C.

= 1,35 + (0,01.3+ 0,04.1).62 = 5,69 gam

A. 2,52 gam.

B. 2,22 gam.

C. 2,62 gam.

D. 2,32 gam.

Hit&ng dan

Hitctng dan

gidi

Dat hai kim loai A, B la M .

Cdch 1:
m gam Fe +

O2

3 gam h6n hop chat r ^ n X

HNO, du

> 0,56 Ht NO.

ThUc chat cac qua t r i n h oxi hod - khuf tren la:

Cho e:

Nhan e:

Fe

Fe'^ + 3e

m
56

3m
56
+ 4e

O2

3-m
32
3m
56

20'-;

+5

mol e

2H^

+ 3e
0,075 mol

m = 2,52 gam.

+ (mol

khu-so

.3x-2y-0,025.3

0,15 mol

Chon dap an A.
B a i 16: H5n hop X gom hai kirn loai A va B dufng trUdc H trong day
dien hoa va c6 hoa t r i khong doi trong cac hop chat. Chia m gam X
thanh hai phan hhng nhau:
- Phdn 1: Hoa tan hoan toan trong dung dich chiJa axit HCl vk H2SO4
loang tao ra 3,36 l i t khi H 2 .
- Phdn 2: Tac dung hoan toan vdi dung dich HNO3 thu duoc V l i t khi
NO (san pham khuf duy nhat).Biet cac the tich k h i do cf
dieu kien tieu chuan. Gia t r i cua V la
A. 2,24 l i t .
B. 3,36 l i t .
C. 4,48 l i t .
D. 6,72 l i t .

->

0,3

N^'
0,1 mol

C. 1,7M.

D. 1,2M.

gidi

7Q9

n = i ^ ^ = 0,08mol
^
22,4
N2

28 ^

37
NO2

= 0,03

mpe = 0,045.56 = 2,52 gam

Hiidng dan

X = 0,045
" ^ 1 7

<-

nhan.5,6)

= mhSn hgp oxu sdt

56x + 16y = 3

N^^ + 3e

B. 1,4M.

.3x - 2y = mol sdn phdm kh^.so e nhan

Ta c6:

H2

Bai 17: Cho ba kim loai A l , Fe, Cu vao 2 l i t dung dich HNO3 phan ufng
vCra du thu dufoc 1,792 l i t k h i X (dktc) gom N 2 va NO2 c6 t i khoi hoi so
vdi He bang 9,25. Nong do mol/lit HNO3 trong dung dich dau la
A. 0,28M.

sinphdm

Chon dap an A.

Chon dap an A.
+ 16y

nhan.

=> V N O = 0,1.22,4 = 2,24 l i t .

= 0,7.3 + (0,025.3.5,6) = 2,52 gam

56x

+ 2e
0,3

<- 0,025 mol

Van dung cong thiic tinh nhanh

Cdch 3: Luon nhd pt

(2)

Vay so mol e nhan cua 2H* bkng so mol e nhan cua N^^.

32
4(3 - m)
+ 0,075
32

h6n. hqp oxit sdt

(1)

Theo (2): So mol e cua M cho bang so mol e cua

mol

Cdch 2:
= 0,7.m

> M^* +

Theo (1): So mol e cua M cho bfing so mol e cua 2W nhan;

->

4(3 - m)

- Ph^n 1: M - + n H *

- Phan 2: 3M + 4nH^ + nNOa'-^ 3M"^ + nNO + 2nH20

Chon dap an A.

mpe

gidi

46
(MN

Ta c6:

+MNO

= 9,25 x 4 - 37 = ^ - ^
X

^
2

la trung binh cong khoi ItfOng phan tuf cua hai khi N2 va NO2 nen:
HN, =nNo, - ^

va

2NO3- +

lOe

mol

NO3" + le

N2

0,08

<- 0,4 <- 0,04 mol

M"^ + n.e

= 0,04

0,04

<r-

"NO,

NO2

0,04 <- 0,04 mol

0,04 mol
"MNO, -

+ 0,08 = 0,12 mol

K i m loai nhufdng bao n h i e u electron t h i cung n h a n bay nhieu goc N O 3

de tao muoi.
=^

Do do:

T^HNO,

(,ao ,nu6i)

nh^,g

n ^ o . ( p . . . g ) = 0,44

=^ [ H N O 3 ] = ^

h,

+ 0,12

0,

04

= 0,56

0,

0,44

mol.

So m o l e nhucJng: n = m o l
56
Qua t r i n h khuf: O2 + 4e
20"^
SO4'" + 4 H * + 2e

mol

Tir (2), (3)

= 4 75,2-a ^

t h a y CO 49 g a m H2SO4 t h a m g i a p h a n ufng, tao muo'i MgS04, H2O va

san p h a m khijf X. X l a

A. SO2

B. S

C . H2S

D . SO2, H2S

Cdch 2:
V a n dung cong thufc t i n h n h a n h
mpe = 0,7.m ;,' kgp ox,t sit + (moljd,, p/,a, khii-so e
fi 79

G o i a la so oxi h o a c u a S trong X.

0,4 mol

S^'^

0,8 mol

(6-a)e

->

0,1 m o l 0 , l ( 6 - a ) mol
49

Chon dap a n A.
BAI T A P V A N D U N G

B a i 1: Hoa t a n hoan toan m gam A l vao dung dich H N O 3 r a t loang t h i

thu dtfoc h o n hop gom 0,015 m o l k h i N2O va 0,01mol k h i N O ( p h a n

T o n g so mol H2SO4 d a dung l a : = 0,5 (mol)

ufng k h o n g tao NH4NO3). Gia t r i cua m la

98
, So mol H2SO4 da dung de tao muoi bang so mol M g = 9,6 : 24 = 0,4 mol.

So mol H2SO4 d a dung de oxi h o a M g l a : 0,5 - 0,4 = 0,1 m o l .

T a c6: 0,1.(6 - a) = 0,8 -> x = - 2 . V a y X l a H2S.

A. 13,5 gam.

B. 1,35 gam.

B a i 19: D e a g a m bot sMt ngoai k h o n g k h i , s a u mot thori g i a n se c h u y e n

dung dich Ca(0H)2 dtf, t h i t h u difoc 4,6 gam k e t tua. P h a n t r S m k h o i

t h a n h h 6 n h o p A c6 k h o i liTcfng l a 75,2 g a m g o m F e , FeO, Fe203 va

Fe304. C h o h o n hop A p h a n iJng he't v d i dung dich H2SO4 d a m dSc,

A. 68,03%.

n o n g thu dugc 6,72 l i t k h i SO2 (dktc). K h o i li/grng a g a m l a :

C . 22,4 g a m .

D . 25,3 g a m .

Iliidng dan giai

1:

Q u a t r i n h oxi h o a :

Fe
a
,
mol

56

3a

phan bang nhau:

- Phan

1: Cho t a c dung v d i H C l dir t h u daoc 3,36 l i t H2.

- Phan

2: Hoa t a n he't t r o n g H N O 3 loang d\i t h u di/oc V l i t m o t k h i

mol

56

A. 2,24 l i t .

B. 3,36 l i t .

C. 4,48 Ht.

D . 5,6 l i t .

B a i 4: Dung dich X gom AgN03 va Cu(N03)2 c6 cung nong do. Lay mot
(1)

D. 68,97%.

do d dktc). Gia t r i cua V la

mol.

^
Fe^".+
3e 32

C. 31,03%.

k h o n g m a u , hoa nau t r o n g k h o n g k h i (cac the t i c h k h i deu

3t

So mol O2 t h a m g i a p h a n iJng: n^, =

B. 13,03%.

B a i 3: M o t hon hop gom h a i bot k i m loai M g va A l di/oc chia t h a n h hai

So m o l F e b a n d a u trong a g a m : rip^ = m-ol.

5&
T5 2

D. 8,1 gam.

FeO va Fe203 dot nong. Sau k h i k e t thiic t h i n g h i e m t h u duac chat

luong FeO t r o n g h o n hop A la

Cdch

C. 0,81 gam

B a i 2: Cho m o t luong CO d i qua o'ng suf difng 0,04 m o l h o n hop A gom

r ^ n B gom 4 chat nSng 4,784 gam. K h i d i r a k h o i o'ng suT hap t h u vao

C h o n dap a n C .

B. 11,2 g a m .

nhan.5,6)

= 0,7.75,2 + ( - ^ ^ . 2 . 5 , 6 ) = 56 gam

D u n g dich H2SO4 d a m dSc vCfa l a c h a t oxi h o a vCfa l a m o i triTcfng.

Mg^^ + 2e

56

Chon dap a n A .

Hii&ng dan giai

A. 56 g a m .

^ 3a ^ ^ ^

32

B a i 18: K h i cho 9,6 g a m M g t a c dung h e t vdi dung dich H2SO4 d a m dac,

(3)

> SO2 + 2H2O

n,^^^ = 4no^ + 2nso,

= 0,28M.

Chon dap an A .

Mg

(2)

lirgng hon hap gom 0,03 mol A l ; 0,05 mol Fe cho vao 100 m l dung dich X
cho t d i k h i phan ijfng ket thiic t h u di/ac chat rkn Y chufa 3 k i m loai.Cho
Y vao H C I du giai phong 0,07 gam k h i . Nong do cua hai muoi la
A. 0,3M.

B. 0,4M.

C. 0,42M.

D. 0,45M.

B a i 5: Cho 1,35 gam hon hop Cu, M g , A l tac dung vdi HNO3 du dUdc 896 m l

hon hap gom N O va NO2 c6 M = 4 2 . T i n h tong khoi lUOng muoi n i t r a t

sinh ra (khi d dktc).
A. 9,41 gam.

B . 10,08 gam.

C. 5,07 gam.

D . 8,15 gam.

B a i 6. Hoa t a n hg't 4,43 gam h 6 n hop A l v a M g t r o n g H N O 3 loang t h u

dugc dung dich A va 1,568 l i t (dktc) h o n hop h a i k h i (deu k h o n g mau)
CO k h o i lirong 2,59 gam t r o n g do c6 m o t k h i b i hoa t h a n h m a u nau
t r o n g k h o n g k h i . T i n h so m o l H N O 3 da p h a n ufng.
A. 0,51 m o l .

B. A . 0,45 m o l .

C. 0,55 m o l .

D . 0,49 m o l .

B a i 7: Hoa t a n hoan toan m gam h 6 n hop gom ba k i m loai bkng dung

dich H N O 3 t h u duoc 1,12 l i t h o n hop k h i D (dktc) gom NO2 va N O . T i
k h o i h o i cua D so v d i hidro bang 18,2. T i n h the t i c h t o i thieu dung
dich H N O 3 37,8% (d = l,242g/ml) can dung.
A. 20,18 m l .

B. 11,12 m l .

C. 21,47 m l .

D . 36,7 m l .

B a i 8: Hoa t a n 6,25 gam hon hop Z n va A l vao 275 m l dung dich H N O 3 thu
dtroc dung dich A , chat rkn B gom cac k i m loai chi/a t a n het can nSng

A . P H l / O N G P H A P Q U I D O I H 6 N H0P N H I E U C H A T V E IT C H A T HCiN

Cdc

chu y khi dp dung phUcfng phdp

quy dot:

1. K h i quy d o i h o n hop nhieu chat (h5n h o p X ) (tCr ba chat t r d l e n )

t h a n h h o n h o p h a i chat hay c h i con m o t chat t a phai
so mol nguyen

to vd bdo toan khoi lii^ng

hon

hao

toan

h^p.

2. Co the quy doi hon hop X ve bat k y cap chat nao, t h a m c h i quy doi ve
mot chat. Tuy nhien t a nen chon cap chat nao don gian c6 i t phan
ufng oxi hoa khijf nhat de don gian viec t i n h toan.
3. T r o n g qua t r i n h t i n h toan theo phiTOng phap quy d o i d o i k h i t a gap
so a m do la do sir bu trCr k h o i lirong cua cac chat t r o n g h o n h o p .
T r o n g trirdng h o p n a y t a v l n t i n h toan b i n h t h u d n g va k e t qua
cuoi cung v a n thoa m a n .
4. K h i quy doi h o n hop X ve m o t chat la Fe^Oy t h i oxit FexOy t i m
diroc c h i la oxit gia d i n h k h o n g c6 thirc.
B a i 1: (DH khoi A-2010):

Hoa t a n hoan toan 2,44 gam h o n h o p h o t X

2,516 gam va 1,12 l i t hon hop k h i D (of dktc) gom N O va NO2. T i khoi

gom FOxOy va Cu b a n g dung dich H2SO4 dac nong (dir). Sau p h a n ufng

cua h6n hop D so v d i H2 la 16,75. T i n h nong do mol/l cua HNO3 va t i n h

t h u dirge 0,504 l i t k h i SO2 (san p h a m khuf duy n h a t , d dktc) va dung

khoi lirong muoi khan t h u duoc k h i c6 can dung dich sau phan ijfng.

dich chijfa 6,6 gam h o n h o p muoi sunfat. P h a n t r a m k h o i lirgng cua

A. 0,65M va 11,794 gam.

B. 0,65M vk 12,35 gam.

Cu t r o n g X la

C. 0,75M va 11,794 gam.

D . 0,55M va 12.35 gam.

A. 39,34%.

B . 65,57%.

B a i 9: D o t chay 5,6 gam b o t Fe t r o n g b i n h difng O2 t h u duoc 7,36 gam

Hii&ng dan

h o n hop A gom Fe203, Fe304 va Fe. Hoa t a n hoan toan luong h 6 n hop
A bang dung dich H N O 3 t h u di/Oc V l i t h 5 n hop k h i B g o m N O va
NO2. T i k h o i cua B so v d i H2 bSng 19. The t i c h V 0 dktc la
A . 672 m l .

B . 336 m l .

C. 448 m l .

D . 896 m l .

B a i 10: Cho a gam h 6 n hop A gom oxit FeO, CuO, Fe203 c6 so m o l bang
nhau tac dung hoan toan v 6 i lirong vira du la 250 m l dung dich HNO3

A. 74,88 gam.

B. 52,35 gam.

C. 61,79 gam.

D . 72,35 g a m .

D . 13,11%.

gidi

2,44 gam X gom Fe^Oy va Cu c6 the tao r a t o i da:

H o n hop Fe203 va CuO c6 k h o i lirong: 2,44 + ^ ^ . 1 6 = 2,8 g a m
So' mol Fe203

Fe2(S04)3;
X

k h i dun nong nhe, t h u diTOc dung dich B va 3,136 l i t (dktc) hon hop k h i
C gom NO2 va N O c6 t i k h o i so v d i hidro la 20,143. T i n h a.

C . 26,23%.

Ta co:

160x + 80y = 2,8

4 0 0 X . 160y = 6 , 6 =

,
CuO >
y

22,4
CUSO4
y

fx = 0,0125
y = 0,01

= 26,23

Chon dap a n C.

Dap a n
1. B

2. B

3. A

4. B

5. C

6. D

7. C

8. A

9. D

10. A

B a i 2: Hoa t a n h e t m gam h o n h o p X g o m FeO, Fe203, Fe304 b ^ n g

H N O 3 dac nong t h u dirge 4,48 l i t k h i NO2 (dktc). Co can dung dich
sau p h a n ufng t h u dirge 145,2 gam muoi k h a n gia t r i eua m la
A. 35,7 gam.

B . 46,4 gam.

C. 15,8 gam.

D . 77,7 g a m .

HUcmg

dan

giai

Hitcfng

Q u y h o n h o p X ve h 6 n h o p h a i c h a t F e O v a FeaOs t a c6
FeO + 4HNO3

0,2 m o l < - 0,2 m o l

Fe203 + 6 H N O 3

> 2Fe(N03)3 + 3 H 2 O

0,2 m o l <

t a c6:

0.6

mol.

gam.

A. 40,24%.

B. 30,7%.

C. 2 0 , 9 7 % .

Vay:
D. 37,5%.

B.140 gam.
HiC&ng

C. 120 g a m .
dan

D . 100 g a m .

3 x - 2 y = 0,4.2

= MMMOO
49,6

Vgo^ = 0 , 0 1 . 2 2 , 4 = 0 , 2 2 4 l i t ( h a y 2 2 4 m l ) .

X . H o a t a n h e t h o n h o p X t r o n g d u n g d i c h H N O 3 (diT) t h o a t r a 0,56 l i t
N O ( d d k t c ) ( l a s a n p h a m khijf d u y n h a t ) . G i a t r i cua m l a

giai

Jx -

A . 2,52 g a m .

j y = 0,65

dan

> F e ( N 0 3 ) 3 + N O + 2H2O

0,025

0,025

<-

Fe2(S04)3

->

0,35

<-

mol

g a m h o n h a p X g o m F e O , F e 2 0 3 , FegOi

t h i c a n 0,05 m o l H 2 . M a t k h a c h o a t a n h o a n t o a n 3,04 g a m h o n

hap

n o n g t h i t h u duac V m l k h i S O 2 (san

p h a m khijf d u y n h a t d d k t c ) . G i a t r i V l a .
C. 3 3 6 m l .

gam

'^foiuo.i^Yo.p,)

= 0,02

mol

=> mpe = 5 6 . ( 0 , 0 2 5 + 0,02) = 2,52 g a m . C h o n d a p a n A .

Bai

X t r o n g d u n g d i c h H 2 S O 4 dSc

0,025 m o l

1 6
=^

Chon dap a n B.
4: D e khur h o a n t o a n 3,04

gam.

giai

Fe + 4HNO3

mp,p^ = 3 - 5 6 . 0 , 0 2 5 = 1,6
->

D . 2,32

Q u y h 6 n h a p c h a t r a n X ve h a i c h a t F e , Fe203:

mFe,,so,), = 0 , 3 5 . 4 0 0 = 140 g a m

B . 448 m l .

C. 2,62 g a m .

Hiidng

=> C h o n d a p a n C.

0,7

B . 2,22 g a m .

0,7

= 20,97%

2Fe

> 0,01 m o l

B a i 5: N u n g m g a m h o t sSt t r o n g o x i , t h u diroc 3 g a m h o n h a p c h a t r ^ n

Q u y h o n h g p X ve h a i c h a t l a F e v a o x i n e n h o n h a p t h a n h FexOy
5 6 x + 1 6 y = 49,6

> Fe2(S04)3 + S O 2 + 4 H 2 O

Chon dap a n A.

b) T i n h k h o i l u o n g m u o i t r o n g dung d i c h Y .
A . 160 g a m .

[ y = 0,01 m o l

0,02

a) T i n h p h a n t r a m k h o i lirgtng o x i t r o n g h o n h o p X .

A . 224 m l .

f x = 0,02 m o l

2 F e O + 4H2SO4

b a n g H2SO4 dac n o n g t h u diroc d u n g d i c h Y v a 8,96 l i t k h i S O 2 ( d k t c ) .

Bai

3y

" 7 2 x + 160y = 3,04

B a i 3 : H o a t a n h o a n t o a n 49,6 g a m h o n hcfp X g&m Fe, F e O , Fe203, FegO,

b ) T a CO sa d o :

2Fe + 3 H 2 O

x + 3 y = 0,05

C h o n dap a n B.

Fe + H2O

Fe203 + 3 H 2

0,4 m o l

=> m x = 0,2. ( 7 2 + 160) = 4 6 , 4

a) T a c6:

F e O + H2 ^
X

145,2
"Fe(No,), =

giai

Q u y h o n h a p X ve h o n h a p h a i c h a t F e O v a Fe203 v d i so m o l l a x , y ,

> Fe(N03)3 + N O 2 + 2 H 2 O

0,2 m o l <

dan

D . 112 m l .

6: H 6 n h a p X g o m ( F e , F e 2 0 3 , Fe304, F e O ) v d i so m o l m 6 i c h a t la

0,1 m o l , h o a t a n h e t v a o d u n g d i c h Y g o m ( H C l v a H2SO4 l o a n g ) 6xi

t h u diiac d u n g d i c h Z. N h d tCr tCf d u n g d i c h C u ( N 0 3 ) 2 I M v a o

dung

d i c h Z cho t d i k h i n g U n g t h o a t k h i N O . T h e t i c h d u n g d i c h C u ( N 0 3 ) 2
can d u n g va the t i c h k h i t h o d t r a (d dktc)?
A . 25 m l ; 1,12 l i t .

B . 0,5 l i t ; 2 2 , 4 l i t .

C. 5 0 m l ; 2,24 l i t .

D . 5 0 m l ; 1,12 l i t .

HUdng

Fe203 + 6 H N O 3

dan gidi

y/2 - > 3y

Quy h 6 n h o p 0,1 m o l FegOs va 0,1 m o l F e O t h a n h 0,1 m o l Fe304.

H o n h o p X gom: Fe304 0,2 m o l ; F e 0,1 m o l + dung dich Y

' Fe304 + 8H^

0,2

Fe + 2 H "

He phuong t r i n h :

lOx

0,06
^NO

dung d i c h HNO3 d i / thu duoc 2,24 l i t k h i NO2 (dktc) l a s a n p h a m khiJ

0,1 m o l

duy n h a t . G i a t r i c u a m l a

=^ VNO = 0,1.22,4 = 2,24 l i t .

A. 11,2 g a m .

B . 10,2 g a m .

n e , K 0 3 . , = | n ^ 0 3 = 0 - 0 5 mol.

H o a t a n h 6 n h o p X v a o dung d i c h HNO3 dU t a c6

F e + 6HNO3

B a i 7: N u n g 8,96 gam F e t r o n g k h o n g k h i difoc h 5 n hop A g o m F e O ,

Fe304, Fe203. A hoa t a n hoan toan t r o n g dung dich chufa 0,5 mol
HNO3 t h i vCfa du, t h a y t h o a t r a k h i N O l a san p h a m khuf duy n h a t . So
C. 0,03.

D . 0,02.

Hiicfng dan gidi

> F e ( N 0 3 ) 3 + 3NO2 + 3H2O

M <

0,1 m o l

=> So m o l cua n g u y e n tuT F e t a o oxit Fe203 l a

8,4
56

mol N O thoat r a l a .

0,1
3

V a y : mx = m^^ + m^^^o^ ^

0,35 , _
>n F e , 0 ,

= 0,16mol

ta CO phaong t r i n h :
2Fe + O2
X

F e O + 4HNO3

0,1

->

> 3 F e ( N 0 3 ) 3 + N O + 5H2O
->

0,1

0,1 m o l

x/3

m ,
C h o n dap a n A.

->

4 F e + 3O2

0,05

y/2

3FeO + IOHNO3
X - > lOx/3

Ta c6: 0,15 mol

> 2Fe203

> F e ( N 0 3 ) 3 + NO2 + 2H2O

2 F e + O2

Fe203:

<

> 2FeO

. 4 F e + 3O2
y

'

Quy hdn hap X vi hat chdt FeO vd

Quy h o n hop A gom ( F e O , Fe304, F e j O g ) t h a n h h o n h o p ( F e O , Fe203)

0,35
3.2

mx = - ^ . 5 6 + - ^ . 1 6 0 = 11,2 g a m .

C h o n dap a n A.

= ^
56

D . 6,9 g a m .

Quy hdn hop X vi hat chdt Fe vd FegO^:

= 0,05 l i t (hay 50 m l ) .

B . 0,04.

C . 7,2 g a m .

HtCdng dan gidi

Chon dap a n C.

A. 0,01.

= 0,02 mol.

c h a t r S n X g o m F e , Fe203, Fe304, F e O . H o a t a n m g a m h 6 n h o p X v a o

> 3Fe'^ + N O t + 2H2O

0,1

V.

B a i 8: N u n g 8,4 g a m F e t r o n g k h o n g k h i , s a u p h a n ufng t h u diiOc m g a m

Dung dich Z: (Fe^^: 0,3 m o l ; Fe^^: 0,4 mol) + Cu(N03)2:

y = 0,1 m o l

C h o n d a p a n D.

0,1 m o l

SFe'^ + NO3- + 4H^

X = 0,06 mol

+ 3y = 0,5

0,4 m o l

> Fe^^ + H2T

0,1

0,3

X + y = 0,16

> Fe'^ + 2 F e ' ^ + 4H2O

0,2

2Fe(N03)3 + SHaO

-> 2FeO
0,1 mol
SFeA
0,025 m o l

= 0,1.72 + 0,025. 160 = 11,2 gam.

n^ol _ 3 _ 0,15
0,05
n CO

Chii y: V a n c6 the quy h o n hcjp X ve h a i chat (FeO va F e 3 0 4 ) hoSc (Fe

va FeO), hoSc (Fe va Fe304) n h i m g viec giai t r d nen phuTc tap
hcfn (cu the la t a p h a i dSt an so m o l m o i chat, lap he phtfong
t r i n h , g i a i he phacfng t r i n h h a i a n so).
Quy hdn hop X ve mot chdt Id

<

0,1.x
=
56
3x-2y

(trong oxit sit)

CO2

=> nco = no = 0,15 m o l -> mo = 0,15.16 = 2,4 gam

=:> mpe = 8 - 2,4 = 5,6 gam -> npe = 0,1 mol.
Theo phiicfng t r i n h p h a n ufng t a c6:
- n CO,

Chon dap a n B.

Vay cong thufc quy doi la FeeOy ( M = 448) va

teeO,

.0,2 - 0,15 m o l -> ncodu = 0,05 mol.

CO + O

X
6
,
> = mol.
y
7

n,, n =

- 75% .

ThUc chat p h a n iJng khijf o x i t s^t la do

0,1 mol.

8,4
=> n., =

75
100

> Fe(N03)3 + (3x-2y) NO2 + ( 3 x - y ) H 2 0

Fe,0y + ( 6 x - 2 y ) H N 0 3
m o l
3x-2y

Fefiy.

%Vco

B a i 2: (DH

= 0,025 mol.

khoi B - 2009): Cho 61,2 gam hon hop X gom Cu va Fe304

tac dung v d i dung dich H N O 3 loang, dun nong va khuay deu. Sau k h i

6-2.7

cac p h a n ufng xay ra hoan toan, t h u diTcfc 3,36 l i t k h i N O (san p h a m

khuf duy n h a t , d dktc), dung dich Y va con l a i 2,4 gam k i m loai. Co

=> mx = 0,025. 448 = 11,2 gam.

can dung dich Y, t h u ducfc m gam muoi k h a n . Gia t r i cua m la

VI. P H l / C l N G P H A P B A G

* NOi d u n g : Phuang
so mol electron

phdp

NGUYEN

bdo todn nguyen

cho phep chung

A. 151,5.

T C T

ti2 vd phuang

ta ggp nhieu phUang

phdp

trinh phdn

ling

C. 137,1.

Hiidng

lai

Idm mot, qui ggn viec tinh todn vd nhdm nhanh dap so.
B a i 1: (CD

B. 97,5.

bdo todn

nung nong diTng 8 gam m o t oxit sat den k h i phan ufng xay r a hoan
toan. K h i t h u dirac sau p h a n iJng c6 t i k h o i so v d i hidro bang 20.C6ng

khii

Fe^")

3Fe304 + 28HNO3

9Fe(N03)3

D. Fe304; 65%.

3Cu + 8HNO3 ^ 3Cu(N03)2

K h i t h u dUdc gom 2 k h i CO2 va CO du c6 M = 40

n^o,

0,2mol

44
28

mol
3
+

2N0

4H2O

mol

Cu + 2Fe(N03)3 -> Cu(N03)2 + 2Fe(N03)2

3x

3x
3x
3x mol
2
2
K h o i X p h a n ufng l a : 61,2 - 2,4 = 58,8

12
40-

nco

I4H2O

> xFe + yCOz

S"co=|g =

2y
y

Fe^Oy + yCO

+ NO

3x

thufc cua oxit s^t va p h a n t r a m the t i c h cua k h i CO2 t r o n g h o n hdp

C. FeaOg; 65%.
dan giai

giai

K i m loai con du la Cu va muoi s^t t h u diioc se la muoi s^t ( I I ) (Cu

Khoi A - 2007): Cho 4,48 l i t CO (d dktc) tCf tvl d i qua ong su:

k h i sau p h a n ufng la.

A. FeO; 75%.
B. FezOg; 75%.
Hiidng

dan

D. 108,9.

"NO

232x + 64(y + 3x ) = 58,8

2
3,36
^ ,^
X
2y = 0,15
= 0,15 m o l ^
22,4
3 " 3

(1)
(2)

Tii (1)

(2) =>

= 0,15, y = 0,15

M u o i t h u dtrcJc gom Cu(N03)2 va Fe(N03)2 c6 k h o i li/ong 1^:

,

(d\i), t h u dMc dung dich X. Cho dung dich AgNOs (du) vao dung dich
X, sau k h i p h a n ufng xay r a hoan toan s i n h r a m gam chat r a n . Gia
t r i cua m la
A. 68,2 g

B. 28,7 g

C. 10,8g

HUdng

d&n

D . 57,4g

giai

0,24 + a = 0,18 + 2a o

Jai 5: Cho h 5 n hop A gom A l , Z n , M g . D e m oxi hoa hoan toan 28,6 gam
A bang oxi dtf t h u diigc 44,6 gam h o n hgfp oxit B. Hoa t a n h e t B t r o n g
dung dich H C l t h u dugc dung dich D . Co can dung dich D difoc h6n
hop muoi k h a n la.
A. 99,6 gam.

c6 p h a n iJng A g * oxi hoa Fe^^ Vay chat rSn t h u diTOc gom A g C l va A g

Goi so m o l cua FeCl2 la x t h i so mol cua N a C l la 2x.

B. 49,8 gam.

C. 74,7 gam.

Hii&ng

dan

(1)

MaOn + 2 n H C l

np^ci,

= 0,1

= 0,2

+ 0,2

= 0,4

(2)

Ap dung dinh luat bao toan khoi li/gng -> Tn.Q^ = 44,6 - 28,6 = 16 gam

mol

=>

no^ = 0,5

n^j

Chon ddp an A .
Hoa t a n hoan toan h o n hcfp gom 0,12mol

FeS2 va a mol CU2S vao dung dich H N O 3 (vCfa du), t h u difcJc dung dich
X (chi chufa h a i muoi sunfat) va k h i duy n h a t N O . Gia t r i cua a la (cho

mol

-> n n c i = 4.0,5

mol

2 mol

m^uoi = mhhki

+ m^,,

= 28,6 + 2.35,5 = 99,6

gam.

Chon dap an A.
B a i 6: De khuf hoan toan 3,04 gam hon hop X gom FeO, Fe304, Fe203

Fe = 56 , Cu = 64 , S = 32):
B. 0,12

C. 0,06

Hiidng

dan

D . 0,04

gidi

Cac nguyen to Fe, Cu, S se h i H N O 3 oxi ho^ l e n so oxi hoa cao nhat.
V a y cong thufc cua h a i m u o i sunfat la Fe2(S04)3 va CUSO4 .
Ta CO so do hop thutc: 2FeS2

2MCln + nH20

Theo phuong t r i n h (1) (2) -> n HCl ~ ' ^ ^ O ,

mol

m An = 0,4.143,5 + 0,1.108 = 68,2g

B a i 4: (DH khoi A - 2007):

gidi

M + -n O2
2

= 0,1
np^ci,

D . 100,8 gam.

Goi M la k i m loai d a i dien cho ba k i m loai t r e n v d i hoa t r i la n .

127x + 58,5.2x = 24,4

HAgci = n N a C i + 2

a = 0,06 (mol)

| T Chon dap a n C.

t o d n nay d day k h o n g chi don t h u a n c6 phan ufng trao doi ma con

A. 0,075

2a (mol)

A p dung d i n h luat bao toan nguyen to ta cd:

FeCl2 va N a C l (c6 t i le so m o l tirong ufng la 1 : 2) vao m o t lirong nyxdc

HAg =

a (mol)

+ T d n g so m o l S sau p h a n ufng: 0,06.3 + 2a = (0,18 + 2a) m o l

B a i 3: (DH khoi B - 2009): Hoa t a n hoan toan 24,4 gam h o n hop gom

2CuS

+ T o n g so m o l S trudc p h a n ufng: 0,12.2 + a = (0,24 + a) m o l

(0,15 + M ^ ) i 8 8 + 3.0,15.180 = 151,5g

2

Chon dap an A .

Bki

CuzS

0,12 (mol)

Fe2(S04)3
0,06 (mol)

can 0,05 mol H2. M a t khac hoa tan hoan toan 3,04 gam h6n hop X
trong dung dich H2SO4 dac thu diioc the tich khi SO2 (san pham khuf
duy nhat) d dieu kien tieu chuan la
A. 448 ml.

B. 224 ml.
Hii&ng

C . 336 ml.
dan

D. 112 ml.

gidi

Thuc chat phan iJng khuf cac oxit tren la

H2
0,05

+0
->

H2O

0,05 m o l

D a t so mol hon hop X gom F e O , Fe304, FezOg Ian lirot la x, y, z.

T a c6:

no = x + 4y + 3z = 0,05 mol

=> n,.., -

(1)

3,04-0,05.16
,
'
= 0,04 mol
56

=> X +

p a i 8: Thoi rat cham 2,24 lit (dktc) mot hon hop khi gom C O v a H2 qua
mot ong sur dung hSn hop A I 2 O 3 , CuO, Fe304, Fe203 c6 khoi luTOng l a
24 gam d\i dang duoc dun nong. Sau k h i ket thuc phan ufng khoi
l i i o n g chat ran con lai trong ong suT l a .
j

3y + 2z = 0,04 mol

->
x+y

=> Z nso =

= ^

Khoi

AI2O3

nung nong, phan

ling hoan toan. Sau phan uTng thu diioc m gam chat r S n va mot hon
hop khi va hoi nSng hon khoi liTOng cua hon hop V la 0,32 gam. Tinh
V va m.
A. 0,224 ht va 14,48 gam.

B . 0,448 lit va 18,46 gam.

C. 0,112 lit va 12,28 gam.

D. 0,448 lit va 16,48 gam.

Hii&ng dan giai

Thiic chat phan ufng khuf cac oxit tren la

CO + 0
H2 + O

> CO2
>

H2O.

Khoi lUtfng hon hop k h i tao thanh nSng hon hon hgfp k h i ban dau
chinh la khoi li/ong cua nguyen tuf oxi trong cac oxit tham gia phan
iJng. Do vay: mo = 0,32 gam.
0 32

{n^Q

ufng khuT

cac oxit l a : C O + O
+ O

>
>

CO2

H2O

lUcJng

chat rSn con lai trong ong s i J la

mrfn= 24 - 1,6 = 22,4 gam.

diing 16,8 gam hon hop 3 oxit: CuO, Fe304,

=>

0,lmol

mo = 1,6 gam.

B a i 7: Thoi tCf tCr V lit hon hop khi (dktc) gom C O va H2 di qua mot ong

n,co

D. 16,8 gam.

no = npo + n^ = O,lmol.

= 0,01 mol

Chon dap an B .

Thiic chat phan

Vay:

Vay: VJ-Q^ = 224 ml.

= "o =
+

= 0,02 mol

moxit = nichairiin + 0,32

16,8

= m + 0,32

V^h(co.H,)

Chon dap an A.
B a i 9: Cho m gam mot ancol (rugu) n o , dOn chuTc X qua binh dimg CuO
(du), nung nong. Sau k h i phan

ufng

hoan toan, khoi Itfcfng chat ran

trong binh giam 0,32 gam. H5n hop hoi thu diroc c6 ti khoi doi vdi
hidro la 15,5. G i a tri cua m l a .
A. 0,92 gam.

B . 0,32 gam.

C . 0,64 gam.

CnH2^lCn20H + CuO ^

C n H 2 . l C H 0 + C u i + H2O

Khoi lirong chat r S n trong binh giam chinh la s o gam nguyen tijf O
trong CuO phan iJng. Do do nhan duoc:
0 32
mo = 0,32 gam -> n,, = - = 0,02 mol
16
CH,,,CHO : 0,02 mol
H6n hop hoi gom:
H,p
: 0,02 mol.

Co M = 31 =>

=> m = 16,48

gam.

= 0,02.22,4 = 0,448 lit.

D . 0,46 gam.

HUdng dan giai

Vay h6n hop hoi c6 tdng so mol la 0,04 mol.

n J = 0,02 mol.

Ap dung dinh luat bao toan khoi luong ta c6:

Chon dap an D .

nhh(co.H,)

H2

y/2
0,02

> 3Fe2(S04)3 + SO2 + IOH2O

C . 20,8 gam.

Hiic/ng dan giai

^x/2

2Fe304 + IOH2SO4
y

B . 11,2 gam.

(2)

Nhan hai ve cua (2) vdri 3 roi trCr (1) ta c6: x + y = 0,02 mol.
Mat khac: 2FeO + 4H2SO4
> Fe2(S04)3 + SO2 + 4H2O
x

A. 22,4 gam.

mhhhoi

= 31.0,04 = 1,24 gam.

niancol + 0,32

= m h h hai

mancol = 1,24

- 0,32

Chon dap a n A.

= 0,92

gam.

B a i 10: D o t chay h o a n t o a n 4,04 g a m m o t h o n h o p h o t k i m loai g o m A l ,

Hii&ng

F e , C u t r o n g k h o n g k h i t h u diTcfc 5,96 g a m h o n h o p 3 o x i t . H o a t a n

FeO

h e t h o n h o p 3 oxit b k n g dung dich H C l 2 M . T i n h t h e t i c h dung dich

FeCI2

IICl

FegO/

H C l can dung.
A . 0,5 l i t .

B . 0,7 l i t .

C. 0 , 1 2 l i t .

Hiiofng dan

D. 1 lit.

dan

gidi.

Fe(OH)2

(UiNn^

t^rongkk

O
2^3

Fe(OH),

FeCl,

V i t r o n g h 6 n hop ban dau da c6 m o t lirgng Fe203 va coi Fe304 = FeO.

Fe203) n e n c h i x e t sir chuyen hoa qua t r i n h : 2 F e O

gidi

Fe203

Do t a n g k h o i lirgng cua Fe203 so v d i h o n h g p dau l a k h o i lirgng o x i

= m o x . t - m k i = 5,96

mo

no =

1,92
16

- 4,04

= 1,92

gam.

ma F e O l a y de tao Fe203

= 0,12 m o l .

no

1,2
can

H o a t a n he't h o n h o p b a o x i t b a n g d u n g d i c h H C l t a o t h ^ n h H2O n h u
sau:

2 H " + O^'
0,24

Goi h h

H2O

<- 0 , 1 2 m o l
0,24

HHCI =

= 0,075(mol)

16

FeO : x(mol)
Fe30,(FeO.Fe203) = y(mol)
0,6

(mol)

0,12 l i t .

T i r ( l ) , (2)

vCra d u V l i t O2 id d k t c ) , t h u dtfcJc 0,3 m o l CO2 v a 0,2 m o l H2O. G i a t i .

=>

no

= 0,1

y = 0,05

C h o n d a p a n C.
B a i 1 1 : D o t c h a y h o a n t o a n 0 , 1 m o l m o t a x i t c a c b o n x y l i c dan chuTc c a -

A . 8,96 l i t .

B . 11,2 l i t .

C. 6,72 l i t .

Hit&ng dan

D . 4,48 l i t .

gidi

0,3

(mol)

<->

(1)
4y

(2)

0,3

mp,o = 3 8 , 3 %

C h o n d a p a n C.
B a i 1 3 : C h o m o t l u o n g k h i C O d i q u a o n g chufa ( h o n h g p A ) g o m 0 , 0 1
dirge 4 , 7 8 4 g a m c h a t r ^ n B g o m b o n c h a t . H o a t a n c h a t r ^ n B b a n g
d u n g d i c h H C l diT t h a y t h o a t r a 0 , 6 2 7 2 l i t H2 (6 d k t c ) . T i n h so m o l
F e 3 0 4 t r o n g h o n h o p B . B i e t r a n g t r o n g B so m o l F e 3 0 4 b a n g

A x i t c a c b o x y l i c d a n chufc c6 2 n g u y e n tuf o x i n e n c6 t h e d S t l a RO2

V a y : nQnjo^, + n g ^ p = noico^) + " o d i ^ o )

A . 0,006.
=> n o (p.u) = 0,6 m o l

B . 0,008.

C. 0 , 0 1 .

Hii&ng

n^^ = 0,3 m o l
Hon hgp A

= 6,72 l i t .

C h o n d a p a n C.

-^tong
o

so m o l F e O v a Fe203.

0,1.2 + no,p, = 0,3.2 + 0 , 2 . 1

FeO

: 0,01 m o l

Fe.Og

: 0,03 m o l

dan

D . 0,012.

gidi

+ C O -> 4 , 7 8 4 g a m B ( F e , Fe203, F e O ,

F e 3 0 4 ) tiTOng l i n g v d i so m o l l a : a, b , c, d ( m o l ) .

B a i 1 2 : H o a t a n a g a m h o n h o p g o m F e O v a Fe304 h e t 3 0 0 m l d u n g d i c h
H C l 2 M dLTOc d u n g d i c h X . C h o X t a c d u n g v d i m o t l u o n g d u n g d i c h
NH3 d i i dirge k e t t u a . N u n g k e t t u a t r o n g k h o n g k h i d e n k h o i liTOng
k h o n g d o i diTOc a + 1 , 2 g c h a t r a n . P h a n t r a m k h o i i J O n g c u a F e O
trong hon hgptren la:
A . 28,47o

trong oxit =

x + y = 0,15

m o l F e O v a 0,03 m o l Fe203 d o t n o n g . S a u k h i ke't t h u c t h i n g h i e m t h u

cua V l a .

=>

npeo = 0,075 ( m o l )

B. 24,6%

C. 3 8 , 3 %

D. 40,2%

H o a t a n B b a n g d u n g d i c h H C l d u t h u dirge n H = ^ f f ^ ^ = 0 , 0 2 8 m o l
22,4
Fe + 2 H C 1 ^

FeCl2 + H2

a = 0,028

<-

(1)

0,028 m o l .

T h e o de b a i : np^^ = ^(r^y^o

+ ^^0,0,)

d = | ( b + c)

T o n g m e l a : (56.a + 160.b + 72.c + 2 3 2 . d ) = 4,784 g a m .

So m o l n g u y e n tuf F e t r o n g h 6 n h o p A bang

Bai

(2)

1,76

(3)

so m o l n g u y e n tuf

trong hon hop B.

T a c6:

npeCA)

= 0,01 + 0,03.2 = 0,07 m o l

n p e (B)

= a + 2b + c + 3d => a + 2b + c + 3d = 0,07

TiX (1. 2, 3, 4)

16: D u n h a i mau
gam

C O 2 va

0,72

(4)

Hiidng

2 k i m l o a i . K h o i liTcmg H 2 O tao

C . 7,2 g a m .
dan

Hikioai =

24

= 0,08

gam

D . 3,6

gam.

gam.

16

C o n g thu-c cau t a o l a C H 3 - O - C H 2 - C H

V a y h a i a n c o l do l a C H 3 O H v a C H 2 =

= CH2.

CH-CH2-OH.

Chon dap a n D.

17,6

VAN

DUNG

gam.

6,4

B a i 1: H o a t a n h o a n t o a n h o n h o p X g o m 0,4 m o l F e O v a O , l m o l Fe203 vao

d u n g d i c h H N O 3 l o a n g , diT t h u duoc d u n g d i c h A v a k h i B k h o n g m a u ,

= ^'^

hoa n a u t r o n g k h o n g k h i . D u n g d i c h A cho tac d u n g v d i d u n g d i c h N a O H

gam.

diT t h u dirge k e t t u a . L a y t o a n bp k e t t u a n u n g t r o n g k h o n g k h i d e n k h o i
l i i o n g k h o n g d o i t h u dUcfc c h a t r a n c6 k h o i l i i o n g l a

Chon dap a n C.

A . 23,0 g a m .

B a i 15: Khut h e t m g a m Fe304 b a n g C O t h u duoc h o n h o p A g o m F e O va

B . 46,4 g a m .
HiCdng

C . 11,2 g a m .
dan

D . 16,04

gam.

