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MC LC

MC LC ...............................................................................................................................................................1
I CNG KIM LOI .......................................................................................................................................3
GIO KHOA.......................................................................................................................................................3
DY IN HA KIM LOI .............................................................................................................................5
N MN KIM LOI ..........................................................................................................................................8
S IN PHN ...............................................................................................................................................9
KIM LOI TC DNG VI MUI ............................................................................................................... 12
KIM LOI TC DNG AXIT HCl/H2SO4 LONG ..................................................................................... 15
KIM LOI TC DNG AXIT HNO3/H2SO4 C ....................................................................................... 17
KIM LOI TC DNG PHI KIM ................................................................................................................... 21
IU CH KIM LOI .................................................................................................................................... 23
TON KH OXIT KIM LOI BNG CO, H2, ......................................................................................... 23
KIM LOI KIM KIM LOI KIM TH ........................................................................................................ 25
GIO KHOA.................................................................................................................................................... 25
NC CNG ................................................................................................................................................ 27
KIM LOI KIM/TH + AXIT/ NC ........................................................................................................ 28
CO2 + DUNG DCH NaOH/Ca(OH)2 ........................................................................................................... 30
MUI CACBONAT HIROCACBONAT ................................................................................................ 31
AXIT + MUI CACBONAT/ HIROCACBONAT ..................................................................................... 32
NHIT PHN MUI KIM LOI KIM/TH ................................................................................................ 32
NHM .................................................................................................................................................................. 34
GIO KHOA.................................................................................................................................................... 34
NHM V HP CHT TC DNG AXIT .................................................................................................. 34
HN HP (Al/Al2O3 V KLK/KLK TH) + H2O ........................................................................................ 36
TNH LNG TNH Al(OH)3, Al2O3 ............................................................................................................ 37
PHN NG NHIT NHM .......................................................................................................................... 38
ST NG V HP CHT ......................................................................................................................... 41
GIO KHOA.................................................................................................................................................... 41
TON OXIT ST............................................................................................................................................ 43
HP CHT VI LU HUNH .................................................................................................................... 45
BI TP LIN QUAN KMnO4 ...................................................................................................................... 46
CROM V HP CHT CA CROM............................................................................................................... 48
CU TO NGUYN T - BNG TUN HON ............................................................................................ 51
GIO KHOA.................................................................................................................................................... 51
CU HNH ELECTRON ................................................................................................................................ 51
TNG S HT............................................................................................................................................... 52
OXIT CAO NHT HP CHT KH VI HIRO ................................................................................... 53
NG V ........................................................................................................................................................ 53
LIN KT HA HC......................................................................................................................................... 54
PHN NG OXI HA KH ............................................................................................................................ 54
TC PHN NG CN BNG HA HC ........................................................................................... 59
GIO KHOA.................................................................................................................................................... 59
BI TP TC PHN NG ................................................................................................................... 61
BI TP CN BNG HA HC ................................................................................................................. 61
S IN LY ....................................................................................................................................................... 63
GIO KHOA.................................................................................................................................................... 63
HP CHT LNG TNH........................................................................................................................... 65
BI TP pH..................................................................................................................................................... 66
BO TON IN TCH ............................................................................................................................... 67
HNG S AXIT-BAZ ................................................................................................................................. 68
NIT V HP CHT ....................................................................................................................................... 70
GIO KHOA.................................................................................................................................................... 70
TNH KHI LNG MUI NITRAT ........................................................................................................... 72
KIM LOI/Fe2+ + HN HP H+ + NO3- ....................................................................................................... 72
NHIT PHN MUI NITRAT ....................................................................................................................... 74

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HALOGEN V HP CHT .............................................................................................................................. 75

PHOTPHO V HP CHT .............................................................................................................................. 76
PHN BN HA HC ..................................................................................................................................... 77
ESTE LIPIT...................................................................................................................................................... 79
PHN 1: ESTE ............................................................................................................................................... 79
GIO KHOA................................................................................................................................................ 79
PHN NG T CHY ESTE .............................................................................................................. 81
PHN NG THY PHN ........................................................................................................................ 83
HIU SUT PHN NG HNG S CN BNG .............................................................................. 88
PHN 2: LIPIT ................................................................................................................................................ 90
DNG 1: L THUYT ............................................................................................................................... 90
DNG 2: THY PHN CHT BO ........................................................................................................ 91
CHNG 2: CACBOHIDRAT ......................................................................................................................... 93
CHNG 3: AMIN AMINO AXIT - PROTEIN ......................................................................................... 100
Phn 1: AMIN ............................................................................................................................................... 100
Phn 2: AMINO AXIT .................................................................................................................................. 103
POLIME V VT LIU POLIME ................................................................................................................... 112
HIDROCACBON NO ....................................................................................................................................... 116
GIO KHOA.................................................................................................................................................. 116
PHN NG TH HALOGEN .................................................................................................................... 116
PHN NG CHY ...................................................................................................................................... 116
HIDRO HA CRAKINH .................................................................................................................... 117
HIDROCACBON KHNG NO ....................................................................................................................... 118
GIO KHOA.................................................................................................................................................. 118
PHN NG OXI HA KHNG HON TON ........................................................................................ 119
PHN NG CHY ...................................................................................................................................... 119
PHN NG CNG HIDRO ....................................................................................................................... 121
PHN NG CNG H2O, HX, X2. .............................................................................................................. 123
PHNG PHP TRUNG BNH ................................................................................................................ 125
PHN NG TH ION KIM LOI ............................................................................................................... 125
HIDROCACBON THM ................................................................................................................................. 126
DN XUT HALOGEN ANCOL PHENOL ............................................................................................ 127
TC DNG KL KIM .................................................................................................................................. 129
PHN NG CHY ...................................................................................................................................... 131
TCH NC ............................................................................................................................................... 134
PHENOL............................................................................................................................................................ 137
GIO KHOA.................................................................................................................................................. 137
ANEHIT XETON ........................................................................................................................................ 141
GIO KHOA.................................................................................................................................................. 141
T CHY................................................................................................................................................... 141
TRNG GNG ......................................................................................................................................... 143
CNG H2....................................................................................................................................................... 146
AXIT CACBOXYLIC ........................................................................................................................................ 148
GIO KHOA.................................................................................................................................................. 148
T CHY AXIT ......................................................................................................................................... 149
TNH CHT AXIT ......................................................................................................................................... 152

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I CNG KIM LOI

GIO KHOA
(H B 12) Pht biu no sau y l sai?
A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng.
B. Cc nhm A bao gm cc nguyn t s v nguyn t p.
C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi

kim.
D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy
c.
2.
(H B 12) Trng hp no sau y to ra kim loi?
A. t FeS2 trong oxi d.
B. Nung hn hp qung apatit, x vn v than cc trong l ng.
C. t Ag2S trong oxi d.
D. Nung hn hp qung photphorit, ct v than cc trong l in.
3.
(H B 11) Thc hin cc th nghim vi hn hp bt gm Ag v Cu (hn hp X):
(a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng).
(b) Cho X vo mt lng d dung dch HNO3 (c).
(c) Cho X vo mt lng d dung dch HCl (khng c mt O2).
(d) Cho X vo mt lng d dung dch FeCl3.
Th nghim m Cu b oxi ho cn Ag khng b oxi ho l
A. (d).
B. (a).
C. (b).
D. (c).
4.
(H B 11) Pht biu no sau y l sai?
A. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x.
B. Thic c th dng ph ln b mt ca st chng g.
C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh
eczema, bnh nga.
D. Nhm l kim loi dn in tt hn vng.
5.
(H B 11) Thc hin cc th nghim sau:
(a) Nhit phn AgNO3.
(b) Nung FeS2 trong khng kh.
(c) Nhit phn KNO3.
(d) Cho dung dch CuSO4 vo dung dch NH3 (d).
(e) Cho Fe vo dung dch CuSO4.
(g) Cho Zn vo dung dch FeCl3 (d).
(h) Nung Ag2S trong khng kh.
(i) Cho Ba vo dung dch CuSO4 (d).
S th nghim thu c kim loi sau khi cc phn ng kt thc l
A. 3.
B. 5.
C. 2.
D. 4.
6.
(H A 07) Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng
trnh phn ng gia Cu vi dung dch HNO3 c, nng l
A. 11.
B. 9.
C. 10.
D. 8.
7.
(C 08) Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO3)2, dung
dch HNO3 (c, ngui). Kim loi M l
A. Al.
B. Zn.
C. Fe.
D. Ag.
8.
(H A 09) Trng hp no sau y khng xy ra phn ng ho hc?
A. Sc kh Cl2 vo dung dch FeCl2.
B. Sc kh H2S vo dung dch CuCl2.
C. Sc kh H2S vo dung dch FeCl2.
D. Cho Fe vo dung dch H2SO4 long, ngui.
9.
(H A 09) Trng hp xy ra phn ng l
A. Cu + Pb(NO3)2 (long)
B. Cu + HCl (long)
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C. Cu + H2SO4 (long)
D. Cu + HCl (long) + O2
10. (H B 13) Trng hp no sau y khng xy ra phn ng?
A. Au + HNO3 c
B. Ag + O3
C. Sn + HNO3 long
D. Ag + HNO3 c
11. (H B 09) C cc th nghim sau:
(I) Nhng thanh st vo dung dch H2SO4 long, ngui.
(II) Sc kh SO2 vo nc brom.
(III) Sc kh CO2 vo nc Gia-ven.
(IV) Nhng l nhm vo dung dch H2SO4 c, ngui.
S th nghim xy ra phn ng ho hc l
A. 2.
B. 1.
C. 3.
D. 4.
12. (C 09) Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl,
va tc dng c vi dung dch AgNO3?
A. Hg, Na, Ca.
B. Al, Fe, CuO.
C. Fe, Ni, Sn.
D. Zn, Cu, Mg.
13. (C 09) Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn
ng thu c dung dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng
thu c kh khng mu T. Axit X l
A. H2SO4 long. B. HNO3.
C. H2SO4 c.
D. H3PO4.
14. (H A 10) Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe 2O3 +
CO (k),
(3) Au + O2 (k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al +
NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l:
A. (1), (3), (6).
B. (2), (5), (6).
C. (2), (3), (4).
D. (1), (4), (5).
15. (H A 10) Cc cht va tc dng c vi dung dch HCl va tc dng c vi
dung dch AgNO3 l:
A. MgO, Na, Ba.
B. Zn, Ni, Sn.
C. Zn, Cu, Fe.
D. CuO, Al, Mg.
16. (C 11) Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng
tc dng vi dung dch HNO3 c, ngui l:
A. Cu, Fe, Al.
B. Fe, Al, Cr.
C. Cu, Pb, Ag.
D. Fe, Mg, Al.
17. (C 12) loi b Al, Fe, CuO ra khi hn hp gm Ag, Al, Fe v CuO, c th dng
lng d dung dch no sau y?
A. Dung dch NaOH.
B. Dung dch Fe(NO3)3.
C. Dung dch HNO3.
D. Dung dch HCl.
18. (C 07) Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi
dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta
cng c mui Y. Kim loi M c th l
A. Mg.
B. Zn.
C. Al.
D. Fe.
19. (H B 08) Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan
hon ton trong dung dch
A. AgNO3 (d).
B. HCl (d).
C. NH3 (d).
D. NaOH (d).
20. (H B 09) Ho tan m gam hn hp gm Al, Fe vo dung dch H 2SO4 long (d). Sau
khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH) 2
(d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng
khng i, thu c cht rn Z l
A. hn hp gm BaSO4 v FeO.
B. hn hp gm Al2O3 v Fe2O3.
C. hn hp gm BaSO4 v Fe2O3.
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D. Fe2O3.
21. (H B 10) Cho cc cp cht vi t l s mol tng ng nh sau:
(a) Fe3O4 v Cu (1:1)
(b) Sn v Zn (2:1)
(c) Zn v Cu (1:1)
(d) Fe2(SO4)3 v Cu (1:1)
(e) FeCl2 v Cu (2:1)
(g) FeCl3 v Cu (1:1)
S cp cht tan han ton trong mt lng d dung dch HCl long nng l
A. 4.
B. 2.
C. 3.
D. 5.
22. (C 10) Kim loi M c th c iu ch bng cch kh ion ca n trong oxit bi kh
H2 nhit cao. Mt khc, kim loi M kh c ion H+ trong dung dch axit long
thnh H2. Kim loi M l
A. Cu.
B. Mg.
C. Fe.
D. Al.
DY IN HA KIM LOI
23. (C 11) Dy gm cc ion u oxi ha c kim loi Fe l
A. Fe3+, Cu2+, Ag+.
B. Zn2+, Cu2+, Ag+.
C. Cr2+, Au3+, Fe3+.
D. Cr2+, Cu2+, Ag+.
24. (C 12) Cho dy cc ion: Fe2+, Ni2+, Cu2+, Sn2+. Trong cng iu kin, ion c tnh oxi
ha mnh nht trong dy l
A. Sn2+.
B. Cu2+.
C. Fe2+.
D. Ni2+.
25. C 07) kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi
A. Fe.
B. Na.
C. K.
D. Ba.
26. (C 08) Cp cht khng xy ra phn ng ho hc l
A. Cu + dung dch FeCl3.
B. Fe + dung dch HCl.
C. Fe + dung dch FeCl3.
D. Cu + dung dch FeCl2.
27. (C 12) Cho dy cc kim loi: Cu, Ni, Zn, Mg, Ba, Ag. S kim loi trong dy phn
ng c vi dung dch FeCl3 l
A. 6.
B. 4.
C. 3.
D. 5.
28. (H A 13) Cho cc cp oxi ha - kh c sp xp theo th t tng dn tnh oxi ha
ca cc ion kim loi: Al3+/Al; Fe2+/Fe; Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau:
(a) Cho st vo dung dch ng(II) sunfat.
(b) Cho ng vo dung dch nhm sunfat.
(c) Cho thic vo dung dch ng(II) sunfat.
(d) Cho thic vo dung dch st(II) sunfat.
Trong cc th nghim trn, nhng th nghim c xy ra phn ng l:
A. (a) v (b).
B. (b) v (c).
C. (a) v (c).
D. (b) v (d).
29. (C 08) Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng
ha hc sau:
X + 2YCl3 XCl2 + 2YCl2; Y + XCl2 YCl2 + X.
Pht biu ng l:
A. Ion Y2+ c tnh oxi ha mnh hn ion X2+.
B. Kim loi X kh c ion Y2+.
C. Kim loi X c tnh kh mnh hn kim loi Y.
D. Ion Y3+ c tnh oxi ha mnh hn ion X2+.
30. (H B 10) Pht biu no sau y khng ng?
A. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh
chuyn thnh mui Cr(VI).
B. Do Pb2+/Pb ng trc 2H+/H2 trong dy in ho nn Pb d dng phn ng vi
dung dch HCl long ngui, gii phng kh H2.
C. CuO nung nng khi tc dng vi NH3 hoc CO, u thu c Cu.
D. Ag khng phn ng vi dung dch H2SO4 long nhng phn ng vi dung dch
H2SO4 c nng.
31. (C 12) Tin hnh cc th nghim sau:
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(1) Cho Zn vo dung dch AgNO3;
(2) Cho Fe vo dung dch Fe2(SO4)3;
(3) Cho Na vo dung dch CuSO4;
(4) Dn kh CO (d) qua bt CuO nng.
Cc th nghim c to thnh kim loi l
A. (1) v (2).
B. (1) v (4).
C. (2) v (3).
D. (3) v (4).
32. (H A 12) Cho cc cp oxi ho - kh c sp xp theo chiu tng dn tnh oxi ho
ca dng oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l
ng?
A. Fe2+ oxi ha c Cu thnh Cu2+.
B. Cu2+ oxi ho c Fe2+ thnh Fe3+.
C. Fe3+ oxi ha c Cu thnh Cu2+.
D. Cu kh c Fe3+ thnh Fe.
33. (C 07) kh ion Fe3+ trong dung dch thnh ion Fe2+ c th dng mt lng d
A. kim loi Mg.
B. kim loi Cu.
C. kim loi Ba.
D. kim loi Ag.
34. (C 07) Th t mt s cp oxi ho - kh trong dy in ho nh sau: Fe2+/Fe;
Cu2+/Cu; Fe3+/Fe2+. Cp cht khng phn ng vi nhau l
A. Fe v dd CuCl2.
B. Fe v dd FeCl3.
C. dd FeCl2 v dd CuCl2.
D. Cu v dd FeCl3.
2+
2+
35. (C 07) Cho cc ion kim loi: Zn , Sn , Ni2+, Fe2+, Pb2+. Th t tnh oxi ho gim
dn l
A. Pb2+ > Sn2+ > Fe2+ > Ni2+ > Zn2+.
B. Sn2+ > Ni2+ > Zn2+ > Pb2+ > Fe2+.
C. Zn2+ > Sn2+ > Ni2+ > Fe2+ > Pb2+.
D. Pb2+ > Sn2+ > Ni2+ > Fe2+ > Zn2+.
36. (H B 13) Cho phng trnh ha hc ca phn ng: 2Cr + 3Sn2+ 2Cr3+ + 3Sn.
Nhn xt no sau y v phn ng trn l ng?
A. Sn2+ l cht kh, Cr3+ l cht oxi ha.
B. Cr l cht oxi ha, Sn2+ l cht kh.
C. Cr l cht kh, Sn2+ l cht oxi ha.
D. Cr3+ l cht kh, Sn2+ l cht oxi ha.
37. (C 10) Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn
hp gm HCl v NaNO3. Nhng dung dch phn ng c vi kim loi Cu l:
A. (1), (3), (5).
B. (1), (2), (3).
C. (1), (3), (4).
D. (1), (4), (5).
38. (H A 12) Cho cc cp oxi ho - kh c sp xp theo chiu tng dn tnh oxi ho
ca dng oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l
ng?
A. Fe2+ oxi ha c Cu thnh Cu2+.
B. Cu2+ oxi ho c Fe2+ thnh Fe3+.
C. Fe3+ oxi ha c Cu thnh Cu2+.
D. Cu kh c Fe3+ thnh Fe.
39. (H A 2007) Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in
ha, cp Fe3+/Fe2+ ng trc cp Ag+/Ag):
A. Ag+, Fe3+, Cu2+, Fe2+.
B. Ag+, Cu2+, Fe3+, Fe2+.
C. Fe3+, Ag+, Cu2+, Fe2+.
D. Fe3+, Cu2+, Ag+, Fe2+.
40. (H A 07) Mnh khng ng l:
A. Fe kh c Cu2+ trong dung dch.
B. Fe3+ c tnh oxi ha mnh hn Cu2+.
C. Fe2+ oxi ho c Cu.
D. Tnh oxi ha ca cc ion tng theo th t: Fe2+, H+, Cu2+, Ag+.
41. (H B 07) Cho cc phn ng xy ra sau y:
(1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag;
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(2) Mn + 2HCl MnCl2 + H2.
Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l
A. Mn2+, H+, Fe3+, Ag+.
B. Ag+ , Mn2+, H+, Fe3+.
C. Mn2+, H+, Ag+, Fe3+.
D. Ag+, Fe3+, H+, Mn2+.
42. (H B 08) Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 ; 2NaBr + Cl2
2NaCl + Br2. Pht biu ng l:
A. Tnh kh ca Br mnh hn ca Fe2+.
B. Tnh kh ca Cl- mnh hn ca Br.
C. Tnh oxi ha ca Cl2 mnh hn ca Fe3+.
D. Tnh oxi ha ca Br2 mnh hn ca Cl2.
43. (C 10) Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in
ho (dy th in cc chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag.
Cc kim loi v ion u phn ng c vi ion Fe2+ trong dung dch l:
A. Zn, Ag+.
B. Ag, Cu2+.
C. Ag, Fe3+.
D. Zn, Cu2+.
44. (C 08) Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn
xy ra
A. s kh Fe2+ v s oxi ha Cu.
B. s kh Fe2+ v s kh Cu2+.
C. s oxi ha Fe v s oxi ha Cu.
D. s oxi ha Fe v s kh Cu2+.
45. (C 09) Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg2+/Mg;
Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion
Fe3+ trong dung dch l:
A. Mg, Cu, Cu2+.
B. Mg, Fe2+, Ag.
C. Mg, Fe, Cu.
D. Fe, Cu, Ag+.
46. (H A 11) Cho cc phn ng sau: Fe + 2Fe(NO3)3 3Fe(NO3)2 ; AgNO3 + Fe(NO3)2
Fe(NO3)3 + Ag. Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi
l:
A. Ag+, Fe3+, Fe2+.
B. Ag+, Fe2+, Fe3+.
C. Fe2+, Fe3+, Ag+.
D. Fe2+, Ag+, Fe3+.
47. (H A 13) Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng
xy ra han ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi.
Hai mui trong X v hai kim loi trong Y ln lt l:
A. Fe(NO3)2; Fe(NO3)3 v Cu; Ag.
B. Cu(NO3)2; AgNO3 v Cu; Ag.
C. Cu(NO3)2; Fe(NO3)2 v Cu; Fe.
D. Cu(NO3)2; Fe(NO3)2 v Ag; Cu.
48. (H A 08) X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc
dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy
th in ho: Fe3+/Fe2+ ng trc Ag+/Ag)
A. Mg, Ag.
B. Fe, Cu.
C. Ag, Mg.
D. Cu, Fe.
49. (C 09) Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO3 2M,
thu c m gam kt ta. Gi tr ca m l
A. 30,18.
B. 34,44.
C. 12,96.
D. 47,4.
50. (C 13) Hn hp X gm FeCl2 v NaCl c t l mol tng ng l 1 : 2. Ha tan han
ton 2,44 gam X vo nc, thu c dung dch Y. Cho Y phn ng han ton vi
dung dch AgNO3 d, thu c m gam cht rn. Gi tr ca m l
A. 5,74.
B. 2,87.
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C. 6,82.
D. 10,80.
51. (H A 12) Cho 100 ml dung dch AgNO3 2a mol/l vo 100 ml dung dch Fe(NO3)2 a
mol/l. Sau khi phn ng kt thc thu c 8,64 gam cht rn v dung dch X. Cho
dung dch HCl d vo X thu c m gam kt ta. Gi tr ca m l
A. 22,96.
B. 11,48.
C. 17,22.
D. 14,35.

52.

53.

54.

55.

56.

57.

58.

59.

N MN KIM LOI
(C 11) Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n
mn
A. km ng vai tr catot v b oxi ha.
B. st ng vai tr anot v b oxi ho.
C. st ng vai tr catot v ion H+ b oxi ha.
D. km ng vai tr anot v b oxi ho.
(C 12) Tin hnh cc th nghim sau:
(a) Cho l Fe vo dung dch gm CuSO4 v H2SO4 long;
(b) t dy Fe trong bnh ng kh O2;
(c) Cho l Cu vo dung dch gm Fe(NO3)3 v HNO3;
(d) Cho l Zn vo dung dch HCl.
S th nghim c xy ra n mn in ha l
A. 1.
B. 4.
C. 2.
D. 3.
(H B 12) Trng hp no sau y xy ra n mn in ho?
A. Si dy bc nhng trong dung dch HNO3.
B. t l st trong kh Cl2.
C. Thanh nhm nhng trong dung dch H2SO4 long.
D. Thanh km nhng trong dung dch CuSO4.
(H B 07) C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2.
Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n
mn in ho l
A. 1.
B. 2.
C. 3.
D. 0.
(H B 09) Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi
tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn
trc l:
A. I, II v III.
B. I, II v IV.
C. I, III v IV.
D. II, III v IV.
(H B 10) C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi
dung dch mt thanh Ni. S trng hp xut hin n mn in ho l
A. 1.
B. 4.
C. 3.
D. 2.
(C 07) Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe
v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp
kim loi trong Fe b ph hu trc l
A. 4.
B. 1.
C. 2.
D. 3.
(H A 08) Bit rng ion Pb2+ trong dung dch oxi ha c Sn. Khi nhng hai thanh
kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li
th
A. c Pb v Sn u khng b n mn in ho.
B. ch c Pb b n mn in ho.
C. ch c Sn b n mn in ho.
D. c Pb v Sn u b n mn in ho.

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60. (H A 08) Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in
cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi
lng
A. in cc Zn gim cn khi lng in cc Cu tng.
B. in cc Zn tng cn khi lng in cc Cu gim.
C. c hai in cc Zn v Cu u gim.
D. c hai in cc Zn v Cu u tng.
61. (H B 08) Tin hnh bn th nghim sau:
- Th nghim 1: Nhng thanh Fe vo dung dch FeCl3;
- Th nghim 2: Nhng thanh Fe vo dung dch CuSO4;
- Th nghim 3: Nhng thanh Cu vo dung dch FeCl3;
- Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl.
S trng hp xut hin n mn in ho l
A. 3.
B. 1.
C. 2.
D. 4.
62. (H A 13) Trng hp no sau y, kim loi b n mn in ha hc?
A. Kim loi st trong dung dch HNO3 long.
B. Thp cacbon trong khng kh m.
C. t dy st trong kh oxi kh.
D. Kim loi km trong dung dch HCl.
63. (C 13) Pht biu no di y khng ng?
A. Tnh cht ha hc c trng ca kim loi l tnh kh.
B. Bn cht ca n mn kim loi l qu trnh oxi ha - kh.
C. n mn ha hc pht sinh dng in.
D. Nguyn tc chung iu ch kim loi l kh ion kim loi thnh nguyn t kim
loi.
S IN PHN
64. (C 13) Sn phm thu c khi in phn dung dch KCl (in cc tr, mng ngn
xp) l
A. K v Cl2.
B. K, H2 v Cl2.
C. KOH, H2 v Cl2.
D. KOH, O2 v HCl.
65. (H A 08) Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s oxi ho ion Na+.
B. s oxi ho ion Cl.

C. s kh ion Cl .
D. s kh ion Na+.
66. (H B 11) Khi in phn dung dch NaCl (cc m bng st, cc dng bng than
ch, c mng ngn xp) th
A. cc dng xy ra qu trnh oxi ho ion Na + v cc m xy ra qu trnh kh
ion Cl.
B. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ho
ion Cl .
C. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion
Cl.
D. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion
Cl.
67. (C 13) in phn dung dch gm NaCl v HCl (in cc tr, mng ngn xp).
Trong qu trnh in phn, so vi dung dch ban u, gi tr pH ca dung dch thu
c
A. khng thay i.
B. gim xung.
C. tng ln sau gim xung.
D. tng ln.
68. (H A 10) Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n
mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l:
A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi.
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n tp Ha 12

B. Phn ng cc dng u l s oxi ho Cl .

C. u sinh ra Cu cc m.
D. Phn ng xy ra lun km theo s pht sinh dng in.
69. (C 10) in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn
dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l
A. catot xy ra s kh: Cu2+ + 2e Cu.
B. catot xy ra s oxi ho: 2H2O + 2e 2OH + H2.
C. anot xy ra s kh: 2H2O O2 + 4H+ + 4e.
D. anot xy ra s oxi ho: Cu Cu2+ + 2e.
70. (H A 07) Dy gm cc kim loi c iu ch trong cng nghip bng phng
php in phn hp cht nng chy ca chng, l:
A. Na, Cu, Al.
B. Fe, Ca, Al.
C. Na, Ca, Zn.
D. Na, Ca, Al.
71. (H A 09) Dy cc kim loi u c th c iu ch bng phng php in phn
dung dch mui ca chng l:
A. Fe, Cu, Ag.
B. Mg, Zn, Cu.
C. Al, Fe, Cr.
D. Ba, Ag, Au.
72. (H B 07) in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr,
c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang
mu hng th iu kin ca a v b l (bit ion SO42- khng b in phn trong dung
dch)
A. 2b = a.
B. b < 2a.
C. b = 2a.
D. b > 2a.
73. (H A 11) in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO 3)2 (in cc
tr, mng ngn xp) n khi khi lng dung dch gim i 10,75 gam th ngng in
phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung
dch sau in phn l
A. KNO3 v KOH.
B. KNO3, KCl v KOH.
C. KNO3 v Cu(NO3)2.
D. KNO3, HNO3 v Cu(NO3)2.
74. (C 11) in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot
thu c 3,2 gam kim loi th th tch kh (ktc) thu c anot l
A. 2,24 lt.
B. 3,36 lt.
C. 0,56 lt.
D. 1,12 lt.
75. (C 12) Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng
in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b
dung dch X tc dng va vi 12,6 gam Fe. Gi tr ca V l
A. 0,15.
B. 0,60.
C. 0,45.
D. 0,80.
76. (H A 12) in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng
dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht
rn X, dung dch Y v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc
thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi
tr ca t l
A. 0,8.
B. 1,2.
C. 1,0.
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n tp Ha 12
D. 0,3.
77. (H A 11) Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X
(vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam
kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t
giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l
A. 4,788.
B. 3,920.
C. 1,680.
D. 4,480.
78. (H B 12) in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1
mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh
(ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l
A. 5,60.
B. 11,20.
C. 22,40.
D. 4,48.
79.
(H B 12) Ngi ta iu ch H2 v O2 bng phng php in phn dung dch
NaOH vi in cc tr, cng dng in 0,67A trong thi gian 40 gi. Dung dch
thu c sau in phn c khi lng 100 gam v nng NaOH l 6%. Nng
dung dch NaOH trc in phn l (gi thit lng nc bay hi khng ng k)
A. 5,08%.
B. 6,00%.
C. 5,50%.
D. 3,16%.
80. (H A 07) in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c
0,32 gam Cu catt v mt lng kh X ant. Hp th han ton lng kh X trn
vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn
li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung
dch NaOH l
A. 0,15M.
B. 0,1M.
C. 0,05M.
D. 0,2M.
81. (H B 09) in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2
0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in
5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ha tan m gam
Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40.
82. (H A 10) in phn (vi in cc tr) mt dung dch gm NaCl v CuSO 4 c cng
s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in
phn trn, sn phm thu c anot l
A. kh Cl2 v H2.
B. kh Cl2 v O2.
C. ch c kh Cl2.
D. kh H2 v O2.
83. (H A 10) in phn (in cc tr) dung dch X cha 0,2 mol CuSO 4 v 0,12 mol
NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650
giy in phn l
A. 1,344 lt.
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n tp Ha 12
B. 2,240 lt.
C. 1,792 lt.
D. 2,912 lt.
84. (H A 10) in phn (in cc tr) dung dch X cha 0,2 mol CuSO 4 v 0,12 mol
NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650
giy in phn l
A. 1,344 lt.
B. 2,240 lt.
C. 1,792 lt.
D. 2,912 lt.
85. (H A 13) Tin hnh in phn dung dch cha m gam hn hp CuSO4 v NaCl
(hiu sut 100%, in cc tr, mng ngn xp), n khi nc bt u b in phn
c hai in cc th ngng in phn, thu c dung dch X v 6,72 lt kh (ktc)
anot. Dung dch X ha tan ti a 20,4 gam Al2O3. Gi tr ca m l
A. 25,6.
B. 51,1.
C. 50,4.
D. 23,5.
86. (H B 09) in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%)
thu c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro
bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu
c 2 gam kt ta. Gi tr ca m l
A. 108,0.
B. 75,6.
C. 54,0.
D. 67,5.
87. (H B 13) in phn nng chy Al2O3 vi cc in cc bng than ch, thu c m
kilogam Al catot v 89,6 m3 (ktc) hn hp kh X anot. T khi ca X so vi H2
bng 16,7. Cho 1,12 lt X (ktc) phn ng vi dung dch Ca(OH)2 d, thu c 1,5
gam kt ta. Bit cc phn ng xy ra han ton. Gi tr ca m l
A. 144,0.
B. 104,4.
C. 82,8.
D. 115,2.
KIM LOI TC DNG VI MUI
88. (C 08) Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi
cc phn ng xy ra han ton, thu c hn hp rn gm ba kim loi l:
A. Fe, Cu, Ag.
B. Al, Cu, Ag.
C. Al, Fe, Cu.
D. Al, Fe, Ag.
89. (H A 12) Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy
ra han ton thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi).
Hai mui trong X l
A. Mg(NO3)2 v Fe(NO3)2.
B. Fe(NO3)3 v Mg(NO3)2.
C. AgNO3 v Mg(NO3)2.
D. Fe(NO3)2 v AgNO3.
90. (H A 09) Cho hn hp gm Fe v Zn vo dung dch AgNO 3 n khi cc phn ng
xy ra han ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi.
Hai mui trong X l
A. Fe(NO3)3 v Zn(NO3)2.
B. Zn(NO3)2 v Fe(NO3)2.
C. AgNO3 v Zn(NO3)2.
D. Fe(NO3)2 v AgNO3.
91. (H A 13) Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01M. Sau khi cc phn ng
xy ra han ton, khi lng kt ta thu c l
A. 2,33 gam.
B. 0,98 gam.
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n tp Ha 12
C. 3,31 gam.
D. 1,71 gam.
92. (H B 07) Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau
khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh
phn phn trm theo khi lng ca Zn trong hn hp bt ban u l
A. 12,67%.
B. 85,30%.
C. 90,27%.
D. 82,20%.
93. (H B 09) Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm
Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm
kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh
st). Khi lng st phn ng l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam.
94. (C 09) Cho m gam Mg vo dung dch cha 0,12 mol FeCl 3. Sau khi phn ng xy
ra han ton thu c 3,36 gam cht rn. Gi tr ca m l
A. 2,88.
B. 4,32.
C. 5,04.
D. 2,16.
95. (C 09) Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M.
Sau khi cc phn ng xy ra han ton th thu c m 2 gam cht rn X. Nu cho m2
gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr
ca m1 v m2 ln lt l
A. 0,54 v 5,16.
B. 1,08 v 5,43.
C. 8,10 v 5,43.
D. 1,08 v 5,16.
96.
(C 10) Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO 4
0,5M. Sau khi cc phn ng xy ra han ton, thu c dung dch X v 30,4 gam hn
hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l
A. 56,37%.
B. 64,42%.
C. 43,62%.
D. 37,58%.
97. (H B 12) Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M.
Sau khi cc phn ng xy ra han ton, thu c dung dch X v 3,333 gam cht rn.
Khi lng Fe trong hn hp ban u l
A. 0,168 gam.
B. 0,123 gam.
C. 0,177 gam.
D. 0,150 gam.
98. (H B 12) Cho m gam bt st vo dung dch hn hp gm 0,15 mol CuSO4 v 0,2
mol HCl. Sau khi cc phn ng xy ra han ton, thu c 0,725m gam hn hp kim
loi. Gi tr ca m l
A. 16,0.
B. 18,0.
C. 16,8.
D. 11,2.
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n tp Ha 12
99. (H B 11) Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc
phn ng xy ra han ton, khi lng dung dch tng thm 9,6 gam so vi khi
lng dung dch ban u. Gi tr ca m l
A. 20,80.
B. 29,25.
C. 48,75.
D. 32,50.
100. (H B 11) Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian
phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm
5,85 gam bt Zn vo Y, sau khi phn ng xy ra han ton thu c 10,53 gam cht
rn Z. Gi tr ca m l
A. 5,12.
B. 3,84.
C. 5,76.
D. 6,40.
101. (H A 08) Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch
AgNO3 1M. Sau khi cc phn ng xy ra han ton, thu c m gam cht rn. Gi tr
ca m l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag)
A. 54,0.
B. 64,8.
C. 32,4.
D. 59,4.
102. (H B 08) Tin hnh hai th nghim sau:
- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra han ton, khi lng cht rn thu c hai th
nghim u bng nhau. Gi tr ca V1 so vi V2 l
A. V1 = 2V2.
B. V1 = 5V2.
C. V1 = 10V2.
D. V1 = V2.
103. (H A 09) Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu 2+
v 1 mol Ag+ n khi cc phn ng xy ra han ton, thu c mt dung dch cha
ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn?
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
104. (H B 09) Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO 3
0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra han ton, thu c dung dch
X v m gam cht rn Y. Gi tr ca m l
A. 2,80.
B. 2,16.
C. 4,08.
D. 0,64.
105. (C 09) Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50
gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra han ton. Lc
dung dch, em c cn thu c 18,8 gam mui khan. Kim loi M l
A. Mg.
B. Cu.
C. Fe.
D. Zn.
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n tp Ha 12
106. (H A 11) Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO 4.
Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo
dung dch H2SO4 (long, d), sau khi cc phn ng kt thc th khi lng cht rn
gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi
lng ca Fe trong X l
A. 58,52%.
B. 48,15%.
C. 51,85%.
D. 41,48%.
107. (H A 13) Cho hn hp X gm 0,01 mol Al v a mol Fe vo dung dch AgNO3 n
khi phn ng han ton, thu c m gam cht rn Y v dung dch Z cha 3 cation
kim loi. Cho Z phn ng vi dung dch NaOH d trong iu kin khng c khng kh,
thu c 1,97 gam kt ta T. Nung T trong khng kh n khi lng khng i, thu
c 1,6 gam cht rn ch cha mt cht duy nht. Gi tr ca m l
A. 6,48.
B. 3,24.
C. 8,64.
D. 9,72.
108. (H B 13) Nhng mt thanh st vo dung dch hn hp cha 0,02 mol AgNO3 v
0,05 mol Cu(NO3)2. Sau khi cc phn ng xy ra han ton, khi lng thanh st tng
m gam (coi ton b kim loi sinh ra bm vo thanh st). Gi tr ca m l
A. 2,00.
B. 3,60.
C. 1,44.
D. 5,36.
KIM LOI TC DNG AXIT HCl/H2SO4 LONG
109. (C 12) Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh
th KNO3 to thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to
thnh kh Z. Cc kh X, Y v Z ln lt l
A. SO2, O2 v Cl2. B. H2, NO2 v Cl2.
C. H2, O2 v Cl2. D. Cl2, O2 v H2S.
110. (H A 12) Ha tan han ton 2,43 gam hn hp gm Mg v Zn vo mt lng va
dung dch H2SO4 long, sau phn ng thu c 1,12 lt H2 (ktc) v dung dch X.
Khi lng mui trong dung dch X l
A. 4,83 gam.
B. 5,83 gam.
C. 7,33 gam.
D. 7,23 gam.
111. (C 07) Ha tan han ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng
va dung dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m
gam mui. Gi tr ca m l
A. 9,52.
B. 10,27.
C. 8,98.
D. 7,25.
112. (C 08) Ha tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp
HCl 1M v H2SO4 0,28M thu c dung dch X v 8,736 lt kh H2 ( ktc). C cn
dung dch X thu c lng mui khan l
A. 38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
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n tp Ha 12
113. (C 11) ha tan han ton 6,4 gam hn hp gm kim loi R (ch c ha tr II) v
oxit ca n cn va 400 ml dung dch HCl 1M. Kim loi R l
A. Ba.
B. Be.
C. Mg.
D. Ca.
114. (C 12) Ha tan han ton 2,7 gam hn hp X gm Fe, Cr, Al bng dung dch HCl
d, thu c 1,568 lt kh H2 (ktc). Mt khc, cho 2,7 gam X phn ng han ton vi
kh Cl2 d, thu c 9,09 gam mui. Khi lng Al trong 2,7 gam X l bao nhiu?
A. 1,08 gam.
B. 0,54 gam.
C. 0,81 gam.
D. 0,27 gam.
115. (C 08) X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam
hn hp gm kim loi X v Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt
kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H2SO4
long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l
A. Ba.
B. Ca.
C. Sr.
D. Mg.
116. (C 07) Ha tan han ton hn hp X gm Fe v Mg bng mt lng va dung
dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l
15,76%. Nng phn trm ca MgCl2 trong dung dch Y l
A. 24,24%.
B. 11,79%.
C. 28,21%.
D. 15,76%.
117. (H A 07) Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit
HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch
dung dch khng i). Dung dch Y c pH l
A. 7.
B. 1.
C. 2.
D. 6.
118. (H B 08) Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt
thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt
lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2
(sn phm kh duy nht, ktc). Gi tr ca m l
A. 12,3.
B. 10,5.
C. 11,5.
D. 15,6.
119. (H A 10) Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2
vo dung dch cha 0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra han ton, thu
c m gam kim loi. Gi tr ca m l
A. 12,80.
B. 12,00.
C. 6,40.
D. 16,53.
120. (H A 10) Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng
nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v
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kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X
tc dng han ton vi O2 (d) to hn hp 3 oxit th th tch kh O 2 (ktc) phn
ng l
A. 2,016 lt.
B. 1,008 lt.
C. 0,672 lt.
D. 1,344 lt.
121. (H A 11) Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch
H2SO4 0,1M. Sau khi cc phn ng xy ra han ton, thu c 0,32 gam cht rn v
c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng
kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng
mui trong dung dch l
A. 0,224 lt v 3,865 g.
B. 0,112 lt v 3,865 g.
C. 0,112 lt v 3,750 g.
D. 0,224 lt v 3,750 g.
122. (C 12) Cho 42,4 gam hn hp gm Cu v Fe3O4 (c t l s mol tng ng l 3
: 1) tc dng vi dung dch HCl d, sau khi cc phn ng xy ra han ton cn li m
gam cht rn. Gi tr ca m l
A. 19,2.
B. 9,6.
C. 12,8.
D. 6,4.
KIM LOI TC DNG AXIT HNO3/H2SO4 C
123. (C 12) Dung dch long (d) no sau y tc dng c vi kim loi st to thnh
mui st(III)?
A. H2SO4.
B. HNO3.
C. FeCl3.
D. HCl.

