2
   

 .

www.ibnalkhatib2.canalblog.com2

 1 3/'4+,-./0)RX$% &'()* (1) !

RX + H 2 O 

ROH + H + + X

 

m.mol.l-1 ; ) 1 < [RX ] 9:20C 6078

 1*( >=6?6/@A
 1BC91CDE07 F7GFHI9J (1
( (*0OH)*( >MN)t1/2 * KL8 )+ (2
t = 0 Q* RJ6* 1STU+( 3
 Z6U:)* KL861U 0);U+W8
X

>X]/ 9)*3 F V(o) = 16 m.mol.l-1.h -1.>*L\50C61[ 38(4

.W^_X`:a) *1S
Xf g R deB(8f2,9 O3C = 5,55.10-3 mol.l-19:AHcCV
[+pH(2) !
 ./AHcCF*R *137I[6U) BW6 H 17U8TU+
X C hO3) 1 <Xmax

( (*0OH)

:2
1):19&)T9J
1 3)T9J  d183S<(2
210
JC 84

A
Z

Po 6  3kl(6

208
80

1H 13()8: )i

206
82

Hg

Hg : 

Pb

214
86

Rn

(1
212
88

Ra

Pb :  Rn : Ra : 
  I )(6

:6isH:  1HKH:o8*:qr :814:13>oEp Al6) n 8(3

1

:1 3/'4%8 : 0

.....
....

Al

.....

+ .... He

.....
1
0

n + ....

  3kt(6 s&137I+

X1):191 3/19JoS8'7O(1.3
 :(Al8(8) 3kl(6 u8B 7 6 (4
10
5

4
2

He

0n +

13
7

N
 : O38

(u):;a6 *9

10
5

4
2

10,010194
1u =1,66054.1027 kg

He

4,001506

c = 3,00.108 m.s-1

13
7

13,001898

1
0

1,008655

1 eV = 1,60218. 1019 J

 . 'U o6 *m:1 _:TU+

X1I19:]4 1q@(1.4
 (eV)(J) ;'U   *1G6 1O _:TU+J(2.4
 .*vR)J ?k8* s&*&

 
 

www.ibnalkhatib2.canalblog.com

1  !
(.1
 ....
[J@,  B, KO 1R/pH :1BC91B41HIJ
 ( y8  )B6X:07:*N)( Dosage en Retour ) % 3/Jk7/3/:1BC91HI;
  (7/y8 *)KL8 )(.2
*)3C 1HO/1CH Q* RJ61U oU: (3
t = 0 s 1y? 6CC M%/

V0 ( RX ) =



[RX ] 100 20
=
= 8 = 8.m.mol.l 1 .h 1
t
0 10

1
8.10 3
.mol.l 1 .s = 2,22.10 6 mol.l 1 .s 1
3600
*3:T1/2*) )g9JT0
HU/)*g9J1CvV0

V0 ( RX ) =

 hqC  B7 9z '3:* 1SJe

 (hqC  B7 9z {6{6:)

 JH8:1%'3:* 1SJ|+q8(4

.* 1Sto]:1%:J 9+*)1%
:* 137I R d:2 !

 
 
  

AH


+
n (AH)

x (mol)

H2O
n (H2O)

A-

n (A-)

H3O+
n (H3O+)

C.V=5,55.10-3mol



 

C.V - X



  

x max

C.V - Xmax



Xmax

Xmax

 !  

xf

C.V - Xf



xf

xf

(mol)



[H O ]

x max=5,55.10-3mol M6) C.V Xmax = 0 6 x max;U+



= 10 pH = 10 2,9 = 1,25.10 3 mol.l 1

n f = X f = H 3O + f .V = 1,25.10 3.1 = 1,25.10 3 mol

 }./cCF*  =

Xf
X max

 xf;U+

1,25.10 3
=
= 22,5 0 0 6  BW6 H 17U8
5,55.10 3

www.ibnalkhatib2.canalblog.com

 (.4) 1  !
 (1
 /6 h8:M7+L 3kl(6 0 n1 p + 1 e :1:&y 1 3/() 1.1
1

  3kl(6 M8t:z t~378

60
27

60
0
Co
28Y + 1 e

60
Y 28
Ni

60
28

:(6 1 3)(2.1

 :J
38 3kl{6 8(2


NA
N
.m = A .m0 .e t :M6) n = m = N N = N A .m J N (t ) = N 0 .e t 
A
A
A NA
A
m (t ) = m0 .e t :t
:KL6 C(3
 .163 h8KL8 1)q t 16) /&13()6  3kl JKL6 C



1/ 2
m0 t

m0 2t1 / 2
m0
m0
m0
nt1 / 2
3t1 / 2

.....

2
4 = 22
8 = 23
2n

:1HO


 3kl{6 8 )qO8:18N 1HO 

m (t) =m0.e-t.ln2/t1/2
n . ln 2 = ln1/2n c3:r<

m(t ) = m0 .e t
: >*L\WL 38

ln 2
t1 / 2

:6

m (t) =m0.e-nt1/2.ln2/t1/2 1HU 1q3 =t = nt1/2 38

m(t) = m0/2n

:M6) m(t )

1/

= m0 .e ln 2 n :1q3 *L8

 t1/2 = 5,25 an :87)(14

 1HU 1q3 ) 2t1/2 = 10,5 an :6 H7/Co196S

m(2t1/2) = m0/4 = 0,5 g

 :t =
-1

m (t ) = m0 .e

m = m0. e = m0/et =

:1q3 () 2.4

38 m(t )

= m0 .e

www.ibnalkhatib2.canalblog.com

 :M 3)1 :1  7T0C/t(3.4

 :CC M%/)*3/a- m

  a = dm(t )

dt t =0

1
= m0 e

= at +b

m
= 0

t =0

38m = m06 t = 01y? 6b1N E

 .b = m0:M6)1 3/=
 m =
  =

m0

t
t + m0 = m0 (1 ) :tC/1 3)

t1 / 2
7,5an ;U+ (1 t ) = 0 t = M6)m = 017U6 
ln 2

)  }q
HU/

 t = 0 1y? 616(8_73:(4.4

a 0 = .N 0 =

  a0 =

23

N0

m
N
N
6,023.10 .2.10
= 8,5.1013 Bq :M6) n0 = 0 = 0 N 0 = A .m0 :J
38
3
A
NA
A
60.10 7,5.365.24.3600
N
a 0 = A m0
A.

2
:K3:(1
 .HSN9J81H376:+BH::HU)_8 &13()8
4
2

He &)v8 & 1H

206
4
Po

82Y + 2 He

210
84

(2

Y 206
82 Pb

206
82

27
13

Al + 24 He 
01 n + 1531P

(3

 :8~3788>*L?6 FrF:8Z)6::)8<*:
10

 5 B

4
2

He

0n +

13
7

(4


:'U  *19_:6S E

= m.C 2 :

(614(1.4

m = m( N ) + m(n) m( B ) + m( He) = 1,008655 + 13,001898 10,010194 4,001506 = 1,147.10 3 u

  (2.4

E = m.C 2 = 1,147.10 3.1,66054.10 27 .(3.10 8 ) 2 = 1,71.10 13 J = 1,07 MeV

 ?k8o6 *