D . 48,0

gam.

hgp

hoan

H 2 S O 4 dac,

toan X bang

ran X gom

Fe, FeO,

Fe304. FeaOs. H o a

tan

n o n g t h u dirge d u n f d i c h Y . Co

can

B . 32 g a m .

C. 40 g a m .

D. 48 g a m

B a i 3: KhOr h o a n t o a n 17,6 g a m h 6 n h g p X g o m F e , F e O , FezOg c a n

2,24

l i t C O ( 0 d k t c ) . K h o i l i r g n g s a t t h u dirge l a

^'^

A . 5,6 g a m .

A p d u n g d i n h l u a t bao t o a n n g u y e n to F e :
3-np,(p,soo => mp,^o, = 0.1-232 = 23,2

iJng t h u dirge h o n

A . 20 g a m .

0,3 m o l

^FeftrongFeSO,) = ^ S O j " =

C. 16,0 g a m .

d u n g d i c h Y , liTOng m u o i k h a n t h u dirge l a

gidi

YezOi -> ( F e O , F e ) -> 3 F e ' "

0,1 m o l

B . 32,0 g a m .

B a i 2: C h o k h i C O d i q u a o n g suT chuTa 16 g a m Fe203 d u n n o n g , sau p h a n

F e . A t a n vCra d u t r o n g 0,3 l i t d u n g d i c h H 2 S O 4 I M cho r a 4,48 l i t k h i

Chon dap d n A.

= 0,48 g a m ; m = ^ . 2

gidi

=^ "^o ( H P ) = 6,4 g a m => no,H,o) = ^

gidi

i|

6 4

^F.(v.,o,)

la.

=> C o n g thufc p h a n tijf cua m o t t r o n g b a ete l a C 4 H 8 O .

BAI TAP

(dktc). T i n h m?
A . 23,2 g a m .

ddn

: ^ m o = 0,72 - 0,48 - 0,08 = 0,16

17,6 g a m h o n h o p

- > m^o = 0,4.18 = 7,2

r i X O u do

D a t c o n g thiJc t o n g q u a t cua m o t t r o n g b a ete l a CxHyO^, t a c6:

12

Hioxit -

H2O. Hai

D. C H 3 O H va C3H5OH.

me - ^ . 1 2

B . 5,4 g a m .

(trong oxit) =

ba

mol

t h a n h la.

mo

gam

HU&ng

B a i 14: Khuf h o a n t o a n 24 g a m h o n h o p C u O v a FCxOy b a n g H 2 dii d n h i e t

A . 1,8 g a m .

hon hop

C. C 2 H 5 O H v a C 4 H 9 O H .

Chon dap a n A.

t h u daac

140C duac

B. C 2 H 5 O H va C 3 H 7 O H .

d = 0,006 m o l .

do cao

chuTc v d i H 2 S O 4 dSc,

A. C H 3 O H va C 2 H 5 O H .

b = 0,006 m o l
c = 0,012

dan

ete. L a y 0,72 g a m m o t t r o n g b a ete d e m d o t c h a y h o a n t o a n t h u duoc

Bai
gam

B . 6,72 g a m .

C. 16,0 g a m .

D . 11,2 g a m .

4: D o t c h a y h o n h g p i i i d r o c a c b o n X t h u dugc 2,24 l i t C O 2 ( d k t c ) v a

2,7 g a m H 2 O . T h e t i c h O2 d a t h a m g i a p h a n ufng c h a y ( d k t c ) l a
.

A . 5,6 l i t .

B . 2,8 l i t .

C. 4,48 l i t .

D . 3,92 l i t .

B a i 5: Hoa t a n hoan t o a n a gam h o n hop X gom Fe va FeaOs t r o n g dung

dich H C l t h u dUOc 2,24 Ht k h i H2 of dktc va dung dich B. Cho dung
dich B tac dung dung dich N a O H du, loc lay k e t tua, nung trong
k h o n g k h i den k h o i liTOng k h o n g doi t h u dtfoc 24 gam chat r ^ n . Gia
t r i cua a la
A. 13,6 gam.

B. 17,6 gam.

C. 21,6 gam.

D. 29,6 gam.

B a i 6: H o n hop X gom M g va AI2O3. Cho 3 gam X tac dung v d i dung

mbw.

PHl/ONG

PHAP TANG GIAM K H O I

LUONG

N p i d u n g : Nguyen tac cua phUOng phap la xem k h i chuyen tii chat A

H<

t h a n h chat B (khong n h a t t h i e t triTc tiep, c6 the bo qua nhieu giai

B

doan t r u n g gian) k h o i l i i g n g t a n g hay g i a m bao nhieu gam thi/dng t i n h

B<

theo 1 mol) va dvla vao k h o i liTcfng thay doi t a de dang t i n h dugc so"

mol chat da t h a m gia p h a n iJng hoSc ngiigc l a i . V i du t r o n g p h a n ufng:

> M C I 2 + H 2 O + COzt

M C O 3 + 2HC1

dich H C l du g i a i phong V Ht k h i (dktc). Dung dich t h u dUdc cho tac

| T a t h a y rkng k h i chuyen 1 m o l M C O 3 t h a n h M C I 2 t h i k h o i lugng tSng

dung v d i dung dich N H 3 du, loc va nung k e t t u a daoc 4,12 gam hot

"

(M + 2

oxit. V CO gia t r i l a :
A. 1,12 l i t .

B. 1,344 l i t .

C. 1,568 l i t .

Trong p h a n ufng este hoa:

t h i tCr 1 m o l R - O H chuyen t h a n h 1 m o l este k h o i Itrgng tSng

clo du t h u diTOc 5,763 gam h 5 n hop muoi. P h a n t r a m k h o i lUdng cua

(R' + 59) - (R' + 17) = 42 gam.

Fe t r o n g A la

N h u vay neu biet k h o i li/gng cua rufgu va k h o i lirgng cua este t a de

B. 16,8%.

- Khoi

C. 19,2%.

dang t i n h dugc so m o l rirgu hoSc ngugc l a i .

D. 22,4%.

V d i bai tap cho k i m loai A day k i m loai B ra k h o i dung dich muoi difdi

A 2007): D o t chay hoan toan m o t the t i c h k h i thien

dang til do:

n h i e n gom metan, etan, propan bSng oxi k h o n g k h i (trong k h o n g khi

- K h o i li/gng k i m loai tSng b^ng me

oxi chiem 20% the tich), t h u duac 7,84 l i t k h i C O 2 (dktc) va 9,9 gam

BAI TAP

hoan t o a n li/cfng k h i t h i e n n h i e n t r e n la
B. 78,4 l i t .

C. 84,0 l i t .

B a i 10: D o t chay hoan toan m gam hon hgp Y gom

va

Dap

B. 8,14 gam.

C. 4,18 gam.

DgNG

A. 4,24 gam.

B. 2,48 gam.
HU&ng

C4H8

MgCl2

va Cu(N03)2 vao n\ldc dirge

C. 4,13 gam.
dan

D. 1,49 gam.

giai

Ap dung d i n h luat bao toan khoi lirgng: Sau mot khoang thdi gian do tSng

t h i t h u di/gc 12,98 gam C O 2 va 5,76 gam H 2 O . Vay m c6 gia t r i la

A. 1,48 gam.

(tan).

dung dich sau phan ufng t h u dirge m gam muoi k h a n . Gia t r i m 1^

D. 0,448 l i t
C2H6, C3H4

niA

dung dich A. N h i i n g vao dung dich A mot t h a n h sSt. Sau mot khoang

gam muoi khan. Hay t i n h the tich k h i H 2 t h u dagc d dktc.

C. 0,224 l i t

t h d i gian lay t h a n h sSt r a can l a i thay t a n g t h e m 0,8 gam. Co can

H C l thu duac dung dich A va k h i H 2 . Co can dung dich A t h u dirge 5 , 7 1

B. 0,112 l i t .

VAN

B a i 1: Hoa t a n 3,28 gam h 5 n hgp muoi

D. 56,0 l i t .

B a i 9: Hoa t a n hoan toan 5 gam hon hap 2 k i m loai X va Y hhng dung dich

A. 0,56 l i t .

(b^m)

- K h o i lugng k i m loai g i a m hkng m/, aan) - T^B (Um)-

H 2 O . The t i c h k h o n g k h i d (dktc) nho n h a t can dung de dot chay

A. 70,0 l i t .

> CH3-COOR' + H 2 O

C H 3 - C O O H + R'-OH

dich H C l dif g i a i phong 0,1 gam k h i . Cho 2 gam A tac dung v d i k h i

B a i 8: {CD

35,5) - ( M + 60) = 11 gam

t i n h liiong C O 2 bay r a .

D. 2,016 l i t .

B a i 7: H o n hcfp A gom M g , A l , Fe, Z n . Cho 2 gam A tac dung v d i dung

A. 8,4%.

va CO 1 mol C O 2 bay ra. N h u vay k h i biet li/gng muoi tSng, t a c6 the

'

D. 16,04 gam

khoi lirgng cua t h a n h Fe bSng do giam khoi lirgng eua dung dich muoi.
Do do: m = 3,28 - 0,8 = 2,48 gam.

an

Chon dap a n B.

1. D

2. C

3. C

4. D

5. C

6. C

7. B

8. A

9. C

10. C

B a i 2: {CD

- Khoi

A 2007): Cho 5,76 gam axit hufu ca X dan chdc, m a c h

ho tac dung h e t v d i CaCOa t h u dirge 7,28 gam m u o i cua a x i t hiJu cO.

Cong thiJc cau tao t h u ggn cua X la

7
^

A. C H 2 = C H - C O O H .

B. C H 3 C O O H .

C. H C ^ C - C O O H .

D. C H 3 - C H 2 - C O O H .

HUdng

dan

p a i 5: N g a m mot v a t b&ng dong c6 k h o i lUdng 15 gam trong 340 gam dung

giai

dich AgNOa 6%. Sau mot thcJi gian lay v a t r a t h a y k h o i luong AgNOa

D a t CTTQ c u a axit hOru ccf X don chufc la RCOOH.

trong dung dich g i a m 25% K h o i liiOng cua v a t sau p h a n ufng la

> ( R C 0 0 ) 2 C a + COzt + H 2 O

2 R C 0 0 H + CaCOs

Cuf 2 mol axit p h a n lifng tao muoi thi khoi lirgng tang (40 - 2) = 38 gam.
X mol axit <

(7,28 - 5,76) = 1,52

^ 5 ^

38

^ ^2 ^ R = 27
nAgNo,,ph..,g.

^ A x i t X: C H 2 = C H - C O O H .

Cu + 2AgNO,3

Chon dap a n A.
B a i 3: Hoa tan hoan toan 23,8 gam hon hop mot muoi cacbonat cua kim
loai hoa tri (I) v a mot muoi cacbonat ciia k i m loai hoa t r i (II) bSng dung
dich H C l t h a y thoat ra 4,48 lit k h i CO2 (dktc). Co c a n dung dich t h u
diicfc sau phan umg t h i khoi lugng muoi k h a n thu diicfc l a bao nhieu?

B. 28,0 gam.

C. 26,8 gam.

HUcfng dan

D. 28,6 gam.

gidi

" m u t f l cacbonat =

> Cu(N03)2 + 2 A g i

0,015 <- 0,03

> 0,03 mol

n i v a t sau phan ijfng H l v a t ban dau +

khoi

gam.

(tan)

B a i 6: Cho dung dich AgNOs dir tac dung v d i dung dich h o n hgtp c6 hoa
tan 6,25 gam h a i muoi K C l va K B r t h u C^iac 10,39 gam h o n hop A g C l
A. 0,08 mol.

B. 0,06 mol.

C. 0,03 mol.
dan

D. 0,055 m o l .

gidi

> k h o i li/(?ng t a n g : 108 - 39 = 69 gam;

0,06 mol <

khoi li/ong tang: 10,39 - 6,25 = 4,14 gam.

Vay t o n g so m o l h o n hop dau la 0,06 mol.

B a i 4: Cho 3,0 g a m m o t a x i t no, don chiJc A t a c dung vCfa du v d i dung

dich N a O H . Co c a n dung d i c h sau p h a n iJng thu dtfoc 4,1 g a m

muoi

k h a n . CTPT c u a A la

Chon dap a n B.
B a i 7: N h i i n g mot t h a n h g r a p h i t diiOc phu m o t Idp k i m loai hoa t r i (II)
vao dung dich CUSO4 di/. Sau p h a n ufng k h o i lii(?ng cua t h a n h g r a p h i t

B. C3H7COOH
HU&ng

C. CH3COOH
dan

D. C2H5COOH.

giam di 0,24 gam. Cung t h a n h g r a p h i t nay neu difoc n h i i n g vao dung

dich AgN03 t h i k h i p h a n ufng xong t h a y k h o i liiong t h a n h g r a p h i t

gidi

t a n g len 0,52 gam. K i m loai hod t r i ( I I ) la k i m loai nao sau day?

Cuf 1 mol a x i t don chufc tao t h a n h 1 m o l muoi t h i k h o i li/cJng tang

A. Pb.

B. Cd.

(23 - 1) = 22 gam, ma theo dau bai khoi liTOng muoi t a n g (4,1 - 3) = 1,^

11

= 0,05 mol. -> Maxit =

= 60 g a m .

D a t CTTQ c u a a x i t no, don chuTc A la C H 2 n + i C 0 0 H n e n t a c6:

14n + 46 = 60

n = 1.

Vay CTPT cua A la CH3COOH.

C. A l .
Hii&ng

gam nen so mol axit la

Chon dap a n C.

"~ m C u

Chon dap a n C .

Hitdng

tong k h o i liTOng muoi k h a n thu difdc l a 23,8 + 2,2 = 26

naxit =

(bam)

CUT 1 mol muoi halogen tao t h a n h 1 mol k e t t u a

mol.

0,2

Chon dap a n A.

A. H C O O H

^lAg

= 15 + (108.0,03) - (64.0,015) = 17,28 gam.

Suy ra k h o i Itfcfng muo'i k h a n t a n g sau p h a n ufng l a 0,2.11 = 2,2 gam.

Vay

gidi

25
0 , 1 2 . = 0,03 mol.
100

luong muoi k h a n t a n g (71 - 60) = 11 gam, ma

~

dan

D. 24,12 gam.

va AgBr. Hay xac d i n h so mol h 6 n hop dau.

Cur 1 mol muoi cacbonat tao t h a n h 1 m o l muoi clorua cho n e n

J^CO^

C. 17,28 gam.

Hitdng
_

_ _340^

0,08

A. 26,0 gam.

B. 2,28 gam.

gam.

> (RC00)2Ca)

(40 la Ca vao - 2 la H r a 2 R C 0 0 H
1^52^ ^

A. 3,24 gam.

dan

D. Sn.

gidi

Dat k i m loai hoa t r i ( I I ) la M v d i so gam la x (gam).

M + CUSO4

> MSO4 + Cu

Cuf M gam k i m loai t a n r a t h i se c6 64 gam Cu bam vao. Vay k h o i

li^Ong k i m loai g i a m ( M - 64) gam;
Vay: x (gam) = ^''^'^^ ^
M -64

^^loi liiong k i m loai g i a m 0,24 gam.

M a t khac: M + 2AgN03
> M(N03)2 + 2Ag
Cuf M gam k i m l o a i t a n r a t h i se c6 216 gam A g bam vao. V a y khS'i
luang k i m loai tSng (216 - M ) gam;
0 52 M
Vay: x (gam) = ' - <
k h o i luong k i m loai tSng 0,52 gam.
216
^
, 0,24.M
0,52.M
- . - . o n i
nA^
Ta c6:
=
> M = 112 ( k i m loai Cd).
M-64
216-M
Chon dap a n B.
B a i 8: Co 1 l i t dung dich h o n hop NazCOa 0,1 mol/1 vk (NH4)2C03 0,25
mol/1. Cho 43 gam h 6 n hgfp BaCh va CaCh vao dung dich do. Sau k h i
cac p h a n ufng k e t thiic t a t h u diTcfc 39,7 gam k e t t i i a A va dung dich B.
T i n h % k h o i luTOng cac chat t r o n g A.
A. % m 3 , ^ ^

B. %m^,co,

= 50%,

%mcco, =

50%-

= 50,38%, %m^^^

= 49,62%.

C. %m^co, = 49,62%, %mcco, = 50,38%.

D. K h o n g xac d i n h duoc.

Ht^&ng dan gidi

T r o n g dung dich:

NazCOg

Hiiceng dan gidi

K h i CI2 d i i chi khijf difcfc muoi N a l theo phifofng t r i n h
2 N a I + CI2
> 2 N a C l + I2
CiJ 1 mol N a l tao t h a n h 1 m o l N a C l
> K h o i lUdng muoi g i a m 127 35,5 = 91,5 gam.
Vay: 0,5 mol <

> 2NH4" + COa^-

=> m N a i = 150.0,5 = 75 gam

Hii&ng dan gidi

Yi t r o n g cung dung dich c6n l a i (cung the tich) n e n :
[ZnS04] = 2,5 [FeS04]
^

2,5x < - 2,5x <

Fe + CuS04
X

=>

T h a n h p h a n cua A:

%m3,co3 =

'

%"icaco, =

Chon dap a n C.

n i l Q7

'

39,7

.100 = 49,62%;

- 49,62 = 50,38%.

x <

(1)

2,5x m o l
>FeS04 + Cu^
X

- >

(2)

mol

nicu ( b ^ m ) - nizn (tan) " T^Fe (tan)

^
=>

= 0,1 m o l ; y = 0,2 m o l .

<-

> ZnS04 + C u i

TCr (1), (2) n h a n dirac do g i a m k h o i l i / a n g cua dung dich la

Vay: m c u

' l 9 7 x + 100y = 39,7

"znso, =2,5np^so^

Zn + C U S O 4

Goi X , y la so m o l BaCOg va CaCOg t r o n g A t a c6:

+ y = 0,3

m N a C i = 104,25 - 75 = 29,25 gam.

Chon dap a n A.
B a i 10: N h i i n g m o t t h a n h k e m va m o t t h a n h s^t vao cung m o t dung
dich C U S O 4 . Sau m o t t h 6 i gian lay h a i t h a n h k i m l o a i r a t h a y t r o n g
dung dich c6n l a i c6 nong do m o l ZnS04 bang 2,5 I a n nong do m o l
FeS04. M a t khac, k h o i liTcfng dung dich g i a m 2,2 gam. K h o i lifcfng
dong bam l e n t h a n h k e m va b a m l e n t h a n h ski I a n liiOt la
A. 12,8 gam; 32 gam.
B. 64 gam; 25,6 gam.
C. 32 gam; 12,8 gam.
D. 25,6 gam; 64 gam.

> Ba^" + 2 C r

CaCla
> Ca^^ + 2 C r
Cac p h a n iJng:
Ba^^ + COg^> BaC03i
(1)
Ca'" + CO3'> CaCOg^
(2)
Theo (1) va (2) cuf 1 mol BaCl2, hoSc CaClz bien t h a n h BaCOg hoSc
CaCOg t h i k h o i iLfOng muoi g i a m (71 - 60) = 11 gam. Do do t o n g so
43 39 7
mol h a i muoi BaCOg va CaCOg bang:
' = 0,3 m o l
M a t o n g so m o l COg^' = 0,1 + 0,25 = 0,35, dieu do chufng to du COg^'.
X

K h o i lugrng muoi giam 104,25 - 58,5 = 45,75 gam.

> 2Na^ + COg^'

(NH4)2C03

BaClz

a i 9: Hoa t a n hoan toan 104,25 gam h o n hop X gom N a C l v^ N a l vao

Vnuf<Jc dugc dung dich A. Sue k h i CI2 du vao dung dich A. K e t thuc t h i
n g h i e m , c6 can dung dich t h u daoc 58,5 gam muoi k h a n . K h o i laong
N a C l C O t r o n g h 6 n hop X la
A. 29,25 gam.
B. 58,5 gam.
C. 17,55 gam.
D. 23,4 gam.

mcu

(Wm

2,2 = 64.(2,5x + x) - 65.2,5x - 56x

X

= 0,4 m o l .

len thanh

kgra) = 64.2,5.0,4 = 64 gam;

(bdm l e n t h a n h s^t)

= 64.0,4 = 25,6 gam.

Chon dap a n B.
^ a i 1 1 : N h u n g t h a n h k e m vao dung dich chiJa 8,32 gam CdS04. Sau k h i
khuf hoan toan ion Cd^^ k h o i luong t h a n h k e m tSng 2,35% so v d i ban
dau. H o i k h o i \\iCng t h a n h k e m ban dau.
A. 60 gam.
B. 70 gam.
C. 80 gam.
D . 90 gam.

HiCcfng ddn

giai

Goi k h o i luong t h a n h k e m ban dau la a gam t h i k h o i lugng t a n ^

^

2,35a

t h e m la

B a i 1 3 : Cho 3,78 gam hot A l p h a n urng vCra du v d i dung dich muoi X C I 3

tao t h a n h dung dich Y. K h o i ItTofng chat t a n t r o n g dung dich Y g i a m
4,06 gam so v d i dung dich XCI3. X a c d i n h cong thufc cua muoi XCI3.
B . AICI3.

A. F e C l 3 .

gam.

100

HU&ng ddn

> ZnS04 + C d
> 112, t a n g (112 - 65) = 47 gam
(= 0,04 mol)
>
gam

Zn + CdS04
65 ^ 1 mol
^
208
Ta

CO

1
0,04

47

= -^^-^

Al

XCI3

= (0,14 mol)

100

Chon dap a n C .
B a i 12: N h i i n g t h a n h k i m loai M hoa t r i 2 vao dung dich CUSO4, sau
m o t t h d i gian lay t h a n h k i m loai ra t h a y k h o i luong g i a m 0 , 0 5 % . Mat
khac n h i i n g t h a n h k i m loai t r e n vao dung dich Pb(N03)2, sau m o t then
gian t h a y k h o i liiOng t a n g 7,1%. X a c d i n h M , biet r a n g so m o l C u S O ,
va Pb(N03)2 t h a m gia d 2 triTdng hgfp nhir nhau.
A. A l .
B. Zn.
C. Mg.
D. F e .
Hiic/ng ddn giai
Goi m la k h o i liiong t h a n h k i m loai, M la nguyen tilf k h o i cua kim
loai, X la so' mol muoi p h a n lifng.
M + CUSO4
> MSO4 + C u i
M (gam) -> 1 m o l

gidi

AICI3

->

0,14

o no

> a = 80 gam.

2,35a

D. K h o n g x a c d i n h .

G o i A l a nguyen tijf k h o i c u a k i m loai X .

100

t i le:

C. C r C l s .

0,14 m o l

T a c 6 : (A + 35,5.3).0,14 - (133,5.0,14) = 4,06

G i a i ra difOc: A = 56.
Vay k i m loai X l a F e va muoi F e C l s .

Chon dap a n A .
B a i 14: Nung 100 gam hon hop gom Na2C03 va NaHCOg cho den, k h i khoi
iLfOng hon hop khong doi diTOc 69 gam chat r S n . Xac d i n h phan t r a m
khoi \\igng cua m5i chat tuong ijfng trong hon hop ban dau.
A. 1 5 , 4 % va 8 4 , 6 % .

B . 2 2 , 4 % va 7 7 , 6 % .

C. 1 6 % va 8 4 % .

D. 2 4 % va 7 6 % .

> 64 gam, g i a m ( M - 64) gam.

Hii&ng

ddn

gidi

0,05.m

X mol

>

giam

gam.

C h i CO NaHCOg b i p h a n buy. D S t x l a so gam N a H C O g .

0,05.m

2NaHC03

=^x=-^l00M-64

(1)

M + Pb(N03)2 -> M(N03)2 + P b i

M (gam) -> 1 m o l
> 2 0 7 , t a n g (207 - M ) gam
,
77,l.m
,l.m
X mol
>
tang
gam
100

> k h o i ItfOng g i a m : 100 - 69 = 31 gam

.168

62

l a co:

> x = 84 gam.
X

01

C h o n dap a n C.

= ^ 0 0 207-M

(2)
0,05.m

T C ( l ) v a ( 2 . t a c 6 : ^

= ^

B a i 1 5 : H o a t a n 3,28 gam h 6 n hop muoi CuCl2 va Cu(N03)2 vao nildc difOc

dung dich A. N h i i n g M g vao dung dich A cho d e n k h i m a t m a u x a n h

7,l.m

TCf (3) giai r a M = 65. V a y k i m loai M l a k e m .

C h o n dao a n B .

> k h o i li/Ong g i a m : 44 + 18 = 62 g a m

Vay N a H C 0 3 c h i e m 8 4 % va Na2C03 c h i e m 1 6 % .

7,l.m
^

Cur n u n g 168 gam

Na2C03 + C O a t + H2O

cua dung dich. L a y t h a n h M g ra c a n l a i t h a y t^ng t h e m 0,8 gam.

,3,

Co

c a n dung dich sau p h a n ufng thu dugc m g a m muoi k h a n . T i n h m ?

A. 1.28 gam.

B. 2,48 gam.

C. 3,1 gam.

D. 0,48 gam.

HuCdng dan

giai

Ta c6:
mtang = m c u - mMg phan tog =

nip^2, - nij^^a, = 3,28

- (nig^,^;, + m^^^, j =

0,8

B a i 6. Dung CO de khuf 40 gam oxit Fe203 thu difcfc 33,92 gam chat rSn

^ m = 3,28 - 0,8 = 2,48 gam.

Chon dap an B.

B A I T A P V A N DgNG
B a i 1 . Cho 115 gam hon hgfp gom ACO3, B2CO3, R2CO3 tac dung het vdi

dung dich HCl thay thoat ra 22,4 Ht CO2 (dktc). Khoi Itrgng muoi
clorua tao ra trong dung dich la
A. 142 gam.

B. 126 gam.

C . 141 gam.

D. 132 gam.

B a i 2. Ngam mot la sMt trong dung dich C U S O 4 . Neu biet khoi luong
dong bam tren la sSt la 9,6 gam t h i khoi lifcfng la sSt sau ngam tang
them bao nhieu gam so vdx ban dau?
A. 5,6 gam.

B. 2,8 gam.

B a i 5. Cho luong k h i CO di qua 16 gam oxit sat nguyen chat duac nung
nong trong mot cai ong. IChi phan ufng thiic hien hoan toan va ket
thiic, thay khoi liTOng ong giam 4,8 gam. Xac dinh cong thiJc va ten
oxit sat dem dung.

C . 2,4 gam.

D. 1,2 gam.

B a i 3. Cho hai thanh sSt c6 khoi lifdng bang nhau.

- Thanh 1 nhiing vao dung dich c6 chula a mol AgNOa.
- Thanh 2 nhiing vao dung dich c6 chiJa a mol Cu(N03)2;
Sau phan uTng, lay thanh s^t ra, say kho vk can lai thay se cho ket
qua nao sau day?

B gom Fe203, FeO va Fe. Cho - B tac dung vdi H2SO4 loang dir, thu
2
dacfc 2,24 lit khi H2 (dktc).
Xac dinh thanh phan theo so mol chat ran B, the tich k h i CO (dktc)
toi thieu de c6 duoc ket qua nay.
Bai 7. Nhiing mot thanh sat nSng 12,2 gam vao 200 ml dung dich CUSO4
0. 5M. Sau mot thdi gian lay thanh kim loai ra, c6 can dung dich diroc
15,52 gam chat ran khan.
a) Viet phLfOng trinh phan ling xay ra, tim khoi Itfcfng tCrng chat c6
trong 15,52

gam chat r ^ n khan.

b) Tinh khoi lucfng thanh kim loai sau phan ling. Hoa tan hoan toan
thanh kim loai nay trong dung dich HNO3 dSc nong, du thu dtfOc
k h i NO2 duy nhat, the tich V lit (do d 27,3 C, 0,55 atm). Viet cac
phuong t r i n h phan ufng xay ra. Tinh V.
Bai 8. Ngam mot thanh dong c6 khoi lirong 140,8 gam vao dung dich
AgN03 sau mot thdi gian lay thanh dong dem can lai thay nSng 171,2
gam. Tinh thanh phan khoi liTcyng cua thanh dong sau phan iJng.
Dap a n

A. Khoi lirong hai thanh sau nhung vSn bang nhau nhtfng khac ban dau.

1. B

B. Khoi li/ong thanh 2 sau nhiing nho hcfn khoi luong thanh 1 sau nhiing.

6. Vco = 8,512 l i t ;

C. Khoi lUdng thanh 1 sau nhiing nho hon khoi liTOng thanh 2 sau nhiing.

D. Khoi lifOng hai thanh khong doi vSn nhiT trtfdc k h i nhiing.
B a i 4. Cho V l i t dung dich A chufa dong th6i FeCl3 I M va Fe2(S04)3 0,5M
tac dung vdfi dung dich Na2C03 c6 du, phan ufng ket thiic thay khoi
lirong dung dich sau phan iJng giam 69,2 gam so vdi tong khoi li/ong
cua cac dung dich ban dau. Gia t r i cua V la:
A. 0,2 lit.

B. 0,24 lit.

C . 0,237 lit.

D.0,336 lit.

2. D.

3. B.
%nFe

4. A.

= 46,51% ;

%nFeo

5. FegOs.
= 37,21% ;%nF,^o, = 16,28%.

7. a) 6,4 gam CUSO4 va 9,12 gam FeS04.

b)

mKL=

12,68 gam; V^o^ = 26,88 lit.

8. Thanh Cu sau phan ling c6

mAg(b&m)

= 43,2 gam v^

mcu(cbniai)

= 128 gam.

V d i cac cong thuTc:

VIII. PHlJONG P H A P GIA TRj T R U N G BJNH

Nguyen tSc cua p h L f O n g phap n h u sau: K h o i Itfcfng phan tuf t r u n g b i n h

C.H^O, ; n,mol

( K L P T T B ) ( k i hieu M ) cung

C^.Hy.O,.; n^mol

(KLNTTB)

chinh

la

nhi/

khoi

k h o i lifong cua

liTOng

nguyen tuf t r u n g b i n h

mot mol

h 5 n h o p , n e n no diioc

t i n h theo cong thufc:

Ta c6: - Nguyen tijf cacbon t r u n g b i n h : x =

^ _ t6ng khoi luong h6n hap (tinh theo gam)

- Nguyen tuf h i d r o t r u n g b i n h : y -

_ M,n, + M , n , + M3n3 + _ X ^ j ^ j

(D

Jn^

t r o n g d o M i , M a , - l a K L P T (hoSc K L N T ) cua cac chat t r o n g h o n hop;

ni, n2,... la so m o l ttfong

ufng

cua cac chat.

xi, X 2 , . . .

2."i

l a % so

m o l ti/ong

B a i 1 : (Khoi A - TSDH

Cho 4,48 l i t h o n h o p X (d dktc) gom 2 hidrocacbon mach h d l o i iii tii

(2)

(cung c h i n h

ufng

la

A. C2H2 va C4H6.

B . C2H2 va C4H8.

C. C3H4 va C4H8.

D . C2H2 va C3H8.

% k h o i luong)

Hii&ng dan gidi

cua cac chat. DSc biet d o i v d i chat k h i t h i x i , X 2 , ... cung c h i n h l a %

4 48

the t i c h n e n cong thufc (2) c6 t h e v i e t t h a n h :

^ -

"hhx = '
hhx
22,4 = 0,2 m o l

M,V,+M,V,-hM3V3^-..._lM.V,
v,.v,.V3....'

nam 2007):

gam. Cong thufc p h a n tuf cua 2 hidrocacbon la

3 . ^ + ...

M = M,x, + M2X2 + M3X3 + ...

do

BAI T A P AP D U N G

toan, so m o l Br2 g i a m d i m o t niJfa va k h o i li/ong b i n h t a n g t h e m 6,7

M =M , . ^ + M ^ . ^ + M

trong

n , H: n2 + ...

qua b i n h chufa 1,4 l i t dung dich Br2 0,5M. Sau k h i p h a n iJng hoan

Cong thufc (1) CO the v i e t t h a n h :

Z^.

+...

. - _ y i H , + y^n^ +

long so mol cac chat trong h6n hop

n , + n 2 + n3 + ...

n, +

nBr.,badiu

Zv.

= 1,4x0,5 = 0,7 m o l
07

t r o n g d o V i , V2,... l a t h e t i c h cua cac chat k h i . N e u h o n h o p c h i c6 2

chat t h i cac cong thufc (1), (2), (3) tuong ufng t r d t h a n h (1'), (2'), ( 3 ' )
nhif sau:

^^Br,pi,g

= 0>35 mol. (giam m o t nufa l a k h o i li/Ong p h a n ufng)

Khoi lifOng b i n h Br2 tang 6,7 gam la so gam ciia hidrocabon khong no.
D a t C T T B ciia h a i hidrocacbon mach h d l a C^H2s^2-2s
k e t 7t t r u n g b i n h ) .

Phuong t r i n h p h a n iJng:

t r o n g d o n l a t d n g s o s o ' m o l cua cac chat t r o n g h o n h o p ,

M = MiXi+M2(l-Xi)

C-H,-^,_,- + aBr,

>

<^T^^2T,.i-2^h^

0,2 m o l

(2')

t r o n g do con so 1 iJng v d i 100% v a

^ ^ M,V.+M,(V-V.)

so l i e n

^g,j

t r o n g do V i l a t h e t i c h k h i thdf n h a t v a V l a t o n g the t i c h h o n hap.

Tii cong thufc t i n h K L P T T B t a suy r a cac cong thufc t i n h K L N T T B .

_^

0 ^5
0,2

^ ^

- > 0,35 m o l
67
_^ i 4 n + 2 - 2 a = - ^ ^ i i = 2,5.
0,2

Do h a i hidrocacbon mach h d p h a n ufng hoan toan v d i dung dich Br2

nen chiing deu l a hidrocacbon k h o n g no. V a y h a i hidrocacbon do la
C2H2 va C4H8. C h o n dap a n B.

B a i 2: Hoa t a n hoan toan 2,84 gam h o n hop h a i muoi cacbonat cua h a i

k i m loai p h a n n h o m I I A va thuoc h a i chu k y l i e n tiep t r o n g bang t u a n

Hiidng dan gidi

hoan bang dung dich H C l t a t h u dirgrc dung dich X va 672 m l CO2 (a

dktc).

Cdch 1:

1. H a y xac d i n h t e n cac k i m l o a i .
A. Be, M g .

Goi X la % the t i c h cua SO2 t r o n g h o n hop ban dau, t a c6:

B. M g , Ca.

C. Ca, Ba.

D. Ca, Sr.

M = 16.3 = 48 = 64.x + 32(1 - x) ^ x = 0,5

2. Co can dung dich X t h i t h u duoc bao nhieu gam muoi khan?

A. 2 gam.

B. 2,54 gam.

C. 3,17 gam.

Vay: moi k h i chiem 50%. NhiT vay trong 20 l i t , moi k h i chiem 10 l i t .

Goi V la so l i t O2 can t h e m vao, t a c6:

D. 2,95 gam.

M ' = 2,5.16 = 40 = ^ ^ , i ^ 3 2 a 0 l V )

Hiidng dan gidi

20+ V

1. Goi A la k i m loai d a i dien cho 2 k i m loai can t i m

G i a i r a CO V = 20 h t .
Chon dap an B.

Cac phtfong t r i n h p h a n i l n g l a
ACO3 + 2HC1
0,03mol

Cdch 2:

> ACI2 + H2O + C 0 2 t

<-

Hon hop k h i ban dau coi nhiT k h i thuf nhat (20 l i t c6 M = 16x3 = 48),
con O2 t h e m vao coi nhif k h i thur h a i , ta c6 phiTOng t r i n h :

0,03mol

M = 2.5.16 = 40 =
n^o
'''''

=^^-0,03mol.
22,4

Chon dap a n B.
B a i 4: Co V l i t k h i A gom H2 va h a i olefin la dong dang l i e n t i e p , t r o n g

M =^
= 94,67 va MA,B = 94,67 - 60 = 34,67
0,03
V i thuoc 2 chu k y l i e n tiep nen h a i k i m loai do 1^ M g ( M = 24) va
Ca ( M = 40).
Chon dap an B.

do H2 chiem 60% ve the t i c h . D a n h6n hc*p A qua bot N i nung ,n6ng

I

dugtc h8n hcfp k h i B. Dot chay hoan toan k h i B di/dc 19,8 gam CO2 va
13,5 gam H2O. Cong thiJc cua h a i olefin la
A. C2H4 va C3H6.

B. CaHe va C4H8.

C . C4H8 va C5H10.

D. C5H10 va CgHiz.

2. KI^PTTB cua cac muoi clorua:

Hin^uoi clorua

HUofng dan gidi

34,67+ 71 = 105,67.

D a t C T T B cua h a i olefin la C ^ H ^ s .

= 105,67 . 0,03 = 3,17 gam.

( j cung dieu k i e n n h i e t do va ap suat t h i the t i c h t y le v d i so' moi k h i .

Chon dap an C.
B a i 3: H5n hop k h i SO2 va O2 c6 t i k h o i so v d i CH4 bang 3. Can t h e m
bao nhieu l i t O2 vao 20 l i t h o n hap k h i do de cho t i k h o i so v d i CH4
g i a m d i - , tufc b k n g 2,5. Cdc h 6 n hop k h i d cung dieu k i e n n h i $ t do
6
va ap suat.
A. 10 l i t .

B. 20 l i t .

20+ V

Rut r a V = 20 l i t .

Vay K L P T T B cua cac muoi cacbonat l a

Mc,c.=

iM^^,

C. 30 l i t .

D. 40 l i t .

H6nhopkhiAc6:

=M . 2
0,6
3

A p dung d i n h luat bao toan kho'i luong va d i n h luat bao toan nguyen
tuf
Dot chay h 5 n hop k h i B cung c h i n h la dot chay hon hop k h i A.
Ta c6:

C.H^R +

>

2H2 + O2

> 2H2O

i i CO2 + i i H2O

(1)
(2)

Theo phuong t r i n h (1) t a c6:

n^o^ = n^o = 0>45 m o l .

=^ "cn, =
T o n g : n^,, = ^

0,45

B a i 6: T r o n g t u n h i e n , dong (Cu) t o n t a i dudi hai d a n g dong v i " C u

*,Cu . K L N T (xap x i k h o i liiOng t r u n g b i n h ) cua Cu la 63,55. T i n h %

,
mol.

ve k h o i luong cua m 6 i loai dong v i .

= 0,75 m o l => n^o,^.,, = 0,75 - 0,45 = 0,3 m o l

=> n,,^ = 0,3 m o l .

T a c 6 : ^

= - M 5 . 2 ^ _ ^

n,,^

0,3.n

A. '^^Cu: 27,5% ; "^^Cu: 72,5%.

B. ^^Cu: 70% ; ^^Cu: 30%.

C. '^^Cu: 72,5% ; '^^Cu: 27,5%.

D . ^^Cu: 30% ; ^^Cu: 70%.

HiCcfng dan

gidi

Goi X la % cua dong v i ^^Cu ta c6 phucrng t r i n h :

M = 63,55 = 65.x + 63(1 - x) : ^ x = 0,275

=> H a i olefin dong d ^ n g l i e n t i e p la C 2 H 4 va CsHe. Chon dap a n B.

V a y : dong v i ^^Cu c h i e m 27,5% va dong v i ^^Cti c h i e m 72,5%.

B a i 5: Tach nUdc hoan toan til hon hop X gom 2 ancol A va B t a duoc

Chon dap an C.

hon hop Y gom cac olefin. Neu dot chay hoan toan X t h i t h u dtfdc 1,76
gam C O 2 . K h i dot chay hoan toan Y t h i tong k h o i lucfng H 2 O vk

B a i 7: Dot c h a y h o a n toan a g a m h 6 n hop h a i rUcfu no, ddn chuTc l i e n

CO,

tiep trong day dong d i n g thu di/oc 3,584 lit C O 2 d dktc va 3,96

tao ra la

gam

H 2 O . T i n h a va x a c d i n h C T P T cua cac rirgu.

A. 2,94 gam.

B. 2,48 gam.

C. 1,76 gam.

HU&ng

dan

D . 2,76 gam.

gidi

A. 3,32

gam;

C H 3 O H va C 2 H 5 O H .

B. 4,32

gam; C 2 H 5 O H va C 3 H 7 O H .

C. 2,32

gam;

C 3 H 7 O H va C 4 H 9 O H .

D. 3,32

gam; C 2 H 5 O H va C 3 H 7 O H .

Hii&ng

H o n hop X gom h a i ancol A va B tach n\l6c dtroc olefin (Y) -> hai
ancol la ruou no, don chiJc.

CH2s.,

p h a n iJng sau:
> nCO^

+ (n + DH^O

CH,,.OH

C,H,, + H2O

nCO,

- K h i dot chay X va dot chay Y cumg d i o so m o l C O 2 n h u nhau.

- D o t chay Y(olefin hay anken) t h i n^o^ = M^^Q .
Vay dot chay Y cho t o n g
(mco^ + m^o) = 0,04.(44 + 18) = 2,48 gam.

+ {n +

DH.O

mol -> (n + 1) x m o l

= 0,22 m o l

(1)

(2)

TCr (1) va (2) g i a i r a x = 0,06 va f i = 2,67.

+ hH,0

xet:

> nCO^
>

'\i
n^o = ( i i + l ) x = ^

(Y)
CH, + ^O,

gidi

3,584
" C O , = S . x = ^ ^ ^ = 0,16mol
22,4

Chon dao a n B.

+ O 2

x mol

CH2,,0H +

dan

Goi i i la so n g u y e n tuf C t r u n g b i n h va x la tong so mol cua h a i rUOu.

D a t C T T B cua h a i ancol A , B la C-II^j^^OH t a c6 cac phiicfng t r i n h

Nhan

va

Ta c6: a = (14 ri + 18).x = (14. 2,67).0,06 + 18.0,06 = 3,32 gam.

i i = 2,67 =

f C2H5QH
^

CgH^OH

Chon dap a n D .
B a i 8: Cho 2,84 gam h o n hcfp 2 rxiqu don chiJc l a dong dang l i e n t i e p
nhau tac dung v d i m o t liXcfng N a vCra du tao ra 4,6 gam chat rSn va V
l i t k h i H 2 6 dktc. T i n h V.
A. 0.896 l i t .

B. 0.672 l i t .

C. 0.448 l i t .

D . 0,336 l i t .

Ta c6:

Hiictng dan giai

-J^Q'^RCOOH

Cdch 1:

^ Q ' ^ R C H J C O O H

D a t R l a goc hidrocacbon t r u n g b i n h va x la t o n g so m o l cua 2 rirau.

ROH + Na
X

> RONa + - H
2 '

mol

> X

Ta c6:

+ 17)x = 2,84

(R +

39)X = 4,6

H C O O H ( M = 46) va

-> .

G i a i r a duac x = 0,08.

V i M a x i t = 53

nen

M ^ , , = 53

muoi

= 75.0,1 = 7,5 gam.

!hon dap a n B.
B a i 10: H 5 n hap 3 rtrau dan chiJc A , B, C c6 t o n g so m o l l a 0,08 v ^ k h o i
laang la 3,38 gam. Xac d i n h CTPT cua rifofu B, b i e t r a n g B va C c6
5
7
^
cung so nguyen tuf cacbon va so m o l rirau A bang t o n g so m o l cua
o

A p dung t a n g g i a m k h o i iLfcJng
Am = 4,6 - 2,84 = 1,76 gam

vxiqu B va C, M B > M c .

= 0,08mol

A.

B.

C H 3 O H .

C.

C 2 H 5 O H .

V^ = - ^ . 2 2 , 4 = 0,896 l i t .

C 3 H 7 O H .

D.

C 4 H 9 O H .

HUdng dan giai

Goi M la nguyen tuf k h o i t r u n g b i n h cua ba rifgu A , B, C.

Chon dap a n A .

