H2O2 Safety Presentation Ver 7 0-09 PDF

Safetyy and Handling
g of Hydrogen
y g Peroxide
Chemical Products Group

Engineering Services
FMC and Responsible

p
Care
Active Member of the American Chemistry Council (ACC) and the
Canadian Chemical Producers Association (CCPA)
Committed to the principles of Responsible Care. A voluntary
industry program started in 1988.
FMC implementing the Responsible Care Management System
(RCMS) at all sites.
RCMS oversees all
ll Health,
H lth Safety,
S f t Security
S
it & Environmental
E i
t l
Programs with FMC.
Third p
party
y auditing
g of RCMS.
Committed to constant improvement in Health, Safety, Security &
Environmental performance every year.
What is Hydrogen Peroxide?

Chemical formula H2O2
Diversified industrial uses
Water-like appearance and physical
p p
properties
Oxidizer
Chemically active
How Is Hydrogen Peroxide Described?

Hydrogen Peroxide solution is described by
concentration as percent by weight of H2O2 in
water.
Hydrogen Peroxide is shipped as 70%, 50%,
35% or 31% but
35%,
b normally
ll stored
d at 50% or lless.

FMC Hydrogen
y g Peroxide Grades
Specifications
Source
Dilution Water
Current Name
Main Uses
Standard
Waste Treatment
Non-food bleaching
FMC internal
Approved tap water
Stannate + other
< 1000 ppm residue @ 35%
Technical
Chemical synthesis
FMC internal
DI water
Organic tin free

Super D
Hair bleach, topical uses

Specialty laundry bleach
Extra stabilizer for stability
on dilution to 1-6%
U.S. Pharmacopeia
for 3% solution
DI water
Stannate + other
SemiConductor
Routine semiconductor
processing
ACS reagent uses
SEMI specifications
DI water
< 1ppm Sn
< 20ppm residue
Additives

FMC Hydrogen
y g Peroxide Grades
Current Name
Main Uses
Specifications
Source
Dilution Water
Additives
SEG
Critical semiconductor
processing
< 10 ppb each metal

DI water
None
RGS
Most critical semiconductor

work
< 1 ppb each metal

DI water
None
Durox
U.S. CFR approved food uses

More stabilizer,
stabilizer suitable for
use in bath type aseptic
packaging
Food Chemical Codex

DI water
Stannate + other
< 60 ppm residue
Durox LR
U.S. CFR approved food uses

Low residue for spray aseptic
packaging use
Food Chemical Codex

DI water
Stannate + other
< 60 ppm residue
OxyPure
Potable water treatment
NSF approved
Food Chemical Codex
DI water
< 60 ppm residue

Sample Applications for H2O2

Pulp & Paper
--Bleaching of Chemical and Mechanical Pulps
--De-inking
Textiles
--Cottons (Stone-washed effect)
--Bleaching
g
Food Processing
--Bacterial Disinfecting Agent
--Fiber Bleaching
Electronics
--Circuit Board Cleaning & Etching
Environmental Applications
--WWTP Oxygen Source
--Reduced Sulfur, Cyanides, NOxTreatment
--Organic Pollutant Treatment
--Bioremediation
--Heavy Metal Removal
Detergent Manufacture
--Perborates/Percarbonates/Peracids
--Liquid
Li id H2O2 Bleach
Bl h
Chemical Manufacturing
--Organic and Inorganic Peroxides
--Epoxides/Oxides/Specialty
p
/
/ p
y Chemicals
Mining
--Leaching Enhancement for Gold
and Silver Extraction
Cosmetic/Medical
--Bleaching of Hair
--Mouthwash (3%)
--Contact Lens Cleaner
--Disinfectant (3%)
Potable Water Treatment

Thee Four
ou Rules
u es of
o H2O2 Use and
a d Handling
a d g
1. Never CONTAMINATE
2. Never CONFINE
3. Never CONTACT
4. Always Have WATER Available
The Four Rules of H2O2 Use and Handling

g
2. Never CONFINE
3. Never CONTACT
4. Always Have WATER Available.
Types of Contamination
Heat & Energy
Materials of Construction
Externally Introduced Materials

10
Chemical Reaction Caused byy Contamination
H2O2 + Contaminant
Yields
Oxygen + Water + Heat
If a Fuel is Present
FIRE
11
Rate of Deecompositio
on
The Effect of Heat on H202
50
100
Temperature
Temperature (oF)
72
151
218
150
(oF)
200
250
Rate of Decomposition
1% per Year
1% per Week
2% per Day
D

