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III.
b)
I.
II.
2.
a)
I. Packing Fraction (f) provide the quantitative measure of the
closeness of packing in a crystal structure and is defined as
f=
II.
i.e.
Where;
Braggs angle,
d= interatomic plane spacing,
n = order of diffraction
b)
4.
5.
a) Ionic bonding: This type of bonding is formed through an
electrostatic attraction between two oppositely charged ions. (Cation,
which is usually a metal, and an anion, which is usually a nonmetal).
Example, reaction of sodium with chlorine (NaCl) and Copper(II)
Chloride (CuCl2).
Ionic compounds dissolve easily in water and other polar solvents.
In solution, ionic compounds easily conduct electricity.
Ionic compounds tend to form crystalline solids with high melting
temperatures.
Ionic compounds are solids, results from the intermolecular forces
(forces between molecules) in ionic solids.
Vander Waals (Inter atomic) bonding: Is the sum of the attractive
or repulsive forces exhibited by solid noble gas crystals and exists
between MOLECULES of the same substance. The outermost electron
shell is completely filled and the electron distribution is spherically
symmetric.
Each
atom
is
neutral
and has no permanent dipole moment. The attractive forces between
the atoms arise from fluctuations in the electron distribution.
Example, London dispersion forces that exist between nonpolar
molecules like chlorine gas and Dipole-Dipole forces that occur in
polar molecules like HCl.
b)
I.
(1)
Where Xn is the equilibrium position of the n th atom so that Xn =
na
Now substituting (1) into
Canceling the common quantities (the amplitude and the timedependent factor) we obtain
Canceling the common factor
II.
6.
a)
The quantum of vibration is called a phonon in analogy with the
photon, which is the quantum of the electromagnetic wave.
Phonons can interact with other particles such as photons, neutrons
and electrons.
Phonon does not carry real physical momentum while Photon had a
momentum hq
A phonon is the collective oscillation of several atoms while a photon
is a packet of energy, which is the base of quantum mechanics.
A phonon is a mode of oscillation that occurs in lattice structures but
photon is a form of energy.
b)
When M1 M2, then M1/ M2 1
A1/A2 0, this gives a normal mode in which the atom with mass M 1
does not oscillate, while the atom with mass M2 oscillate with
frequency given in the equation above.
A1/A2 1 gives normal mode in which the atoms within the same
primitive cell move in phase, and the frequency is determine by the
lager one say M1
I.
II.
7.
a)
I.
II.
III.
b)
III.