124. (C 11) nhn ra ion NO3 trong dung dch Ba(NO3)2, ngi ta un nng nh dung
dch vi
A. kim loi Cu.
B. dung dch H2SO4 long.
C. kim loi Cu v dung dch Na2SO4.
D. kim loi Cu v dung dch H2SO4 long.
125. (H B 12) Ha tan Au bng nc cng toan th sn phm kh l NO; ha tan Ag
trong dung dch HNO3 c th sn phm kh l NO2. s mol NO2 bng s mol NO
th t l s mol Ag v Au tng ng l
A. 1 : 2.
B. 3 : 1.
C. 1 : 1.
D. 1 : 3.
126. (C 07) Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi
cc phn ng xy ra han ton, thu c dung dch Y v mt phn Fe khng tan.
Cht tan c trong dung dch Y l
A. MgSO4 v FeSO4.
B. MgSO4, Fe2(SO4)3 v FeSO4.
C. MgSO4 v Fe2(SO4)3.
D. MgSO4.
127. (H A 07) nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong
ba l b mt nhn, ta dng thuc th l
A. Al.
B. CuO.
C. Cu.
D. Fe.
128. (H B 07) Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn
ng han ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan
l
A. Fe(NO3)3.
B. HNO3.
C. Fe(NO3)2.
D. Cu(NO3)2.
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129. (C 13) Cho m gam Al phn ng han ton vi dung dch HNO 3 long (d), thu
c 4,48 lt kh NO (ktc, sn phm kh duy nht). Gi tr ca m l
A. 4,05.
B. 2,70.
C. 8,10.
D. 5,40.
130. (C 13) Cho 2,8 gam hn hp X gm Cu v Ag phn ng han ton vi dung dch
HNO3 d, thu c 0,04 mol NO2 (sn phm kh duy nht ca N+5) v dung dch
cha m gam mui. Gi tr ca m l
A. 4,08.
B. 3,62.
C. 3,42.
D. 5,28.
131. (C 08) Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X
(sn phm kh duy nht, ktc). Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
132. (C 09) Ha tan han ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO 3
long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu,
trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho
dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm
khi lng ca Al trong hn hp ban u l
A. 19,53%.
B. 10,52%.
C. 12,80%.
D. 15,25%.
133. (C 11) Ha tan han ton 13,00 gam Zn trong dung dch HNO3 long, d thu c
dung dch X v 0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l
A. 18,90 gam.
B. 37,80 gam.
C. 28,35 gam.
D. 39,80 gam.
134. (C 12) Ha tan han ton 8,9 gam hn hp gm Mg v Zn bng lng va 500
ml dung dch HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O
(ktc) duy nht v dung dch X cha m gam mui. Gi tr ca m l
A. 31,22.
B. 34,10.
C. 33,70.
D. 34,32.
135. (H B 08) Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng
xy ra han ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui
khan thu c khi lm bay hi dung dch X l
A. 13,32 gam.
B. 6,52 gam.
C. 13,92 gam.
D. 8,88 gam.
136. (H B 12) Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung
dch HNO3 1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc)
gm NO v N2O. T khi ca X so vi H2 l 16,4. Gi tr ca m l
A. 98,20.
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B. 97,20.
C. 98,75.
D. 91,00.
137. (H B 11) Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1)
vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra
han ton, thu c a mol kh NO (sn phm kh duy nht ca N +5). Trn a mol NO
trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H 2O, thu
c 150 ml dung dch c pH = z. Gi tr ca z l
A. 2.
B. 4.
C. 3.
D. 1.
138. (H A 07) Ha tan han ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3,
thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai
mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l
A. 3,36.
B. 2,24.
C. 4,48.
D. 5,60.
139. (H B 07) Thc hin hai th nghim:
1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO.
2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M
thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin.
Quan h gia V1 v V2 l
A. V2 = V1.
B. V2 = 2,5V1.
C. V2 = 2V1.
D. V2 = 1,5V1.
140. (H A 08) Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3
0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra han ton, sinh ra V lt kh NO
(sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,672.
B. 0,448.
C. 1,792.
D. 0,746.
141. (H B 08) Th tch dung dch HNO3 1M (long) t nht cn dng ha tan han
ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy
nht l NO)
A. 1,2 lt.
B. 0,6 lt.
C. 0,8 lt.
D. 1,0 lt.
142. (H A 09) Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu
c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng
22. Kh NxOy v kim loi M l
A. NO v Mg.
B. NO2 v Al.
C. N2O v Al.
D. N2O v Fe.
143. (H A 09) Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy
ra han ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X
c th ha tan ti a m gam Cu. Gi tr ca m l
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A. 1,92.
B. 3,20.
C. 0,64.
D. 3,84.
144. (H B 09) Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v
H2SO4 0,25M. Sau khi cc phn ng xy ra han ton, thu c 0,6m gam hn hp
bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln
lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48.
145. (H B 09) Cho 61,2 gam hn hp X gm Cu v Fe 3O4 tc dng vi dung dch HNO3
long, un nng v khuy u. Sau khi cc phn ng xy ra han ton, thu c 3,36
lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi.
C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
146. (H B 09) Khi ha tan han ton 0,02 mol Au bng nc cng toan th s mol HCl
phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,02.
B. 0,06 v 0,01.
C. 0,03 v 0,01.
D. 0,06 v 0,02.
147. (H B 09) Ha tan han ton 1,23 gam hn hp X gm Cu v Al vo dung dch
HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung
dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra han ton
thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr
ca m ln lt l
A. 21,95% v 2,25.
B. 78,05% v 2,25.
C. 21,95% v 0,78.
D. 78,05% v 0,78.
148. (H B 10) Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol
H2SO4 (long). Sau khi cc phn ng xy ra han ton, thu c V lt kh NO (sn
phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 8,96.
C. 4,48.
D. 10,08.
149. (C 10) Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d
dung dch HNO3. Sau khi cc phn ng xy ra han ton, thu c 0,896 lt mt kh X
(ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam mui khan. Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
150. (C 10) Cho a gam Fe vo 100 ml dung dch hn hp gm HNO 3 0,8M v Cu(NO3)2
1M. Sau khi cc phn ng xy ra han ton, thu c 0,92a gam hn hp kim loi v
kh NO (sn phm kh duy nht ca). Gi tr ca a l
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n tp Ha 12
A. 5,6.
B. 11,2.
C. 8,4.
D. 11,0.
151. (H A 11) un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3
vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht
rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm
kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l
A. 40,5.
B. 50,4.
C. 33,6.
D. 44,8.
152. (H A 11) Cho 7,68 gam Cu vo 200 ml dung dch gm HNO 3 0,6M v H2SO4 0,5M.
Sau khi cc phn ng xy ra han ton (sn phm kh duy nht l NO), c cn cn
thn ton b dung dch sau phn ng th khi lng mui khan thu c l
A. 20,16 gam.
B. 19,76 gam.
C. 19,20 gam.
D. 22,56 gam
153. (H A 13) Cho 12 gam hp kim ca bc vo dung dch HNO3 long (d), un nng
n phn ng han ton, thu c dung dch c 8,5 gam AgNO3. Phn trm khi
lng ca bc trong mu hp kim l
A. 45%.
B. 55%.
C. 30%.
D. 65%.
KIM LOI TC DNG PHI KIM
154. (H B 08) Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt
c dng rc ln thu ngn ri gom li l
A. ct.
B. mui n.
C. vi sng.
D. lu hunh.
155. (C 11) Cho hn hp X gm Cu, Ag, Fe, Al tc dng vi oxi d khi un nng c
cht rn Y. Cho Y vo dung dch HCl d, khuy k, sau ly dung dch thu c cho
tc dng vi dung dch NaOH long, d. Lc ly kt ta to thnh em nung trong
khng kh n khi lng khng i thu c cht rn Z. Bit cc phn ng xy ra
han ton. Thnh phn ca Z gm:
A. Fe2O3, CuO.
B. Fe2O3, CuO, Ag.
C. Fe2O3, Al2O3. D. Fe2O3, CuO, Ag2O.
156. (C 11) t chy han ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c
30,2 gam hn hp oxit. Th tch kh oxi (ktc) tham gia phn ng l
A. 4,48 lt.
B. 8,96 lt.
C. 17,92 lt.
D. 11,20 lt.
157. (H A 07) Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc
dng han ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam.
Th tch dung dch HCl 2M va phn ng ht vi Y l
A. 75 ml.
B. 50 ml.
C. 57 ml.
D. 90 ml.

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158. (C 10) Cho m gam bt crom phn ng han ton vi dung dch HCl (d), thu c
V lt kh H2 (ktc). Mt khc, cng m gam bt crom trn phn ng han ton vi kh O 2
(d), thu c 15,2 gam oxit duy nht. Gi tr ca V l
A. 2,24.
B. 4,48.
C. 3,36.
D. 6,72.
159. (C 09) Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh
O2, n khi cc phn ng xy ra han ton, thu c 23,2 gam cht rn X. Th tch
dung dch HCl 2M va phn ng vi cht rn X l
A. 200 ml.
B. 400 ml.
C. 800 ml.
D. 600 ml.
160. (C 12) Oxi ho han ton m gam kim loi X cn va 0,25m gam kh O2. X l kim
loi no sau y?
A. Cu.
B. Ca.
C. Al.
D. Fe.
161. (H B 10) Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau
mt thi gian thu c 2,71 gam hn hp Y. Ha tan han ton Y vo dung dch
HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3
phn ng l
A. 0,12.
B. 0,14.
C. 0,16.
D. 0,18.
162. (H B 10) Hn hp bt X gm Cu, Zn. t chy han ton m gam X trong oxi (d),
thu c 40,3 gam hn hp gm CuO v ZnO. Mt khc, nu cho 0,25 mol X phn
ng vi mt lng d dung dch KOH long nng, th thu c 3,36 lt kh H2 (ktc).
Phn trm khi lng ca Cu trong X l
A. 19,81%.
B. 29,72%.
C. 39,63%.
D. 59,44%.
163. (H B 12) t chy hn hp gm 1,92 gam Mg v 4,48 gam Fe vi hn hp kh X
gm clo v oxi, sau phn ng ch thu c hn hp Y gm cc oxit v mui clorua
(khng cn kh d). Ha tan Y bng mt lng va 120 ml dung dch HCl 2M, thu
c dung dch Z. Cho AgNO3 d vo dung dch Z, thu c 56,69 gam kt ta. Phn
trm th tch ca clo trong hn hp X l
A. 51,72%.
B. 76,70%.
C. 53,85%.
D. 56,36%.
164. (H B 12) t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp
cht rn Y. Cho Y vo nc d, thu c dung dch Z v 2,4 gam kim loi. Dung dch
Z tc dng c vi ti a 0,21 mol KMnO4 trong dung dch H2SO4 (khng to ra
SO2). Phn trm khi lng ca Fe trong hn hp X l
A. 72,91%.
B. 64,00%.
C. 66,67%.
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n tp Ha 12
D. 37,33%.
165. (C 09) t chy han ton 7,2 gam kim loi M (c ho tr hai khng i trong hp
cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th
tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l
A. Mg.
B. Cu.
C. Be.
D. Ca.
166. (C 13) Cho 7,84 lt hn hp kh X (ktc) gm Cl2 v O2 phn ng va vi 11,1
gam hn hp Y gm Mg v Al, thu c 30,1 gam hn hp Z. Phn trm khi lng
ca Al trong Y l
A. 75,68%.
B. 24,32%.
C. 51,35%.
D. 48,65%.
IU CH KIM LOI
167. (C 09) Nguyn tc chung c dng iu ch kim loi l
A. cho hp cht cha ion kim loi tc dng vi cht oxi ho.
B. cho hp cht cha ion kim loi tc dng vi cht kh.
C. kh ion kim loi trong hp cht thnh nguyn t kim loi.
D. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi.
168. (C 11) Dy gm cc oxit u b Al kh nhit cao l:
A. FeO, MgO, CuO.
B. PbO, K2O, SnO.
C. Fe3O4, SnO, BaO.
D. FeO, CuO, Cr2O3.
169. (C 12) Kim loi no sau y iu ch c bng phng php thy luyn?
A. Mg.
B. Ca.
C. Cu.
D. K.
170. (H A 12) Dy cc kim loi u c th c iu ch bng phng php in phn
dung dch mui (vi in cc tr) l:
A. Ni, Cu, Ag.
B. Ca, Zn, Cu.
C. Li, Ag, Sn.
D. Al, Fe, Cr.
171. (C 08) Hai kim loi c th c iu ch bng phng php in phn dung dch
l
A. Al v Mg.
B. Na v Fe.
C. Cu v Ag.
D. Mg v Zn.
TON KH OXIT KIM LOI BNG CO, H2,
172. (H B 12) Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt
thi gian thu c cht rn X v kh Y. Cho Y hp th han ton vo dung dch
Ba(OH)2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3
d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 2,24.
B. 4,48.
C. 6,72.
D. 3,36.
173. (H A 07) Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung
nhit cao. Sau phn ng hn hp rn cn li l:
A. Cu, Fe, Zn, Mg.
B. Cu, Fe, ZnO, MgO.
C. Cu, FeO, ZnO, MgO.
D. Cu, Fe, Zn, MgO.
174. (C 07) Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3,
MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k,
thy cn li phn khng tan Z. Gi s cc phn ng xy ra han ton. Phn khng
tan Z gm
A. MgO, Fe, Cu. B. Mg, Fe, Cu.
C. MgO, Fe3O4, Cu.
D. Mg, Al, Fe, Cu.
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175. (H A 08) Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d
hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra han ton,
khi lng hn hp rn gim 0,32 gam. Gi tr ca V l
A. 0,224.
B. 0,448.
C. 0,112.
D. 0,560.
176. (C 08) Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp
rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra han ton, thu
c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4
gam kt ta. Gi tr ca V l
A. 1,120.
B. 0,896.
C. 0,448.
D. 0,224.
177. (H A 09) Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung
nng n khi phn ng han ton, thu c 8,3 gam cht rn. Khi lng CuO c
trong hn hp ban u l
A. 0,8 gam.
B. 8,3 gam.
C. 2,0 gam.
D. 4,0 gam.
178. (H A 07) thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol
Ag2O), ngi ta ha tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung
dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%)
A. 2c mol bt Cu vo Y.
B. 2c mol bt Al vo Y.
C. c mol bt Al vo Y.
D. c mol bt Cu vo Y.
179. (H A 07) Ha tan han ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml
axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c
cn dung dch c khi lng l
A. 4,81 gam.
B. 5,81 gam.
C. 3,81 gam.
D. 6,81 gam.
180. (C 07) Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch
H2SO4 20% thu c dung dch mui trung ha c nng 27,21%. Kim loi M l
A. Cu.
B. Zn.
C. Fe.
D. Mg.
181. (H A 09) Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau:
Na2O v Al2O3; Cu v FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan
han ton trong nc (d) ch to ra dung dch l
A. 3.
B. 2.
C. 1.
D. 4.

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KIM LOI KIM KIM LOI KIM TH

GIO KHOA
182. (H B 11) Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l:
A. Na, K, Ca.
B. Na, K, Ba.
C. Li, Na, Mg.
D. Mg, Ca, Ba.
183. (C 11) Dy gm cc kim loi u c cu to mng tinh th lp phng tm khi l:
A. Na, K, Ca, Ba. B. Na, K, Ca, Be.
C. Li, Na, K, Mg. D. Li, Na, K, Rb.
184. (C 10) Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l:
A. Be, Mg, Ca.
B. Li, Na, K.
C. Na, K, Mg.
D. Li, Na, Ca.
185. (C 12) Pht biu no sau y l ng?
A. Trong hp cht, tt c cc kim loi kim u c s oxi ha +1.
B. Tt c cc kim loi nhm IIA u c mng tinh th lp phng tm khi.
C. Tt c cc hiroxit ca kim loi nhm IIA u d tan trong nc.
D. Trong nhm IA, tnh kh ca cc kim loi gim dn t Li n Cs.
186. (H B 12) Khi ni v kim loi kim, pht biu no sau y l sai?
A. Cc kim loi kim c mu trng bc v c nh kim.
B. Trong t nhin, cc kim loi kim ch tn ti dng hp cht.
C. T Li n Cs kh nng phn ng vi nc gim dn.
D. Kim loi kim c nhit nng chy v nhit si thp.
187. (H B 11) Pht biu no sau y l sai?
A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim
gim dn.
B. nhit thng, tt c cc kim loi kim th u tc dng c vi nc.
C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thu tinh.
D. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al 2O3 bn
vng bo v.
188. (C 07) Trong cng nghip, natri hiroxit c sn xut bng phng php
A. in phn dd NaCl, khng c mng ngn in cc.
B. in phn dd NaNO3, khng c mng ngn in cc.
C. in phn dd NaCl, c mng ngn in cc.
D. in phn NaCl nng chy.
189. (C 07) Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c
th l
A. NaOH v NaClO.
B. Na2CO3 v NaClO.
C. NaClO3 v Na2CO3.
D. NaOH v Na2CO3.
190. (H A 08) T hai mui X v Y thc hin cc phn ng sau:
o

t
X
X1 + CO2 ;

X1 + H2 O X2;

X2 + Y X + Y1 + H2O;
X2 + 2Y X + Y2 + 2H2O
Hai mui X, Y tng ng l
A. BaCO3, Na2CO3.
B. CaCO3, NaHCO3.
C. MgCO3, NaHCO3.
D. CaCO3, NaHSO4.
+X
+Y
+Z
191. (C 10) Cho s chuyn ho sau: CaO
CaCl2
Ca(NO3 )2
CaCO3
Cng thc ca X, Y, Z ln lt l:
A. HCl, HNO3, Na2CO3.
B. Cl2, AgNO3, MgCO3.
C. HCl, AgNO3, (NH4)2CO3.
D. Cl2, HNO3, CO2.
192. (H B 07) Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u
bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha
A. NaCl, NaOH. B. NaCl.
C. NaCl, NaHCO3, NH4Cl, BaCl2.
D. NaCl, NaOH, BaCl2.
193. (H B 09) Thc hin cc th nghim sau:
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(I) Cho dung dch NaCl vo dung dch KOH.
(II) Cho dung dch Na2CO3 vo dung dch Ca(OH)2.
(III) in phn dung dch NaCl vi in cc tr, c mng ngn.
(IV) Cho Cu(OH)2 vo dung dch NaNO3.
(V) Sc kh NH3 vo dung dch Na2CO3.
(VI) Cho dung dch Na2SO4 vo dung dch Ba(OH)2.
Cc th nghim u iu ch c NaOH l:
A. II, III v VI.
B. I, II v III.
C. I, IV v V.
D. II, V v VI.
194. (H B 11) Thc hin cc th nghim sau:
(a) Nung NH4NO3 rn.
(b) un nng NaCl tinh th vi dung dch H2SO4 (c).
(c) Sc kh Cl2 vo dung dch NaHCO3.
(d) Sc kh CO2 vo dung dch Ca(OH)2 (d).
(e) Sc kh SO2 vo dung dch KMnO4.
(g) Cho dung dch KHSO4 vo dung dch NaHCO3.
(h) Cho PbS vo dung dch HCl (long).
(i) Cho Na2SO3 vo dung dch H2SO4 (d), un nng.
S th nghim sinh ra cht kh l
A. 4.
B. 6.
C. 5.
D. 2.
195. (H B 08) Phn ng nhit phn khng ng l
o

t
A. NaHCO3
NaOH + CO2.
o

t
B. NH4NO2
N2 + 2H2O.
o

t
t
C. NH4Cl
D. 2KNO3
NH3 + HCl.
2KNO2 + O2.
196. (C 09) Ch dng dung dch KOH phn bit c cc cht ring bit trong nhm
no sau y?
A. Fe, Al2O3, Mg. B. Mg, Al2O3, Al.
C. Zn, Al2O3, Al. D. Mg, K, Na.
197. (H A 10) Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht
tc dng c vi dung dch NaOH long nhit thng l
A. 4.
B. 5.
C. 3.
D. 6.
198. (C 13) Dung dch no di y khi phn ng han ton vi dung dch NaOH d,
thu c kt ta trng?
A. Ca(HCO3)2. B. FeCl3.
C. AlCl3.
D. H2SO4.
199. (H A 11) Phn chua c dng trong ngnh cng nghip thuc da, cng nghip
giy, cht cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ho hc
ca phn chua l
A. (NH4)2SO4.Al2(SO4)3.24H2O.
B. K2SO4.Al2(SO4)3.24H2O.
C. Na2SO4.Al2(SO4)3.24H2O.
D. Li2SO4.Al2(SO4)3.24H2O.
200. (H A 11) Hp cht no ca canxi c dng c tng, b bt khi gy xng?
A. Vi sng (CaO).
B. vi (CaCO3).
C. Thch cao sng (CaSO4.2H2O).
D. Thch cao nung (CaSO4.H2O).
201. (H B 11) Khi in phn dung dch NaCl (cc m bng st, cc dng bng than
ch, c mng ngn xp) th
A. cc dng xy ra qu trnh oxi ho ion Na + v cc m xy ra qu trnh kh

ion Cl .
B. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ho
ion Cl .
C. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion
Cl.
D. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion

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Cl .
202. (C 09) Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch
NaOH l:
A. NaHCO3, ZnO, Mg(OH)2.
B. Mg(OH)2, Al2O3, Ca(HCO3)2.
C. NaHCO3, Ca(HCO3)2, Al2O3.
D. NaHCO3, MgO, Ca(HCO3)2.
NC CNG
203. (C 08) Hai cht c dng lm mm nc cng vnh cu l
A. Na2CO3 v HCl.
B. Na2CO3 v Na3PO4.
C. Na2CO3 v Ca(OH)2.
D. NaCl v Ca(OH)2.
204. (H B 08) Mt mu nc cng cha cc ion: Ca2+, Mg2+, HCO3, Cl, SO42. Cht
c dng lm mm mu nc cng trn l
A. Na2CO3.
B. H2SO4.
C. NaHCO3.
D. HCl.
205. (H A 11) Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l:
A. NaOH, Na3PO4, Na2CO3.
B. HCl, Ca(OH)2, Na2CO3.
C. KCl, Ca(OH)2, Na2CO3.
D. HCl, NaOH, Na2CO3.
206. (C 11) Mt cc nc c cha cc ion: Na+ (0,02 mol), Mg2+(0,02 mol), Ca2+ (0,04
mol), Cl (0,02 mol), HCO3 (0,10 mol) v SO42 (0,01 mol). un si cc nc trn cho
n khi cc phn ng xy ra han ton th nc cn li trong cc
A. l nc mm. B. c tnh cng vnh cu.
C. c tnh cng ton phn.
D. c tnh cng tm thi.
207. (H B 13) Mt loi nc cng khi un si th mt tnh cng. Trong loi nc cng
ny c ha tan nhng hp cht no sau y?
A. Ca(HCO3)2, Mg(HCO3)2.
B. Ca(HCO3)2, MgCl2.
C. CaSO4, MgCl2. D. Mg(HCO3)2, CaCl2.
XC NH KIM LOI
208. (H B 13) Khi ha tan han ton m gam mi kim loi vo nc d, t kim loi no
sau y thu c th tch kh H2 (cng iu kin nhit v p sut) l nh nht?
A. K.
B. Na.
C. Li.
D. Ca.
209. (C 12) Ha tan han ton 1,1 gam hn hp gm mt kim loi kim X v mt kim
loi kim th Y (MX < MY) trong dung dch HCl d, thu c 1,12 lt kh H2 (ktc). Kim
loi X l
A. Li.
B. Na.
C. Rb.
D. K.
210. (H B 07) Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm
IIA (phn nhm chnh nhm II) tc dng ht vi dung dch HCl (d), thot ra 0,672 lt
kh H2 ( ktc). Hai kim loi l
A. Mg v Ca.
B. Ca v Sr.
C. Sr v Ba.
D. Be v Mg.
211. (H B 08) Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim
M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. Rb.
B. K.
C. Li.
D. Na.
212. (H B 09) Ha tan han ton 2,9 gam hn hp gm kim loi M v oxit ca n vo
nc, thu c 500 ml dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh
H2 ( ktc). Kim loi M l
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n tp Ha 12
A. Na.
B. Ca.
C. Ba.
D. K.
213. (H A 10) Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y
tc dng ht vi lng d dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X,
Y l
A. kali v bari.
B. liti v beri.
C. natri v magie.
D. kali v canxi.
214. (H B 10) Ha tan han ton 2,45 gam hn hp X gm hai kim loi kim th vo 200
ml dung dch HCl 1,25M, thu c dung dch Y cha cc cht tan c nng mol
bng nhau. Hai kim loi trong X l
A. Mg v Ca.
B. Be v Mg.
C. Mg v Sr.
D. Be v Ca.
215. (C 10) Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H 2SO4 (d),
thu c dung dch cha 7,5 gam mui sunfat trung ha. Cng thc ca mui
hirocacbonat l
A. NaHCO3.
B. Ca(HCO3)2.
C. Ba(HCO3)2.
D. Mg(HCO3)2.
216. (C 11) Ha tan han ton 6,645 gam hn hp mui clorua ca hai kim loi kim
thuc hai chu k k tip nhau vo nc c dung dch X. Cho ton b dung dch X
tc dng han ton vi dung dch AgNO3 (d), thu c 18,655 gam kt ta. Hai kim
loi kim trn l
A. Rb v Cs.
B. Na v K.
C. Li v Na.
D. K v Rb.
217. (H B 13) Ha tan han ton 24 gam hn hp X gm MO, M(OH)2 v MCO3 (M l
kim loi c ha tr khng i) trong 100 gam dung dch H2SO4 39,2%, thu c 1,12 lt
kh (ktc) v dung dch Y ch cha mt cht tan duy nht c nng 39,41%. Kim loi
M l
A. Zn.
B. Ca.
C. Mg.
D. Cu.
KIM LOI KIM/TH + AXIT/ NC
218. (C 07) Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X
v 3,36 lt H2 ( ktc). Th tch dung dch axit H2SO4 2M cn dng trung ha dung
dch X l
A. 150ml.
B. 75ml.
C. 60ml.
D. 30ml.
219. (H A 10) Ha tan han ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu
c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol
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n tp Ha 12
tng ng l 4 : 1. Trung ha dung dch X bi dung dch Y, tng khi lng cc mui
c to ra l
A. 13,70 gam.
B. 12,78 gam.
C. 18,46 gam.
D. 14,62 gam.
220. Ha tan ht mt lng hn hp gm K v Na vo H 2O d, thu c dung dch X v
0,672 lt kh H2 (ktc). Cho X vo dung dch FeCl3 d, n khi phn ng xy ra hon
ton, thu c m gam kt ta. Gi tr ca m l
A. 2,14.
B. 6,42.
C. 1,07.
D. 3,21.
221. (H B 13) Hn hp X gm hai kim loi kim v mt kim loi kim th. Ha tan hon
ton 1,788 gam X vo nc, thu c dung dch Y v 537,6 ml kh H2 (ktc). Dung
dch Z gm H2SO4 v HCl, trong s mol ca HCl gp hai ln s mol ca H2SO4.
Trung ha dung dch Y bng dung dch Z to ra m gam hn hp mui. Gi tr ca m l
A. 4,460.
B. 4,656.
C. 3,792.
D. 2,790.
222. (C 12) Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 :
1). Cho X tc dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc
dng vi dung dch H2SO4 long (d) thu c 0,25V lt kh. Bit cc kh o cng
iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe v Al trong X
tng ng l
A. 16 : 5.
B. 5 : 16.
C. 1 : 2.
D. 5 : 8.
223. (C 07) Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung
dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch
dng l
A. 0,75M.
B. 1M.
C. 0,25M.
D. 0,5M.
224. (C 13) Cho 50 ml dung dch HNO3 1M vo 100 ml dung dch KOH nng x mol/l,
sau phn ng thu c dung dch ch cha mt cht tan duy nht. Gi tr ca x l
A. 0,5.
B. 0,3.
C. 0,8.
D. l,0.
225. (C 07) Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M
thu c dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu
c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l
A. 1,59.
B. 1,17.
C. 1,71.
D. 1,95.
226. (C 11) Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d
thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht
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n tp Ha 12
rn khan. Ha tan hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho
t t n ht dung dch Z vo 0,5 lt dung dch CrCl3 1M n phn ng hon ton thu
c kt ta c khi lng l
A. 54,0 gam.
B. 20,6 gam.
C. 30,9 gam.
D. 51,5 gam.
CO2 + DUNG DCH NaOH/Ca(OH)2
227. (H B 13) Hp th hon ton 2,24 lt kh CO2 (ktc) vo 750 ml dung dch Ba(OH)2
0,2M, thu c m gam kt ta. Gi tr ca m l
A. 29,55.
B. 19,70.
C. 9,85.
D. 39,40.
228. (C 13) Hp th hon ton 2,24 lt kh CO2 (ktc) vo dung dch Ca(OH)2 d, thu
c m gam kt ta. Gi tr ca m l
A. 19,70.
B. 10,00.
C. 1,97.
D. 5,00.
229. (H B 12) Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v
NaOH 0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr
ca m l
A. 19,70.
B. 23,64.
C. 7,88.
D. 13,79.
230. (H A 08) Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp
gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l
A. 9,85.
B. 17,73.
C. 19,70.
D. 11,82.
231. (H A 09) Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn
hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l
A. 1,182.
B. 3,940.
C. 1,970.
D. 2,364.
232. (C 10) Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M,
thu c dung dch X. Coi th tch dung dch khng thay i, nng mol ca cht
tan trong dung dch X l
A. 0,6M.
B. 0,2M.
C. 0,1M.
D. 0,4M.
233. (H A 11) Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH
0,025M v Ca(OH)2 0,0125M, thu c x gam kt ta. Gi tr ca x l
A. 0,75.
B. 1,25.
C. 2,00.
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n tp Ha 12
D. 1,00.
234. (H A 13) Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X
vo nc, thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam
Ba(OH)2. Hp th hon ton 6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta.
Gi tr ca m l
A. 15,76.
B. 39,40.
C. 21,92.
D. 23,64.
235. (C 12) Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200 ml dung dch gm NaOH
0,1M v KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao
nhiu gam cht rn khan?
A. 2,58 gam.
B. 2,22 gam.
C. 2,31 gam.
D. 2,44 gam.
236. (H A 07) Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2
nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l
A. 0,032.
B. 0,06.
C. 0,04.
D. 0,048.
237. (H B 11) Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3
0,2M v KOH x mol/lt, sau khi cc phn ng xy ra hon ton thu c dung dch Y.
Cho ton b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt ta. Gi tr
ca x l
A. 1,6.
B. 1,2.
C. 1,0.
D. 1,4.
MUI CACBONAT HIROCACBONAT
238. (H A 10) Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c
2 lt dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl 2 (d) thu c
11,82 gam kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un
nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng
ng l
A. 0,08 v 4,8.
B. 0,04 v 4,8.
C. 0,14 v 2,4.
D. 0,07 v 3,2.
239. (H B 13) Cho 200 ml dung dch Ba(OH)2 0,1M vo 300 ml dung dch NaHCO3 0,1M,
thu c dung dch X v kt ta Y. Cho t t dung dch HCl 0,25M vo X n khi bt
u c kh sinh ra th ht V ml. Bit cc phn ng u xy ra hon ton. Gi tr ca V
l
A. 80.
B. 40.
C. 160.
D. 60.
240. (C 09) Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2
gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l
A. 39,4.
B. 19,7.
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C. 15,5.
D. 17,1.

n tp Ha 12

AXIT + MUI CACBONAT/ HIROCACBONAT

(H A 07) Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3
ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi
trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l:
A. V = 11,2(a - b).
B. V = 22,4(a - b).
C. V = 22,4(a + b).
D. V = 11,2(a + b).
242. (H A 09) Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t
tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt
kh ( ktc). Gi tr ca V l
A. 4,48.
B. 3,36.
C. 2,24.
D. 1,12.
243. (H A 10) Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch
cha Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,020.
B. 0,030.
C. 0,015.
D. 0,010.
244. (C 13) Ha tan hon ton 20,6 gam hn hp gm Na 2CO3 v CaCO3 bng dung
dch HCl d, thu c V lt kh CO2 (ktc) v dung dch cha 22,8 gam hn hp mui.
Gi tr ca V l
A. 4,48.
B. 1,79.
C. 5,60.
D. 2,24.
245. (H A 12) Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch
Ba(HCO3)2 thu c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo
bnh n khi khng cn kh thot ra th ht 560 ml. Bit ton b Y phn ng va
vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l
A. 3,94 gam.
B. 7,88 gam.
C. 11,28 gam.
D. 9,85 gam.
NHIT PHN MUI KIM LOI KIM/TH
246. (H B 07) Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu
c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch
NaOH 1M, khi lng mui khan thu c sau phn ng l
A. 6,3 gam.
B. 5,8 gam.
C. 6,5 gam.
D. 4,2 gam.
247. (H B 08) Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr
sinh ra 8,96 lt kh CO2 ( ktc). Thnh phn phn trm v khi lng ca
CaCO3.MgCO3 trong loi qung nu trn l
A. 50%.
B. 40%.
C. 84%.
THPT Tn Tc
32
241.

Vng Quc Vit

n tp Ha 12
D. 92%.
248. (H B 11) Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v
m gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi
cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H 2 l 16.
Thnh phn % theo khi lng ca KMnO4 trong X l
A. 74,92%.
B. 72,06%.
C. 27,94%.
D. 62,76%.
249. (H A 10) Pht biu no sau y ng?
A. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n
bari) c nhit nng chy gim dn.
B. Kim loi xesi c dng ch to t bo quang in.
C. Kim loi magie c kiu mng tinh th lp phng tm din.
D. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng.

THPT Tn Tc

33

Vng Quc Vit

n tp Ha 12

NHM
GIO KHOA
250. (H B 13) Cho phng trnh phn ng aAl + bHNO3 cAl(NO3)3 + dNO + eH2O. T
l a : b l
A. 1 : 3.
B. 2 : 3.
C. 2 : 5.
D. 1 : 4.
251. (H B 13) Cho s phn ng: Al2(SO4)3 X Y Al. Trong s trn, mi mi
tn l mt phn ng, cc cht X, Y ln lt l nhng cht no sau y?
A. NaAlO2 v Al(OH)3.
B. Al(OH)3 v NaAlO2.
C. Al2O3 v Al(OH)3.
D. Al(OH)3 v Al2O3.
252. (C 10) Nh t t dung dch NaOH n d vo dung dch X. Sau khi cc phn ng
xy ra hon ton ch thu c dung dch trong sut. Cht tan trong dung dch X l
A. AlCl3.
B. CuSO4.
C. Ca(HCO3)2.
D. Fe(NO3)3.
253. (H B 10) Pht biu no sau y khng ng khi so snh tnh cht ha hc ca
nhm v crom?
A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui.
B. Nhm c tnh kh mnh hn crom.
C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol.
D. Nhm v crom u bn trong khng kh v trong nc.
254. (H A 07) Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng
xy ra l
A. c kt ta keo trng v c kh bay ln.
B. c kt ta keo trng, sau kt ta tan.
C. ch c kt ta keo trng.
D. khng c kt ta, c kh bay ln.
255. (H B 09) Th nghim no sau y c kt ta sau phn ng?
A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.
B. Cho dung dch NH3 n d vo dung dch AlCl3.
C. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
D. Thi CO2 n d vo dung dch Ca(OH)2.
256. (C 13) Pht biu no sau y khng ng?
A. Trong cng nghip, kim loi Al c iu ch bng phng php in phn Al 2O3
nng chy.
B. Al(OH)3 phn ng c vi dung dch HCl v dung dch KOH.
C. Kim loi Al tan c trong dung dch HNO3 c, ngui.
D. Trong cc phn ng ha hc, kim loi Al ch ng vai tr cht kh.
257. (H A 07) Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu
c kt ta th cn c t l
A. a : b = 1 : 4.
B. a : b < 1 : 4.
C. a : b = 1 : 5.
D. a : b > 1 : 4.
258. (C 10) Ha tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c
dung dch X v cht rn Y. Sc kh CO2 n d vo dung dch X, sau khi cc phn
ng xy ra hon ton thu c kt ta l
A. Fe(OH)3.
B. K2CO3.
C. Al(OH)3.
D. BaCO3.
259. (H B 07) thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt:
A. dng kh CO nhit cao, dung dch HCl (d).
B. dng kh H2 nhit cao, dung dch NaOH (d).
C. dng dung dch NaOH (d), dung dch HCl (d), ri nung nng.
D. dng dung dch NaOH (d), kh CO2 (d), ri nung nng.
NHM V HP CHT TC DNG AXIT
260. (C 08) Chia m gam Al thnh hai phn bng nhau:
- Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh H2;
- Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn
THPT Tn Tc

34

Vng Quc Vit

n tp Ha 12
phm kh duy nht). Quan h gia x v y l
A. x = 2y.
B. y = 2x.
C. x = 4y.
D. x = y.
261. (H A 09) Ha tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu
c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi
ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn
khan. Gi tr ca m l
A. 38,34.
B. 34,08.
C. 106,38.
D. 97,98.
262. (H A 13) Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376
lt (ktc) hn hp kh X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X
so vi H2 bng 18. Gi tr ca m l
A. 21,60.
B. 18,90.
C. 17,28.
D. 19,44.
263. (H A 09) Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung
dch H2SO4 10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau
phn ng l
A. 101,68 gam.
B. 88,20 gam.
C. 101,48 gam.
D. 97,80 gam.
264. (H A 13) Ha tan hon ton 1,805 gam hn hp gm Fe v kim loi X bng dung
dch HCl, thu c 1,064 lt kh H2. Mt khc, ha tan hon ton 1,805 gam hn hp
trn bng dung dch HNO3 long (d), thu c 0,896 lt kh NO (sn phm kh duy
nht). Bit cc th tch kh u o iu kin tiu chun. Kim loi X l
A. Zn.
B. Cr.
C. Al.
D. Mg.
265. (C 10) Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl
(d), thu c V lt kh H2 (ktc) v dung dch X. Nh t t dung dch NH3 n d vo
dung dch X thu c kt ta, lc ht lng kt ta, nung n khi lng khng i
thu c 2,04 gam cht rn. Gi tr ca V l
A. 0,448.
B. 0,224.
C. 1,344.
D. 0,672.
266. (H A 08) Ha tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH
(d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X,
lng kt ta thu c l 46,8 gam. Gi tr ca a l
A. 0,45.
B. 0,40.
C. 0,55.
D. 0,60.
267. (H A 13) Cho 25,5 gam hn hp X gm CuO v Al2O3 tan hon ton trong dung
dch H2SO4 long, thu c dung dch cha 57,9 gam mui. Phn trm khi lng
ca Al2O3 trong X l
A. 60%.
B. 40%.
THPT Tn Tc

35

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C. 80%.
D. 20%.
268.

269.

270.

271.

272.

273.