Ta c6: M =

= 42,25
0,08

Nhi/ v a y p h a i c6 i t n h a t m o t rixau c6 M < 42,25.

B a i 9: Co 100 gam dung dich 23% cua m o t axit dan chufc (dung dich A ) .
T h e m 30 gam m o t axit dong dang l i e n tiep vao dung dich t a duac
dung dich B. T r u n g hoa ^ d u n g dich B b ^ n g 500 m l dung dich N a O H

Chi

0. 2 . (viia du) t a duac dung dich C.

CO

Taco:

C H 3 O H

n^ =

1. H a y xac d i n h C T P T cua cac axit.

A. H C O O H va

C H 3 C O O H .

B.

C H 3 C O O H

C.

va

D.

C 3 H 7 C O O H

C 3 H 7 C O O H .

va
va

C 2 H 5 C O O H .
C 4 H 9 C O O H .

2. Co can dung dich C t h i t h u dtrac bao nhieu gam muoi khan?

A. 5,7 gam.

+ 23 - 1 = 75

V i la axit dan chuTc n e n so m o l muoi bSng so m o l axit bSng 0,1

Cdch 2:

C 2 H 5 C O O H

( M = 60).

2. Theo phuang phap K L P T T B :

Chon dap a n A .

Vay:

C H 3 C O O H

Chon dap a n A .

Vay: V^ = - ^ . 2 2 , 4 = 0,896 l i t .

np^ = ^

= 53.

0,1

2
(R

23
= 2,3 g a m ,
10
30
= 3 gam.
10

B. 7,5 gam.

C. 5,75 gam.

D . 7,55 gam.

Hiidng dan giai

1. Theo phirang phap K L P T T B :
Vi chilay nen
^ 10

nNaOH

= 0,2 . 0,5 = O,lmol

'

CO

( M

5 +3

32)

= 0,05 m o l

mA

= 32. 0,05 = 1,6 gam.

niB

+ c = 3,38 - 1,6 = 1,78 gam;

HB+C = 0,08
M

B+C

- 0,05

= 0,03

mol

1,78
= 59,33.
0,03

Goi y l a so nguyen tuf H t r u n g b i n h t r o n g p h a n tuf h a i riiau B v a C.

Ta c6: C^H^OH = 59,33 hay 12x + y + 17 = 59,33 ( y -> 2x + 2)
=^ 12x + y = 42,33

B i e n luan:

Chi

- Phan
X

30,33

18,33

6,33

< 0

CO n g h i e m

1: C h o t a c d u n g vdri N a d u , k e t t h i i c p h a n ufng t h u dugc 3,36 l i t

H2 ( d k t c ) .

Phan

2: T a c h n u d c h o a n t o a n 6 180C, x u c t a c H2SO4 d a c t h u dugc

m o t a n k e n cho h a p t h u vao b i n h dUng dung dich b r o m d u
t h a y CO 3 2 g a m Br2 b i ma't m a u . C T P T h a i a n c o l t r e n l a

k h i x = 3. B , C p h a i c6 m o t riiou c6 so n g u y e n ti)

H < 6,33 v a m o t riTOu c6 so n g u y e n tuf H > 6,33.

V a y mgu B l a C 3 H 7 O H .
Co 2 c a p n g h i e m :

C 3 H 5 O H (CH2 = C H - CH2OH) v a C 3 H 7 O H

A. C H 3 O H v a C 2 H 5 O H .

B. C2H5OH va C3H7OH.

C. C H 3 O H v a C 3 H 7 O H .

D. C2H5OH va C4H9OH.

B a i 6: C h i a h 6 n h g p g o m 2 a n d e h i t n o d o n chijfc l a m h a i p h a n b a n g n h a u :

C3H3OH ( C H = C - C H 2 O H ) va C3H7OH
Chon dap an C .

IP

- Phan

1: D e m d o t c h a y h o a n t o a n t h u dtfoc 1,08 g a m nUd'c.

- Phdn

2: T a c d u n g v d i H2 d u ( N i , t) t h i t h u dugc h o n h g p A . D e m A
d o t c h a y h o a n t o a n t h i t h e t i c h k h i CO2 ( d k t c ) t h u dugc l a

BAI T A P V A N D U N G

Bai

A . 1,434 l i t .

1: D o t c h a y h o a n t o a n 0 , 1 m o l h 6 n h o p h a i a x i t cacboxylic l a dong

d a n g k e tiep t h u di/Oc 3 , 3 6 l i t .CO2 (dktc) v a 2,7 g a m H2O. So m o l cua

Bai

m o i a x i t I a n liJOt l a

C.

A . 0,903 g a m .

B a i 2 : Co 3 ancol b e n k h o n g p h a i l a dong p h a n c u a n h a u . Do't c h a y m o i

c h a t d e u c6 so m o l C O 2 b S n g 0,75 I a n so m o l H 2 O . 3 ancol l a

C. CsHgO; C 3 H 8 O 2 ; C 3 H 8 O 3 .

P ; CsHgO; C S H G O ; CsHgOz.;

A. 9 , 5 2 1 g a m .

C. C 3 H 7 O H v a C 4 H 9 O H . '
Bai
r

, -

B. C 2 H 5 O H v a C 3 H 7 O H . . '

Bai

5: M o t h o n h o p X g o m 2 ancol thuoc cung d a y dong d a n g c6 khoi

l i r g n g 30,4 g a m . C h i a X t h a n h h a i p h a n b a n g n h a u .

A.'2,55 gam.

p::5,05:gam-

B.-5,52 g a m ,

G. ,5,25 g a m ,

t h u y p h a n h o a n t o a n 26,4 g a m h 5 n h g p X b&ng 100 m l d u n g d i c h

N a O H 2 0 % ( d = 1,2 g/ml) r o i d e m c6 c a n t h i t h u dugc 3 3 , 8 g a m c h a t

h a i c h a t nitro n a y dugc 0,07 m o l N2. H a i c h a t nitro do l a

D . Cg H2(N02)4 v a C6H(N02)5.

c a n d u n g d i c h t h u dugc h o n h g p X . K h o i l u g n g c u a X l a .

h o i 0 136,5C v a 1 a t m t h i t h u dugc 8 4 0 m l h o i este. M a t k h a c d e m

I t r g n g p h a n tuf h o n k e m n h a u 4 5 d v C . D o t c h a y h o a n t o a n h o n hc(p

C. Ce H 3 ( N 0 2 ) 3 v a C6H2(N02)4.

D . 0,704 g a m .

t h a n h t\i a x i t d o n chufc v a r u g u d o n chufc. C h o 2,2 g a m h o n h g p X b a y

4: N i t r o b o a b e n z e n dugc 1 4 , 1 g a m h 5 n h o p h a i c h a t riitro c6 k h o i

B. Cg H4(N02)2 v a C6H3(N02)3.

C. 9,215 g a m .

B a i 10: H 6 n h g p X g o m 2 este A , B d o n g p h a n v d i n h a u v a d e u dugc t a o

D . C 4 H 9 O H v a C s H n O H . :'

A . Ce H 5 N O 2 v a C6H4(N02)2.

B . 9,125 g a m .

v i r a d u v d i N a t h a y t h o a t r a 0,672 l i t k h i ( d k t c ) v a m o t d u n g d i c h . Co

Jtinhv J h u y j r h a n luign'g.est'e t r e h b a n g <JuTig ,dieh*,Na0H tbwrjji/^cj5,56

.

D . 0,93 g a m .

B a i 9 : C h o 4,2 g a m h o n h g p g o m r u g u e t y l i c , p h e n o l , a x i t f o m i c t a c d u n g

d o n chiJc, dong d a n g l i e n tiep t h u difOc-5,28 g a m h 6 n h o p 3 este t r u n g

-

C. 0 , 9 4 g a m .

v d i d u n g d i c h H C l t h i t h u dugc 18,975 g a m m u o i . V a y k h o i l u g n g H C l
p h a i dCing l a

giftm i n u o i . r H a i r a o u J ^

B . 0,39 gam.

B a i 8 : C h o 9 , 8 5 g a m h o n h g p 2 a m i n d o n chufc n o b a c 1 t a c d u n g vCra d i i

B. CgH'sO; C 3 H 6 O 2 ; C 4 H 1 0 O .

B a i 3 : C h o a x i t o x a l i c H Q O C - C O O H t a c d u n g v6i h o n h o p h a i ancol no,

A . CH3OH v a C 2 H 5 O H . .

h g p X g o m cac o l e f m . N e u d o t c h a y h o a n t o a n Y t h i t h u dugc

v a CO2 t a o r a l a

D . 0,06 m o l v a 0,04 m o l .

A . CaHgO; C 3 H 8 G ; C 4 H 1 0 O .

D . 1,444 l i t .

0,66 g a m CO2. V a y k h i d o t c h a y h o a n t o a n X t h i t o n g k h o i l u g n g H2O

B . 0,045 m o l v a 0,055 m o l .

0,04 m o l v a 0,06 m o l .

C. 1,344 l i t .

7 : T a c h nUdc h o a n t o a n tCr h o n h g p Y g o m h a i rUOu A , B t a dugc

h5n

A. 0,05 m o l va 0,05 m o l .

B. 1,443 l i t .

r a n k h a n . V a y c o n g thufc p h a n tuf c u a este l a

A. C 2 H 4 O 2 .

B . C3H6O2.

C. C 4 H 8 O 2 .

D . C.H10O2.

^ap a n
.

1. A

2. C

3. A

4. A

5. C

6. C

7. D

8. B

9. B

10. C

B a i 1 0 : K i m loai Fe p h a n iJng dvtac v d i dung dich

A. CUSO4.

GlOl THiSU M O T S6 B O B E O N THITHPT

V A B E THICAO BXNG - B ^ I HQC

B. Al2(S04)3.

C. MgS04.

D. ZnS04.

B a i 11: C h a t p h a n ufng dugc v d i Cu(0H)2 tao ra dung dich mau x a n h

l a m la
A. phenol.

B. e t y l axetat.

C. ancol etylic.

D. glixerol.

B a i 12: Trong dieu k i e n t h i c h hop, axit fomic (HCOOH) phan ufng dugc v d i
A.

GI61 T H I E U M Q T S O D E T H I

THCT

TOT

NGHIEP

A. H C l .

DE THI THljr TOT NGHIf P THPT

B. Cu.

C. C2H5OH.

D. N a C l .

'

B a i 13: Cho cac k i m loai N a , M g , Fe, A l ; k i m loai c6 t i n h khuf m a n h

n h a t 1^

M o n t h i : Hoa hoc - Ban ccf b a n

Thai gian Idm bai 90 phut

A. A l .

B. N a .

C. M g .

D. Fe.

B a i 14: Cho m gam k i m loai A l tac dung v d i m o t liTofng dil dung dich
N a O H , t h u dugc 3,36 l i t k h i H2 (d dktc). Gia t r i cua m la

B a i 1 : So dong p h a n a m i n c6 cong thufc p h a n tuf C2H7N la

A. 4.

B. 3.

C. 2.

D . 5.

B a i 2: So electron Idp ngoai cung cua cac nguyen tuf k i m loai thuoc phan
n h o m c h i n h n h o m I I la
A. 3.

B. 2.

C. 4.

D . 1.

B a i 3: Cong thijfc chung cua oxit k i m loai thuoc phan nhom chinh nhom I la
A . R2O3.

B. RO2.

C. R2O.

D.

RO.

B a i 4: T e n goi cua polime c6 cong thufc ( - C H 2 - C H 2 - ) n la

A. poll v i n y l clorua.

B. poH etilen.

C. poll m e t y l metacrylat.

D. polistiren.

B a i 5: C h a t p h a n ufng dudc v d i dung dich N a O H tao k e t tua la

A. KNO3.

B. FeCls.

C. BaCl2.

D . K2SO4.

B a i 6: Qud t r i n h nhieu p h a n tijf nhd (monome) k e t hdp v d i nhau thanh

p h a n tijf Idn (polime) dong t h d i g i a i phong nhiifng p h a n tuf nUdc goi la
p h a n ufng
A. n h i e t p h a n .

B. trao d o i .

C. t r u n g hop.

D . t r u n g ngifng

B a i 7: C h a t t h a m gia p h a n ufng t r u n g hop tao ra polime la

A. CH3-CH3.

B. CH3-CH2-CH3.

C. C H 3 - C H 2 - C I .

D. CH2 = C H - C H 3 .
B. M g O .

C. K O H .

B. H C l .

C. H2SO4.

C. 5,4.

D. 2,7.

B a i 15: T r u n g hoa m gam axit CH3COOH b k n g 100ml dung dich N a O H

l M . , G i a t r i cua m la
A. 9,0.

B. 3,0.

C a u 16: K i m loai A l khong

C. 12,0.

D. 6,0.

p h a n ufng v d i dung dich

A. H2SO4 dac, nguoi.

B. Cu(N03)2.

C. H C l .

D. N a O H .

B a i 17: Cho 4,6 gam ancol etylic phan ufng vdi liicfng d\i k i m loai Na, thu diicfc
V l i t k h l H2 (d dktc). Gia t r i cua V la
A. 3,36.

B. 4,48.

C. 2,24.

D.

1,12.

B a i 18: Phuong phap t h i c h hgfp dieu che k i m loai Ca tuf CaCl2 la

A. n h i e t p h a n CaCl2.
B. dung N a khuf Ca^' t r o n g dung dich CaClz.
C. dien p h a n dung dich CaCl2.

fiai 19: C h a t p h a n dng diTcfc v d i dung dich CaCl2 tao k e t tua 1^

D . CuO.

B a i 9: De phan biet dung dich AICI3 va dung dich K C l ta dung dung dich
A. N a O H .

B. 8,1.

D. dien p h a n CaCl2 ndng chay.

B a i 8: C h a t p h a n ufng duac v d i dung dich N a O H la

A. AI2O3.

A. 10,8.

D . NaN03.

A. Mg(N03)2.

B. NazCOg.

C. NaNOg.

B a i 20: C h a t cd t i n h oxi hoa nhiftig khong

A. Fe.

B. Fe203.

D. H C l .

cd t i n h khuf la

C . FeClg.

D. F e O .

B a i 21: A x i t aminoaxetic (NH2CH2COOH) tac dung ducfc v d i dung dich

A. NaNOa.

B. N a C l .

C. N a O H .

D. Na2S04.

B a i 22: T r u n g hoa V m l dung dich N a O H I M b k n g 100ml dung dich H C l

I M . Gia t r i cua V la
A. 400.

B. 200.

C. 100.

D. 300.

B a i 23: Chat p h a n ufng diJcfc vdfi dung dich AgNOs t r o n g N H 3 , dun nong
tao r a k i m loai A g la
A. glucozO.

hoan toan v d i m o t luofng d i i AgN03 t r o n g dung dich NH3, dun n o n g

t h u dtroc 21,6 gam k i m loai Ag. Cong thufc cua X la
A. C H 3 C H O .

C. xenlulozcf.

D. t i n h hot.

B. C6H5NH2 ( a n i l i n ) .

C. CgHsOH.

D. C H 3 C O O H .

B a i 25: H a i k i m loai deu p h a n iJng v d i dung dich Cu(N03)2 g i a i phong

k i m loai Cu la
C. A l va Ag.

C. H C H O .

D. C 2 H 5 C H O .

tao r a k i m loai A g la

B a i 34: De

B. C H 3 C H 2 O H .

C. C H 3 C H O .

p h a n biet dung dich phenol

D. C H 3 C O O H .

(CeHsOH)

va ancol

D. Fe va Ag.

B a i 26: Cong thiJc chung cua day dong dang ancol no, dcfn chuTc, mach

A. k i m loai Na.

B. quy t i m .

C. n\idc brom.

D. dd N a C l .

B a i 35: Oxi hoa C H 3 C H 2 O H b^ng CuO dun nong, t h u difoc andehit c6

cong thufc la
A. C H 3 C H O .

B. C H 3 C H 2 C H O .

C. C H 2 = C H - C H O .

D. H C H O .

B a i 36: Chat khdng

ho la

p h a n iJng v d i b r o m la

A. CH2-iOH (n > 3).

B. CH2.iOH (n > 1).

A. CgHsOH.

B. C6H5NH2.

C. C H 2 n . i C H 0 (n > 0).

D. C H 2 , i C 0 0 H (n > 0).

C. C H 3 C H 2 O H .

D. CH2 = C H - C O O H .

B a i 27: Cho p h a n ufng a A l + bHNOa ^ cAl(N03)3 + dNO + eHzO

B a i 37: Dun nong este CH3COOC2H5 v d i m o t lifong vCra du dung dich

He so a, b, c, d, e la cac so nguyen, t o i g i a n . Tong (a + b) bSng

N a O H , san p h a m t h u di/oc la

A. 5.

A. C H 3 C 0 0 N a va C H 3 O H .

B. C H 3 C 0 0 N a va C 2 H 5 O H .

C. H C O O N a va C 2 H 5 O H .

D. C2H5COONa va C H 3 O H .

B. 4.

C. 7.

D. 6.

B a i 28: A n d e h i t axetic c6 cong thufc la

A. C H 3 C O O H .

B. H C H O .

B a i 29: A x i t axetic khdng

A. CaCOs.

C. C H 3 C H O .

D. H C O O H .

p h a n ufng v d i

B. Na2S04.

C. N a O H .

D. Na2C03.

diioc m gam mot oxit. Gia t r i cua m la

B. 14.

C. 8.

B a i 31: Cau h i n h electron cua nguyen tijf N a (Z = 11)

A. l s ' 2 s ' 2 p ' ' 3 s l
C. Is'2s22p3s\. Is'2s22p'3s'3p\

B. l s ' 2 s ' 2 p ^ '

B a i 38: K i m loai khdng

A. Ba.

B a i 30: Nung 21,4 gam Fe(0H)3 a nhiet cao den khoi lugng khong doi, thu
A. 16.

etylic

(C2H5OH), t a dung thuoc thuf la

A. H C O O H .

B. Fe va A u .

B. C 3 H 7 C H O .

B a i 33: Chat p h a n ufng dirac vdri AgN03 t r o n g dung dich NH3, dun nong
A. C H 3 N H 2 .

B. saccarozcf.

B a i 24: Chat p h a n ufng di/cfc v d i a x i t H C l la

A. A l va Fe.

a i 32: Cho 4,4 gam m o t andehit no, don chiJc, mach hd X p h a n ufng

D. 12.

p h a n iJng v d i nUdc d n h i e t do t h i / d n g la

B. Na.

C. Fe.

D. K

B a i 39: K i m loai tac dung dtfOc v d i a x i t H C l la

A. Cu.

B. A u .

B a i 40: N h o m oxit (AI2O3) khong

A. N a O H .

B. H N O 3 .

C. Ag.

D. Zn.

p h a n ufng duTOc v d i dung dich

C. H2SO4.

D. N a C l .

DE THI THIJf TOT NGHIfP THPT

M o n t h i : Hoa hoc - Ban cor b a n

Be 2
B a i 1: Hoa t a n m gam A l bSng dung dich H C l (dir), t h u duac 3,36 l i t H2

B. 2,70.

C. 1,35.

C. A l .

A. N a O H , H C l . B. Na2S04, K O H .

D. Na.

B a i 4: Cho sa do chuyen hoa: Fe

C. K C l , NaNOg.
FeClg

A. 4.

B. 4,48.

C. 3,36.

A. a n i l i n .

C. C2H4.

D . (C2H5)20.

B a i 6: Dong p h a n cua glucozcf l a

B. xenloluza.

A. 2.
C. fructozd.

D . mantoza.

C. H 2 N - C H 2 - C O O H .

A. I I A .

D. C2H6.

B a i 8: Cho day cac chat: CH3OH, CH3COOH, CH3COOCH3,

B. 1.

C. 3.

D . 2.

B. ancol etylic.

C. a x i t ax'5tic.

D. benzen.

B. 4.

C. 5.

D. 3.

B a i 18: T r o n g bang t u a n hoan, M g la k i m loai thuoc n h o m

B a i 7: Chat p h a n ling duac vdi cac dung dich: N a O H , H C l la

B. CH3COOH.

MgC^.

B a i 17: Cho day cac k i m loai: Na, Cu, Fe, Ag, Zn. So k i m loai trong day
phan ijfng diTOc vdi dung dich H C l la

c h i n h (chat hufu cor) la

B. (CH3)20.

D. 2,24.

C a u 16: K e t t u a tao t h a n h k h i nhd niidc b r o m vao

D. H C l , N a O H .

B a i 5: Dun nong ancol etylic v d i H2SO4 dSc d 170C, t h u duac san pham

A. C2H5OH.

A. 1,12.

B a i 15: Cho day cac k i m l o a i : Fe, N a , K, Ca. So k i m loai t r o n g day tac

dung diiac v d i niidc d n h i e t do t h i / d n g la

D. N a C l , H2SO4.

Y I a n lucjt la

A . saccaroza.

k h i N2 (of dktc). Gia t r i cua V 1^

D. dien p h a n MgCl2 nong chay

F e ( 0 H ) 3 . H a i chat X,

B. N a C l , Cu(0H)2. C. H C l , A1(0H)3.

D. C2H5COOH

a i 13: Dot chay hoan toan 0,2 m o l m e t y l a m i n (CH3NH2), s i n h r a V l i t

C. dung K khuf Mg^"^ t r o n g dung dich

B. M g .

B a i 3: AI2O3 p h a n ufng dJcfc vdfi ca h a i dung dich:

A. C2H6.

C. C2H3COOH.

B. dien p h a n dung dich MgCl2.

n h a t la

A. CI2, N a O H .

B. CH3COOH.

A. n h i e t p h a n MgCl2.

D. 5,40.

B a i 2: Cho day cac k i m l o a i : K , M g , N a , A l . K i m loai t r o n g day manh

A. K.

A. C3H7COOH.

B a i 14: Phildng phap t h i c h hap dieu che k i m loai M g tCr MgCl2 la

(d dktc). Gia t r i cua m l a

A . 4,05.

a i 12: A x i t acrylic c6 cong thufc la

B. l A .

C. I V A .

D. I I I A .

B a i 19: P o l y v i n y l clorua) dtrdc dieu che tii p h a n iJng t r u n g hop

CH3CHO,

CeHsOH. So chat t r o n g day tac dung dirac v d i N a s i n h r a H2 la

A. C H 3 - C H = C H C l .

B. CH2 = C H - C H 2 C I

A. 5.

C. CH3CH2CI.

D. CH2 = C H C l .

B. 2.

C.3.

D. 4.

B a i 9: San p h a m tao t h a n h c6 chat k e t tua k h i dung dich Fe2(S04)3 tac

B a i 20: So n h o m h i d r o x i ( - 0 H ) t r o n g m o t p h a n tijf glixerol la

dung v d i dung dich

A. N a O H .

B. Na2S04.

C. N a C l .

A. 3.

D. CUSO4.

A. CH2.iOH.

dien p h a n hap chat nong chay cua k i m loai do

B. A g .

C. N a .

D. Cu.

B a i 11: San p h a m tao t h a n h c6 chat k e t t u a k h i dung dich Na2C03 tac

dung v d i dung dich
A. CaClz.

B. K C l .

C. K O H .

D. NaNOg.

C. 4.

D. 2.

B a i 21: Cong thiJc chung cua a x i t cacboxylic no, dofn chuTc, mach h d l a

B a i 10: T r o n g cong nghiep, k i m loai dilgtc dieu che b k n g phiiong phap

A. Fe.

B. 1.

B. CH2.iC00H.

C. CnH2.iCH0.

D. CnHzn-iCOOH

B a i 22: So dong p h a n cau tao uTng v d i cong thiJc p h a n tuf C2H6O la

^
'^

A. 5.

B. 4.

C. 2.

D. 3.

B a i 23: Dung dich l a m quy t i m chuyen sang mau x a n h la

A . NaNOa.

B. N a C l .

C. Na2S04.

D. N a O H .

B a i 24: Cho 3,2 gam ancol metylic phan ufng hoan toan v6i Na (du), thu duac V
l i t k h i H2 (cf dktc). Gia t r i cua V la
A. 2,24.

B. 3,36.

B a i 25: C h a t t h a m gia p h a n ufng t r a n g

A. t i n h hot.

B. a x i t axetic.

C. 4,48.
gUOng

D- 1,12.

la

C. xenlulozo.

du m gam Fe. Gia t r i cua m l a

B. 2,8.

C. 5,6.

D. 8,4.

B a i 27: Hoa t a n 6,4 gam Cu bang axit H2SO4 d^c, nong (dif), s i n h r a V
l i t k h i SO2 (san p h a m khut duy n h a t 6 dktc). Gia t r i ciia V la
A. 2,24.

B. 3,36.

C. 6,72.

D . 4,48.

X ^

CH3COOH (moi m u i t e n

A. H C H O .
B. C2H5CHO.
C. CH4.
B a i 37: Phenol (CeHgOH) tac dung duoc v d i
A. N a C l .

D. mantozo.

B a i 26: De p h a n iJng hoan toan v d i 100ml dung dich CUSO4 I M , can vCra
A. 11,2.

B a i 36: Cho so do p h a n u T n g : C2H5OH

L f n g v d i m o t p h a n iJng). C h a t X la

B. CH4.

D. CH3CHO.

C. N a O H .

D. NaNOg.

B a i 38: Chat X c6 cong thijfc phan ttf C3H6O2 la este cua axit axetic
(CH3COOH). Cong thuTc cau tao cua X la
A. C2H5COOH. B. CH3COOCH3.
C. HCOOC2H5.
B a i 39: Ancol metylic c6 cong thufc la
A. C 2 H 5 O H .

B. C 3 H 7 O H .

C. C H 3 O H .

D. HOC2H4CHO.
D.

C4H9OH.

B a i 40: Thuoc thijf de p h a n biet axit axetic va ancol etyilc la

A. phenolphtalein.
B. quy t i m .
C. nude brom.

D. AgN03 t r o n g dung dich NH3.

B a i 28: H o p chat sSt ( H ) sunfat c6 cong thuTc la

A . Fe2(S04)3.

B. F e S 0 4 .

C. F e ( 0 H ) 3 .

D. FezOs-

DE THI THUr TOT NGHIf P THPT

B a i 29: Cho day cac chat: FeClz, CUSO4, BaCla, KNO3. So chat trong day

M o n t h i : Hoa hoc - Ban co ban

phan uTng dtfgfc v6i dung dich N a O H la

A. 3.

B . 2.

C. 1.

D . 4.

Oe3

B a i 30: T r o n g dung dich CUSO4, ion Cu^^ k h o n g b i khut bofi k i m loai

A. Zn.

B. A g .

C. M g .

D. F e .

B a i 31: Cho phi/ong t r i n h hoa hoc: a A l + b Fe304 -> c F e + dAl203. (a, b,

c, d la cac so nguyen, t o i gian). T d n g cac he so a, b, c, d la
A. 26.

B. 24.

C. 27.

D . 25.

B a i 32: K i m loai p h a n ufng di/grc v d i dung dich H2SO4 b a n g la

A. A u .

B. A g .

C. A l .

D . Cu

B a i 33: So electron Idp ngoai cung cua nguyen tuf A l la

A. 1.

B. 2.

C. 4.

D. 3.

B a i 34: T r u n g hoa 6 gam CH3COOH can V m l dung dich N a O H I M . Gia

t r i cua V la
A . 400.

B. 100.

C. 300.

D. 200.

B a i 35: Chat tac dung duac v d i AgNOs t r o n g dung dich NH3, dun nong
tao ra A g la
A. CH3COOH.

B. CH3CHO.

C. CH3COOCH3.

D. CH3OH.

B a i 1: Chat t h a m gia p h a n uTng t r u n g hop tao r a polime la

A. CH3-CH3.

B. CH3-CH2-CH3.

C. C H 3 - C H 2 - C I .

D. CH2 = C H - C H 3 .

B a i 2: Cho 4,6 gam ancol etylic p h a n iJng v d i lufcrng diT k i m loai N a , t h u

dugc V l i t k h i H2 (d dktc). Gia t r i cua V la
A. 3,36.

B. 4,48.

C. 2,24.

D. 1,12.

B a i 3: Dun nong este HCOOCH3 v d i m o t li/cfng viia du dung dich N a O H ,

san p h a m t h u diidc la
A. CHsCOONa va C2H5OH.

B. HCOONa va CPI3OH.

C. HCOONa va C2H5OH.

D. CHaCOONa va CH3OH.

B a i 4: So electron Idp ngoai cung cua cac nguyen tuf k i m loai thuoc p h a n
n h o m c h i n h n h d m I I la
A. 3.

B. 2.

C. 4.

D. 1.

^ a i 5: H a i dung dich deu p h a n ufng dtroc v d i k i m loai Fe la

A. CUSO4 va ZnCl2.

B. CUSO4 va H C l .

C. ZnCl2 va FeCh,

D. H C l va AICI3.

B a i 6: C h a t c6 t i n h oxi hoa nhufng khong

A. Fe.

B. FeaOa.

C. FeClg.

D. FeO.

B a i 7: Cho m gam k i r n l o a i A l tac dung vdi m o t ladng dif dung dich

N a O H , t h u duoc 3,36 l i t k h i Ha id dktc). Gia t r i cua m la
A. 10,8.

B. 8,1.

C. 5,4.

B. Cu.

C. C2H5OH.

B a i 10: K i m loai A l khong

C. 12,0.

D. 6,0.

B. Cu(N03)2.

C. H C l .

D. N a O H .

C. M g .

D . Fe.

B. poll e t i l e n .

C. poll m e t y l metacrylat.

D. polistiren.

B. M g O .

C. 8.

B. 3.

C. K O H .
C. 2.

C a u 16: De p h a n biet dung dich phenol

(C2H5OH), ta dung thuoc thuf la
A. k i m loai N a .

B. quy t i m .

B. H C O O H va CgHsNHz ( a n i l i n ) .
C. CH3NH2 va CeHsOH (phenol).
D. H C O O H va CeHsOH (phenol).

D. Na2C03.

B. CH3CH2CHO.

C. CH2 = C H - C H O .

D. H C H O .

A. CH2_iOH (n > 3).

B. C H 2 n . i O H (n > 1).

C. C n H 2 n ^ i C H 0 (n > 0).

D. C n H g n + i C O O H (n > 0).

B. FeClg.

C. BaCl2.

D. K2SO4.

A. n h i e t p h a n CaCl2.

D. dien p h a n CaCl2 nong chay.

D. CuO.

B a i 25: Chat p h a n ufng dirge v d i dung dich H2SO4 tao r a k e t t u a la

A. N a O H .

D. 5.
(CgHsOH)

C. nirdc b r o m .

B a i 17: H a i chat deu p h a n iJng v d i dung dich N a O H la

A. CH3COOH va C6H5NH2 (aniUn).

C. H C l .

C. dien p h a n dung dich CaCl2.

D . 12.

B a i 15: So dong p h a n a m i n c6 cong thufc phan tijf C2H7N la

A. 4.

B. N a C l .

B. dung N a khilf Ca^"^ t r o n g dung dich CaCl2.

B a i 14: Chat p h a n ufng dirge v d i dung dich N a O H la

A. AI2O3.

D. fructozcf.

B a i 24: Phaong phap t h i c h hgp dieu che k i m loai Ca tCr CaCl2 la

t h u dirge m gam m o t oxit. Gia t r i cua m la

B. 14.

A. Ca(N03)2.

A. KNO3.

B a i 13: N u n g 21,4 gam F e ( 0 H ) 3 d n h i e t cao den k h o i lUdng k h o n g doi,

A. 16.

C. xenlulozd.

B a i 23: Chat p h a n iJng dirge v d i dung dich N a O H tao k e t tua la

B a i 12: T e n goi cua poHme c6 cong thiJc ( - C H 2 - C H 2 - ) la

A. poll v i n y l clorua.

B. saccarozcf.

hof la

n h a t la
B. N a .

D. 300.

B a i 22: Cong thufc chung cua day dong dang ancol no, ddn ehiJe, m a c h

B a i 11: Cho cac k i m l o a i N a , M g , Fe, A l ; k i m loai c6 t i n h khijf m a n h

A. A l .

A. glucozo.

A. CH3CHO.

p h a n iJng v d i dung dich

A. H2SO4 dac, nguoi.

C. 100.

B a i 21: Oxi hoa CH3CH2OH bSng CuO dun nong, t h u dirge andehit c6
cong thuTc la

I M . Gia t r i cua m la
B. 3,0.

B. 200.

B a i 20: De l a m m e m nirdc curng v i n h cufu, t a dung dung dich

D. N a C l .

B a i 9: T r u n g hoa m gam a x i t CH3COOH b^ng 100ml dung dich N a O H

A. 9,0.

A. 400.

B a i 19: Chat thuoc l o a i disaccarit la

D. 2,7.

B a i 8: Trong dieu k i e n t h i c h hop, axit fomic (HCOOH) phan uTng duac vdri
A. H C l .

B a i 18: T r u n g hoa V m l dung dich N a O H I M bSng 100ml dung dich H C l

I I M . Gia t r i cua V la

c6 t i n h khuf la

va ancol

etylic

D. dd N a C l .

B. Na2C03.

C. BaClz.

D. N a C l .

B a i 26: Este etylfomiat CO cong thiJe la

A. CH3COOCH3.

B. HCOOC2H5.

C. H C O O C H = CH2.

D . HCOOCH3.

B a i 27: A x i t axetie CH3COOH khong

A. Na2S04.

B. N a O H .

p h a n lifng v d i
C. Na2C03.

D . CaO

B a i 28: De p h a n bit dung dich AICI3 va dung dich K C l t a dung dung

dich
A. N a O H .

B. H C l .

C. H2SO4.

D. NaNOs-

B a i 29: C h a t p h a n uTng dUdc v d i AgNOs t r o n g dung dich NH3, dun nong

tao ra k i m loai A g la
A. C H 3 N H 2 .

DE THI THljr TOT NGHlfP THPT

'

B. C H 3 C H 2 O H .

C. C H 3 C H O .

M o n t h i : Hoa hoc - Ban cO ban

D.CH3COOH.

B a i 30: Cho 4,4 gam m o t andehit no, don chiJc, mach hd X p h a n ufng

Oe4

hoan toan v d i m o t Itrcmg dir AgNOs t r o n g dung dich N H 3 , dun nong

thu dugfc 21,6 gam k i m loai A g . Cong thiJc cua X la
A. C H 3 C H O .

B. C 3 H 7 C H O .

C. H C H O .

D.

C2H5CHO.

B a i 31: H a i k i m loai deu p h a n dng v d i dung dich Cu(N03)2 g i a i phong

k i m loai Cu la
A. A l va Fe.

B. Fe va A u .

C. A l va A g .

p h a n t i l Idn (polime) dong t h d i g i a i phong nhufng p h a n tOf nifdc goi la

phan ufng
B. trao d o i .

B a i 33: Cap chat khong

C. t r u n g hop.

D. truing ngiing.

xay r a p h a n ufng la

A. Fe + Cu(N03)2.

B. Cu + AgNOg.

C. Zn + Fe(N03)2.

D- A g + Cu(N03)2.

C. ancol etylic.

D. glixerol.

B. N a C l .

C. N a O H .

D. Na2S04.

A. ls'2s'V3s'.

'

c A1(N03)3 + d N O + e H 2 0

B. 4.

C. 7.

D . 6.

B a i 38: C h a t p h a n ufng Axiqc v d i CaCOs la

A. C H 3 C H 2 O H .

B. CeHsOH.

C. C H 2 = C H - C O O H .

D . CeHgNHz (anilin)

B a i 39: K i m loai khong

p h a n ufng v d i nifdc d n h i e t do thadng la

B. Na.

C. Ba.

D . K.

B a i 40: H a i k i m loai A l va Cu deu p h a n ufng dadc v d i dung dich

A. N a C l loang.

A. (c)

B. (a), (b), (c)

C. (b), (c)

D . (a), (b)

B a i 2: Cho 0,01 mol aminoaxit (A) tac dung du vdi 80 m l dung dich H C l

A. 120

B. 150

C. 147

D . 97

B a i 3: Lay t h a n h k i m loai R hoa t r i I I n h i i n g vao 250 m l dd C U S O 4 1,4

B. H 2 S O 4 loang.

C. H N O 3 loang.

R giam 0,35 gam. Xac d i n h k i m loai R.

A. Zn (65)

B. Fe (56)

C. M g (24).

D . Cr (52)

B a i 4: Cho 4,32 gam A l t h i khuf h e t bao nhieu gam o x i t sat tir. B i e t san
G. 20,8g gam-

D. 83,52 gam.*.' .

Bai 5: L a y 7 , 0 4 g'am est.e e4H80.2'x8ipiiDilg-hoa t r o n g m o i t r i i d r i g N a O H

b . lsW2p^3s'3p\

He so a, b, c, d, e la cac so nguyen, t o i g i a n . Tong (a+b) bSng

A. Fe.

P h a t bieu d i i n g la?

. . ' A . 41,76-gam ' JB.;.l%92.ga^._*. ;

. B. ls22s'2p^

B a i 37: Cho p h a n ufng a A l + bHNOa

A. 5.

(c) H a m lifpng %C c6 t r o n g thep la 0 , 0 1 - 2%.

p h a m cuoi cung la Fe

B a i 36: Cau h i n h electron cua nguyen tuf N a (Z = 11)

C. l s W 2 p ' 3 s \

(b) Nguyen tac san xuat thep la thiTc h i e n qua t r i n h khuf quang sat
oxit bang CO d n h i e t dp cao.

M . Sau k h i p h a n d n g hoan toan n h a n tha'y khd'i krgng t h a n h k i m loai

B. e t y l axetat.

B a i 35: A x i t aminoaxetic ( N H 2 C H 2 C O O H ) tac dung difcifc v d i dung dich

A. NaNOo.

Si, M n , S.. CO trong quSng sat bang each oxi hoa chiing r o i loai bo.

(A) la?

la

A. phenol.

0,125 M . Co can t h i t h u di/pc 1,835 gam muoi. K h o i Itfong phan tuf cua

B a i 34: Chat p h a n ufng ducfc v d i C u ( 0 H ) 2 tao r a dung dich mau xanh

lam

Mk^^ (a) Nguyen tic san xuat gang la l a m g i a m h a m liicfng cac tap chat C,

D . Fe va A g .

B a i 32: Qua t r i n h n h i e u p h a n tuT nho (monome) k e t hop v d i nhau t h a n h

A. n h i e t p h a n .

B a i 1 : Cho cac p h a t bieu

D. N a O H loang

du t h i t h u diipc 6,56 gam muoi.. Cong thufc cau tao cua este la?
A. C 2 H 5 C O O C H 3

C; H C O O C H ( C H 3 ) 2

B.

HCOOCH2-CH,-CH3

D. C H 3 C O O C 2 H 5

B a i 6: T i n h dan dien theo chieu t a n g dan la?

A. Cu < A g < Fe

B. Fe < Cu < A g

C. Fe < A g < Cu

D . A g < Cu < Fe

B a i 7: N h o m k i m loai nao c6 the dieu che bang phifang phap

luyen?
A. M g , Cu, Fe

B. Fe, C i , Cu

C. A g , K, Fe

B a i 8: Cac p h a t bieu dung ve p e p t i t va protein la?

(1) L i e n k e t p e p t i t la l i e n k e t - C O - N H -

nhiet

D . A l , Na, Cu

(2) So lien k e t peptit trong p h a n t t f peptit c6 n goc amino axit l a ( n - 1 )

Cau

(4) P r o t e i n l a nhuTng p o l i p e p t i t c6 p h a n tuf k h o i \dn tix v a i c h u c n g h i n

'

(5) P r o t e i n c o n g o i l a a b u m i n ( 1 6 n g t r a n g t r u t n g )

A . (1), (3), (4), (5), (6)

B . (3), (5), (6)

C. (1), (2), (3) (4), (5), (6)

D . (1), (2), (4)

C. 4

9,36 g a m k e t t u a . G i a t r i cua V la?

A . 1,8 l i t h o a c 2,4 l i t

B . 2,2 l i t hoSc 2,4 l i t

C. 0,6 l i t

D . 2,4 l i t hoSc 3,6 l i t .

B. isopropyl

C. m e t y l p r o p i o n a t

D. propyl fomat.

fomat

B a i 12: C h o c o n g thufc a m i n o a x i t l a C3H7NO2. So d o n g p h a n a m i n o a x i t la?

B. 4

C. 3
cac

D. 5

A . dd HNO3

B. Cu(0H)2/0H-

C. Q u y t i m

D. AgNOs/NHg

C. (a) < (c) < (d) < (e) < (b) < (f)

D . (a) < (c) < (e) < (d) < (b) < (f).

A. monome

B.doan mach

C. n g u y e n t o

D . m a t x i c h cau t r u e

B. fructoza

C. saccarozo

D. t i n h bot

B a i 2 0 : T h u y p h a n t r i s t e a r i n t r o n g m o i trufcfng k i e m N a O H t h u di/gfc

D . Cu^^ o x i h o a dugc Z n .

p o h m e : (a) n i l o n - 6 , 6 ; (b) P V C ;

(c) cao

A. natristearat va glixerol

B. natristearat va etilenglicol

C. n a t r i o l e a t v a g l i x e r o l

D. kalistearat va glixerol.

B a i 2 1 : C h o h o n h o p F e , A g , C u . C h o n t h u o c thuf de t a c h A g

A . d d CUSO4

su b u n a ;

(d)

p o l i p e p t i t ; (e) t h i i y t i n h hQu co. C h a t n a o difoc d i e u che b S n g phuong

A . (b), ( ( d ) , (e)

B . ( b ) , (c), (e)

C. (b), (c)

D . (a), ( b ) , (c), (e)

la?

B. dd H C l

C. d d A g N O a

D. dd

A. FeO, M g O

B . Fe203, M g O , AI2O3

C. FezOs, M g O

D . F e O , M g O , AI2O3.

FeCh

B a i 2 3 : H a p c h a t cua n g u y e n t o n a o t h a i r a t r o n g s i n h b o a t g a y t h u n g
t a n g ozon?
A. Cacbon

p h a p t r u n g hofp?

nguyen

k h o n g k h i d e n k h o i li/Ong k h o n g d o i t h i t h u d\Jac c h a t r ^ n Ik?

Zn^* + C u . P h a t b i e u nao s a i ve p h a n utng?

C. T i n h khuf Z n > C u
cac

B . (c) < (f) < (b) < (a) < (d) < (e)

t o a n v d i d u n g d i c h N a O H da, loc l a y k e t t u a d e m n h i e t p h a n t r o n g

B . T i n h o x i h o a Zn^^ < C u ^*

15: C h o

(e)

B a i 2 2 : C h o d u n g d i c h g o m cac m u o i : F e C l 2 , MgCl2, AICI3 t d c d u n g h o a n

A . Z n o x i h o a duac Cu^^

Bai

d i p h e n y l a m i n , (d) d i m e t y l a m i n ,

A . (a) < (b) < (f) < ( d ) < (c) < (e)

luong ra k h o i hon hop

d d m a t n h a n : a b u m i n , glucozcf, ancol

e t y l i c , g l i x e r o l c h i c a n d u n g 1 t h u o c thuf nao?

1065.

s a n p h a m la?

A. etylaxetat

B a i 14: C h o puf: Z n + C u

D. 10000 va

A. xenluloza

m e t y l i c . T e n cua este la?

p h a n b i e t dMc

C. 1065 v a 1 0 0 0 0

B a i 19: C h a t n a o k h o n g c6 k h a n a n g t h a m g i a p h a n ufng t h u y p h a n ?

B a i 11: C h o este c6 c o n g thufc p h a n tuf l a C4H8O2 di/oc t a o r a boti a n c o l

13: D e

B. 10065 v a 10000

B a i 18: P h a n tuf p o l i m e bao g o m sU iSp d i l 5 p l a i cua r a t n h i e u cac

D. 3

B a i 10: C h o V l i t d d N a O H 0,2 M v a o d d chufa 0,15 m o l AICI3 t h u dtfoc

Bai

A . 1065 v a 5 6 0 0 0 0

N a O H , (f) a n i l i n

n h a u CO x a y r a phifcfng t r i n h p h a n uTng la?

