Bi ging K thut x l nc thi Thc s Lm Vnh Sn

3.8.5.3.Oxy ho bng oxy trong khng kh

Ngoi chc nng l oxy trong khng kh c s dng tch st ra khi nc cp, oxy cn
s dng oxy ho sunfua trong nc thi ca nh my giy, ch bin du m. Qu trnh
oxy ho hyrosunfua thnh sunfua lu hunh din ra qua cc giai on thay i ho tr ca
lu hunh t -2 n -6.
S2- --> S --> S10O62- --> S2O32- --> SO32- --> SO42-

Nc ngng

1
Q

Nc
sach
7

3
Nc
thai
2
5

Khong kh

Hnh 3.4.3 : S o nguyen ly cong nghe oxy hoa sunfua

S nguyn l cng ngh oxy ha sunfua

1. Thung ra nc thai ; 2. Bm ; 3. Thiet b trao oi nhiet ; 4. Thap oxy ; 5. Bo phan

phan phoi khong kh ; 6. Thiet b tach khong kh ; 7. Thiet b lam sach.

1. Thng ra nc thi; 2. Bm; 3. Thit b trao i nhit; 4. Thp oxy ha;

5. B phn thi khng kh; 6. Thit b tch khng kh; 7. Thit b lm sch

3.8.5.4.Oxy ho bng pyroluzit

Pyroluzit thng c s dung oxy ho As3+ n As5+ theo phn ng sau :
H2AsO2 + MnO2 + H2SO4 = H2AsO4 + MnSO4 + H2O.
Khi tng nhit s lm tng mc oxy ho. Ch oxy ho` ti u nh sau :Lng MnO2
tiu tn : MnO2 bng 4 ln so vi lng tnh ton theo l thuyt : axit ca nc l 30
40 g/l ; nhit ca nc l 70oC - 80oC.
Qu trnh oxy ho ny thng c tin hnh bng cch lc nc thi qua lp vt liu MnO2
buc khuy trn nc thi vi vt liu MnO2.
3.8.5.5.Ozon ha
Phng php ny dng kh tp cht nhim bn, kh mu, kh cc v l c trong nc.
Qu trnh oxy ho c th lm sch nc thi khi phenol, sn xut du m, H2S, cc hp cht
Asen, cc cht hot ng b mt, xyanua, cht nhum,...
Trong x l bng ozon, cc hp cht h c b phn hu v xy ra s kh trng i vi nc.
Cc vi khun b cht nhanh so vi x l bng clo vi nghn ln.
3.8.6. X l nc thi bng phng php in ho.
Cc phng php in ho cho php thu hi t nc thi cc sn phm c gi tr bng cc s
cng ngh tng i n gin v c th t ng ho. Khng cn s dng tc nhn ho
hc, nhc im l tiu hao in nng.
Gm cc phng php chnh sau :
Oxy ho ca anot v kh ca catot.
ng t in
Tuyn ni bng in.
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