274.

n tp Ha 12

HN HP (Al/Al2O3 V KLK/KLK TH) + H2O

(C 12) Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 :
1). Cho X tc dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc
dng vi dung dch H2SO4 long (d) thu c 0,25V lt kh. Bit cc kh o cng
iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe v Al trong X
tng ng l
A. 16 : 5.
B. 5 : 16.
C. 1 : 2.
D. 5 : 8.
(H A 12) Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu
c dung dch X trong sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th
bt u xut hin kt ta; khi ht 300 ml hoc 700 ml th u thu c a gam kt ta.
Gi tr ca a v m ln lt l
A. 15,6 v 27,7.
B. 23,4 v 35,9.
C. 23,4 v 56,3.
D. 15,6 v 55,4.
(H B 07) Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot
ra V lt kh. Nu cng cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh.
Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th tch kh o
trong cng iu kin)
A. 39,87%.
B. 29,87%.
C. 49,87%.
D. 77,31%.
(H A 08) Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc
(d). Sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m
gam cht rn khng tan. Gi tr ca m l
A. 43,2.
B. 7,8.
C. 5,4.
D. 10,8.
(C 09) Ha tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c
200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO 2 (d)
vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l
A. 8,3 v 7,2.
B. 8,2 v 7,8.
C. 11,3 v 7,8.
D. 13,3 v 3,9.
(H A 13) Hn hp X gm Ba v Al. Cho m gam X vo nc d, sau khi cc phn
ng xy ra hon ton, thu c 8,96 lt kh H2 (ktc). Mt khc, ha tan hon ton m
gam X bng dung dch NaOH, thu c 15,68 lt kh H2 (ktc). Gi tr ca m l
A. 16,4.
B. 29,9.
C. 24,5.
D. 19,1.
(C 13) Hn hp X gm Ba, Na v Al, trong s mol ca Al bng 6 ln s mol ca
Ba. Cho m gam X vo nc d n phn ng hon ton, thu c 1,792 lt kh H 2
(ktc) v 0,54 gam cht rn. Gi tr ca m l
A. 3,90.
B. 5,27.
C. 3,45.

THPT Tn Tc

36

Vng Quc Vit

D. 3,81.

n tp Ha 12

TNH LNG TNH Al(OH)3, Al2O3

275. ((H B 07) Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH
0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l
A. 1,2.
B. 1,8.
C. 2.
D. 2,4.
276. (H A 08) Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al 2(SO4)3 v
0,1 mol H2SO4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht
ca V thu c lng kt ta trn l
A. 0,45.
B. 0,25.
C. 0,05.
D. 0,35.
277. (C 09) Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol
FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m
l
A. 4,128.
B. 1,560.
C. 5,064.
D. 2,568.
278. (H A 12) Cho 500 ml dung dch Ba(OH)2 0,1M vo V ml dung dch Al2(SO4)3 0,1M;
sau khi cc phn ng kt thc thu c 12,045 gam kt ta. Gi tr ca V l
A. 300.
B. 75.
C. 200.
D. 150.
279. (H B 11) Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng
vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam
kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl 2 (d) th thu c
33,552 gam kt ta. T l x : y l
A. 3 : 4.
B. 3 : 2.
C. 4 : 3.
D. 7 : 4.
280. (C 09) Ha tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu
c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau
phn ng thu c m gam kt ta. Gi tr ca m l
A. 54,4.
B. 62,2.
C. 46,6.
D. 7,8.
281. (H B 10) Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3
nng x mol/l, thu c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip
175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca x l
A. 1,2.
B. 0,8.
C. 0,9.
D. 1,0.
282. (H B 13) Th tch dung dch NaOH 0,25M cn cho vo 15 ml dung dch Al2(SO4)3
0,5M thu c lng kt ta ln nht l
THPT Tn Tc
37

Vng Quc Vit

A. 210 ml.
B. 60 ml.
C. 90 ml.
D. 180 ml.
283.

284.

285.

286.

287.

288.

n tp Ha 12

PHN NG NHIT NHM

(C 07) Phn ng ho hc xy ra trong trng hp no di y khng thuc loi
phn ng nhit nhm?
A. Al tc dng vi Fe3O4 nung nng.
B. Al tc dng vi CuO nung nng.
C. Al tc dng vi Fe2O3 nung nng.
D. Al tc dng vi axit H2SO4 c, nng.
(H A 12) Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn
ng nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c
hn hp gm
A. Al, Fe, Fe3O4 v Al2O3.
B. Al2O3, Fe v Fe3O4.
C. Al2O3 v Fe.
D. Al, Fe v Al2O3.
(C 09) iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm
vi hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l
A. 40,5 gam.
B. 81,0 gam.
C. 54,0 gam.
D. 45,0 gam.
(H B 07) Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau
khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X
phn ng vi axit HCl (d) thot ra V lt kh H2 ( ktc). Gi tr ca V l
A. 4,48.
B. 3,36.
C. 7,84.
D. 10,08.
(C 11) Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng
c khng kh), sau khi phn ng xy ra hon ton thu c cht rn Y. Khi lng
kim loi trong Y l
A. 16,6 gam.
B. 11,2 gam.
C. 5,6 gam.
D. 22,4 gam.
(C 12) Nung hn hp bt gm Al v Fe2O3 (trong iu kin khng c oxi), thu c
hn hp cht rn X. Chia X thnh 2 phn bng nhau:
- Cho phn 1 vo dung dch HCl (d) thu c 7,84 lt kh H2 (ktc);
- Cho phn 2 vo dung dch NaOH (d) thu c 3,36 lt kh H2 (ktc).
Bit rng cc phn ng u xy ra hon ton. Phn trm khi lng ca Fe trong X

l
A. 33,61%.
B. 42,32%.
C. 66,39%.
D. 46,47%.
289. (H B 12) Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c
khng kh) n khi phn ng xy ra hon ton. Chia hn hp thu c sau phn ng
thnh hai phn bng nhau. Phn mt phn ng va vi 300 ml dung dch NaOH
1M (long). ha tan ht phn hai cn va dung dch cha a mol HCl. Gi tr ca
a l
A. 0,9.
THPT Tn Tc
38

Vng Quc Vit

n tp Ha 12
B. 1,3.
C. 0,5.
D. 1,5.
290. (H B 11) Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam
Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X.
Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng
xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu cho ton b X vo mt lng
d dung dch NaOH (c, nng), sau khi cc phn ng kt thc th s mol NaOH
phn ng l
A. 0,14 mol.
B. 0,08 mol.
C. 0,16 mol.
D. 0,06 mol.
291. (H A 08) Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c
khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh
hai phn bng nhau:
- Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc);
- Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc).
Gi tr ca m l
A. 29,43.
B. 29,40.
C. 22,75.
D. 21,40.
292. (C 08) t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c
khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc
dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l
A. 150.
B. 100.
C. 200.
D. 300.
293. (H B 09) Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c
khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc
dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 (
ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.
B. 48,3.
C. 36,7.
D. 57,0.
294. (H B 10) Trn 10,8 gam bt Al vi 34,8 gam bt Fe 3O4 ri tin hnh phn ng nhit
nhm trong iu kin khng c khng kh. Ha tan hon ton hn hp rn sau phn
ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc). Hiu sut ca
phn ng nhit nhm l
A. 80%.
B. 90%.
C. 70%.
D. 60%.
295. (H A 13) Hn hp X gm 3,92 gam Fe, 16 gam Fe2O3 v m gam Al. Nung X nhit
cao trong iu kin khng c khng kh, thu c hn hp cht rn Y. Chia Y
thnh hai phn bng nhau. Phn mt tc dng vi dung dch H2SO4 long (d), thu
c 4a mol kh H2. Phn hai phn ng vi dung dch NaOH d, thu c a mol kh
H2. Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 3,51.
THPT Tn Tc

39

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B. 4,05.
C. 5,40.
D. 7,02.

THPT Tn Tc

n tp Ha 12

40

Vng Quc Vit

296.

297.

298.

299.

300.

301.

302.

n tp Ha 12

ST NG V HP CHT
GIO KHOA
(H A 13) Kim loi st tc dng vi dung dch no sau y to ra mui st(II)?
A. HNO3 c, nng, d.
B. CuSO4.
C. H2SO4 c, nng, d.
D. MgSO4.
(C 08) Cho s chuyn ho (mi mi tn l mt phng trnh phn ng): NaOH
dd X
dd Y
dd Z

Fe(OH)2
Fe2(SO4)3
BaSO4. Cc dd (dung dch) X, Y, Z ln
lt l:
A. FeCl3, H2SO4 (c, nng), Ba(NO3)2.
B. FeCl3, H2SO4 (c, nng), BaCl2.
C. FeCl2, H2SO4 (c, nng), BaCl2.
D. FeCl2, H2SO4 (long), Ba(NO3)2.
(H A 11) Thc hin cc th nghim sau:
(1) t dy st trong kh clo.
(2) t nng hn hp bt Fe v S (trong iu kin khng c oxi).
(3) Cho FeO vo dung dch HNO3 (long, d).
(4) Cho Fe vo dung dch Fe2(SO4)3.
(5) Cho Fe vo dung dch H2SO4 (long, d).
C bao nhiu th nghim to ra mui st(II)?
A. 1.
B. 2.
C. 3.
D. 4.
(C 12) Dung dch long (d) no sau y tc dng c vi kim loi st to thnh
mui st(III)?
A. H2SO4.
B. HNO3.
C. FeCl3.
D. HCl.
(H B 10) Cho s chuyn ho: Fe3O4 + dung dch HI (d) X + Y + H2O. Bit X
v Y l sn phm cui cng ca qu trnh chuyn ho. Cc cht X v Y l
A. Fe v I2.
B. FeI3 v FeI2.
C. FeI2 v I2.
D. FeI3 v I2.
(H B 11) Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch
FeCl2 l:
A. Bt Mg, dung dch BaCl2, dung dch HNO3.
B. Kh Cl2, dung dch Na2CO3, dung dch HCl.
C. Bt Mg, dung dch NaNO3, dung dch HCl.
D. Kh Cl2, dung dch Na2S, dung dch HNO3.
+ FeCl
t
+ CO d, t
Y Z
(H B 12) Cho s chuyn ho: Fe(NO3)3
X
o

+T
Fe(NO3)3.

Cc cht X v T ln lt l
A. FeO v NaNO3.
B. FeO v AgNO3.
C. Fe2O3 v Cu(NO3)2.
D. Fe2O3 v AgNO3.
303. (C 07) Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi
dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta
cng c mui Y. Kim loi M c th l
A. Mg.
B. Zn.
C. Al.
D. Fe.
304. (C 08) Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch
X1. Cho lng d bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n
khi phn ng xy ra hon ton, thu c dung dch X2 cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v H2SO4.
305. (H A 11) Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d)
thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH
(long, d) thu c kt ta
A. Fe(OH)3.
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n tp Ha 12
B. Fe(OH)3 v Zn(OH)2.
C. Fe(OH)2, Cu(OH)2 v Zn(OH)2.
D. Fe(OH)2 v Cu(OH)2.
306. (H B 08) Nguyn tc luyn thp t gang l:
A. Tng thm hm lng cacbon trong gang thu c thp.
B. Dng cht kh CO kh oxit st thnh st nhit cao.
C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c
thp.
D. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp.
307. (H A 11) Qung st manhetit c thnh phn chnh l
A. FeCO3.
B. FeS2.
C. Fe3O4.
D. Fe2O3.
308. (H A 08) Trong cc loi qung st, qung c hm lng st cao nht l
A. manhetit.
B. hematit .
C. xierit.
D. hematit nu.
309. (H A 12) Qung no sau y giu st nht?
A. Xierit.
B. Manhetit.
C. Hematit .
D. Pirit st.
310. (C 10) Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn
hp gm HCl v NaNO3. Nhng dung dch phn ng c vi kim loi Cu l:
A. (1), (3), (5).
B. (1), (2), (3).
C. (1), (3), (4).
D. (1), (4), (5).
311. (H A 09) Trng hp xy ra phn ng l
A. Cu + Pb(NO3)2 (long)
B. Cu + HCl (long)
C. Cu + H2SO4 (long)
D. Cu + HCl (long) + O2
312. (H A 08) Cho s chuyn ho qung ng thnh ng:
+ O , to

+ O , to

+ X, t
2
2
CuFeS2
X
Y
Cu. Hai cht X, Y ln lt l:

A. Cu2S, CuO.
B. Cu2O, CuO.
C. Cu2S, Cu2O.
D. CuS, CuO.
313. (C 10) Cht rn X phn ng vi dung dch HCl c dung dch Y. Cho t t dung
dch NH3 n d vo dung dch Y, ban u xut hin kt ta xanh, sau kt ta tan,
thu c dung dch mu xanh thm. Cht X l
A. FeO.
B. Cu.
C. CuO.
D. Fe.
314. (H B 09) Ho tan m gam hn hp gm Al, Fe vo dung dch H 2SO4 long (d). Sau
khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2
(d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng
khng i, thu c cht rn Z l
A. hn hp gm BaSO4 v FeO.
B. hn hp gm Al2O3 v Fe2O3.
C. hn hp gm BaSO4 v Fe2O3.
D. Fe2O3.
315. (C 13) Pht biu no sau y khng ng?
A. Kim loi Fe phn ng vi dung dch HCl to ra mui st(II).
B. Dung dch FeCl3 phn ng c vi kim loi Fe.
C. Kim loi Fe khng tan trong dung dch H2SO4 c, ngui.
D. Trong cc phn ng ha hc, ion Fe2+ ch th hin tnh kh.
316. (C 13) Thc hin cc th nghim sau:
(a) Sc kh Cl2 vo dung dch NaOH nhit thng.
(b) Cho Fe3O4 vo dung dch HCl long (d).
(c) Cho Fe3O4 vo dung dch H2SO4 c, nng (d).
(d) Ha tan ht hn hp Cu v Fe2O3 (c s mol bng nhau) vo dung dch H2SO4
long (d).
Trong cc th nghim trn, sau phn ng, s th nghim to ra hai mui l
A. 2.
B. 4.
C. 1.
D. 3.
317. (H B 13) Ha tan hon ton x mol Fe vo dung dch cha y mol FeCl 3 v z mol
HCl, thu c dung dch ch cha mt cht tan duy nht. Biu thc lin h gia x, y
v z l
A. 2x = y + 2z.
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n tp Ha 12
B. 2x = y + z.
C. x = y 2z.
D. y = 2x.
318. (H B 13) Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d), thu c
dung dch X. Trong cc cht: NaOH, Cu, Fe(NO3)2, KMnO4, BaCl2, Cl2 v Al, s cht
c kh nng phn ng c vi dung dch X l
A. 4.
B. 6.
C. 5.
D. 7.
319. (C 08) Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO 3)2, dung
dch HNO3 (c, ngui). Kim loi M l
A. Al.
B. Zn.
C. Fe.
D. Ag.
320. (H B 08) Cht phn ng vi dung dch FeCl3 cho kt ta l
A. CH3NH2.
B. CH3COOH.
C. CH3OH.
D. CH3COOCH3.
321. (H A 09) Trng hp no sau y khng xy ra phn ng ho hc?
A. Sc kh Cl2 vo dung dch FeCl2.
B. Sc kh H2S vo dung dch CuCl2.
C. Sc kh H2S vo dung dch FeCl2.
D. Cho Fe vo dung dch H2SO4 long, ngui.
322. (H B 08) Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng
c vi Cu(OH)2 l
A. 2.
B. 3.
C. 4.
D. 1.
TON OXIT ST
323. (H A 08) ho tan hon ton 2,32 gam hn hp gm FeO, Fe 3O4 v Fe2O3 (trong
s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr
ca V l
A. 0,08.
B. 0,18.
C. 0,23.
D. 0,16.
324. (H A 08) Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi
dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht,
ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l
A. 49,09.
B. 34,36.
C. 35,50.
D. 38,72.
325. (H B 07) Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha
tan ht hn hp X trong dung dch HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn
phm kh duy nht). Gi tr ca m l
A. 2,62.
B. 2,32.
C. 2,22.
D. 2,52.
326. (H B 08) Cho 9,12 gam hn hp gm FeO, Fe 2O3, Fe3O4 tc dng vi dung dch
HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu
c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l
A. 6,50.
B. 7,80.
C. 9,75.
D. 8,75.
327. (H B 09) Ha tan hon ton 20,88 gam mt oxit st bng dung dch H 2SO4 c,
nng thu c dung dch X v 3,248 lt kh SO 2 (sn phm kh duy nht, ktc). C
cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l
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n tp Ha 12
A. 52,2.
B. 54,0.
C. 58,0.
D. 48,4.
328. (H B 12) t 5,6 gam Fe trong khng kh, thu c hn hp cht rn X. Cho ton
b X tc dng vi dung dch HNO3 long (d), thu c kh NO (sn phm kh duy
nht) v dung dch cha m gam mui. Gi tr ca m l
A. 18,0.
B. 22,4.
C. 15,6.
D. 24,2.
329. (C 09) Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung
dch HCl 2M, thu c dung dch Y c t l s mol Fe 2+ v Fe3+ l 1 : 2. Chia Y thnh
hai phn bng nhau. C cn phn mt thu c m 1 gam mui khan. Sc kh clo (d)
vo phn hai, c cn dung dch sau phn ng thu c m 2 gam mui khan. Bit m2
m1 = 0,71. Th tch dung dch HCl dng l
A. 320 ml.
B. 80 ml.
C. 240 ml.
D. 160 ml.
330. (H B 13) Cho m gam mt oxit st phn ng va vi 0,75 mol H2SO4, thu c
dung dch ch cha mt mui duy nht v 1,68 lt kh SO 2 (ktc, sn phm kh duy
nht ca S+6). Gi tr ca m l
A. 24,0.
B. 34,8.
C. 10,8.
D. 46,4.
331. (H B 13) Hn hp X gm FeO, Fe2O3 v Fe3O4. Cho kh CO qua m gam X nung
nng, sau mt thi gian thu c hn hp cht rn Y v hn hp kh Z. Cho ton b
Z vo dung dch Ca(OH)2 d, n phn ng hon ton, thu c 4 gam kt ta. Mt
khc, ha tan hon ton Y trong dung dch H2SO4 c, nng (d), thu c 1,008 lt
kh SO2 (ktc, sn phm kh duy nht) v dung dch cha 18 gam mui. Gi tr ca m
l
A. 6,80.
B. 7,12.
C. 13,52.
D. 5,68.
332. (C 13) Hn hp X gm FeCl2 v NaCl c t l mol tng ng l 1 : 2. Ha tan hon
ton 2,44 gam X vo nc, thu c dung dch Y. Cho Y phn ng hon ton vi
dung dch AgNO3 d, thu c m gam cht rn. Gi tr ca m l
A. 5,74.
B. 2,87.
C. 6,82.
D. 10,80.
333. (C 11) Ho tan hon ton hn hp X gm 0,2 mol Fe v 0,2 mol Fe 2O3 vo dung
dch axit H2SO4 long (d), thu c 2,24 lt kh (ktc) v dung dch Y. Cho lng d
dung dch NaOH vo dung dch Y, sau khi phn ng xy ra hon ton thu c m
gam kt ta. Gi tr nh nht ca m l
A. 57,4.
B. 59,1.
C. 60,8.
D. 54,0.
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n tp Ha 12
334. (H B 07) Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng
(d), thot ra 0,112 lt ( ktc) kh SO2 (l sn phm kh duy nht). Cng thc ca
hp cht st l
A. FeO.
B. FeS2.
C. FeS.
D. FeCO3.
335. (H B 09) Cho 61,2 gam hn hp X gm Cu v Fe 3O4 tc dng vi dung dch HNO3
long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36
lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi.
C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
336. (H B 10) Ho tan hon ton 2,44 gam hn hp bt X gm Fe xOy v Cu bng dung
dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO 2 (sn phm kh
duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi
lng ca Cu trong X l
A. 39,34%.
B. 65,57%.
C. 26,23%.
D. 13,11%.
337. (H B 11) luyn c 800 tn gang c hm lng st 95%, cn dng x tn
qung manhetit cha 80% Fe3O4 (cn li l tp cht khng cha st). Bit rng lng
st b hao ht trong qu trnh sn xut l 1%. Gi tr ca x l
A. 1394,90.
B. 1325,16.
C. 1311,90.
D. 959,59.
HP CHT VI LU HUNH
338. (H A 11) Nung m gam hn hp X gm FeS v FeS 2 trong mt bnh kn cha khng
kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton,
thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N 2,
14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l
A. 26,83%.
B. 19,64%.
C. 59,46%.
D. 42,31%.
339. (H B 08) Nung mt hn hp rn gm a mol FeCO 3 v b mol FeS2 trong bnh kn
cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit
ban u, thu c cht rn duy nht l Fe 2O3 v hn hp kh. Bit p sut kh trong
bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn
ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k)
A. a = 2b.
B. a = 0,5b.
C. a = b.
D. a = 4b.
340. (H B 12) Ho tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn
phm thu c gm dung dch X v mt cht kh thot ra. Dung dch X c th ha tan
ti a m gam Cu. Bit trong cc qu trnh trn, sn phm kh duy nht ca u l NO.
Gi tr ca m l
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n tp Ha 12
A. 12,8.
B. 6,4.
C. 9,6.
D. 3,2.
341. (H A 07) Ho tan hon ton hn hp gm 0,12 mol FeS 2 v a mol Cu2S vo axit
HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO.
Gi tr ca a l
A. 0,12.
B. 0,04.
C. 0,075.
D. 0,06.
342. (C 13) Ha tan ht 0,2 mol FeO bng dung dch H2SO4 c, nng (d), thu c
kh SO2 (sn phm kh duy nht). Hp th hon ton kh SO 2 sinh ra trn vo dung
dch cha 0,07 mol KOH v 0,06 mol NaOH, thu c dung dch cha m gam mui.
Gi tr ca m l
A. 15,32.
B. 12,18.
C. 19,71.
D. 22,34.
343. (H A 12) Cho 18,4 gam hn hp X gm Cu 2S, CuS, FeS2 v FeS tc dng ht vi
HNO3 (c nng, d) thu c V lt kh ch c NO2 ( ktc, sn phm kh duy nht)
v dung dch Y. Cho ton b Y vo mt lng d dung dch BaCl2, thu c 46,6
gam kt ta; cn khi cho ton b Y tc dng vi dung dch NH 3 d thu c 10,7 gam
kt ta. Gi tr ca V l
A. 38,08.
B. 24,64.
C. 16,8.
D. 11,2.
BI TP LIN QUAN KMnO4
344. (C 10) Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 +
H2O. Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn
ng l
A. 23.
B. 27.
C. 47.
D. 31.
345. (H B 11) Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2
+ KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho
hc ca phn ng trn l
A. 27.
B. 24.
C. 34.
D. 31.
346. (H B 10) Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung
dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn
ng oxi ho - kh l
A. 3.
B. 5.
C. 4.
D. 6.
347. (C 12) Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh
th KNO3 to thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to
thnh kh Z. Cc kh X, Y v Z ln lt l
A. SO2, O2 v Cl2. B. H2, NO2 v Cl2.
C. H2, O2 v Cl2. D. Cl2, O2 v H2S.
348. (C 11) Cho 3,16 gam KMnO4 tc dng vi dung dch HCl c (d), sau khi phn
ng xy ra hon ton th s mol HCl b oxi ha l
A. 0,10.
B. 0,05.
C. 0,02.
D. 0,16.
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349. (H A 07) Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung
dch X. Dung dch X phn ng va vi V ml dung dch KMnO 4 0,5M. Gi tr ca V
l
A. 20.
B. 80.
C. 40.
D. 60.
350. (H A 11) Ho tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch
H2SO4 (long, rt d), sau khi cc phn ng kt thc ch thu c dung dch X. Dung
dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l
A. 1,24.
B. 3,2.
C. 0,96.
D. 0,64.
351. (H B 11) Ho tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c
150 ml dung dch Y. Thm H2SO4 (d) vo 20 ml dung dch Y ri chun ton b
dung dch ny bng dung dch KMnO4 0,1M th dng ht 30 ml dung dch chun. Phn
trm khi lng FeSO4 trong hn hp X l
A. 68,4%.
B. 9,12%.
C. 31,6%.
D. 13,68%.
352. (H A 09) Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn
hp rn (c cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t
chy l
A. 95,00%.
B. 25,31%.
C. 74,69%.
D. 64,68%.
353. (H B 11) Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v
m gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi
cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16.
Thnh phn % theo khi lng ca KMnO4 trong X l
A. 74,92%.
B. 72,06%.
C. 27,94%.
D. 62,76%.
354. (H B 12) t 16,2 gam hn hp X gm Al v Fe trong kh Cl 2 thu c hn hp
cht rn Y. Cho Y vo nc d, thu c dung dch Z v 2,4 gam kim loi. Dung dch
Z tc dng c vi ti a 0,21 mol KMnO4 trong dung dch H2SO4 (khng to ra
SO2). Phn trm khi lng ca Fe trong hn hp X l
A. 72,91%.
B. 64,00%.
C. 66,67%.
D. 37,33%.

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CROM V HP CHT CA CROM

355. (C 10) Pht biu no sau y khng ng?
A. Ancol etylic bc chy khi tip xc vi CrO3.
B. Crom(III) oxit v crom(III) hiroxit u l cht c tnh lng tnh.
C. Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+.
D. Crom(VI) oxit l oxit baz.
356. (H A 07) Pht biu khng ng l:
A. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat.
B. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh.
C. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh.
D. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng
c vi dung dch NaOH.
357. (H B 12) Pht biu no sau y l sai?
A. Clo c dng dit trng nc trong h thng cung cp nc sch.
B. Amoniac c dng iu ch nhin liu cho tn la.
C. Lu hunh ioxit c dng lm cht chng nm mc.
D. Ozon trong khng kh l nguyn nhn chnh gy ra s bin i kh hu.
358. (H A 11) Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch
Na2CrO4 l:
A. Dung dch chuyn t khng mu sang mu da cam.
B. Dung dch chuyn t mu vng sang khng mu.
C. Dung dch chuyn t mu da cam sang mu vng.
D. Dung dch chuyn t mu vng sang mu da cam.
359. (C 11) Khi cho lng d dung dch KOH vo ng nghim ng dung dch kali
icromat, dung dch trong ng nghim
A. chuyn t mu da cam sang mu vng.
B. chuyn t mu vng sang mu .
C. chuyn t mu da cam sang mu xanh lc.
D. chuyn t mu vng sang mu da cam.
+ Cl (d)
+ KOH (ac, d) + Cl
X
Y. Bit Y l hp cht
360. (C 12) Cho s phn ng: Cr
t
t
2

ca crom. Hai cht X v Y ln lt l

A. CrCl2 v Cr(OH)3.
B. CrCl3 v K2Cr2O7.
C. CrCl3 v K2CrO4.
D. CrCl2 v K2CrO4.
361. (H B 09) Cho s chuyn ho gia cc hp cht ca crom:
+ (Cl2 + KOH)
+ H2SO4
+ (FeSO4 + H2SO4 )
+ KOH
Cr(OH)3
X
Y
Z
T

362.

363.

Cc cht X, Y, Z, T theo th t l:
A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3.
B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3.
C. KCrO2; K2Cr2O7; K2CrO4; CrSO4.
D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3.
(H A 13) Cho phng trnh phn ng:
aFeSO4 + bK2Cr2O7 + cH2SO4 dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O.
T l a : b l
A. 6 : 1.
B. 2 : 3.
C. 3 : 2.
D. 1 : 6.
+ Cl d
+ dung dch NaOH d
X
(H A 13) Cho s phn ng: Cr
Y. Cht Y trong s
t
t
2
o

trn l
A. Na[Cr(OH)4]. B. Na2Cr2O7.
C. Cr(OH)2.
D. Cr(OH)3.
364. (C 10) Cho m gam bt crom phn ng hon ton vi dung dch HCl (d), thu c
V lt kh H2 (ktc). Mt khc, cng m gam bt crom trn phn ng hon ton vi kh O 2
THPT Tn Tc
48

Vng Quc Vit

n tp Ha 12
(d), thu c 15,2 gam oxit duy nht. Gi tr ca V l
A. 2,24.
B. 4,48.
C. 3,36.
D. 6,72.
365. (H A 08) oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt
KOH, lng ti thiu Cl2 v KOH tng ng l
A. 0,03 mol v 0,04 mol.
B. 0,03 mol v 0,08 mol.
C. 0,015 mol v 0,08 mol.
D. 0,015 mol v 0,04 mol.
366. (C 11) Ho tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d
thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht
rn khan. Ho tan hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho
t t n ht dung dch Z vo 0,5 lt dung dch CrCl3 1M n phn ng hon ton thu
c kt ta c khi lng l
A. 54,0 gam.
B. 20,6 gam.
C. 30,9 gam.
D. 51,5 gam.
367. (H A 10) C cc pht biu sau:
(1) Lu hunh, photpho u bc chy khi tip xc vi CrO3.
(2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O.
Cc pht biu ng l:
A. (1), (2), (3).
B. (1), (3), (4).
C. (2), (3), (4).
D. (1), (2), (4).
368. (H B 10) Pht biu no sau y khng ng khi so snh tnh cht ha hc ca
nhm v crom?
A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui.
B. Nhm c tnh kh mnh hn crom.
C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol.
D. Nhm v crom u bn trong khng kh v trong nc.
369. (H B 10) Pht biu no sau y khng ng?
A. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh
chuyn thnh mui Cr(VI).
B. Do Pb2+/Pb ng trc 2H+/H2 trong dy in ho nn Pb d dng phn ng vi
dung dch HCl long ngui, gii phng kh H2.
C. CuO nung nng khi tc dng vi NH3 hoc CO, u thu c Cu.
D. Ag khng phn ng vi dung dch H 2SO4 long nhng phn ng vi dung dch
H2SO4 c nng.
370. (H B 11) Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht
trong dy tc dng c vi dung dch NaOH (c, nng) l
A. 4.
B. 6.
C. 3.
D. 5.
371. (H A 12) Nhn xt no sau y khng ng?
A. Vt dng lm bng nhm v crom u bn trong khng kh v nc v c mng
oxit bo v.
B. Crom l kim loi cng nht trong tt c cc kim loi.
C. Nhm v crom u b th ng ha bi HNO3 c, ngui.
D. Nhm v crom u phn ng vi dung dch HCl theo cng t l s mol.
372. (H A 12) Nhn xt no sau y khng ng?
A. BaSO4 v BaCrO4 hu nh khng tan trong nc.
B. Al(OH)3 v Cr(OH)3 u l hiroxit lng tnh v c tnh kh.
C. SO3 v CrO3 u l oxit axit.
THPT Tn Tc

49

Vng Quc Vit

n tp Ha 12
D. Fe(OH)2 v Cr(OH)2 u l baz v c tnh kh.
373. (H B 12) Pht biu no sau y l ng?
A. Tt c cc phn ng ca lu hunh vi kim loi u cn un nng.
B. Trong cng nghip, nhm c sn xut t qung olomit.
C. Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc.
D. CrO3 tc dng vi nc to ra hn hp axit.
374. (H B 12) Pht biu no sau y l sai?
A. Cr(OH)3 tan trong dung dch NaOH.
B. Trong mi trng axit, Zn kh Cr3+ thnh Cr.
C. Photpho bc chy khi tip xc vi CrO3.
D. Trong mi trng kim, Br2 oxi ha CrO2 thnh CrO42.
375. (C 13) Pht biu no sau y khng ng?
A. Cu(OH)2 tan c trong dung dch NH3.
B. Cr(OH)2 l hiroxit lng tnh.
C. Kim loi Cu phn ng c vi dung dch hn hp KNO3 v HCl.
D. Kh NH3 kh c CuO nung nng.
376. (H A 13) Cho cc pht biu sau:
(a) Trong bng tun hon cc nguyn t ha hc, crom thuc chu k 4, nhm VIB.
(b) Cc oxit ca crom u l oxit baz.
(c) Trong cc hp cht, s oxi ha cao nht ca crom l +6.
(d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha.
(e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom(III).
Trong cc pht biu trn, nhng pht biu ng l:
A. (b), (c) v (e). B. (a), (c) v (e).
C. (b), (d) v (e). D. (a), (b) v (e).

THPT Tn Tc

50

Vng Quc Vit

377.

378.

379.

380.

381.

382.

383.

384.

385.

386.

387.

388.

n tp Ha 12

CU TO NGUYN T - BNG TUN HON

GIO KHOA
(H B 07) Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh
nhm VIII), theo chiu tng ca in tch ht nhn nguyn t th
A. tnh kim loi tng dn, bn knh nguyn t gim dn.
B. tnh kim loi tng dn, m in tng dn.
C. m in gim dn, tnh phi kim tng dn.
D. tnh phi kim gim dn, bn knh nguyn t tng dn.
(C 07) Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m
in ca cc nguyn t tng dn theo th t
A. M < X < Y < R. B. R < M < X < Y.
C. Y < M < X < R.
D. M < X < R < Y.
(H A 08) Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo
th t tng dn t tri sang phi l
A. Li, Na, O, F.
B. F, Na, O, Li.
C. F, Li, O, Na.
D. F, O, Li, Na.
(H B 08) Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang
phi l:
A. N, P, O, F.
B. N, P, F, O.
C. P, N, F, O.
D. P, N, O, F.
(H B 09) Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy
gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri
sang phi l:
A. N, Si, Mg, K. B. K, Mg, Si, N.
C. K, Mg, N, Si. D. Mg, K, Si, N.
(H A 10) Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th
A. bn knh nguyn t tng, m in gim.
B. bn knh nguyn t v m in u tng.
C. bn knh nguyn t gim, m in tng.
D. bn knh nguyn t v m in u gim.
55
26
(H A 10) Nhn nh no sau y ng khi ni v 3 nguyn t: 26
13 X, 26Y, 12 Z ?
A. X v Z c cng s khi.
B. X, Z l 2 ng v ca cng mt nguyn t ho hc.
C. X, Y thuc cng mt nguyn t ho hc.
D. X v Y c cng s ntron.
(H B 07) Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation
bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp
cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l
A. LiF.
B. NaF.
C. AlN.
D. MgO.
(C 11) Trong bng tun han cc nguyn t ho hc, nguyn t X nhm IIA,
nguyn t Y nhm VA. Cng thc ca hp cht to thnh t 2 nguyn t trn c
dng l
A. X2Y3.
B. X2Y5.
C. X3Y2.
D. X5Y2.
CU HNH ELECTRON
(C 13) trng thi c bn, nguyn t ca nguyn t X c 4 electron lp L (lp
th hai). S proton c trong nguyn t X l
A. 7.
B. 6.
C. 8.
D. 5.
(H A 13) trng thi c bn, cu hnh electron ca nguyn t Na (Z = 11) l
A. 1s22s22p53s2.
B. 1s22s22p63s1.
2
2
6
2
C. 1s 2s 2p 3s .
D. 1s22s22p43s1.
(H B 13) S proton v s ntron c trong mt nguyn t nhm ( 27
13 Al ) ln lt l
A. 13 v 14.

THPT Tn Tc

B. 13 v 15.

C. 12 v 14.

D. 13 v 13.
51

Vng Quc Vit

n tp Ha 12
+
389. (H A 12) Nguyn t R to c cation R . Cu hnh electron phn lp ngoi
cng ca R+ ( trng thi c bn) l 2p6. Tng s ht mang in trong nguyn t R l
A. 10.
B. 11.
C. 22.
D. 23.
+

390. (H A 07) Dy gm cc ion X , Y v nguyn t Z u c cu hnh electron

1s22s22p6 l:
A. Li+, F, Ne.
B. Na+, F, Ne.
C. K+, Cl, Ar.
D. Na+, Cl, Ar.
2+
391. (H A 07) Anion X v cation Y u c cu hnh electron lp ngoi cng l 3s23p6.
V tr ca cc nguyn t trong bng tun han cc nguyn t ha hc l:
A. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th
t 20, chu k 3, nhm IIA (phn nhm chnh nhm II).
B. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th
t 20, chu k 4, nhm IIA (phn nhm chnh nhm II).
C. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th
t 20, chu k 4, nhm IIA (phn nhm chnh nhm II).
D. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s
th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II).
392. (C 08) Nguyn t ca nguyn t X c cu hnh electron 1s22s22p63s23p64s1,
nguyn t ca nguyn t Y c cu hnh electron 1s22s22p5. Lin kt ho hc gia
nguyn t X v nguyn t Y thuc loi lin kt
A. kim loi.
B. cng ho tr.
C. ion.
D. cho nhn.
2+
2
2
6
2
393. (H A 09) Cu hnh electron ca ion X l 1s 2s 2p 3s 3p63d6. Trong bng tun
han cc nguyn t ho hc, nguyn t X thuc
A. chu k 4, nhm VIIIA.
B. chu k 4, nhm IIA.
C. chu k 3, nhm VIB.
D. chu k 4, nhm VIIIB.
394. (C 10) Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l:
1s22s22p63s1; 1s22s22p63s2; 1s22s22p63s23p1. Dy gm cc kim loi xp theo chiu
tng dn tnh kh t tri sang phi l:
A. Z, Y, X.
B. X, Y, Z.
C. Y, Z, X.
D. Z, X, Y.
2+
3+
395. (H A 11) Cu hnh electron ca ion Cu v Cr ln lt l
A. [Ar]3d74s2 v [Ar]3d3.
B. [Ar]3d9 v [Ar]3d3.
C. [Ar]3d9 v [Ar]3d14s2.
D. [Ar]3d74s2 v [Ar]3d14s2.
TNG S HT
396. (C 09) Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52
v c s khi l 35. S hiu nguyn t ca nguyn t X l
A. 17.
B. 23.
C. 18.
D. 15.
397. (H B 10) Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht
mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t
M l
A. [Ar]3d54s1.
B. [Ar]3d64s2.
C. [Ar]3d64s1.
D. [Ar]3d34s2.
398. (C 12) Nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52.
Trong ht nhn nguyn t X c s ht khng mang in nhiu hn s ht mang in
l 1. V tr (chu k, nhm) ca X trong bng tun han cc nguyn t ha hc l
A. chu k 3, nhm VA.
B. chu k 3, nhm VIIA.
C. chu k 2, nhm VIIA.
D. chu k 2, nhm VA.
THPT Tn Tc

52

Vng Quc Vit

n tp Ha 12
399. (H A 12) X v Y l hai nguyn t thuc cng mt chu k, hai nhm A lin tip. S
proton ca nguyn t Y nhiu hn s proton ca nguyn t X. Tng s ht proton
trong nguyn t X v Y l 33. Nhn xt no sau y v X, Y l ng?
A. n cht X l cht kh iu kin thng.
B. m in ca X ln hn m in ca Y.
C. Lp ngoi cng ca nguyn t Y ( trng thi c bn) c 5 electron.
D. Phn lp ngoi cng ca nguyn t X ( trng thi c bn) c 4 electron.
400. (C 08) Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l
7. S ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt
nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t ca
nguyn t:
A. Fe v Cl.
B. Na v Cl.
C. Al v Cl.
D. Al v P.
401. (C 09) Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p.
Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron
lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X,
Y ln lt l
A. kim loi v kim loi.
B. kh him v kim loi.
C. kim loi v kh him.
D. phi kim v kim loi.
OXIT CAO NHT HP CHT KH VI HIRO
(H A 12) Phn trm khi lng ca nguyn t R trong hp cht kh vi hiro (R c
s oxi ha thp nht) v trong oxit cao nht tng ng l a% v b%, vi a : b = 11 : 4.
Pht biu no sau y l ng?
A. Phn t oxit cao nht ca R khng c cc.
B. Oxit cao nht ca R iu kin thng l cht rn.
C. Trong bng tun han, R thuc chu k 3.
D. Nguyn t R ( trng thi c bn) c 6 electron s.
403. (H B 12) Nguyn t Y l phi kim thuc chu k 3, c cng thc oxit cao nht l YO3.
Nguyn t Y to vi kim loi M hp cht c cng thc MY, trong M chim 63,64%
v khi lng. Kim loi M l
A. Zn.
B. Cu.
C. Mg.
D. Fe.
404. (H B 08) Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3.
Trong oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R
l
A. As.
B. N.
C. P.
D. S.
405. (H A 09) Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns 2np4.
Trong hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm
khi lng ca nguyn t X trong oxit cao nht l
A. 50,00%.
B. 27,27%.
C. 60,00%.
D. 40,00%.
NG V
402.

THPT Tn Tc

53

Vng Quc Vit

n tp Ha 12
63
65
406. (C 07) Trong t nhin, nguyn t ng c hai ng v l 29 Cu v 29 Cu . Nguyn t
khi trung bnh ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng
63
Cu l
v 29

407.