A. 2

t r o n g m o i l o a i p o l i m e t r e n la?

(a) m e t y l a m i n , (b) a m o n i a c , (c)

B a i 9: C h o cac c h a t : Fe(N03)3, F e , A g N 0 3 , C u . So cSp c h a t t a c d u n g vdi

B. 5

m S t x i c h t u o n g ilng

B a i 17: SSp x e p cac a m i n sau d a y t h e o c h i e u t i n h b a z o t a n g d a n .

(6) P r o t e i n c h i c6 t r o n g d o n g v a t

A. 2

m o t l o a i t i n h b o t v a m o t l o a i P E c6 K L P T t r u n g b i n h

tLfOng iJng l a : 1 7 2 5 3 0 d v C v a 2 8 0 0 0 0 d v C . So

(3) C h o p e p t i t G l y - A l a - G l y - G l y - V a l t h u o c l o a i t e t r a p e p t i t

den h a n g t r i e u dvC

16: C h o

B. N i t d

C. L o u h u y n h

D . Clo

B a i 2 4 : D u n g d i c h F e S 0 4 v a d u n g d i c h CUSO4 d e u t a c d u n g dtrgtc v d i
A. Cu.

B. Z n

C. F e .

D. Ag.

Bai

25: Cho 7,168 l i t CO2 dkc vao 140 m l dd Ca(0H)2 2 M . T m h k h o i

lugfng k e t tua?

A. 24 gam

B . 32 gam

C. 4 gam

D. 28 gam

p a i 33: Phuong phap san xuat xa phong la?

A. Dun chat beo v d i dung dich k i e m N a O H t r o n g cdc t h u n g k i n d
n h i e t do cao
B. L a y san p h a m chiing cat tCf dau mo cho tac dung v d i Na2C03

B a i 26: N h o m chat nao deu c6 t i n h lifSng tinh?

A. C 6 H 5 - N H 2 , A1(0H)3, C r ( 0 H ) 3

C. L a y m9 dong v a t tac dung v d i dung dich h o n hcfp gom N a O H , K O H

B. H 2 N - C H ( C H 3 ) - C O O H , F e ( 0 H ) 3 , Ca(HC03)2

D. L a y a x i t beo tac dung v d i dung dich k i e m N a O H , dun soi d t cao.

C. H 2 N - C H 2 - C O O H , CraOs, NaHCOa

B a i 34: De dieu che l , 0 8 g A g can dien phan dung dich AgN03 t r o n g

t h d i gian bao lau v d i ciTdng do I = 5,36A

D. H 2 N - ( C H 2 ) 6 - N H 2 , Zn(0H)2, AI2O3

B a i 27: Cho 16,74 gam a n i h n tac dung hoan toan v d i dung dich Br2 t i n h
m k e t tiia t h u duoc?
A. 19,8 gam

B . 118,8 gam

C. 29,7 gam

D. 59,4 gam

chi so a x i t cua chat beo?

C. 8

D. 7.

p h a n t u gan dung cua p r o t e i n X c6 0,16 %

lUu h u y n h , biet r a n g cac 1 p h a n tuf protein chi chufa 1 nguyen tuf liJu
huynh.
A. 50 dvC

C. 3 p h u t

B. 2000 dvC

C. 20000 dvC

D. 50000 dvC.

B a i 30: H a n che cua xa phong la?

A. nguyen lieu san xuat kho k i e m
B. gay h a i cho da

A. Fe + dung dich H C l .

B. Fe + dung dich FeCl3.

C. Cu + dung dich FeCl2.

D. Cu + dung dich FeClg.

A. Bao quan N a t r o n g dau hoa

B. N g a m Fe t r o n g FeCl2
C. De bao ve khung ctfa bang thep can son 1 Idp de each l i vdi moi tnfdng
D. Dong CO xe m a y dang nong t a t ntrdc l a n h vao de n h a n h nguoi m a y
B a i 37: T r a d n g hop k h o n g xay r a p h a n ufng v d i NaHCOs k h i :
A. tac dung v d i CO2.

B. dun nong.

C. tac dung v d i N a O H .

D. tac dung v d i CH3COOH

B a i 38: Cho 4 chat r S n : BaS04, Na2S04, NaaCOg, CaCOg. Chon

C. t o n xa phong k h i dung p h a i vdi nifdc ciJng

thuoc thuf de n h a n biet chung?

D. l a m h a i m o i trufdng do kho p h a n huy.

A. H2O, CO2

B. H2O, H C l

C. CaCl2, NasCOa

D. H C l , CO2

B a i 31: Cho 25 gam h o n hop bpt gom 5 oxit k i m loai ZnO, F e O , F e s O i ,

MgO, Fe203 tac dung viia du v d i 200 m l dung dich H C l 2 M . K e t thuc

B . 38 .

C. 39,6 g.

D. 39,2g.

B a i 32: L e n men m gam glucozO v d i hieu suat 80% t h u difoc san pham
la CO2 va ancol etylic. L a y lUcfng CO2 t r e n qua dung dich ntfdc voi
t r o n g da t h i t h u difdc 18 gam k e t tua. T i n h m?
A. 12,96 gam

B. 20,25 gam

C. 6,2 gam

nhom

B a i 39: Cho 1,75 gam h o n hop k i m loai Fe, A l , Z n t a n hoan t o a n t r o n g

dung dich H C l , t h u diroc 1,12 Ht k h i H2 (dktc). Co can dung dich k h o i

p h a n ufng, k h o i lUOng muoi c6 t r o n g dung dich X la

A. 36g.

D. 20 p h u t

B a i 36: Viec l a m nao sau day p h a n khoa hoc.

B. 5

B a i 29: Xac d i n h k h o i iMng

B. 30 p h u t

B a i 35: Cap chat k h o n g xay r a p h a n ufng hoa hoc la

B a i 28: Can 120 m l dd K O H 0,2 M de t r u n g hoa 224 gam chat beo. T i n h

A. 6

A. 60 p h u t

D. 32,4 gam

liiong muoi k h a n t h u duoc l a :

A. 5,5 gam

B. 5,2 gam.

C. 5 gam.

B a i 40: Nguyen tijf Fe c6 Z = 26, cau h i n h e cua Fe^' la

A. [ A r ] 3 d M s l

B. [ A r ] 3 d '

C. [ A r ] 3 d l

D. [ A r ] 4s^3d^

D. 5,3 gam.

DE THI T H I j r TOT NGHl|P THPT

Mon t h i : Hoa hoc

Oe5
B a i 1: Este C H 3 C O O C 2 H 5 phan ufng vdi dung dich NaOH (dun n6ng)
sinh ra cac san pham hOfu ccf la
A. CzHsCOONa va C H 3 O H .
B. CzHsONa va CH3COOH.
C. CH3C00Na va C 2 H 5 O H .
D. C 2 H 5 C O O H va CH30Na.
B a i 2: De chuyen chat beo long thanh chat beo r^n, ngubi ta thUotng cho
chat beo long tac dung vdi
}'
A. H2O.
B. NaOH.
C. CO2.
D. H2.
B a i 3: Vinyl axetat diigtc dieu che bSng phan ling cua
A. axit axetic vdi ancol vinylic.
B. axit axetic vdi axetilen.
C. axit axetic vdi vinyl clorua.
D. axit axetic vdi etilen.
B a i 4: Len men chat X sinh ra san pham gom ancol etylic va khi
cacbonic. Chat X la
A. glucozo
B. xenlulozo.
C. tinh hot.
D. saccaroza.
B a i 5: Cho day cac chat: glucozcf, xenlulozcf, saccaroza, mantozcf,
fructozd. So chat trong day tham gia phan uTng trang bac la
A. 1.
B. 2.
C. 3.
D. 4.
B a i 6: Day gom cac chat dugc xep theo chieu tSng dan life baza tii t r a i
sang phai la
A. C 6 H 5 N H 2 , N H 3 , C H 3 N H 2 .

B. N H 3 , C 6 H 5 N H 2 , C H 3 N H 2 .

C. C H 3 N H 2 , N H 3 , C 6 H 5 N H 2 .

D. C H 3 N H 2 , C 6 H 5 N H 2 , N H 3 .

B a i 7: So amino axit dong phan cau tao ciia nhau i l n g vdi cong thufc
phan tuf C4H9NO2 la
A. 3.
B. 4.
C. 2.
D. 5.
B a i 8: Polime daac dung de che tao thuy tinh hffu ca (plexiglas) la
A. poll (metyl acrylat).

B. poli(metyl metacrylat).

C. poll (phenol - fomandehit).

D. poli (metyl axetat).

B a i 9: Day gom cac chat deu phan ufng dtfgfc vdi dung dich NaOH la
A. C 2 H 5 C I , C 2 H 5 C O O C H 3 , C H 3 C O O H .
B. C 2 H 5 O H , C 2 H 5 C O O C H 3 , C H 3 C O O H .

C. CaHsCl, C 2 H 5 C O O C H 3 , C H 3 O H .
D. C2H5CI, C2H5COOCH3, CeHs- CH2OH.

a i 10: Day gom cac chat tham gia phan ufng trang bac la
A. andehit axetic, saccaroza, mantoza
B. axit axetic, glucoza, mantoza.
C. andehit axetic, glucoza, mantoza.
D. andehit axetic, glucoza, mantoza.

B a i 11: Hoa tan hoan toan 0,1 mol h6n hap gom Na2C03 va KHCO3 vao
dung dich HCl. D i n k h i thoat ra vao binh dUng dd Ca(0H)2 dtf t h i
khoi li/ang ket tua thu difac la:
A. 6,17 gam

B. 8,2 gam

C. 10 gam

D. 11 gam.

Bai 12: Khi xa phong hoa triolein bSng dung dich NaOH thu duac san
pham la
A. natri oleat va glixerol.

B. natri oleat va etilen glicol.

C. natri stearat va glixerol.

D. natri stearat va etilen glicol.

Bai 13: Cho 200 ml dung dich AICI3 1,5M tac dung vdi V lit dung dich NaOH
0,5M lirang ket tua thu di/ac la 15,6 gam. Gia t r i Idn nhat cua V la
A. 1,2.

B. 1,8.

C. 2,4.

D. 2.

Bai 14: Cho day cac ion kim loai sau: Cu^*, Al^^ Fe^"^ va Ag^. Trat t\i sip
xep cac ion theo thuT t\l tinh oxi hoa giam dan (theo chieu tii trai sang
phai) la
A. Ag\^ Al'\. Ag^ A['\
C. Ag\^ Cu'\. Cu^\^ Fe'^ Ag\
Bai 15: TCf glyxin va alanin c6 the tao ra may chat dipeptit?
A.l
B.2
C.3
D.4
C a u 16: Cau hinh electron cua cation
co phan Idp ngo^i cung la 2p^.
Nguyen tijf R la
A. Na.
B. K.
C. L i .
D. Mg.
Bai 17: Cho s^t Ian lirat vao cac dung dich: FeClg, A I C I 3 , CuCl2,
Pb(N03)2, HCl, H2SO4 dac nong (du). So tri/dng hap phan iJng sinh ra
muoi sat (H) la
A. 5.
B. 4.
C. 3.
D. 6.
Bai 18: Nguyen t^c chung de dieu che k i m loai 1^
A. khuf ion k i m loai th^nh nguyen tuf.
B. oxi hoa ion k i m loai thanh k i m loai.
C. cho ion k i m loai tAc dung vdi axit.
D. cho ion k i m loai tac dung vdi baza.

B a i 1 9 : C h o d a y cac k i m l o a i : K , N a , B a , C a , B e . So k i m l o a i t r o n g d a y
khuT daac nudrc d n h i e t do t h u d n g l a
A . 5.

B . 2.

C. 3.

D . 4.

B a i 2 0 : C h o d a y cac k i m l o a i : K , C a , A l , F e . K i m l o a i t r o n g d a y c6 t i n h

B. Ca.

C. A l .

D . Fe.

B a i 2 1 : C h o d a y cac c h a t : N a , N a z O , N a O H , N a H C O a . So c h a t t r o n g day

B. 1.

C. 3.

D. 4

B a i 2 2 : C h a t X l a m o t bazcf m a n h , dirgfc sijf d u n g de s a n x u a t c l o r u a v o l .

B. N a O H .

C. B a ( 0 H ) 2 .

D . Ca(0H)2.

B a i 2 3 : C h o d a y cac c h a t : AICI3, N a H C O g , A 1 ( 0 H ) 3 , N a z C O s , A l . So chat

t r o n g d a y deu t a c d u n g duoc v d i a x i t H C l , d u n g d i c h N a O H l a
A . 2.

B . 4.

C. 3.

D . 5.

A . N a H C O s , A 1 ( 0 H ) 3 , AI2O3.

B . AICI3, A 1 ( 0 H ) 3 , AI2O3.

C. A l , A 1 ( 0 H ) 3 , AI2O3.

D . AICI3, A 1 ( 0 H ) 3 , Al2(S04)3.

B a i 2 5 : C h o 4,6 g a m k i m l o a i k i e m M t a c d u n g v d i \\igng niXdc (d\i) s i n h

r a 2,24 H t H2 ( d k t c ) . K i m l o a i M l a
B. Na.

C. L i .

"

D . Cs.

B a i 2 6 : C h o d a y cac c h a t : F e , FeO, Fe203, F e ( 0 H ) 2 , F e ( 0 H ) 3 . So chp +

t r o n g d a y k h i t a c d u n g v d i d u n g d i c h HNO3 l o a n g s i n h r a s a n p h a n .
k h i (chufa n i t d ) l a
A . 5.

B . 5,6.

C. 4 , 2 .

D . 7,0.

A . S a t b i o x i h o a b d i clo t a o t h a n h h d p c h a t sMt ( H ) .
B . S a t t a c d u n g v d i a x i t l o a n g H2SO4, H C l d e u t a o t h a n h h u p c h a t
(III).

C. H u p c h a t s a t ( n ) b i o x i h o a t h a n h h u p c h a t s ^ t ( H I ) .
D . H u p c h a t sat ( H I ) b i o x i h o a t h a n h

sit.

C2H5OH k h i t i e p x u c v d i n o . H u p c h a t do l a
A. CrOs.

B . Cr203.

C. C r ( 0 H ) 3 .

D . Cr2(S04)3.

B a i 3 2 : K i m l o a i X cd t h e khuf duuc Fe^^ t r o n g d u n g d i c h FeCl3 t h a n h

Fe^* n h u n g k h o n g khijf duuc H"^ t r o n g d u n g d i c h H C l t h a n h H2. K i m
loai X la

B a i 2 4 : D a y g o m cac c h a t d e u c6 t i n h c h a t l u d n g t i n h .

A. K.

A . 2,8.

B a i 3 1 : M o t h u p c h a t c u a c r o m c6 k h a n a n g l a m hoc c h a y S, C, P ,

Chat X la
A. K O H .

t r i cua m l a

sit

t a c d u n g dugc vdi d u n g d i c h H C l s i n h r a c h a t k h i l a
A . 2.

t h e t i c h k h i N O ( s a n p h a m d u y n h a t , a d k t c ) t h u duoc l a 1,12 l i t . G i a

B a i 30: P h a t b i e u n a o sau d a y dung?

khuf m a n h n h a t l a
A. K.

B a i 2 9 : C h o m g a m F e t a n h o a n t o a n t r o n g l i f p n g d u d u n g d i c h HNO3,

A. M g .

B. Fe.

C. Z n .

D. Cu.

B a i 3 3 : T h u o c thijf de p h a n b i e t b a d u n g d i c h r i e n g b i e t : N a O H , H C l ,
H2SO4 l o a n g l a
A. BaC03.

B. Al.

C. F e .

D . BaS04.

C. p o l i e s t e .

D . tu v i s c o .

B a i 34: N i l o n - 6 , 6 la m o t loai
A . tu a x e t a t .

B . tu p o l i a m i t .

B a i 3 5 : C h o m o t l o a i q u S n g chiJa sit t r o n g t U n h i e n d a duuc l o a i bo t a p

c h a t . H o a t a n q u S n g n a y t r o n g d u n g d i c h HNO3 t h a y cd k h i m a u n a u

B . 2.

C. 4.

D . 3.

B a i 2 7 : C h o 5,5 g a m h o n hap g o m h a i k i m l o a i A l v a F e v a o d u n g d i c h
H C l ( d u ) , t h u dugc 4 , 4 8 l i t k h i H2 ( d k t c ) . K h o i l u g n g c u a A l v a Fc
t r o n g h 6 n hap I a n l i / d t l a

b a y r a ; d u n g d i c h t h u dUUc c h o t a c d u n g v d i d u n g d i c h BaCl2 t h a y cd
k e t t i i a t r S n g ( k h o n g t a n t r o n g a x i t m a n h ) . L o a i q u S n g do l a
A. xiderit.

B. hematit.

C. m a n h e t i t .

D . p i r i t s^t.

B a i 3 6 : K h i c h o F e t a c d u n g v d i d u n g d i c h HNO3 l o a n g t h a y t h o a t r a

A. 2,7gam va 2,8gam.

B . 2,8gam v a 2,7gam.

m o t k h i k h o n g m a u , h o a n a u t r o n g k h o n g k h i . IChi d d l a

C. 2 , 5 g a m v a 3,Ogam.

D . 3,5gam v a 2,0gam.

A . N2.

B a i 2 8 : C h o 6,85 g a m k i m l o a i X t h u o c n h d m I I A v a o nUdc, t h u dugc

1,12 l i t k h i H2 ( d k t c ) . K i m l o a i X l a
A . Sr.

B. Ca.

B. N O .

C. NO2.

D . NH3.

B a i 3 7 : C h o d a y c a c c h a t : N a H C 0 3 , NaaCOg, Ca(HC03)2, FeCh,

c h a t t r o n g d a y p h a n uTng dUUc v d i d u n g d i c h N a O H l a

C. M g .

D. Ba.

A . 4.

B . 2.

C. 3.

D . 5.

AICI3. So

B a i 38: K h i dun ancol X (cong thuTc phan tuf C2H6O) v d i a x i t Y(c6ng thiJc
phan tuf C2H4O2) CO a x i t H2SO4 dSc l a m chat xuc tac t h u diTdc este c6
cong thurc p h a n tuf
A. C4H10O2.

B. C4H8O2.

C. C4H10O3.

D . C4H8O3

B a i 39: K h i dun hdp chat X vdi dung dich N a O H t h u dtfcfc hon hop 2 chat
hOu ca Y (C2H4NNa02) va Z (CzHeO). Cong thufc phan tuf cua X la
A. C4H7NO2.

B. C4H10NO2.

C . C4H9NO2.

D . C4H7NNa02.

B a i 40: N e u cho dung dich Na2C03, vac dung dich FeCh t h i xuat h i e n
A. k e t tua mau nau do.

B a i 6: Cac dung dich C H 3 N H 2 (1), K O H (2), K C l (3), Ba(OH)2 (4) c6 cung

nong do m o l , p H dung dich c6 thiJ tvt la
A. (4) = (2) < (1) < (3)

B. (4) < (2) < (1) < (3)

C. (3) < (1) < (2) < (4)

D . (3) < (1) < (2) = (4)

B a i 7: T r o n g phong t h i n g h i e m , k h o n g dieu che oxi bSng each

A. P h a n h u y niidc oxi gia diTdi xuc tac M n 0 2
B. N h i e t p h a n m u o i AgNOa
C. N h i e t p h a n K M n 0 4 h o a c KCIO3
D. Chimg cat p h a n doan k h o n g k h i long.

B. CO k h i thoat ra, sau do chuyen dan sang mau nau do.

B a i 8: Thiic h i e n p h a n ufng giufa N2 va H2 ( t i le mol 1:4), t r o n g b i n h k i n

C . k e t tua mau trSng hcfi x a n h .

CO xuc tac, t h u di/oc h 6 n hap c6 dp suat giam 20% so v d i ban dau

D . k e t tua m a u x a n h l a m .

t r o n g cung dieu k i e n . H i e u suat p h a n ufng l a :

A. 50%

B. G l d l T H I E U MQT S O D E THI THLT DAI H(?C VA C A O DANG

M o n t h i : Hoa hoc
.
, , . o n 7 '/
Thai gian lam bai 90 phut

A. Dong tCr anot d i chuyen ve catot; mau x a n h dung dich k h o n g d d i .

B. Dong tii catot d i chuyen ve anot; mau x a n h dung dich k h o n g d d i .

cdu 40)
nguyen tuf nguyen to X b k n g
B. 4

C. 6

D. 7

B a i 2: I o n nao dildi day c6 cau h i n h electron cua k h i h i e m Ne?

Cr

1. Na*

2.

A . 1;2;3

B. 3;4;5

3.0'-

4. N ' -

C . 1;3;4;5

D . 1;2;3;4

5. A l ' ^

B a i 3: Cho so do: X + H2SO4 (du) -> FeS04 + SO2 + H2O. Chat X c6 the la:
B. Fe

C. FeO

D . FeSOs

B a i 4: Este hoa 0,3mol CH3COOH va 0,3mol C2H5OH, k h i p h a n ufng dat

can bang, difoc 17,6gam este. H ^ n g so can bang cua p h a n ufng l a :
A. 6

B. 4

C. 8

D . 10

B a i 5: T r o n m gam dung dich H C l 20% v d i 4 m gam dung dich H C l 30%

se duoc dung dich c6 nong do
A. 25%

C. Dong tCr anot d i chuyen ve catot; mau x a n h dung dich n h a t d a n .

D. Dong tii anot d i chuyen ve catot; mau x a n h dung dich d a m d a n .

B a i 1 : T d n g so n , p, e t r o n g nguyen tuf nguyen to X bang 10. So k h o i cua

A. FeS

D . 60%

taong nao sau day mo ta diing k e t qua t h i n g h i e m

I. PHAN C H U N G CHO C A C TAT C A C A C THi SINH (40 c S u , tCr c&u 1 dhn

A. 3

C. 75%

B a i 9: D i e n p h a n dung dich CUSO4 v d i h a i dien ciXc hkng dong. H i e n

DE THI THUf DAI HQC VA CAO DANG

M a d e 111

B. 25%

B. 28%

C. 24%

D . 22%

B a i 10: Cho cac k i m l o a i : N a , Cu, M g , Fe. Thuf tii g i a m dan t i n h khuf l a :

A. M g , Fe, N a , Cu

B. Cu, Fe, M g , N a .

C. N a , M g , Fe, Cu

D . N a , Fe, M g , Cu

B a i 11: Cong thiJc oxit cao n h a t cua m o t nguyen to la R2O5. Cong thiJc
hop chat hidrua cao n h a t l a :
|||.. A. R H

B. RH5

C. R H 2

D. RH3

B a i 12: Nho tii tii dung dich H C l va dung dich NazCOa. H i e n t u o n g quan
sat diroc l a :
A. Co k e t tua xuat h i e n ngay.
B. K e t tua xuat h i e n r o i l a i t a n
C. M o t thofi gian m d i t h a y sui bot k h i
D. L a p tufc CO k h i bay r a .

B a i 13: Dung dich X chufa a mol N a H C O a va b mol NagCOa.

Thi nghiem 1: Cho (a + b) mol CaCl2 vao dung dich X duoc m gam ket tua
Thi nghiem 2: Cho (a + b) mol Ca(0H)2 vao dung dich X daoc m' gam
ket tua. So sanh dung la
A. m' < m

B. m < m'

C. m -> m'

D. m = m'

B a i 14: Nhiet phan m gam mot hop chat cua sit trong khong k h i cho
den khi khoi liiong khong doi duoc - ^ g a m rSn. Vay hop chat da
dung CO cong thuTc la:
A. Fe(N03)3

B. Fe(0H)3

C. Fe(N03)2

D. Fe(0H)2

diioc dung dich X. Chia dung dich X lam hai phan bang nhau.
ufng

v t e du vdi 200ml dung dich K I 1,5M

Phan 2: Lam mat mau vCfa du V ml dung dich KaCrgOT 0,5M.

Chi ra V
A. 150

B. 100

C. 50

D. 25

C a u 16: Hon hop X gom A l va Na. Chia X lam 2 phan bang nhau.
+ Cho phan 1 vao mfdc dir thay thoat ra 4,48 l i t k h i (dkc)
+ Cho phan 2 phan

uTng

vdi dung dich NaOH

diT

thay thoat ra 7,84 l i t

khi (dkc).
B. 16,7gam

B a i 18: Mot dung

D. 7,7gam

B. Fe203
djch

C. Fe

D. Fe304

X chufa cac ion: Mg^\, NH^va CI". Chia X

D. Chi Fe(N03)2

B a i 20: Cho 5 gam hon hop X gom Mg, A l , Zn, Fe tac dung vdi laong da
dung dich HCl, daoc 2,24 l i t khi (dkc). Mat khac 5 gam X tac dung
vdi k h i clo da thu daoc 12,526 gam hon hop muoi. Phan tram khoi
laong Fe trong X la:

- Phan 1 tac dung vdi dung dich NaOH da, dun nong thu dilgfc 0,58 gam
ket tua va 0,672 Ht khi (dkc)
- Phan 2 tac dung vdi dung dich BaCl2 da thu dagc 4,66 gam ket tua.
Tong khoi laong cac chat trong dung dich X la:
B. 3,055gam

B. 13,44%

C. 19,28%

D. 18,92%

B a i 21: Them ta t a den k h i da dung dich Ba(0H)2 0,1M vao 300ml dung
dich Al2(S04)3 0,05M. ta thay xuat hien ket tua trSng, tang dan, roi
lai thay ket tua tan dan, den khi da dung qua V ml dung dich B a C l 2
thi thay ket tiia khong tan them naa. Chi ra V
A. 550
B. 600
C. 500
D. 450
B a i 22: Vitamin A cong thiJc phan tuf C20H30O, c6 chufa 1 vong 6 canh va
khong chaa lien ket 3. So lien ket doi trong phan tuf vitamin A la:
A. 7
B. 6
C. 5
D. 4
B a i 23: Nung hon hop gom 0,2mol C2H2 va 0,3mol H2 c6 xuc tac N i ,
daoc hdn hop X. Dot chay X, dan toan san ph&m qua dung dich nadc
voi trong c6 da, khoi laong binh tang.
B. 17,6gam

C. 30gam

D. 26,6gam
H2SO4

dac d nhiet do thich hop thi c6 the thu daoc toi da bao nhieu ete?
A. 5

B. 3

C. 4

D. 6

!ai 25: Tinh axit tang dan theo trat ta

A. p-clophenol < p-nitrophenol < p-bromphenol
B. p-clophenol < p-bromphenol < p-nitrophenol
C. p-bromphenol < p-clophenol < p-nitrophenol
D. p-nitrophenol < p-bromphenol < p-clophenol

lam hai phan bSng nhau.

A. 4,110gam

C. chi Fe(N03)3

B a i 24: Dun nong hon hop gom 3 ancol la ROH, R'OH va R"OH vdi
C. 8,6gam

B a i 17: Mot hoc sinh dieu che Fe2(S04)3 bSng each Ian li/Oc cho Fe, FeO,
FezOa va Fe304 tac dung vdi H 2 S O 4 dSc, nong. De thu dtfoc laong
Fe2(S04)3 nhtf nhau t h i suf dung chat nao tiet kiem axit nhat?
A. FeO

B. Fe(N03)3 va H N O 3

A. 9gam

Chi ra khoi luong hon hop X.

A. 15,4gam

A. Fe(N03)2 va Cu(N03)2

A. 14,33%

B a i 15: Hoa tan mot luong Fe304 hhng dung dich H2SO4 loang dir thu
Phdn 1: Phan

B a i 19: Hoa tan a gam hon hop Fe, Cu (ti le khoi laong 6:4) bkng mot
luong dung dich H N O 3 . Sau phan ufng thu duoc dung dich X, con lai
0,2a gam rSn va thay c6 k h i thoat ra. Dung dich X chaa.

C. 5,110gam

D. 6,110gam

ai 26: Cho 0,05mol hon hop hai andehit hen tiep trong day dong dang
tac dung vdi laong da dung dich AgN03/NH3 daoc 18,9gam Ag. Cong
thdc phan tuf hai andehit la:
A. C2H4O va C3H6O

B. HCHO va C2H4O

C. C3H4O va C4H6O

D. C3H6O va C4H8O.

Bai

27: D o t chay ( C H 3 C O O ) 2 C a t h u dtfoc san p h a m gom CO2, H2O va

m o t chat r S n . Chat r a n do l a :

A. C a C O a

B. Ca(HC03)2

C. CaO

Bai

D. Ca

B a i 28: Cho hflu hop cac chat hOfu co don chufc c6 cong thufc p h a n tijf
C2H4O2 tac dung h e t v d i N a O H t h u daoc h 6 n hop cac chat hOfu co Y.

34: Cho cac polime sau: cao su isopren, PVC, c a o su b u n a - N , t o

capron, poli(phenol-fomandehit), n i l o n - 6 , 6 . So polime d U d c dieu che
bang phan uTng t r u n g hop, t r u n g n g i T n g , dong t r u n g hop I a n l u g t l a :

A. 4,2,1

B. 2,3,2

C. 2,3,1

D. 3,2,1

B a i 35: X la este cua a - a m i n o a x i t Y va ancol etylic. D o t chay hoan t o a n

Y gom c6:

20,6gam X t h u duoc 35,2gam CO2, 16,2gam H2O va 2,24 l i t N2 (dkc).

A. CHsONa, CHgCOONa,

Cong thufc cau tao t h u gon cua X l a :

HCOONa

B. CH3OH, CH3COOH, H C O O H

A. H2N-(CH2)2-COO-C2H5

B. H z N - C H C C H s K C O O H

C. CHsCOONa,

C. H 2 N - C H 2 - C O O - C 2 H 5

D.

CH3OH

D. CH3OH, CHsCOONa,

HCOONa

H2N-CH(CH3)-COO-C2H5

B a i 36: Cho h 6 n hgfp X gom 2 chat hGu ca p h a n ufng v d i K O H vCra du,

B a i 29: Xa phong hoa hoan toan 8,86gam chat beo X can dung 62ml

can dung 500ml dung dich K O H I M . Sau p h a n ufng t h u h o n hop 2

dung dich K O H 0,5M t h u di/gtc muoi k a l i cua cac a x i t beo va 0,92gam

muoi cua 2 a x i t no, don va 1 ancol no, don Y. Cho Y tac dung h e t v d i

glixerol. C h i so xa phong va chi so a x i t cua chat beo X I a n luat l a :

N a duoc 3,36 l i t H2 (dktc). Cho biet 2 chat hufu ccf t r e n la hop chat gi?

A. 200 va 6,45

B. 200 va 193,45

A. 1 a x i t + 1 ancol

B. 1 este +1 a x i t

C. 196 va 8,4

D. 198,8 va 5,6.

C. 1 este + 1 ancol

D. 2 este.

B a i 30: Cho cac chat sau:

B a i 37: Chat huTu co X chi chufa 1 loai n h o m chufc tac dung v d i 1 l i t dung

1. H 2 N - C H 2 - C O O H 2. H C O O H

3. H O O C - ( C H 2 ) 2 - C H ( N H 2 ) - C O O H

dich N a O H 0,5M t h u daoc muoi va O,lmol m p t ancol. De t r u n g ho^

4. H 2 N - ( C H 2 ) 4 - C H ( N H 2 ) - C O O H

5.

li/ong N a O H du can dung 0,5 l i t dung dich H C l 0,4M. Vay X co cong

CH3CH(NH2)COOH

thufc dang

So chat l a m doi mau quy t i m a m l a :

A. 2
Bai

B. 3

C. 5

D. 4

31: L y s i n : H 2 N - ( C H 2 ) 4 - C H ( N H 2 ) - C O O H . Cho m gam l y s i n phan

A. R - C O O - R '
Bai

B. ( R - C 0 0 ) 3 R '

C. ( R - C 0 0 ) 2 R '

D. R ( C 0 0 - R ' ) 3 .

38: Cho h o n hop e t y l isobutylrat, a x i t 2-metylpropanoic,

metyl

iJng v d i dung dich chOfa 0,2mol N a O H t h u d\Xac dung dich X, dung dich

butanoat p h a n ufng vCra du v d i 200ml dung dich h 5 n hop N a O H 0,05M

X p h a n ling vCra du v d i dung dich chura 0,4mol H C l . Gia t r i m 1^:

va K O H 0,1M. K h o i luang muoi t h u diTOc sau p h a n ufng l a :

A. 13,2gam

A. 3,54gam

B. 29,2gam

C. 14,2gam

D . 14,6gam

B a i 32: Cac a m i n the h i e n daac t i n h bazo la do a m i n c6:

D. 3,3gam.

X + NaOH - ^ Y + Z

B. Nguyen tijf N c6 do a m dien Idn

Z + H2

C. K h a n a n g p h a n ufng v d i a x i t tao muoi

B a i 33: D o t chay hoan t o a n cacbohidrat X b l i n g m o t luang

oxi vCra du

n h a n t h a y no^: n^o,: n^^^o = 1 : 1 : 1- X c6 k h a nSng l a m m a t m^u

nifdc b r o m . Vay X c6 the la cacbohidrat nao t r o n g so cac chat sau?
C. Saccarozd

C2H5OH

Z + Cu(0H)2 + N a O H

D. Nguyen tuf N con doi electron chaa t h a m gia l i e n k e t .

B. Fructozd

C. 3,78gam

B a i 39: Cho so do sau:

A. K h a n a n g t h u y p h a n tao O H "

A. Glucozo

B. 3,62gam

D . Mantozd.

Y + C u 2 0 i + H2O

Vay X CO cong thufc p h a n tuf la

A. C4H6O3
ai

40:

Cho

B. C5H8O2
day

cac

chat:

C. C4H8O2
C2H3CI,

C2H4,

D. C4H6O2.
CgHg,

C2H3COOH,

H2N(CH2)5COOH. So chat t r o n g day co k h a n a n g t h a m gia p h a n dng

t r u n g hop l a :
A. 2

B. 3

C. 4

D . 5.

B a i 48: Thuy phan (moi trUcfng OH ) cac chat sau:

II. P H A N R I E N G ( 1 0 c a u )
Thi

siiih hoc thco cliiiang

cho chuang trlnh

trlnh

nao tlii chl diCgc lam phdn

do (phdn A hoac

danh

ieng

B)

D. Phan ufng mau dat trang thai can bSng.

B a i 42: Cho so do chuyen hoa (m6i mui ten la mot phan ufng, cae ky
hieu utng vdi s a n pham chinh):
Y

B . Y la xeton

C. T la hop chat tap chuTc

D. Z thuoc loai hdp chat v6 co.

C. AgNOg

A. 43,2gam

B. 2,7

C. 2,8

D. 5,8

B. C 5 H 8 O 4

C. C 4 H 4 O 4

D. C 3 H 4 O 4

B. 21,6gam

C. 24gam

D. 12gam

B a i 54: Chon phat bieu dung

D. 0,34V.

A. Dung dong k i m loai de khuf ion Zn^* trong dung dich

B. Dung ion Ag^ de oxi hoa Fe^* trong dung dich
C. Dung ion Mg^^ de oxi hoa sSt k i m loai trong dung dich.

D. 3

D. Dung nhom k i m loai de oxi hoa ion Ag* trong dung dich
Bai 55: Cho phan ufng: C U 2 O + H 2 S O 4 bang -> C U S O 4 + Cu + H 2 O ; Chon

D. [Ne]3d^4s^

D. NaOH.

D. 10208 va 36240 goc.

Bai 53: Khoi lugng ket tua toi da k h i dun 4,5gam HCHO vdi Cu(0H)2
trong moi trudng kiem la

B a i 46: Cau hinh electron cua Cr (Z = 24) la

B. N a 2 S 0 4

C. 5401 va 18210 goc

A. C 4 H 6 O 4

Bai 45: Cho cac c h a t sau: FeCh, Nal, NajSOa, NaOH, HCl, H N O 3 . So hop
chat C O kha nang khu Cr**^ (trong Cr^O^") -> Cr^^ (dieu kien c6 du) la

A. H N O 3

B. 21604 va 72840 goc

KOH vufa du thu ducfc 9,6gam muoi. Cong thiJc phan tuf cua axit la:

chuan cua cSp oxi hoa khuf Cu^VCu la:

B a i 47: De p h a n biet cac dung dich: NaCl, CuCla, FeClz, FeCls, AlCl3,c6
the dung thuoc thuf la:

A. 10802 va 36420 goc

B a i 52: 5,8gam mot axit cacboxylic mach thSng X tac dung vdi lifcfng

B a i 44: Cho bie't: E,,,.eu, = I . I V ; E"^,.^^ = -0,76V. The' dien cifc

C. [Ar]3d^4s^

D. H 2 N C 3 H 5 ( C O O H ) 2 .

A. 2,4

D. Nho dung dich thuoc t i m vao dung dich axeton, mau t i m bi mat

B. [Kr]3d^4s^

C. ( H 2 N ) 2 C 4 H 8 ( C O O H ) 2

bang nhau, dung dich tao thanh c6 c6 pH bSng

C. Nho dung dich kali dicromat vao dung dich axetandehit, mau da
cam bi mat

C. 2

B. H a N C s H g C O O H

B a i 51: Tron hai dung dich HCl 0,002M va H 2 S O 4 0,001M vdi the tich

dung hien tuong t h i nghiem?

C. 1,86V

A. H O O C C 3 H 5 ( N H 2 ) 2

Theo chifcfng trinh Nang cao (10 cdu, tii cdu 51 den cdu 60)

B. Nho dung dich thuoc tim vao dung dich axetandehit, mau tim bi mat.

A. [Ar]3d'4s^

D. 1

dung so' goc glucozcf c6 trong moi loai xenlulozO tren Ian luot la

A. Nho n\idc brom vao dung dich axetandehit, mau cua brom hi mat.

C. 5

1.750.000dv.C va trong scfi gai la 5.900.OOOdv.C. Vay mot each gan

A. X la ancol bac I

B.

B. 2

B a i 50: Kho'i Itrcrng phan tuf trung binh cua xenlulozo trong scfi bong la

Chon phat bieu dung

'

6. C H 3 C H 2 C C I 3

thanh 22,02 gam muoi. Cong thiJc phan tuf cua X la:

C. Tang hieu s u a t phan ijfng t h u a n

A. 5

5. CaHsBr

22,92gam muoi. Cung 17,64gam X tac dung vdi li/ong viTa du HCl tao

B. Tang toe do phan ufng nghieh

B . -0,34V

4. C H 2 = CHCl

ai 49: 17,64gam amino axit X tac dung vCra du vdi dung dich NaOH tao

A. Tang toe do phan ufng thuan

A. -1,86V

3. C I C H 2 C H 2 C H 2 C I

A. 3

B a i 41: Chat xiic tac trong phan iJng thuan nghich lam

B a i 43: Mo ta nao sau day khong

2. C H 3 C H C I 2 C H 3

So trUcfng hop thu ducfc san pham cuoi cung la ancol?

Theo chiftfng trinh C h u a n (10 cdu, tii cdu 41 den cdu 50)

Propilen - i l i ^ X - i ^ ^

1. C H 3 C H C I 2

phat bieu diing. Trong phan iJng ...

A. H 2 S O 4 la chat oxi hoa

B. C U 2 O la chat khuf

C. C U 2 O tu oxi hoa khuf

D. H 2 S O 4 la chat khuf.

B a i 56: 5,6gam oxit k i m l o a i hoa t r i 2 t a n vCfa du t r o n g 175ml dung dich

fit THI

H2SO4 0,4M. TCr dung dich t h u diTpc t a c6 the k e t t i n h dupe 17,5gam

JVIa de

t i n h the muoi n g a m nudc. Cong thufc p h a n tijf cua muoi n g a m nUdc la:
A. CUSO4.5H2O

B. CUSO4.4H2O

C. MgS04.7H20

D . ZnS04.7H20.

Dung dich 1

Dung dich 2

Dung dich 3

cor

HCO3

C O ^ va HCO3

. A. Cho dung dich N a C l diT, Ipc, cho a x i t H C l vao nifdc Ipc

v d i xuc tac

da ba nguyen to C, H , O.
C. 4

D. 5

C. 4

D.

5
xep

B. Na^ > M g ' ^ > F" > O'"

C. F" > M g ' " > N a " > O ' -

D . O'" > F" > N a " > M g ' " .

k e t cpng hoa tri?

A. NH4CI

B. CaFa

C. PH3

D. CH2O

B a i 4: P h a n iJng
K M n 0 4 + SnS04 + H2SO4 - > Sn(S04)2 + MnS04 + K2SO4 + H2O, cd
B. 30

C. 62

D. 32

B a i 5: Dung dich nUdc cua X l a m quy t i m nga mau x a n h , con dung dich
Y k h o n g l a m quy doi mau. T r p n X v d i Y t h u dupc k e t t u a . X, Y I a n

NaOH

lirpt la

B. m - m e t y l a n i l i n

C. p-crezol

D. o-crezol

B. T i n h hot va xenlulozo deu k h o n g cho phan ufng t h u y p h a n

C. T i n h bpt va xenlulozo deu k h o n g t h a m gia p h a n ufng t r a n g gUcfng
td: H = li

= 12; N = 14; O = 16; F ^ 19; Ne = 20; Na = 23; Mg = 24;

= 27; S = 32; CI = 35.5;

K = 39; Ca = 40; Cr = 52; Mn = 55;

Fe - 56; Cu = 64; Br = 80; Ag = 108; Ba = 137.

C. K O H va FeCl3

D. N a O H va K2SO4.

A. D i e n p h a n dung dich KNO3.

B. D i e n p h a n dung dich CUSO4

C. D i e n p h a n dung dich N a C l

D. D i e n p h a n dung dich ZnCl2.

B a i 7: Hoa t a n h e t m gam bpt Cu t r o n g dung dich HNO3, toan bp k h i

D . T i n h bpt va xenlulozo deu c6 the tao ra mau v d i iot

tii (theo dvC) cua cdc nguyen

B. K2CO3 va Ba(N03)2

hoa xanh? B i e t cac t h i n g h i e m deu dung dien cifc trcf

A. T i n h bpt va xenlulozcf deu t a n t r o n g nifdc Svayde

nguyen

A. NazCOa va KNO3

B a i 6: T r o n g t r u d n g hpp nao sau day tao t h a n h dung dich l a m quy t i m

B a i 60: N h a n x e t nao sau day la dung?

Al

B. 2

A. Mg'^> Na^> F - > O ' -

V a y X \h:

He = 4 ,C

phut

B a i 2: Cho cac ion N a \, F", O^". Day nao diTdi day dupe s^p
.
diing theo chieu g i a m dan ban k i n h ion?

A.31

Cho biet khdi lugng

Thai gian lam bai 90

t o n g cac he so can b^ng (nguyen, t o i gian) la

HoC

A. m - c r e z o l

M o n t h i : Hoa hoe

112

A. 3

B a i 59: Cho sa do sau: X + HNO2 ^ Y + N2t + H2O

Y +

DANG

B a i 3: H p p chat nao dtfdi day t r o n g p h a n tuf c6 ca l i e n k e t ion va l i e n

H2SO4 d a c , CO the t h u diTpc t o i da bao nhieu san p h a m hufu co chufa t o i

B. 3

CAO

I'l

D. Cho dung dich Ca(0H)2 dU, Ipc, cho a x i t H C l vao nifdfc Ipc
Dun nong tii tit h o n hpp etanol va p r o p a n - 2 - o l

C. Cho dung dich BaClz dif, Ipc, cho a x i t H C l vao nude Ipc

VA

B a i 1: So electron doe t h a n t r o n g m o t ion Fe^"^ (Z = 26) d t r a n g t h a i

i
khong bi kich thich la:

B. Cho dung dich NH4CI dU, Ipc, cho a x i t H C l vao nirdc Ipc

A.