12
Materials of Construction
Storage Tanks
-- #5254 Al
Aluminum
i
(P
(Passivated)
i t d)
(Consult with FMC on Application)
-- SS316L/SS304L (Passivated)
(Standard and Technical Grades only)
Pumps (Passivated)
-- SS316
SS316, B356 Aluminum
-- Mechanical Seals
Pure Ceramic, Silicon Carbide,
Teflon, SS316
-- Polyethylene (linear/Cross-Linked HD)

(Consult with FMC on Application)
Hoses (Passivated)
-- SS316, SS304
Piping (Passivated)
-- SS316, SS316L, SS304, SS304L
-- 1060 Aluminum
Gaskets, Diaphragms,
O-Rings
O
R ngs
Valves (Vented, Passivated)
-- Virgin Teflon, PP363 Vinyl,

Garlock Gylon, Viton A
-- SS316, B356 Aluminum

-- Virgin
Vi i T
Teflon
fl Seats
S
and
dS
Seals
l
13
Reasons for Passivation

Removes surface impurities
Provides a compatible metal oxide
surface for Hydrogen Peroxide contact:
-- Ensuring stability and quality
-- Inhibiting corrosion

14
Partial List of Common Materials to Avoid

Graphite
Gr
phit
Copper
Magnesium Alloys
Brass
Chromium
Lubricating
Lubricating Oil
Bronze
B
Iron/Steel
Lead
Nickel
Monel
Pipe
Pipe Dope
Do Not Use These Materials: They will cause

accelerated decomposition of Hydrogen Peroxide
15
Decomposition of H2O2 by Pure Metals

Low
Decomposition
Aluminum
Al
i
Tantalum
Zirconium
Moderate
Decomposition
Silicon
Sili
Tin
High
Decomposition
Beryllium
B
lli
Cadmium
Chromium
Cobalt
Columbium
Copper
Gold
Iron
Lead
Magnesium
Manganese
Mercury
Molybdenum
Ni k l
Nickel
Platinum
Silver
Sodium
Titanium
Tungsten
Zincc
16
INCREASED STABIL
LITY
Decomposition
p
of H2O2 byy Pure Metals
INCREASED CONTAMINATION
Semi
Food
Technical
Standard
Super D
17
Externally Introduced Materials

Wrong materials delivered into storage
vessel
H2O2 delivered
d li
d iinto wrong tank
k
Process backs up into H2O2 system
Returning unused H2O2 into original
container
Dust, dirt, etc.
18
Indications of Hydrogen Peroxide Decomposition
Pressure build up
-- Activation of pressure relief devices
H2O2 visually active
-- Rapid
R pid b
bubbling
bblin
Temperature increase
Temperature
Gas or steam evolution
19

g
2. Never CONFINE
3. Never CONTACT
20
Reasons for Not Confining Hydrogen Peroxide

Hydrogen
H
d
P
Peroxide
id always
l
d
decomposes, only
l
the rate varies.
A volume ratio of 200:1 of Oxygen liberated to
liquid decomposed is possible.
Pressure build up will occur in a closed system.
Excess pressure build up can result in tank
Excess
or line rupture or failure.
21
Horizontal Tank

22
Vertical Tank

23
Pressure Relief in Pipe Between Closed Valves

24
Two Methods of Venting

g the Ball Cavityy of a Valve

25

g
2. Never CONFINE
3. Never CONTACT
26
Types
yp of Contact
Personal Exposure
Contact with Flammable
or Combustible Materials

27
Proper
p Personal Protection Equipment
q p
Typical/Daily Work Around H2O2 Equipment
Chemical Safety Goggles

Rubber Gloves
Increased Exposure Due to Spillage,

Maintenance or Sampling
All of the Above

Neoprene
p
or Vinyl
y Acid Suit
Neoprene Boots
Full Face Shield
28
Hazards of Improper
p p Protection
Lack of Eye
Protection
Possible Ulceration of the

Cornea
Lack of Protective
Clothing
Possible Burning of Skin
Cotton Clothing
Could Catch on Fire
L h F
Leather
Footwear
C ld C
Could
Catch
h on Fi
Fire

29
Possible Health Hazards Caused

By Exposure To Hydrogen Peroxide
Eyes
-- May cause irreversible tissue damage, including blindness
Skin
-- Causes whitening of the skin or, after prolonged exposure,
redness
d
and
d bli
blistering
i
Inhalation
-- Mayy cause irritation and inflammation in the nose and
throat
Taken Internally
-- Swallowing
S ll i may produce
d
corrosion
i off th
the gastrointestinal
t i t ti l
tract that may be life-threatening
Refer to Material Safety Data Sheet for more Details
30
Chemical Reaction Caused by Contact with a Fuel
H2O2 + Fuel
F l
Yields
Oxygen + Water +
FIRE
Fuel - Any Organic Combustible (ie. Wood, Leather Boots...)