A. 27%.
B. 50%.
C. 54%.
D. 73%.
(H B 11) Trong t nhin clo c hai ng v bn:
t, cn li l

35
17

37
17

Cl chim 24,23% tng s nguyn

Cl . Thnh phn % theo khi lng ca

37
17

Cl trong HClO4 l

A. 8,43%.
B. 8,79%.
C. 8,92%.
D. 8,56%.
408.

409.

410.
411.

412.

413.

414.

415.

416.

417.

LIN KT HA HC
(C 12) Cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn
t ch cha lin kt cng ha tr khng cc l
A. 3.
B. 4.
C. 5.
D. 2.
(H B 11) Pht biu no sau y l sai?
A. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht.
B. Tt c cc tinh th phn t u kh nng chy v kh bay hi.
C. Tinh th nc , tinh th iot u thuc loi tinh th phn t.
D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho
tr.
(H A 08) Hp cht trong phn t c lin kt ion l
A. HCl.
B. NH4Cl.
C. H2O.
D. NH3.
(H B 09) Pht biu no sau y l ng?
A. Photpho trng c cu trc tinh th nguyn t.
B. th rn, NaCl tn ti di dng tinh th phn t.
C. Nc thuc loi tinh th phn t.
D. Kim cng c cu trc tinh th phn t.
(C 09) Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l:
A. HF, Cl2, H2O. B. O2, H2O, NH3.
C. H2O, HF, H2S. D. HCl, O3, H2S.
(H B 10) Cc cht m phn t khng phn cc l:
A. HBr, CO2, CH4.
B. Cl2, CO2, C2H2.
C. NH3, Br2, C2H4.
D. HCl, C2H2, Br2.
(C 10) Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt
A. cng ho tr khng phn cc.
B. cng ho tr phn cc.
C. hiro.
D. ion.
(H A 13) Lin kt ha hc gia cc nguyn t trong phn t HCl thuc loi lin kt
A. cng ha tr c cc.
B. hiro.
C. cng ha tr khng cc.
D. ion.
(H B 13) Cho gi tr m in ca cc nguyn t: F (3,98); O (3,44); C (2,55); H
(2,20); Na (0,93). Hp cht no sau y l hp cht ion?
A. NaF.
B. CO2.
C. CH4.
D. H2O.
(C 13) Lin kt ha hc trong phn t Br2 thuc loi lin kt
A. ion.
B. hiro.
C. cng ha tr khng cc.
D. cng ha tr c cc.
PHN NG OXI HA KH

THPT Tn Tc

54

Vng Quc Vit

n tp Ha 12
418. (C 11) Cho cc cht: KBr, S, SiO2, P, Na3PO4, FeO, Cu v Fe2O3. Trong cc cht
trn, s cht c th b oxi ha bi dung dch axit H2SO4 c, nng l
A. 4.
B. 5.
C. 7.
D. 6.
419. (C 11) Kh no sau y khng b oxi ho bi nc Gia-ven?
A. SO2.
B. CO2.
C. HCHO.
D. H2S.
420. (C 09) Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm
thnh v c th c dng lm cht ty mu. Kh X l
A. SO2.
B. O3.
C. NH3.
D. CO2.
421. (H A 12) Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2?
A. Dung dch BaCl2, CaO, nc brom.
B. Dung dch NaOH, O2, dung dch KMnO4.
C. O2, nc brom, dung dch KMnO4.
D. H2S, O2, nc brom.
422. (C 07) SO2 lun th hin tnh kh trong cc phn ng vi
A. H2S, O2, nc Br2.
B. dung dch NaOH, O2, dung dch KMnO4.
C. dung dch KOH, CaO, nc Br2.
D. O2, nc Br2, dung dch KMnO4.
423. (H A 07) Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh
n khi lng khng i, thu c mt cht rn l
A. FeO.
B. Fe3O4.
C. Fe2O3.
D. Fe.
424. (C 08) Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht
trong dy b oxi ha khi tc dng vi dung dch HNO3 c, nng l
A. 3.
B. 5.
C. 4
D. 6.
425. (H B 12) Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ha tan cng s mol
mi cht vo dung dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l
A. Fe3O4.
B. Fe(OH)2.
C. FeS.
D. FeCO3.
426. (H A 07) Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2,
Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn
ng thuc loi phn ng oxi ho - kh l
A. 7.
B. 6.
C. 8.
D. 5.
427. (H B 07) Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th
mt phn t CuFeS2 s
A. nhng 12 electron.
B. nhn 13 electron.
C. nhn 12 electron.
D. nhng 13 electron.
428. (H B 12) Cho cc cht ring bit sau: FeSO4, AgNO3, Na2SO3, H2S, HI, Fe3O4,
Fe2O3 tc dng vi dung dch H2SO4 c, nng. S trng hp xy ra phn ng oxi
ho - kh l
A. 6.
B. 3.
C. 4.
D. 5.
429. (H B 08) Cho cc phn ng:
(1) Ca(OH)2 + Cl2 CaOCl2 + H2O;
(2) 2H2S + SO2 3S + 2H2O;
(3) 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O;
o

t
KCl + 3KClO4;
(4) 4KClO3

(5) O3 O2 + O.
S phn ng oxi ho kh l
A. 5.
B. 4.
C. 2.
D. 3.
430. (H B 10) Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung
dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn
ng oxi ho - kh l
A. 3.
B. 5.
C. 4.
D. 6.
THPT Tn Tc

55

Vng Quc Vit

431. (H A 07) Cho cc phn ng sau:
a) FeO + HNO3 (c, nng)
c) Al2O3 + HNO3 (c, nng)

n tp Ha 12
b) FeS + H2SO4 (c, nng)
d) Cu + dung dch FeCl3

Ni, t
e) CH3CHO + H2

f) glucoz + AgNO3 (hoc Ag2O) trong dd NH3

g) C2H4 + Br2
h) glixerol (glixerin) + Cu(OH)2
Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l:
A. a, b, c, d, e, h. B. a, b, c, d, e, g.
C. a, b, d, e, f, g. D. a, b, d, e, f, h.
432. (H A 13) Tin hnh cc th nghim sau:
(a) Sc kh etilen vo dung dch KMnO4 long.
(b) Cho hi ancol etylic i qua bt CuO nung nng.
(c) Sc kh etilen vo dung dch Br2 trong CCl4.
(d) Cho dung dch glucoz vo dung dch AgNO3 trong NH3 d, un nng.
(e) Cho Fe2O3 vo dung dch H2SO4 c, nng.
Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l
A. 3.
B. 4.
C. 2.
D. 5.
433. (H A 09) Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn
ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.
B. MnO2.
C. CaOCl2.
D. K2Cr2O7.
434. (H A 09) Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu2+, Cl-. S cht v
ion c c tnh oxi ha v tnh kh l
A. 7.
B. 5.
C. 4.
D. 6.
435. (H B 08) Cho dy cc cht v ion: Cl2, F2, SO2, Na+, Ca2+, Fe2+, Al3+, Mn2+, S2, Cl.
S cht v ion trong dy u c tnh oxi ho v tnh kh l
A. 5.
B. 4.
C. 3.
D. 6.
2+
436. (H A 11) Cho dy cc cht v ion: Fe, Cl2, SO2, NO2, C, Al, Mg , Na+, Fe2+, Fe3+.
S cht v ion va c tnh oxi ho, va c tnh kh l
A. 6.
B. 4.
C. 5.
D. 8.
437. (H A 10) Thc hin cc th nghim sau:
(I) Sc kh SO2 vo dung dch KMnO4.
(II) Sc kh SO2 vo dung dch H2S.
(III) Sc hn hp kh NO2 v O2 vo nc.
(IV) Cho MnO2 vo dung dch HCl c, nng.
(V) Cho Fe2O3 vo dung dch H2SO4 c, nng.
(VI) Cho SiO2 vo dung dch HF.
S th nghim c phn ng oxi ho - kh xy ra l
A. 6.
B. 5.
C. 4.
D. 3.
438. (C 10) Nguyn t S ng vai tr va l cht kh, va l cht oxi ho trong phn
ng no sau y?
A. S + 2Na Na2S.
B. S + 6HNO3 (c) H2SO4 + 6NO2 + 2H2O.
C. 4S + 6NaOH(c) 2Na2S + Na2S2O3 + 3H2O.
D. S + 3F2 SF6.
439. (H B 10) Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH .
Phn ng ny chng t C6H5-CHO
A. va th hin tnh oxi ho, va th hin tnh kh.
B. ch th hin tnh oxi ho.
C. ch th hin tnh kh.
THPT Tn Tc

56

Vng Quc Vit

n tp Ha 12
D. khng th hin tnh kh v tnh oxi ho.
440. (C 13) Cho cc phng trnh phn ng:
(a) 2Fe + 3Cl2 2FeCl3.
(b) NaOH + HCl NaCl + H2O.
(c) Fe3O4 + 4CO 3Fe + 4CO2.
(d) AgNO3 + NaCl AgCl + NaNO3.
Trong cc phn ng trn, s phn ng oxi ha - kh l
A. 2.
B. 1.
C. 3.
D. 4.
441. (C 11) Cho phn ng: 6FeSO4 + K2Cr2O7 + 7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3 +
K2SO4 + 7H2O. Trong phn ng trn, cht oxi ha v cht kh ln lt l
A. K2Cr2O7 v FeSO4.
B. K2Cr2O7 v H2SO4.
C. H2SO4 v FeSO4.
D. FeSO4 v K2Cr2O7.
t
442. (C 12) Cho phn ng ha hc: Cl2 + KOH
KCl + KClO3 + H2O. T l gia s
nguyn t clo ng vai tr cht oxi ha v s nguyn t clo ng vai tr cht kh
trong phng trnh ha hc ca phn ng cho tng ng l
A. 1 : 5.
B. 5 : 1.
C. 3 : 1.
D. 1 : 3.
443. ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca
k l
A. 3/14.
B. 4/7.
C. 1/7.
D. 3/7.
444. (H A 13) Cho phng trnh phn ng:
aFeSO4 + bK2Cr2O7 + cH2SO4 dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O.
T l a : b l
A. 6 : 1.
B. 2 : 3.
C. 3 : 2.
D. 1 : 6.
445. (H B 13) Cho phng trnh phn ng aAl + bHNO3 cAl(NO3)3 + dNO + eH2O. T
l a : b l
A. 1 : 3.
B. 2 : 3.
C. 2 : 5.
D. 1 : 4.
446. (H A 12) Cho cc phn ng sau:
(a) H2S + SO2 (b) Na2S2O3 + dd H2SO4 (long)
(c) SiO2 + Mg
to
(d) Al2O3 + dung dch NaOH

1:2
o

(e) Ag + O3
S phn ng to ra n cht l
A. 3.
B. 6.
447.

(g) SiO2 + dung dch HF

C. 5.

D. 4.
to

t
(H B 07) Cho cc phn ng: (1) Cu2O + Cu2S
; (2) Cu(NO3)2
; (3) CuO
o

t
t
+ CO
; (4) CuO + NH3
S phn ng to ra kim loi Cu l

448.

449.

450.

A. 3.
B. 1.
C. 2.
D. 4.
(H B 12) Cho phng trnh ha hc (vi a, b, c, d l cc h s):
aFeSO4 + bCl2 cFe2(SO4)3 + dFeCl3. T l a : c l
A. 4 : 1.
B. 3 : 2.
C. 2 : 1.
D. 3 : 1.
(H B 09) Cho cc phn ng sau:
(a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O.
(b) HCl + NH4HCO3 NH4Cl + CO2 + H2O.
(c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O.
(d) 2HCl + Zn ZnCl2 + H2.
S phn ng trong HCl th hin tnh kh l
A. 2.
B. 3.
C. 1.
D. 4.
(H A 08) Cho cc phn ng sau:
4HCl + MnO2 MnCl2 + Cl2 + 2H2O.
2HCl + Fe FeCl2 + H2.
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.

THPT Tn Tc

57

Vng Quc Vit

n tp Ha 12
6HCl + 2Al 2AlCl3 + 3H2.
16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
S phn ng trong HCl th hin tnh oxi ha l
A. 2.
B. 3.
C. 1.
D. 4.
451. (C 13) Cho cc phng trnh phn ng sau:
(a) Fe + 2HCl FeCl2 + H2.
(b) Fe3O4 + 4H2SO4 Fe2(SO4)3 + FeSO4 + 4H2O.
(c) 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
(d) FeS + H2SO4 FeSO4 + H2S.
(e) 2Al + 3H2SO4 Al2(SO4)3 + 3H2.
Trong cc phn ng trn, s phn ng m ion H+ ng vai tr cht oxi ha l
A. 2.
B. 1.
C. 4.
D. 3.
452. (H B 11) Cho cc phn ng:
(a) Sn + HCl (long)
(b) FeS + H2SO4 (long)
t

(c) MnO2 + HCl (c)

o

(d) Cu + H2SO4 (c)

(e) Al + H2SO4 (long)
(g) FeSO4 + KMnO4 + H2SO4
S phn ng m H+ ca axit ng vai tr cht oxi ho l
A. 3.
B. 5.
C. 2.
D. 6.
(H A 07) Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng
trnh phn ng gia Cu vi dung dch HNO3 c, nng l
A. 11.
B. 9.
C. 10.
D. 8.
(H A 09) Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O. Sau
khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn,
ti gin th h s ca HNO3 l
A. 13x - 9y.
B. 46x - 18y.
C. 45x - 18y.
D. 23x - 9y.
(H B 13) Thc hin cc th nghim sau:
(a) Cho Al vo dung dch HCl.
(b) Cho Al vo dung dch AgNO3.
(c) Cho Na vo H2O.
(d) Cho Ag vo dung dch H2SO4 long.
Trong cc th nghim trn, s th nghim xy ra phn ng l
A. 1.
B. 2.
C. 4.
D. 3.
(H A 09) Trng hp xy ra phn ng l
A. Cu + Pb(NO3)2 (long)
B. Cu + HCl (long)
C. Cu + H2SO4 (long)
D. Cu + HCl (long) + O2
(H B 13) Trng hp no sau y khng xy ra phn ng?
A. Au + HNO3 c
B. Ag + O3
C. Sn + HNO3 long
D. Ag + HNO3 c
(H A 10) Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe 2O3 +
CO (k), (3) Au + O2 (k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc
trng hp xy ra phn ng oxi ho kim loi l:
A. (1), (3), (6).
B. (2), (5), (6).
C. (2), (3), (4).
D. (1), (4), (5).
(H B 13) Cho phn ng: FeO + HNO3 Fe(NO3)3 + NO + H2O. Trong phng
trnh ca phn ng trn, khi h s ca FeO l 3 th h s ca HNO3 l
A. 6.
B. 8.
C. 4.
D. 10.
o

453.

454.

455.

456.

457.

458.

459.

THPT Tn Tc

58

Vng Quc Vit

460.
461.

462.

463.

464.

465.

n tp Ha 12

TC PHN NG CN BNG HA HC
GIO KHOA
(C 08) Hng s cn bng ca phn ng xc nh ch ph thuc vo
A. nhit .
B. p sut.
C. cht xc tc.
D. nng .
(C 12) Cho cn bng ha hc: CaCO3 (rn)
CaO (rn) + CO2 (kh). Bit phn
ng thun l phn ng thu nhit. Tc ng no sau y vo h cn bng cn bng
cho chuyn dch theo chiu thun?
A. Tng nng kh CO2.
B. Tng p sut.
C. Gim nhit . D. Tng nhit .
(H B 12) Cho phn ng: N2 (k) + 3H2 (k)
2NH3 (k); H = 92 kJ. Hai bin php
u lm cn bng chuyn dch theo chiu thun l
A. gim nhit v gim p sut.
B. tng nhit v tng p sut.
C. gim nhit v tng p sut.
D. tng nhit v gim p sut.
(H B 08) Cho cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k); phn ng thun l
phn ng to nhit. Cn bng ho hc khng b chuyn dch khi
A. thay i nng N2.
B. thm cht xc tc Fe.
C. thay i p sut ca h.
D. thay i nhit .
(C 11) Cho cn bng ha hc: N2 (k) + 3H2 (k) 2NH3 (k) H < 0. Cn bng trn
chuyn dch theo chiu thun khi
A. tng nhit ca h phn ng.
B. gim p sut ca h phn ng.
C. tng p sut ca h phn ng.
D. thm cht xc tc vo h phn ng.
(C 07) Cho phng trnh ho hc ca phn ng tng hp amoniac:
t , xt

2NH3(k).
N2 (k) + 3H2 (k)

Khi tng nng ca hiro ln 2 ln, tc phn ng thun

A. tng ln 8 ln. B. gim i 2 ln.
C. tng ln 6 ln. D. tng ln 2 ln.
466. (H B 11) Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0.
Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h
nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut
chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo
chiu thun?
A. (1), (2), (4), (5).
B. (2), (3), (5).
C. (2), (3), (4), (6).
D. (1), (2), (4).
467. (H A 08) Cho cn bng ho hc: 2SO2 (k) + O2 (k) 2SO3 (k); phn ng thun l
phn ng to nhit. Pht biu ng l:
A. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng.
B. Cn bng chuyn dch theo chiu nghch khi gim nng O2.
C. Cn bng chuyn dch theo chiu thun khi tng nhit .
D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3.
468. (H A 10) Cho cn bng: 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit th t khi
ca hn hp kh so vi H2 gim i. Pht biu ng khi ni v cn bng ny l:
A. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit
.
B. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit
.
C. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit
.
D. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit
.
469. (C 08) Cho cc cn bng ho hc:
THPT Tn Tc

59

Vng Quc Vit

n tp Ha 12

2NH3 (k) (1)

N2 (k) + 3H2 (k)

2HI (k) (2)

H2 (k) + I2 (k)

2SO3 (k) (3)

2SO2 (k) + O2 (k)

N2O4 (k) (4)

2NO2 (k)

470.

471.

472.

473.

Khi thay i p sut nhng cn bng ha hc b chuyn dch l:

A. (1), (2), (3).
B. (2), (3), (4).
C. (1), (3), (4).
D. (1), (2), (4).
(C 13) Trong bnh kn c h cn bng ha hc sau: CO2 (k) + H2 (k)
CO (k) +
H2O (k); H > 0. Xt cc tc ng sau n h cn bng: (a) tng nhit ; (b) thm
mt lng hi nc; (c) gim p sut chung ca h; (d) dng cht xc tc; (e) thm
mt lng CO2. Trong nhng tc ng trn, cc tc ng lm cn bng chuyn dch
theo chiu thun l:
A. (a) v (e).
B. (b), (c) v (d).
C. (d) v (e).
D. (a), (c) v (e).
(H A 13) Cho cc cn bng ha hc sau:
(a) H2 (k) + I2 (k)
2HI (k).
(b) 2NO2 (k)
N2O4 (k).
(c) 3H2 (k) + N2 (k)
2NH3 (k).
(d) 2SO2 (k) + O2 (k)
2SO3 (k).
nhit khng i, khi thay i p sut chung ca mi h cn bng, cn bng ha
hc no trn khng b chuyn dch?
A. (b).
B. (a).
C. (c).
D. (d).
(H A 09) Cho cn bng sau trong bnh kn: 2NO2 (k)
N2O4 (k).
(mu nu )
(khng mu)
Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c
A. H > 0, phn ng ta nhit.
B. H < 0, phn ng ta nhit.
C. H > 0, phn ng thu nhit.
D. H < 0, phn ng thu nhit.
(C 09) Cho cc cn bng sau:
xt, t

2SO3 (k);
(1) 2SO2 (k) + O2 (k)

xt, t

2NH3 (k);
(2) N2 (k) + 3H2 (k)

CO (k) + H2O (k);

(3) CO2 (k) + H2 (k)

H2 (k) + I2 (k)
(4) 2HI (k)

474.

Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l

A. (1) v (3).
B. (3) v (4).
C. (1) v (2).
D. (2) v (4).

CO2 (k) + H2 (k)

(C 09) Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k)

H < 0. Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm
mt lng H2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu
t u lm thay i cn bng ca h l:
A. (1), (2), (4).
B. (1), (2), (3).
C. (2), (3), (4).
D. (1), (4), (5).
o
475. (H A 10) Xt cn bng: N2O4 (k) 2NO2 (k) 25 C. Khi chuyn dch sang mt
trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2
A. tng 9 ln.
B. tng 3 ln.
C. tng 4,5 ln.
D. gim 3 ln.
476. (H B 10) Cho cc cn bng sau:
(I) 2HI (k) H2 (k) + I2 (k);
(II) CaCO3 (r) CaO (r) + CO2 (k);
(III) FeO (r) + CO (k) Fe (r) + CO2 (k);
(IV) 2SO2 (k) + O2 (k) 2SO3 (k).
Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l
THPT Tn Tc

60

Vng Quc Vit

A. 4.
477.

B. 3.

n tp Ha 12
D. 1.

C. 2.

PCl3 (k) + Cl2 (k); H > 0. Cn bng

(C 10) Cho cn bng ho hc: PCl5 (k)

chuyn dch theo chiu thun khi

A. thm PCl3 vo h phn ng.
C. tng nhit ca h phn ng.
478.

B. tng p sut ca h phn ng.

D. thm Cl2 vo h phn ng.

2HI (k); H > 0. Cn bng

(H A 11) Cho cn bng ho hc: H2 (k) + I2 (k)

khng b chuyn dch khi

A. gim nng HI.
B. gim p sut chung ca h.
C. tng nhit ca h.
D. tng nng H2.
479. (H B 13) Trong mt bnh kn c cn bng ha hc sau: 2NO2 (k)
N2O4 (k). T
khi hi ca hn hp kh trong bnh so vi H2 nhit T1 bng 27,6 v nhit T2
bng 34,5. Bit T1 > T2. Pht biu no sau y v cn bng trn l ng?
A. Khi tng nhit , p sut chung ca h cn bng gim.
B. Khi gim nhit , p sut chung ca h cn bng tng.
C. Phn ng thun l phn ng ta nhit.
D. Phn ng nghch l phn ng ta nhit.
BI TP TC PHN NG
480. (C 10) Cho phn ng: Br2 + HCOOH 2HBr + CO2. Nng ban u ca Br2 l a
mol/lt, sau 50 giy nng Br2 cn li l 0,01 mol/lt. Tc trung bnh ca phn ng
trn tnh theo Br2 l 4.10-5 mol/(l.s). Gi tr ca a l
A. 0,012.
B. 0,016.
C. 0,014.
D. 0,018.
481. (C 12) Cho phn ng ha hc: Br2 + HCOOH 2HBr + CO2. Lc u nng ca
HCOOH l 0,010 mol/l, sau 40 giy nng ca HCOOH l 0,008 mol/l. Tc trung
bnh ca phn ng trong khong thi gian 40 giy tnh theo HCOOH l
A. 5,0.105 mol/(l.s).
B. 2,5.105 mol/(l.s).
C. 2,5.104 mol/(l.s).
D. 2,0.104 mol/(l.s).
482. (H A 12) Xt phn ng phn hy N2O5 trong dung mi CCl4 45oC: N2O5 N2O4 +
1

O2. Ban u nng ca N2O5 l 2,33M, sau 184 giy nng ca N2O5 l 2,08M.

Tc trung bnh ca phn ng tnh theo N2O5 l

A. 2,72.103 mol/(l.s).
B. 1,36.103 mol/(l.s).
C. 6,80.104 mol/(l.s).
D. 6,80.103 mol/(l.s).
483. (H B 09) Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c
33,6 ml kh O2 ( ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy
trn l
A. 5,0.104 mol/(l.s).
B. 5,0.105 mol/(l.s).
C. 1,0.103 mol/(l.s).
D. 2,5.104 mol/(l.s).
484. (H B 13) Cho phng trnh ha hc ca phn ng: X + 2Y Z + T. thi im
ban u, nng ca cht X l 0,01 mol/l. Sau 20 giy, nng ca cht X l 0,008
mol/l. Tc trung bnh ca phn ng tnh theo cht X trong khong thi gian trn l
A. 4,0.104 mol/(l.s).
B. 1,0.104 mol/(l.s).
C. 7,5.104 mol/(l.s).
D. 5,0.104 mol/(l.s).
BI TP CN BNG HA HC
485. (C 11) Cho phn ng: H2 (k) + I2 (k) 2HI (k). nhit 430C, hng s cn bng
KC ca phn ng trn bng 53,96. un nng mt bnh kn dung tch khng i 10 lt
cha 4,0 gam H2 v 406,4 gam I2. Khi h phn ng t trng thi cn bng 430C,
nng ca HI l
A. 0,275M.
B. 0,225M.
C. 0,151M.
THPT Tn Tc

61

Vng Quc Vit

n tp Ha 12
D. 0,320M.
486. (H B 11) Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10
lt. Nung nng bnh mt thi gian 830oC h t n trng thi cn bng: CO (k) +
H2O (k) CO2 (k) + H2 (k) (hng s cn bng KC = 1). Nng cn bng ca CO,
H2O ln lt l
A. 0,08M v 0,18M.
B. 0,018M v 0,008M.
C. 0,012M v 0,024M.
D. 0,008M v 0,018M
487. (H A 09) Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi
nng tng ng l 0,3M v 0,7M. Sau khi phn ng tng hp NH 3 t trng thi
cn bng toC, H2 chim 50% th tch hn hp thu c. Hng s cn bng KC
toC ca phn ng c gi tr l
A. 2,500.
B. 3,125.
C. 0,609.
D. 0,500.
488. (C 09) Cho cc cn bng sau:

2HI (k);
(1) H2 (k) + I2 (k)

1
1

HI (k)
H2 (k) +
I2 (k)

2
2

1 H2 (k) + 1 I2 (k);
(3) HI (k)

2
2

H2 (k) + I2 (k)
(4) 2HI (k)

(2)

2HI (k).
(5) H2 (k) + I2 (r)

bng

nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn

A. (2).

THPT Tn Tc

B. (5).

C. (3).

D. (4).

62

Vng Quc Vit

489.

490.

491.

492.

493.

494.

495.

496.

497.

498.

499.

n tp Ha 12

S IN LY
GIO KHOA
(H B 08) Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz),
CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l
A. 2.
B. 4.
C. 3.
D. 5.
(C 09) Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt
dung dch l:
A. Ag+, Na+, NO3, Cl.
B. Mg2+, K+, SO42, PO43.
C. H+, Fe3+, NO3, SO42.
D. Al3+, NH4+, Br, OH.
(C 10) Dy gm cc ion cng tn ti trong mt dung dch l:
A. Al3+, PO43, Cl, Ba2+.
B. Ca2+, Cl, Na+, CO32.
C. K+, Ba2+, OH, Cl.
D. Na+, K+, OH, HCO3.
(C 13) Dy gm cc ion cng tn ti trong mt dung dch l:
A. K+; Ba2+; Cl v NO3.
B. Cl ; Na+; NO3 v Ag +.
C. K+; Mg2+; OH v NO3.
D. Cu2+ ; Mg2+; H+ v OH.
(C 11) C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha
mt trong cc dung dch AgNO3, ZnCl2, HI, Na2CO3. Bit rng:
- Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh;
- Dung dch trong ng nghim 2 v 4 khng phn ng c vi nhau.
Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l:
A. ZnCl2, HI, Na2CO3, AgNO3.
B. ZnCl2, Na2CO3, HI, AgNO3.
C. AgNO3, HI, Na2CO3, ZnCl2.
D. AgNO3, Na2CO3, HI, ZnCl2.
(H A 13) Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l:
A. HNO3, NaCl v Na2SO4.
B. HNO3, Ca(OH)2 v KNO3.
C. NaCl, Na2SO4 v Ca(OH)2.
D. HNO3, Ca(OH)2 v Na2SO4.
(C 13) Dung dch H2SO4 long phn ng c vi tt c cc cht trong dy no
sau y?
A. Al2O3, Ba(OH)2, Ag.
B. CuO, NaCl, CuS.
C. FeCl3, MgO, Cu.
D. BaCl2, Na2CO3, FeS.
(C 11) Tin hnh cc th nghim sau:
(1) Sc kh H2S vo dung dch FeSO4;
(2) Sc kh H2S vo dung dch CuSO4;
(3) Sc kh CO2 (d) vo dung dch Na2SiO3;
(4) Sc kh CO2 (d) vo dung dch Ca(OH)2;
(5) Nh t t dd NH3 n d vo dd Al2(SO4)3;
(6) Nh t t dd Ba(OH)2 n d vo dd Al2(SO4)3.
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l
A. 5.
B. 6.
C. 3.
D. 4.
(C 08) Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht
trong dy tc dng vi lng d dung dch Ba(OH)2 to thnh kt ta l
A. 5.
B. 4.
C. 1.
D. 3.
(C 08) Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht
trong dy to thnh kt ta khi phn ng vi dung dch BaCl2 l
A. 4.
B. 6.
C. 3.
D. 2.
(H A 11) Tin hnh cc th nghim sau:
(1) Cho dung dch NaOH vo dung dch Ca(HCO3)2.
(2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(3) Sc kh H2S vo dung dch FeCl2.
(4) Sc kh NH3 ti d vo dung dch AlCl3.
(5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(6) Sc kh etilen vo dung dch KMnO4.

THPT Tn Tc

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n tp Ha 12
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 4.
B. 6.
C. 3.
D. 5.
500. (H A 13) Cht no sau y khng to kt ta khi cho vo dung dch AgNO3?
A. HCl.
B. K3PO4.
C. KBr.
D. HNO3.
501. (H A 09) C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4,
FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch
trn. Sau khi phn ng kt thc, s ng nghim c kt ta l
A. 4.
B. 2.
C. 5.
D. 3.
502. (H B 10) Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2,
NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt
ta l
A. 4.
B. 7.
C. 5.
D. 6.
503. (H A 07) C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung
dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt
ta thu c l
A. 2.
B. 4.
C. 1.
D. 3.
504. (H B 07) Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2,
dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l:
A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2.
B. HNO3, NaCl, Na2SO4.
C. NaCl, Na2SO4, Ca(OH)2.
D. HNO3, Ca(OH)2, KHSO4, Na2SO4.
505. (H B 07) Cho 4 phn ng:
(1) Fe + 2HCl FeCl2 + H2;
(2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O;
(3) BaCl2 + Na2CO3 BaCO3 + 2NaCl;
(4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4;
Cc phn ng thuc loi phn ng axit - baz l
A. (2), (3).
B. (1), (2).
C. (2), (4).
D. (3), (4).
506. (H A 12) Cho cc phn ng sau:
(a) FeS + 2HCl FeCl2 + H2S
(b) Na2S + 2HCl 2NaCl + H2S
(c) 2AlCl3 + 3Na2S + 6H2O 2Al(OH)3 + 3H2S + 6NaCl
(d) KHSO4 + KHS K2SO4 + H2S
(e) BaS + H2SO4 (long) BaSO4 + H2S
S phn ng c phng trnh ion rt gn S2- + 2H+ H2S l
A. 1.
B. 3.
C. 2.
D. 4.
507. (C 08) Trng hp khng xy ra phn ng ha hc l
t
2H2O + 2SO2.
A. 3O2 + 2H2S
B. FeCl2 + H2S FeS + 2HCl.
C. O3 + 2KI + H2O 2KOH + I2 + O2.
D. Cl2 + 2NaOH NaCl + NaClO + H2O.
(H B 09) Cho cc phn ng ha hc sau:
(1) (NH4)2SO4 + BaCl2
(2) CuSO4 + Ba(NO3)2
(3) Na2SO4 + BaCl2
(4) H2SO4 + BaSO3
(5) (NH4)2SO4 + Ba(OH)2
(6) Fe2(SO4)3 + Ba(NO3)2
Cc phn ng u c cng mt phng trnh ion rt gn l:
A. (1), (2), (3), (6).
B. (1), (3), (5), (6).
C. (2), (3), (4), (6).
D. (3), (4), (5), (6).
(H B 08) Cht phn ng vi dung dch FeCl3 cho kt ta l
A. CH3NH2.
B. CH3COOH.
C. CH3OH.
D. CH3COOCH3.
o

508.

509.

THPT Tn Tc

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n tp Ha 12
510. (H B 08) Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng
c vi Cu(OH)2 l
A. 2.
B. 3.
C. 4.
D. 1.
511. (H B 12) Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu
tm ha xanh. Trn ln hai dung dch trn thu c kt ta. Hai cht X v Y tng
ng l
A. KNO3 v Na2CO3.
B. Ba(NO3)2 v Na2CO3.
C. Na2SO4 v BaCl2.
D. Ba(NO3)2 v K2SO4.
512. (H A 10) Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc
dng c vi c 4 dung dch trn l
A. NH3.
B. KOH.
C. NaNO3.
D. BaCl2.
HP CHT LNG TNH
513. (H A 12) Cho dy cc cht: Al, Al(OH)3, Zn(OH)2, NaHCO3, Na2SO4. S cht trong
dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH
l
A. 5.
B. 4.
C. 3.
D. 2.
514. (H B 11) Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3,
K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc
dng c vi dung dch NaOH?
A. 3.
B. 5.
C. 4.
D. 2.
515. (H A 07) Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3,
Zn(OH)2. S cht trong dy c tnh cht lng tnh l
A. 4.
B. 5.
C. 2.
D. 3.
516. (H A 11) Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht
trong dy c tnh cht lng tnh l
A. 3.
B. 4.
C. 2.
D. 1.
517. (H A 08) Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S
cht u phn ng c vi dung dch HCl, dung dch NaOH l
A. 7.
B. 6.
C. 5.
D. 4.
518. (C 08) Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S
cht trong dy c tnh cht lng tnh l
A. 5.
B. 2.
C. 3.
D. 4.
519. (C 09) Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol
FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m
l
A. 4,128.
B. 1,560.
C. 5,064.
D. 2,568.
520. (C 09) Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2
gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l
A. 39,4.
B. 19,7.
C. 15,5.
D. 17,1.
521. (C 09) Ha tan hon ton 47,4 gam phn chua KAl(SO 4)2.12H2O vo nc, thu
c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau
phn ng thu c m gam kt ta. Gi tr ca m l
A. 54,4.
B. 62,2.
C. 46,6.
D. 7,8.
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n tp Ha 12
2
3+
+

522. (C 08) Dung dch X cha cc ion: Fe , SO4 , NH4 , Cl . Chia dung dch X thnh
hai phn bng nhau:
- Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh
( ktc) v 1,07 gam kt ta;
- Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng
khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch
c nc bay hi)
A. 3,73 gam.
B. 7,04 gam.
C. 7,46 gam.
D. 3,52 gam.
BI TP pH
523. (H B 10) Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng
ng?
A. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4.
B. in li ca axit fomic s gim khi thm dung dch HCl.
C. Khi pha long dung dch trn th in li ca axit fomic tng.
D. in li ca axit fomic trong dung dch trn l 14,29%.
524. (C 13) Dung dch cht no di y c mi trng kim?
A. NH4Cl.
B. Al(NO3)3.
C. CH3COONa.
D. HCl.
525. (C 10) Dung dch no sau y c pH > 7?
A. Dung dch CH3COONa.
B. Dung dch NaCl.
C. Dung dch Al2(SO4)3.
D. Dung dch NH4Cl.
526. (C 07) Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4,
C6H5ONa, nhng dung dch c pH > 7 l
A. Na2CO3, C6H5ONa, CH3COONa.
B. Na2CO3, NH4Cl, KCl.
C. KCl, C6H5ONa, CH3COONa.
D. NH4Cl, CH3COONa, NaHSO4.
527. (C 08) Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3
(4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l:
A. (3), (2), (4), (1).
B. (4), (1), (2), (3).
C. (1), (2), (3), (4).
D. (2), (3), (4), (1).
528. (H B 13) Trong s cc dung dch c cng nng 0,1M di y, dung dch cht
no c gi tr pH nh nht?
A. NaOH.
B. HCl.
C. H2SO4.
D. Ba(OH)2.
529. (C 11) Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH = 3,0
thu c dung dch Y c pH =11,0. Gi tr ca a l
A. 1,60.
B. 0,80.
C. 1,78.
D. 0,12.
530. (H B 07) Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml
dung dch (gm H2SO4 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH
ca dung dch X l
A. 7.
B. 6.
C. 1.
D. 2.
531. (H A 08) Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M
c 2V ml dung dch Y. Dung dch Y c pH l
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n tp Ha 12
A. 1.
B. 2.
C. 4.
D. 3.
532. (H B 08) Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch
NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit
trong mi dung dch [H+][OH] = 1014)
A. 0,15.
B. 0,12.
C. 0,30.
D. 0,03.
533. (H B 09) Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100
ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X.
Dung dch X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
534. (H A 07) Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit
HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch
dung dch khng i). Dung dch Y c pH l
A. 7.
B. 1.
C. 2.
D. 6.
BO TON IN TCH
535. (C 12) Dung dch E gm x mol Ca2+, y mol Ba2+, z mol HCO3. Cho t t dung dch
Ca(OH)2 nng a mol/l vo dung dch E n khi thu c lng kt ta ln nht th
va ht V lt dung dch Ca(OH)2. Biu thc lin h gia cc gi tr V, a, x, y l
A. V = 2a(x+y).
B. V = a(2x+y).
x+2y
.
a
x+y
D. V =
.
a

C. V =

(H B 12) Mt dung dch gm: 0,01 mol Na+; 0,02 mol Ca2+; 0,02 mol HCO3 v a
mol ion X (b qua s in li ca nc). Ion X v gi tr ca a l
A. NO3 v 0,03.
B. Cl v 0,01.
C. CO32 v 0,03.
D. OH v 0,03.
537. (H B 11) Dung dch X gm 0,1 mol H+, z mol Al3+, t mol NO3 v 0,02 mol SO42.
Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn
ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l
A. 0,020 v 0,012.
B. 0,012 v 0,096.
C. 0,020 v 0,120.
D. 0,120 v 0,020.
538. (C 07) Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42.
Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln
lt l
536.

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n tp Ha 12
A. 0,03 v 0,02.
B. 0,05 v 0,01.
C. 0,01 v 0,03.
D. 0,02 v 0,05..
539. (H A 10) Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO42 v x mol OH. Dung
dch Y c cha ClO4, NO3 v y mol H+; tng s mol ClO4 v NO3 l 0,04. Trn X v
Y c 100 ml dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l
A. 1.
B. 12.
C. 13.
D. 2.
540. (H A 10) Cho dung dch X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl;
0,006 mol HCO3 v 0,001 mol NO3. loi b ht Ca2+ trong X cn mt lng va
dung dch cha a gam Ca(OH)2. Gi tr ca a l
A. 0,180.
B. 0,120.
C. 0,444.
D. 0,222.
541. (H B 10) Dung dch X cha cc ion: Ca2+, Na+, HCO3 v Cl, trong s mol ca
ion Cl l 0,1. Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2
gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH) 2 (d), thu
c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam
cht rn khan. Gi tr ca m l
A. 9,21.
B. 9,26.
C. 8,79.
D. 7,47.
542. (H B 13) Dung dch X cha 0,12 mol Na+; x mol SO42 ; 0,12 mol Cl v 0,05 mol
NH4+ . Cho 300 ml dung dch Ba(OH)2 0,1M vo X n khi cc phn ng xy ra hon
ton, lc b kt ta, thu c dung dch Y. C cn Y, thu c m gam cht rn khan.
Gi tr ca m l
A. 7,190.
B. 7,705.
C. 7,875.
D. 7,020.
HNG S AXIT-BAZ
543. (C 12) Bit 25C, hng s phn li baz ca NH3 l 1,74.105, b qua s phn li
ca nc. Gi tr pH ca dung dch NH3 0,1M 25C l
A. 4,76.
B. 9,24.
C. 11,12.
D. 13,00.
544. (H A 12) Dung dch X gm CH3COOH 0,03M v CH3COONa 0,01M. Bit 25oC,
Ka ca CH3COOH l 1,75.105, b qua s phn li ca nc. Gi tr pH ca dung dch
X 25oC l
A. 4,28.
B. 4,04.
C. 4,76.
D. 6,28.
545. (H B 09) Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa
0,1M. Bit 25oC, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi
tr pH ca dung dch X 25oC l
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n tp Ha 12
A. 1,00.
B. 4,24.
C. 2,88.
D. 4,76.
546. (H A 11) Dung dch X gm CH3COOH 1M (Ka = 1,75.105) v HCl 0,001M. Gi tr
pH ca dung dch X l
A. 2,33.
B. 2,43.
C. 2,55.
D. 1,77.

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547.

548.

549.

550.

551.

552.