HQC

U. PHAN CHUNG CHO TAT CA CAC THi SINH (40 cSu, tCr c^u 1 dfen cau 40)

B a i 57: Chpn each phan biet ba dung dich chufa anion sau:

B a i 58:

THUr DAI

1^

N O (duy n h a t ) t h o a t ra cho tac dung v d i 2,24 l i t oxi (dkc) dupe h 6 n

ML

hpp k h i Z. H a p t h u h e t Z vao nude dupe dung dich chi chda HNO3.

Hp Gia t r i m la
A. 12,8

B. 6,4

C. 9,6

D. 16

B a i 8 : Cho chuoi p h a n uTng

K O H -> KCIO3 -> K C l

T N 2 : Cho m gam bot Fe (du) vao dung dich chufa b m o l AgNOg

K C I O - > KHCO3 -> K2CO3

KCl

Sau k h i p h a n iJng xay r a hoan toan, k h o i lUOng chat r f i n t h u duoc or

h a i t h i n g h i e m deu bSng nhau. So sanh nao diidi day la diing?

So phan ufng oxi hoa khijf la

A. 4

B. 3

C. 5

A. a = 5b

D. 2

B a i 9 : R e m tac dung v d i dung dich H2SO4 loang, cho t h e m vao do vai

giot dung dich CUSO4. H i e n tugtng quan sat dugfc l a :
A. Hot k h i t h o a t r a n h i e u h d n

B. B o t k h l t h o a t r a i t dan

C. Bot k h i t h o a t r a k h o n g doi

D. B o t k h i ngCfng t h o a t r a ngay.

B. b = 10a

C. a = b

D. b = 5a.

B a i 1 7 : D i e n p h a n dung dich chiJa a mol K C l va b m o l Cu(N03)2 (dien

I
circ trcf, CO m a n g ngan). De dung dich sau dien p h a n hoa t a n dugc
MgO t h i sir l i e n he gifla a va b l a :
A. B < 2a

B. a > 2b

C. a = 2b

B a i 1 8 : Phan ufng nao sau day khong

B a i 1 0 : K h o i liTcrng s^t ciic dai t a n dtfcfc t r o n g 200ml dung dich H N O

D. a < 2b.

t h u duac h o n hgp muoi?

2 M la bao nhieu? (Biet chi tao san p h a m khuf duy n h a t NO)

Mk^ A . Phenyl axetat + N a O H

B. V i n y l axetat + K O H

A. 5,6gam

D. Fe304 + H C l

B. 10,08gam

G. 8,4gam

D. 5,04gam

B a i 1 1 : D i n k h i X vao dung dich K I c6 pha t h e m v a i giot ho t i n h bot,

C. K O H + Ba(HC03)2 ^

i B a i 1 9 : Hoa t a n chat r ^ n X vao dung dich H N O 3 loang nh\i duac dung

dich Y va k h o n g t h a y k h i t h o a t r a . Cho N H 3 dir vao dung dich Y, loc

k h o n g t h a y xuat h i e n m a u x a n h t i m . V a y X la
A . Clo

B. B r o m

C. Ozon

D. Oxi

B a i 1 2 : T r o n dung dich X (H2SO4 0,02M) v d i dung dich Y ( N a O H 0,03M)

B. 3 : 2

C.l : 1

CaCOa b i n h i e t p h a n l a :
B. 50%

C. 13,92%

D. 22%

B a i 1 4 : Cho m o t lifcfng Fe t a n h e t t r o n g 200ml dung dich H N O 3 2 M thu

dugc dung dich chufa m gam muoi va c6 k h i N O la san p h a m khuf du^

A. 7,84

B. 8,4gam

C. 9,8gam

t i n h k h i e t bang each chi dung m o t ho6 chat nao dudi day?

1) Dung dich N a O H

2) Dung dich H N O 3

3) Dung dich H C l

4) Dung dich AgN03

5) Dung dich FeCla

6) Dung dich Cu(N03)2

A. 3,4,5

C. 2,6

B. 1,3,4,5

T N I : Cho m gam bot Fe (dix) vao dung dich chufa 2a m o l Cu(N03)2

G. 2,24

2. F e C l 2

3. (NH4)2C03

5. Mg(N03)2

6. K2Cr207

Dung dich khong

D. CuO.

D . 5,6.

tao k e t t u a v d i Ba(0H)2 la

A. (1), (4) va (5)

B. (1), (5) va (6)

p C . (4)va(6)

D. (4)

B a i 2 2 : T r o n g cac chat sau: AI4C3, C a C 2 , K C N , H G H O , NaHG03,GHCl3,

I I N a a C O a , C2H5OH, CHaCOONa. So' hgp chat hUu ca l a :
A. 4

B. 5

G. 6

D. 7

B a i 2 3 : Hidrocacbon X c6 ti k h o i h a i so v d i CH4 b^ng 4,5. Cho X t^c

dung v d i clo tao 4 dong p h a n monoclo. T a n goi cua X l a :

D . 1,2,3,4,5

C a u 1 6 : T i e n h a n h 2 t h i n g h i e m sau:

B. 6,72

1. N a H C 0 3

4. NaN03

D. l l , 2 g a m

B a i 1 5 : M o t mau A g b i I a n t a p chat la A l va Z n . Co the t h u dtfdc Ag

C. FegOs

B a i 2 1 : Cho cac dung dich sau:

n h a t . K h o i luang Fe bSng bao nhieu de m dat gia t r i I d n nhat?

A. 5,6gam

B. ZnO

B a i 2 0 : Cho tCr tCf 500ml dung dich chiJa Na2C03 0,4M va N a H C 0 3 I M

vao 450ml dung dich H C l I M , p h a n ufng hoan toan, t h u diTOc V l i t
CO2. Gia t r i V l a :

D. 4 : 3

B a i 1 3 : N u n g nong m gam CaCOa dtfcfc 0,78m gam r a n . Vay p h a n t r a n

A. 78%

k e t t i i a , nung t r o n g k h o n g k h i l a i t h u dtrgfc rSn X. Vay X c6 the la

chat nao sau day?
A. Fe304

t h u dagc dung dich c6 p H = 2. T i le the t i c h V ^ : V Y l a :

A. 2 : 3

* | A . pentan

C. neo-pentan

B. isopentan
D. 2 , 2 - d i m e t y l propan.

B a i 24: N h a n xet nao sau day khong

l a i 31: Tix glyxin v^ alanin c6 the tao th^nh toi da bao nhieu tripeptit?

dung?

A. 27

A. A n l y l bromua de t h a m gia p h a n iJng the h o n p h e n y l a m i n

B. 8

C. 6

D . 9.

^ai 32: Cho cac amino a x i t sau:

B. V i n y l clorua c6 the ducfc dieu che tCf 1,2 - dicloetan

1) A x i t 2 - a m i n o - 3 - p h e n y l propanoic (phenylalanin)

C. T h u y p h a n e t y l clorua t r o n g m o i trUcJng k i e m ducfc ancol bac h a i

2) A x i t 2 - a m i n o - 3 - m e t y l butanoic (vaUn)

D . tfng vdfi cong thuTc p h a n tijf C4H9Br c6 4 dong p h a n cau tao

3) A x i t 2 - a m i n o - 4 - m e t y l pentanoic (leuxin)

B a i 25: Cho h a i p h a n uTng

4) A x i t 2 - a m i n o - 3 - m e t y l pentanoic (isoleuxin)

CeHsOH + N a O H ^ CeHgONa + H2O

N h a n d i n h khong

CO2 + CeHsONa ^ CeHjOH + NaHCOg

dung ve cac amino a x i t da cho

A. Deu la hgfp chat hufu ca dan chiJc

H a i p h a n ufng t r e n chufng to:

B. Deu la hap chat cd t r o n g ca the dong v a t

A. phenol c6 t i n h a x i t

C. Deu la hap chat hC?u ca t a p chat

B. phenol c6 t i n h a x i t m a n h han a x i t cacbonic

|i

C. phenol eo t i n h a x i t va t i n h axit m a n h han a x i t cacbonic

B a i 33: Xenluloza t a n dugc t r o n g

D . phenol c6 t i n h a x i t va t i n h a x i t yeu han a x i t cacbonic

A. Nude brom

B a i 26: 7,74g andehit mach k h o n g p h a n n h a n h X tac dung vCra du vdi

dung dich chufa 34,4gam b r o m . X c6 cong thuTc p h a n tuf:
A. CH2O

B. C3H4O2

C. C4H8O

D. Deu la t h a n h p h a n tao nen p r o t e i n

D . C4H6O2

C. Nude v o i t r o n g
B a i 34: P o l i ( v i n y l ancol)

D . Cu(0H)2/0HCH,

B a i 27: T r u n g hoa 4,5gam a x i t cacboxylic X bSng N a O H vCra du, c6 car.

duac 6,7 gam muoi k h a n . X c6 cong thufc p h a n tuf l a :
A. C2H4O2

B. C2H2O4

C. C3H4O2

D . C4H6O4

B a i 28: E la este c6 t i k h o i hai so vdfi H2 bang 44. Xa phong hoa 4,4gani

bang N a O H vCra du r o i c6 can duac 4 , l g a m muoi khan. Chi ra ten cua E
A. propyl fomat

B. e t y l axetat

C. isopropyl fomat

D . m e t y l propionat.

B a i 29: X la este dan thufc. Lay m gam X tac dung vdfi N a O H vCra du thu
duac san pham hOfu ca duy nhat Y. Dot chay hoan toan liigfng Y t r e n
dirac: 5,3gam NagCOs; 10,08 l i t CO2 (dkc); 8 , l g a m H2O. Chi ra gia t r i mA. 10

B. 5

C. 33,2

D . 12,4.

B a i 30: A x i t glutamic: H O O C - ( C H 2 ) 2 - C H ( N H 2 ) - C O O H . Cho 14,7

gam

axit glutamic p h a n ufng v d i 200ml dung dich H C l I M t h u dirac dung

dich X. Cho X p h a n ufng v d i laang vCra dij K O H t h u dUdc dung dich ^
CO can Y t h u duac liigfng muoi k h a n l a :
A . 22,3gam

B. 30,8gam

C. 37,2gam

CHOH

dufgfc dieu che t r i i c t i e p tCf

A. V i n y l axetat

B. P o l i ( v i n y l clorua)

C. V i n y l ancol

D. Poli ( v i n y l axetat).

B a i 35: Cho cung m o t k h o i lugfng m o i chat: C H 3 O H , H C O O H ,

C2H4(OH)2, C3H5(OH)3 tac dung v d i iMng d\i N a . So' m o l H2 Idn n h a t
sinh ra tCr p h a n iJng cua N a v d i
A. C H 3 O H

B. H C O O H

C. C3H5(OH)3

D . C2H4(OH)2.

B a i 36: H i d r o hoa hoan toan ( N i , t) cac chat sau:

1. Glucoza

2. Fructoza

3. B u t a - l , 3 - d i e n

4. A x e t a n d e h i t

5. B u t - 2 - e n

6. Ancol anlylic

7. Mantoza

8. Saccaroza

Cac chat cho cung san p h a m l a :

: A. 1 va 2; 3 va 5
C. 3 va 6; 7 va 8

D . 63,35gam.

B. Dung dich [Cu(NH3)4](OH)2

B. 1 va 2; 3 va 5; 4 va 6
D. 1 va 2; 7 va 8.

B a i 37: D o t chay hoan toan 0,2 mol hon hop gom axit propionic, ancol
etyUc, etilen glycol. DSn san p h a m chay qua b i n h dung H 2 S O 4 dSc
t h a y k h o i liiOng b i n h t a n g m gam. C h i r a m
A. 3,6

B. 10,8

C . 7,2

D. 9.

B. C4H8O2

C. C4H10O

D . C4H8O.

B a i 39: Oxi hoa m gam ancol etylic b k n g oxi (xuc tac, t) di/cfc h o n hop
gom X andehit, nxidc va ancol nhu. Cho X p h a n iJng v d i lifgrng diX Na
t h a y thoat r a 2,24 l i t H2 (dkc). Gia t r i m la
A. 4,6

B. 9,2

C. 6,9

"'Q^'^"

B . (3) < (1) < (2) < (4)

D . (1) < (4) < (3) < (2).

B a i 44: Cho h o n hgp rSn X gom MgO, ZnO, AI2O3, FezOg va Cu vao
dung dich H C l dir. Sau k h i khuay deu cac p h a n ufng xay r a hoan toan
dirge dung dich Y va r a n Z. Vay dung dich Y gom
A. MgCl2, Z n C l 2 , A I C I 3 , F e C l a , C u C l 2 , H C l
B . MgCl2, Z n C l 2 , A I C I 3 , FeCls, H C l

D . 18,4

C. MgCl2, Z n C l 2 , AICI3, FeCla, H C l

B a i 40: N h a n d i n h so do sau:
CH3COCH3 - ^ ^ X

\. (3) < (1) < (4) < (2)

C. (4) < (1) < (3) < (2)

B a i 38: H o p chat nao diidi day c6 6 dong phan dOn chiJc, mach hd?
A . C3H9N

Jai 4 3 : Cho cac chat sau: andehit axetic (1); axit fomic (2); ancol etylic
(3); d i m e t y l ete (4). ThiJ t u n h i e t do soi diing la

D. MgCl2, Z n C l 2 , A I C I 3 , FeCl3, CuCl2, H C l .

) Y

H.so4."

) C4H6O2

a i 45: De p h a n ilng vCra du v d i 100ml dung dich CrCl3 I M can m gam

Zn. Gia t r i m la:

Hop chat Y CO dSc d i e m

A. 3,25

A. Co k h a nang t r a n g guong
B. Co the l a m m a t mau nifdc b r o m

B . 9,75

C . 6,5

D. 4,875.

a i 46: X e t cac hon hgp cung so' m o l . P h a t bieu nao sau day la sai?

C. La axit cacboxylic don chuTc no

A . H o n hgp N a 2 0 va AI2O3 t a n h e t t r o n g nUdc diT

D. Tac dung dirge ca N a va N a O H .

B . H 6 n hgp Fe203 va Cu t a n h e t trong dung dich H C l dir

II. PHAN RieNG (10cau)

Thi sink hoc theo chuang trinh
cho chuang trinh

C . H o n hgp K N O 3 + Cu t a n h e t trong dung dich H2SO4

nao thi chl dugc Idm phdn danh

rieng

do (Phdn A hodc B)

a i 47: T r o n g tU nhien c6 nhieu nguon chat hufu cd sau k h i bi t h o i rufa tao

T h e o chxidng t r i n h C h u a n (10 cdu, tii cau 41 den cdu

B a i 41: Cho p h a n ling: CaCOg ^

D . H o n hgp FeS va CuS t a n het trong dung dich H C l dir.

50)

CaO + CO2. K h i ha n h i e t do cua he

ra k h i H2S. Tuy nhien t r o n g khong k h i h a m lirgng H2S r a t thap v i :

A . H2S t a n n h i e u t r o n g nirdc

p h a n ufng ngiTdi ta t h a y ap suat k h i CO2 g i a m d i . Dieu nay chufng to

B . H2S bi CO2 t r o n g k h o n g k h i oxi hoa t h a n h chat khac

p h a n ufng da cho c6:

C . H2S b i O2 t r o n g k h o n g k h i oxi hoa cham t h a n h chat khac

A. Chieu t h u a n la t h u n h i e t

B. Chieu t h u a n la toa n h i e t

C. Chieu nghich la t a n g ap suat

D. Chieu t h u a n la g i a m ap suat.

B a i 42: H g p chat X c6 cong thufc p h a n tuf C4H8O. X tac dung v d i dung

dich AgNOa/NHs sinh r a A g k e t tua. H i d r o hoa X t h a n h Y. D u n Y v d i
H 2 S O 4 sinh r a anken mach k h o n g n h a n h . Ten cua X l a :
A. Butanal

B. A n d e h i t isobutyric

C. 2 - m e t y l p r o p a n a l

D. butan-2-on.

D . H2S b i p h a n huy d n h i e t do thirdng tao r a S va H2.

a i 48: Dun ancol ddn chufc X v d i H2SO4 dSc t h u dirge hgp chat Y. B i e t
dy/x = 1,609. Ten goi cua X l a :
A. metanol

B . propanol

C . etanol

D. propan-2-ol.

a i 49: H o n hgp X gom e t y l a m i n , d i m e t y l a m i n va etylamoni axetat.

Cho m o t lirgng X tac dung vira du v d i dung dich chufa 0,3moi H C l , sau
p h a n ling t h u di/gc dung dich Y chiJa lirgng muoi la
A. 24,45gam

B . 24,15gam

C . 20,25gam

D . 8,15gam.

B a i 50: TCr m t a n xenlulozo ngUcfi t a san xuat ducrc 53,46 t a n xenlulozo

t r i n i t r a t (biet hieu suat p h a n ufng chuyen hoa xenlulozo la 90%). C h i
ra m

B a i 58: Cho ode chat sau: phenol, ancol etylic, e t y l clorua. P h d t bleu n^o
sau day la diing?
A . Co m o t chat tac dung dirge v d i N a

A. 26,24 t a n

B. 32,40 t a n

C. 16,2 t a n

D . 29,16 t a n .

T h e o chiTcfng t r i n h N a n g c a o (10 cdu, tit cdu 51 den cdu 60)

B a i 51: Cho dung dich chuTa h o n hop NH3 0,1M va NH4CI 0,1M. B i e t a
dieu k i e n t h i n g h i e m NH3 c6 Kb = l , 8 . 1 0 ' l C h i r a p H cua dung dich
A . 4,74

B . 9,26

C. 8,26

D . 5,74.

B a i 52: O x i hoa 4,4g m o t andehit don chufc dtroc 6 g a m a x i t tUdng iJng

( H = 100%). A n d e h i t t r e n l a :
A. H C H O

B. CH3CHO

C. C2H5CHO

D . C2H3CHO.

B a i 53: H o p chat dotn chufc X c6 phan t r a m k h o i liTdng cacbon, h i d r o Ian

luat bang 54,54% va 9,09%, con l a i la o x i . Dung dich X l a m do quy
B. C3H6O2

C. Ca ba chat deu tac dung dirge v d i dung dich Na2C03

D. Ca ba chat deu t a n t o t t r o n g ni/dc.
B a i 59: K h i t h u y p h a n m o t pentapeptit ta c h i t h u dirge cac d i p e p t i t sau:
G l y - A l a ; T y r - P h e ; A l a - V a l ; V a l - T y r . Chon cau t a o dung cho p e p t i t
tren?
A. T y r - P h e - G l y - A l a - V a l

B. A l a - V a l - T y r - P h e - G l y

C. G l y - A l a - V a l - T y r - P h e

D. V a l - T y r - P h e - G l y - A l a .

B a i 60: P h a n iJng hoa hoc nao dirdi day dung de chiing m i n h glucozo
t r o n g p h a n tijf co nhieu n h o m O H Hen ke?
A . Dung dich glucozo p h a n iJng v d i dung dich A g N 0 3 / N H 3 dun nong.

t i m . C h i r a cong thufc p h a n tuf X.

A. C2H4O2

B. Co h a i chat tac dung dirge v d i dung dich N a O H

C. C4H8O2

B. C4H6O2.

B a i 54: Goi E i ; E2; E3; E4 I a n lifot la suat dien dong chuan cua cac p i n

B. Dung dich glucozo phan ufng vdi dung dich Cu(OH)2/NaOH dun nong.

dien hoa: M g - C u ; M g - H z ; Z n - H z ; A l - H2. V a y t a c6:

C. Dung dich glucoza p h a n ufng v d i dung dich Cu(OH)2/NaOH 0 n h i e t

do thirdng

A. E3 > E4 > E2 > E l

B . E l > E2 > E3 > E4

D. Dung dich glucozd p h a n ufng v d i k a l i .

C. E l > E2 > E4 > E3

D . E l > E4 > E3 > E2.

B a i 55: Hoa t a n h o n h d p g o m CUSO4 v a AICI3 vao niTdc t h u difgrc dung

Cho biet khoi lugng

nguyen

tit (theo dvC) cua cac nguyen

to: H = 1

He = 4 ;C = 12; N = 14; O = 16; F = 19; Ne = 20; Na = 23; Mg = 24

dich X. Chia X l a m h a i p h a n bang nhau:

Al = 27; S = 32; CI = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55

Phan 1: Cho phan ufng v d i dung dich BaCl2 diT thu duac 6,99gam ket tua.

Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137.

Phan

2: Cho phan ufng v d i dung dich N a O H d\i t h u k e t tua, loc, nung

k e t t u a den k h o i lUdng k h o n g d o i t h u dirge m gam chat rin.
D E T H I THOT D A I H Q C V A C A O D A N G

Chi ra m.
A . 2,4

B. 3,2

C. 4,8

D . 5,4.

B a i 56: Cho m gam Z n p h a n ufng h e t v d i dung dich HNO3 t h u dirge 2,24

. .
M a de 113

M o n t h i : Hoa hoc
Thai gian Idni bai 90 phut

l i t NO2 (dkc) la san p h a n khuf duy n h a t . Hoa t a n h e t 2 m gam Z n bang

I. PHAN CHUNG CHO TAT CA C A C THi SINH (40 cSu, tif c^u 1 dfen c^u 40)

dung dich N a O H t h a y t h o a t r a V l i t k h i (dkc). C h i r a V .

B a i 1: H g p chat MX3 co t o n g so dien mang h a t la 128. T r o n g h g p chat,

A. 1,12

B. 2,24

C. 3,36

D . 4,48.

B a i 57: De diet chuot trong m o t nha kho, ngudi ta dot luu huynh r o i dong
k i n cOfa l a i . Chuot h i t phai k h o i se b i siTng yet hau, co giat, te l i e t co
quan ho hap dan den ngat ma chet. Chat g i da l a m chuot chet?
A. H2S

B. H2SO4

C. SO2

D . SO3.

so proton cua cac nguyen tuf X nhieu h o n so' proton cua M la 38. Cong
thufe cua hgp chat t r e n l a :
A. FeCl3

B. AICI3

C. FeF3

B a i 2: T r o n g p h a n tuf NH4CI eo:

A. 3 Hen k e t egng hoa t r i va m o t l i e n k e t i o n

D. AlBr3

B. 1 l i e n k e t c h o - n h a n va 2 l i e n k e t i o n

C t i c k h i t r o n g 3 chau X, Y, Z Ian luot la:

C. 4 l i e n k e t cong hoa t r i va 1 l i e n k e t c h o - n h a n

A. H C l , H2S, N2

B. N2, H C l , H2S

D . 4 l i e n k e t cong hoa t r i va 1 l i e n k e t ion.

C. N2, H2S, H C l

D . H C l , N2, H2S.

B a i 3: Xet p h a n tfng t h u a n nghich: 2SO2 + O2

2SO3. K h i p h a n ufng

dat can bang, neu ta g i a m the t i c h he xuong 3 Ian t h i can b k n g p h a n

ufng se

B a i 9: N h i i n g m o t la k i m loai M vao dung dich FeCls. Sau m o t thc/i

gian, lay t h a n h k i m loai ra can t h a y k h o i li/cfng k h o n g doi. Vay M c6
the la k i m loai nao t r o n g cac so k i m loai sau:
A. Z n

A. Dich chuyen theo chieu t h u a n

B. D i c h chuyen theo chieu nghich
I

C. K h o n g chuyen dich
D . Dich chuyen theo chieu t h u n h i e t
B a i 4: Loai phan dam nao dxidi day anh hirdng khong dang ke den do chua?
A. NH4NO3

B. (NH4)2S04

B a i 5: H o n hop X gom FeS, S va FeS2. Cho 6 gam gam X p h a n ufng v 6 i

B a i 6: Dung dich K M n 0 4 khong

D . 0,12.

C. CeHsCH = CH2 va C6H5CH3

D. CH3CH2CHO va CH2 = CHCH2OH

B a i 7: H a i k h i nao sau day khong

A. 24,44

B. SO2 va CO2

the cung t o n t a i t r o n g m o t b i n h
C. H2S va SO2

D. C H 3 N H ; , N a \.

B. 12

C. 10

D . 12,22.

B a i 13: D a n luong k h i CO2 vao dung dich N a O H diTOc dung dich X, chia
X l a m 2 p h a n b ^ n g nhau.

chufa?
A. O2 va CI2

NO"

I M va Ca(0H)2 0,05M t h u duoc m gam muoi. C h i ra m .

sau day?
B. C2H4 va C2H6

D . 9.

B a i 12: Hap t h u het 2,688 l i t CO2 (dkc) b ^ n g 200ml dung dich N a O H

AMC dung de p h a n biet h a i mau nao

A . SO2 va CO2

C. 3,96

B. Ca''\

C. N H ; , K\'i-

dung dich chufa x m o l BaCl2. C h i ra x

C.0,15

B. 4,5

A. N a \^ C I -

(san p h a m k h i i duy n h a t , a dkc). De k e t tua het ion SO^ t r o n g X can

B. 0,05

D. M g

B a i 11: Ion CO3' k h o n g t o n t a i t r o n g dung dich nao sau day?

HNO3 dac, nong, dii di/cJc dung dich X va t h a y thoat ra 16,8 l i t N O .

A. 0,1

C. Cu

Jai 10: Khuf 5,74gam h 6 n hop X gom Fe203, Fe304, CuO, N i O 6 n h i e t do

cao hkng CO dif, sau p h a n ufng t h u difoc 4,3 gam rSn va t h o a t ra h 5 n
hop k h i Y.DKn Y vao dung dich Ca(0H)2 dtf t h u difoc m gam k e t tua.
Gia t r i m la:
A. 5,14

C. (NH2)2CO (ure) D . NH4CI

B. Fe

Cho Ba(0H)2 diT vao p h a n 1 t h u di/Oc m gam ket tua

Cho B a ( H C 0 3 ) 2 dir vao p h a n 2 t h u difOc m ' gam k e t tua

B i e t m ' > m . Vay t r o n g dung dich X chiJa

D . CO2 va CO

B a i 8: Co 3 chat k h i : H2S, N2, H C l ditog t r o n g 3 ong n g h i e m , dilgfc up

ngiioc t r e n cac chau nirdc (xem h i n h ve)

A. H a i muoi N a H C 0 3 va Na2C03

B. C h i muoi N a H C 0 3

C. C h i muoi Na2C03

D . M u o i Na2C03 va N a O H .

B a i 14: Dot m o t ItfOng A l t r o n g 6,72 l i t O2. Chat r a n t h u diTOc sau p h a n

nufng hoa t a n hoan toan vao dung dich H C l t h a y bay ra 6,72

l i t H2.

Cac the t i c h do 0 dieu k i e n tieu chuan. Kho'i liiong A l da dCing.

A. 5,4gam
\r--.

ChauX

C. 8 , l g a m

D. 16,2gam

B a i 15: N h i e t p h a n 10 gam Fe(N03)3 m o t thcri gian diroc 6,76 gam r a n .

Z.-ZZ.

Chau Y

B. 10,8gam

Chau Z

Vay % Fe(N03)3 h i n h i e t p h a n la
A. 83,33%

B. 50%

C. 67,6%

D . 48,4%.

C a u 16: X l a hon hcfp r ^ n gom BaO, AI2O3, FezOg va C u O . Cho X vao

nude dir dMc dung dich M va rSn N . RSn N t a n m o t p h a n t r o n g dung
dich N a O H dir, con l a i rin T. D i n m o t luong CO du qua T(nung nong)
t h u dUdc r a n F. Ran F c6 dSc d i e m nao sau day?

B a i 22: So l i e n k e t 6 t r o n g a n k i n CnH2 _ 2 l a :
A. 3n

C . Tan het t r o n g dung dich FeCls dU

D. Tan het t r o n g dung dich N a O H dU.
B a i 17: Dung 8,1 gam A l de khuf 47,2gam hon hgp oxit k i m loai gom

A. 10,6

C. 20

B. 8,8

D . 10.

Vay X , Y, Z c6 dac d i e m
A. La ancol dong dang

A . 39,4gam

B. Co k h o i luong p h a n tiJf hon k e m nhau 14 dv.C

B a i 18: ThUc h i e n cac p h a n ufng di^n

C.24,7gam
phan

D.31,9gam.

v d i dien cUc trcf

C. Deu k h o n g tao phufc v d i Cu(0H)2

Dung dich AgNOa t h u dUcJc k h i X

Dung dich CuClg duoc k h i Y

Dung dich N a C l (c6 m a n g ngan) t h u dUgtc k h i Y va Z

va axetic monoxit. C H 3 O H + C O

Vay X , Y, Z Ian luat la

axit axetic v d i hieu xua't 80%, can luong metanol va C O Ian luot la

D . Co k h o i luong p h a n tuf hon k e m nhau 16 dv.C.

B a i 25: Phuong phap h i e n dai de dieu che axit axetic la d i tii metanol

A. N2; CI2; O2

B. O2; CI2; H2

C. H2; O2; CI2

D . NO2; CI2; H2.

C. 5,12kg va 4,48kg

D . 6,4kg va 7kg.

t r i n h la

^'h'cncn, , C6H5CH(CH3)2

> C g H s O H . De^ t h u duoc 4 7 k g

qua

78%)

A. 50kg

D . 20gam.

B. 64,1kg

C. 39kg

D . 30,42kg

B a i 27: Phenol kho t a n t r o n g nudc, n a t r i phenolat t a n r a t t o t t r o n g

nude. L y do l a :

B a i 20: Hoa t a n h o n hop X gom M g va A l bang 200ml dung dich H N O

(vCra du), sinh ra 3.36 l i t N O (la san p h a m khuf duy n h a t , d dkc). Nong

B. 8kg va 7kg ,

phenol ngudi ta can dung luong benzen la (biet hieu suat cua

du t h u dU(?c 2,24 l i t N O (dkc) la san p h a m khuf duy n h a t . C h i ra khoi

C. 16,9gam

A. 6,4kg va 5,6kg

CeHe

m o t t h d i gian dUgfc hon hop r a n X . Hoa t a n X t r o n g dung dich HNO3

B. 21,6gam

C H 3 C O O H . De t h u dugc 12kg

a i 26: T r o n g cong nghiep, ngudi ta san xuat phenol theo so do sau:

B a i 19: Cho hon hap gom 0,2 mol Fe va O,lmol Cu p h a n ufng v d i oxi

luong chat r a n X
A. 19,6gam

cua

nhau. K h i dot chay m o i ancol deu t h u duoc n^Q^ : n Q = 3 : 4

k h o n g t h a y k h i t h o a t r a va con l a i r a n Y. C h i ra k h o i lUcJng r a n Y
B. 40gam

D . 2n - 1.

B a i 24: X , Y, Z la cac ancol mach h d , k h o n g p h a i la dong p h a n

FezOs, CuO, FeO d n h i e t do cao. P h a n ufng hoan toan t h u duac hon

hop X . Cho X p h a n ufng v d i lUdng dU dung dich N a O H dun nong

C. 3n - 3

B a i 23: Dot chay hoan toan h6n hop cac hidrocacbon C2H2, C4H4 va
CeHg. D a n toan bo san pha'm chay vao b i n h dUng Ca(0H)2 du t h a y
kho'i luong b i n h t a n g m gam dong t h d i xuat h i e n 20gam k e t t i i a . C h i
, ra m

A. Tan h e t t r o n g dung dich H2SO4 loang du

B. Tan het t r o n g dung dich CUSO4 du

B. 3n - 2

A. N a t r i phenolat k h o n g cd h e n k e t h i d r o v d i H2O

B. Phenol c6 k h o i luong p h a n tuf nho hon n a t r i phenolat

C. Phenol la hop chat cong hoa t r i , n a t r i phenolat la hop chat ion

p H t a n g dan: H C O O H ( l ) , HC1(2), C H 3 C O O H ( 3 ) , H2S04{4)

D . Phenol la axit yeu, n a t r i phenolat la m u o i .

A. (3) < (1) < (2) < (4)

B. (4) < (3) < (1) < (2)

B a i 28: T r o n g cung dieu k i e n n h i e t do, ap suat, k h o i luong 1 l i t h o i este

C. (2) < (4) < (3) < (1)

D . (4) < (2) < (1) < (3).

do cua dung dich H N O 3 da dung l a :

A. 3 M

B. 2,5M

C. 0,75M

D . 3,2M.

B a i 21: Sap xep cac dung dich sau day (cung nong do mol/1) theo t r a t tii

E gap hai Ian k h o i luong 1 Ht CO2. Vay E c6 cong thufc p h a n tuf?

A. C3H4O2

B. C4Ha02

C. C4Hfi02

D . C2H4O,.

B a i 29: Xa phong hoa este X diicfc hon hcjp h a i muoi CHgCOONa, HCOONa
va ancol Y c6 cong thuTc C 2 H 6 O 2 . Cong thufc phan tCf cua X la:
A. C5H10O4

Bai

30:

Dot

B. C 6 H 1 0 O 4

chay

hoan

toan

C. C 4 H 6 O 4

O,lmol

hon

D. C 5 H 8 O 4 .

hop

gom

metylamin,

d i m a t y l a m i n , t r i m e t r y l a m i n va e t y l a m i n bang oxi vCra du t h i the tich

N 2 t h u duoc (d dkc) l a :
A. 4,48 l i t

B. 2,241it

C. l,121it

D. 3,361it.

B a i 3 1 : TCr 0,2 mol g l y x i n va 0,1 m o l a l a n i n c6 the tao t h a n h k h o i luong

dipetit cue d a i la
A. 19,9 gam

B. 25,3 gam

C. 21,2 gam

D. 18,5 gam.

B a i 32: TCr g l y x i n , a l a n i n va v a l i n c6 the tao t h a n h t o i da bao nhieu

tripeptit?
A. 9

B. 27

1) GlucozO

2) Fructozo

5) T i n h hot

6) Xenlulozo

C. 3

D. 18.

B. C H 3 C O O H v a C 2 H 5 O H

C. C H 3 C O O H v a C 3 H 7 O H

D. C 2 H 5 C O O H v a C 4 H 9 O H .

B a i 38: O,lmol este X p h a n iJng v d i N a O H vCfa du t h u di/gc O,lmol

HCOONa, 0,2mol CHgCOONa va 9,2gam ancol Y. Cong thiJc p h a n t t l
X la:
A. C6H10O4

B. CgHizOe

C. C8H14O4

D . CrHiaOg.

B a i 39: Thuc h i e n p h a n uTng n h i e t n h o m den hoan t o a n m gam h 5 n hop

X gom A l va Fe204. Chia h o n hop sau p h a n ufng t h a n h h a i p h a n
k h o n g bang nhau
Phan

1: Cho p h a n iJng v d i dung dich N a O H dif, s i n h r a 0,336 l i t k h i

3) SaccarozO

B. 5

C. 4

4) MantozO.

D. 4.

B a i 34: M o t loai cao su l\iu hoa chufa 3,5% lifu h u y n h . B i e t r a n g k h i luu

hoa, S da t h a y the cho H of n h o m m e t i l e n t r o n g mach cao su. So mSt
x i c h cao su t r u n g b i n h c6 m o t cau n o i - S - S - l a :
B. 26

C. 13,5

Phan 2: Cho vao H N O 3 loang, d i i diioc 3,696 l i t N O (dkc)

Chi ra k h o i lifOng r l n X

So cacbohidrat cho diioc p h a n urng t h u y p h a n l a :

A. 22

A. H C O O H va C 2 H 5 O H

(dkc) va con l a i 2,52 gam r ^ n

B a i 33: T r o n g so cac cacbohidrat sau:

A. 2

luong cung so m o l hon hop X v a Y , s i n h ra 11,2 l i t C O 2 (dkc) v a

10,8gam H 2 O . H a i chat X, Y I a n lifot l a :

D. 13.

B a i 35: Cho 5,3 gam h o n hop h a i a x i t cacboxyUc (don chiJc, dong dang
l i e n tiep) tac dung v d i 20gam dung dich N a O H 40%. Co can dung d i c l i

A. 17,64gam

B. 9,66gam

C. 21,2gam

D. 14,49gam.

B a i 40: Cho cac chat: n a t r i axetat, amoni clorua, phenylamoni clorua,

a n i l i n , phenol, ancol etylic, a l a n i n , a x i t glutamic. So' chat t r o n g day
l a m doi mau quy t i m a m la
A. 7

B. 6

C. 4

D . 3.

li. PHAN R i e N G (10 cau;

Thi sinh hoc theo chuong trinh nao thi chi duac Idm phdn danh
cho chiiong trinh do (phdn A hodc B)

ring

T h e o chifofng t r i n h C h u a n (10 cau, tii cdu 41 den cau 50)

a i 41: Cho cac p h a t bieu sau:

sau p h a n ufng dtfoc l l , 5 g a m rSn k h a n . H a i a x i t da dung la

1) Phan ufng thuan nghich la phan ufng xay ra theo 2 c'ueu ngufOc nhau

A. C H 3 C O O H va C 2 H 5 C O O H

B. H C O O H va C H 3 C O O H

2) Phan ufng bat thuan nghich la phan ufng xay ra theo 1 chieu xac d i n h

C. C 2 H 3 C O O H va C 3 H 5 C O O H

D. C 2 H 5 C O O H va

C3H7COOH.

B a i 36: Cho cac chat sau: phenol, ancol etylic, a x i t axetic, axetandehit,
m e t y l a m i n , g l y x i n , a n i l i n , amoni axetat. So chat tac dung diTOc ca vdi
dung dich N a O H va dung dich H C l la
A. 2

B. 3

C. 5

D. 6.

B a i 37: X la ancol d o n chufc, Y la a x i t cacboxylic don chiJc, deu no, mach

ho. X h o n Y m o t nguyen tuf cacbon t r o n g p h a n tijf. Dot chay h e t m o t

3) Can b k n g hoa hoc la t r a n g t h a i ma p h a n ufng da xay r a hoan t o a n

4) K h i p h a n iJng t h u a n nghich dat t r a n g t h a i can b^ng hoa
liTOng cac chat se k h o n g doi

hoc,

5) K h i p h a n iJng t h u a n nghich dat t r a n g t h a i can bSng hoa hoc, p h a n

iJng se dCrng l a i
Cac phat bieu s a i :
A. 2,3,5

B. 3,4,5

C. 3,5

D . 1,4,5

B a i 4 2 : A n d e h i t da chuTc X chay hoan toan cho ngo, - n^^o = n ^ . X l a :

A. andehit no, mach h d

B. andehit no, mach vong

C. andehit chiia no

D . andehit t h o m .

B a i 43: D o t chay hoan toan O . l m o l a x i t cacboxyUc X t h u daoc chiXa den

8g h o n hop H2O va CO2.X l a :
A. axit fomic

B. a x i t axetic

C. a x i t acrylic

D . a x i t oxalic.

B a i 44: Ion nao dadi day c6 the oxi hoa dugfc ion Fe^^ t r o n g dung dich
A. Cu'^

B. Ag^

C. C I -

D. Fe'^

B a i 45: De dieu che duoc 30,4gam Cr203 can n h i e t p h a n t o i t h i e u bao

nhieu gam (NH4)2Cr207?
A. 68,6

B. 75,6

C. 50,4

D . 151,2.

B a i 46: Can lay bao nhieu gam t i n h the CUSO4.5H2O vao bao n h i e u gam
dung dich CuS048% de tao r a 560gam dung dich C U S O 4
A. 480 va 80

B. 120 v a 440

C. 80 va 480

16%?

D . 60 va 500.

B a i 47: Co the p h a n biet 4 lo m a t n h a n : Na2S04; NaNOg; H 2 S O 4 loang

va H N O 3 loang chi v d i thuoc thuf l a :

A. M g O

B. FeO

C. ZnO

D . CuO.

B a i 48: H o p chat nao di/di day c6 so dong p h a n cau tao nhieu nhat?
A. CgHsO

B. C 4 H 9 C I

C. C 4 H 1 0 O

D. C3H7CI.

B a i 52: D o t chay hoan toan a x i t cacboxylic X bang m o t liTcfng vCra du oxi

dugc h o n hop ( k h i va hoi) c6 t y so k h o i so vdri H2 la 15,5.X la a x i t
A. axit ddn chuTc, no mach h d

B. axit don chufc, chua no, mach h d

C. axit da chuTc, no, mach h d

D . axit thOm

B a i 53: Co bao n h i e u xeton cong thurc p h a n tuf C 6 H 1 2 O ?

A. 7

B. 4

C. 5

B a i 54: TCr cac cap oxi hoa khuf: A l ^ V A l ; Zn^VZn; Cu^VCu; AgVAg. Co the
lap dugfc t o i da bao n h i e u p i n dien hoa.
A. 5

B. 6

C. 4

loang vCfa du dirge dung dich X. Cho dung dich N a O H di/ vao dung
dich X dugc k e t tua Z c6 mau vang, chuyen sang xanh k h i de t r o n g
k h o n g k h i . Vay chat r a n A co cong thuTc phu hgp la
A. CuO

B. FeO

C. Cr203

A. 2,06gam

B. l , 7 2 g a m

C. l,03gam

B. G i a m dan, c6 liic g i a m dot nggt

A. 3

C. G i a m deu

B a i 50: Dun 100ml dung dich glucozO vdi mot luong dtf AgNOs/NHs thu
dagc li/dng A g dung bang lirgng A g sinh ra k h i cho 6,4gam Cu tac dung
het vdi dung dich AgN03. Nong do mol/1 cua dung dich glucozo l a :
A. I M

B. 2 M

C. 5 M

D. lOM.

T h e o chxidng t r i n h N a n g cao (10 cdu, til cdu 51 den cdu

60)

B a i 51: T r o n g b i n h k i n 2 Ht chiJa 2mol N2 va 8mol H2. Thifc h i e n phan

iJng t o n g hop N H 3 den k h i dat t r a n g t h a i can bang t h a y ap suat sau
bang 0,8 ap suat liic b a n dau (BiS't n h i e t do trUdc va sau nhiT nhau)
Hang so can bang cua he la
A. 0,128

B. 0,75

C. 0,25

D . 1,25.

D . 0,86gam.

B a i 57: K h i chuan do dung dich axit m a n h bang bazo m a n h , p H cua

dung dich t r o n g qua t r i n h chuan do

daoc v d i a x i t va bazo cua hop chat c6 cong thiJc p h a n tijf C 3 H 7 O 2 N la

D . 5.

D . CrO.

B a i 56: T h e m 0,02mol N a O H vao dung dich chuTa 0,01mol CrClg r o i de

t r o n g k h o n g k h i den p h a n iJng hoan toan t h u diigc ke't tua sau cung
CO k h o i lirgng:

A. T a n g dan, c6 luc t a n g dot ngot

C. 4

D . 7.

B a i 55: A l a chat r a n c6 mau den. Hoa t a n A bang m o t liTc/ng H 2 S O 4

B a i 49: So luong dong phan mach ho, c6 mach cacbon l i e n tuc, tac dung
B. 6

D . 6.

D . T a n g deu.
B a i 58: Dun l , 6 6 g h o n hgp h a i ancol v d i H 2 S O 4 d a m dac t h u dirge h a i
anken dong dang ke tiep nhau (hieu suat 100%). Neu dot h o n hgp
anken do can dung 2,688 h t O2 (dktc). T i m cong thiic cau tao cua h a i
ancol, biet ete tao t h a n h tCr h a i ancol la c6 n h a n h
A. C 2 H 5 O H , C H 3 C H 2 C H 2 O H

B. C 2 H 5 O H , ( C H 3 ) 2 C H O H

C. (CH3)2CHOH, Ch3(CH2)30H

D . (CH3)2CHOH, (CH3)3COH.

