MONIKA DIXIT (934)

ASSIGNMENT=

TO PLOT GRAPHS IN EXCEL.

QUES 1: Using EXCEl, calculate the pressure of nitrogen gas at three different
temperatures
250K, 350K and 400K as a function of height using the barometric formula
P=PoExp(-Mgh/RT)
Also plot the ratio of P/Po versus the height of the column at these
temperatures 250K, 350K
and 400K. Po is the pressure of the gas at the bottom of the column. Altitude
ranges from
0 to 1000m
Po=
101325Pa
R= 8.314 Pa M3k-1mol-1

TABLE
S.
No.
1

Heig
ht
0

100

200

300

400

500

600

700

800

10

900

11

1000

P250K
101325
99996.1
2
98684.6
6
97390.4
96113.1
2
94852.5
9
93608.5
9
92380.9
1
91169.3
3
89973.6
4
88793.6
3

P350K
101325
100374
99431.9
4
98498.7
2
97574.2
5
96658.4
7
95751.2
7
94852.5
9
93962.3
5
93080.4
6
92206.8
5

P400K
101325
100492.
4
99666.6
3
98847.6
5
98035.4
97229.8
2
96430.8
6
95638.4
7
94852.5
9
94073.1
7
93300.1
5

P250K/Po
1
0.98688
5
0.97394
2
0.96116
9
0.94856
3
0.93612
2
0.92384
5
0.91172
9
0.89977
1
0.88797
1
0.87632
5

P350K/Po
1
0.99061
4
0.98131
7
0.97210
7
0.96298
3
0.95394
5
0.94499
2
0.93612
2
0.92733
6
0.91863
3
0.91001
1

P400K/Po
1
0.99178
3
0.98363
3
0.97555
0.96753
4
0.95958
4
0.95169
9
0.94387
8
0.93612
2
0.92843
0.92080
1

P250/Po versus height

1.05
1

f(x) = - 0x + 1

0.95

P250K/Po

0.9
0.85
0.8
0

200

400

600

800

1000

1200

Height of the column

P400K/Po versus height

1.02
1

f(x) = - 0x + 1

0.98
0.96

P400K/Po

0.94
0.92
0.9
0.88
0

200

400

600

800

Height of the column

1000

1200

P350K/Po versus height

P350K/Po

1.02
1
0.98
0.96
0.94
0.92
0.9
0.88
0.86

f(x) = - 0x + 1

200

400

600

800

Height of the column

1000

1200

QUES 2: The following data represents variation of heat capacity at constant pressure (Cp) of Al 2O3 as a
function

of temperature i.e. Cp= a+Bt+Ct2. using spreadsheet, plot Cp of and fit the data to polynomial of degre
determine the value of constants a,b,c.
S. No.
1
2
3
4
5
6

Cp(JK-1mol-1)
0.009
1.49
12.8
31.9
51.1
57.9

T/K
10
50
100
150
200
220

From the graph the values of the constants are a= -2.1726

b= 0.0638
c= 0.001

Cp(JK-1mol-1) versus T/K

70

60

f(x) = 0x^2 + 0.06x - 2.17

50

40

Cp(JK-1mol-1)

30

20

10

0
0

50

100

150

T/K

200

250

QUES 3: Using spreadsheet, calculate the pressure of carbon dioxide gas (CO 2) at
various volumes (from 0.05 to 0.5dm3 in steps of 0.05) assuming it to be van der
waals gas
and plot P-V isotherm at 28K
a= 3.610 atm dm6mol-2
b= 0.0429 dm3mol-1
R= 0.0821 atm K-1 mol-1
S. No.

Volume of (CO2)
1
2
3
4
5
6
7
8
9
10

Pressure
1446.845
-1.54291
31.19888
40.39927
41.34671
39.72164
37.36552
34.9144
32.59043
30.46265

0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5

Pressure versus Volume of (CO2)

1600
1400
1200
1000
800

Pressure
600
400
200
0
0

0.1

0.2

0.3

-200

Volume of (CO2)

0.4

0.5

0.6

QUES 4: Using spreadsheet plot molar conductance m vs c^.5.Fit the data to a straight line
using equation m = om - k and calculate om
S. No.
1
2
3
4
5
6

Concentration
17.68
10.8
2.67
1.28
0.83
0.19

c1/2(M1/2)
4.204759
3.286335
1.634013
1.131371
0.911043
0.43589

Molar Conductance /Sm2 mol-1

42.45
45.91
51.81
54.09
55.78
57.42

om = 58.889
k= -3.9535

Molar Conductance /Sm2 mol-1 versus c1/2(M1/2)

70
60
f(x) = - 3.95x + 58.89
50
40

Molar Conductance /Sm2 mol-1

30
20
10
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5

c1/2(M1/2)

AIM=Using spreadsheet plot fraction of molecules having velocities between 0-1200

in intervals of 100 at 400k versus velocities (maxwell distribution of molecular
velocities )
for carbon monoxide gas

Given=
M=molecular mass
R=gas constant
T=temperature in Kelvin
V=velocity

SNO.
1
2
3
4
5
6
7
8
9
10
11

Velocity
0
100
200
300
400
500
600
700
800
900
1000

f(v)
0
0.000187
0.000659
0.001201
0.001591
0.001702
0.001542
0.001214
0.000843
0.000522
0.00029

f(v) versus Velocity

0
0
0
0
0

f(v)

0
0
0
0
0
0

200

400

600

Velocity

800

1000

1200

P250/Po versus height

1.05
1

f(x) = - 0x + 1

0.95

P250K/Po

0.9
0.85
0.8
0

200 400 600 800 10001200

Height of the column