553.

n tp Ha 12

NIT V HP CHT
GIO KHOA
(H A 07) Trong phng th nghim, iu ch mt lng nh kh X tinh khit,
ngi ta un nng dung dch amoni nitrit bo ha. Kh X l
A. N2.
B. NO.
C. NO2.
D. N2O.
(H B 13) Ha tan mt kh X vo nc, thu c dung dch Y. Cho t t dung dch
Y n d vo dung dch ZnSO4, ban u thy c kt ta trng, sau kt ta tan ra.
Kh X l
A. NO2.
B. HCl.
C. SO2.
D. NH3.
(H B 12) Pht biu no sau y l ng?
A. Hn hp FeS v CuS tan c ht trong dung dch HCl d.
B. Thi khng kh qua than nung , thu c kh than t.
C. Photpho d bc chy trong khng kh iu kin thng.
D. Dung dch hn hp HCl v KNO3 ha tan c bt ng.
(H B 07) Khi cho Cu tc dng vi dung dch cha H2SO4 long v NaNO3, vai tr
ca NaNO3 trong phn ng l
A. cht xc tc. B. mi trng.
C. cht oxi ho. D. cht kh.
(C 10) Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l
A. ng(II) oxit v dung dch NaOH.
B. ng(II) oxit v dung dch HCl.
C. dung dch NaOH v dung dch HCl.
D. kim loi Cu v dung dch HCl.
(H B 07) Trong phng th nghim, ngi ta thng iu ch HNO3 t
A. NaNO3 v H2SO4 c.
B. NaNO3 v HCl c.
C. NaNO2 v H2SO4 c.
D. NH3 v O2.
(H A 08) Cho cc phn ng sau:
o

t
(1) Cu(NO3)2

850 C, Pt
(3) NH3 + O2

t
(5) NH4Cl

t
(2) NH4NO2

t
(4) NH3 + Cl2

t
(6) NH3 + CuO

Cc phn ng u to kh N2 l:
A. (1), (3), (4).
B. (1), (2), (5).
C. (2), (4), (6).
D. (3), (5), (6).
554. (H B 10) Pht biu no sau y khng ng?
A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c
pH ln nht.
B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh.
C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng.
D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng.
555. (H A 11) Khi so snh NH3 vi NH4+, pht biu khng ng l:
A. Trong NH3 v NH4+, nit u c cng ha tr 3.
B. Phn t NH3 v ion NH4+ u cha lin kt cng ha tr.
C. Trong NH3 v NH4+, nit u c s oxi ha 3.
D. NH3 c tnh baz, NH4+ c tnh axit.
KIM LOI + HNO3
556. (C 08) Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X
(sn phm kh duy nht, ktc). Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
THPT Tn Tc
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n tp Ha 12
557. (H A 09) Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO 3 long, thu
c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng
22. Kh NxOy v kim loi M l
A. NO v Mg.
B. NO2 v Al.
C. N2O v Al.
D. N2O v Fe.
558. (C 10) Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d
dung dch HNO3. Sau khi cc phn ng xy ra hon ton, thu c 0,896 lt mt kh X
(ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam mui khan. Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
559. (H A 09) Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy
ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X
c th ha tan ti a m gam Cu. Gi tr ca m l
A. 1,92.
B. 3,20.
C. 0,64.
D. 3,84.
560. (H B 09) Khi ha tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl
phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,02.
B. 0,06 v 0,01.
C. 0,03 v 0,01.
D. 0,06 v 0,02.
561. (C 09) Ha tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3
long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu,
trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho
dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm
khi lng ca Al trong hn hp ban u l
A. 19,53%.
B. 10,52%.
C. 12,80%.
D. 15,25%.
562. (H A 07) Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3,
thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai
mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l
A. 3,36.
B. 2,24.
C. 4,48.
D. 5,60.
563. (H B 08) Th tch dung dch HNO3 1M (long) t nht cn dng ha tan hon
ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy
nht l NO)
A. 1,2 lt.
B. 0,6 lt.
C. 0,8 lt.
D. 1,0 lt.
564. (H B 09) Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch
HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung
THPT Tn Tc
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n tp Ha 12
dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton
thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr
ca m ln lt l
A. 21,95% v 2,25.
B. 78,05% v 2,25.
C. 21,95% v 0,78.
D. 78,05% v 0,78.
565. (H A 11) un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3
vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht
rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO 2 (khng c sn phm
kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l
A. 40,5.
B. 50,4.
C. 33,6.
D. 44,8.
566. (H B 09) Cho 61,2 gam hn hp X gm Cu v Fe 3O4 tc dng vi dung dch HNO3
long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36
lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi.
C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
TNH KHI LNG MUI NITRAT
567. (C 11) Ha tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c
dung dch X v 0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l
A. 18,90 gam.
B. 37,80 gam.
C. 28,35 gam.
D. 39,80 gam.
568. (H B 08) Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng
xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui
khan thu c khi lm bay hi dung dch X l
A. 13,32 gam.
B. 6,52 gam.
C. 13,92 gam.
D. 8,88 gam.
569. (C 12) Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500
ml dung dch HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O
(ktc) duy nht v dung dch X cha m gam mui. Gi tr ca m l
A. 31,22.
B. 34,10.
C. 33,70.
D. 34,32.
570. (H B 12) Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung
dch HNO3 1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc)
gm NO v N2O. T khi ca X so vi H2 l 16,4. Gi tr ca m l
A. 98,20.
B. 97,20.
C. 98,75.
D. 91,00.
KIM LOI/Fe2+ + HN HP H+ + NO3THPT Tn Tc
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n tp Ha 12
571. (H B 07) Thc hin hai th nghim:
1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO.
2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra
V2 lt NO.
Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h
gia V1 v V2 l
A. V2 = V1.
B. V2 = 2,5V1.
C. V2 = 2V1.
D. V2 = 1,5V1.
572. (H A 08) Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3
0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO
(sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,672.
B. 0,448.
C. 1,792.
D. 0,746.
573. (H B 09) Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v
H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp
bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln
lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48.
574. (H B 10) Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol
H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn
phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 8,96.
C. 4,48.
D. 10,08.
575. (C 10) Cho a gam Fe vo 100 ml dung dch hn hp gm HNO 3 0,8M v Cu(NO3)2
1M. Sau khi cc phn ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v
kh NO (sn phm kh duy nht ca). Gi tr ca a l
A. 5,6.
B. 11,2.
C. 8,4.
D. 11,0.
576. (H A 11) Cho 7,68 gam Cu vo 200 ml dung dch gm HNO 3 0,6M v H2SO4 0,5M.
Sau khi cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn
thn ton b dung dch sau phn ng th khi lng mui khan thu c l
A. 20,16 gam.
B. 19,76 gam.
C. 19,20 gam.
D. 22,56 gam
577. (H B 11) Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1)
vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra
hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5). Trn a mol NO
trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H 2O, thu
c 150 ml dung dch c pH = z. Gi tr ca z l
A. 2.
THPT Tn Tc

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B. 4.
C. 3.
D. 1.

n tp Ha 12

BI TON NH3
578. (H A 10) Hn hp kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X
mt thi gian trong bnh kn (c bt Fe lm xc tc), thu c hn hp kh Y c t khi
so vi He bng 2. Hiu sut ca phn ng tng hp NH3 l
A. 25%.
B. 50%.
C. 36%.
D. 40%.
579. (H A 10) Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng,
thu c cht rn X (gi s phn ng xy ra hon ton). Phn trm khi lng ca
Cu trong X l
A. 85,88%.
B. 14,12%.
C. 87,63%.
D. 12,37%.
NHIT PHN MUI NITRAT
580. (C 10) Sn phm ca phn ng nhit phn hon ton AgNO 3 l:
A. Ag2O, NO, O2. B. Ag2O, NO2, O2.
C. Ag, NO, O2.
D. Ag, NO2, O2.
581. (H B 09) Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh
hn s mol mui tng ng. t mt lng nh tinh th Y trn n kh khng mu,
thy ngn la c mu vng. Hai mui X, Y ln lt l:
A. KMnO4, NaNO3.
B. Cu(NO3)2, NaNO3.
C. CaCO3, NaNO3.
D. NaNO3, KNO3.
582. (H B 11) Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng
ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba
kim loi t 14,16 gam X?
A. 10,56 gam.
B. 3,36 gam.
C. 7,68 gam.
D. 6,72 gam.
583. (H B 11) Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn
ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch
tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra
hon ton. Phn trm khi lng ca X phn ng l
A. 70%.
B. 25%.
C. 60%.
D. 75%.
584. (C 08) Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu
c hn hp kh X (t khi ca X so vi kh hiro bng 18,8). Khi lng Cu(NO3)2
trong hn hp ban u l
A. 8,60 gam.
B. 20,50 gam.
C. 11,28 gam.
D. 9,40 gam.
585. (H A 09) Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt
thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo
nc c 300 ml dung dch Y. Dung dch Y c pH bng
THPT Tn Tc
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n tp Ha 12
A. 4.
B. 2.
C. 1.
D. 3.
586. (H B 09) Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2),
KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l
A. KClO3.
B. KMnO4.
C. KNO3.
D. AgNO3.
HALOGEN V HP CHT
587. (C 09) Cht dng lm kh kh Cl2 m l
A. Dung dch H2SO4 m c.
B. Na2SO3 khan.
C. CaO.
D. dung dch NaOH c.
588. (C 11) Mc phn cc ca lin kt ho hc trong cc phn t c sp xp theo
th t gim dn t tri sang phi l:
A. HBr, HI, HCl B. HI, HBr, HCl
C. HCl , HBr, HI
D. HI, HCl , HBr
589. (H A 07) Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. in phn nng chy NaCl.
B. cho dung dch HCl c tc dng vi MnO2, un nng.
C. in phn dung dch NaCl c mng ngn.
D. cho F2 y Cl2 ra khi dung dch NaCl.
590. (C 10) Pht biu no sau y ng?
A. Dung dch NaF phn ng vi dung dch AgNO3 sinh ra AgF kt ta.
B. Iot c bn knh nguyn t ln hn brom.
C. Axit HBr c tnh axit yu hn axit HCl.
D. Flo c tnh oxi ha yu hn clo.
591. (H A 11) Pht biu no sau y l sai?
A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo.
B. m in ca brom ln hn m in ca iot.
C. Tnh axit ca HF mnh hn tnh axit ca HCl.
D. Tnh kh ca ion Br- ln hn tnh kh ca ion Cl592. (H B 13) Cho cc pht biu sau:
(a) Trong cc phn ng ha hc, flo ch th hin tnh oxi ha.
(b) Axit flohidric l axit yu.
(c) Dung dch N long c dng lm thuc chng su rng,
(d) Trong cc hp cht, cc halogen (F, Cl, Br, I) u c s oxi ha: -1, +1, +3, +5 v
+7.
(e) Tnh kh ca ion halgoenua tng n theo th t: F-; Cl-; Br-; I-.
Trong cc pht biu trn, s pht biu ng l
A. 2.
B. 3.
C. 4.
D. 5.
593. (C 11) Pht biu no sau y khng ng?
A. Trong cc hp cht, ngoi s oxi ho -1, flo v clo cn c cc s oxi ho +1, +3,
+5, +7.
B. Mui AgI khng tan trong nc, mui AgF tan trong nc.
C. Flo c tnh oxi ha mnh hn clo.
D. Dung dch HF ha tan c SiO2.
594. (H B 08) Cho cc phn ng:
(1) O3 + dung dch KI ;
o

595.

t
;
(2) F2 + H2O

t
;
(3) MnO2 + HCl c

(4) Cl2 + dung dch H2S .

Cc phn ng to ra n cht l:
A. (1), (2), (3).
B. (1), (2), (4).
(H A 10) Pht biu khng ng l:

C. (1), (3), (4).

THPT Tn Tc

D. (2), (3), (4).

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n tp Ha 12
A. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong
cc hp cht.
B. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung
photphorit, ct v than cc 1200oC trong l in.
C. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon.
D. Hiro sunfua b oxi ho bi nc clo nhit thng.
596. (H B 10) Phng php loi b tp cht HCl c ln trong kh H 2S l: Cho hn
hp kh li t t qua mt lng d dung dch
A. Pb(NO3)2.
B. NaHS.
C. AgNO3.
D. NaOH.
597. (H A 11) Khng kh trong phng th nghim b nhim bi kh clo. kh c, c
th xt vo khng kh dung dch no sau y?
A. Dung dch NH3.
B. Dung dch NaCl.
C. Dung dch H2SO4 long.
D. Dung dch NaOH.
598. (C 11) Cho 3,16 gam KMnO4 tc dng vi dung dch HCl c (d), sau khi phn
ng xy ra hon ton th s mol HCl b oxi ha l
A. 0,10.
B. 0,05.
C. 0,02.
D. 0,16.
599. (H B 07) Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau
khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c
nng l
A. 0,24M.
B. 0,48M.
C. 0,2M.
D. 0,4M.
600. (H B 09) Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y
l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu
nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm
khi lng ca NaX trong hn hp ban u l
A. 58,2%.
B. 41,8%.
C. 52,8%.
D. 47,2%.
601. (H A 12) Hn hp X c khi lng 82,3 gam gm KClO3, Ca(ClO3)2, CaCl2 v KCl.
Nhit phn hon ton X thu c 13,44 lt O2 (ktc), cht rn Y gm CaCl2 v KCl.
Ton b Y tc dng va vi 0,3 lt dung dch K2CO3 1M thu c dung dch Z.
Lng KCl trong Z nhiu gp 5 ln lng KCl trong X. Phn trm khi lng KCl
trong X l
A. 12,67%.
B. 18,10%.
C. 25,62%.
D. 29,77%.
PHOTPHO V HP CHT
602. (H B 08) Thnh phn chnh ca qung photphorit l
A. NH4H2PO4.
B. CaHPO4.
C. Ca3(PO4)2.
D. Ca(H2PO4)2.
+ H3PO4
+ KOH
+ KOH
603. (H B 10) Cho s chuyn ho: P2O5
Y
X
Z.
Cc cht X, Y, Z ln lt l
A. K3PO4, K2HPO4, KH2PO4.
B. KH2PO4, K2HPO4, K3PO4.
THPT Tn Tc

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n tp Ha 12
C. K3PO4, KH2PO4, K2HPO4.
D. KH2PO4, K3PO4, K2HPO4.
604. (C 12) Cho 1,42 gam P2O5 tc dng hon ton vi 50 ml dung dch KOH 1M, thu
c dung dch X. C cn dung dch X thu c cht rn khan gm
A. K3PO4 v KOH.
B. K2HPO4 v K3PO4.
C. KH2PO4 v K2HPO4.
D. H3PO4 v KH2PO4.
605. (H B 08) Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c
c cc cht:
A. K3PO4, K2HPO4.
B. H3PO4, KH2PO4.
C. K3PO4, KOH.
D. K2HPO4, KH2PO4.
606. (H B 09) Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H 3PO4 0,5M, thu
c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l
A. KH2PO4 v K3PO4.
B. KH2PO4 v K2HPO4.
C. KH2PO4 v H3PO4.
D. K3PO4 v KOH.
607. (H A 13) Oxi ha hon ton 3,1 gam photpho trong kh oxi d. Cho ton b sn
phm vo 200 ml dung dch NaOH 1M n khi phn ng xy ra hon ton, thu c
dung dch X. Khi lng mui trong X l
A. 16,4 gam.
B. 14,2 gam.
C. 12,0 gam.
D. 11,1 gam.
PHN BN HA HC
608. (C 12) Thnh phn chnh ca phn bn phc hp amophot l
A. Ca3(PO4)2 v (NH4)2HPO4.
B. NH4NO3 v Ca(H2PO4)2.
C. NH4H2PO4 v (NH4)2HPO4.
D. NH4H2PO4 v Ca(H2PO4)2.
609. (H B 13) Pht biu no sau y l ng?
A. Thnh phn chnh ca supephotphat kp gm hai mui Ca(H2PO4)2 v CaSO4.
B. Ur c cng thc l (NH2)2CO.
C. Supephotphat n ch c Ca(H2PO4)2.
D. Phn ln cung cp nit cho cy trng.
610. (H A 09) Pht biu no sau y l ng?
A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO 3-) v ion amoni
(NH4+).
B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3.
C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK.
D. Phn ur c cng thc l (NH4)2CO3.
611. (H B 09) Phn bn no sau y lm tng chua ca t?
A. KCl.
B. NH4NO3.
C. NaNO3.
D. K2CO3.
612. (C 09) Phn bn nitrophotka (NPK) l hn hp ca
A. (NH4)2HPO4 v KNO3.
B. NH4H2PO4 v KNO3.
C. (NH4)3PO4 v KNO3.
D. (NH4)2HPO4 v NaNO3.
613. (H A 08) Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn
ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc
dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l
A. amoni nitrat. B. ure.
C. natri nitrat.
D. amophot.
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n tp Ha 12
614. (H B 10) Mt loi phn supephotphat kp c cha 69,62% mui canxi
ihirophotphat, cn li gm cc cht khng cha photpho. dinh dng ca loi
phn ln ny l
A. 48,52%.
B. 42,25%.
C. 39,76%.
D. 45,75%.
615. (H A 12) Mt loi phn kali c thnh phn chnh l KCl (cn li l cc tp cht
khng cha kali) c sn xut t qung xinvinit c dinh dng 55%. Phn trm
khi lng ca KCl trong loi phn kali l
A. 95,51%.
B. 65,75%.
C. 87,18%.
D. 88,52%.

THPT Tn Tc

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616.
617.

618.

619.
620.

621.

622.

623.

624.

625.

626.

n tp Ha 12

ESTE LIPIT
PHN 1: ESTE
GIO KHOA
(H A 08) S ng phn este ng vi cng thc phn t C4H8O2 l
A. 2.
B. 4.
C. 6.
D. 5.
(C 07) S hp cht n chc, ng phn cu to ca nhau c cng cng thc
phn t C4H8O2, u tc dng c vi dung dch NaOH l
A. 5.
B. 3.
C. 6.
D. 4.
(C 09) S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc
dng c vi dung dch NaOH nhng khng tc dng c vi Na l
A. 4.
B. 1.
C. 2.
D. 3.
(H A 10) Tng s cht hu c mch h, c cng cng thc phn t C 2H4O2 l
A. 1.
B. 2.
C. 4.
D. 3.
(H A 08) Pht biu ng l:
A. Khi thy phn cht bo lun thu c C2H4(OH)2.
B. Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng
l mui v ru (ancol).
D. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu.
(C 12) Cho cc este: etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4),
phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un
nng) sinh ra ancol l:
A. (1), (3), (4).
B. (3), (4), (5).
C. (1), (2), (3).
D. (2), (3), (5).
(C 08) Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH,
HCOOCH3. S cht trong dy tham gia phn ng trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
(C 12) Pht biu no sau y l ng?
A. Este isoamyl axetat c mi chui chn.
B. Etylen glicol l ancol no, n chc, mch h.
C. Axit bo l nhng axit cacboxylic a chc.
D. Ancol etylic tc dng c vi dung dch NaOH.
(C 12) Cho cc pht biu:
(1) Tt c cc anehit u c c tnh oxi ho v tnh kh;
(2) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc;
(3) Phn ng thy phn este trong mi trng axit l phn ng thun nghch;
(4) Tt c cc ancol no, a chc u ha tan c Cu(OH)2.
Pht biu ng l
A. (2) v (4).
B. (1) v (3).
C. (3) v (4).
D. (1) v (2).
(H B 11) Pht biu no sau y ng?
A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t OH trong
nhm COOH ca axit v H trong nhm OH ca ancol.
B. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh
benzyl axetat c mi thm ca chui chn.
C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php
ho hc, ch cn dng thuc th l nc brom.
D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to
hng trong cng nghip thc phm, m phm.
(H A 07) Mnh khng ng l:
A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.
B. CH3CH2COOCH=CH2 c th trng hp to polime.
C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2.

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D. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui.
627. (H A 08) Cho s chuyn ho sau: C3H4O2 + NaOH X + Y ; X + H2SO4 long
Z + T. Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l:
A. HCOONa, CH3CHO.
B. HCHO, CH3CHO.
C. HCHO, HCOOH.
D. CH3CHO, HCOOH.
628. (C 12) Cho s phn ng:
+ AgNO /NH
+ NaOH
+ NaOH

C2H3O2Na. Cng thc cu to

Z
Este X (C4HnO2)
t
t
t
o

ca X tha mn s cho l
A. CH3COOCH2CH3.
B. CH2=CHCOOCH3.
C. CH3COOCH=CH2.
D. HCOOCH2CH2CH3.
629. (H B 10) Hp cht hu c mch h X c cng thc phn t C 5H10O. Cht X khng
+ CH3OOH
+ H2
phn ng vi Na, tho mn s chuyn ho sau: X
Y
Este c
H2SO4 dac
Ni, t o
mi chui chn. Tn ca X l
A. pentanal.
C. 2,2-imetylpropanal.

B. 2-metylbutanal.
D. 3-metylbutanal.
o

t
2Y + H2O (1) ; Y + HCl (long)
(C 12) Cho cc phn ng sau: X + 2NaOH
Z + NaCl (2). Bit X l cht hu c c cng thc phn t C6H10O5. Khi cho 0,1 mol Z
tc dng ht vi Na (d) th s mol H2 thu c l
A. 0,15.
B. 0,20.
C. 0,10.
D. 0,05.
631. (H A 12) Cho s chuyn ha sau:
(a) C3H4O2 + NaOH X + Y
(b) X + H2SO4 (long) Z + T
(c) Z + dd AgNO3/NH3 (d) E + Ag + NH4NO3
(d) Y + dd AgNO3/NH3 (d) F + Ag + NH4NO3
Cht E v cht F theo th t l
A. HCOONH4 v CH3CHO.
B. (NH4)2CO3 v CH3COONH4.
C. HCOONH4 v CH3COONH4.
D. (NH4)2CO3 v CH3COOH.
632. (H A 13) Cho s cc phn ng:
t
Y + Z;
X + NaOH (dung dch)

630.

t
T + P;
Y + NaOH (rn)
CaO
o

1500 C
Q + H2;
T
o

t
Z.
Q + H2O
xt
o

633.

Trong s trn, X v Z ln lt l:
A. CH3COOCH=CH2 v CH3CHO.
B. HCOOCH=CH2 v HCHO.
C. CH3COOCH=CH2 v HCHO.
D. CH3COOC2H5 v CH3CHO.
(H B 11) Cho s phn ng:
xt, t
(1) X + O2
axit cacboxylic Y1 ;
o

xt, t
ancol Y2 ;
(2) X + H2
o

xt, t

Y3 + H2O.
(3) Y1 + Y2

Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l

A. anehit acrylic. B. anehit propionic.
C. anehit metacrylic.
D. anehit axetic.
634. (C 13) Trng hp no di y to ra sn phm l ancol v mui natri ca axit
cacboxylic?
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t

A. HCOOCH=CHCH3 + NaOH

n tp Ha 12

B. CH3COOCH2CH=CH2 + NaOH
o

C. CH3COOCH=CH2 + NaOH
o

D. CH3COOC6H5 (phenyl axetat) + NaOH

o

635.

636.

637.

638.

639.

640.

641.

(H B 07) Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam

X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin).
Cng thc cu to thu gn ca X v Y l
A. C2H5COOCH3 v HCOOCH(CH3)2.
B. HCOOCH2CH2CH3 v CH3COOC2H5.
C. C2H3COOC2H5 v C2H5COOC2H3.
D. HCOOC2H5 v CH3COOCH3.
(H B 10) Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat,
imetyl ete, s cht c kh nng lm mt mu nc brom l
A. 5.
B. 4.
C. 6.
D. 3.
PHN NG T CHY ESTE
(H B 08) Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra
bng s mol O2 phn ng. Tn gi ca este l
A. etyl axetat.
B. metyl axetat.
C. metyl fomat.
D. n-propyl axetat.
(H A 11) t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic
n chc v mt ancol n chc) thu c 0,22 gam CO 2 v 0,09 gam H2O. S este
ng phn ca X l
A. 4.
B. 5.
C. 6.
D. 2.
(H B 11) Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon
ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X
l
A. 75%.
B. 72,08%.
C. 27,92%.
D. 25%.
(C 07) Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn
phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht
X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8
gam mui ca axit hu c Y v cht hu c Z. Tn ca X l
A. etyl propionat.
B. metyl propionat.
C. isopropyl axetat.
D. etyl axetat.
(H A 11) t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl
acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d).
Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi
lng dung dch Ca(OH)2 ban u thay i nh th no?
A. Gim 7,38 gam.
B. Tng 2,70 gam.
C. Tng 7,92 gam.

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n tp Ha 12
D. Gim 7,74 gam.
642. (H A 08) Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng)
v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
B. Cht X thuc loi este no, n chc.
C. Cht Y tan v hn trong nc.
D. un Z vi dung dch H2SO4 c 170oC thu c anken.
643. (H B 09) Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt
lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc,
X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip.
Cng thc phn t ca hai este trong X l
A. C2H4O2 v C5H10O2.
B. C2H4O2 v C3H6O2.
C. C3H4O2 v C4H6O2.
D. C3H6O2 v C4H8O2.
644. (H B 09) Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi
dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6
gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X
th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l
A. O=CH-CH2-CH2OH.
B. HOOC-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
645. (H B 12) t chy hon ton m gam hn hp X gm hai este ng phn cn dng
27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc
dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu
c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (MY < MZ).
Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3.
B. 4 : 3.
C. 3 : 2.
D. 3 : 5.
646. (C 10) t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH3,
CH3OH thu c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X
phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng
thc ca CxHyCOOH l
A. C3H5COOH.
B. CH3COOH.
C. C2H3COOH.
D. C2H5COOH.
647. (C 10) Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit
cacboxylic k tip nhau trong dy ng ng (M X < MY). t chy hon ton m gam Z
cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng
thc este X v gi tr ca m tng ng l
A. (HCOO)2C2H4 v 6,6.
B. HCOOCH3 v 6,7.
C. CH3COOCH3 v 6,7.
D. HCOOC2H5 v 9,5.
THPT Tn Tc

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n tp Ha 12
648. (H B 09) Cho hn hp X gm hai hp cht hu c no, n chc tc dng va
vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc).
Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo
bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca
hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5.
B. C2H5COOH v C2H5COOCH3.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
649. (H A 10) t chy hon ton mt este n chc, mch h X (phn t c s lin kt
nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc
th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung
dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan.
Gi tr ca m l
A. 10,56.
B. 7,20.
C. 8,88.
D. 6,66.
PHN NG THY PHN
650. (C 09) Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml
dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn
khan. Cng thc cu to ca X l
A. C2H5COOCH=CH2.
B. CH3COOCH=CHCH3.
C. CH2=CHCH2COOCH3.
D. CH2=CHCOOC2H5.
651. (H B 08) Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1
mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v
17,8 gam hn hp mui. Cng thc cu to thu gn ca X l
A. CH3COO-(CH2)2-OOCC2H5.
B. CH3OOC-(CH2)2-COOC2H5.
C. CH3OOC-CH2-COO-C3H7.
D. CH3COO-(CH2)2-COOC2H5.
652. (C 08) Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng
vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c
28 gam cht rn khan. Cng thc cu to ca X l
A. CH2=CH-CH2-COO-CH3.
B. CH2=CH-COO-CH2-CH3.
C. CH3-COO-CH=CH-CH3.
D. CH3-CH2-COO-CH=CH2.
653. (C 08) X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v
CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti
thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
654. (H A 07) X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M.
Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi
lng l
A. 8,56 gam.
B. 8,2 gam.
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C. 3,28 gam.
D. 10,4 gam.
655. (C 11) Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch
NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c
v 3,2 gam mt ancol. Cng thc ca X l
A. CH3COOCH=CH2.
B. CH3COOC2H5.
C. C2H5COOCH3.
D. CH2=CHCOOCH3.
656. (C 13) Este X c cng thc phn t C4H8O2. Cho 2,2 gam X vo 20 gam dung dch
NaOH 8%, un nng, sau khi phn ng xy ra hon ton, thu c dung dch Y. C
cn Y thu c 3 gam cht rn khan. Cng thc cu to ca X l
A. CH3COOCH2CH3.
B. HCOOCH(CH3)2.
C. HCOOCH2CH2CH3.
D. CH3CH2COOCH3.
657. (H A 13) Cht no sau y khi un nng vi dung dch NaOH thu c sn phm
c anehit?
A. CH3COOCH2CH=CH2.
B. CH3COOC(CH3)=CH2.
C. CH2=CHCOOCH2CH3.
D. CH3COOCH=CHCH3.
658. (H B 07) Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c
2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l
A. ru metylic. B. etyl axetat.
C. ru etylic.
D. axit fomic.
659. (H B 10) Hp cht hu c mch h X c cng thc phn t C 6H10O4. Thu phn X
to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng
thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
660. (H B 10) Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y
(MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat.
B. metyl axetat.
C. etyl axetat.
D. vinyl axetat.
661. (C 13) Hp cht X c cng thc phn t C5H8O2, khi tham gia phn ng x phng
ha thu c mt anehit v mt mui ca axit cacboxylic. S ng phn cu to
tha mn tnh cht trn ca X l
A. 3.
B. 2.
C. 5.
D. 4.
662. (H B 13) Este no sau y khi phn ng vi dung dch NaOH d, un nng khng
to ra hai mui?
A. C6H5COOC6H5 (phenyl benzoat).
B. CH3COO[CH2]2OOCCH2CH3.
C. CH3OOCCOOCH3.
D. CH3COOC6H5 (phenyl axetat).
663. (C 10) Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c
sn phm gm 2 mui v ancol etylic. Cht X l
A. CH3COOCH2CH2Cl.
B. CH3COOCH2CH3.
C. CH3COOCH(Cl)CH3.
D. ClCH2COOC2H5.
664. (H B 12) Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu
c c kh nng trng bc. S este X tha mn tnh cht trn l
A. 4.
B. 3.
C. 6.
D. 5.
665. (H A 07) Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng
axit thu c axetanehit. Cng thc cu to thu gn ca este l
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n tp Ha 12
A. HCOO-CH=CH-CH3.
B. CH3COO-CH=CH2.
C. CH2=CH-COO-CH3.
D. HCOO-C(CH3)=CH2.
666. (H A 09) X phng ho mt hp cht c cng thc phn t C 10H14O6 trong dung
dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn
hnh hc). Cng thc ca ba mui l:
A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
B. HCOONa, CHC-COONa v CH3-CH2-COONa.
C. CH2=CH-COONa, HCOONa v CHC-COONa.
D. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
667. (H A 09) Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va
ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc
brom v 3,4 gam mt mui. Cng thc ca X l
A. HCOOC(CH3)=CHCH3.
B. CH3COOC(CH3)=CH2.
C. HCOOCH2CH=CHCH3.
D. HCOOCH=CHCH2CH3.
668. (C 07) Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn
dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc
Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung
dch NaOH li thu c cht Y. Cht X c th l
A. HCOOCH=CH2.
B. CH3COOCH=CH2.
C. CH3COOCH=CH-CH3.
D. HCOOCH3.
669. (C 07) Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham
gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao
nhiu cng thc cu to ph hp vi X?
A. 2.
B. 5.
C. 3.
D. 4.
670. (C 08) Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c
kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng)
nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l:
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH.
D. CH3-COOH, H-COO-CH3.
671. (C 08) Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH
(un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a
mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T
(bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l
A. 44 vC.
B. 58 vC.
C. 82 vC.
D. 118 vC.
672. (C 09) Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va
vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt
ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht
hu c l
A. hai este.
B. mt este v mt axit.
C. mt este v mt ancol.
D. hai axit.
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n tp Ha 12
673. (C 08) Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi
500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai
axit cacboxylic v mt ru (ancol). Cho ton b lng ru thu c trn tc
dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm
A. mt axit v mt este.
B. mt este v mt ru.
C. mt axit v mt ru.
D. hai este.
674. (H A 09) X phng ha hon ton 66,6 gam hn hp hai este HCOOC 2H5 v
CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng
hn hp X vi H2SO4 c 140oC, sau khi phn ng xy ra hon ton thu c m
gam nc. Gi tr ca m l
A. 4,05.
B. 8,10.
C. 18,00.
D. 16,20.
675. (H A 09) X phng ho hon ton 1,99 gam hn hp hai este bng dung dch
NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai
ancol l ng ng k tip nhau. Cng thc ca hai este l
A. CH3COOCH3 v CH3COOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. HCOOCH3 v HCOOC2H5.
676. (H A 10) Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung
dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit
cacboxylic n chc. Hai axit l
A. HCOOH v C2H5COOH.
B. HCOOH v CH3COOH.
C. C2H5COOH v C3H7COOH.
D. CH3COOH v C2H5COOH.
677. (H A 11) Este X c to thnh t etylen glicol v hai axit cacboxylic n chc.
Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m
gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam.
Gi tr ca m l
A. 16,5.
B. 15,5.
C. 14,5.
D. 17,5.
678. (H B 12) Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc
dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc
cu to thu gn ca X l
A. CH3COOCH2C6H5.
B. HCOOC6H4C2H5.
C. C6H5COOC2H5.
D. C2H5COOC6H5.
679. (H B 11) Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau
khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn
phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh
cht trn l
A. 5.
B. 2.
C. 4.
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n tp Ha 12
D. 6.
680. (C 11) x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch
h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny
u khng tham gia phn ng trng bc. Cng thc ca hai este l
A. C2H5COOC2H5 v C3H7COOCH3.
B. C2H5COOCH3 v CH3COOC2H5.
C. HCOOC4H9 v CH3COOC3H7.
D. CH3COOC2H5 v HCOOC3H7.
681. (H B 12) un nng m gam hn hp X gm cc cht c cng mt loi nhm chc
vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit
cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi
Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung nng cht rn thu
c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht
kh. Gi tr ca m l
A. 40,60.
B. 22,60.
C. 34,30.
D. 34,51.
682. (C 11) Hp cht hu c X c cng thc phn t l C4H8O3. X c kh nng tham
gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thy
phn ca X trong mi trng kim c kh nng ha tan Cu(OH)2 to thnh dung dch
mu xanh lam. Cng thc cu to ca X c th l
A. CH3COOCH2CH2OH.
B. HCOOCH2CH(OH)CH3.
C. HCOOCH2CH2CH2OH.
D. CH3CH(OH)CH(OH)CHO.
683. (C 11) phn ng ht vi mt lng hn hp gm hai cht hu c n chc X
v Y (MX < MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra
hon ton thu c 24,6 gam mui ca mt axit hu c v m gam mt ancol. t
chy hon ton lng ancol trn thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng
thc ca Y l
A. CH3COOCH3.
B. C2H5COOC2H5.
C. CH2=CHCOOCH3.
D. CH3COOC2H5.
684. (C 11) Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1
mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c
cha 0,22 mol Ca(OH)2 th vn thu c kt ta. Thu phn X bng dung dch NaOH
thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm
khi lng ca oxi trong X l
A. 37,21%.
B. 36,36%.
C. 43,24%.
D. 53,33%.
685. (C 12) Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng
th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11
gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l
A. C2H5COOCH3.
B. C2H5COOC2H5.
C. CH3COOC2H5.
D. HCOOC3H7.
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n tp Ha 12
686. (H B 09) Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol
n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X
phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu
c m gam cht rn. Gi tr m l
A. 27,75.
B. 24,25.
C. 26,25.
D. 29,75.
687. (H A 13) Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gam
X vo 360 ml dung dch NaOH 0,5M (d 20% so vi lng cn phn ng) n phn
ng hon ton, thu c dung dch Y. C cn Y thu c m gam cht rn khan. Mt
khc, t chy hon ton 6,9 gam X cn va 7,84 lt O2 (ktc), thu c 15,4 gam
CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l
A. 13,2.
B. 11,1.
C. 12,3.
D. 11,4.
688. (H B 13) Thy phn hon ton m1 gam este X mch h bng dung dch NaOH d,
thu c m2 gam ancol Y (khng c kh nng phn ng vi Cu(OH)2) v 15 gam hn
hp mui ca hai axit cacboxylic n chc. t chy hon ton m2 gam Y bng oxi
d, thu c 0,3 mol CO2 v 0,4 mol H2O. Gi tr ca m1 l
A. 14,6.
B. 11,6.
C. 10,6.
D. 16,2.
HIU SUT PHN NG HNG S CN BNG
689. (C 08) un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc,
hiu sut phn ng este ho bng 50%). Khi lng este to thnh l
A. 6,0 gam.
B. 4,4 gam.
C. 8,8 gam.
D. 5,2 gam.
690. (H A 07) Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3
gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m
gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca
m l
A. 8,10.
B. 10,12.
C. 16,20.
D. 6,48.
691. (C 07) un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n
khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn
ng este ho l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
692. (C 10) Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H 2SO4
c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l
A. 31,25%.
B. 40,00%.
C. 62,50%.
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n tp Ha 12
D. 50,00%.
693. (H A 07) Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH,
lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo
axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn
ng este ho thc hin cng nhit )
A. 0,456.
B. 2,412.
C. 2,925.
D. 0,342.
694. (H A 12) t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n
chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc
nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam
hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l
A. 8,16.
B. 4,08.
C. 2,04.
D. 6,12.
695. (H A 07) Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH,
lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo
axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn
ng este ho thc hin cng nhit )
A. 0,456.
B. 2,412.
C. 2,925.
D. 0,342.
696. thu c 1,6 mol este E ngi ta thc hin phn ng este ha t 2 mol axit
axetic v a (mol) ancol etylic. Bit hng s cn bng ca phn ng ny l 4 th gi tr
ca a l:
A. 3,2.
B. 2,8.
C. 6,4.
D. 4,8.
697. Hng s cn bng ca phn ng este ha ca axit axetic vi ancol etylic ny l 4.
Nu cho hn hp cng s mol axit v ancol tc dng vi nhau khi lng este thu
c l ln nht th % ancol v axit b este ha l:
A. 50%.
B. 66,7%.
C. 33,3%.
D. 65%.
698. (H A 12) Kh este no, n chc, mch h X bng LiAlH4 thu c ancol duy nht
Y. t chy hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton
0,1 mol X thu c tng khi lng CO2 v H2O l
A. 24,8 gam.
B. 16,8 gam.
C. 18,6 gam.
D. 28,4 gam.
699. X l este no, n chc, mch h. Kh hon ton X bng LiAlH 4 thu c hn hp
Y gm hai ancol ng ng lin tip. Cho 3,9 gam Y tc dng ht vi Na thu 1,12 lt
H2 (kc). Cng thc phn t ca X l:
A. C3H6O2.
B. C4H8O2.
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n tp Ha 12
C. C2H4O2.
D. C3H4O2.
700. X l este no, n chc, mch h. Kh hon ton mt lng X thu c 1 ancol
duy nht, t chy lng ancol trn, thu c 4,48 lt CO 2 (kc) v 5,4 gam H2O. X
l
A. CH3COOC2H3.
B. CH3COOC2H5.
C. HCOOCH3.
D. C2H5COOC2H5.
701. Kh hon ton m gam este no, n chc X bng LiAlH 4 thu c hn hp Y gm
hai ancol. t chy hon ton Y thu c 4,48 lt CO2 (kc) v 5,4 gam H2O. X c th
l
A. HCOOC3H7.
B. CH3COOC2H5.
C. C2H5COOC2H5.
D. HCOOC2H5.
702. Kh hon ton m gam este no, n chc X thu c hn hp hai ancol. Lng
ancol thu c cho tc dng ht vi Na thy thot ra 1,12 lt H 2 (kc). t chy
cng m gam X thu c 3,36 lt CO2 (kc). Ch ra m:
A. 3,7 gam.
B. 3,4gam.
C. 7,4gam.
D. 6,8gam.
PHN 2: LIPIT
DNG 1: L THUYT
703. (C 11) Cng thc ca triolein l
A. (CH3[CH2]14COO)3C3H5.
B. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5.
C. (CH3[CH2]16COO)3C3H5.
D. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5.
704. (H A 12) Cho cc pht biu sau:
(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi
hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5,
(C17H35COO)3C3H5.
S pht biu ng l
A. 4.
B. 1.
C. 2.
D. 3.
705. (H B 13) Pht biu no sau y khng ng?
A. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
B. Cc cht bo thng khng tan trong nc v nh hn nc.
C. Cht bo b thy phn khi un nng trong dung dch kim.
D. Cht bo l trieste ca etylen glicol vi cc axit bo.
706. (H B 11) Triolein khng tc dng vi cht (hoc dung dch) no sau y?
A. H2O (xc tc H2SO4 long, un nng).
B. Cu(OH)2 ( iu kin thng).
C. Dung dch NaOH (un nng).
D. H2 (xc tc Ni, un nng).
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n tp Ha 12
707. (H B 11) Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat,
tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng
sinh ra ancol l
A. 2.
B. 4.
C. 5.
D. 3.
708. (H A 08) Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring
bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch
hp, s phn ng xy ra l
A. 4.
B. 2.
C. 3.
D. 5.
709. (C 09) Pht biu no sau y sai?
A. Nhit si ca este thp hn hn so vi ancol c cng phn t khi.
B. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn.
C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.
D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol.
710.