B a i 59: T h u y p h a n hoan toan I m o l pentapeptit X dirge 3 m o l g l y x i n , 1

mol alanin va 1 m o l v a l i n . Neu t h u y p h a n k h o n g hoan toan X t h i
t r o n g h o n hgp san pha'm t h a y co cac d i p e p t i t A l a - G l y ; G l y - A l a va

t r i p e p t i t G l y - G l y - V a l . V a y amino a x i t dau N va dau C cua pentapeptit

B a i 4: Biet Cu c6 so hieu nguyen tCf la 29. Cau h i n h electron cua ion Cu"^ la

X Ian \Mt l a :
A . a l a n i n va v a l i n

B. g l y x i n va v a l i n

C. g l y x i n va alanin

D . v a l i n va alanin

A. [Ar]3d'4s^

A l + HNO3

k e t tua do gach v d i Cu(0H)2 t r o n g m o i triTdng k i e m dun nong. Tuy

L y do l a :
A. t r o n g p h a n ttif fructozO k h o n g c6 n o i doi C = C

A. 66

B. fructozO chi chuyen hoa t h a n h glucozO t r o n g moi trUcfng k i e m

He = 4 ;C
Al = 27;

= 12;'N
S = 32;

cua cdc nguyen

K = 39;

C. 64

D . 62.

t h a n h p h a n p h a n t r S m ve the t i c h cua h o n hop k h i sau p h a n iJng.

to: H = 1;

= 14; O = 16; F = 19; Ne = 20; Na = 23; Mg = 24;

CI = 35,5;

B. 60

sau phan iJng t h a y the t i c h k h i d i ra g i a m 1/10 so v d i ban dau. T i n h

D . phan tiJf glucozo dang mach h d c6 n h o m - C H O

ti2 (theo dvC)

A1(N03)3 + N O + N2O + H2O

B a i 6: Di/a m o t h6n hop k h i N2 va H2 c6 t y le 1 : 3 vao t h a p t o n g hop,

C. phan tijf fructozO dang mach h d k h o n g c6 n h o m - C H O

luong nguyen

D.[Ar]3d^.

(Biet t i le the t i c h N2O: N O = 1 : 3). Sau k h i can bang phi/ong t r i n h

hoa hoc t r e n v d i he so cac chat la nhCfng so nguyen, t o i g i a n t h i he
so cua H N O 3 l a .

n h i e n , chi c6 glucozcf l a m m a t mau nUdc b r o m , con fructozO t h i khong,

bi^'t kiwi

C.[Ar]3d^

B a i 5: Cho phirong t r i n h hoa hoc:

B a i 60: GlucozO va fructozo deu cho dtroc p h a n ufng t r a n g guong, deu t a o

Cho

B. [Ar]3d^4s^

Ca = 40; Cr = 52; Mn =

55;

A. 20%, 60%, 20%

B. 22,22%, 66,67%, 11,11%

C. 30%, 60%, 10%

D . 33,33%, 50%, 16,67%.

a i 7: Day gom cac chat nao sau day deu c6 t i n h liTdng tinh?

Fe = 56; Cu = 64; Br = 80; Ag = 108;Ba = 137

A. A l , NaHCOg, NaAlOa, ZnO, Be(0H)2

B. H2O, Zn(0H)2, C H 3 C O O N H 4 , H 2 N C H 2 C O O H , NaHCOg

DE THI THUT DAI HQC VA CAO DANG

C. AICI3, H2O, N a H C 0 3 , Zn(0H)2, ZnO

M o n t h i : Hoa hoc
^ . ^ ^ ^^^^
^j^^^

M a de 114

D . ZnCl2, AICI3, NaA102, N a H C 0 3 , H 2 N C H 2 C O O H .

a i 8: Co 4 dung dich t r o n g suot, m 6 i dung dich chi chiJa m o t cation va

I. P H A N C H U N G C H O T A T C A THJ S I N H (40 c^u, tCr c&u 1 d^n c^u 40):

m o t loai anion. Cac loai ion t r o n g ca 4 dung dich gom: Ca^"^, Mg^"^,

B a i 1: Cho m o t luong k h i CO d i qua ong sut diTng m gam FegOa nung

P b ' ^ N a \, cr,

nong. Sau m o t t h d i gian t h u dugc 10,44 gam chat rSn X gom Fe, FeO,

A. B a C l 2 , MgS04, NaaCOs, Pb(N03)2

FezOa va Fe304. Hoa t a n h e t X t r o n g dung dich H N O 3 dfic, nong t h u

B. BaC03, MgS04, N a C l , Pb(N03)2

di/gc 4,368 l i t N O 2 (san p h a m khut duy n h a t a dieu k i e n chuan). Gia

C. B a C l 2 , PbS04, MgCl2, Na2C03

t r i cua m l a .
A. 12

B. 24

C. 10,8

D . Mg(N03)2, B a C l 2 , NagCOs, PbS04.

D . 16.

B a i 2: D o t chay hoan toan m o t hon hop A (glucozo, andehit fomic, a x i '

axetic) can 2,24

B a i 9: K h i n h i e t p h a n hoan toan 100 gam m 5 i chat sau: K C I O 3 (xiic tac

h t O2 (dieu k i e n chuan). D i n san p h a m chay qu;

MnOa), K M n 0 4 , K N O 3 va AgN03. Chat tao ra lirgng O2 i t n h a t la

b i n h difng dung dich Ca(0H)2, t h a y k h o i li/gng b i n h t a n g m gam. Gi^'

t r i cua m la
A. 6,2

B. 4,4

C. 3,1

D . 12,4.

A. K C I O 3

B. N

C. F

D . Ne.

B. K M n 0 4

C. K N O 3

D . AgN03

B a i 10: P h a t bieu nao sau day la diing:

A. Photpho trSng cd cau true m a n g t i n h the nguyen tuf, photpho do c6
cau true polime

B a i 3: Tong.sd' h a t cua m o t nguyen tijf X la 28. X la

A. O

C O 3 ' - , NO3-. Do la 4 dung dich gi?

B. N i t r o p h o t k a la h 6 n hop cua NH4H2PO4 va K N O 3

"

Bai

Dot c h a y h o a n t o a n 4,872 gam mot h i d r o c a c b o n X, d a n san

qua b i n h d U n g dung d i c h niXdc v o i t r o n g . Sau p h a n i J n g t h u
d u g c 27,93 gam k e t t u a va t h a y k h o i lUcJng dung d i c h g i a m 5,586
gam. Cong thuTc p h a n tijf cua X l a

C. T h u y t i n h l o n g l a d u n g dich d a m d a c c u a NagSiOs v a K 2 S i 0 3
D. Cacbon monooxit

silic d i o x i t la o x i t a x i t

B a i 11: Cho cdc k i m l o a i : C r , W , Fe, Cu, Cs. S^p xep theo chieu t a n g
dan do cuTng tCr t r a i sang p h a i la

A. C H 4

A. Cu < Cs < Fe < W < Cr

B. Cs < Cu < Fe < W < C r

C. Cu < Cs < Fe < C r < W

D . Cs < Cu < Fe < Cr < W.

D. C 4 H 8 .

loai va anot t h u 0,336 l i t k h i id dieu k i e n chuan). Coi the t i c h dung

dich k h o n g doi t h i p H cua dung dich t h u duoc bSng
A. 12

cua m 1^
C. 13.80

C. C4H10

H 2 O b i dien p h a n d h a i eiTc t h i dCrng l a i , t a i catot t h u 1,28 gam k i m

I M va Cu(N03)2 I M . K e t thuc p h a n l i n g t h u dirge m gam r ^ n . Gia t r i

B. 13.20

B. C 3 H 6

B a i 19: D i e n p h a n 2 l i t dung dich hon hap gom N a C l va C U S O 4 den k h i

B a i 12: Hoa t a n 5,4 gam h o t A l vao 150 m l dung dich A chufa Fe(N03)3

A. 10.95

18:

pham chay

Bai

D. 15.20.

B. 13

C. 2

D. 3.

20: Cho tCr tCr 150 m l dd H C l I M vao 500 m l dung dich A

B a i 13: A la hon hgp k h i gom S O 2 va C O 2 c6 t y k h o i h m so v d i H 2 la 27.

dung dich B. Cho dung d i c h B tac dung v d i dung dich B a ( 0 H ) 2 d u t h i

D a n a m o l h o n hgp k h i A qua b i n h diTng 1 l i t dung dich N a O H 1,5a

thu dirge 29,55 gam k e t tua. N o n g dp m o l cua Na2C03 va

M , sau p h a n uTng c6 can dung dich t h u dugc m gam m u o i . Bieu thufc

t r o n g dung dich A I a n lirgt l a :

\ 0,18M va 0,26M

l i e n he giOfa m va a la
A. m = 105a

B. m = 103,5a

C. m = 116a

0,8M va H2SO4 0 , 2 M , san p h a m khuf duy n h a t la k h i N O . So

B. 2,24 va 11,2

C. 6,72 v a 4,48

A. 7,90

D . 5,6 va 1,2.

300 m l dung dich N a O H I M vao A , t h u dUde a gam k e t t u a . M a t khac,

D. 10,08.

B. MnOz + 4HC1 - M n C l 2 + C I 2 + 2 H 2 O

tua. Gia t r i cua m l a

C. 17,1

C. 5,64

A. Fe + K N O 3 + 4 H C 1 ^ FeCl3 + K C l + N O + 2 H 2 O

neu cho 400 m l dung dich N a O H I M vao A , cung t h u dagc a gam k e t

B. 42,75

B. 8,84

Sai 22: H a y cho b i e t , p h a n uTng n^o sau day H C l dong v a i t r 6 la chat

oxi hoa?

15: Hoa t a n h e t m gam Al2(S04)3 vao n U d c difcJc dung dich A . Cho

A. 21,375

gam

muoi k h a n t h u dirge la

gia t r i cua V l a
Bai

D. 0,2M va 0,4M.

B a i 21: Cho 3,2 gam Cu tac dung v d i 100ml dung dich h o n hap H N O 3

B a ( 0 H ) 2 I M va N a O H I M . Sau p h a n ufng t h u duac 19,7 gam k e t tua,

A. 2,24 va 4,48

NaHCOs

B. 0,21M va 0,18M

^ C. 0,21M va 0,32M

D. m = 141a.

14: Sue V Ht C O 2 (dieu k i e n chuan) vao 200 m l dung dich X gom

Bai

gom

Na2C03 va NaHCOg t h i t h u dircJe 1,008 l i t k h i (dieu k i e n chuan) va

C. Fe + 2 H C l - > F e C l 2 + H 2

D . 22,8.

D. N a O H + H C l

C a u 16: A l a h 6 n hap cac muoi Cu(N03)2, Fe(N03)2, Fe(N03)3, Mg(N03)2-

N a C l + HgO.

dung dich chufa 50 gam muoi A. Loe k e t tiia t h u di/gc dem nung t r o n g

J C a u 23: Cho h o n hgp k i m loai M g , Z n , Fe vao dung dich chiJa AgNOs va

Cu(N03)2.. Sau k h i p h a n uTng xay r a hoan toan t h u dirge dung dich X

chan k h o n g den k h o i lucfng k h o n g doi t h u dMc m gam oxit. Gia t r i

gom 3 m u o i va chat r S n Y gom ba k i m loai. Ba m u o i t r o n g X 1^

cua m la

A . Mg(N03)2, Fe(N03)3, AgNOg

B. Mg(N03)2, Zn(N03)2, Cu(N03)2

C. Mg(N03)2, Zn(N03)2, Fe(N03)3

D . Mg(N03)2, Zn(N03)2, Fe(N03)2.

T r o n g do O c h i e m 9,6% ve k h o i luofng. Cho dung dich K O H dif vao

A. 47,3
Bai

B. 44,6

C. 17,6

D. 39,2.

17: Cho a m o l hot k e m vao dung dich c6 ho^ t a n b mol Fe(N03)3-

Tim

dieu k i e n l i e n he giiifa a va b de sau k h i k e t thiic p h a n iJng

k h o n g CO k i m l o a i .
A. a > 2b

B . b > 3a

C. b > 2a

D . b = 2a/3.

Wki
*

24: Cho 6,4 gam dung dich rirgu A c6 nong do 71,875% tac dung v d i
lirgng dir N a t h u dirge 2,8 l i t H 2 dieu k i $ n chuan. So nguyen tiJf H c6
t r o n g eong thufc p h a n tuf ri/gu A la
A. 4

B. 6

C. 8

D . 10.

B a i 2 5 : Cho cac cong thiJc p h a n tuT sau: C3H7CI, CgHgO v a C3H9N. H a y

cho biet suf sSp xep n^o sau day theo chieu t a n g dan so lirang dong
p h a n ling v d i cac cong thdc p h a n tijf do?

B i i i 3 2 : C h o cac chat: amoniac (1); anilin (2); p-nitroanilin(3); p - m e t y l a n i l i n

(4) ; metylamin (5) ; dimetylamin (6) . H a y chon sU sAp xep cac chat tr&n
theo thuf hi lire bazo tSng dan .

A. C3H7CI < CaHsO < C3H9N

B. CsHgO < C3H9N < C3H7CI

A. (3) < (2) < (4) < (1) < (5) < (6)

B. (2) > (3) > (4) > (1) > (5) > (6)

C. CaHsO < C3H7CI < C3H9N

D. C3H7CI < C3H9N < CgHsO.

C. (2) < (3) < (4) < (1) < (5) < (6)

D. (3) < (1) < (4) <(2) < (5) < (6).

CgHsOH,

B a i 33: T h u y p h a n 34,2 gam mantozcf v d i hieu suat 50%. Sau do t i e n

H2NCH2COOH tac dung vCfa du v d i 40 m l dung dich N a O H I M . Tong

h a n h p h a n drig t r a n g bac v d i dung dich t h u dtfdc. K h o i lifong A g k e t

k h o i liiOng muoi k h a n t h u diiOc sau k h i p h a n ufng la

tua la

B a i 26: Cho 2,46

A. 3,52 gam

gam h 6 n hop gom

B. 6,45 gam

H C O O H , CH3COOH,

C. 8,42 gam

D . 3,34 gam.

B a i 27: Day cac chat deu l a m m a t mau dung dich thuoc t i m la

A. 43,2 gam

B. 32,4 gam

C. 21,6 gam

D. 10,8 gam.

B a i 34: Cd 45,75 gam cao su b u n a - S p h a n dng v d a het v d i 20 gam b r o m

A. E t i l e n , axetilen, andehit fomic, toluen

t r o n g CCI4. T i le m^t xich butadien va s t i r e n t r o n g cao su b u n a - S Ik

B. Axeton, e t i l e n , andehit axetic, cumen

A. 1 : 3

B a i 28: D o t chay 1,6 gam m o t este E d a n chdc diroc 3,52 gam CO2 va
1,152 gam H2O. N e u cho 10 gam E tac dung v d i 150ml dung dich
N a O H I M , CO can dung dich sau p h a n dng t h u daoc 16 gam chat rAn
k h a n . V a y cong thiJc cua a x i t tao n e n este t r e n c6 the la
A. CH2 = C H - C O O H

B. CH2 = C ( C H 3 ) - C 0 0 H

C. HOOC(CH2)3CH20H

D. H O O C - C H 2 - C H ( O H ) - C H 3 .

B a i 29: Chat beo A c6 chi so a x i t l a 7. De xa phong ho^ 10 k g A , ngi/di

t a dun nong no v d i dung dich chda 1,420 k g N a O H . Sau k h i p h a n ufng
xay ra ho^n t o a n de t r u n g hoa h 6 n hop, can dung 500ml dung dich
H C l I M . K h o i liiofng xa phong (kg) t h u duac la
C. 10,3445

D. 3 : 5.

glucozo, andehit axetic, m e t y l axetat, mantozo, n a t r i fomat, axeton. So

D. Xiclobutan, b u t - l - i n , m - x i l e n , a x i t axetic.

B. 10,3435

C. 2 : 3

B a i 35: Cho cac chat sau: axetilen, a x i t fomic, fomandehit, p h e n y l fomat,

C. Benzen, b u t - l - e n , a x i t fomic, p - x i l e n

A. 10,3425

B. 1 : 2

D. 10,3455.

B a i 30: Day chi chda nhij-ng amino a x i t c6 so n h o m amino va so nhom

cacboxyl bSng nhau la
A. Gly, A l a , Glu, T y r

B. Gly, V a l , T y r , A l a

C. Gly, V a l , L y s , A l a

D. Gly, A l a , Glu, Lys.

B a i 31: Cho 29,8 gam h o n hop 2 a m i n don chufc ke' t i e p tac dung h e t vdi
dung dich H C l , l a m kho dung dich t h u difOc 51,7 gam m u o i khanCong thufc phan t i i 2 a m i n l a
A. CH5N v^ C2H7N

B. C2H7N va C3H9N

C. C3H9N va C4HHN

D. C3H7N va C4H9N.

chat CO the t h a m gia p h a n d n g t r a n g gUcJng la

A. 8

B. 7

C. 5

D. 6.

B a i 36: De n h a n biet ba lo m a t n h a n : phenol, s t i r e n , ancol

'
benzylic,

ngadi t a dung m o t thuoc thilr duy n h a t 1^

A. Nirdc brom

B. Dung dich N a O H

C. N a

D. Ca(0H)2.

a i 37: H o n hgp k h i X gom H2 va C2H4 c6 t i k h o i so v d i He l a 3,75.

D a n X qua N i nung ndng, t h u dtroc h o n hdp k h i Y c6 t i k h o i so v d i He
la 5. H i e u suat cua p h a n d n g h i d r o hoa \k

A. 4 0 %
B. 50%
C. 2 5 %
D. 20%.
a i 38: Day gom cac chat c6 the dieu che triTc t i e p (bkng m o t p h a n dng)
tao r a a x i t axetic l a :
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. C2H4(OH)2, CH3OH, CH3CHO.
C. CH3CHO, CeHiaOg (glucoza), CH3OH.
D. CH3OH, C2H5OH, CH3CHO.
J a i 39: Cho day cac chat: CH4, C2H2, C2H4, C2H5OH, CH2 = C H - C O O H ,
C6H5NH2(anilin), CeHgOH (phenol), C6H6(benzen), CH3CHO. So
^ tA.
ron
5 g day p h a n dng
B. 6 dUdc v d i ni/dc bC.
rom
7 la
D . 8.

chat

B a i 40: Ruau X,
t r o n g p h a n tijf,
hoan toan h o n
m o l COziHzO =

andehit Y , a x i t cacboxyUc Z c6 cung so n g u y e n tijf H

t h u p c cac day dong dang no don chufc mach hof. Dot
hop ba chat nay (c6 so m o l bang nhau) t h u diXOc t i le
11:12. V a y cong thufc p h a n tijf c u a X, Y , Z l a :

A. C H 4 O , C 2 H 4 O , C 2 H 4 O 2

B. C 2 H 6 O , CgHeO, C 3 H 6 O 2

C. CsHgO, C4H8O, C4H8O2

D. C4H10O, C5H10O, C5H10O2.

II.

PHAN

R I S N G [10

cau]: Thl sinh chi du<?c l^m mpt trong hai phSn

(ph3n A ho#c B )
T h e o chtfcfng t r i n h C h u a n (10 c a u , til c a u 41 d e n c a u 50)
B a i 41: Cho cac dung dich s a u : NazCOg, N a O H va CHsCOONa c6 cung
nong do mol/1 va c6 cac gia t r i p H ti/ong i l n g la p H i , pH2 va pHa. Su
s^p xep nao diing v d i t r i n h tir t a n g dan p H .

B a i 4 7 : Cho 0,1 mol chat X ( C H 6 O 3 N 2 ) tac d u n g vdi d u n g dich chuTa 0,2 mol
N a O H d u n nong t h u duoc chat k h i l a m x a n h giay qui t i m a m va dung
dich Y. Co can dung dich Y t h u daoc m gam r S n k h a n . Gia t r i cua m
la
A. 8,5

B. 12,5

C. 15

D. 21,8.

B a i 48: Hoa t a n 19,2 gam Cu vao 500 m l dung dich NaNOs I M , sau d6
t h e m vao 500ml dung dich H C l 2 M . K e t thiic p h a n iJng t h u diTOc dung
dich X va k h i N O duy n h a t , p h a i t h e m bao nhieu m l dung dich N a O H
I M vao X de k e t t u a h e t ion Cu^*
A. 600

B. 800

C. 400

D. 120.

B a i 49: T h u y p h a n hoan toan m o t lifOng mantozO, sau do cho t o a n bo

iLfOng glucozo t h u di/oc l e n men t h a n h ancol etylic t h i t h u di/Oc

100

m l ancol 46. K h o i luong r i e n g cua ancol la 0,8gam/ml. H a p t h u t o a n

A. pHs < p H i < pH2

B. pH3< pH2 < p H i

bo k h i CO2 vao dung dich N a O H dtf t h u difOc muoi c6 k h o i luong la

C. p H i < pH3 < pH2

D. p H i < pH2 < pHa.

A. 106 gam

B. 84,8 gam

C. 212 gam

D.169,6 gam.

B a i 42: Cho 13,8 gam a x i t A tac dung v d i 16,8 gam K O H , c6 c a n dung

B a i 50: H i d r a t hoa 3,36 l i t C2H2 (dieu k i e n chuan) t h u dugfc h o n hop A

dich s a u p h a n ufng t h u daoc 26,46 gam chat r S n . Cong thiJc c a u tao

(hieu suat p h a n ufng 60%). Cho h 5 n hop san p h a m A tdc dung v d i

thu gon cua A la

dung dich Ag20/NH3 d i i t h u dtfOc m gam chat r S n . Gia t r i cua m l a

A. CsHeCOOH

B. C 2 H 5 C O O H

C. C H 3 C O O H

D. H C O O H

C. 14,4

D. 48,24.

B a i 51: X e t p h a n ufng t h u a n nghich sau:

A. T i n h oxi hoa cua A g " > Cu^" > Fe^" > Ni^^ > Fe^*

S02(k) + N02(k)

B. T i n h k h i l c u a K > M g > Z n > N i > Fe > H g

K h i dat can b^ng hoa hoc t h i con l a i 0,02(mol) NO2. V a y hSng so can

D. T i n h oxi hoa cua Ag* > I2 > Fe^* > Cu^* > S^".

bang Kc la

44: Can t o i t h i e u bao n h i e u gam N a O H (mi) va CI2 (m2) de phan

iJng hoan toan v d i 0,01 m o l CrCla. Gia t r i cua m i va ma I a n luot la

A. 3,2 v^ 1,065

B. 3,2 va 0,5325

C. 6,4 vk 0,5325

D. 6,4 va 1,065.

S03(k) + NO(k).

Cho O . l K m o l ) SO2, O,l(mol) NO2, 0,07(mol) S O 3 vao b i n h k i n 1 l i t .

C. T i n h khijf cua K > Fe > Cu > T > Fe^* > A g

B a i 45: Chi dung mot thuoc thijf phan biet cac k i m loai s a u : M g , Zn, Fe, Ba?
A. Dung dich N a O H

B. Dung dich H 2 S O 4 loang

C. Dung dich H C l

D. Ni/dc.

A. 18

B. 20

C. 23

D . 0,05.

B a i 52: Cho N a d i l tac dung v d i a gam dung dich C H 3 C O O H . K e t thuc

11a
p h a n ling, t h a y k h o i liiOng H2 s i n h r a la
. V a y nong dp C% dung
240
dich a x i t la
A. 10%

B. 25%

C. 4.58%

D . 36%.

B a i 53: Cho 0,1 mol hon hop X gom hai andehit no, don chufc, mach hof, ke

B a i 46: Dot chay hoan t o ^ n 1 m o l ancol no A can 3,5 m o l O2. Cong thufc

tiep nhau trong day dong d^ng tac dung vdi lifong d i i dung dich AgNOa
trong NH3, dun nong t h u dtfOc 32,4 gam Ag. H a i andehit trong X la

p h a n tuf c u a A la
A. C 2 H 6 O

B . 33,84

T h e o chvTcfng t r i n h N a n g c a o (10 c a u , txi c a u 51 d e n c a u 60)

B a i 43: Chon p h a t bieu d i i n g :

Bai

A. 19,44

B. C 2 H 6 O 2

C. C 3 H 8 O 3

D. C 3 H 6 O 2 .

A. C H 3 C H O va C 2 H 5 C H O .

B. C H 3 C H O va C 3 H 5 C H O .

C. H C H O v^ C H 3 C H O .

D. H C H O va C 2 H 5 C H O .

B a i 54: Day g o m cac k i m l o a i d e u tac d u n g diXgrc v d i d u n g dich FeCls Ik:

A.

Fe, M g , Cu, A g , A l

C. Cu, Ag, A u , M g , Fe

A. 0,05 va 0,7

B. 0,05 va 0,35

C. 0,1 va 0,7

D. 0,1 va 0,35.

B. 35,84

C. 31,36

D. 25,088.

B. N a O H va Ca(0H)2

C. Nude b r o m va Ca{0H)2

D . K M n 0 4 va N a O H .

C. 28

D . CgHeOa.

D. 16.

B a i 60: L e n m e n m gam glucozo v d i hieu suat 90%, \\Xgng CO2 s i n h r a

hap t h u h e t vao nirdc v o i t r o n g t h u dtfoc 15 gam k e t t u a va k h o i
lirang dung dich g i a m 5,1 gam. Gia t r i m la
A . 20,25

B . 22,5

Cho bi&'t khoi luang nguyen

He = 4;C

C. 30

D . 45.

tit (theo dvC) cua cac nguy^n

td: H = 1;

K = 39; Ca = 40; Cr = 52; Mn = 55;

Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137.

C . 34,6

D. 26,05.

B a i 2: Dot chay este E b l i n g oxi vCra du t h a y n^o^ : n^o ^^o^

=1:1:1-

Vay dot chay het 0,5mol E can t o i t h i e u bao n h i e u l i t O2 (dkc)?

A. l l , 2 1 i t

B. 16,81it

C. 23,52 l i t

D. 22,41it.

Y + N a O H - ^ ^ C H 4 + ....
K e t luan nao sau day la dung?
A. Z la t h a m gia p h a n ufng cong v d i brom
B. Z t h a m gia phan ufng giiang
C. Y la a x i t axe tic
D. X daac tao t h a n h tCr p h a n l i n g giiJa a x i t va ancol.
B a i 4: Ancol dan chiic X chay cho mgo^ : m p = 1 1 : 9 . Dot chay hoan
toan 1 mol X r o i hap t h u toan bo san p h a m chay vao 600 m l dung
dich Ba(0H)2 I M t h i luang ke't tua xuat h i e n l a :
A. l l , 4 8 g

B. 5 9 , I g

C . 39,4g

D. 19,7g.

B a i 5: Oxi hoa 4 gam ancol dan chufc X b^ng oxi k h o n g k h i (cd xuc tac
va dun nong) t h u dufoc 5,6g h o n hap gom andehit, ancol dU v a nifdc. X

= 12; N = 14; O = 16; F = 19; Ne = 20; Na = 23; Mg = 24;

Al = 27; S = 32; CI = 35,5;

B. 35,2

X + N a O H -> Y + Z

B a i 59: Cho 20 gam h 6 n hap ba a m i n no ddn chiJc la dong d^ng ke t i e p

CO t i le mol tifcfng iJng la 1: 10 : 5, tac dung vCfa du v d i dung dich H C l
t h u dirac 31,68 gam h 6 n hop muoi. Tong so' dong p h a n cua ba a m i n
t r e n la
B. 14

A. 15,65

B a i 3: Chat hufu ca X c6 cong thufc p h a n tijf C4H6O2. Co cac p h a n iJng:

B a i 58: Dot chay hoan toan 1 mol ancol no A can 2,5 m o l O2. Cong thiJc
p h a n tur cua A la

A. 7

tac dung v d i 150ml

gam chat rSn. Gia t r i m la

A. Niidc brom va N a O H

C. CgHgOg

\ PHAN CHUNG CHO TAT C A C A C THi SINH (40 cSu, tCf cSu 1 dfen cu 40)
dung dich Ba(0H)2 I M . Co can dung dich sau p h a n iJng t h u difdc m

B a i 57: De nhan biet cac k h i : CO2, SO2, HgS, N2 can dung cac dung dich:

B. C2H6O2

Thdi gian lam bai 90 phrit

B a i 1: Cho 12,55gam muoi CHgCHCNHgCDCOOH

B a i 56: Hoa t a n hoan toan hon hop gom FeS2 0,24 mol va CU2S vao
dung dich HNO3 vCra du t h u difOc dung dich X (chi chufa h a i muoi
sunfat) va V l i t k h i N O duy n h a t . Gia t r i cua V la

A. CaHgO

M o n t h i : Hoa hoc

D. A u , Cu, A l , M g , Z n .

B a i 55: C a n bao nhieu a m o l K2Cr207 va b mol H C l de dieu che dtroc

3,36 l i t CI2 dieu k i e n chuan. Gia t r i a va b Ian lifot l a :

A. 34,048

T H I THUT D A I H Q C V A C A O D A N G

Di

B. Fe, Z n , Cu, A l , M g

CO cong thdc:
A. C H 3 O H

B. C 2 H 5 O H

C. C 3 H 5 O H

D . C3H7OH.

B a i 6: Co bao nhieu hgp chat hufu ca C T H S O vCra tac dung v d i N a vCra tac
dung v d i NaOH?
A. 1

B. 2

C. 3

D . 4.

a i 7: Hoa t a n 11,6 gam h 6 n hap k i m loai Fe va Cu bang HNO3 d5c,

nong du, t h u duac dung dich A v^ s i n h ra 5,6 l i t (dkc) h 6 n hap k h i X

gom N O va N O 2 (khong c6 s a n p h a m nao khac). Bie't dx/e, = 18,2.

Li/Ong muo'i n i t r a t t r o n g dung dich A la
A. 45,7gam

B. 47,5gam

loang du vao dung dich sau p h a n ufng dugtc m o t dung dich c6 the hoa

C. 39,5gam

D. 35,9gam.

B a i 8: Cho 3,36 Kt k h i clo vao 300ml dung dich K O H I M d 100C, t h u

dufOc dung dich X. Lucfng bac clorua t o i da t h u dUdc k h i cho X phan
ufng v d i AgNOs l a :
A. 16,5gam

B. 35,875gam

C. 21,525gam

D. 43,05gam.

B a i 9: N h u n g m o t la sat vao dung dich C U S O 4 , s a u m o t thori gian l a y la

sit r a can t h a y k h o i lifofng t a n g 0,2g. I ^ o i liTcfng dong d a bam vao la
sat la
A. l , 6 g

B. 4,8g

C a u 16: Hoa t a n 3,6 gam FeO b l i n g H N O 3 loang, vCfa du. T h e m H 2 S O 4

C. 5,6

D. 3,2g.

B a i 10: D i e n p h a n 5 0 m l dung dich C U S O 4 I M v d i dien c\ic tra, dong

dien k h o n g doi I = 2A t r o n g t h 6 i gian 32 p h u t 10 giay. Sau dien
p h a n , k h o i li/ang dung dich se

t a n t o i da m gam bot Cu va tao r a V lit N O (dkc). Gia t r i m va V I a n

laot l a :
A. 16gam va 3,36 l i t

B. 14,4gam va 3,36 l i t

C.l,6gam va 3,36 lit

D. 16gam va 4,48 lit.

B a i 17: Cho Ba vao Ian luot cac dung dich: N H 4 C I (1), Na2C03 (2) ,
K2SO4

(3), A I C I 3 du (4), M g (N03)2 (5), K O H (6) se t h a y h i e n tUdng k e t

tua d:
A . 2,3,4,5

B. 2,3,4

C. 3,4,5

B a i 18: Cho cac p h a n ufng:

1) C U S O 4 + H 2 O

'

2) Cu(N03)2

A. tang 1,6 gam

B. g i a m 1,28 gam

3) CuO

+ CO

4) CuO

C. tang 1,28 gam

D. g i a m 1,6 gam.

5) CuO

+ Cu

6) Fe

B a i 11: Hoa t a n m gam h o n hc;p CaCOa va MgCOa bang dung dich H C l

du t h u dtfoc 3,36 l i t k h i (dkc) va dung dich chiJa 15,45gam muoi, m c6
gia t r i la
A. 10,2

B. 13,8

C. 12,8

D. 10,8.

C a u 12: Cho V h t dung dich N a O H 1,8M vao 1 l i t dung dich H 2 S O 4 I M

t h u diroc dung dich sau c6 p H = 1. Gia t r i V la
A. 2

B. 1

C. 1,05

D.0,47.

C a u 13: Hoa t a n 3,24 gam A l bang liTdng du dung dich H N O 3 t h u A\Xac V

l i t (dkc) h o n hgp X gom N2 va NgO (khong c6 san p h a m khuf khac).
B i e t dx/^ = 18. C h i r a V
A . 8,064

B. 0,896

C. 1,12

D. 0,672.

C a u 14: Thuc h i e n p h a n iJng n h i e t n h o m 17,4 gam h o n hap gom A l va

Fe203 t h u dirgrc h o n hop X. Hoa t a n X t r o n g luotng dir dung dich HNO3
dac, nong t h a y t h o a t r a 13,44 l i t NO2 (dkc) duy n h a t . % k h o i lirang
Fe203 t r o n g h o n h d p dau la
A. 6,9%

B. 9 3 , 1 %

C. 31,03%

D . 68,97%.

B a i 15: Cho 200ml dung dich N a O H nong do a mol/lit phan ijfng vdfi 200ml
dung dich A I C I 3 0,5M t h u ducfc 6,24 gam ket tua. Gia t r i cua a l a
A. 1,2M hoac 1,6M

B. 1,2M

C. 1,6M

D. 0,4M hoac 0,6M.

D . 2,3,5.

+ CH3NH2
+ CuCl2

So p h a n ufng tao r a dong k i m loai la

A. 4

B. 2

C.l

D.3.

B a i 19: Hoa t a n h e t r a n X gom Fe, FeO, Fe203, Fe304 vao H N O 3 loang,

da difoc 2,24 Ht N O (dkc). Vay neu hoa t a n h e t X t r o n g H 2 S O 4 dac,
nong dif t h i the t i c h S O 2 (dkc) t h u dUdc l a :
A. 5,04 l i t

B. 10,08 l i t

C. 1,12 l i t

D. 3,36 l i t .

B a i 20: Hoa t a n het 20,15 gam hon hcfp NaaCOs, CaC03 va BaC03 bang
dung dich H C l thoat ra 3,36 l i t C O 2 . K h o i li/dng muoi clorua t h u daoc la:
A. 21,8 gam

B. 24 gam

C. 25 gam

D. 23,45 gam.

B a i 21: D u n g k i m loai nao sau day de p h a n biet cac dung dich: C u C l 2 ,

NH4CI,

A. Cu

FeClg, (NH4)2S04, AgNOg, K N O 3 ?

B. M g

C. N a

D. Ba.

B a i 22: K h i metan b i I a n t a p chat la e t i l e n , axetilen, xiclopropan.

Co

the l a m sach k h i m e t a n bang each dan h 5 n hgfp k h i qua

A. B i n h difng N i , nung nong

B. Dung dich ntfdfc b r o m dif

C. B i n h diing k h i clo da.

D. Dung dich AgNOg/ N H 3 da.

B a i 23: M e n t o l , C 1 0 H 2 0 O va m e n t o n , CioHigO chiing deu c6 t r o n g t i n h

dau bac h a . B i e t p h a n tuf m e n t o l k h o n g c6 n o i doi, con p h a n t*^
menton c6 1 n o l doi. Vay k e t l u a n nao dadi day dung:

B a i 31: K h i t r u n g n g U i i g 13,1 gam axite-aminocaproic v d i h i e u suat

80%, ngoai amino a x i t du, nguTdi t a t h u dUcfc H 2 O va m gam polime.
Gia t r i cua m la

A. M e n t o l va menton deu c6 cau tao v6ng

B. M e n t o l va menton deu c6 cau tao mach h d
C. M e n t o l c6 cau tao vong, menton c6 cau tao mach h d

A. 9,04

D. M e n t o l c6 cau tao mach hof, menton c6 cau tao vong.

B a i 24: A x i t acrylic khong
A. CaCOs

C.Nudc B r o m

C. 11,02

D. 10,41.

B a i 32: Do't chay hoan toan l , 5 g a m chat hCfu ccf X Wang oxi vC/a du t h u

tac dung v d i chat nao dudi day?

B. C H 3 N H 2

B. 8,43

D. Cu.

B a i 25: P h a n ufng nao dudi day chiing m i n h n h o m - O H a n h hifdng den

vong benzen?
A. Phenol + niidc b r o m

B. Phenol + N a

C. Phenol + N a O H

D. Phenol + a n h i d r i t axetic.

dUcJc 0,896 l i t C O 2 ; 0,9gam H 2 O va 0,224 l i t N 2 (cac the t i c h do d dkc).

Vay X cd cong thufc l a :

A. C 2 H 5 N

B. C 4 H 9 N

C.C4H10O2N2

D.C2H5O2N.

B a i 33: Cho 4,12gam, h d n hofp X gom 2 andehit d d n chufc Hen t i e p t r o n g

B a i 26: Cho a mol andehit X p h a n iJng v d i 4a m o l H 2 (N2, t " ) , p h a n uTng

hoan toan t h u diTcfc 2a m o l hon hdp Y. Cho Y phan ufng v d i N a (dii),
s i n h r a a m o l H 2 . Vay andehit X thuoc l o a i :

day dong dang tac dung v d i liTdng diT dung dich AgNOs/NHs
25,92gam bac. Vay % so mol cac andehit t r o n g X la
A. 20% va 80%

B.30% va 70%

C. 50% va 50%

D . 25% v a 75%.

B a i 34: K h i dot chay m o t loai polime chi t h u difdc C O 2 va H 2 O v d i t i l e

A. No, dan chufc, mach h d

mol 1 : 1 . Polime da cho c d the \k:

B. Chiia no (1 n o i doi C = C), h a i chiJc, mach h d

A. Poll ( v i n y l axe tat)

B. xenlulozd

C. Chifa no (1 n o i doi C = C), dofn chufc, mach h d

C. PoH ( v i n y l ancol)

D. poll (phenol - f o m a n d e h i t ) .

D. No, ba chufc, mach h d .

B a i 27: Cho 12,76 gam andehit don chiJc X p h a n ling v d i liTgfng diT dung

B a i 35: Cho cac chat:

1) C H 3 - C H 2 - C O O H

2) C H 3 - C H C l -

dir dircfc 9,856 l i t N O 2 (dkc). X cd cong thufc phan tuf l a :

3) C H 2 C I - C H 2 - COOH

4) C H 3 - C H F - C O O H .

A. C 2 H 4 O

Thuf t i i t i n h a x i t tSng d a n l a :

dich AgNOs/ N H 3 . Luang A g s i n h ra cho tac dung v d i H N O 3 dSc, nong

B. CaHeO

C. C 3 H 4 O

D. C 4 H 8 O .

B a i 28: D o t chay hoan toan 0,2mol este E. H a p t h u h e t san p h a m chay

vao nifdc v o i t r o n g dirge dung dich X va 20gam k e t t u a . Dun nong
dung dich X l a i cd lOgam k e t t u a nCfa. Vay este E cd dSc d i e m :

A. (1) < (2) < (4) < (3)

B. (1) < (3) < (4) < (2)

C. (1) < (3) < (2) < (4)

D. (4) < (3) < (2) < (1).

B. L a este chi/a no

A. A x i t metacrylic

B. But - 2 - e n

C. T h u y p h a n E di/gc andehit.

C. Propen

D. Isopren.

D. Cho diicfc p h a n ufng t r a n g guang.

B a i 37: Thuoc t h d nao difdi day p h a n biet dtfdc cac dung dich: glucozd,

B a i 29: Este E chi chda m o t loai n h o m cMtc cd cong thufc (C3H403). Vay
cong thufc p h a n tijf cua E l a :
Bai

B. CgHsOe

C. C 9 H 1 2 O 9

D Ci2Hi60i2.

30: T r u n g hoa m gam h d n hap gom t r i m e t y l a m i n , p r o p y l a m i n va

e t y l m e t y l a m i n va e t y l m e t y l a m i n can viTa du 0,2mol H C l . K h o i lifdng

muo'i k h a n t h u dugc sau p h a n dng l a :
A. 1 9 , l g a m

B. 12,73gam

C. 15,5gam

COOH

B a i 36: C h a t n a o dtfdi day c d dong p h a n h i n h hoc?

A. Tac dung di/gtc v d i N a O H theo t i le m o l 1:2

A. C 3 H 4 O 3

diTdc

D. 2 1 gam.

ancol etylic, axetandehit, glixerol?

A. Cu ( 0 H ) 2 / 0 H

B. AgNOa/NHg

C. N a O H

D. N a .

Bai

38: Cho 12gam a x i t axetic tac dung v d i 9,2gam g l i x e r o l (xuc tac

H2SO4 dac) dun nong t h u 10,9 g a m trieste. H i e u suat p h a n l i n g la

A. 25%

B. 50%

C. 75%

D. 80%.

B a i 39: Chat hOfu ccr X c6 1 n h o m amino, 1 chile este. H a m lugrng n i t o

t r o n g X l a 15,73%. Xa phong h o a hoan toan m g a m chat X, t o a n bo
ancol s i n h ra cho d i qua CuO (dtf) nung nong, t h u difoc andehit Y. Cho
Y thiic h i e n p h a n ufng t r a n g gufcfng t h a y c6 16,2 gam A g k e t t u a . Gia
t r i cua m l a :
A. 7,725 gam

B. 3,3375gam

C. 6,675 gam

D. 5,625 gam.

B a i 40: Este X c6 cong thuTc C7H12O4. X tac dung v d i N a O H , dun nong

B a i 47: D e p h a n biet SO2 v a CO2, cd the dung

1) dung dich K M n 0 4
A. 1;2;3

A. 3.

B. 1.

C. 2.

D. 4.

cho chuang

C. 2

D. 1;3

nhau.
Phan

1: D o t chay hoan t o a n , t h u difgc 4,48 l i t k h i CO2 (dktc)

Phan

2: D e h i d r a t hoa hoan t o a n t h u diTote h 6 n hgfp h a i anken. N e u

dot chay he't h a i anken t h i t h u dufgfc bao n h i e u gam ni/dc?

A. 0,72 gam

B. l , 8 g a m

C.l,08gam

D . 3,6gam.

B a i 49: Melamin va ure la 2 chat tCmg dtfOc dUa vao thiic pham vdi muc dich
A. T a n g do dam

II. PHAN RieNG (10 cau)

Tlii sinh hoc theo chiCang trinh

B. 1

3) dung dich Br2

B a i 48: Chia m gam m gam h d n hgp h a i ancol t h a n h h a i p h a n b a n g

t h u dirge muoi va 2 ancol Y, Z. B i e t Y va Z deu c6 the tach niidc tao

anken. So cong thiic cau tao cua X l a :

2) dung dich Ca(0H)2

nao thi chi dugc lam phan

danli

rieng

B. Bo sung khoang chat can t h i e t

C. N a n g h a m liiofng n i t d t r o n g thiic p h a m

trinh do (phan A hodc B)

B a i 41: Cho 18,5 gam r a n X gom Fe, FeO va FeaOsvao 200ml dung dich
HNO3. Sau p h a n iJng, dtfcfc 2,24 l i t (dkc) k h i N O va con l a i 1,46 gam

D. Bao quan thuc p h a m k h o i 6 i moc.

B a i 50: T i n h k h o i li/ofng glucozd t r o n g niJdc qua nho de sau k h i l e n men

sat chufa t a n . Vay nong do m o l dung dich HNO3 da cho l a :

cho t a 100 l i t vang 10. B i e t hieu suat p h a n ufng l e n men dat 9^%,

A. 3,2M.

ancol etylic cd k h o i lacfng r i e n g la 0,8g/ml. Gia t h i e t r a n g t r o n g niJdc

B. 2 M .

C. 1,8M.

D. 2,5M.

B a i 42: A x i t nao sau day c6 t r o n g t h a n h p h a n nguyen lieu t o n g hgfp

nilon-6,6?
A. Axitoxalic

B. A x i t a d i p i c

C. A x i t t a x e t i c

D. Axitglutamic

B a i 43: Chat X c6 n o i doi C = O, c6 cong thufc p h a n tijf C5H10O. So dong

p h a n cau tao cua X la
A. 6

B.7

C.8

200ml dung dich chuTa Cu(N03)2 I M . Sau p h a n iJng t h u di/gfc 18,4gam

Y gom 2 k i m loai. K h o i liJcfng Fe t r o n g hon hgp X l a :

A. 2,4gam

B. l l , 2 g a m

C. 8gam

D.4,8gam.

