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Estimator Based Flooding Predictor For (13C) Cryogenic Separation Column - Pop2008 PDF
Estimator Based Flooding Predictor For (13C) Cryogenic Separation Column - Pop2008 PDF
I. INTRODUCTION
Isotopes are species of the same element with different number of neutrons in the nucleus. For instance, the chemical element carbon consists of the basic species (12C) and the
heavier stable isotope (13C) with a ratio of natural concentration of (98.89% / 1.11%) [1,2]. If some chemical compounds of
carbon with higher concentration in (13C) isotope in detriment
of (12C) can be obtained, the detection of those chemical compounds brings valuable quantitative and qualitative information
in various domains: chemical engineering, biology, medicine,
etc.
A great variety of technologies able to create compounds
with higher abundance in the isotope of interest are known today. In the case of (13C) one of these is the cryogenic distillation.
The separation process analysis is based on the hydrodynamic process- specific for each separation technology- and
the separation process itself, relatively independent of the
technology used.
II. PRINCIPLE OF THE SEPARATION METHOD
Unfortunately, the physical and chemical properties of the
compounds of (12C) and (13C) are very close, being difficult to
separate. Even though, very small differences in properties
must be used to raise the concentration of (13C) to separate
the isotope of interest. For instance, at very low temperatures
( 190D C ) the carbon monoxide based on (12C) has a higher
vapor pressure (p) than the monoxide based on (13C). It is possible to find and to maintain a small range of temperature in
which the gaseous phase (related to (12C)) coexists with the
liquid phase (based on (13C)). It is necessary to distillate the
compounds (12CO versus 13CO) in a distillation column like in
the typical industrial distillation equipment [3]: the gaseous
phase must be evacuated and the liquid phase which contains
a greater abundance of 13CO - is kept as end-product. The basic
factor is the separation coefficient [1], given by the ratio
of the vapor pressures:
=
pD13 CO
pD12 CO
>1
(1)
with = 1.011 , pD13 CO the vapor pressure of 13CO and pD12 CO the
vapor pressure of 12CO.
This particular isotope separation technology is called
cryogenic distillation.
III. BASIC EQUIPMENT DESCRIPTION
The equipment is called cryogenic distillation column,
figure 1, and is divided for simplicity- in three parts [3]: the
boiler (B) on the bottom side, the condenser (C) at the top side
and the packed distillation column (tower). The external
flows are: the feed flow (F), the waste flow (W) and the product flow (P).
In the column, an upward vapor (gas) stream, generated by
the evaporation in the boiler is brought into contact with a
downward flowing stream of liquid produced by condensation
in the condenser zone. The boiler is heated with an electrical
resistor and the condenser is cooled with liquid nitrogen. During this permanent contact, the concentration of (13CO) increases in the liquid phase in the column basis. The packing material
inside the column increases the contact surface between the
liquid and the gaseous phases. In order to flow up from the
boiler to the condenser, the vapor stream needs some effective
area through the elements of the packing material. This area is
greater by dry packing material and smaller by wet material.
The gaseous upstream needs a differential pressure along the
column. Every liquid droplet is submissive to the force of gravity and, in the opposite direction, to the pressure force of the
gas. In normal mode of operation, the gravity is stronger and
the liquid phase flows as droplets to the boiler.
In order to improve the prediction, the actual output (differential pressure p ) is compared with the predicted value p(t + k ) . The measured value p(t ) , filtered by
H 1 (s ) (low pass filter) is compared with the estimated value y (t ) . The prediction error, (t ) , smoothed by H 2 ( s) , is
added to the predicted value p(t + k ) in order to obtain the
If (t ) is the flow rate of the gaseous phase for carbon monoxide and ( Rh ) is the hydrodynamic resistance, in a simplified version one supposes that:
k el Pel
(2)
1 / Rh = a b Pel
(3)
and
Pel (p.u.)
p (p.u.)
k
b3 4
b2 3
b 2
= el Pel + k el
Pel =
Pel + k el
Pel + k el
a
a4
a3
a2
= a1 Pel + a 2 Pel2 + a3 Pel3 + a 4 Pel4
(4)
87
109
140
210
230
340
1
k el Pel
b
b 2 2 b 3 3
k el +
Pel +
Pel +
Pel Pel =
a a2
a b Pel
a3
a4
74
By polynomial interpolation, with fourth order approximation, the following values of the coefficients are obtained:
44
250
200
150
100
40
50
60
70
80
Electrical power (p.u.)
90
100
110
= p k p k 1
D
Pel , k Pel ,k 1
>
D
< (D)
lim
(8)
(9)
VII. CONCLUSIONS
The disastrous consequences of the flooding phenomenon in
distillation column justify the theoretical and practical effort of
the specialists in order to predict/avoid this process. The general solution, at least according to actual references, is the predictive control theory and methods. In the particular case of the
cryogenic distillation for (13C) separation, where the information for the temperature distribution in the column is not available, accurate and prompt information about the differential
column pressure using commercially available transducers and
about the liquid level in the boiler, using a patented modern
transducer [6], the evolution of the first and second derivative
of these variables can predict and avoid the column flooding.
The solution is modern, effective and low-cost.
ACKNOWLEDGMENT
The authors acknowledge the support of the Romanian National Education and Research Ministery under PN2 Grant
81023/14.09.2007.
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
Figure 6. Evolution of the differential pressure derivative
[7]
[8]
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13
C through Isotope Exchange, (in Romanian), Casa Cartii de Stiinta,
1994
S. Skogestad, Dynamics and Control of Distillation Columns- a Tutorial
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2005
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