711.

712.

713.

714.

715.

716.
717.

718.

719.

+ HCl
+H2 du (Ni, t )
+ NaOH du, t

(H A 10) Cho s chuyn ho: Triolein

X
Y
Z. Tn gi ca Z l
A. axit oleic.
B. axit linoleic.
C. axit stearic.
D. axit panmitic.
(H B 12) S trieste khi thy phn u thu c sn phm gm glixerol, axit
CH3COOH v axit C2H5COOH l
A. 9.
B. 4.
C. 6.
D. 2.
(H B 07) Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH
v C15H31COOH, s loi trieste c to ra ti a l
A. 6.
B. 3.
C. 4.
D. 5.
Tng s loi cht bo nhiu nht c th c to ra khi cho hn hp 3 axit bo (
gm axit stearic, axit linoleic v axit oleic) tc dng vi glixerol l:
A. 12.
B. 18.
C. 24.
D. 16.
Tng s sn phm este c th c to nhiu nht khi cho glixerol tc dng vi
hn hp 3 axit bo (gm axit stearic, axit panmitic v axit oleic) l:
A. 6
B. 18.
C. 24.
D. 39.
Phn t este E (ch cha mt loi nhm chc) to bi axit benzoic v glixerol, c
tng s lin kt v s mch vng l:
A. 3.
B. 6.
C. 12.
D. 15.
Cht bo no di y l cht bo cha no:
A. C51H98O6.
B. C57H110O6.
C. C55H104O6.
D. C53H102O6.
Khi thy phn cht bo X trong dung dch NaOH, thu c glixerol v hn hp 2
mui C17H35COONa, C15H31COONa c khi lng hn km nhau 1,817 ln.Trong
phn t X c:
A. 3 gc C17H35COO
B. 2 gc C17H35COO
C. 2 gc C15H31COO
D. 3 gc C15H31COO
DNG 2: THY PHN CHT BO
(H A 07) Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin)
v hai loi axit bo. Hai loi axit bo l
A. C15H31COOH v C17H35COOH.
B. C17H31COOH v C17H33COOH.
C. C17H33COOH v C15H31COOH.
D. C17H33COOH v C17H35COOH.
(H B 08) X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH.
C cn dung dch sau phn ng thu c khi lng x phng l
A. 17,80 gam.
B. 18,24 gam.
C. 16,68 gam.
D. 18,38 gam..

THPT Tn Tc

91

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n tp Ha 12
720. (H A 13) Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung
dch NaOH d, un nng, thu c m gam glixerol. Gi tr ca m l
A. 27,6.
B. 4,6.
C. 14,4.
D. 9,2.
721. ((C 13) Khi x phng ha triglixerit X bng dung dch NaOH d, un nng, thu
c sn phm gm glixerol, natri oleat, natri stearat v natri panmitat. S ng phn
cu to tha mn tnh cht trn ca X l
A. 4.
B. 2.
C. 1.
D. 3.
722. Thy phn a gam mt este X thu c 0,92 gam glixerol, 3,02 gam natri linoleat
C17H31COONa v m gam natri oleat C17H33COONa. Tnh gi tr ca a, m. Vit CTCT
c th c ca X

THPT Tn Tc

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723.
724.
725.

726.

727.

728.

729.

730.

731.

732.

733.

734.

n tp Ha 12

CHNG 2: CACBOHIDRAT
(H A 09) Cacbohirat nht thit phi cha nhm chc ca
A. ancol.
B. xeton.
C. amin.
D. anehit.
(H B 13) Cacbohirat no sau y thuc loi isaccarit?
A. Amiloz.
B. Saccaroz.
C. Glucoz.
D. Xenluloz.
(H B 13) Cht no di y khi cho vo dung dch AgNO3 trong NH3 d, un nng,
khng xy ra phn ng trng bc?
A. Mantoz.
B. Fructoz.
C. Saccaroz.
D. Glucoz.
(C 10) Cp cht no sau y khng phi l ng phn ca nhau?
A. Ancol etylic v imetyl ete.
B. Saccaroz v xenluloz.
C. Glucoz v fructoz.
D. 2-metylpropan-1-ol v butan-2-ol.
(C 13) Dy cc cht no di y u phn ng c vi Cu(OH)2 iu kin
thng?
A. Etylen glicol, glixerol v ancol etylic.
B. Glucoz, glixerol v saccaroz.
C. Glucoz, glixerol v metyl axetat.
D. Glixerol, glucoz v etyl axetat.
(H A 10) Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz.
B. mt gc -glucoz v mt gc -fructoz
C. hai gc -glucoz.
D. mt gc -glucoz v mt gc -fructoz
(H A 13) Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung
dch AgNO3 trong NH3 d, un nng?
A. vinylaxetilen, glucoz, axit propionic.
B. vinylaxetilen, glucoz, anehit axetic.
C. glucoz, imetylaxetilen, anehit axetic.
D. vinylaxetilen, glucoz, imetylaxetilen.
(H A 13) Dy cc cht u c kh nng tham gia phn ng thy phn trong dung
dch H2SO4 un nng l:
A. glucoz, tinh bt v xenluloz.
B. saccaroz, tinh bt v xenluloz.
C. glucoz, saccaroz v fructoz.
D. fructoz, saccaroz v tinh bt.
(C 12) Cho dy cc cht: anehit axetic, axetilen, glucoz, axit axetic, metyl axetat.
S cht trong dy c kh nng tham gia phn ng trng bc l
A. 3.
B. 2.
C. 5.
D. 4.
(H A 09) Dy gm cc dung dch u tham gia phn ng trng bc l:
A. Glucoz, mantoz, axit fomic, anehit axetic.
B. Fructoz, mantoz, glixerol, anehit axetic.
C. Glucoz, glixerol, mantoz, axit fomic.
D. Glucoz, fructoz, mantoz, saccaroz.
(H B 10) Cc dung dch phn ng c vi Cu(OH)2 nhit thng l:
A. glixerol, axit axetic, glucoz.
B. lng trng trng, fructoz, axeton.
C. anehit axetic, saccaroz, axit axetic.
D. fructoz, axit acrylic, ancol etylic.
(H B 10) Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ha
tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom.
Cht X l
A. xenluloz. B. mantoz.
C. glucoz .
D. saccaroz.

THPT Tn Tc

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n tp Ha 12
735. (C 10) Thu phn hon ton tinh bt trong dung dch axit v c long, thu c
cht hu c X. Cho X phn ng vi kh H2 (xc tc Ni, to), thu c cht hu c Y.
Cc cht X, Y ln lt l:
A. glucoz, sobitol.
B. glucoz, saccaroz.
C. glucoz, etanol.
D. glucoz, fructoz.
736. (H B 09) Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc
Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn
ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca
xenluloz l:
A. (2), (3), (4) v (5).
B. (3), (4), (5) v (6).
C. (1), (2), (3) v (4).
D. (1), (3), (4) v (6).
737. (C 11) Cho cc cht: saccaroz, glucoz, fructoz, etyl fomat, axit fomic v anehit
axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc
va c kh nng phn ng vi Cu(OH)2 iu kin thng l
A. 3.
B. 5.
C. 4.
D. 2.
738. (H B 12) Th nghim no sau y chng t trong phn t glucoz c 5 nhm
hiroxyl?
A. Kh hon ton glucoz thnh hexan.
B. Cho glucoz tc dng vi Cu(OH)2.
C. Tin hnh phn ng to este ca glucoz vi anhirit axetic.
D. Thc hin phn ng trng bc.
739. (H A 07) chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi
ta cho dung dch glucoz phn ng vi
A. Cu(OH)2 trong NaOH, un nng.
B. Cu(OH)2 nhit thng.
C. kim loi Na.
D. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng.
740. (C 07) Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau:
A. glucoz, mantoz, glixerin (glixerol), anehit axetic.
B. lng trng trng, glucoz, fructoz, glixerin (glixerol).
C. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic.
D. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic.
741. (H A 08) Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn
ng
A. ha tan Cu(OH)2.
B. trng gng.
C. trng ngng.
D. thy phn.
742. (H B 08) Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11
(mantoz). S cht trong dy tham gia c phn ng trng gng l
A. 5.
B. 3.
C. 6.
D. 4.
743. (C 08) Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S
cht trong dy tham gia phn ng trng gng l
A. 3.
B. 4.
C. 2.
D. 5.
744. ((H B 13) Cho cc pht biu sau:
(a) Hiro ha hon ton glucoz to ra axit gluconic.
(b) iu kin thng, glucoz v saccaroz u l nhng cht rn, d tan trong
nc.
(c) Xenluloz trinitrat l nguyn liu sn xut t nhn to v ch to thuc sng
khng khi.
(d) Amilopectin trong tinh bt ch c cc lin kt -1,4-glicozit.
(e) Sacaroz b ha en trong H2SO4 c.
(f) Trong cng nghip dc phm, saccaroz c dng pha ch thuc.
Trong cc pht biu trn, s pht biu ng l
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A. 2.
B. 3.
C. 5.
D. 4.
745. (C 13) Pht biu no sau y l ng?
A. Hiro ha hon ton glucoz (xc tc Ni, un nng) to ra sobitol.
B. Xenluloz tan tt trong nc v etanol.
C. Thy phn hon ton tinh bt trong dung dch H2SO4, un nng, to ra fructoz.
D. Saccaroz c kh nng tham gia phn ng trng bc.
746. (C 12) Cho cc pht biu sau:
(1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc;
(2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc
tc;
(3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp;
(4) Xenluloz v saccaroz u thuc loi isaccarit.
Pht biu ng l
A. (1) v (2).
B. (3) v (4).
C. (2) v (4).
D. (1) v (3).
747. (C 11) C mt s nhn xt v cacbohirat nh sau:
(1) Saccaroz, tinh bt v xenluloz u c th b thu phn.
(2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng
tham gia phn ng trng bc.
(3) Tinh bt v xenluloz l ng phn cu to ca nhau.
(4) Phn t xenluloz c cu to bi nhiu gc -glucoz.
(5) Thu phn tinh bt trong mi trng axit sinh ra fructoz.
Trong cc nhn xt trn, s nhn xt ng l
A. 2.
B. 4.
C. 3.
D. 5. D. 3
748. (H A 12) Cho cc pht biu sau v cacbohirat:
(a) Tt c cc cacbohirat u c phn ng thy phn.
(b) Thy phn hon ton tinh bt thu c glucoz.
(c) Glucoz, fructoz v mantoz u c phn ng trng bc.
(d) Glucoz lm mt mu nc brom.
S pht biu ng l
A. 1.
B. 2.
C. 3.
D. 4.
749. (H B 11) Cho cc pht biu sau v cacbohirat:
(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu
xanh lam.
(d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng
axit, ch thu c mt loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO 3 trong NH3 thu c
Ag.
(g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l
A. 5.
B. 6.
C. 4.
D. 3.
750. (H B 11) Cho cc pht biu sau:
(a) C th dng nc brom phn bit glucoz v fructoz.
(b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau.
(c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO 3 trong
NH3.
(d) Trong dung dch, glucoz v fructoz u ha tan Cu(OH) 2 nhit thng
cho dung dch mu xanh lam.
(e) Trong dung dch, fructoz tn ti ch yu dng mch h.
(g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ).
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S pht biu ng l
A. 4.
B. 5.
C. 3.
D. 2.
751. (H B 09) Pht biu no sau y khng ng?
A. Glucoz tc dng c vi nc brom.
B. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH.
C. Glucoz tn ti dng mch h v dng mch vng.
D. dng mch h, glucoz c 5 nhm OH k nhau.
752. (H B 07) Pht biu khng ng l
A. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng
gng.
B. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O.
C. Dung dch fructoz ha tan c Cu(OH)2.
D. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt
monosaccarit.
753. (H A 12) Cho cc pht biu sau:
(a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng
s mol H2O.
(b) Trong hp cht hu c nht thit phi c cacbon v hiro.
(c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn
t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau.
(d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag.
(e) Saccaroz ch c cu to mch vng.
S pht biu ng l
A. 5.
B. 3.
C. 4.
D. 2.
754. (H A 13) Cho cc pht biu sau:
(a) Glucoz c kh nng tham gia phn ng trng bc.
(b) S chuyn ha tinh bt trong c th ngi c sinh ra mantoz.
(c) Mantoz c kh nng tham gia phn ng trng bc.
(d) Saccaroz c cu to t hai gc -glucoz v -fructoz.
Trong cc pht biu trn, s pht biu ng l
A. 4.
B. 2.
C. 3.
D. 1.
755. (H B 09) Pht biu no sau y l ng?
A. Saccaroz lm mt mu nc brom.
B. Xenluloz c cu trc mch phn nhnh.
C. Amilopectin c cu trc mch phn nhnh.
D. Glucoz b kh bi dung dch AgNO3 trong NH3.
756. (H A 12) Cho s phn ng:
xu c ta c
Y
(a) X + H2O
(b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3
xuc tac
E + Z
(c) Y
a nh sa ng
(d) Z + H2O
X+G
cha t die p lu c

X, Y, Z ln lt l:
A. Xenluloz, fructoz, cacbon ioxit.
B. Xenluloz, saccaroz, cacbon ioxit.
C. Tinh bt, glucoz, etanol.
D. Tinh bt, glucoz, cacbon ioxit.
757. (C 07) Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln
lt l
A. CH3CH2OH v CH2=CH2.
B. CH3CHO v CH3CH2OH.
C. CH3CH2OH v CH3CHO.
D. CH3CH(OH)COOH v CH3CHO.
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758. (C 08) Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng):
Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l:
A. C2H5OH, CH3COOH.
B. CH3COOH, CH3OH.
C. CH3COOH, C2H5OH.
D. C2H4, CH3COOH.
759. (C 09) Cho cc chuyn ho sau:
Ni, t

Sobitol
Y + H2

xt, t

Y ;
X + H2O

Amoni gluconat + 2Ag + 2NH4NO3

Y + 2AgNO3 + 3NH3 + H2O

xt

E+Z
Y

760.

761.

762.

763.

764.

nh sng

X+G
Z + H2O
diep luc

X, Y v Z ln lt l:
A. tinh bt, glucoz v kh cacbonic.
B. xenluloz, glucoz v kh cacbon oxit.
C. xenluloz, fructoz v kh cacbonic.
D. tinh bt, glucoz v ancol etylic.
(H A 08) Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 2,25 gam.
B. 1,82 gam.
C. 1,44 gam.
D. 1,80 gam.
TRNG GNG CACBOHYRAT
(C 07) Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d
AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol
(hoc mol/l) ca dung dch glucoz dng l
A. 0,20M.
B. 0,10M.
C. 0,01M.
D. 0,02M.
(C 10) Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c
dung dch X. Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3
trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 21,60.
B. 2,16.
C. 4,32.
D. 43,20.
(H B 11) Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt
thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%).
Khi cho ton b X tc dng vi mt lng d dung dch AgNO 3 trong NH3 th lng
Ag thu c l
A. 0,090 mol.
B. 0,12 mol.
C. 0,095 mol.
D. 0,06 mol.
(H B 12) Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong
mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung
ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d
dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l
A. 6,480.
B. 9,504.
C. 8,208.
D. 7,776.

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765.

766.

767.

768.

769.

770.

771.

n tp Ha 12

LN MEN RU
(C 12) Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu
sut ca qu trnh ln men l 80%. Gi tr ca V l
A. 46,0.
B. 57,5.
C. 23,0.
D. 71,9.
(H B 08) Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5
lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring
ca ru etylic nguyn cht l 0,8 g/ml)
A. 6,0 kg.
B. 5,4 kg.
C. 5,0 kg.
D. 4,5 kg.
(H A 07) Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%.
Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c
550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta.
Gi tr ca m l
A. 750.
B. 650.
C. 810.
D. 550.
(H A 11) Ancol etylic c iu ch t tinh bt bng phng php ln men vi
hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m
gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dung dch X. Bit khi
lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m
l
A. 324.
B. 486.
C. 297.
D. 405.
(C 13) Tin hnh sn xut ancol etylic t xenluloz vi hiu sut ca ton b qu
trnh l 70%. sn xut 2 tn ancol etylic, khi lng xenluloz cn dng l
A. 5,031 tn.
B. 10,062 tn.
C. 3,521 tn.
D. 2,515 tn.
(C 09) Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO 2 sinh
ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt
ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l
A. 48.
B. 58.
C. 30.
D. 60.
(H A 09) Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp
th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch
sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi
tr ca m l
A. 20,0.
B. 30,0.
C. 13,5.
D. 15,0.

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772. (H A 13) Ln men m gam glucoz to thnh ancol etylic (hiu sut phn ng
bng 90%). Hp th hon ton lng kh CO2 sinh ra vo dung dch Ca(OH)2 d, thu
c 15 gam kt ta. Gi tr ca m l
A. 7,5.
B. 15,0.
C. 18,5.
D. 45,0.
773. (C 11) Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic.
Hiu sut qu trnh ln men to thnh ancol etylic l
A. 54%.
B. 40%.
C. 80%.
D. 60%.
774. (H A 10) T 180 gam glucoz, bng phng php ln men ru, thu c a gam
ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln
men gim, thu c hn hp X. trung ha hn hp X cn 720 ml dung dch NaOH
0,2M. Hiu sut qu trnh ln men gim l
A. 90%.
B. 10%.
C. 80%.
D. 20%.

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775.

776.
777.

778.
779.
780.

781.

782.

783.

784.

785.

786.

787.

788.

n tp Ha 12

CHNG 3: AMIN AMINO AXIT - PROTEIN

Phn 1: AMIN
(C 12) Cng thc chung ca amin no, n chc, mch h l
A. CnH2n-5N (n 6).
B. CnH2n+1N (n 2).
C. CnH2n-1N (n 2).
D. CnH2n+3N (n 1).
(H A 12) S amin bc mt c cng cng thc phn t C3H9N l
A. 3.
B. 1.
C. 2.
D. 4.
(C 09) S ng phn cu to ca amin bc mt c cng cng thc phn t C 4H11N
l
A. 3.
B. 2.
C. 5.
D. 4.
(C 10) S amin thm bc mt ng vi cng thc phn t C7H9N l
A. 3.
B. 2.
C. 5.
D. 4.
(H A 13) Dung dch no sau y lm phenolphtalein i mu?
A. axit axetic.
B. alanin.
C. glyxin.
D. metylamin.
(H B 13) S ng phn amin bc mt, cha vng benzen, c cng cng thc phn
t C7H9N l
A. 3.
B. 2.
C. 5.
D. 4.
(H A 10) Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng
phn cu to nht l
A. C3H9N.
B. C3H7Cl.
C. C3H8O.
D. C3H8.
(H B 11) Ancol v amin no sau y cng bc?
A. (CH3)3COH v (CH3)3CNH2.
B. (C6H5)2NH v C6H5CH2OH.
C. (CH3)2CHOH v (CH3)2CHNH2.
D. C6H5NHCH3 v C6H5CH(OH)CH3.
(H B 11) Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2)
CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l:
A. (2), (1), (3).
B. (3), (1), (2).
C. (1), (2), (3).
D. (2), (3), (1).
(H B 07) Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac.
B. amoni clorua, metyl amin, natri hiroxit.
C. metyl amin, amoniac, natri axetat.
D. anilin, amoniac, natri hiroxit.
(C 10) Dung dch no sau y lm qu tm chuyn mu xanh?
A. Phenylamoni clorua.
B. Anilin.
C. Glyxin.
D. Etylamin.
(H A 12) Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH
(4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim
dn l:
A. (3), (1), (5), (2), (4).
B. (4), (1), (5), (2), (3).
C. (4), (2), (3), (1), (5).
D. (4), (2), (5), (1), (3).
(C 13) Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang
phi l:
A. Phenylamin, amoniac, etylamin.
B. Etylamin, amoniac, phenylamin.
C. Etylamin, phenylamin, amoniac.
D. Phenylamin, etylamin, amoniac.
(H A 12) Pht biu no sau y l ng?
A. Tt c cc peptit u c phn ng mu biure.
B. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit.
C. Mui phenylamoni clorua khng tan trong nc.

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D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai.
+ HONO
+ CuO
+ CH3I
Z. Bit Z c
Y
789. (H B 07) Cho s phn ng: NH3
X
t le mol 1:1
to

790.

791.

792.

793.

794.

795.

796.

797.

kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l:

A. C2H5OH, CH3CHO.
B. CH3OH, HCOOH.
C. C2H5OH, HCHO.
D. CH3OH, HCHO.
(C 08) Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH,
CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl
l
A. 4.
B. 2.
C. 3.
D. 5.
(H A 09) Pht biu no sau y l ng?
A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
C. Benzen lm mt mu nc brom nhit thng.
D. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni.
(C 12) Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va
vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi
tr ca V l
A. 320.
B. 50.
C. 200.
D. 100.
(C 07) trung ha 25 gam dung dch ca mt amin n chc X nng 12,4%
cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l
A. C3H5N.
B. C2H7N.
C. CH5N.
D. C3H7N.
(H B 11) Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng
ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba
kim loi t 14,16 gam X?
A. 10,56 gam.
B. 3,36 gam.
C. 7,68 gam.
D. 6,72 gam.
(C 08) Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi
phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c
9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l
A. 5.
B. 4.
C. 2.
D. 3.
(H A 09) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu
c 15 gam mui. S ng phn cu to ca X l
A. 4.
B. 8.
C. 5.
D. 7.
(C 09) Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t
C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung
dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l
A. HCOONH2(CH3)2.

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B. CH3CH2COONH4.
C. HCOONH3CH2CH3.
D. CH3COONH3CH3.
798. (H B 10) Trung ha hon ton 8,88 gam mt amin (bc mt, mch cacbon khng
phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l
A. H2NCH2CH2CH2CH2NH2.
B. CH3CH2CH2NH2.
C. H2NCH2CH2NH2.
D. H2NCH2CH2CH2NH2.
799. (C 10) Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy
ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui.
Cng thc ca 2 amin trong hn hp X l
A. C3H7NH2 v C4H9NH2.
B. CH3NH2 v C2H5NH2.
C. C2H5NH2 v C3H7NH2.
D. CH3NH2 v (CH3)3N.
800. (H B 13) Cho 0,76 gam hn hp X gm hai amin n chc, c s mol bng nhau,
phn ng hon ton vi dung dch HCl d, thu c 1,49 gam mui. Khi lng ca
amin c phn t khi nh hn trong 0,76 gam X l
A. 0,58 gam.
B. 0,31 gam.
C. 0,45 gam.
D. 0,38 gam.
801. (C 11) Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v
khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol
Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng?
A. Trong phn t X c mt lin kt .
B. Phn t X c mch cacbon khng phn nhnh.
C. Tn thay th ca Y l propan-2-ol.
D. Tch nc Y ch thu c mt anken duy nht.
802. (C 13) t chy hon ton mt amin n chc X trong kh oxi d, thu c kh N2;
13,44 lt kh CO2 (ktc) v 18,9 gam H2O. S cng thc cu to ca X l
A. 4.
B. 3.
C. 2.
D. 1.
803. (H A 12) Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l
ng ng k tip (MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2
(ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht Y l
A. etylamin.
B. propylamin.
C. butylamin.
D. etylmetylamin.
804. (H A 07) Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2,
1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca
X l
A. C4H9N.
B. C3H7N.
C. C2H7N.
D. C3H9N.

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805. (H A 10) t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra
8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o
cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh
nit. Cht X l
A. CH3-CH2-CH2-NH2.
B. CH2=CH-CH2-NH2.
C. CH3-CH2-NH-CH3.
D. CH2=CH-NH-CH3.
806. (H B 10) t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu
c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl
(d), s mol HCl phn ng l
A. 0,1.
B. 0,4.
C. 0,3.
D. 0,2.
807. (H B 11) Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y
gm metylamin v etylamin c t khi so vi H2 l 17,833. t hon ton V1 lt Y
cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh o cng
iu kin nhit , p sut). T l V1 : V2 l
A. 2 : 1.
B. 1 : 2.
C. 3 : 5.
D. 5 : 3.
808. (H B 12) t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai
hirocacbon ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp
Y gm kh v hi. Dn ton b Y i qua dung dch H2SO4 c (d), th tch kh cn li
l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon l
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C2H6 v C3H8.
D. C3H8 v C4H10.
809. (H A 10) Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip.
t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml
hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th
cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t
ca hai hirocacbon l
A. CH4 v C2H6.
B. C2H4 v C3H6.
C. C2H6 v C3H8.
D. C3H6 v C4H8.
Phn 2: AMINO AXIT
810. (H B 09) S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l
A. 3.
B. 1.
C. 2.
D. 4.
811. (H A 11) S ng phn amino axit c cng thc phn t C3H7O2N l
A. 1.
B. 2.
C. 4.
D. 3.
812. (H A 11) Dung dch no sau y lm qu tm i thnh mu xanh?
A. Dung dch glyxin.
B. Dung dch valin.
C. Dung dch lysin.
D. Dung dch alanin.
813. (C 11) Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH v
H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu
phenolphtalein l
A. 3.
B. 4.
C. 2.
D. 5.
THPT Tn Tc

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814. (H A 13) Trong cc dung dch: CH3CH2NH2, H2NCH2COOH, H2NCH2
CH(NH2)COOH, HOOCCH2CH2CH(NH2)COOH, s dung dch lm xanh qu tm
l
A. 4.
B. 3.
C. 1.
D. 2.
815. (C 11) Hai cht no sau y u tc dng c vi dung dch NaOH long?
A. CH3NH3Cl v CH3NH2.
B. CH3NH3Cl v H2NCH2COONa.
C. CH3NH2 v H2NCH2COOH.
D. ClH3NCH2COOC2H5 v H2NCH2COOC2H5.
816. (H A 12) Dung dch cht no sau y lm qu tm chuyn thnh mu hng?
A. Axit ,-iaminocaproic.
B. Axit -aminopropionic.
C. Axit -aminoglutaric.
D. Axit aminoaxetic.
817. (C 09) Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc
dng vi dung dch NaOH (to) v vi dung dch HCl (to). S phn ng xy ra l
A. 4.
B. 3.
C. 5.
D. 6.
818. (H A 08) C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2NCH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH,
H2N-CH2-COONa. S lng cc dung dch c pH < 7 l
A. 3.
B. 5.
C. 4.
D. 2.
819. (H B 12) Alanin c cng thc l
A. C6H5-NH2.
B. CH3-CH(NH2)-COOH.
C. H2N-CH2-COOH.
D. H2N-CH2-CH2-COOH.
820. (H B 13) Amino axit X c phn t khi bng 75. Tn ca X l
A. alanin.
B. glyxin.
C. valin.
D. lysin.
821. (C 13) Phn trm khi lng ca nguyn t nit trong alanin l
A. 15,73%.
B. 18,67%.
C. 15,05%.
D. 17,98%.
822. (C 12) S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic
tng ng l
A. 1 v 2.
B. 1 v 1.
C. 2 v 1.
D. 2 v 2.
823. (C 12) Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn
thay th ca X v Y ln lt l
A. propan1amin v axit 2aminopropanoic.
B. propan1amin v axit aminoetanoic.
C. propan2amin v axit aminoetanoic.
D. propan2amin v axit 2aminopropanoic.
824. (C 12) Pht biu no sau y l ng?
A. Axit glutamic l thnh phn chnh ca bt ngt.
B. Amino axit thuc loi hp cht hu c tp chc.
C. Cc amino axit thin nhin hu ht l cc -amino axit.
D. nhit thng, cc amino axit u l nhng cht lng.
825. (H B 11) Pht biu khng ng l:
A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit.
B. Etylamin tc dng vi axit nitr nhit thng to ra etanol.
C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi
triu.
D. Metylamin tan trong nc cho dung dch c mi trng baz.
826. (H A 10) Pht biu ng l:
A. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz.
B. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit.
C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh
m.
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D. Axit nucleic l polieste ca axit photphoric v glucoz.
827. (C 11) Pht biu no sau y ng?
A. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit.
B. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho hp
cht mu tm.
C. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng
axit.
D. Amino axit l hp cht c tnh lng tnh.
828. (H B 14) C bao nhiu tripeptit (mch h) khi thy phn hon ton u thu c
sn phm gm alanin v glyxin?
A. 8.
B. 5.
C. 7.
D. 6.
829. (H B 12) Cho dy cc cht sau: toluen, phenyl fomat, fructoz, glyxylvalin (Gly-Val),
etylen glicol, triolein. S cht b thu phn trong mi trng axit l
A. 6.
B. 3.
C. 4.
D. 5.
830. (H B 07) Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l
A. protit lun cha chc hiroxyl.
B. protit lun l cht hu c no.
C. protit c khi lng phn t ln hn.
D. protit lun cha nit.
831. (H B 07) Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y),
amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi
dung dch NaOH v u tc dng c vi dung dch HCl l
A. X, Y, T.
B. Y, Z, T.
C. X, Y, Z, T.
D. X, Y, Z.
832. (H A 08) Pht biu khng ng l:
A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2COO.
B. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
C. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v
nhm cacboxyl.
D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin).
833. (H B 08) un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung
dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l:
A. H3N+-CH2-COOHCl, H3N+-CH2-CH2-COOHCl.
B. H2N-CH2-COOH, H2N-CH2-CH2-COOH.
C. H3N+-CH2-COOHCl, H3N+-CH(CH3)-COOHCl.
D. H2N-CH2-COOH, H2N-CH(CH3)-COOH.
834. (H A 09) Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l
A. dung dch NaOH.
B. dung dch NaCl.
C. Cu(OH)2/NaOH.
D. dung dch HCl.
835. (C 10) ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c
vi dung dch NaOH, va phn ng c vi dung dch HCl?
A. 4.
B. 2.
C. 1.
D. 3.
836. (C 09) Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O; Y +
HCl (d) Z + NaCl. Cng thc cu to ca X v Z ln lt l
A. H2NCH2COOC2H5 v ClH3NCH2COOH.
B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH.
D. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH.
837. (C 09) Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom.
Tn gi ca X l
A. amoni acrylat. B. axit -aminopropionic.
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C. axit -aminopropionic.
D. metyl aminoaxetat.
838. (H B 08) Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung
dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t
(theo vC) ca Y l
A. 85.
B. 68.
C. 46.
D. 45.
839. (H B 09) Cho hai hp cht hu c X, Y c cng cng thc phn t l C 3H7NO2.
Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y
to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l
A. CH3OH v NH3.
B. CH3OH v CH3NH2.
C. CH3NH2 v NH3.
D. C2H5OH v N2.
840. (H B 10) Hai hp cht hu c X v Y c cng cng thc phn t l C 3H7NO2, u
l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh.
Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l
A. vinylamoni fomat v amoni acrylat.
B. amoni acrylat v axit 2-aminopropionic.
C. axit 2-aminopropionic v amoni acrylat.
D. axit 2-aminopropionic v axit 3-aminopropionic.
841. (C 11) Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X
phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn
gi ca X l
A. glyxin.
B. valin.
C. alanin.
D. phenylalanin.
842. (C 12) Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl
d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui
khan?
A. 16,73 gam.
B. 8,78 gam.
C. 20,03 gam.
D. 25,50 gam.
843. (H A 07) -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit
HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l
A. H2NCH2COOH.
B. CH3CH2CH(NH2)COOH.
C. H2NCH2CH2COOH.
D. CH3CH(NH2)COOH.
844. (C 13) Cho 100 ml dung dch amino axit X nng 0,2M phn ng va vi 80
ml dung dch NaOH 0,25M, thu c dung dch Y. Bit Y phn ng ti a vi 120 ml
dung dch HCl 0,5M, thu c dung dch cha 4,71 gam hn hp mui. Cng thc
ca X l
A. H2NC3H5(COOH)2.
B. (H2N)2C2H3COOH.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH.
845. (H A 12) Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong
phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X
THPT Tn Tc
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n tp Ha 12
cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn
3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong
d th khi lng kt ta thu c l
A. 13 gam.
B. 20 gam.
C. 15 gam.
D. 10 gam.
846. (H B 12) Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung
dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch
HCl d, thu c dung dch cha m gam mui. Gi tr ca m l
A. 44,65.
B. 50,65.
C. 22,35.
D. 33,50.
847. (H B 11) Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc
hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng
hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO
(un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc
dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta.
Gi tr ca m l
A. 3,56.
B. 5,34.
C. 2,67.
D. 4,45.
848. (C 07) Hp cht X c cng thc phn t trng vi cng thc n gin nht, va
tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong
phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng
40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton
vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan.
Cng thc cu to thu gn ca X l
A. CH2=CHCOONH4.
B. H2NCOO-CH2CH3.
C. H2NCH2COO-CH3.
D. H2NC2H4COOH.
849. (C 08) Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho
15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu
c 19,4 gam mui khan. Cng thc ca X l
A. H2NC3H6COOH.
B. H2NCH2COOH.
C. H2NC2H4COOH.
D. H2NC4H8COOH.
850. (H B 09) Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl
0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40
gam dung dch NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH.
851. (H A 10) Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl
2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy
ra hon ton, s mol NaOH phn ng l
A. 0,70.
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B. 0,50.
C. 0,65.
D. 0,55.
852. (H A 10) Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h.
X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton
X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l
A. 7 v 1,0.
B. 8 v 1,5.
C. 8 v 1,0.
D. 7 v 1,5.
853. (H A 09) Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m 1
gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c
m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l
A. C5H9O4N.
B. C4H10O2N2.
C. C5H11O2N.
D. C4H8O4N2.
854. (H B 10) Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton
vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc,
nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha
(m+36,5) gam mui. Gi tr ca m l
A. 112,2.
B. 165,6.
C. 123,8.
D. 171,0.
855. (H A 09) Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X
phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y
nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng
lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca
m l
A. 10,8.
B. 9,4.
C. 8,2.
D. 9,6.
856. (H A 07) Cho hn hp X gm hai cht hu c c cng cng thc phn t
C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v
4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z
i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l
A. 16,5 gam.
B. 14,3 gam.
C. 8,9 gam.
D. 15,7 gam.
857. (H B 08) Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N
phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c
cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l
A. H2NCH2COOCH3.
B. HCOOH3NCH=CH2.
C. H2NCH2CH2COOH.
D. CH2=CHCOONH4.
858. (H A 13) Cho 100 ml dung dch amino axit X nng 0,4M tc dng va vi 80
ml dung dch NaOH 0,5M, thu c dung dch cha 5 gam mui. Cng thc ca X l
A. NH2C3H6COOH.
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B. NH2C3H5(COOH)2.
C. (NH2)2C4H7COOH.
D. NH2C2H4COOH.
859. (H B 13) Amino axit X c cng thc H2NCxHy(COOH)2. Cho 0,1 mol X vo 0,2 lt
dung dch H2SO4 0,5M, thu c dung dch Y. Cho Y phn ng va vi dung dch
gm NaOH 1M v KOH 3M, thu c dung dch cha 36,7 gam mui. Phn trm khi
lng ca nit trong X l
A. 10,526%.
B. 10,687%.
C. 11,966%.
D. 9,524%.
860. (C 09) Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t
C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung
dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l
A. HCOONH2(CH3)2.
B. CH3CH2COONH4.
C. HCOONH3CH2CH3.
D. CH3COONH3CH3.
861. (H A 11) Khi ni v peptit v protein, pht biu no sau y l sai?
A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin
kt peptit.
B. Thy phn hon ton protein n gin thu c cc -amino axit.
C. Tt c cc protein u tan trong nc to thnh dung dch keo.
D. Protein c phn ng mu biure vi Cu(OH)2.
862. (H A 11) Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, mcrezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c
vi dung dch NaOH long, un nng l
A. 3.
B. 6.
C. 4.
D. 5.
863. (C 12) Pht biu no sau y l sai?
A. Protein n gin c to thnh t cc gc -amino axit.
B. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
C. Trong phn t ipeptit mch h c hai lin kt peptit.
D. Tripeptit GlyAlaGly c phn ng mu biure vi Cu(OH)2.
864. (C 10) Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu
c ti a bao nhiu ipeptit khc nhau?
A. 1.
B. 4.
C. 2.
D. 3.
865. (C 12) Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch
KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam
mui khan. Gi tr ca m l
A. 1,46.
B. 1,36.
C. 1,64.
D. 1,22.
866. (C 09) Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi
ca X bng 100.000 vC th s mt xch alanin c trong phn t X l
A. 453.
B. 479.
C. 382.
D. 328.
867. (H B 10) Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1
mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon
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ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c
ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Phe-Gly-Ala-Val.
B. Gly-Ala-Val-Val-Phe.
C. Gly-Ala-Val-Phe-Gly.
D. Val-Phe-Gly-Ala-Gly.
868. (H A 11) Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn
hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l
A. 111,74.
B. 66,44.
C. 90,6.
D. 81,54.
869. (H A 13) Cho X l hexapeptit AlaGlyAlaValGlyVal v Y l tetrapeptit GlyAla
GlyGlu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit,
trong c 30 gam glyxin v 28,48 gam alanin. Gi tr ca m l
A. 73,4.
B. 77,6.
C. 83,2.
D. 87,4.
870. (H B 12) un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol
tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng
kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c
mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m l
A. 51,72.
B. 54,30.
C. 66,00.
D. 44,48.
871. (H A 11) Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn
hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm
cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c
cn cn thn dung dch, th lng mui khan thu c l
A. 8,15 gam.
B. 7,09 gam.
C. 7,82 gam.
D. 16,30 gam.
872. (H A 13) Peptit X b thy phn theo phng trnh phn ng X + 2H2O 2Y + Z
(trong Y v Z l cc amino axit). Thy phn hon ton 4,06 gam X thu c m gam
Z. t chy hon ton m gam Z cn va 1,68 lt kh O2 (ktc), thu c 2,64 gam
CO2; 1,26 gam H2O v 224 ml kh N2 (ktc). Bit Z c cng thc phn t trng vi
cng thc n gin nht. Tn gi ca Y l
A. lysin.
B. axit glutamic.
C. glyxin.
D. alanin.
873. (H A 07) t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2,
0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch
NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca
X l
A. H2N-CH2-CH2-COOH.
B. H2N-CH2-COO-CH3.
C. H2N-CH2-COO-C3H7.
D. H2N-CH2-COO-C2H5.
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874. (H B 10) ipeptit mch h X v tripeptit mch h Y u c to nn t mt
aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH).
t chy hon ton 0,1 mol Y, thu c tng khi lng CO 2 v H2O bng 54,9 gam.
t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong
d, to ra m gam kt ta. Gi tr ca m l
A. 120.
B. 60.
C. 30.
D. 45.
875. (H B 13) Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton hn
hp gm X v Y ch to ra mt amino axit duy nht c cng thc H2NCnH2nCOOH.
t chy 0,05 mol Y trong oxi d, thu c N2 v 36,3 gam hn hp gm CO2, H2O.
t chy 0,01 mol X trong oxi d, cho sn phm chy vo dung dch Ba(OH)2 d, thu
c m gam kt ta. Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 11,82.
B. 17,73.
C. 23,64.
D. 29,55.
876. (C 13) Cho X l axit cacboxylic, Y l amino axit (phn t c mt nhm NH 2). t
chy hon ton 0,5 mol hn hp gm X v Y, thu c kh N 2; 15,68 lt kh CO2 (ktc)
v 14,4 gam H2O. Mt khc, 0,35 mol hn hp trn phn ng va vi dung dch
cha m gam HCl. Gi tr ca m l
A. 4,38.
B. 5,11.
C. 6,39.
D. 10,22.

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877.

878.

879.

880.

881.

882.
883.

884.

885.
886.

887.

888.