B a i 45: K i m loai M tac dung v d i CI2 va dung dich H C l tao 2 muoi

Biet
A. Pb

M^^ deu cd t i n h khuf. Vay M la

B. M g

C. Fe

B. Na2S03, SO2, FeCl2, Na2S04

D. Fe203, FeCh,

CTZO^,

C.16,476kg

D.18kg.

T h e o chifofng t r i n h N a n g c a o (10 cau, tii cau 51 den cdu 60)

B a i 51: Pha loang dung dich H C l cd p H = 3 bao nhieu I a n de dirge dung
dich cd p H = 4?
B. 4

C.9

D.IO.

B a i 52: So v d i ancol cung so cacbon, andehit cd

A. n h i e t do soi cao hcfn

B. t a n trong nirdc n h i e u han

C. n h d m ehiJc chiTa no

D. lien ket hidro vdi nude ben han.

B a i 53: A x i t nao cd cong thiJc ddn g i a n n h a t la C3H4O3?

A. C2H4(COOH)2

B. C6H9(COOH)3

C.C3H5(COOH)3

D. CH2(COOH)2.

m o t la n h i i n g vao dung dich Cu(N03)2. Sau m o t t h d i gian lay m o i la

B a i 46: Day cac chat vCra cd t i n h o x i - h o a vCra cd t i n h khijf

B. KzCraOy, Na2S03, SO2,

B. 17,52kg

B a i 54: Cd h a i la k i m l o a i M . M o t la n h i i n g vao dung dich Pb(N03)2;

D. Cr.

A. CI2, SO2, FeCl2, CrCls

A. 15,26kg

A. 5

D.5.

B a i 44: Cho 13,6 gam h 6 n hap X h a i k i m loai M g va Fe tac dung v d i

rin

qua nho chi cd glucozcf l e n m e n tao ancol.

r a can, t h a y m o t l a cd k h o i lirgng t a n g , m o t la cd kho'i lirgng g i a m so

FeCh
KMnO,.

v d i trirdc p h a n ufng. Vay M cd the l a k i m loai nao dirdi day

A. Fe

B. M g

C. A l

D. Z n .

B a i 55: 23,8 gam k i m loai X t a n t r o n g dung dich H C l vixa du tao dung

dich X^^ Dung dich nay tac dung

viTa

DE

du v d i 400ml dung dich FeClg

I M tao r a ion X'^\

M a de 116

Vay X la:
A. Fe

B. Sn

C. Pb

D. Cr.

ket tua. V c6 gia t r i l a :

D- 150ml hoSc 350ml.

C.

Cau

B.

9,81 va 4,32

58: Chat c6 cong thutc p h a n tuf nao diTdi day c6 the tac dung v d i

Bai

B . C5H12O2

59: P h a n ling

CH3NH2

CH3NH2

C.

+ HNO2 ^

CeHeOz
CH3OH

ciia Z, X l a :

A. A x i t malonic

D.
+ Ng +

C3H4O2.

cho t h a y

H2O,

'

A. 0,118mg

C9H16O4.

Thuy phan E

C. A x i t oxalic

D. A x i t axetic.

B. 4,28mg

C. 0,337mg

Khoi

D. 0,674mg.

C8H15O4N.

X tac dung vdi

dung dich N a O H dun ndng cho ra hon hop metanol, etanol va muoi n a t r i

cua mot a - a m i n o a x i t mach khong phan nhanh T. Vay T c6 ten la:

A. a x i t a - a m i n o a d i p i c

B. a x i t glutamic

C. a x i t a-aminosuccinic

D. g l y x i n .

Jai 5: Cho h o n hdp hot Fe, A l vao dung dich hon hop A g N 0 3 va
Cu(N03)2. Sau p h a n ufng t h u dirge dung dich Y chda 2 cation la
A . A\'\

C. Co t i n h oxi hoa
D. Co the dong vai t r o m o i trifdng t r o n g cac p h a n ufng oxi hoa khijf.
60: De p h a n biet 4 lo m a t n h a n chda cac

dung dich: glucoza,

A. C u ( 0 H ) 2 / 0 H -

B. N a

C. N a O H

D. Dung dich AgNOg/NHa.

nguyen

ti2 (theo dvC) cua cac nguyen

.2+

D. e^\u

.2+

1. K i m loai N a

2. Dung dich N a O H

A. l h o a c 3

B.2hoac3

3. Nude b r o m

C. 1,2 hoSc 3

D. 1 hoSc 2

khoi lugng rieng cua giam la I g / m l . Vay mau giam a n nay c6 nong do la:
A. 4%

to: H = 1;

K = 39; Ca = 40; Cr = 52; Mn = 55;

Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137.

C. A?\u

B a i 7: De trung hoa 40ml giam an can 25ml dung dich N a O H I M . Biet

= 12; N = 14; O = 16; F = 19; Ne = 20; Na = 23; Mg = 24;

= 27; S = 32; CI = 35,5;

B. A l ^ ^ Fe,2+

B a i 6: Hoa chat nao diidi day dung de p h a n biet 2 lo m a t n h a n chda

dung dich phenol va benzen?

saccarozo, ancol etylic va fomon, ta chi can dung

Al

D.6.

B. Co t i n h khuf

He = 4 ;C

B. A x i t acrylic

i B a i 4: X la chat hCfu ccf c6 cong thufc phan tuf

la hop chat:

Cho biet khoi lugng

C. 2

k h a n a n g tach nude tao anken. So cacbon cua Y gap 2 I a n so cacbon

A. Co t i n h bazcf

Bai

B. 8

I B a i 3: M o i ngay ccf the m o t ngudi can t r u n g b i n h la 0,2mg iot.

I
liiong K I O 3 dap ufng yeu cau t r e n l a :

3,18 va 10,83

D . 4,32 va 9,81.

CTHSO

A. 4

(xuc tac axit) dtfofc axit cacboxylic X va 2 ancol Y, Z. B i e t Y, Z deu c6

N a O H theo t i le mol 1 : 2?
A.

phut

B a i 2: E la hop chat hO-u ccf, cong thufc phan tijf

B a i 57: Chuan do 50,00ml dung dich N a O H 0,05M hkng dung dich H C l

0,10M. Gia t r i p H cua dung dich sau k h i da t h e m nhCfng the t i c h H C l :
24,50ml va 25,50ml Ian luot l a :
A. 10,38 va 3,18

Thai gian lam bai 90

ban, so electron doc t h a n cua X la

[

C. 350ml

M o n t h i : Hoa hoc

B a i 1: Ion X^" c6 cau h i n h e Idp ngoai cung la 3s^ 3p^. CJ t r a n g t h a i cO

dung v d i V m l dung dich N a O H 2 M , sau p h a n dng t h u daoc 10,3 gam

B . 300ml hoSc 600ml

DANG

I. PHAN CHUNG CHO TAT CA C A C THl SINH (40 c^u, tCf cu 1 d^n cSn 40)

B a i 56: Dung dich X chiJa CrCls I M . L a y 200ml dung dich X cho tac

A. 150ml

THI THUf D^il HQC VA CAO

B. 3,5%

C. 5%

D. 3,75%.

B a i 8: Xa phong va chat giSt rijfa t d n g hgp c6 chung dSc diem l a :

A. K h o n g h i g i d m tAc dung t a y rijfa t r o n g nude cdng

B. P h a n tuf gom m o t dau p h a n cUe gSn v d i duoi d^i k h o n g p h a n cUc

+ Cho phan 2 tdc dung v d i lucfng du dung dich AgNOa/NHa duoc

17,287gam bac

C. Duac dieu che tCr chat beo thuc v a t hoSc dong v a t

D. Chufa chat este va c6 mach cacbon p h a n n h a n h

X gom 2 andehit c6 cong thiic p h a n tuf l a :

B a i 9: Dem m gam hon hop A l va Zn t a n het t r o n g dung dich h o n hop

H C l va H2SO4 loang t h u diioc 5,6 l i t H2 (dkc). N e u cho 2 m gam h 5 n
hop t r e n vao dung dich h 6 n hop K O H , N a O H diS, the t i c h H2 (dkc) t h u
duoc se l a :
A. 9,8 l i t

B. 5,61it

B a i 10: Este n^o sau day khong

C. 8,4 l i t

D. 11,2 l i t .

ancol?
C. etyl axetat

D. v i n y l axetat.

B. C6H5CH3

B. 9

A. CsHgOz va C6H10O2

B. C 5 H 4 O 2 va C 6 H 4 O 2

C. C5H6O2 va C6H8O2

D. C4H6O2 va

18:

Mot

loai

nUdc

chuTa 0,01mol

C. CgHsNOa

D. CeHsNHgCl.

C. 8

0,02mol

Ca^\l

H C O 3 va 0,02mol C I " . Dun nong niTdc t r e n m o t t h d i

B. H2SO4 + Ba(0H)2

C. H C l + K O H

D. H N O 3 + M g ( 0 H ) 2 .

B. Nirdc ciJng t a m t h d i

C. Ni/dc m e m

D. Ntrdc cufng toan p h a n .

1. NH4NO3
I

ufng xay r a giufa

A. H C l + Fe(0H)2

A. Nufdc cufng v i n h cufu

B a i 19: Cho cac p h a n i l n g oxi hoa sau (chiia xet he so can b^ng):

D . 6.

B a i 13: HgO^ + O H ' -> 2H2O phu hop phaong t r i n h i o n t h u gon phan

2. A1(N03)3

N 2 0 t + H2O
AI2O3 + NO2T + O2T

3. CI2 + N a O H > N a C l + NaClO + H2O

(

4. F e S 0 4 + K M n 0 4 + H2SO4 > Fe2(S04)3 + M n O a + K2SO4 + H2O

5. CI2 + K O H d K C l + K C I O 3 + H2O

B a i 14: Hoa t a n k i m loai I I A vao nudc t h u dUOc dung dich X va 4,48 l i t

h i d r o (dkc). Co can dung dich X difOc 34,2g r ^ n . K i m loai la

P h a n ufng tir oxi hoa khuf 1^:

A. Ba

A. 1, 2, 3, 5

B. Be

Na^

C5H8O2.

gian t h u dufgfc

B a i 12: Co bao n h i e u dong p h a n , cong thiJc p h a n tuf la C5H12O?

A. 7

D. C H 2 O va CaHgO.

Mg2^0,05mol

anilin

Y CO the la chat nao dudi day:

A. CeHsBr

C. C H 2 O va C4H6O

Bai

B a i 1 1 : Cho so do chuyen hoa

Benzen ^ X -> Y ^

B. C H 2 O va C2H4O

B a i 17: X la h 5 n hop 2 este don chuTc (tao bdi cung m o t a x i t v d i 2 ancol

h e n t i e p t r o n g day dong dSng). Dot chay hoan toan 21,4gam X diioc
1,1 mol CO2 va 0,9 m o l H2O. Cong thiJc p h a n tuf 2 este t r e n l a :

thu dU<^c b^ng p h a n utng giOfa a x i t va

A. A n l y l axetat B. m e t y l acrylat

A. C H 2 O va C3H4O

C. Ca

D. M g .

B a i 15: Dung dich X chufa AICI3 va FeClg. T h e m NH3 diX vao 100ml X. Loc

B. 1, 2, 3

C. 1, 2

D . 3, 5.

B a i 20: Cho cac p h a t bieu sau:

ket tua, rufa sach, nung trong khong k h i den k h o i luong khong doi dacfc

1. Phan ufng thuan nghich la phan ufng xay ra theo mot chieu xac d i n h .

13,lgam r a n . Cho 100ml X phan ufng vdi AgN03 dif diiOc 82,55gam ket

2. Can bang hoa hoc la can bSng dong.

tua. Nong do mol/1 cua AICI3 va FeClg trong X Ian li/Ot la:

3. K h i t h a y doi t r a n g t h a i can bang he, can bSng se chuyen dich ve

A. I M va I M

B. 3,3625M va 1,6375M

C. I M va 0,75M

D. 0,5M va 0,5M.

C a u 16: X la h o n hop 2 andehit don chiJc. Chia 0,12mol X l a m 2 phan

p h i a chong l a i sir t h a y doi ay.

4. P h a n ufng t h u a n nghich 2NO2 ^

N2O4 k h o n g phu thuoc sir t h a y doi

ap suat.

b^ng nhau:

Cac phat bieu dung:

+ D o t chay h e t p h a n 1 duoc 6,16gam CO2 va l , 8 g a m H2O

A. 3, 4

B. 2, 3

C. 2, 4

D. 1, 4.

B a i 21: Co hien tuong gi xay ra k h i dien phan dung dich chijfa dong t h 5 i
NaCl va H C l , c6 pha vai giot quy t i m vdi dien cue tro, mang ngan xop?
A. Dung dich ban dau mau do, se hoa t i m , cuoi cung chuyen sang xanh.
B. Dung dich ban dau mau xanh, se hoa t i m , cuoi cung chuyen sang do.
C. Dung dich ban dau mau do, se hoa xanh, cuoi cung chuyen sang t i m .
D. Dung dich ban dau mau t i m , se hoa do, cuoi cung chuyen sang xanh.
B a i 22: D a n CO qua 5,8g oxit sit

Fe^Oy nung nong m o t thofi gian t h u

duoc hon hop rSn X. Cho X t a n het t r o n g dung dich HNO3 b a n g duoc
dung dich Y. Co can dung dich Y con l a i 18,15g muoi sit

(III) khan.

Oxit sat phu hop.

A. Fe202

B. Fe203

C. Fe304

D.

FeO.

B a i 23: X la hon hop 2 a n k i n . Dot chay X duoc 6,6g CO2 va l , 8 g H2O.

K h o i lugng b r o m ciic dai c6 the phan ufng v d i hon hop X l a :
A. 8g

B. 16g

C. 4g

D. 2g.

B a i 24: I s o p r e n c6 the cong hop b r o m theo t i le m o l 1: 1 tao t h a n h so

dong p h a n cau tao l a :
A. 3.

B. 2.

C. 4.

D. 1.

B a i 25: Mijfc do phan circ cua cac lien ket tang dan theo t r a t t u nao sau day?
A. NH3; H2O; CH4.
C. C H 4 ; H2O; NH3

Cung 0,92gam h 6 n hop X p h a n iJng duoc v 6 i t o i da bao nhieu m o l H2:

B. 0,07mol.

C. 0,035mol.

D. 0,05mol.

B a i 27: Hoa t a n het m gam h 6 n hop gom Fe, FeO, Fe203 va Fe304 bSng
H N O 3 dac nong t h u diioc 4,48 l i t k h i NO2 (dkc). Co can dung dich sau
phan ijtng duoc 145,2 gam muoi k h a n . Gia t r i m
A. 42,8gam

B. 33,6 gam

C. 46,4 gam

D. 43,2 gam.

B a i 28: De c6 59,4 k g xenlulozO t r i n i t r a t can dung t o i t h i e u bao nhieu

k g xenlulozO va bao nhieu k g HNO3? Cho hieu suat p h a n ufng dat
90%.
A. 18kg va 42kg

B. 36kg va 21kg

C. 72kg va 21kg

D. 36kg va 42kg.

B. 11,6 gam

C. 17,4 gam

D. 8,5 gam.

B a i 30: Hoa t a n h 6 n hop N a va 1 k i m loai l A vao nUdc duoc dung dich

X . - X CO can difoc l , 6 g An.
z
H C l 0,5M. K i m loai l a :
A.Li

Neu t r u n g hoa ^ X can 5 0 m l dung dich

2

B. K

C. Cs

D.Rb.

B a i 31: D a n V l i t CO2 (dkc) vao 250ml dung dich N a O H I M . T i n h gia t r i

V de t h u diroc 2 m u o i :
A. 2 , 8 < V < 5 , 6

B. V < 2 , 8

C.2,8 < V < 5,6

D. V < 5,6.

B a i 32: C h i r a p h a t bieu sai

A. Dung dich mantozo hoa t a n dirge Cu(0H)2
B. T h u y p h a n saccarozo cung n h a mantozO (H"^, t) deu cho cung san
pham.
C. Dung dich fructozo hoa t a n dugc Cu(0H)2.
D. San p h a m t h i i y p h a n den cung xenlulozO (B.\ c6 the tao k e t
tua do gach v d i Cu(0H)2/ O H " dun nong.

A. P h a n tuf eo l i e n k e t ba v d i n a n g li/ong l i e n k e t I d n

D. H2O; C H 4 ; NH3.

B a i 26: Cho 0,92gam hon hop X gom axetilen va andehit axetic phan
iJng hoan toan v d i dung dich AgN03/NH3 t h u difOc 5,64gam k e t tua.
A. 0,04mol.

A. 5,8 gam

B a i 33: O dieu k i e n thtrdng, N2 t r o ve mat hoa hoc v i

B. C H 4 ; NH3; H2O
^

B a i 29: Hoa t a n m gam FeCOa vao dung dich H N O 3 du duoc 4,48 l i t

(dkc) h o n hop k h i X gom CO2 va NO2. C h i ra m

B. Co ban k i n h nguyen tuf nho n h a t t r o n g n h o m V A

C. Nguyen tijf c6 5e or Idp ngoai cung
D. N i t o CO do a m d i e n k h a cao (3,04)
B a i 34: Chia 0,3 mol a x i t cacboxyHc X l a m h a i p h a n hkng nhau
+ Dot chay h e t p h a n 1 duoc 19,8g CO2
+ Cho p h a n 2 tac dung v d i 0,2mol N a O H , t h a y sau p h a n urng k h o n g
con N a O H . Vay X ed cong thufc p h a n tuf l a :
A. C3H4O2

B. C6H8O4

C. C3H6O4

D.C3H4O4.

B a i 35: D i n m o t luong k h i CO d i i qua h 6 n hop r a n X nung nong gom

A I 2 O 3 , Fe203 va CuO. Sau p h a n iJng duoc r a n Y va h 5 n hop k h i Z. Cho
rfin Y vao dung dich N a O H du.
A. r a n Y b i t a n m o t p h a n , k h o n g c6 k h i t h o a t ra

B. C O k h i t h o a t r a , r a n Y t a n h e t

B a i 4 3 : Dot chay hoan toan 1 m o l ancol no X can 3,5 m o l O2. Cong thiJc
phan t\!i cua X l a :

C. C O k h i t h o a t r a , r a n Y h i t a n m o t p h a n

A. C2H6O

D. r ^ n Y h i t a n hoan t o a n , k h o n g c6 k h i t h o a t r a .
B a i 36: X,Y la hai k h i khong mau. L a n
brom t h i X l a m

niTdc

cho moi k h i loi tCr ttr qua

nUcrc

brom nhat mau dan, trong k h i Y l a m n\idc brom

sam mau dan. Vay X,Y c6 the l a n

A. H2S va H C l

liTgtt

lUoft

B. SO2 va H I

la rihCfng k h i nao diidi day?

C. CI2 va H C l

D. SO2 va H C l .

B a i 37: K h o i lagng p h a n tuf cua to - n i l o n - 6 , 6 la 25000, cua to n i l o n - 6

la 15000. So m ^ t x i c h t r o n g cong thiic p h a n tijf cua chung l a n \ixat l a :
A. 110 va 114

B. 95 va 98

C. 110 va 132

D. 110

va

98.

B a i 38: l O i i dun h o n hop a x i t oxalic vdfi h a i ancol 1^ metanol va etanol

B. C3H6O2

C. C2H6O2

B a i 44: Cho cac chat:

DNaCl

2)CuS04

3)AgN03

A. 1,2,3,5

B. 2,3,5

C. C O cac hop chat hoa t r i H va H I

D. 2.

B.Na, K , M g

C. A l , K , Fe

D. Ba, L i , K.

C a u 40: Dot chay 5,8 gam chat M t a t h u difcfc 2,65gam NazCOg, 2,25gam
H2O va 12,lgam CO2. Cong
A. CfiHsONa

phan tuf cua M la

thiJc

B. CHsCOONa

C. CTHvONa

D. CzHaCOONa.

B a i 46: Dung dich muoi clorua k i m loai M c6 mau x a n h . Cho dung dich
N a O H du vao dung dich nay t h a y c6 k e t tua, sau do k e t tua t a n h e t .
Sue k h i clo vao dung dich sau p h a n ufng t h u dirge dung dich c6 mau
vang. Vay M l a :
A. Zn

B. Cr

C. A l

D. Cu.

B a i 47: Uu diem cua phirong phap chuan do penmanganat la

II. P H A N R i e N G ( 1 0 c a u ;

Thi sink hoc theo chuang trinh

D. 2,3,4,5

D. deu k h o n g t a n t r o n g HNO3 dac, nguoi.

B a i 39: Dung dich K O H diX c6 the hoa t a n het dtfoc h o n hop rSn
A. Z n , Cu, Fe

C. 1,5

A. deu C O the dtfOc dieu che b^ng p h a n iJng nhiet n h o m

t h u duoc l a :
C.4

nao thi chi diCgc lam phan danh

ri^ng

A. KMn04 la chat oxi hoa m a n h , k h o n g phu thuoc p H .

B. Khong can xac d i n h l a i nong do KMn04 sau k h i pha che

cho chuang trinh do (phdn A hodc B)

T h e o chvCdng t r i n h C h u a n (10 cau, tU cau 41 den cau 50)

C. KMn04 k h a ben, k h o n g h i p h a n huy ngoai a n h sang

B a i 41: Cho he can bang toa n h i e t : 2SO2 + O2

D. Khong can dung chi t h i , KMn04 dong thcfi la chi t h i .

2SO3 (xuc tac V2O5).

Can bkng hoa hoc se chuyen dich sang chieu nghich t r o n g trUcfng hop
n a o sau day?
A. H a n h i e t do cua b i n h p h a n

ufng

B. Tang ap suat chung cua h o n hop

C. Tang nong do k h i oxi
D. T h e m SO3.
B a i 42: Hidrocacbon X chi chiJa cac l i e n k e t a . Dot chay X t h u
nco, =

HH^O..

A. ankan

X t h u o c loai
B. anken

5) H2SO4.

B a i 45: Diem gio'ng nhau giiJa C r wh Fe nao dudi day dirge neu r a la
khong
dung

B. deu thuoc p h a n n h o m V I B

B. 3

4) ZnClz

Dung dich sau dien phan chat nao hoa t a n dufOc AI2O3?

(xiic tac H2SO4 dac, t) t h i so san p h a m chufa chiJc este t o i d a c6 the

A. 5

D. CaHsOa.

C. xicloankan

D. a n k i n .

dUOc

B a i 48: Dun nong h o n hgp X gom 2 ancol don chiJc Hen tiep t r o n g day
dong dang v<Ji H2SO4 dac d 140C. Sau p h a n ufng diTOc h o n hgp Y gom
5,4gam niTdc va 19,4 gam ba ete. H a i ancol ban dau da dung l a :
A. CH3OH va C2H5OH

B. C3H7OH va C4H9OH.

C. C 3 H 5 O H va C 4 H 7 O H

D . C 2 H 5 O H va C 3 H 7 O H .

B a i 49: L a y 15,4 gam chat X cong thufc p h a n tuf C2H7O2N tac dung v d i
dung dich N a O H vira du, dun nong dirge dung dich chufa m gam muoi
va k h i Y. B i e t Y c6 the l a m x a n h quy a m va san p h a m chay cua Y
l a m due nirdc voi t r o n g . Gia t r i m l a :
A. 23,4

B. 15,4

C.13,6

D.16,4.

B a i 50: L e n men ancol tCr glucoza sinh ra 2,24 l i t CO2 (dkc). Liicrng N a
t o i thieu can lay de phan ufng het v d i luctng ancol sinh ra la
A. 23g

B.2,3g

C.3,2g

D.4,6g.

T h e o chifoTng t r i n h N a n g cao (10 cdu, til cdu 51 di'n cdu

60)

B a i 51: Dung dich X chuTa CH3COOH 0,15M va CHsCOONa 0,1M. B i e t

CH3C.OOH CO Ka = 1,75.10"'.
Dung dich X c6 p H la
A. 4,58

B. 5,58

C. 2,79

D. 3,79.

B a i 52: So dong p h a n ancol C5H12O p h a n iJng v d i CuO, t " s i n h ra

andehit va xeton Ian \\iqi l a :
A. 3 va 2

B. 4 va 3

C. 3 va 3

D . 4 va 4.

B a i 53: Vdi dieu kien thich hcfp, ta c6 the dieu che axetandehit tnrc tiep tCr
DCzHsOH

2)C2H4

3)C2H2

4) C2H5COOH.

A. 1 va 3

B. 1,2 va 3

C. 2 va 3

D . 3 va 4.

B a i 54: D i e n phan dung dich CUSO4 v d i dien cUc trot cho den k h i catot
vCra bat dau c6 k h i t h o a t r a t h i ngCrng, nghia la
A. H2O chiia b i oxi hoa of catot.

B i l l 58: Phan biet 3 mSu:phenol, s t i r e n , ancol benzylic c6 the

A. chi dung N a

B. chi dung dung dich Br2

C. chi dung dung dich N a O H

D . chi dung dung dich H C l

B a i 59: K h i t h u y phan hoan toan I m o l pentapeptit t h u duoc I m o l g l j T c i n ,

2mol alanin, 2mol Phe. K h i thuy phan khong hoan toan pentapeptit
noi t r e n cho hdn hdp dipeptit, trong do c6 A l a - G l y , A l a - Phe ma k h o n g
thay CO Phe - A l a . Cong thufc cau tao cua pentapetit nay la
A. A l a - Gly - Phe - Phe - A l a

B. Gly - A l a - A l a - Phe -

Phe

C. A l a - Gly - Phe - A l a - Phe

D . A l a - Gly - A l a - Phe -

Phe.

B a i 60: Cacbohidrat khong

A. Fructozcf
Cho
He^
Al =
Fe =

biet
4 ;
27;
56;

cho phan ufng cong H2 la

B. Mantozcf

C. Glucozot

D . Saccarozcf.

kho'i liCgng nguyen tii (theo dvC) cua cdc nguyen to: H = 1;
C = 12; N = 14; O = 16; F = 19; Ne = 20; Na = 23; Mg = 24;
S = 32; CI = 35.5; K = 39; Ca = 40; Cr = 52; Mn = 55;
Cu - 64; Br = 80; Ag = 108;Ba = 137.

C. DAP AN CAC BO DE THI TNTHPT

B. I o n Cu'^^ b i khuf vCra h e t 6 catot

D4 1

C. H2O chua b i khuf d catot

Cau

DA

Cau

DA

Cau

DA

Cau

DA

11

21

31

12

22

32

13

23

33

14

24

34

15

25

35

Cho toan bo h o n hop X p h a n ufng v d i H C l dSc, d i i thoat ra V l i t khi

16

26

36

H2 (dkc). Gia tri cua V la

17

27

37

18

28

38

ddng) la t h d i d i e m

19

29

39

A. p H dung dich bat dau thay ddi dot ng6t

10

20

30

40

D. H2O vCra bSt dau b i oxi hoa d anot.

B a i 55: Oxi hoa het 7,02 gam k i m loai M bang CI2. M u o i tao t h a n h sau
phan ufng dem hoa t a n h e t vao niidc diTcfc dung dich X. Cho tCr tCr dung
dich N a O H vao dung dich X t h a y cd k e t tua, sau do k e t tiia vCra het
t h i ngCrng, t h a y da dung h e t 270ml dung dich N a O H 2 M . V a y M la
A. Z n

B. A l

C. Cr

D . Sn.

B a i 56: Nung h o n hcJp hot gom 15,2 gam Cr203 va m gam A l 6 n h i e t do

cao. Sau khi p h a n ufng hoan t o a n , t h u difotc 23,3 gam h o n hgtp rSn X.

A. 7,84

B. 4,48

C. 3,36

D.10,08.

B a i 57: T r o n g phuoing phap p h a n t i c h chuan do, d i e m cuo'i (hay d i e m

B. chi thi chuyen mau r d , ta ket thuc chuan do

C. p H dung dich dat den d i e m t r u n g hoa
D. chat can chuan do va chat chuan do p h a n ufng vCra het

De 2

Bi 4

Cau

DA

Cau

DA

Cau

DA

Cau

DA

Cau

DA

Cau

DA

Cau

DA

Cau

DA

11

21

31

12

22

32

33

34

11

21

31

12

22

32

13

23

33

14

24

34

13

23

15

25

35

14

24

16

26

36

15

25

35

16

26

36

c
c

19

29

39

17

27

37

10

20

30

40

18

28

38

19

29

39

10

20

30

40

Cau

DA

Cau

DA

Cau

DA

Cau

DA

11

21

31

12

22

32

13

23

33

14

24

34

15

25

35

16

26

36

17

27

37

18

28

38

19

29

39

10

20

30

40

17

27

37

18

28

38

De 3
Cau

DA

Cau

DA

Cau

DA

Cau

DA

11

21

31

12

22

32

13

23

33

ri4

24

34

15

25

35

16

26

36

17

27

37

18

28

38

19

29

39

10

20

30

40

D^ 5

D. D A P A N V A HLTdNG D A N G I A I D E DAI H O C
D A P

A N

V A

HL/(3NG

D A N G I A I

M A

D E

B a i 14: Cac hop chat sat t r o n g cac dap an n h i e t phan t r o n g k h o n g k h i

deu tao FeaOa.

111

2M

D A

Cau

D A

Cau

D A

Cau

D A

16

31

46

17

32

47

18

33

48

19

34

49

20

35

50

21

36

51

22

37

52

23

38

53

24

39

54

Phan

10

25

40

55

Phdn 2: C h i Fe'^ p h a n iJng:

11

26

41

56

12

27

42

57

13

28

43

58

14

29

44

59

15

30

45

60

HiCdng dan

gidi

2M

N2

+ 3H2

Trirdc:

4 (mol)

Pa:

3x

Sau:

(1 - x)

(4 - 3x)

H k h i sau pu =

(5

2.x)

> 160 (gam)

4m

>
9

=> m = 180. C h i n h la F e ( N 0 3 ) 2

Chon dap a n C.
B a i 15: Fe304

'W^^-i

> Pe^^ + 2Fe^*

a -> 2a (mol)

1: C h i Fe^" p h a n iJng:

2Fe^^ + 21"
2Fe^^ + I2
2a
> 2a = 0,3
=^ a = 0,15 (mol)
3Fe'^ + Cr"'^ ^ 3Fe^" + C r ' "
0,15

=>

> 0,05 (mol)

"K^crA = |"cr-

2x (mol)

C a u 16: P h a n 1 p h a n iJng v d i H2O g i a i phong so m o l H2 < P h a n 2 p h a n

ling v d i dung dich N a O H dir. => O t h i n g h i e m 1 lirong A l dir.
Na

+H2O

^NaOH+

-Ha
2

TNI:

>

TN2:

(mol)

- .a(mol)
2

> - .a(mol)
2

A l + N a O H + 3H2O ^ N a [ A l ( 0 H ) 4 ] + - H 2

Theo de, ap ap suat g i a m , turc la so m o l k h i g i a m .

Ta c6:

=
= 0,8 =^ X = 0,5(mol) ^ H = 50%

5
Chon dap a n A .

(mol)

Chon dap a n C.

2NH3
2x(mol)

= ^,025

V = 0,05 l i t = 50ml.

B a i 8: X e t hon hap gom I m o l N2 va 4 m o l H2

=>

FezOa + .... + ....

Cau

TNI:

TN2:

Tii T N I

>
>
2a = 0,2 => a = 0,1 (mol)

-.a
2
-.b
2

TiX

TN2

i .a + - .b = 0,35
2
2

B a i 21: K e t tua k h o n g t a n t h e m nffa tiJc la luc Al(OH)3 vCfa t a n h e t , chi

^ b = 0,2 (mol)

c6n l a i B a S 0 4

V a y nix = 2.(0,1.23 + 0,2.27) = 15,4gam

Al^^ + 3 0 H - A 1 ( 0 H ) 3

Chon dap a n A .

A1(0H)3 + O H - ^ Al(OH),-

B a i 18: P h i n 1: M g ' ^ + 2 0 H - -> Mg(0H)2

0,01 <
+ OH-

NH;

n^,^. =

0,01 (mol)
NHs + H2O

0,03 <

0,03 (mol)

C2H2

Bao toan d i e n t i c h , cho t a : 2.0,02 + 0,06 = 2.0,04 + x =^ x = 0,02 (mol)

K h o i Itfong chat t a n t r o n g
X = 0,02.24 + 0,06.18 + 0,04.96 + 0,02.35,5 = 6,11 gam
Chon dap a n D.

=>

+ HCl

Zn

muoi

AICI3

Hot
+ Jtl2

ZnCl^

Ta c6: nncipu = 2.n^ = 0,2mol

mmuA

nikimioai +

Al

+ CI2

Zn

mM.6iTN2

mMuoiTNi

Vay

%mFe

Chon dap an B.

12,lgam

0,2

0,4

H2

H2O

0,3

> 0,3 (mol)

0,2 (mol)

3,5 > 2 ^

H6n hop andehit don thiJc

0,05

Chon dap a n B .
B a i 31: So do p h a n iJng:
HaN - (CH2)4 - CH(NH2) - C O O H (x mol)
. N a O H (0,2 mol)

ZnCl^
V-

(Vifadu)

Ta c6:

'CIH3N - (CH2), - C m N H g C l ) - C O O H (x mol)

-i-HCKO^mol)
^

N a C l (0,2 mol)

0,4 = 0,2 + 2.x => x = 0,1 (mol)

=>m

.100% = 13,44%

= nicoj + mj,^o = 0,4.44 + 0,5.18 = 26,6gam

mbinhtang

"Andehit

AICI3

a.(56 + 106,5) - a(56 + 71) = 0,426

a = 0,012 (mol)
0,012.56

muoi '

2CO2 + H2O

B a i 26: Ta c6

= 12,526 - 12,1 = 0,426gam

m -c,., - mfec, = 0,426gam o

T^H,

FeCL (a mol)

Fe (a mol)
Theo de:

niHci -

MgCl^

Mg
T N 2 : K i m loai X

V = 0,6 l i t = 600ml

p h a i chufa H C H O , do h a i andehit la dong dSng ke t i e p , andehit con

l a i la CH3CHO.

FeCL (a mol)

Fe (a mol)

Bao t o a n k h o i lugng, cho t a :

= 0,06mol

Chon dap a n D.

fMgCl^

Mg
Al

-"^OH-

diioc hoan t o a n giong dot chay h o n hop C2H2 va H2 ban dau:

S O ^ va X m o l C I ' .

T N I : K i m loai X

B a i 23: T h a n h p h a n cac nguyen to t r o n g X chi gom C va H . D o t chay X

0,02 (mol)

V a y t r o n g dung dich X chufa 0,02 m o l M g ' " ; 0,06 m o l N H ^ ; 0,04 m o l

B a i 20:

nB3,oH,, =

Chon dap a n B .

P h a n 2: Ba'^ + S O ^ - > BaS04

0,02 <

= 4.0,03 = 0,12mol

4.n^,3.

= 146.0,1 = 14,6gam. Chon dap a n D .

B a i 38: H o n hop etyl isobutyrat, a x i t 2 - m e t y l propanoic, m e t y l butanoat

p h a n ling v d i h o n hop N a O H , K O H (chung la M O H ) tao h 6 n hop
muoi dong p h a n

24

39

54

10

25

40

55

11

26

41

56

12

27

42

57

13

28

43

58

14

29

44

59

15

30

45

60

CgH^COOC^Hs
+ M O H (0,03mol) -> C3H7COOM (0,03mol) + ...

CgH^COOH
[C3H7COOCH,,

+ m^^. + m^. = 3,62gam

= ^ niMuoi =

Chon dap an B .
B a i 49: A m i n o a x i t X: (H2N)R(C00H)
(H2N)nR(C00H) + m N a O H ^ (H2N)R(C00Na)n, + mHzO
a

Hic/ng dan

> a (mol)

B a i 7: Qua r a t nhieu p h a n uTng, Cu nhiidng electron, N*^ n h a n electron

(H2N)nR(C00H) + n H C l -> (C1H3N)R(C00HU + nHsO

a

tao N*^ r o i nhLforng l a i cho oxi trot l a i N*^. Vay suo't qua t r i n h p h a n

> a (mol)

Phucrng phap tSng g i a m k h o i

T a c6:

ufng

iMng.

chi

CO

Cu nhtfdng electron va O2 n h a n electron

Cu ^ Cu^* + 2.e

O2 + 4.e

22m.a = 22,92 - 17,64 => m.a = 0,24

0,2

0,1 -> 0,4

36,5.n.a = 22,02 - 17,64

=> mcu = 12,8 gam.

Vay = i
m
2
B a i 56: M O
0,07

a.n = 0,12

<t-

0,4

B a i 12: Phan i J n g :

+ H2SO4

->

MSO4

^0,07

0,07 (mol)

H2O

M = 64.M la C u

=^ ncuso,x..,o = "cuso, = 0,07mol ^

20"^

Chon dap a n A.

C h i dap a n D la dung,

Ta c6: 0,07.(M + 16) = 5,6

=> X

gidi

17,5 = 0,07.(160 + 18.x)

OH"

Trifdc pir:

0,04Vx

0,03VY

Pir:

0,03VY

0,03VY

Sau p i / :

(0,04Vx - 0,03VY)

(sau p h a n ufng p H = 2

= 5

H2O

a x i t du)

Theo de, t a c6: sau p h a n ufng I H * ] = 0,01M

Chon dap a n A.

D A P A N V A H l / C i N G D A N G I A I M A D E 112

(0,04Vx - 0,03VY) = 0,01.(Vx + V Y )

VY

Cau

DA

Cau

DA

Cau

DA

Cau

DA

16

31

46

17

32

47

18

33

48

Fe + 4 H N O 3 ^ Fe(N03)3 + N O + 2H2O
0,1 < - 0,4

19

34

49

20

35

50

21

36

51

52

53

22

37

23

38

Chon dap a n D.
B a i 14: m d a t gia t r i Idn n h a t k h i Fe dir t r o n g p h a n ufng v d i HNO3 t i e p
tuc p h a n ufng v d i Fe^^ diia he't ve Fe^*
0,1 (mol)

Fe + 2Fe(N03)3 ^ 3Fe(NO:,)2
0,05 f - 0,1
=> mpe = 0,15.56 = 8,4gam
Chon dap a n B.

Cau 16:
Fe
2a
Fe

Fe.2+
2a
+ 2Ag^
2Ag"

Cu
2a (mol)
2Ag

>

Fe^

>

B a i 39:
=> Ami = 16.a (gam)

b
=> Am2 = 80.b (gam)
b
l.b ^
2
Theo de, ta c6: => Ami = Am2
=> a = 5b
B a i 2 0 : Nho tCr tCr hon hap NaaCOg, NaHCOs vao dung dich HCl, phan
iJng lap tufc, dong thofi ca hai muoi tao CO2
NazCOg + 2HC1 ^ 2NaCl + CO2 + H2O
a ->
2.a ^
a (mol)
NaHCOg + HCl
NaCl + CO2 + H2O
b -)
b
->
b (mol)
Tinh tdng so mol, axit thieu.
Ta c6: 2.a + b = 0,45
Mat khac, trong moi giot dung dich muoi phan iJng, deu c6 t i le:
nNa,co, ^ 0.4 _ 2 _

a _ 2

n^aHco,

fa = 0,1
^

|b = 0,25

TrUdc pa:

Pu:

Sau p J :

(a-x)

(a-x)
H2O

+ KOH
du

1
2 "

T a c6: ^ (a - x) + ^ x = 0,1 => a = 0,1 (mol)

=> m = 4,6gam

B a i 4 5 : Chu y: Zn chi khuf duac Cr^^ thanh Cr^*

Zn + 2Cr'* ^ Z n ' * + 2Cr='*

C6H702(OH)3 + 3HNO3

Y (san pham duy nhat)

> C6H702(ON02)3 + 3H2O

0,9.297 = 267,3 (tan)

<-

53,46 (tan)

x = 32,4 (tan)
Chon dap an B.

D A P A N M A D E 113
Cau

DA

Cau

DA

Cau

DA

Cau

DA

16

31

46

17

32

47

H C l (0,2 mol)

18

33

48

K O O C - (CH^)^ - CH(NH)2 - C O O K (0,1 mol)

19

34

49

K C l (0,2 mol)

20

35

50

21

36

51

22

37

52

=> nimuai = 37,2gam

Chon dAp An C.

i (a - x)

H2

162 (tan)

H O O C - (CH2)2 - CH(NH2) - C O O H (0,1 mol)

V(/a

->

Li

= > V = 7,84 l i t .

=> X la este vong. Cong thiJc Y: C^HyOaNa.

2CxHy03Na
Na2C03 + (2x - DCOz + yW
0,05.y
0,1
<0,05 ^ (2x - 1).0,05
0 , 0 5 . ( 2 x - l ) = 0,45
fx = 5
0,05.y = 0,45
[y = 9
m = lOgam.
=> Y: CsHgOsNa ^ X: CsHgOz
Chon dap an A.
B a i 3 0 : Sa do phan iJng:

1
- H2
2

Phan urng vdi Na: C2H5OH

Chon dap an A.
B a i 2 9 : Este dan chufc X + NaOH

C H 3 C H O + H2O

B a i 5 0 : De dan gian, ta tinh todn tren mot m i t xich glucoza

n CO, = 0,35 mol

C 2 H 5 O H + - O2

23

38

53

54

24

39

10

25

40

55

11

26

41

56

12

27

42

57

13

28

43

58

14

29

44

59

15

30

45

60

B a i 12: Ta c6:

+ l.e

FeS ^ Fe^^ + S'^ + 9.e

a
^

S^" + 6.e

Ta

CO

Bai

CO2

+ 20H -> CO^- + H 2 O

CO2

+ OH ^ HCO^
n^,^^, =0,1 (mol)
n,,^^ =0,02 (mol)

15:

= 12,22gam

2Fe(N03)3

Pi/:

Chon dap an D

FczOg + 6NO2 + - O 2

Imol (242gam)

0,5mol (SOgam)

=> 1 mol Fe(N03)3 pu khoi luong rSn giam 162 gam

X <r-

0,75

de cho giam 3,24gam

= 0,02 mol
0,02.242-.100% = 48,4%

6.b

,
'88a + 32b = 6
h^ '
9a + 6b = 0,75

n,,_ = O,l(mol)

1,833 =>Tao hai loai muoi

N^'

0,75 ^

a > 9.a

S (b mol)

_ " N . O H + 2nc,(o),^ ^ 0,22

"co,
0,12

Muoi = ion diiOng + ion am

=> niMuoi

B a i 5: Co the coi FeSa = FeS.S => Hon hop X chi gom <

on

De dang tinh duoc

Hiidng dan gidi

FeS (a mol)

a = 0,05

Chon dap an D.

b = 0,05

B a i 17:

= 0,1 (mol). Chon dap an A.

Al + h6n hop oxit

B a i 8: HCl tan tot trong niidc, lam giam' ap suat trong ong nghiem, dSn
den nadc dang len cao. H 2 S tan it, N2 khong tan. Chon dap an D.

h5n hop X

X + dung dich NaOH

khong thoat khi ^ X khong chiJa Al => trong

phan urng nhiet phan nhom, Al phan iJng het.

2A1 + h6n hop oxit

B a i 10: Sa do
H6n hop oxit + CO -> r^n kim loai + hon hop khi Y fco
CO,

du

Bao toan kho'i lifOng, ta c6:

moxit

+ rnco,,, =

^rin

+ ^co^

=> mco,- mco^ = l,44gam, mSt khac nco, = H C Q , = a (mol)

=> 44.a - 28.a = 1,44 => a = 0,09mol

m, = m^.^o, + mnsn hop oxit = 55,3gam

0,3

A I 2 O 3 + ...

