Scribd Logo
Upload

Welcome to Scribd!

  • Developing the Redlich-Kister equation for activity coefficients

    Uploaded by

    MartinGarcíadeSánchez
    4 views7 pages
    The document develops an equation for Ve using the Redlich-Kister equation. Values for A, B, and C are substituted into the equation. The equation is then derived with respect to X1 to determine how ∆V changes with X1. ∆V1 and ∆V2 are calculated for values of X1 from 0 to 1 to show how the chemical potential changes on either side of the phase boundary.

    Original Description:

    Original Title

    CALCULOS TERMO 2.docx

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document develops an equation for Ve using the Redlich-Kister equation. Values for A, B, and C are substituted into the equation. The equation is then derived with respect to X1 to determine how ∆V changes with X1. ∆V1 and ∆V2 are calculated for values of X1 from 0 to 1 to show how the chemical potential changes on either side of the phase boundary.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    4 views7 pages

    Developing the Redlich-Kister equation for activity coefficients

    Uploaded by

    MartinGarcíadeSánchez
    The document develops an equation for Ve using the Redlich-Kister equation. Values for A, B, and C are substituted into the equation. The equation is then derived with respect to X1 to determine how ∆V changes with X1. ∆V1 and ∆V2 are calculated for values of X1 from 0 to 1 to show how the chemical potential changes on either side of the phase boundary.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 7

    DESARROLLANDO LA ECUACIN

    X 1 X 2 2
    A + B ( X 1 X 2 ) +C
    V e= X 1 X 2

    SUSTITUYENDO VALORES DE A, B, C EN ECUACIN DE REDLICH KISTER

    X 212 X 1 X 2+ X 22
    A +B X 1B X 2 +C
    X1 X2
    X 1 X 2 [ A + B X 1B X 2+ C X 212 CX 1 X 2+C X 22 ]
    A X 1 X 2 +B X 21 X 2B X 1 X 22 +C X 31 X 22C X 21 X 22 +C X 1 X 32
    DONDE

    X 2=1X 1

    SUSTITUYENDO

    X2
    3

    1 X 1
    1 X 1 2+C X 1
    1X 1 2 +C X 31( 1X 1 )2 C X 21
    1X 1 B X 1
    A X 1 (1 X 1)+ B X 21
    MULTIPLICANDO

    12 X 1 + X 21
    A X 1 A X 21 + B X 21B X 31B X 1 ( +C X 31C X 412 C X 21 ( 12 X 1 + X 21 ) +C X 1 ( 13 X 1 +3 X 21 X 31 ) )
    DESARROLLANDO

    A X 1 A X 21 + B X 21B X 31B X 1 +2 B X 21B X 31 +C X 31 C X 412C X 21 +4 C X 312 C X 41+C X 13 C X 21+3 C X 31


    SE SUMAN TERMINOS
    2

    A X 1 A X 1 B X 1 +3 B X 12 B X 1 +C X 15 C X 1 +8 C X 14 C X
    AL AGRUPAR

    X 1 ( AB+C )
    X 21 (A+3 B5 C )
    X 31 (2 B+8 C)

    4
    1

    X 1(4 C)

    ECUACIN FINAL
    2
    3
    4
    Ve= ( AB+C ) X 1+ (A+ 3 B5C ) X 1+ (2 B+8 C ) X 1 +(4 C) X 1

    A= -10.768
    B= 5.8024
    C= 15.54

    X 1=

    (nV )

    Al derivar
    d V
    = ( AB+C )+ 2 (A +3 B5 C ) X 1 +3 (2 B+8 C ) X 2116 C X 31
    d X1

    V 1=V +

    X 2d V
    d X1

    X 1d V
    d X1

    V 2=V

    ( AB+C ) =-1.0304
    2 ( A+3 B5 C )= -99.0496

    3 (2 B+8 C ) = 338.1456
    16 C= 248.64

    V 1=V + ( X 2(1.0304 )+ (99.0496 ) X 1+ (338.1456 ) X 21 248.64 X 31 )

    0
    (1.0304 ) + (99.0496 ) (0)+ ( 338.1456 ) (0)2248.64 ()
    ( 3 ] =1. 0304

    V 1=0+1
    0.1
    (1.0304 ) + (99.0496 ) (0.1)+ ( 338.1456 ) (0.1)2248.64()
    ( 3 ] =7.5139

    V 1=0.4917+0.9

    0.2
    (1.0304 ) + (99.0496 ) (0.2)+ ( 338.1456 ) (0.2)2248.64()
    ( 3 ] =8.8276