889.

n tp Ha 12

POLIME V VT LIU POLIME

(H A 12) Loi t no sau y c iu ch bng phn ng trng hp?
A. T nitron.
B. T visco.
C. T xenluloz axetat.
D. T nilon-6,6.
(H B 12) Cc polime thuc loi t nhn to l
A. t visco v t nilon-6,6.
B. t tm v t vinilon.
C. t nilon-6,6 v t capron.
D. t visco v t xenluloz axetat.
(C 13) T no di y thuc loi t nhn to?
A. T nilon-6,6. B. T axetat.
C. T tm.
D. T capron.
(H B 13) Trong cc polime: t tm, si bng, t visco, t nilon-6, t nitron, nhng
polime c ngun gc t xenluloz l
A. si bng, t visco v t nilon-6.
B. t tm, si bng v t nitron.
C. si bng v t visco.
D. t visco v t nilon-6.
(H B 13) T nitron (olon) l sn phm trng hp ca monome no sau y?
A. CH2=CHCN. B. CH3COOCH=CH2.
C. CH2=C(CH3)COOCH3.
D. CH2=CHCH=CH2.
(H A 07) Nilon6,6 l mt loi
A. t visco.
B. polieste.
C. t poliamit.
D. t axetat.
(H B 07) Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2.
B. CH2=CH-CH=CH2, C6H5CH=CH2.
C. CH2=CH-CH=CH2, CH3-CH=CH2.
D. CH2=CH-CH=CH2, lu hunh.
(C 07) Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn
ng trng hp
A. C2H5COO-CH=CH2.
B. CH2=CH-COO-C2H5.
C. CH3COO-CH=CH2.
D. CH2=CH-COO-CH3.
(H B 08) Polime c cu trc mng khng gian (mng li) l
A. amilopectin. B. PE.
C. nha bakelit.
D. PVC.
(C 10) Polime no sau y c tng hp bng phn ng trng ngng?
A. poli(metyl metacrylat).
B. poli(etylen terephtalat).
C. polistiren.
D. poliacrilonitrin.
(H A 11) Sn phm hu c ca phn ng no sau y khng dng ch to t
tng hp?
A. Trng hp vinyl xianua.
B. Trng ngng hexametyleniamin vi axit aipic.
C. Trng ngng axit -aminocaproic.
D. Trng hp metyl metacrylat.
(H A 08) Pht biu ng l:
A. Tnh axit ca phenol yu hn ca ru (ancol).
B. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp.
C. Tnh baz ca anilin mnh hn ca amoniac.
D. Cao su thin nhin l sn phm trng hp ca isopren.
(C 12) Pht biu no sau y l ng?
A. Si bng, t tm thuc loi polime thin nhin.
B. T visco, t xenluloz axetat u thuc loi t tng hp.
C. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
D. T nilon6,6 c iu ch t hexametyleniamin v axit axetic.

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890. (C 12) Pht biu no sau y l sai?
A. Poli(metyl metacrylat) c dng ch to thy tinh hu c.
B. Cao su bunaN thuc loi cao su thin nhin.
C. Lc baz ca anilin yu hn lc baz ca metylamin.
D. Cht bo cn c gi l triglixerit hoc triaxylglixerol.
891. (C 11) Cho cc polime: (1) polietilen, (2) poli(metyl metacrylat), (3) polibutaien, (4)
polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime
c th b thu phn trong dung dch axit v dung dch kim l:
A. (1), (4), (5).
B. (1), (2), (5).
C. (2), (5), (6).
D. (2), (3), (6).
892. (H A 13) T nilon-6,6 l sn phm trng ngng ca
A. axit aipic v etylen glicol.
B. axit aipic v hexametyleniamin.
C. axit aipic v glixerol.
D. etylen glicol v hexametyleniamin.
893. (H A 12) C cc cht sau: keo dn ure-fomanehit; t lapsan; t nilon-6,6; protein;
si bng; amoni axetat; nha novolac. Trong cc cht trn, c bao nhiu cht m
trong phn t ca chng c cha nhm -NH-CO-?
A. 6.
B. 4.
C. 3.
D. 5.
894. (H B 12) Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin
(4), vinyl axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l
A. (1), (2) v (3). B. (1), (2) v (5).
C. (1), (3) v (5). D. (3), (4) v (5).
895. (H B 11) Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t
nilon-6,6. C bao nhiu t thuc loi t poliamit?
A. 1.
B. 2.
C. 3.
D. 4.
896. (C 07) Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron,
t enang, nhng loi t no thuc loi t nhn to?
A. T tm v t enang.
B. T visco v t nilon-6,6.
C. T nilon-6,6 v t capron.
D. T visco v t axetat.
897. (C 08) T nilon - 6,6 c iu ch bng phn ng trng ngng
A. HOOC-(CH2)2-CH(NH2)-COOH.
B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH.
C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2.
D. H2N-(CH2)5-COOH.
898. (H A 09) Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng
ng l
A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH.
B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH.
C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH.
D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH.
899. (H B 09) Dy gm cc cht u c kh nng tham gia phn ng trng hp l:
A. stiren; clobenzen; isopren; but-1-en.
B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen.
C. buta-1,3-ien; cumen; etilen; trans-but-2-en.
D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua.
900. (H B 09) Pht biu no sau y l ng?
A. T visco l t tng hp.
B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
C. Trng hp stiren thu c poli(phenol-fomanehit).
D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome
tng ng.
901. (C 09) Trong thc t, phenol c dng sn xut
A. nha rezit, cht dit c 2,4-D v thuc n TNT.
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B. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D.
C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric.
D. nha rezol, nha rezit v thuc tr su 666.
902. (H A 10) Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron,
nilon-6,6. S t tng hp l
A. 5.
B. 2.
C. 3.
D. 4.
903. (H A 10) Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7;
(4) poli(etylen-terephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm
ca phn ng trng ngng l:
A. (1), (3), (6).
B. (1), (2), (3).
C. (1), (3), (5).
D. (3), (4), (5).
904. (H B 10) Cc cht u khng b thu phn trong dung dch H2SO4 long nng l:
A. t capron; nilon-6,6; polietilen.
B. poli(vinyl axetat); polietilen; cao su buna.
C. nilon-6,6; poli(etylen-terephtalat); polistiren.
D. polietilen; cao su buna; polistiren.
905. (H B 10) Cho s chuyn ho sau:
o

+ H2 , t
+Z
xt, t
Y
Cao su buna-N.
C2H2
X
Pd, PbCO 3
xt, t o , p
o

Cc cht X, Y, Z ln lt l:
A. benzen; xiclohexan; amoniac.
B. axetanehit; ancol etylic; buta-1,3-ien.
C. vinylaxetilen; buta-1,3-ien; stiren.
D. vinylaxetilen; buta-1,3-ien; acrilonitrin.
906. (H A 12) Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo
ng t l mol):
(a) X + 2NaOH X1 + X2 + H2O
(b) X1 + H2SO4 X3 + Na2SO4
(c) nX3 + nX4 nilon-6,6 + 2nH2O
(d) 2X2 + X3 X5 + 2H2O
Phn t khi ca X5 l
A. 174.
B. 216.
C. 202.
D. 198.
907. (H A 11) Cho s phn ng:
+ HCN
X;
CHCH
trung hp
polime Y;
X
ong trung hp
Z.
X + CH2=CH-CH=CH2

Y v Z ln lt dng ch to vt liu polime no sau y?

A. T nilon-6,6 v cao su cloropren.
B. T nitron v cao su buna-S.
C. T capron v cao su buna.
D. T olon v cao su buna-N.
908. (H A 07) Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung
bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l
A. 3.
B. 6.
C. 5.
D. 4.
909. (H A 08) Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt
on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v
capron nu trn ln lt l
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n tp Ha 12
A. 113 v 152.
B. 121 v 114.
C. 113 v 114.
D. 121 v 152.
910. (H A 08) Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250
kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4
chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%)
A. 224,0.
B. 286,7.
C. 358,4.
D. 448,0.

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HIDROCACBON NO
GIO KHOA
911. (H A 13) Tn thay th (theo IUPAC) ca (CH3)3CCH2CH(CH3)2 l
A. 2,2,4,4-tetrametylbutan.
B. 2,4,4-trimetylpentan.
C. 2,2,4-trimetylpentan.
D. 2,4,4,4-tetrametylbutan.
912. (C 08) Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon
thuc dy ng ng ca
A. ankan.
B. ankin.
C. ankaien.
D. anken.
913. (C 10) S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien
ln lt l:
A. 5; 3; 9.
B. 4; 3; 6.
C. 3; 5; 9.
D. 4; 2; 6.

914.

915.

916.

917.

918.

919.

PHN NG TH HALOGEN
(H A 13) Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi
clo theo t l mol 1 : 1, thu c ba dn xut monoclo l ng phn cu to ca nhau?
A. neopentan.
B. pentan.
C. butan.
D. isopentan.
(C 08) t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol
H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c
duy nht. Tn gi ca X l
A. 2-Metylbutan.
B. etan.
C. 2,2-imetylpropan.
D. 2-Metylpropan.
(H B 07) Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht
c t khi hi i vi hiro l 75,5. Tn ca ankan l
A. 3,3-imetylhecxan.
B. isopentan.
C. 2,2,3-trimetylpentan.
D. 2,2-imetylpropan.
(C 07) Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng
83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu
c 2 dn xut monoclo ng phn ca nhau. Tn ca X l
A. 2-metylpropan.
B. 2,3-imetylbutan.
C. butan.
D. 3-metylpentan.
(H B 08) Hirocacbon mch h X trong phn t ch cha lin kt v c hai
nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6
th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l
s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3.
B. 2.
C. 5.
D. 4.
PHN NG CHY
(C 10) t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY
> MX), thu c 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l
A. C2H4.
B. CH4.
C. C2H6.
D. C2H2.

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n tp Ha 12
920. (C 12) t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy
ng ng, thu c 2,24 lt kh CO2 (ktc) v 3,24 gam H2O. Hai hirocacbon trong
X l
A. C2H6 v C3H8.
B. CH4 v C2H6.
C. C2H2 v C3H4.
D. C2H4 v C3H6.
921. (H B 12) t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c
cng thc n gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht
trong X l
A. mt ankan v mt ankin.
B. hai ankaien.
C. hai anken.
D. mt anken v mt ankin.
922. (C 07) t chy hon ton mt th tch kh thin nhin gm metan, etan, propan
bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh
CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t
chy hon ton lng kh thin nhin trn l
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
923. (H A 10) t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm
chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng
c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t
ca X l
A. C3H8.
B. C2H6.
C. C3H4.
D. C3H6.
HIDRO HA CRAKINH
924. (H A 08) Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp
Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2
bng 12. Cng thc phn t ca X l
A. C5H12.
B. C3H8.
C. C6H14.
D. C4H10.
925. (C 12) Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn
hp kh X gm ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th
tch ca butan trong X l
A. 66,67%.
B. 25,00%.
C. 50,00%.
D. 33,33%.
926. (H B 11) Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C 4H10,
C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch
brom (d) th s mol brom ti a phn ng l
A. 0,24 mol.
B. 0,36 mol.
C. 0,60 mol.
D. 0,48 mol.

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927.

928.

929.

930.

931.

932.

933.
934.

935.

936.

937.

938.

939.

940.

941.

n tp Ha 12

HIDROCACBON KHNG NO
GIO KHOA
(H B 11) Trong qu gc chn rt giu hm lng
A. vitamin A.
B. ete ca vitamin A.
C. -caroten.
D. este ca vitamin A.
(H B 13) Hirocacbon no sau y khi phn ng vi dung dch brom thu c 1,2ibrombutan?
A. But-1-en.
B. Butan.
C. Buta-1,3-ien.
D. But-1-in.
(H A 09) Hirocacbon X khng lm mt mu dung dch brom nhit thng.
Tn gi ca X l
A. xiclohexan.
B. xiclopropan.
C. stiren.
D. etilen.
(C 13) Cht no di y khi phn ng vi HCl thu c sn phm chnh l 2clobutan?
A. But-1-en.
B. Buta-1,3-ien.
C. But-2-in.
D. But-1-in.
(H A 08) Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol),
sn phm chnh thu c l
A. 3-metylbuten-2 (hay 3-metylbut-2-en).
B. 3-metylbuten-1 (hay 3-metylbut-1-en).
C. 2-metylbuten-2 (hay 2-metylbut-2-en).
D. 2-metylbuten-3 (hay 2-metylbut-3-en).
(H A 11) Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut
ibrom (ng phn cu to v ng phn hnh hc) thu c l
A. 2.
B. 4.
C. 3.
D. 1.
(C 10) Cht no sau y c ng phn hnh hc?
A. 2-clopropen. B. But-2-en.
C. 1,2-icloetan.
D. But-2-in.
(C 11) Cht no sau y c ng phn hnh hc?
A. CH2=CH-CH=CH2.
B. CH3-CH=C(CH3)2.
C. CH3-CH=CH-CH=CH2.
D. CH2=CH-CH2-CH3.
(H A 08) Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l
A. 4.
B. 1.
C. 2.
D. 3.
(C
09)
Cho
cc
cht:
CH2=CHCH=CH2;
CH3CH2CH=C(CH3)2;
CH3CH=CHCH=CH2; CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn
hnh hc l
A. 4.
B. 1.
C. 2.
D. 3.
(H B 08) Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2
(anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc
brom l
A. 8.
B. 6.
C. 5.
D. 7.
(H B 08) Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z
bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan.
B. ankin.
C. ankaien.
D. anken.
((C 11) Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan
v xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l
A. 6.
B. 4.
C. 5.
D. 3.
(H A 12) Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S
cht trong dy lm mt mu dung dch brom l
A. 5.
B. 4.
C. 2.
D. 3.
(H B 13) Cho dy cht sau: isopren, anilin, anehit axetic, toluen, pentan, axit
metacrylic v stiren. S cht trong dy phn ng c vi nc brom l
A. 6.
B. 4.
C. 7.
D. 5.

THPT Tn Tc

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n tp Ha 12
942. (H A 07) Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch
NH3, l:
A. anehit fomic, axetilen, etilen.
B. axit fomic, vinylaxetilen, propin.
C. anehit axetic, butin-1, etilen.
D. anehit axetic, axetilen, butin-2.
943. (C 13) S ng phn cu to, mch h ng vi cng thc phn t C 4H6 l
A. 2.
B. 5.
C. 4.
D. 3.
944. (H B 11) S ng phn cu to ca C5H10 phn ng c vi dung dch brom l
A. 8.
B. 7.
C. 9.
D. 5.
945. (H B 12) Cho dy chuyn ha sau:
+H
+H O
+H O
CaC2
Y
Z.
X
Pd/PbCO , t
H SO , t
2

Tn gi ca X v Z ln lt l
A. axetilen v ancol etylic.
B. axetilen v etylen glicol.
C. etan v etanal. D. etilen v ancol etylic.
946. (C 13) Trng hp m tn etilen thu c 1 tn polietilen (PE) vi hiu sut phn
ng bng 80%. Gi tr ca m l
A. 1,80.
B. 2,00.
C. 0,80.
D. 1,25.
PHN NG OXI HA KHNG HON TON
947. (C 10) iu kin thch hp: cht X phn ng vi cht Y to ra anehit axetic;
cht X phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l:
A. C2H2, H2O, H2.
B. C2H4, O2, H2O.
C. C2H2, O2, H2O.
D. C2H4, H2O, CO.
948. (H B 07) Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c
cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1
gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l
A. 60%.
B. 50%.
C. 80%.
D. 70%.
949. (C 09) kh hon ton 200 ml dung dch KMnO 4 0,2M to thnh cht rn mu
nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l
A. 1,344.
B. 2,240.
C. 4,480.
D. 2,688.
PHN NG CHY
950. t chy hon ton hirocacbon X bng lng oxi va . Sn phm chy sau khi
dn qua CaCl2 khan th th tch kh gim ch cn mt na. CTPT ca X l:
A. C2H6.
B. C4H6.
C. C2H4.
D. C3H8.
951. (H B 08) t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2
lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p
sut). Cng thc phn t ca X l
A. C2H4.
B. C2H6.
THPT Tn Tc
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n tp Ha 12
C. C3H8.
D. CH4.
952. (H B 10) Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng
11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc).
Cng thc ca ankan v anken ln lt l
A. CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
953. (H A 07) Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t
chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4
c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca
X l
A. C3H8.
B. C3H6.
C. C4H8.
D. C3H4.
954. (H A 12) t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin
thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch
Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch
gim bt 19,912 gam. Cng thc phn t ca X l
A. CH4.
B. C3H4.
C. C4H10.
D. C2H4.
955. (H B 08) Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch
brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li
1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc
phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. C2H6 v C3H6.
B. CH4 v C3H6.
C. CH4 v C2H4.
D. CH4 v C3H4.
956. (H A 07) Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi
lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh
hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l
A. 30.
B. 10.
C. 40.
D. 20.
957. (H A 12) t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy
ng ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p
sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y,
trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt.
Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l
A. 46,43%.
B. 10,88%.
C. 31,58%.
D. 7,89%.
958. (C 08) t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp
hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit
v p sut). T khi ca X so vi kh hiro l
THPT Tn Tc

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n tp Ha 12
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1.
959. (C 08) t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c
s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn
hp M ln lt l
A. 75% v 25%.
B. 20% v 80%.
C. 35% v 65%.
D. 50% v 50%.
960. (C 13) Hn hp kh X gm C2H6, C3H6 v C4H6. T khi ca X so vi H2 bng 24.
t chy hon ton 0,96 gam X trong oxi d ri cho ton b sn phm chy vo 1 lt
dung dch Ba(OH)2 0,05M. Sau khi cc phn ng xy ra hon ton, thu c m gam
kt ta. Gi tr ca m l
A. 9,85.
B. 5,91.
C. 13,79.
D. 7,88.
961. (H A 08) Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi
t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l
A. 16,80 gam.
B. 20,40 gam.
C. 18,96 gam.
D. 18,60 gam.
PHN NG CNG HIDRO
962. (H B 13) Trong cc cht: stiren, axit acrylic, axit axetic, vinylaxetilen v butan, s
cht c kh nng tham gia phn ng cng hiro (xc tc Ni, un nng) l
A. 4.
B. 2.
C. 5.
D. 3.
963. (H B 10) C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol
ch bng phn ng cng H2 (xc tc Ni, to)?
A. 3.
B. 5.
C. 2.
D. 4.
964. (H A 12) Hiro ha hon ton hirocacbon mch h X thu c isopentan. S
cng thc cu to c th c ca X l
A. 6.
B. 7.
C. 4.
D. 5.
965. (C 09) Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn
phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. 2-metylpropen, cis-but-2-en v xiclobutan.
D. xiclobutan, 2-metylbut-2-en v but-1-en.
966. (C 13) Cho cc cht: but-1-en, but-1-in, buta-1,3-ien, vinylaxetilen, isobutilen,
anlen. C bao nhiu cht trong s cc cht trn khi phn ng hon ton vi kh H 2 d
(xc tc Ni, un nng) to ra butan?
A. 6.
B. 5.
C. 4.
D. 3.
967. (H A 12) Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung
nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro
ho l
A. 70%.
B. 80%.
C. 60%.
THPT Tn Tc
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n tp Ha 12
D. 50%.
968. (C 09) Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni
nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng
hiro ho l
A. 25%.
B. 20%.
C. 50%.
D. 40%.
969. (H B 12) Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp
X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn
hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon ton, khi lng
brom tham gia phn ng l
A. 0 gam.
B. 24 gam.
C. 8 gam.
D. 16 gam.
970. (C 09) Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi
gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho
ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng.
Gi tr ca m l
A. 16,0.
B. 32,0.
C. 3,2.
D. 8,0.
971. (H A 13) Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni.
Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 8.
Sc X vo lng d dung dch AgNO3 trong NH3 n phn ng hon ton, thu c
hn hp kh Y v 24 gam kt ta. Hn hp kh Y phn ng va vi bao nhiu mol
Br2 trong dung dch?
A. 0,20 mol.
B. 0,10 mol.
C. 0,25 mol.
D. 0,15 mol.
972. (H A 08) un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni,
sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh
ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi
O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,04 gam.
B. 1,64 gam.
C. 1,20 gam.
D. 1,32 gam.
973. (H A 10) un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt
bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom
(d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn
hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l
A. 0,585.
B. 0,620.
C. 0,205.
D. 0,328.
974. (C 07) Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt
niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong
dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi
THPT Tn Tc

122

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n tp Ha 12
16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 (
ktc) v 4,5 gam nc. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
975. (C 10) Cho 3,12 gam ankin X phn ng vi 0,1 mol H 2 (xc tc Pd/PbCO3, to), thu
c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l
A. C2H2.
B. C4H6.
C. C5H8.
D. C3H4.
976. (H A 11) Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho
qua cht xc tc nung nng, thu c hn hp Y gm C 2H4, C2H6, C2H2 v H2. Sc Y
vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt
hn hp kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon
ton hn hp Y l
A. 26,88 lt.
B. 44,8 lt.
C. 33,6 lt.
D. 22,4 lt.
977. (H B 09) Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn
phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni,
sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu
nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l
A. CH2=C(CH3)2.
B. CH2=CH2.
C. CH2=CH-CH2-CH3.
D. CH3-CH=CH-CH3.
978. (H A 13) Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt
X (ktc) vo bnh kn c sn mt t bt Ni. un nng bnh mt thi gian, thu c hn
hp kh Y c t khi so vi H2 bng 10. Tng s mol H2 phn ng l
A. 0,070 mol.
B. 0,050 mol.
C. 0,015 mol.
D. 0,075 mol.
979. (C 13) Cho 27,2 gam ankin X tc dng vi 15,68 lt kh H 2 (ktc) c xc tc thch
hp, thu c hn hp Y (khng cha H2). Bit Y phn ng ti a vi dung dch cha
16 gam Br2. Cng thc phn t ca X l
A. C4H6.
B. C3H4.
C. C2H2.
D. C5H8.
PHN NG CNG H2O, HX, X2.
980. (H A 10) Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A. 3-etylpent-3-en.
B. 2-etylpent-2-en.
C. 3-etylpent-2-en.
D. 3-etylpent-1-en.
981. (H B 12) Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu
c sn phm chnh l
A. 2-metylbutan-2-ol.
B. 3-metylbutan-2-ol.
C. 3-metylbutan-1-ol.
D. 2-metylbutan-3-ol.
982. (H A 07) Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
THPT Tn Tc
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n tp Ha 12
A. eten v but-2-en (hoc buten-2).
B. 2-metylpropen v but-1-en (hoc buten-1).
C. propen v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
983. (C 07) Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c
H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon
ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch
NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng
thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k)
A. C2H5OH v C3H7OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C4H9OH.
D. C4H9OH v C5H11OH.
984. (H B 10) Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi
ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng.
Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v
hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d
dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1ol trong X l
A. 65,2%.
B. 16,3%.
C. 48,9%.
D. 83,7%.
985. (H A 12) Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un
nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch
AgNO3 trong NH3 thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen
l
A. 60%.
B. 80%.
C. 92%.
D. 70%.
986. (H B 09) Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 :
1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr
th thu c hai sn phm hu c khc nhau. Tn gi ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
987. (H A 07) Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua
bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i
mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2
hirocacbon l
A. C3H4 v C4H8.
B. C2H2 v C3H8.
C. C2H2 v C4H8.
D. C2H2 v C4H6.
988. (H A 07) Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm
c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l
A. C4H8.
B. C3H6.
C. C3H4.
D. C2H4.
THPT Tn Tc

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n tp Ha 12

PHNG PHP TRUNG BNH

989. (H B 11) Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi
H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy
vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m
l
A. 7,3.
B. 6,6.
C. 3,39.
D. 5,85.
990. (H A 08) Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi
t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l
A. 16,80 gam.
B. 20,40 gam.
C. 18,96 gam.
D. 18,60 gam.
991. (H A 09) Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon
trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol,
cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,2 mol C2H4 v 0,1 mol C2H2.
C. 0,1 mol C3H6 v 0,2 mol C3H4.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
PHN NG TH ION KIM LOI
992. (H B 13) Cho 3,36 lt kh hirocacbon X (ktc) phn ng hon ton vi lng d
dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Cng thc phn t ca X l
A. C4H4.
B. C3H4.
C. C4H6.
D. C2H2.
993. (H A 11) Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt
lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu
ng phn cu to tha mn tnh cht trn?
A. 2.
B. 5.
C. 6.
D. 4.
994. (H A 11) t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht
bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc
dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c
ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l:
A. CHC-CH3, CH2=CH-CCH.
B. CHC-CH3, CH2=C=C=CH2.
C. CH2=C=CH2, CH2=CH-CCH.
D. CH2=C=CH2, CH2=C=C=CH2.
995. (H B 09) Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi
dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho
13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO 3 trong NH3,
thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l
A. 20%.
B. 50%.
C. 25%.
D. 40%.
THPT Tn Tc
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n tp Ha 12
HIDROCACBON THM

(H B 11) Cho phn ng:

C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O.
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn
ng trn l
A. 27.
B. 24.
C. 34.
D. 31.
997. (H A 11) Cho dy chuyn ho sau:
996.

+ C 2 H4
+ Br2 , as
KOH/C 2 H5OH
X

Y
Benzen
Z (trong X, Y, Z l sn phm
1:1
to
xt,t o

chnh).

998.

Tn gi ca Y, Z ln lt l
A. 1-brom-1-phenyletan v stiren.
B. benzylbromua v toluen.
C. 1-brom-2-phenyletan v stiren.
D. 2-brom-1-phenylbenzen v stiren.
(H B 10) Cho s phn ng:
+ Br2
+ CuO
+ H2O
Y
Z.
Stiren
X
to
H+
H+ , t o
Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l:
A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br.
B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH.
C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH.
D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3.

THPT Tn Tc

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DN XUT HALOGEN ANCOL PHENOL

999. (C 10) Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c
xp theo chiu tng dn t tri sang phi l:
A. anlyl clorua, propyl clorua, phenyl clorua.
B. anlyl clorua, phenyl clorua, propyl clorua.
C. phenyl clorua, propyl clorua, anlyl clorua.
D. phenyl clorua, anlyl clorua, propyl clorua.
+

KCN
H3O , t
X
1000. (C 11) Cho s chuyn ha: CH3CH2Cl
Y. Trong s trn,
X v Y ln lt l
A. CH3CH2CN v CH3CH2COOH.
B. CH3CH2CN v CH3CH2CHO.
C. CH3CH2CN v CH3CH2OH.
D. CH3CH2NH2 v CH3CH2COOH.
+

H3 O
+ KCN
Y. Cng thc cu to
X
1001. (H A 12) Cho s chuyn ha: CH3Cl
to

ca X, Y ln lt l:
A. CH3NH2, CH3COONH4.
C. CH3NH2, CH3COOH.
CH3COOH.

B. CH3CN, CH3CHO.
D. CH3CN,
+

H3O
+ KCN
Y. Cng thc cu
X
1002. (H A 09) Cho s chuyn ha: CH3CH2Cl
to

to ca X, Y ln lt l:
A. CH3CH2NH2, CH3CH2COOH.
C. CH3CH2CN, CH3CH2CHO.
1003. (H B 08) Cho cc phn ng:
o

B. CH3CH2CN, CH3CH2COOH.
D. CH3CH2CN, CH3CH2COONH4.

t
HBr + C2H5OH
;

C2H4 + Br2 ;

C2H4 + HBr ;

askt
C2H6 + Br2
.
(1:1)

S phn ng to ra C2H5Br l
A. 4.
B. 3.
C. 2.
D. 1.
1004. (H B 10) Pht biu no sau y ng?
A. Khi un C2H5Br vi dung dch KOH ch thu c etilen.
B. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng.
C. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi.
D. un ancol etylic 140oC (xc tc H2SO4 c) thu c imetyl ete.
1005. (H A 13) Trng hp no sau y khng xy ra phn ng?
t

(a) CH2=CHCH2Cl + H2O

;
o

(b) CH3CH2CH2Cl + H2O ;

t cao
; (vi C6H5 l gc phenyl)
(c) C6H5Cl + NaOH (c)
p cao
o

(d) C2H5Cl + NaOH

o

A. (b).
B. (a).
C. (d).
D. (c).
1006. (H B 13) un si dung dch gm cht X v KOH c trong C2H5OH, thu c
etilen. Cng thc ca X l
A. CH3COOH.
B. CH3CHCl2.
C. CH3CH2Cl.
D. CH3COOCH=CH2.
1007. (H B 13) Cht no sau y trong phn t ch c lin kt n?
A. Metyl fomat.
B. Axit axetic.
C. Anehit axetic.
D. Ancol etylic.
1008. (H A 13) ng vi cng thc phn t C4H10O c bao nhiu ancol l ng phn cu
to ca nhau?
A. 4.
B. 3.
C. 2.
D. 5.
1009. (C 12) S ancol bc I l ng phn cu to ca nhau c cng thc phn t C5H12O
l
A. 8.
B. 1.
C. 4.
D. 3.
THPT Tn Tc

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n tp Ha 12
1010. (C 11) S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc
dng vi CuO un nng sinh ra xeton l
A. 2.
B. 3.
C. 5.
D. 4.
1011. (C 11) un si hn hp gm propyl bromua, kali hiroxit v etanol thu c sn
phm hu c l
A. propan-2-ol.
B. propin.
C. propen.
D. propan.
1012. (H B 07) Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol,
phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc
dng c vi dung dch NaOH l
A. 3.
B. 5.
C. 6.
D. 4.
1013. (H B 07) Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca
benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime,
khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t
C8H10O, tho mn tnh cht trn l
A. 2.
B. 4.
C. 3.
D. 1.
1014. (C 07) Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2CH2-CH2OH (Y); HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOHCH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh
lam l
A. X, Y, R, T.
B. X, Z, T.
C. Z, R, T.
D. X, Y, Z, T.
1015. (H A 08) Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang
phi l:
A. C2H6, CH3CHO, C2H5OH, CH3COOH.
B. CH3COOH, C2H6, CH3CHO, C2H5OH.
C. CH3CHO, C2H5OH, C2H6, CH3COOH.
D. C2H6, C2H5OH, CH3CHO, CH3COOH.
1016. (H B 08) Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete
v axit fomic. S cht tc dng c vi Cu(OH)2 l
A. 3.
B. 2.
C. 4.
D. 1.
1017. (C 09) Dy gm cc cht u tc dng vi ancol etylic l:
A. HBr (to), Na, CuO (to), CH3COOH (xc tc).
B. NaOH, K, MgO, HCOOH (xc tc).
C. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH.
D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O.
1018. (H B 09) Cho cc hp cht sau:
(a) HOCH2-CH2OH.
(b) HOCH2-CH2-CH2OH.
(c) HOCH2-CH(OH)-CH2OH.
(d) CH3-CH(OH)-CH2OH.
(e) CH3-CH2OH.
(f) CH3-O-CH2CH3.
Cc cht u tc dng c vi Na, Cu(OH)2 l:
A. (a), (b), (c).
B. (c), (d), (f).
C. (a), (c), (d).
D. (c), (d), (e).
1019. (H B 09) Cho s chuyn ho:
+ Mg, ete khan
H2SO4ac
+ HBr
Z .
Y
X (anken)
Butan-2-ol
to
Trong X, Y, Z l sn phm chnh. Cng thc ca Z l
A. (CH3)3C-MgBr.
B. CH3-CH2-CH2 -CH2-MgBr.
C. CH3-CH(MgBr)-CH2-CH3.
D. (CH3)2CH-CH2-MgBr.
1020. (H A 10) Cho s chuyn ho:
dd Br2
O2 , xt
NaOH
CH3 OH, t , xt
CuO, t
X
Y
T
C3H6
Z
E (Este a chc).
o

Tn gi ca Y l
A. propan-1,2-iol.
C. glixerol.
THPT Tn Tc

B. propan-1,3-iol.
D. propan-2-ol.
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n tp Ha 12
1021. (H A 12) Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H2SO4
c thu c anken Y. Phn t khi ca Y l
A. 42.
B. 70.
C. 28.
D. 56.
1022. (C 07) C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu
to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%?
A. 2.
B. 3.
C. 4.
D. 5.
1023. (H A 08) Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt
qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn
ru (ancol) ng vi cng thc phn t ca X l
A. 2.
B. 4.
C. 1.
D. 3.
TC DNG KL KIM
1024. (H A 07) Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy
ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l
A. C3H5OH v C4H7OH.
B. C3H7OH v C4H9OH.
C. CH3OH v C2H5OH.
D. C2H5OH v C3H7OH.
1025. (C 10) Cho 10 ml dung dch ancol etylic 46o phn ng ht vi kim loi Na (d), thu
c V lt kh H2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8
g/ml. Gi tr ca V l
A. 4,256.
B. 2,128.
C. 3,360.
D. 0,896.
1026. (C 10) Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c
cht hu c X. Tn gi ca X l
A. metyl vinyl xeton.
B. propanal.
C. metyl phenyl xeton.
D. imetyl xeton.
1027. (C 08) Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu
c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to
ca X l
A. CH3-CHOH-CH3.
B. CH3-CH2-CHOH-CH3.
C. CH3-CO-CH3.
D. CH3-CH2-CH2-OH.
1028. (H B 07) Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d),
nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32
gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l
A. 0,92.
B. 0,32.
C. 0,64.
D. 0,46.
1029. (C 12) Cho m gam hn hp hi X gm hai ancol (n chc, bc I, l ng ng k
tip) phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi
THPT Tn Tc

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n tp Ha 12
ca Y so vi kh hiro bng 14,5. Cho ton b Y phn ng hon ton vi lng d
dung dch AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l
A. 14,0.
B. 10,1.
C. 18,9.
D. 14,7.
1030. (H A 08) Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau
trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z
v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi
mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam
Ag. Gi tr ca m l
A. 7,8.
B. 7,4.
C. 9,2.
D. 8,8.
1031. (H B 08) Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu
c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng
vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu
sut ca phn ng oxi ho CH3OH l
A. 70,4%.
B. 65,5%.
C. 76,6%.
D. 80,0%.
1032. (C 10) Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu
c 6,2 gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn
hp X phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng, thu
c m gam Ag. Gi tr ca m l
A. 16,2.
B. 21,6.
C. 10,8.
D. 43,2.
1033. (H A 10) Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va
4,8 gam CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch
AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol l:
A. CH3OH, C2H5CH2OH.
B. CH3OH, C2H5OH.
C. C2H5OH, C3H7CH2OH.
D. C2H5OH, C2H5CH2OH.
1034. (H B 09) Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy
ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO
nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt
lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l
A. 15,3.
B. 13,5.
C. 8,1.
D. 8,5.
1035. (H B 12) Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit
cacboxylic, mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn
bng nhau. Phn mt cho tc dng ht vi Na d, thu c 0,504 lt kh H2 (ktc).
Phn hai cho phn ng trng bc hon ton thu c 9,72 gam Ag. Phn trm khi
lng ancol b oxi ho l
A. 50,00%.
THPT Tn Tc

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n tp Ha 12
B. 62,50%.
C. 31,25%.
D. 40,00%.
1036. (H B 13) Tin hnh ln men gim 460 ml ancol etylic 8o vi hiu sut bng 30%.
Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml v ca nc bng 1
g/ml. Nng phn trm ca axit axetic trong dung dch thu c l
A. 2,51%.
B. 2,47%.
C. 3,76%.
D. 7,99%.
1037. (C 13) Oxi ha m gam ancol n chc X, thu c hn hp Y gm axit cacboxylic,
nc v ancol d. Chia Y lm hai phn bng nhau. Phn mt phn ng hon ton vi
dung dch KHCO3 d, thu c 2,24 lt kh CO2 (ktc). Phn hai phn ng vi Na va
, thu c 3,36 lt kh H2 (ktc) v 19 gam cht rn khan. Tn ca X l
A. metanol.
B. etanol.
C. propan-2-ol.
D. propan-1-ol.
1038. (C 09) Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic,
nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO 3 (d), thu c
0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l
A. 2,30 gam.
B. 4,60 gam.
C. 5,75 gam.
D. 1,15 gam.
1039. (H B 10) Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi
ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng.
Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v
hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d
dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1ol trong X l
A. 65,2%.
B. 16,3%.
C. 48,9%.
D. 83,7%.
PHN NG CHY
1040. (C 12) t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn
va V1 lt kh O2, thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin
tiu chun. Biu thc lin h gia cc gi tr V1,V2, a l
A. V1 = 2V2 + 11,2a.
B. V1 = V2 22,4a.
C. V1 = V2 + 22,4a.
D. V1 = 2V2 11,2a.
1041. (H A 09) Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h
thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
V
A. m 2a
.
22, 4
V
B. m 2a
.
11, 2
V
C. m a
.
5, 6
THPT Tn Tc

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n tp Ha 12

V
.
5, 6
1042. (H A 10) t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy
ng ng, thu c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 5,42.
B. 5,72.
C. 4,72.
D. 7,42.
1043. (C 13) t chy hon ton 1 mol ancol no, mch h X cn va 3,5 mol O 2.
Cng thc phn t ca X l
A. C3H8O3.
B. C2H6O2.
C. C2H6O.
D. C3H8O2.
1044. (H A 12) t chy hon ton mt lng ancol X to ra 0,4 mol CO2 v 0,5 mol H2O.
X tc dng vi Cu(OH)2 to dung dch mu xanh lam. Oxi ha X bng CuO to hp
cht hu c a chc Y. Nhn xt no sau y ng vi X?
A. Trong X c 3 nhm -CH3.
B. Hirat ha but-2-en thu c X.
C. Trong X c 2 nhm -OH lin kt vi hai nguyn t cacbon bc hai.
D. X lm mt mu nc brom.
1045. (C 08) t chy hon ton mt ru (ancol) a chc, mch h X, thu c H2O v
CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l
A. C2H6O2.
B. C2H6O.
C. C3H8O2.
D. C4H10O2.
1046. C 07) t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol
tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh
CO2 thu c ( cng iu kin). Cng thc phn t ca X l
A. C3H8O3.
B. C3H4O.
C. C3H8O2.
D. C3H8O.
1047. (H A 09) Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng
ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l
3 : 4. Hai ancol l
A. C3H5(OH)3 v C4H7(OH)3.
B. C2H5OH v C4H9OH.
C. C2H4(OH)2 v C4H8(OH)2.
D. C2H4(OH)2 v C3H6(OH)2.
1048. (C 13) t chy hon ton mt lng ancol X cn va 8,96 lt kh O 2 (ktc), thu
c 6,72 lt kh CO2 (ktc) v 7,2 gam H2O. Bit X c kh nng phn ng vi
Cu(OH)2. Tn ca X l
A. propan-1,3-iol.
B. propan-1,2-iol.
C. glixerol.
D. etylen glicol.
1049. (C 08) t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng
k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol

D. m a

THPT Tn Tc

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n tp Ha 12
hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t
ca X, Y l:
A. C2H6O2, C3H8O2.
B. C2H6O, CH4O.
C. C3H6O, C4H8O.
D. C2H6O, C3H8O.
1050. (H A 09) t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt
kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH) 2 th
to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l
A. 9,8 v propan-1,2-iol.
B. 4,9 v propan-1,2-iol.
C. 4,9 v propan-1,3-iol.
D. 4,9 v glixerol.
1051. (H B 07) X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn
5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l
A. C3H5(OH)3.
B. C3H6(OH)2.
C. C2H4(OH)2.
D. C3H7OH.
1052. (C 12) t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy
ng ng, thu c 15,68 lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin
phn ng este ha m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu
sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a l
A. 25,79.
B. 15,48.
C. 24,80.
D. 14,88.
1053. (C 11) t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng
ng thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng
hn hp X nh trn vi H2SO4 c nhit thch hp chuyn ht thnh ete th
tng khi lng ete thu c l
A. 6,45 gam.
B. 5,46 gam.
C. 4,20 gam.
D. 7,40 gam.
1054. (H A 13) t chy hon ton hn hp X gm 0,07 mol mt ancol a chc v 0,03
mol mt ancol khng no, c mt lin kt i, mch h, thu c 0,23 mol kh CO2 v
m gam H2O. Gi tr ca m l
A. 2,70.
B. 2,34.
C. 8,40.
D. 5,40.
1055. (H A 13) Hn hp X gm ancol metylic, ancol etylic v glixerol. t chy hon ton
m gam X, thu c 15,68 lt kh CO2 (ktc) v 18 gam H2O. Mt khc, 80 gam X ha
tan c ti a 29,4 gam Cu(OH)2. Phn trm khi lng ca ancol etylic trong X l
A. 23%.
B. 16%.
C. 8%.
D. 46%.
1056. (H B 13) Hn hp X gm ancol metylic, etylen glicol. Cho m gam X phn ng hon
ton vi Na d, thu c 2,24 lt kh H2 (ktc). t chy hon ton m gam X, thu
c a gam CO2. Gi tr ca a l
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A. 2,2.
B. 4,4.
C. 8,8.
D. 6,6.
1057. (H B 12) Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon
ton m gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi
Na d thu c ti a V lt kh H2 (ktc). Gi tr ca V l
A. 3,36.
B. 11,20.
C. 5,60.
D. 6,72.
1058. (H B 12) t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt
kh CO2 (ktc) v 15,3 gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu
c 4,48 lt kh H2 (ktc). Gi tr ca m l
A. 12,9.
B. 15,3.
C. 12,3.
D. 16,9.
1059. (H B 10) t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc,
mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v
12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l
A. 14,56.
B. 15,68.
C. 11,20.
D. 4,48.
TCH NC
1060. (H B 13) Tn gi ca anken (sn phm chnh) thu c khi un nng ancol c
cng thc (CH3)2CHCH(OH)CH3 vi dung dch H2SO4 c l
A. 3-metylbut-2-en.
B. 2-metylbut-1-en.
C. 2-metylbut-2-en.
D. 3-metylbut-1-en.
1061. (H A 07) Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba
anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu
gn ca X l
A. CH3CH(CH3)CH2OH.
B. CH3CH(OH)CH2CH3.
C. (CH3)3COH.
D. CH3OCH2CH2CH3.
1062. (C 08) Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4
c, 140oC) th s ete thu c ti a l
A. 4.
B. 2.
C. 1.
D. 3.
1063. (C 13) Hn hp X gm hai ancol n chc, ng ng k tip. un nng 16,6 gam
X vi H2SO4 c 140C, thu c 13,9 gam hn hp ete (khng c sn phm hu
c no khc). Bit cc phn ng xy ra hon ton. Cng thc ca hai ancol trong X l
A. C3H5OH v C4H7OH.
B. CH3OH v C2H5OH.
C. C3H7OH v C4H9OH.
D. C2H5OH v C3H7OH.