0,15 mol

Trong X chiJa 0,15mol

X

..un..nc.NaOMdu^Y^

AI2O3

my = mx - m^,o^ = 55,3 - 0,15.102 = 40 gam

Chon dap an B.
B a i 19:

Dan Y qua dung dich Ca(0H)2 dii, chi C O 2 phan ufng tao ket tua
C O 2 + Ca(0H)2
=> m = 9gam
Chon dap an D.

CaCOa + H 2 O

J'T^

Cho so do phan ufng: Fe, Cu ^

+ HNOj

Cu=^*
NO

X6t tokn bo quA t r i n h p h a n ilng:

Fe

Fe'* + 3.e

0,2

O2 + 4.e ^

- ^ 0 , 6

Cu ^ Cu^^ + 2.e
0,1

HCOO

20"^

4.a

CH3COO
CH3COO

HIQ^

B a i 35: Theo de a x i t p h a n i J n g het, N a O H c6 the dif, t a k h o n g dung so

mol N a O H de t i n h toan

C3H5 ^

N a O H (c6 the du)

+ H2O

DAP

AN CHI TIET CHO

I. P H A N C H U N G C H O

Bai

gam

TAT

mol)

n C 0 2 + (n + 1 ) H 2 0

C-iH2-202

+ Quy ddi h o n hgp X t h a n h Fe va O

n e n : SSnpe + 16no = 10,44

(1)

+ D L B T E: Snpe = 2no + n^o,

(2)

+ Tif (1) vd ( 2 ) - * n F e = 0,15 m o l

m = 0,5.0,15.160 = 12 gam

a ->

Chon ddp An A.

-> a.(n + 1)
(n-

DCOz

Cdch
(n-

1)H20

a.(n - 1)

mu
.
. ra.n + a ( n - l ) = 0,5
Theo de, t a c6 <^ ,
,
,
,^ ^
[ a ( n + l ) + a ( n - l ) = 0,6

a.(n - 1)

fa = 0,1
1
[n = 3

Vay X la C 3 H 7 O H va Y \k C H 3 C O O H .

B a i 38:
0,1 m o l este X

gidi

+ Theo de mx = 10,44 gam

B a i 37: A n c o l CH2 + 2 O (a mol); a x i t C_iH2n-202 (a

a.n

40):

Cdch 1: Phacfng phap quy doi

CH3COOH

->

C A THi S I N H (40 cu. tCr cu 1 dfen cu

1:

Chon dap d n B.

C h o n ddp An B.

D l f B I D A I H O C K H O I A 2009

Hii&ng ddn

=> nacooH = H H ^ O = O,lmol = * R + 45 = 53 = > R = 8

CH2n.20

-^^^

Bao toan k h o i lUtfng, cho t a :

Vay 2 a x i t la H C O O H

CTPT :CgHiA

M O N H O A H O C M A D E 114

fRCOONa

= "^axit + niNaOH " IHrfn = 1 , 8

Y la C3H5(OH)3

=^ X : o CTPT: C8H12O6 => Chon dap An B.

=> mx = 21,6gam => Chon dap a n B.

^Hfi

R = 41 ( C 3 H 5 )

0,1

HCOO

0,8 = 0,3 + 4.a = a = 0,125 (mol)

RCOOH + N a O H -> rfin

0,2

=> (R + 17.3).0,1 = 9,2

0,3 < - 0 , 1

M a t khac, bao toan k h o i l U d n g cho t a : nix = mpe + m c u +

-> H C O O N a + 2CH3COONa + R ( 0 H ) 3

CHgCOO^^^

N ^ ' + 3.e ^ N^^

0,2

R + 3NaOH

CH3COO

2:

Ap dung cong thufc nhanh: m F e = 0,7.mhjhop(KitFe + 5,6.netraod6i = 8,4 gam

Suy r a : npe = 0,15 m o l

Stfdo:

2Fe
0,15

Fe203
^

0,075

=> m = 0,075.160 = 12 (g)

B a i 2:
+ De t h a y r d n g cAc chat t r o n g h o n hdp A c6 cung cong thiJc dan g i a n

^ ^ a O H ^

0,1 mol HCOONa + 0,2 m o l CHsCOONa + Y

=> Trong X chdTa 3 goc a x i t => X Id este 3 chuTc tao b d i ancol 3 chufc Y
vk ckc a x i t don chufc.

(CH20) + nOa -> nCOz + nHaO

+ Theo phaang t r i n h t r e n : n^o^ = n^o = no^ = 0,1 m o l
+ K h o i laang b i n h tdng chinh la khoi lugng H2O va CO2
Chon dap An A.

m = 6,2 gam.

B a i 7:

B a i 3:
* PhifOng p h a p t h o n g t h a d n g

+ A l , Z n C l a , AICI3, N a A l O a k h o n g p h a i l a c h a t l u d n g t i n h .

T
T
,
+ Til d i e u k i e n : p < n < l , 5 p ^ < p < ( v d i T l a t o n g so h a t )
3,5
o

Chon dap an B .
B a i 8:

T h e o de t a ducfc: 8 < p < 9,33

+ BaCOa, P b S 0 4 l a nhCfng c h a t k e t t i i a n e n c h i c6 d a p a i l A l a p h u h a p .

+ p=8 ^ X : 0 - > n

= 8 - T = 26 ( l o a i )

+ p=9 ^ X : F ^ n

= 1 0 ^ T = 28 (thoa)

C h o n dap a n A .
B a i 9:

* Phifcfng p h a p k i n h n g h i e m

+ De t h a y r & n g A g N O s l a c h a t c6 p h a n tijf k h o i I d n n h a t n e n se c6 so m o l

"28"

V i T < 6 0 (va k h a c 5 8 ) n e n p =

= 9

^3.

_3_

X :F

3
_ 1.
_
n h o n h a t , m a t k h a c no^ = - n^co, = - rinMM, =

C h o n d a p a n C.

_ 1

^ ^AgNo,

Chon dap a n D.

C a u h i n h e l e c t r o n cua C u l a [Ar]3d'''4s' -> Cu^ : [Ar]3d^

B a i 10:

Chon dap a n D .

+ P h o t p h o t r a n g c6 cau t r u e m a n g t i n h t h e p h a n tuf.
+ N i t r o p h o t k a l a h 6 n h a p cua (NH4)2HP04 v a KNO3.

B a i 5:

+ Cacbon m o n o o x i t l a o x i t t r u n g t i n h .

* PhUcfng p h a p t h o n g thiXdng
C a n b a n g phuctog t r i n h hkng

phiicfng p h a p o x i h o a - k h u f

C h o n d a p a n C.
B a i 11:

* Phirong p h a p k i n h n g h i e m
+ A p d u n g c o n g thufc n h a n h :

n^^^Q^

4n^Q

lOnn^o =

+ K i m l o a i c6 d o cufng I6n n h a t l a C r .
22n^^Q

+ Suy r a h e so t o i g i a n cua HNO3 p h a i c h i a h e t cho 22, t r o n g c a

+ K i m l o a i c6 d o cufng n h o n h a t l a Cs.
Chon dap a n B .
B a i 12:

d a p a n c h i c6 d a p a n A l a t h o a m a n .

nAi=

C h o n dap a n A .
Cdch

B a i 6:

N2

0,2 m o l ; n^^^.^o,), = 0.15 m o l ;

Al

3H2

3Fe'^

Al'^+

0,05 < - 0 , 1 5

2NH3

2A1

+ 3Cu^^

0,1

<-0,15

->

Phanufng:

3a

2a

2A1

3Fe'^

CanbSng:

1-a

3-3a

2a

0,05

->

0,075

0,15
2A1^^ + 3 F e
0,075

m = 5 6 . 0 , 0 7 5 + 6 4 . 0 , 1 5 = 13,8 g a m

The tich k h i giam: 2a

C h o n d a p a n C.
Cdch

Chon dap an B.

3Fe'^

2 A f ^ + 3Cu

% N 2 = J 1 0 0 % = 22,22%
4-0,2.2

= 0.15 m o l

0,15

Ban dau:

2a/4 = 1/10 -> a = 0,2

n(,,^03),

1:

Phaong phap 3 dong

T h e o de:

"KNO^

n e n A g N O s l a c h a t t a o r a l u a n g O2 i t n h a t .

B a i 4:

+ Vi

2: P h i r a n g p h a p k h o a n g v a B T E
np^.3,

+ 2np^,. < 3 n ^ , < 3n^,^3,

2n^^,,

+ N e n suy r a : m = 0,15.64 + 56.(0,2-0,15/3 - 0,15.2/3).3/2 = 13,8 g a m

B a i 13:

B a i 17:

= 54
* Cdch 1: Phucfng phap t r u n g b i n h
+ X e m A la k h i X O 2 v i M A = 54
X = 22
Theo de T = n N a o n / n x o , = 1.5 -> P h a n
M A

+ De sau k h i ke't thuc p h a n ufng k h o n g c6 k i m loai t h i so

Fe(N03)3 vCra du hoSc
A p dung D L B T E => b > 2a
uTng

sinh ra 2 muoi

NaHXOg va NazXOg
X O 2 + NaOH
X

+ V i de khong noi mi6c voi trong diT nen k h i dan san pham chay qua
binh diing dung dich nLfdc voi trong, ket thuc phan utog se sinh 2 muoi

X O 2 + 2 N a O H ^ NazXOa + H 2 O
2y

T a CO he p t

fx

+y = a

[x

+ 2y = 1,5a

Ta c6: m^o^ + m^o = 27,93 - 5,586 = 22,344 gam

^
,
x = y = 0,5 amol

m = 0,5a.94 + 0 , 5 a . l l 6 = 105a
Chon dap a n A.
* Cdch

Chon ddp a n C.
B a i 18:

NaHXOa
X

Hay 44nc + 9H = 22,344

(1)

Theo de: 12nc + na = 4,872

(2)

TCr (1) va (2) nc = 0,336; n = 0,84

A p dung cong thiJc n h a n h : m = (54 + 18).a + 22.1,5a = 105a

ncuisinh ra) = 0,02

B a i 14:
* PhUcfng phap k i n h n g h i $ m n^j^. = 0,6 mol, n^^^o^ = 0,1 m o l
+ T H l : nco, = ne^co, = O , l m o l ^ V = 2,24 Ht
= n.

H B ^ C O , = 0,5

mol

->

= 11,2

mol,

CUSO4

n K h i = 0,015

+ 2NaCl ^

a mol
+ Vi

Cu +

>

n K h i = 0,015

C4H10

mol

nen

b mol

+ THl:

nNaOH(i)

= 3nkft tua = 0,3 m o l

(*)

+ TH2:

nNaOH(2)

= 4.n^,,. -

(**)

nk^ttoa

= 0,4 m o l

+ TCr (*) \k (**) suy r a n^,,. = 0,125 m o l

m = 0,5.0,125.342 = 21,375 gam

Chon dap d n A .

CI2

+ Na2S04

CUSO4

dir

+ H2SO4

->

+^02

0,5b

. , . fa + b - 0,02
+ Theo de t a c6 he <^
[a + 0,5b = 0,015
=> a = b = O.Olmol -> n^^, = 0,02mol ^

[ H " ] = 0,01-> p H = 2

Chon dap a n C.
B a i 20:

C a u 16:
Phuang phdp tSng g i a m k h o i lifdng
1
1 9,6.50
^,
,
n^. = no = .
= 0 , 1 mol
3
3 100.16
+ So do hop thllc: 2NO3 (trong mu6i) ^
(trong oxit)
+ Theo qui \Ac
t^c tang
tS] giam ^

mol

a mol

C U S O 4 + H 2 O ^.Cu

B a i 15:

Chon dap d n B.

= 4 : 10 ->

lit

Chon dap d n B.

nH

B a i 19:

De t h a y p h a n iJng s i n h 2 m u o i

nco,

nc :

Chon dap a n C.

2:

+ TH2:

mol

m = 50 - - . n^^. .(2.62 - 16) = 44,6 gam

2
^

* Phaang phap n h a m
+ nnci = 0,15 m o l ,
+

n^^^co^ = n H c i -

+ ^n.uco, =

nco,
nco,

n^^co, +

Chon dap a n B.

= 0,045 m o l ,

nn^co^

= 0,105 mol ^

"^^co,

"

HHCI

= 0,15 m o l

[NajCOa] = 0 , 2 I M

= 0,09 m o l

[NaHCOg] = 0,18M

B a i 26:

B a i 21:
Ta CO p t pu: 3Cu + 8H* + 2 NO'

+ A p dung phuong phap t a n g giam k h o i liTOng:

SCu^* + 2NO + 4H2O

m^usi = 2,46 + 22.0,04 = 3,34 gam

ncu = 0,05 m o l , n . = 0,12 m o l , n^^ = 0,08 m o l

+ Dd t h a y

het

triTdc

n ^ ; o - =

-> ncu(phan .jg)

Chon dap d n D.

0 12 3
-^-z^ = 0.045 m o l

B a i 27:

(0,08 - 0,12/4) = 0,05 m o l

' Axeton, benzen, xiclobutan k h o n g l a m m a t mau dung dich thuoc t i m

NO;, (tao muoi)

+ Suy r a m^uoi = 0,045.64 + 0,05.62 + 0,02.96 = 7,9 gam

du a n h i e t do cao.

Chon dap a n A .

Chon dap a n A .
B a i 28:

B a i 22:

n^o^ = 0,08 mol, n,,^^ - 0,064 m o l

+ H C l la chat oxi hoa k h i va chi k h i phan iJng s i n h H2.

Chon dap a n C.
C a u 23:

S6H

* Phuong phap loai trCr

+ A ) Sai v i c6 muoi s&t t h i dung dich X p h a i c6 muoi k e m

Chon dap a n C.

+ B) Sai v i c6 muoi dong t h i dung dich X phai c6 muoi sSt

+ C) Sai v i CO s i n h muoi sat III t h i dung dich X phai c6 muoi dong

B a i 29:
So m g K O H can de t r u n g hoa 10 k g chat beo A l a :

* Phiiong phap k i n h n g h i e m
khuf

10000.7 = 70000 m g = 0,07 k g

de t h a y X gom: Mg(N03)2, Zn(N03)2,

Suy r a N a O H can de t r u n g hoa chat beo A l a :

Fe(N03)2
Chon dap a n D.

^
56

B a i 24:
mp^ou = 6,4.71,875/100 = 4,6 gam
mnudc = 1,8 gam

2.0,064

D l thay: 10 + 0,15.40 = 16 -> E la este vong -> Chon dap a n C. la

phu hop

Nguyen tic: KhOf m a n h gap oxi-hoa m a n h

+ Dung true o x i - hoa

2.n^o

n^aac =

= 0,00125 (Kmol)

N a O H can dung de phan iJng v d i 10 k g A l a :

0,1 m o l

M 2 0 - ^ =

nn2 = 0,125 m o l

40

46

1000

0,035 (Kmol)

A p dung d i n h luat bao toan k h o i lUgfng t a c6

Mruau =
n = 92.n/3 ( v d i n la so n h o m chuTc OH)

0,125.2 - 0,1
D I t h a y A: CsHsCOIDa

n i A + m N a O H ( p h a n iJiig v6i A) = T^xh phbng + IHgiixerol +

m^aph6ng

= 10 + 0,035.40 - O,0M25.18 - 92.1/3.(0,035 - 0,00125)

Chon dap a n C.

= 10,3425 gam
Chon dap a n A .

B a i 25:
So dong p h a n c a c chat c6 cung so C nhiing d i cung cac nguyen tuf c6
so hoa t r i Idn hon t h i c6 so dong phan nhieu h o n .
Vi C I C O hoa t r i I, O c6 hoa t h i I I , N c6 hoa t r i I I I n e n s o liTOng
phan

cua

C3H7CI

Chon dap a n A .

niH20

< CaHgO <

C3H9N.

dong

B a i 30:
+ Glu CO 2 n h o m cacboxyl va 1 n h o m amino.
+ L y s CO 1 n h o m cacboxyl va 2 n h o m amino.
Chon dap a n B.

B a i 37:

B a i 31:
M =

^^'^

^ 49,67 -> dap a n B la phu hap

36^5

PhU0ng phap ducfng cheo + phucfng phap 3 d6ng

+ Theo de dx/He = 3,75 n e n :

Chon dap a n B .

4.3,75-2

B a i 32:

H2

M a t do electron cang cao t h i t i n h bazcf cang m a n h .

Chon dap a n A .

Ban dau:

Con l a i :

Luu y:
+ 1 m o l mantozor t i e n h a n h p h a n uTng t r a n g bac s i n h 2 m o l A g

nmantozo = 0,1

mol

+ Suy r a : m A g = 108.(0,1.0,5.2 + 0,1.0,5.4) = 32,4 gam

C2H4

= 1 -> n,,^ - n^y,^ = x(mol)

->

C2H6

x
x.H%

x.H%.

x.(l-H%) x.(l-H%)

x.H%

+ M a t khac: dy/He = 5 n e n :

x.(l-H%).2 + x.(l-H%).28

+ 1 m o l mantozot thuy p h a n hoan toan sau do l a y dung dich t h u dxiac

t i e n h a n h p h a n ufng t r a n g bac sinh 4 m o l A g .

Phan urng: x . H %

B a i 33:

x.H%.30

x.(2 - H % )

= 5.4

^ H % - 50%
* Phuctng phap B T K L + t i i chon

liTOng

chat

+ D L B T K L : nx.4.3,75 = nY.4.5 -> 3nx = 4nY

Chon dap a n B.
B a i 34:

-> Chon nx = 4 mol va ny = 3 m o l

nButa-l,3-clien
nstiren =

4.3,75-28

n.

= nBrom = 0,125

mol

45,75-0,125.54
^07=^^1
= 0,375 m o l
104

'

Ti le m a t x i c h butadien va stiren t r o n g cao su b u n a - S la

T=i?5,1=1:3
0,375

Chon dap a n A .
B a i 35:
A x e t i l e n , m e t y l axetat, axeton k h o n g t h a m gia p h a n i l n g t r a n g guang.
Chon dap a n B.
B a i 36:
+ Phenol + b r o m - > k e t tua t r ^ n g
+ Stiren + b r o m -> m a t m a u dung dich b r o m
+ Ancol benzylic + b r o m - > k h o n g c6 h i e n tirong
Chon dap d n A .

+ So mol k h i g i a m c h i n h la so m o l H2 p h a n ufng
+ Suf dung dudng cheo: n Hi

ban dau ~

^Cjll^

ban dau ~

nIIj

p h a n ijfng

= 1 mol

-> H % = - = 50%
2
Chon dap a n B.
B a i 38:
+ CH3OH + C O - ^ C H a C O O H
+ C2H5OH + O2
+ 2CH3CHO +O2

> CH3COOH + H2O

2CH3COOH

Chon dap a n D .
B a i 39:
CH4, C2H5OH, CgHeCbenzen) k h o n g phan iJng dugc v d i nudc b r o m .
Chon dap a n B.

B a i 44:

B a i 40:

PhUdng phap tif chon laong chat

CO2 : H 2 O = 11 : 12 ^

chon

n,,o,^

= 11 mol va

n^o

Phuang phap thong thudng (Tinh theo phudng trinh)

2CrCl3 + I B N a O H + 3CI2 ^

= 12 m o l

0,01 mol ^ 0 , 0 8 - ^ 0 , 0 1 5

Suy r a nx = 1 2 - 1 1 = 1 m o l
V i 3 chat CO so mol bkng nhau nen so nguyen tuf H trong m6i chat la

-If-

Suy r a m N a O H = 3,2 gam va

3ncK;i3 =

+ BTNT:

II. PHAN R I ^ N G [10 cau]: Thi sinh chi duoc l^m mpt trong hal phSn
(phSn A hoac B)
T h e o chvtdng t r i n h C h u a n (10 c a u , txi c a u 41 d e n c a u 50)

m^,,^ = 1,065

gam

Phirong phap k i n h n g h i e m (BTE + B T N T )

+ BTE:

Chon dap a n C.

2Na2Cr04 + 12NaCl + 8 H 2 O

2nc,^

nNaOH = ^n^^^cro,

n^^ = 0,015
+ nNaci

mol

8nc,ci3

->

m^,^ = 1,065

= 0,08 mol ->

gam

mNaon =

3,2 gam

Chon dap a n A .
B a i 45:
Cho m o i mau thuf k i m loai tac dung vdi m 5 i o n g n g h i e m diTng dung
dich

H2SO4

loang, ong n g h i e m c6 tao k e t t u a trSng t h i k i m loai cho

vao la Ba, tiep tuc cho Ba dif vao v i t r o n g dung dich c6 niTdc n e n Ba

B a i 41:
Tinh bazo cang m a n h t h i p H cang cao v i t i n h bazo cua
N a O H > Na2C03 > CHgCOONa nen pHa < p H i < p H 2
Chon dap a n A .

se tac dung vdi nUdc tao Ba(0H)2, l a y dung dich t h u duac l a m thuoc
thuf, cho tCi tii cho den d i i vao 3 ong n g h i e m con l a i :
+ Ong n g h i e m nao chi tao k e t tua t r a n g t h i k i m loai cho vao l a M g .
+ Ong n g h i e m nao tao k e t t i j a t r ^ r i g sau do ke't t u a t a n h e t t h i k i m

B a i 42:

loai cho vao la Z n .

PhUcfng phap bao toan k h o i liTcfng

+ n K O H = 0,3

mol v i

- 88,2

(le) n e n K O H

0,3
+ mH^o = 13,8 + 16,8 - 26,46 = 4,14 gam
-> n A = nn^o = ^ = 0 , 2 3 m o l
SuyraM.=

du

+ Ong n g h i e m nao tao k e t tua mau luc n h a t sau do chuyen sang mau
nau do t h i k i m loai cho vao la Fe.
Chon dap a n B.
B a i 46:
* Phiicfng phap t h o n g thiicJng
+ D a t cong thu-c A la CnH2n+20x
CH2n.20x + ( 6 " + 2 - 2x ^

i||=60

Chon dap a n C.
B a i 43:
+ A ) Sal v i t i n h oxi hoa cua Fe^^ >Cu^^
+ B) Sal v i t i n h khijf cua Fe > N i
+ D ) Sai v i t i n h oxi hoa cua Fe^^ > 12Chon dap a n C.

+ Theo de:

(^ILtlz^)
4

= 3,5 -> 6n - 2x = 12 ^

* Phifofng phdp k i n h n g h i e m
Vi ^
Chon dap

= 3,5 -> So C = So O = 3
C.

_^ ^^Q^ ^ ( n + l ) H 2 0

n = 3 va x = 3

B a i 52:

B a i 47:
+ Tii gia t h i e t suy ra cong thiJc cau tao cua X la: CH3NH3NO3
+ RSn gom: N a O H diT (0,1 mol) va NaNOa (0,1 mol)

240

B a i 53:

B a i 48:
3Cu + 8H^ + 2NO3 -> 3Cu'^ + 2 N 0 + 4H2O
du va Cu phan ufng het: n.

= 1 - 0,3/3.8 = 0,2 mol

Chon dap an C.
B a i 54:

+ De ket tua h e t ion Cu^* t h i

= n.

= 0,3
+ V i nAg/nx = 3 va X gom h a i andehit no, dcfn chiic nen X p h a i chufa
H C H O m a t khac la hai andehit ke tiep nhau t r o n g day dong dang
nen chi c6 dap an C la phu hop.
nAg

ncu = 0,3 m o l , n,,, = I m o l , n^^^. = 0,5 mol

+ 2ncu = 0,2 + 2.0,3 = 0,8 mol ->V = 800 m l

Ag, A u k h o n g tac dung v d i dung dich FeCla.

Chon ddp an B.

B a i 49:

B a i 55:

+ So m o l CO2:

n^^o^ = netyiic = 46.0,8/46 = 0,8 mol

mu6-i

Cdch

1: Dua vao phtrang t r i n h

n(,,^ = 0,15 mol

= m^,^,o, = 106.0,8 = 84,8 gam

KzCraOT + 14HC1 - ) 2 C r C l 3 + 2KC1 + 3CI2 + 7H2O *

Chon dap an B.

0,05 mol

B a i 50:
n c , H , = 0.15

18

^5%

Chon dap an B.

Chon dap an B.

nNaOH

Suy ra: ^-^^ + ^:(LlC%) ^ U a

60

m = 0,1.40 + 0,1.85 = 12,5 gam

+ De thay

H2 sinh ra do N a p h a n iJng v d i C H 3 C O O H v ^ nir<Jc t r o n g dung dich

0,7 m o l

<-

0,15 m o l

Cdch 2: Phuong phap B T E + B T N T

mol

+ B T E : 6nK^cr,o, = 2nc,^

+ H o n hap A gom 0,09 mol C H 3 C H O va 0,06 mol C2H2 d\i

+ Ran gom A g va C2Ag2

+ B T N T : nci =

= O'O^ mol

nK^crA =

3ncK:,, + n K c i +

2nc,^ = Hn^^crA = 0,7 m o l

Chon dap an A .

m = 108.2.0,09 + 240.0,06 = 33,84 gam

Cau

Chon dap an B.

56:

Cdch

1: Phuong phap B T D T + B T N T + BTE

T h e o chifcfng t r i n h N a n g cao (10 c a u , t ^ c a u 51 d e n c a u 60)

+ Goi a la so m o l CugS. Dung dich X chufa cac i o n : Fe^^, Cu^*, S O / "

B a i 51:

+ B T D T : 3.n^,^. + 2n^. = 2 n ^ . .

+ PhiTdng phap 3 dong: S02(k) + N02(k) ^ S03(k) + NO(k)

+ B T N T : 3.0,24 + 2.2a = 2.(2.0,24 + a) ^ . a = 0,12 mol

Ban dau:

0,11

0,1

0,07

Phan iJng:

0,08

0,08

0,08

0,08

Chon dap an B.

Can b&ng:

0,03

0,02

0,15

0,08

Cdch

Suy ra Kc =
Chon dap an B.

0,08.0,15 _
0,03.0,02

+ BTE:15. 0,24 + 0,12. 10 = nNo.3

nNo = 1,6 m o l ^

V = 35,84 l i t

2:

+ A p dung cong thiJc n h a n h n^^

g = -^F^S^

0,12 (mol)

+ B T E : 15.0,24 + 0,12.10 = nNo.3 -> n N o = 1,6 m o l ^

V = 35,84 l i t

D A P A N MA D E 115

B a i 57:

Cau

DA

Cau

DA

Cau

DA

Cau

DA

+ Nhom I : Lam mat mau dung dich brom gom S O 2 va H2S

16

31

46

+ Nhom I I : Khong lam mat mau dung dich brom gom C 0 2 v a N2

17

32

47

18

33

48

19

34

49

20

35

50

21

36

51

22

37

52

23

38

53

24

39

54

10

25

40

55

11

26

41

56

12

27

42

57

13

28

43

58

14

29

44

59

15

30

45

60

* Dung nifdc brom ta phan biet dUflc 2 nhom:

* Dung Ca(0H)2 ta nhan biet dirge

SO2

va

CO2

c6 xuat hien ket tua t r i n g

Chon dap an C.
B a i 58:
* Phirong phap thong thiTdng
Dat cong thiJc A la

CnH2n+20x

CH2.20. ^ ( 6 n + 2 - 2 x ^ Q ^ _^ ^ ^ ^ ^ ^ ( n + l ) H 2 0

+ Theo de: ( 6" + 2 - 2x ^ = 2,5 -> 6n - 2x = 8 ^ n = 2 va x = 2

4
* Phirong phap kinh nghiem
Vi ^

= 2,5 -> So C = So O = 2

"A

Chon dap an B.
C a u 59:
* PhiTdng phap kinh nghiem
+ Ma.i = 3ig8_2o = 62,5
36,5
+ Goi X la amin c6 phan tijf khoi nho nhat. Theo gia thiet ta c6
X + 10.(X + 14) + 5.(X + 28) = 62,5.(1 + 10 + 5) -> X = 45
+ Suy ra 3 amin tren la:

C 2 H 7 N , C3H9N, C4H11N

+ Ap dung cong thufc tinh so dong phan: T = 2 ^ 2^ + 2^ = 14

Chon dap an B.

Hiidng dan

B a i 1:
2CH3CH(NH3Cl)COOH + 2Ba(OH)2 ^ [CH3CH(NH2)COO]2Ba + BaCl2 + 4 H 2 O
0,1
->
0,1
->
0,2
Phan ling chi tao thanh H 2 O la chat khi c6 can t h i bay hoti, cac chat
con lai (san pham va bazcf dif) deu of dang r ^ n
^

mrin = m^^uiu

+ m,,oH),-

m^Oj = 15 - 5,1 = 9,9 gam -> n^o^ = 0,225 mol

Suy ra m = 0,5.0,225.180.100/90 = 22,5 gam
Chon dap an B.

^..,0

= 12,55 + 0,15.171 - 0,2.18 = 34,6gam

Chon dap an C.
B a i 4: CJiyO ^

B a i 60:

gidi

Theo d l : ^

niH^o

XCO2

+ ^H^O
2

n^n = Imol

9y

=>

= i => X chi CO the' la C H 4 O

4

Ta CO- ^^^^ =

= 1,2 => Phan ufng tao hai loai muoi

Va n,,co, = ^on- ' ^ c o , = 0.2mol ^

HIRT

= 39,4gam

D i dang tinh duoc

B a i 5: R - C H 2 - O H + - O ^
1

->

1 ->

<-

= 0,1 mol

m d u n g dich giam =1,6

n A n c o i ban d i u >

nAncoipi/

dirdng cheo, de dang t i m difgfc

M(Fe, Cu)

M"^ + n.e

nwo,

=0.1

N + 3.e

a.n

0,45 <- 0,15

+4

N + l.e -> N
M " V n . NO-3 ->M(N03)

0,1

<r-

0,1

a.n
Muo.

= m^. +

= 11,6 + a.n.62 = 45,7 gam

5KC1 + KCIO3 + SHzO

^
^

0,36

lO.a <- a
8.a < a

IS.a = 0,36

a = 0,02

V = (0,02 + 0,02).22,4 = 0,896 lit

Chon dap an B.
B a i 14: Sof do 17,4 gam

Al

Al(amol)

Af^

Fe,03

Fe^^

Al^^ + 3.e

=> 3.a = 0,6

3.a

N + l.e -> N
0,6 ^

0,6

a = 0,2 (mol)
17 4 - 5 4

0,25 (mol)

Trong hon hgfp dau mAi = 5,4 gam =^ %m^,^^o^ = '

17,4

0,25 (mol)

= 35,875 gam.

Chon dap an B.

->

KCl + AgNOa ^ AgCl + KNO3

m^gci

mNOg

A.

B a i 8: 3CI2 + 6 K 0 H

0,25

0,12

2N'^ + lO.e -> N2

Toan bo qua t r i n h phan ufng, chi c6 A l nhudng electron va N""^ nhan

electron.

Bao toan electron => a.n = 0,55(mol)

m

Al ^ A P ^ + 3.e

2N"^ + 8.e ^ N2O

+5

0,15

=> m = 15,45 - 1,65 = 13,8 gam.

B a i 13: Bang quy t^c dJcfng cheo, de dang tinh diioc n^,^ ^ n^^o

B a i 7: Bang each dat an, giai he phi/cfng t r i n h hoac dung phUofng phap

Chon dap An

MCO3 + 2HC1 ^ MCI2 + H2O + CO2

(M + 60) gam ^ (M + 71) gam ^ 22,4 lit
Theo phUOng trinh, cu" giai phong 22,4 lit khi CO2 thi khoi luong muoi
se tang 11 gam.
Theo de Vco, = 3,36 lit
Am = 1,65 gam
Chon dap an B.

Chon dap an A.

gam

B a i 11:

Mx < 40 =^ A chi c6 the la CH3OH

->

= 0,01 mol

Chon dap an D.

1 (mol)

1,6 (gam)

Mat khac, phan ufng con ancol dir =>

-> 0,1

nc^ = 0,02 mol; IIQ^

^"""^ > R-CHO + H2O

Theo pt Imol ancol phan ufng, khoi liigfng hon hgtp tang 16(gam)
Theo de

Cu + - O2 + H2SO4

CUSO4 + H2O -^s^

Chon dap an C.

Puf:

B a i 10: Khoi lugng dung dich giam do Cu ket tiia va O2 thoat ra khoi
dung dich.

Chon dap an D.
B a i 15: n^,c,^ = 0,l(mol) ^ n^,^om,c^^A = 0,1 (mol)
Theo de, n A u o m , = 0,08 (mol) < 0,1 => Co hai trUcrng hop

'

= 68,97%

T H 1:

AICI3

+ 3NaOH
Al(OH)3 + 3NaCl
0,24 <- 0,08

HNaOH = 0,24

(mol)

=> a = 1,2

B a i 44: Y gom hai kim loai la Cu va F e du

Mg + CUSO4 -> MgS04 + Cu

T H 2: A I C I 3 het (ket tua cUc dai roi tan

bdt)

n^aOH = 0.3

+ 0.02

= 0,32

=> a =

b ->

Cu

0,05

0,025 (mol)

3Cu

8H* +

0,225

2Fe'"

1,6M

+ Cu^^

2NO3 ^

3Cu^^ + 2 N 0

0,15

<r-

+ 4H2O

0,15(mol)

=> mcu = 0,25.64 = 16gam; V = 3,36 l i t

Chon dap an A.
B a i 30: 3 amin la dong phan: C3H9N
C3H9N

+ HCl ^

0,2
=> nimuoi

C3H10NCI

^
= 19,1 gam

0,2
Chon dap an A.

B a i 39: X chufa 1 nguyen tuf N trong phan

^ ^

D i dang bien luan duoc cong thufc phan tuf X la

cau tao H 2 N - C H 2 - C O O - C H 3 .
H 2 N - C H 2 - C O O - C H 3 + NaOH
CH3OH
HCHO
0,0375

= 15,73% =^
C2H7O2N,

^^gNO,/NH, ^

0,15

n^ = nAncoi = HAndehit = 0,0375 (mol)

=> m = 3,3375 gam
Chon dap an B.

- 89

cong thiJc

H2N-CH2-COONa + C H 3 O H

) HCHO

=> A m i

= 64.a - 24.a = 40.a

=>

= 64.b - 56.b = 8.b

FeS04 + Cu
->

Am2

'40.a + 8.b = 18,4 - 13,6

Ta c6: a + b = 0,2

Chon dap an A.
C a u 16: FeO
> Fe(N03)3
0,05
^
0,05 (mol)
Them H 2 S O 4 loang, du. Dung dich chufa cac tac nhan phan ufng Cu 1^
Fe'^ va
+ NO"
2Fe'^

>

Fe + CUSO4

AICI3 + 3NaOH ^ A1(0H)3 + 3NaCl

0,1 ^
0,3 ^
0,1 (mol)
Tiep tuc NaOH3 tan bdt 0,02 mol, con lai 0,08 mol
A1(0H)3 + NaOH
Na[Al(0H)4]
0,02
0,02 (mol)
=>

fa = 0,1
l b = 0,l

=> Trong hon hop dau, m M g = 0,1.24 = 2,4 gam => mpe = 11,2 gam
(khong dung b = 0,1 mol la lu'Ong sAt phan ufng < sSt ban dau, vi
sat du).
Chon dap an B.
B a i 56: Cr(0H)3 tuong tu A1(0H)3, tufc la c6 hai trucfng hop. Xem lai
each giai cau 15.
DAP A N MA D E 116
Cau

DA

Cau

DA

Cau

DA

Cau

DA

16

31

46

17

32

47

18

33

48

19

34

49

20

35

50

21

36

51

22

37

52

23

38

53

24

39

54

10

25

40

55

11

26

41

56

12

27

42

57

13

28

43

58

14

29

44

59

15

30

45

60

Hit&ng dan

B a i 17: H a i este dem dot chay la dong d^ng l i e n tiep

giai

B a i 9: A l , Z n phan ufng v d i axit. A l , Zn la chat khuf,

C . H ^ O ^ - ^ ^ x C O ^ + ^ H 2 0 . G i a i dugc

(ciia axit) la chat

oxi hoa. A l , Zn phan ufng v d i dung dich bazcf. A l , Z n la chat khuf,

(cQa niJdc) la chat oxi hoa
=^ m gam h 5 n hdp A l , Zn

B a i 18: 2 H C 0 - ^

B a i 15:

0,05

100ml X

(I
a mol
2

AICI3 (a mol)
>

h mol
2

<

f A1(0H),3 (a

>

F e d , (b mol)

mol)

Fe(OH), (b mol)

Ag (b mol)

[FeCl^ (b mol)

"c- +

H^O + CO^" + CO^ t

0,025 mol

= 0,03 > 0,025, tjjfc la C O , ' khong ket tua het dugc Ca^^ va Mg^"

i^Mg^-

=> Sau k h i dun nong dung dich v a n con Ca^"^. Mg^*, CI"...

B a i 22: Bao toan nguyen to Fe:

nKe/FHNo^),

=> (3.a +2.b).143,5 + 108.b = 82,55 (**)

mKo/Ke.o,

-IM

=> C,^..,

C a u 16:
P h a n 2: 0,06 mol andehit dan chufc ^Mio,!NMi!l^0,16 mol A g
2,67 =>Hon hap andehit gom

n Andehit
De dang lap diioc he phiicfng t r i n h

Ph^nl:

f H C H O (amol)
n
C^HyO (bmol)

4.a + 2.b = 0,16

b = 0,04

CO2(0,02 + 0,04.x) mol

^
H2O(0,02 + 0,02.y) mol

^ I 0,02 + 0,02.y = 0,1

y = 4

X gom H C H O va C3H4O.
Chon dap a n A.

= 0,075 mol

= 4,2 gam ^ mo/p,_o, = 1-6 gam

0,1

Chon dap a n C.
B a i 23: Ta c6:

n, = n,^ - n , , , , = 0,15 - 0,1 = 0,05 mol

A n k i n + 2Br2

C' X H
y O(bmol)
a - 0,02

x = 3

no

HCHO(amol)

a + b = 0,06

J0,02 + 0,04.x = 0,14

=npe,No,),

x^rv^MZ5 = 3 ^
y

Chon dap a n A.

Chon A

Chon dap an A.
AgCl (3.a + 2.b) mol

1*'^','

TCr (*) va (**)=> 1^ :

=9

=> T h u duoc nudc cufng v i n h cufu.

51.a + 80.b = 13,1 (*)

lOOml X

5,6 l i t H2.

2m gam h 6 n hop A l , Zn -> 11,2 l i t H2.

AI2O3

C,,H,0,

hon hop este

x = 5,5

ni3r,

= 2n ^= 0,1 ^

mi3,^

= 16gam

Chon dap an B.
B a i 26:
0,92 gam X

C2H2(a mol)
CH.,CHO(b mol)

26.a + 44.b = 0,92

^ W N H ^

5^64 gam

Ja = 0,01

240.a + 2.108.b = 5,64 ^ j b - 0,015

C2H, + 2H,
C H 3 C H O + H2

n,| = 2.0,01 + 0,015 = 0,035mol => Chon dap a n C.

CgAggCa mol)
Ag(2b mol)

B a i 27: Hon hop Fe, FeO, FezOg

Fe304 o Fe.Oy (a mol)

FexOy ^ xFe'" + yO'^ + (3x -

->

a.x

+5

2y).e

N + l.e
0,2

a.(3x - 2y)

+1

0,2

a.(3x - 2y) = 0,2

Ja.x = 0,6
^ |a.x.(56 + 62.3) = 145,2 ^ ja.y = 0,8
n^Fe.o,

CH3COOH

Trade

0,15

Phan l i :

CH3COO- +

0,1
->

Can bkng: (0,15 - x)

Do

(0,1 + x)

Ta co: K. = ^^'UCll,COOJ_
[CH3COOH]

= a.(56x +16y) = 46,4 gam

Chon dap an C.
B a i 29:

B a i 51:

X = 0,1 ^ 0,1 - X 0,1

^Mi^
(0,15-x)
1,75.10-'

FeCOg + 4HNO3 ^ Fe(N03)3 + NO2 + CO2 + 2H2O

=:> X = 2,625.10"'

4,48 l i t hon hgp k h i gom CO2 va NO2 vdi t i le mol 1 : 1

= n^o,

0,1 mol =>

np,co, =

0.1

^ m^^co, = H . ^ gam

Chon dap an C.
B a i 34:
Phan 1: 0,15 mol X - ^

<-

MCln + 4NaOH ^ Na4-[M(OH)4] + nNaCl

4.a

=> a = 0,135 mol =i> M = 52

Chon dap an C.

2 R - 0 H ^ R-O-R + H2O
0,3 (mol)

0,3(2R + 16) = 19,4 => R = 24,33 ^ hai ancol la

B a i 56:
CH3OH
C2H5OH

n^^o,

= 0,1 mol

Bao toan khoi li/gng, cho ta:

2A1 + Cr203

Chon dap an A.
B a i 49: C2H7O2N + NaOH

muoi + k h i Y

Y CO tinh b a z O => Y la amin hoSc amoniac. Y chay tao san pham lam
due nitdc voi trong => Y la amin
X la muoi cua amin, chi c6 the la: HCOONH3CH3
HCOONH3CH3 + NaOH ^
-

m = 0,2.68 = 13,6 (gam)

Chon dap an C.

MC1

B a i 48: Dat chung hai ancol la R - O H

0,2

B a i 55: M + - C I 2
2
X la axit da chufc,

Chon dap an D.

0,3

Chon dap an A.

0,45 mol CO2 => X c6 3 C

Phan 2: 0,15 mol X phan ufng > 0,2mol NaOH

cac dap an chi c6 axit 2 chiJc
X la axit 2 chiJc.

pH = 4,58

HCOONa + CH3NH2 + H2O

0,2(mol)

mAi = mx -

mcr^o,

= 8,1 gam

nM

= 0,3 mol

AI2O3 + 2Cr

De dang tinh dtfoc, sau phan ufng, X chufa: 0,1 mol A l (di/), O,lmol
AI2O3, 0,2 mol Cr

Al - i l i ^ U ^ H ,
2
=> V = 0,35 . 22,4 = 7,84 l i t
Chon dap ^ n A.

Cr - ^ H ^

Ldl NOI DAU

Phan 1. CAC DANG BAI TAP AP OgNG CACH TINH NHANH

Dang 1 : K I M LOAI T A G D U N G V6l A X I T

Dang 2 : O X I T K I M LOAI T A G D U N G VOl A X I T HGI, H2SO4 (loang)

17

Dang 3: K H L / G A G O X I T - K I M LOAI B A N G (GO, G, H2, Al)

20

Dang 4 : K I M LOAI T A G D U N G VOi D U N G DjGH MUOl

28

Dang 5. GO2, SO2TAG D U N G V 6 l D U N G D]GH K I E M

35

MOT S O HOP GHAT QUAN TRONG GUA

GANXl

Dang 6. MUOl G A G B O N A T T A G D U N G VOl D U N G D I G H HGI, H2SO4 loang

41
49

Dang 7. K I M LOAI S A T Bl 0X1 H O A T H A N H H O N H O P (Fe, FeO, Fe203, Fe304) ....51

D A N G MUOl N H O M T A G D U N G VOl B A Z O

54

GAG D A N G B A I T A P G H A T H D U G O DEM D O T

61

GAG D A N G B A I T O A N T l ^ G H O N L U O N G G H A T

67

D A N G BAI T A P OIEN PHAN

77

G A G G O N G T H Q G TI'NH N H A N H

92

Phan 2. MpT SO PHaONG PHAP GIAI NHANH BAI TAP TRAC NGHIf M
AP DUNG CAC D!NH LUAT

93

M O T SO BAI T A P V A N D U N G

100

M O T S O B A I T A P VAN DUNG

112

Phan 3. GI6I THIEU MPT SO Bp DE PN THI THPT VA DE THI

CAP DANG- DAI HpC
MyC LyC

164
272