    V 1=1.3848+0.8
    0.3
    (1.0304 ) + (99.0496 ) (0.3)+ ( 338.1456 ) (0.3)2248.64 ()
    ( 3 ] =7.1443

    V 1=2.2265+0.7

    0.4
    (1.0304 ) + (99.0496 ) (0.4)+ ( 338.1456 ) (0.4)2248.64()
    ( 3 ] =4.1895

    V 1=2.7136+ 0.6
    0.5
    (1.0304 ) + (99.0496 ) (0.5)+ ( 338.1456 ) (0.5)2248.64 ()
    ( 3 ] =1.2414

    V 1=2.692+0.5

    0.6
    (1.0304 ) + (99.0496 ) (0.6)+ ( 338.1456 ) (0.6)2248.64()
    ( 3 ] =0.8698

    V 1=2.1566+0.4
    0.7
    (1.0304 ) + (99.0496 ) (0.7)+ ( 338.1456 ) (0.7)2 248.64()
    ( 3 ] =1.7611

    V 1=1.2517+ 0.3

    0.8
    (1.0304 ) + (99.0496 ) (0.8)+ ( 338.1456 ) (0.8)2248.64 ()
    ( 3 ] =1.4971

    V 1=0.2707+ 0.2
    0 .9
    (1.0304 ) + (99.0496 ) (0 .9)+ ( 338.1456 ) (0 .9)2248.64()
    ( 3 ] =0.5901

    V 1=0 .3437+ 0.1

    1
    (1.0304 ) + (99.0496 ) (1)+ (338.1456 ) (1)2248.64()
    ( 3 ] =0

    V 1=0+0

    V 2=V ( X 1(1.0304 ) + (99.0496 ) X 1 + ( 338.1456 ) X 21248.64 X 31)


    0
    (1.0304 ) + (99.0496 ) (0)+ ( 338.1456 ) (0)2248.64 ()
    ( 3 ] =0

    V 2=00

    0 .1
    (1.0304 ) + (99.0496 ) (0.1)+ ( 338.1456 ) (0 .1)2 248.64()
    ( 3 ] =0.2885

    V 2=0.49170.1

    0.2
    (1.0304 ) + (99.0496 ) (0.2)+ ( 338.1456 ) (0.2)2248.64()
    ( 3 ] =0.4759

    V 2=1.38480.2
    0.3
    (1.0304 ) + (99.0496 ) (0.3)+ ( 338.1456 ) (0.3)2248.64 ()
    ( 3 ] =0.1188

    V 2=2.22650.3

    0.4
    (1.0304 ) + (99.0496 ) (0.4)+ ( 338.1456 ) (0.4)2248.64()
    ( 3 ] =1.7296

    V 2=2.71360.4
    0.5
    (1.0304 ) + (99.0496 ) (0.5)+ ( 338.1456 ) (0.5)2248.64 ()
    ( 3 ] =4.1426

    V 2=2.6920.5

    0.6
    (1.0304 ) + (99.0496 ) (0.6)+ ( 338.1456 ) (0.6)2248.64()
    ( 3 ] =6.6962

    V 2=2.15660.6
    0.7
    (1.0304 ) + (99.0496 ) (0.7)+ ( 338.1456 ) (0.7)2 248.64()
    ( 3 ] =8.2815

    V 2=1.25170.7

    0.8
    (1.0304 ) + (99.0496 ) (0.8)+ ( 338.1456 ) (0.8)2248.64 ()
    ( 3 ] =7.3422

    V 2=0.27070.8
    0.9
    (1.0304 ) + (99.0496 ) (0.9)+ ( 338.1456 ) (0.9)2248.64 ()
    ( 3 ] =1.8742

    V 2=0.34370.9

    1
    (1.0304 ) + (99.0496 ) (1)+ (338.1456 ) (1)2248.64()
    ( 3 ] =10.5744

    V 2=01

    V 1=V 1 + V 1

    V1

    V1

    V 11=40.7695

    )=

    V2

    V 2=V 2 + V 2 ( V 2 )=V 1=18

    V1

    V2

    -1.0304

    39.7391

    18

    -7.5139

    0.2885

    33.2556

    18.2885

    -8.8276

    0.4759

    31.9419

    18.4759

    -7.1443

    -0.1188

    33.6252

    17.8812

    -4.1895

    -1.7296

    36.58

    16.2704

    -1.2414

    -4.1426

    39.5281

    13.8574

    0.8698

    -6.6962

    41.6393

    11.3038

    1.7611

    -8.2815

    42.5306

    9.7185

    1.4971

    -7.3422

    42.2666

    10.6578

    0.5901

    -1.8742

    41.3596

    16.1258

    10.5744

    40.7695

    28.5744

    You might also like