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1064. (H A 09) un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c
hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu
c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l
A. C2H5OH v CH2=CH-CH2-OH.
B. C2H5OH v CH3OH.
C. CH3OH v C3H7OH.
D. CH3OH v CH2=CH-CH2-OH.
1065. (C 07) Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt
anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v
5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X?
A. 5.
B. 4.
C. 3.
D. 2.
1066. (H B 08) un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau
trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu
c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru
trn l
A. CH3OH v C2H5OH.
B. C3H7OH v C4H9OH.
C. C3H5OH v C4H7OH.
D. C2H5OH v C3H7OH.
1067. (H B 08) un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong
iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l
1,6428. Cng thc phn t ca X l
A. C4H8O.
B. CH4O.
C. C2H6O.
D. C3H8O.
1068. (H A 10) Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t
chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng
nc sinh ra t ancol kia. Ancol Y l
A. CH3-CH2-CH(OH)-CH3.
B. CH3-CH2-CH2-OH.
C. CH3-CH2-CH2-CH2-OH.
D. CH3-CH(OH)-CH3.
1069. (H B 10) t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc
cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc,
nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l
A. 7,85 gam.
B. 7,40 gam.
C. 6,50 gam.
D. 5,60 gam.
1070. (H B 11) Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh
hn ca Y) l ng ng k tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
- un nng phn 2 vi H2SO4 c 140oC to thnh 1,25 gam hn hp ba ete. Ho
hi hon ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam
N2 (trong cng iu kin nhit , p sut).
Hiu sut phn ng to ete ca X, Y ln lt l
A. 25% v 35%.
B. 20% v 40%.
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D. 30% v 30%.

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PHENOL
GIO KHOA
1071. (H A 13) Phenol phn ng c vi dung dch no sau y?
A. NaCl.
B. HCl.
C. NaHCO3.
D. KOH.
1072. (C 13) Dung dch phenol (C6H5OH) khng phn ng c vi cht no sau y?
A. NaOH.
B. NaCl.
C. Br2.
D. Na.
1073. (C 07) Trong cng nghip, axeton c iu ch t
A. xiclopropan. B. propan-1-ol.
C. propan-2-ol.
D. cumen.
1074. (H B 08) nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin
qua phn ng gia phenol vi
A. Na kim loi.
B. H2 (Ni, nung nng). C. dung dch NaOH.
D. nc Br2.
1075. (C 08) Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol.
S cht trong dy phn ng c vi NaOH (trong dung dch) l
A. 3.
B. 2.
C. 1.
D. 4.
1076. (H A 09) Hp cht hu c X tc dng c vi dung dch NaOH v dung dch
brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l
A. anilin.
B. phenol.
C. axit acrylic.
D. metyl axetat.
1077. (H B 07) S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u
tc dng c vi dung dch NaOH l
A. 2.
B. 3.
C. 1.
D. 4.
1078. (C 13) S ng phn cha vng benzen, c cng thc phn t C 7H8O, phn ng
c vi Na l
A. 3.
B. 5.
C. 4.
D. 2.
1079. (H B 12) C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O?
A. 3.
B. 5.
C. 6.
D. 4.
1080. (C 11) S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O,
trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi
NaOH l
A. 7.
B. 6.
C. 4.
D. 5.
1081. (H A 12) Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH).
S cht trong dy c kh nng lm mt mu nc brom l
A. 5.
B. 4.
C. 3.
D. 2.
1082. (H B 13) Cho cc pht biu sau:
(a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH.
(b) Phn ng th brom vo vng benzen ca phenol (C6H5OH) d hn ca benzen.
(c) Oxi ha khng hon ton etilen l phng php hin i sn xut anehit
axetic.
(d) Phenol (C6H5OH) tan t trong etanol.
Trong cc pht biu trn, s pht biu ng l
A. 4.
B. 2.
C. 3.
D. 1.
1083. (H A 10) Trong s cc pht biu sau v phenol (C6H5OH):
(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl.
(2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia phn ng th brom v th nitro d hn benzen.
Cc pht biu ng l:
A. (1), (2), (4).
B. (2), (3), (4).
C. (1), (2), (3).
D. (1), (3), (4).
1084. (H A 12) Cho cc pht biu sau v phenol (C6H5OH):
(a) Phenol tan nhiu trong nc lnh.
(b) Phenol c tnh axit nhng dung dch phenol trong nc khng lm i mu qu
tm.
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(c) Phenol c dng sn xut phm nhum, cht dit nm mc.
(d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong
benzen.
(e) Cho nc brom vo dung dch phenol thy xut hin kt ta.
S pht biu ng l
A. 4.
B. 2.
C. 5.
D. 3.
1085. (H B 07) Dy gm cc cht u phn ng vi phenol l:
A. dung dch NaCl, dung dch NaOH, kim loi Na.
B. nc brom, axit axetic, dung dch NaOH.
C. nc brom, anhirit axetic, dung dch NaOH.
D. nc brom, anehit axetic, dung dch NaOH.
1086. (H A 07) Pht biu khng ng l:
A. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc
dng vi dung dch NaOH li thu c natri phenolat.
B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung
dch HCl li thu c phenol.
C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung
dch NaOH li thu c anilin.
D. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra
cho tc dng vi kh CO2 li thu c axit axetic.
1087. (C 07) Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S
cp cht tc dng c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
1088. (C 07) Hp cht hu c X (phn t c vng benzen) c cng thc phn t l
C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d,
s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi
NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l
A. C6H5CH(OH)2.
B. HOC6H4CH2OH.
C. CH3C6H3(OH)2.
D. CH3OC6H4OH
+X
+ NaOH d
Y (hp
1089. (H A 09) Cho dy chuyn ho sau: Phenol
Phenyl axetat
to
cht thm). Hai cht X, Y trong s trn ln lt l:
A. axit axetic, phenol.
B. anhirit axetic, phenol.
C. anhirit axetic, natri phenolat.
D. axit axetic, natri phenolat.
1090. (H B 12) Cho phenol (C6H5OH) ln lt tc dng vi (CH3CO)2O v cc dung dch:
NaOH, HCl, Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l
A. 3.
B. 4.
C. 2.
D. 1.
1091. (H B 11) Ha tan cht X vo nc thu c dung dch trong sut, ri thm tip
dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln
lt l:
A. phenol, natri hiroxit, natri phenolat.
B. phenylamoni clorua, axit clohiric, anilin.
C. anilin, axit clohiric, phenylamoni clorua.
D. natri phenolat, axit clohiric, phenol.
1092. (H B 07) Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu
c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng
thc cu to thu gn ca X l
A. HOCH2C6H4COOH.
B. C2H5C6H4OH.
C. HOC6H4CH2OH.
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D. C6H4(OH)2.
1093. (H B 09) Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch
NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu
c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l
A. HO-C6H4-COOCH3.
B. CH3-C6H3(OH)2.
C. HO-CH2-C6H4-OH.
D. HO-C6H4-COOH.
1094. (H B 10) Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit
cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO 2, CO,
N2 v H2. Gi tr ca x l
A. 0,60.
B. 0,36.
C. 0,54.
D. 0,45.
1095. (H B 10) Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi4-metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l:
A. (1), (3), (5), (6).
B. (1), (2), (4), (6).
C. (1), (2), (4), (5).
D. (1), (4), (5), (6).
1096. (C 10) Pht biu ng l:
A. Vinyl axetat phn ng vi dung dch NaOH sinh ra ancol etylic.
B. Thu phn benzyl clorua thu c phenol.
C. Phenol phn ng c vi nc brom.
D. Phenol phn ng c vi dung dch NaHCO3.
1097. (C 09) Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T).
Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l:
A. (Y), (T), (Z), (X).
B. (X), (Z), (T), (Y).
C. (T), (Y), (X), (Z).
D. (Y), (T), (X), (Z).
BI TP
1098. (C 12) Cho dung dch cha m gam hn hp gm phenol (C6H5OH) v axit axetic
tc dng va vi nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6tribromphenol. Trung ha hon ton X cn va 500 ml dung dch NaOH 1M. Gi tr
ca m l
A. 33,4.
B. 21,4.
C. 24,8.
D. 39,4.
1099. (C 11) Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri
(d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X
cn 100 ml dung dch NaOH 1M. Gi tr ca m l
A. 7,0.
B. 21,0.
C. 14,0.
D. 10,5.
1100. (H A 12) Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5,
p-HO-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong
dy tha mn ng thi 2 iu kin sau?
(a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng.
A. 3.
B. 4.
C. 1.
D. 2.
1101. (H A 11) Hp cht hu c X cha vng benzen c cng thc phn t trng vi
cng thc n gin nht. Trong X, t l khi lng cc nguyn t l m C : mH : mO = 21 :
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2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol
ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh
cht trn?
A. 10.
B. 7.
C. 9.
D. 3.
1102. (H A 10) Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu
phn trong dung dch H2SO4 long. thu c 145 gam axeton th lng cumen
cn dng (gi s hiu sut qu trnh iu ch t 75%) l
A. 300 gam.
B. 600 gam.
C. 500 gam.
D. 400 gam.

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ANEHIT XETON
GIO KHOA
1103. (H A 08) S ng phn xeton ng vi cng thc phn t C5H10O l
A. 6.
B. 3.
C. 5.
D. 4.
1104. (H A 07) Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn
ng c vi (CH3)2CO l
A. 2.
B. 1.
C. 4.
D. 3.
1105. (H A 09) Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra
anehit axetic l:
A. CH3COOH, C2H2, C2H4.
B. C2H5OH, C2H4, C2H2.
C. C2H5OH, C2H2, CH3COOC2H5.
D. HCOOC2H3, C2H2, CH3COOH.
1106. (C 09) Qu trnh no sau y khng to ra anehit axetic?
A. CH3CH2OH + CuO (to).
B. CH2=CH2 + H2O (to, xc tc HgSO4).
o
C. CH2=CH2 + O2 (t , xc tc).
D. CH3COOCH=CH2 + dung dch NaOH
(to).
1107. (C 10) Anehit no mch h X c cng thc n gin nht C 2H3O. Cng thc phn
t ca X l
A. C4H6O2.
B. C8H12O4.
C. C2H3O.
D. C6H9O3.
1108. (H B 08) Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c
cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng
ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt
CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH.
B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
C. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.
D. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH.
1109. (H A 11) X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O.
X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi
Na nhng c phn ng trng bc. Z khng tc dng c vi Na v khng c phn
ng trng bc. Cc cht X, Y, Z ln lt l:
A. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH.
B. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3.
C. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH.
D. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO.
1110. (H A 11) Pht biu no sau y v anehit v xeton l sai?
A. Anehit fomic tc dng vi H2O to thnh sn phm khng bn.
B. Axeton khng phn ng c vi nc brom.
C. Axetanehit phn ng c vi nc brom.
D. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn.
1111. (H B 11) Cho cc pht biu sau:
(a) Anehit va c tnh oxi ho va c tnh kh.
(b) Phenol tham gia phn ng th brom kh hn benzen.
(c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt.
(d) Dung dch axit axetic tc dng c vi Cu(OH)2.
(e) Dung dch phenol trong nc lm qu tm ho .
(g) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng l
A. 4.
B. 2.
C. 5.
D. 3.
T CHY

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1112. (H B 07) t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c
mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2
electron. X thuc dy ng ng anehit
A. no, hai chc.
B. no, n chc.
C. khng no c hai ni i, n chc.
D. khng no c mt ni i, n chc.
1113. (H A 11) t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi
nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt
lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l
A. anehit axetic.
B. anehit fomic.
C. anehit no, mch h, hai chc.
D. anehit khng no, mch h, hai chc.
1114. (H B 07) Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit
tng ng. Cng thc ca anehit l
A. C2H3CHO.
B. CH3CHO.
C. HCHO.
D. C2H5CHO.
1115. (H B 09) t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v
0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi
un nng. Cht X l
A. O=CH-CH=O.
B. CH2=CH-CH2-OH.
C. CH3COCH3.
D. C2H5CHO.
1116. (H B 09) t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht
X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br 2 theo t l
mol 1 : 1. Cng thc cu to ca X l
A. HO-CH2-CH2-CH=CH-CHO.
B. HOOC-CH=CH-COOH.
C. HO-CH2-CH=CH-CHO.
D. HO-CH2-CH2-CH2-CHO.
1117. (H B 10) Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon
Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu
c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l
A. CH4.
B. C2H2.
C. C3H6.
D. C2H4.
1118. (H B 12) t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn
va 110 ml kh O2, thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung
dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc th tch kh v hi o cng iu
kin. Cng thc phn t ca X l
A. C4H8O2.
B. C4H10O.
C. C3H8O.
D. C4H8O.
1119. (H B 11) Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon).
t chy hon ton x mol hn hp M, thu c 3x mol CO 2 v 1,8x mol H2O. Phn
trm s mol ca anehit trong hn hp M l
THPT Tn Tc

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n tp Ha 12
A. 30%.
B. 40%.
C. 50%.
D. 20%.
1120. (C 13) Hn hp X gm hai anehit no, n chc, mch h (t l s mol 3 : 1). t
chy hon ton mt lng X cn va 1,75 mol kh O 2, thu c 33,6 lt kh CO2
(ktc). Cng thc ca hai anehit trong X l
A. HCHO v CH3CHO.
B. CH3CHO v C2H5CHO.
C. HCHO v C2H5CHO.
D. CH3CHO v C3H7CHO.
TRNG GNG
1121. (C 13) Cho 4,4 gam anehit n chc X phn ng hon ton vi lng d dung
dch AgNO3 trong NH3, un nng, thu c 21,6 gam Ag. Cng thc ca X l
A. C2H3CHO.
B. HCHO.
C. CH3CHO.
D. C2H5CHO.
1122. (C 09) Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip
nhau trong dy ng ng tc dng vi lng d dung dch AgNO 3 trong NH3, un
nng thu c 32,4 gam Ag. Hai anehit trong X l
A. HCHO v C2H5CHO.
B. CH3CHO v C2H5CHO.
C. C2H3CHO v C3H5CHO.
D. HCHO v CH3CHO.
1123. (H A 07) Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d
AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng
ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc).
Cng thc cu to thu gn ca X l
A. CH3CHO.
B. HCHO.
C. CH3CH2CHO.
D. CH2 = CHCHO.
1124. (H A 07) Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong
dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol
Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l
A. CH3CHO.
B. OHC-CHO.
C. HCHO.
D. CH3CH(OH)CHO.
1125. (C 07) Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc
Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca
anehit l
A. HCHO.
B. CH2=CH-CHO.
C. OHC-CHO.
D. CH3CHO.
1126. (H A 08) Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d
Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ha tan
hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh
duy nht, ktc). Cng thc ca X l
A. C2H5CHO.
THPT Tn Tc
143

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n tp Ha 12
B. C4H9CHO.
C. C3H7CHO.
D. HCHO.
1127. (H A 13) Khi lng Ag thu c khi cho 0,1 mol CH3CHO phn ng hon ton vi
lng d dung dch AgNO3 trong NH3, un nng l
A. 21,6 gam.
B. 43,2 gam.
C. 16,2 gam.
D. 10,8 gam.
1128. (H A 10) Cho m gam hn hp etanal v propanal phn ng hon ton vi lng
d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5
gam mui amoni ca hai axit hu c. Gi tr ca m l
A. 9,5.
B. 10,9.
C. 14,3.
D. 10,2.
1129. (C 10) Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X phn ng c
vi kim loi Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi
Na v ha tan c CaCO3. Cng thc ca X, Y ln lt l:
A. CH3COOH, HOCH2CHO.
B. HCOOCH3, HOCH2CHO.
C. HCOOCH3, CH3COOH.
D. HOCH2CHO, CH3COOH.
1130. (C 08) t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O.
Nu cho X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s
mol Ag gp bn ln s mol X phn ng. Cng thc ca X l
A. HCHO.
B. CH3CHO.
C. (CHO)2.
D. C2H5CHO.
1131. (H B 11) Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh
hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO 3 trong NH3,
sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E
tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l
A. anehit acrylic.
B. anehit butiric.
C. anehit propionic.
D. anehit axetic.
1132. (H A 13) Cho 13,6 gam mt cht hu c X (c thnh phn nguyn t C, H, O) tc
dng va vi dung dch cha 0,6 mol AgNO3 trong NH3, un nng, thu c 43,2
gam Ag. Cng thc cu to ca X l
A. CH2=C=CHCHO.
B. CH3CCCHO.
C. CHCCH2CHO.
D. CHC[CH2]2CHO.
1133. (C 08) Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d
Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra
hon ton, khi lng Ag to thnh l
A. 43,2 gam.
B. 10,8 gam.
C. 64,8 gam.
D. 21,6 gam.
THPT Tn Tc
144

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n tp Ha 12
1134. (C 13) Cho hn hp gm 0,05 mol HCHO v 0,02 mol HCOOH vo lng d dung
dch AgNO3 trong NH3, un nng. Sau khi cc phn ng xy ra hon ton, thu c m
gam Ag. Gi tr ca m l
A. 15,12.
B. 21,60.
C. 25,92.
D. 30,24.
1135. (H B 11) hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi
lng 1,64 gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng
vi mt lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc
cu to ca hai anehit trong X l
A. CH2=C(CH3)-CHO v OHC-CHO.
B. OHC-CH2-CHO v OHC-CHO.
C. H-CHO v OHC-CH2-CHO.
D. CH2=CH-CHO v OHC-CH2-CHO.
1136. (H A 09) Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch
AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc
tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi
cng thc chung l
A. CnH2n(CHO)2 (n 0).
B. CnH2n+1CHO (n 0).
C. CnH2n-1CHO (n 2).
D. CnH2n-3CHO (n 2).
1137. (H B 12) Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch
AgNO3 trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn
va 0,5 mol H2. Dy ng ng ca X c cng thc chung l
A. CnH2n(CHO)2 (n 0).
B. CnH2n-3CHO (n 2).
C. CnH2n+1CHO (n 0).
D. CnH2n-1CHO (n 2).
1138. (H B 09) Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v
c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v
43,24%. Cng thc cu to ca X v Y tng ng l
A. HO-CH2-CHO v HO-CH2-CH2-CHO.
B. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO.
C. HO-CH(CH3)-CHO v HOOC-CH2-CHO.
D. HCOOCH3 v HCOOCH2-CH3.
1139. (C 11) Hn hp G gm hai anehit X v Y, trong MX < MY < 1,6MX. t chy hn
hp G thu c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung
dch AgNO3 trong NH3 thu c 0,25 mol Ag. Tng s cc nguyn t trong mt phn
t Y l
A. 6.
B. 9.
C. 10.
D. 7.
1140. (H B 13) Hai cht hu c X v Y, thnh phn nguyn t u gm C, H, O, c cng
s nguyn t cacbon (MX < MY). Khi t chy hon ton mi cht trong oxi d u thu
c s mol H2O bng s mol CO2. Cho 0,1 mol hn hp gm X v Y phn ng hon
ton vi lng d dung dch AgNO3 trong NH3, thu c 28,08 gam Ag. Phn trm
khi lng ca X trong hn hp ban u l
A. 39,66%.
B. 60,34%.
THPT Tn Tc

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C. 21,84%.
D. 78,16%.

n tp Ha 12

CNG H2
1141. (H A 10) Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn
thay th l
A. 2-metylbutan-3-on.
B. metyl isopropyl xeton.
C. 3-metylbutan-2-ol.
D. 3-metylbutan-2-on.
1142. (C 10) ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi
tc dng vi kh H2 (xc tc Ni, to) sinh ra ancol?
A. 3.
B. 4.
C. 2.
D. 1.
1143. (C 08) Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3),
CH2=CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng
to ra mt sn phm l:
A. (2), (3), (4).
B. (1), (2), (4).
C. (1), (2), (3).
D. (1), (3), (4).
1144. (H A 08) un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn
ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch
kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc
dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit
A. khng no (cha mt ni i C=C), hai chc.
B. no, n chc.
C. no, hai chc.
D. khng no (cha mt ni i C=C), n chc.
1145. (H B 09) Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc,
mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol.
Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O 2 (
ktc). Gi tr ca m l
A. 17,8.
B. 24,8.
C. 10,5.
D. 8,8.
1146. (C 09) Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc,
mch h, k tip nhau trong dy ng ng (M X < MY), thu c hn hp hai ancol c
khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam
CO2. Cng thc v phn trm khi lng ca X ln lt l
A. CH3CHO v 67,16%.
B. HCHO v 32,44%.
C. CH3CHO v 49,44%.
D. HCHO v 50,56%.
1147. (H B 11) X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h,
phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2
mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b
cc ancol trong Y ri cho tc dng vi Na (d), c V lt H 2 (ktc). Gi tr ln nht
ca V l
A. 22,4.
B. 13,44.
C. 5,6.
D. 11,2.
1148. (H A 09) Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung
nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu
c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm
theo th tch ca H2 trong X l
A. 46,15%.
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n tp Ha 12
B. 35,00%.
C. 53,85%.
D. 65,00%.
1149. (H A 10) Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu
phn trong dung dch H2SO4 long. thu c 145 gam axeton th lng cumen
cn dng (gi s hiu sut qu trnh iu ch t 75%) l
A. 300 gam.
B. 600 gam.
C. 500 gam.
D. 400 gam.

THPT Tn Tc

147

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n tp Ha 12

AXIT CACBOXYLIC
GIO KHOA
1150. (H B 08) Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy
cng thc phn t ca X l
A. C6H8O6.
B. C9H12O9.
C. C3H4O3.
D. C12H16O12.
1151. (C 12) Cht no sau y va tc dng c vi dung dch NaOH, va tc dng
c vi nc Br2?
A. CH3CH2COOH.
B. CH3COOCH3.
C. CH2=CHCOOH.
D. CH3CH2CH2OH.
1152. (H A 13) Dung dch axit axetic phn ng c vi tt c cc cht trong dy no
sau y?
A. NaOH, Cu, NaCl.
B. Na, NaCl, CuO.
C. NaOH, Na, CaCO3.
D. Na, CuO, HCl.
1153. (C 11) Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. HCOOH, CH3COOH, CH3CH2COOH.
B. CH3COOH, CH2ClCOOH, CHCl2COOH.
C. CH3COOH, HCOOH, (CH3)2CHCOOH.
D. C6H5OH, CH3COOH, CH3CH2OH.
1154. (C 12) Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao
nht trong dy l
A. axit etanoic.
B. etanol.
C. etanal.
D. etan.
1155. (H B 07) Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v
imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l
A. T, Z, Y, X.
B. T, X, Y, Z.
C. Z, T, Y, X.
D. Y, T, X, Z.
1156. (H B 09) Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri
sang phi l:
A. CH3COOH, C2H5OH, HCOOH, CH3CHO.
B. CH3CHO, C2H5OH, HCOOH, CH3COOH.
C. CH3COOH, HCOOH, C2H5OH, CH3CHO.
D. HCOOH, CH3COOH, C2H5OH, CH3CHO.
1157. (H B 12) Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng
thc phn t C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin
trn l
A. 3.
B. 2.
C. 4.
D. 1.
CaO, t
1158. (H B 12) Cho phng trnh ha hc: 2X + 2NaOH
2CH4 + K2CO3 +
Na2CO3 . Cht X l
A. CH2(COOK)2. B. CH2(COONa)2. C. CH3COOK.
D. CH3COONa.
o

+ Z (xt, t )
+ M (xt, t )
+ X (xt, t )
1159. (C 11) Cho s phn ng: CH4
T
CH3COOH
Y
(X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng). Cht T
trong s trn l
A. C2H5OH.
B. CH3CHO.
C. CH3OH.
D. CH3COONa.
1160. (H B 13) Cho s phn ng: C2H2 X CH3COOH. Trong s trn mi mi
tn l mt phn ng, X l cht no sau y?
A. CH3COONa. B. HCOOCH3.
C. CH3CHO.
D. C2H5OH.
1161. (H B 11) Cho s phn ng:
+ HCN
+ H2O
X1
(1) CH3CHO
X2
H+ , t o
o

+ CO2
+ HCl
+ Mg
Y2
Y1
Y3.
(2) C2H5Br
ete

Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l
A. axit 2-hiroxipropanoic v axit propanoic.
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n tp Ha 12
B. axit 3-hiroxipropanoic v ancol propylic.
C. axit axetic v axit propanoic.
D. axit axetic v ancol propylic.
1162. (H A 07) Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai
dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t
CH3COOH th c 1 phn t in li)
A. y = x + 2.
B. y = x - 2.
C. y = 2x.
D. y = 100x.
1163. (H B 07) Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t
C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l
A. 4.
B. 5.
C. 3.
D. 2.
1164. (H B 09) Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton
vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l
A. etylen glicol.
B. axit aipic.
C. ancol o-hiroxibenzylic.
D. axit 3-hiroxipropanoic.
1165. (C 09) Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit
axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH.
C. C2H4(OH)2, CH3OH, CH3CHO.
D. CH3OH, C2H5OH, CH3CHO.
1166. (C 09) Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y
u tc dng vi Na; X tc dng c vi NaHCO 3 cn Y c kh nng tham gia phn
ng trng bc. Cng thc cu to ca X v Y ln lt l
A. HCOOC2H5 v HOCH2COCH3.
B. C2H5COOH v HCOOC2H5.
C. C2H5COOH v CH3CH(OH)CHO.
D. HCOOC2H5 v HOCH2CH2CHO.
1167. (H B 10) Dy gm cc cht u tc dng vi H2 (xc tc Ni, to), to ra sn phm c
kh nng phn ng vi Na l:
A. C2H3CH2OH, CH3COCH3, C2H3COOH.
B. C2H3CHO, CH3COOC2H3, C6H5COOH.
C. C2H3CH2OH, CH3CHO, CH3COOH.
D. CH3OC2H5, CH3CHO, C2H3COOH.
T CHY AXIT
1168. (C 11) Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm
chc. t chy hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn
gi ca X l
A. axit axetic.
B. axit malonic.
C. axit oxalic.
D. axit fomic.
1169. (H B 12) Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol
X cn 0,24 mol O2, thu c CO2 v 0,2 mol H2O. Cng thc hai axit l
A. HCOOH v C2H5COOH.
B. CH2=CHCOOH v CH2=C(CH3)COOH.
C. CH3COOH v C2H5COOH.
D. CH3COOH v CH2=CHCOOH.
1170. (H B 07) t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt
O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96.
B. 11,2.
C. 6,72.
THPT Tn Tc

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n tp Ha 12
D. 4,48.
1171. (H A 09) Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t
chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO 2 ( ktc). Nu trung ha
0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l:
A. HCOOH, HOOC-COOH.
B. HCOOH, HOOC-CH2-COOH.
C. HCOOH, C2H5COOH.
D. HCOOH, CH3COOH.
1172. (H A 10) Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u
mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca
Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2
(ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn
ng este ho (hiu sut l 80%) th s gam este thu c l
A. 22,80.
B. 34,20.
C. 27,36.
D. 18,24.
1173. (H A 11) t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol
H2O (vi z = y x). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn
ca E l
A. axit oxalic.
B. axit fomic.
C. axit aipic.
D. axit acrylic.
1174. (H A 11) t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc,
mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO 2 (ktc)
v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l
A. V

28
(x 62y)
95

B. V 28 (x 62y)

95
C. V 28 (x 30y)
55
D. V 28 (x 30y)
55

1175. (H B 07) Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h

v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong
bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong
bnh lc ny l 0,95 atm. X c cng thc phn t l
A. C4H8O2.
B. C3H6O2.
C. CH2O2.
D. C2H4O2.
1176. (H A 11) Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc
dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon
ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr
ca y l
A. 0,8.
B. 0,2.
C. 0,3.
D. 0,6.
THPT Tn Tc

150

Vng Quc Vit

n tp Ha 12
1177. (H A 11) Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no
a chc Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca
5,6 gam N2 (o trong cng iu kin nhit , p sut). Nu t chy ton b hn hp
hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc cu to ca X, Y ln lt l
A. H-COOH v HOOC-COOH.
B. CH3-CH2-COOH v HOOC-COOH.
C. CH3-COOH v HOOC-CH2-CH2-COOH.
D. CH3-COOH v HOOC-CH2 -COOH.
1178. (H A 13) Bit X l axit cacboxylic n chc, Y l ancol no, c hai cht u mch
h, c cng s nguyn t cacbon. t chy hon ton 0,4 mol hn hp gm X v Y
(trong s mol ca X ln hn s mol ca Y) cn va 30,24 lt kh O2, thu c
26,88 lt kh CO2 v 19,8 gam H2O. Bit th tch cc kh o iu kin tiu chun.
Khi lng ca Y trong 0,4 mol hn hp trn l
A. 11,4 gam.
B. 19,0 gam.
C. 9,0 gam.
D. 17,7 gam.
1179. (H A 13) Cho X v Y l hai axit cacboxylic mch h, c cng s nguyn t cacbon,
trong X n chc, Y hai chc. Chia hn hp gm X v Y thnh hai phn bng
nhau. Phn mt tc dng ht vi Na, thu c 4,48 lt kh H2 (ktc). t chy hon
ton phn hai, thu c 13,44 lt kh CO2 (ktc). Phn trm khi lng ca Y trong
hn hp l
A. 42,86%.
B. 57,14%.
C. 85,71%.
D. 28,57%.
1180. (H B 13) Hn hp X gm hai axit cacboxylic n chc, mch h, k tip nhau trong
cng dy ng ng. t chy hon ton 4,02 gam X, thu c 2,34 gam H2O. Mt
khc 10,05 gam X phn ng va vi dung dch NaOH, thu c 12,8 gam mui.
Cng thc ca hai axit l
A. CH3COOH v C2H5COOH.
B. C2H5COOH v C3H7COOH.
C. C3H5COOH v C4H7COOH.
D. C2H3COOH v C3H5COOH.
1181. (H B 13) Hn hp X gm hiro, propen, axit acrylic, ancol anlylic (C3H5OH). t
chy hon ton 0,75 mol X, thu c 30,24 lt kh CO2 (ktc). un nng X vi bt Ni
mt thi gian, thu c hn hp Y. T khi hi ca Y so vi X bng 1,25. Cho 0,1 mol
Y phn ng va vi V lt dung dch Br2 0,1M. Gi tr ca V l
A. 0,3.
B. 0,6.
C. 0,4.
D. 0,5.
1182. (H B 13) Axit cacboxylic X hai chc (c phn trm khi lng ca oxi nh hn
70%), Y v Z l hai ancol ng ng k tip (MY < MZ). t chy hon ton 0,2 mol
hn hp gm X, Y, Z cn va 8,96 lt kh O2 (ktc), thu c 7,84 lt kh CO2 (ktc)
v 8,1 gam H2O. Phn trm khi lng ca Y trong hn hp trn l
A. 15,9%.
B. 29,9%.
C. 29,6%.
D. 12,6%.
1183. (H B 13) Hn hp X gm mt axit cacboxylic no, n chc, mch h v mt ancol
n chc, mch h. t chy hon ton 21,7 gam X, thu c 20,16 lt kh CO2
THPT Tn Tc

151

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n tp Ha 12
(ktc) v 18,9 gam H2O. Thc hin phn ng este ha X vi hiu sut 60%, thu c
m gam este. Gi tr ca m l
A. 9,18.
B. 15,30.
C. 12,24.
D. 10,80.
1184. (H A 12) t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n
chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc
nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam
hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l
A. 8,16.
B. 4,08.
C. 2,04.
D. 6,12.
1185. (H A 12) Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt
axit no, a chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi
bng th tch ca 2,8 gam N2 (o trong cng iu kin nhit , p sut). t chy
hon ton 8,64 gam hn hp hai axit trn thu c 11,44 gam CO2. Phn trm khi
lng ca X trong hn hp ban u l
A. 72,22%.
B. 27,78%.
C. 35,25%.
D. 65,15%.
1186. (C 10) t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH3,
CH3OH thu c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X
phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng
thc ca CxHyCOOH l
A. C3H5COOH.
B. CH3COOH.
C. C2H3COOH.
D. C2H5COOH.
TNH CHT AXIT
1187. (H A 07) t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc,
trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l
A. HOOC-COOH.
B. HOOC-CH2-CH2-COOH.
C. CH3-COOH.
D. C2H5-COOH.
1188. (C 13) Hn hp X gm hai axit cacboxylic n chc, ng ng k tip. Cho 5,4
gam X phn ng hon ton vi dung dch NaHCO 3 d, thu c 2,24 lt kh CO2
(ktc). Cng thc ca hai axit trong X l
A. C3H7COOH v C4H9COOH.
B. CH3COOH v C2H5COOH.
C. C2H5COOH v C3H7COOH.
D. HCOOH v CH3COOH.
1189. (H B 07) trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng
200 gam dung dch NaOH 2,24%. Cng thc ca Y l
A. C2H5COOH.
B. CH3COOH.
C. C3H7COOH.
D. HCOOH.
THPT Tn Tc

152

Vng Quc Vit

n tp Ha 12
1190. (C 07) Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3
thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l
A. CH2=CH-COOH.
B. CH3COOH.
C. HC C-COOH.
D. CH3-CH2-COOH.
1191. (C 07) un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n
khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn
ng este ho l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
1192. (H A 08) Trung ha 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn
dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn
hp cht rn khan c khi lng l
A. 8,64 gam.
B. 4,90 gam.
C. 6,80 gam.
D. 6,84 gam.
1193. (H B 08) Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500
ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam
hn hp cht rn khan. Cng thc phn t ca X l
A. CH3COOH.
B. HCOOH.
C. C3H7COOH.
D. C2H5COOH.
1194. (H B 09) Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s
nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi
Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam
CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X
ln lt l
A. HOOC-CH2-COOH v 70,87%.
B. HOOC-CH2-COOH v 54,88%.
C. HOOC-COOH v 60,00%.
D. HOOC-COOH v 42,86%.
1195. (H A 11) Trung ha 3,88 gam hn hp X gm hai axit cacboxylic no, n chc,
mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2
gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l
A. 3,36 lt.
B. 4,48 lt.
C. 1,12 lt.
D. 2,24 lt.
1196. (C 11) Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX < MY < 82).
C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi
dung dch KHCO3 sinh ra kh CO2. T khi hi ca Y so vi X c gi tr l
A. 1,47.
B. 1,91.
C. 1,57.
D. 1,61.
1197. (H A 12) Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m
gam X phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy
THPT Tn Tc
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n tp Ha 12
hon ton m gam X cn 2,016 lt O2 (ktc), thu c 4,84 gam CO2 v a gam H2O.
Gi tr ca a l
A. 1,62.
B. 1,44.
C. 3,60.
D. 1,80.
1198. (H B 12) un nng m gam hn hp X gm cc cht c cng mt loi nhm chc
vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit
cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi
Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung nng cht rn thu
c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht
kh. Gi tr ca m l
A. 40,60.
B. 22,60.
C. 34,30.
D. 34,51.
1199. (H B 11) Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca
Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H 2O.
Mt khc, nu cho a mol X tc dng vi lng d dung dch NaHCO3, th thu c
1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l
A. 46,67%.
B. 40,00%.
C. 25,41%.
D. 74,59%.
1200. (H B 09) Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v
CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc,
trung ha 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca
CH2=CH-COOH trong X l
A. 0,56 gam.
B. 1,44 gam.
C. 0,72 gam.
D. 2,88 gam.
1201. (C 09) Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic,
nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO 3 (d), thu c
0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l
A. 2,30 gam.
B. 4,60 gam.
C. 5,75 gam.
D. 1,15 gam.
1202. (C 09) Trung ha 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100
ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d
dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn gi ca X l
A. axit propanoic.
B. axit metacrylic.
C. axit etanoic.
D. axit acrylic.
1203. (H A 10) Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca
axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l
A. axit propanoic.
B. axit etanoic.
C. axit metanoic.
D. axit butanoic.
THPT Tn Tc

154

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n tp Ha 12
1204. (H A 10) Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k
tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H 2
(ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn
hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng
este ho t hiu sut 100%). Hai axit trong hn hp X l
A. C3H7COOH v C4H9COOH.
B. CH3COOH v C2H5COOH.
C. C2H5COOH v C3H7COOH.
D. HCOOH v CH3COOH.
1205. (H B 10) Hn hp Z gm hai axit cacboxylic n chc X v Y (M X > MY) c tng
khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung
dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch
AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X
trong Z l
A. C3H5COOH v 54,88%.
B. C2H3COOH v 43,90%.
C. C2H5COOH v 56,10%.
D. HCOOH v 45,12%.
1206. (H B 10) Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp
hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va
vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng
thc ca X v Y l
A. HCOOH v CH3OH.
B. CH3COOH v CH3OH.
C. HCOOH v C3H7OH.
D. CH3COOH v C2H5OH.
1207. (C 10) Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau
phn ng hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch
Y. C cn dung dch Y, thu c 31,1 gam hn hp cht rn khan. Cng thc ca 2
axit trong X l
A. C2H4O2 v C3H4O2.
B. C2H4O2 v C3H6O2.
C. C3H4O2 v C4H6O2.
D. C3H6O2 v C4H8O2.
1208. (C 10) Axit cacboxylic X c cng thc n gin nht l C 3H5O2. Khi cho 100 ml
dung dch axit X nng 0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V
ml kh CO2 (ktc). Gi tr ca V l
A. 448.
B. 224.
C. 112.
D. 336.
1209. (H A 11) Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu
c axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin).
phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH
1M. Gi tr ca V l
A. 0,72.
B. 0,48.
C. 0,24.
D. 0,96.
1210. (H A 13) Hn hp X cha ba axit cacboxylic u n chc, mch h, gm mt axit
no v hai axit khng no u c mt lin kt i (C=C). Cho m gam X tc dng va
vi 150 ml dung dch NaOH 2M, thu c 25,56 gam hn hp mui. t chy hon
THPT Tn Tc

155

Vng Quc Vit

n tp Ha 12
ton m gam X, hp th ton b sn phm chy bng dung dch NaOH d, khi lng
dung dch tng thm 40,08 gam. Tng khi lng ca hai axit cacboxylic khng no
trong m gam X l
A. 15,36 gam.
B. 9,96 gam.
C. 12,06 gam.
D. 18,96 gam.

THPT Tn Tc

156