Chem 155 First Hour Exam 2001 Version II: Answers provided‘Chem 155 First Hour Exam ‘October 3, 2001 Name:, I be given to correct answers only when all necessary steps are shown. (12) 1. True or false? Just write "T" or “F" after each question. (a) AHis astate function. F (b) P-V work is usually negligible for solids and liquids. T (©) AS =0 for an adiabatic, reversible expansion of an ideal gas. —T (d) Cy is always temperature independent for an ideal gas. F (©) In acyclic process such as 1 + 2 followed by 2 1, we have AG =0. T off = 0 foran ideal gas. “T (12) 2. List the condition(s) under which each of the following equations can be applied. If no conditions are required, write “none.” (@) AH = AU + APV) Nowe &) Piv} = Pav} Theat yes, atiabele , yeversiple- (©) w = -aRTIn ¥ Zheak pes, isolhimesh. , yeortpsi ble. Cp _s d) y= Paz @r=a=3 Fiteal gos, aeonaTemie, © as = 48 Lenstitat presgine., ate. Gritibiitw (D So = 0at0K. Pz pect, per cry sfabline page 1 of 5 pages(4) 3. Circle the only one of the following substances that has a nonzero A¢H® value at 25°C, Cgraphite) On(g) (Ha(s) Hel) Fe(s) (6) 4.A gas iindergoes an irreversible expansion along the path shown below. Calculate the work done in joules. (Hint: Work done is given by area under curve.) Lok doe = -PAV Spl: - (2a (A-WL = - BL ab Steph: zee becanx 2V= 0 Step IL: ~ (sabi) (3-2)L = -3L ah / Titrh wok does ~ 3 Late F-Bx/* TF (8) 5. The intemal energy (U) of one mole of a monatomic ideal gas is (3/2)RT. Calculate AF of the ges in joules when the temperature of the gas is increased from 300 K to 400 K. Holl+epy = BRT + MRT 44~ ZRAT + mRAT g 208 BAT K peak) (0-300) K+ (Uh (EHR TK eet ) * (400-300) = 2.08 */0°T (© 6. List three processes that can increase the entropy of a system. SS CAP AA Sj Miking B gates Cor bape tef solihs } Halig page 2 of S pages(12) 7. In class, we focused mostly on gas expansions. Now consider the reversible, isothermal compression of 0.50 mole of an ideal gas from 2.0 L to 1.0 L at 298 K. (a) Calculate w, q, AU, AH, and AS for the process. (b) Can you still describe the work done in this case as the maximum work done? Explain. (@) AU =0, AH =O fr sa ise erual process ineheng ae ite Gas dn “ART be = (050 rR EHATK past") 098 K) bo BL, = 8b T f=-w= -Bb4/0°7 AS = of br Bo lAS0nt WEMTK yuh) be 2 229. 5K 4 D No. Fhe temp Lene. is the winirn acecint because The ying peu is ak jofvretfesi tts Thaw He. eifeneh, he Pee (10) 8. 16.2 moles of Ar and 20.2 moles of Xe are mixed at constant temperature (298 K) and pressure. What is the fora! entropy of the system after mixing? Assume ideal behavior. Phere Ort foe weer J Aug = ~RC Ny Peg + tx) A es y= gee = OWS whe ede = O55 Sun S2 (BI TK treat fond) bac HS ianel) hess) = 285K! 2. SA) ah SMe) Shel = [208 + Ub 258) + (2246 )] - = 6140S Kt page 3 of 5 pages(16) 9. For each of the following processes, state whether the following quantities listed are positive (+), negative (-), or zero (0). All the changes refer to the system. (a) Melting ethanol. (molar volume of liquid ethanol > molar volume of solid ethanol) (b) Heating a gas at constant volume, (©) Inreversible, adiabatic expansion of an ideal gas. (@) Burning hydrogen in air. { 2H2fA(g) + O2(¢) ——> 2H,0() ] q w AU OH @ -£ = + + (b) + 0 + + O @ - =~ = @ - + = = © 10, Ammonium nitrate (NH4NO3) dissolves spontancously and endothermically in water. Deduce the sign of AS (of the system) for this process. Does your result make sense physically? Explain. AG = AH - TAS AS = S424 T AG ZO (spolecous proccss) AH >O (eed chernic ) “ 25 >0 page 4 of 5 pages(8) 11. The AsG? of CIF(g) is -56.0 kJ mol-}, (a) Calculate the equilibrium constant for the reaction at 298 K: 2CIF(g) Cla(g) + Fa(g) (b) What is AG for the reaction if the partial pressures of Clz, Fa, and CiF are 1.4 atm, 0.90 atm, and 0.35 atm, respectively. Is the reaction more or less favored under these conditions? (4) AG= DAGAE) - WAG (A) - O4GE) = (QL BOR melt) = -HZ AT peek! AG’? = -RT AK Ke AGT « eo CA YI) = 43x" OW I2G= AG» Rr be . = M2110? T mek t+ (BANY2IB La Fars ee AKIO TT nel! ~ BTID? FT tert”! = ARK OTT mk = -/ RA AI nel + Tle jeecleon with be Heert. Sperifitcctores | [have neither given nor received aid on this examination. page 5 of $ pagesChem 155 First Hour Exam October 3, 2001. Useful information R = 8314 K! mol! 1Latm = 101.35 At298 K: ‘S*(Ar) = 154.8) K-! mol-! ‘S°(Ke) = 169.6 JK mot} page 6 of 5 pages