31
2. Never CONFINE
3.
3 Never CONTACT
32
Water Should Always Be Readily Available
W
Water
Dil
Dilutes H
Hydrogen
d
P
Peroxide
id
A Dilute Solution is
Less Hazardous

33
Emergency
g y Response
p
Equipment
q p
When Handling
g H2O2
Safety Showers
Eyewash
y
Water Hose

34
Eyes
First Aid
-- Immediately flush eyes with plenty of water

for at least 15 minutes.
Body
-- Flush skin with water. Remove and wash
contaminated clothing and shoes promptly
and thoroughly.
Internal
-- If swallowed, drink water immediately to dilute.
Do not cause vomiting.
g Call a Physician.
y
35
Fires Involving
g Hydrogen
y g Peroxide
Hydrogen Peroxide is non-flammable
Use water for extinguishing fire
If fire is near storage vessel
p y
-- Cool with external water spray

36
Responding
p
g to Accelerated Decomposition
p
Keep area clear of all personnel

Keep equipment cool with external
water spray
Flush equipment with water

37

g
2. Never CONFINE
3. Never CONTACT
38
General Rules for Maintenance and Repair
Wear proper protective equipment

Relieve pressure on system (shut off H2O2 flow & isolate storage tank)
Introduce and flush water through the piping system
Lock out equipment
Drain Water
Rinse off all parts with Water (i.e. fittings, nuts, bolts, gaskets)
Repair and clean component
Cleanliness during repair is crucial
Repassivate if necessary
N incompatible
No
i
p tibl material
t i l or equipment
q ip
t substitutions
b tit ti
Check operation
Restart
39
Four Ways
y to Maintain Safetyy & Quality
Q
y
Passivation
-- Make sure all components of the Hydrogen Peroxide system are
properly passivated
Inspection
I
i
-- Tanks and delivery system should be inspected once every two years
Sampling
-- Hydrogen Peroxide testing
-- Water quality testing
Maintenance
-- Repair defects immediately
-- Repassivate equipment if needed
40
General Overview
Protect against contamination
Flush
Flush Hydrogen Peroxide spillage with water
Never return Hydrogen Peroxide to its original container
-- Dilute with plenty of water and discard abiding by proper
regulations
Keep Hydrogen Peroxide storage vented at all times
Use clean, passivated equipment only
Keep
Keep combustibles away from Hydrogen Peroxide storage
and handling areas
Drain Hydrogen Peroxide equipment and flush with water
Drain
before repair or disassembly
41

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Safetyy and Handling

Chemical Products Group

FMC and Responsible

What is Hydrogen Peroxide?

How Is Hydrogen Peroxide Described?

Chemical Products Group

Organic tin free

Hair bleach, topical uses

Chemical Products Group

< 10 ppb each metal

Most critical semiconductor

< 1 ppb each metal

U.S. CFR approved food uses

Food Chemical Codex

U.S. CFR approved food uses

Food Chemical Codex

Potable water treatment

< 60 ppm residue

Chemical Products Group

Sample Applications for H2O2

Potable Water Treatment

Chemical Products Group

The Four Rules of H2O2 Use and Handling

Chemical Products Group

Chemical Reaction Caused byy Contamination

The Effect of Heat on H202

Chemical Products Group

-- Polyethylene (linear/Cross-Linked HD)

Valves (Vented, Passivated)

-- Virgin Teflon, PP363 Vinyl,

-- SS316, B356 Aluminum

Reasons for Passivation

Chemical Products Group

Partial List of Common Materials to Avoid

Do Not Use These Materials: They will cause

Decomposition of H2O2 by Pure Metals

Externally Introduced Materials

Indications of Hydrogen Peroxide Decomposition

The Four Rules of H2O2 Use and Handling

Reasons for Not Confining Hydrogen Peroxide

Chemical Products Group

Chemical Products Group

Pressure Relief in Pipe Between Closed Valves

Chemical Products Group

Two Methods of Venting

Chemical Products Group

The Four Rules of H2O2 Use and Handling

Chemical Products Group

Chemical Safety Goggles

Increased Exposure Due to Spillage,

All of the Above

Possible Ulceration of the

Possible Burning of Skin

Could Catch on Fire

Chemical Products Group

Possible Health Hazards Caused

Chemical Reaction Caused by Contact with a Fuel

Fuel - Any Organic Combustible (ie. Wood, Leather Boots...)

The Four Rules of H2O2 Use and Handling

Water Should Always Be Readily Available

Chemical Products Group

Chemical Products Group

-- Immediately flush eyes with plenty of water