Ans Sol 10 PDF

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AIITS-HCT-VIII (Paper-2)-PCM(S)-JEE(Advanced)/15
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ALL INDIA INTEGRATED TEST SERIES ANSWERS, HINTS & SOLUTIONS

HALF COURSE TEST VIII
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICCS

1. B B B
2. C C C
3. A D C
4. A A D
5. A, C A, B, C D
6. B, C A, C, D A, B, C
qualified in JEE (Advanced), 2014.
7. A, B, C A, B, C A, C, D
8. A, C A, B, C B, C
9. B, C A, B, C A, D
(A) (t) (A) (q, r, t) (A) (p, q, r, s)
(B) (q) (B) (p, r) (B) (q)
1. (C) (q) (C) (p, r, s, t) (C) (r)
(D) (p) (D) (p, r) (D) (p)
(A) (p, q, r, s, t) (A) (p, q) (A) (r)

(B) (p, q, r, s, t) (B) (p, q, s) (B) (s)
2 (C) (p, q, r, s, t) (C) (p, q, s) (C) (q)
(D) (r) (D) (q, r, s, t) (D) (p)
1. 3 3 8
2. 8 4 3
3. 6 3 8
4. 8 4 6
5. 5 6 1
6. 2 4 3
7. 8 2 9
8. 2 4 5
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2
Physics PART I
SECTION A
K 8K
1. 0 , ' = 4 0
m m/2
GM e m GM e m GM e m
2. E1
R Re 3R e
Re e
2
1 1 GM e GM e m
E 2 mv 02 m. .
2 2 R 3R e
R e
2
(C)
3. For vertical equilibrium T

uptrust
T = weight upthrust

3 L
T 2LA g (2L x)Ag Ag x (2Lx)/2
O
4 2
where is the density of water weight
for rotational equilibrium about O
2L x L
(2L x)Ag L cos Ag x L cos
2 2
x=L
4. If v be the velocity at mean position in two cases then

1 1 m
mv 2 kA 12 and T1 T2 2
2 2 k
A1 = A 2
5. Buoyant forces on both the spheres will be same because volume of both the spheres is same
and weight of the hollow sphere is less. If A and a are the accelerations of solid and hollow
spheres respectively, then A > a.
6. P = (4r2)T4
dT 3T 4 1
R
dt s r
SECTION C
1. At point P slope is tan 150

d 1
tan 150
dT 3
PM d PM
Since
RT dT RT 2
3
V2
3. 4ms 2 Mg
R
V2 N
Mg N = 10 N 1. 4
R
N = 6 Newtons
K M
4. T 2
M K
M1M2 M2
T1 2 T2 2
K(M1 M2 ) K
M2
T2 2
K
2
M1 M2 T2 M M2 1 M2
9 1
M1 T1 M1 M1
M2
8
M1
5 = 120
K = 2 / 3

V 180 36X
K
X=5
6. While floating net force = zero

Increase in buoyancy force = increase in weight
V
g xg
2
V
x
2
15.92 7.96 6 7 m
7. tan 10 7.96 10 Newton
Mg 1 10
2m N N
Y 3 2 7
8 1011 2
3.14(10 m) 7.96 10 m m
8. 5
1
5ms
10t Jeep Vrel
10t
Vrel 5 1 4t 2
5 1 10
sin gsin aN
2 2
5 1 4t 1 4t 1 4t 2
Vrel225 5
R (1 4t 2 )3 /2 (17)3/ 2 1 4t 2 17
aN 10 2
t = 2 seconds.
4
Chemistry PART II
SECTION A
3. (i) use PV = nRT

w
PV = RT
m
(ii) due to hydrogen bonding aNH3 aCO2
1
(iii) mean free path ()
2
3
(iv) Average K.E per molecule = kT.
2
5. (A) Aniline does not undergo Fridel Craft reaction due to lone pair on N-atom which directly
attacks on AlCl3.
(B) formation of carbocation at bridge head position is not favoured.
(C) CHCl3 alc. KOH :CCl2 (dichlorocarbene)
Cl Cl
: CCl2 C Cl

Cl
(D) Three times protonation followed by ring expansion gives benzene.
6. In the option (b), the H atom is linked to an sp2 hybridised C atom.
8. r = K [A]m [B]n
on calculation, m = 2, n = 1 & K = 2.66 108 mol-2 l2 sec-1 at 300 K
so, K will be > 2.66 108 at 320 K.
Hence, (A, B, C)
SECTION C
1. The PV diagram for the given changes is as:
(P1, 300 K) (P1, T2)

A B
P (in atm)
(P2, 300 K)
C
20 40 V1
V (in litres)
for isobaric process AB,
5
V1 V2
(from Charles law)
T1 T2
20 40
,
300 T2
T2 = 600 K
wt = wAB + wBC
Now, wAB = nRdT (Isobaric process)
= 2 2 (600 300) = 1200 cal.
wBC = for adiabatic process
w = n CV T
3
= 2 R (600 300)
2
= 1800 Cal
wT = 1200 1800 = 3000 Cal = 3 kcal.
2. H2 O
Mg2 C3 Mg(OH)2 H3C C C H (i) Na
H3C C C CH2 CH3
(ii) CH3 CH2 Cl
(A)
Ni/H2
H
Cl / h
C C C C C+ C C C C C
monochlorination
CH3 CH2 CH2 CH2 CH3
(Enantiomeric)
Cl Cl (B)
+
C C C C C Cl
3. 30 ml of N/50 HCl = 30 ml of N/50 Mg(HCO3)2

= 30 ml of N/50 CaCO3 = 100 ml of tap water
E N V
mass of CaCO3 in 100 ml tap water =
1000
50 30
= 0.03 g
50 1000
Hardness = 300 ppm
X=3
diglyme
4. NaBH4 I2
solution
B 2H6 H2 2NaI
X
Cl2
B 2H6 2NH3 B2H6 .2NH3

B3N3H6 B3N3H4 Cl2
adduct Y dichloro derivatives
So, dichloro derivatives of (Y) = 4
6
Mathematics PART III
SECTION A
1. Let the equation of the line L be y 2 = m(x 8), m < 0

2
P 8 , 0 , Q = (0, 2 8m)
m
2
OP + OQ = 8 2 8m 18
m
2. Let centre C = (a, 0)

COP = 45
OP = 2 2 CP A C B
OC = 4 O
The point on the circle with greatest abscissa is B P
= OB = 4 2 2 (2, 2)
b
3. y = mx 2am am3, y = mx + 2b +
m2
b
For common normal, 2b 2am am3 0
m2
am5 + 2am3 + 2bm2 + b = 0
Maximum 5 normal
4. Equation of tangent y mx a 2m2 b 2

1
Equation of a perpendicular from centre (0, 0) on the tangent is y x
m
x x2
Required locus y x a2 2 b2
y y
5. Pair of tangents SS = T2
tan
2 h2 ab
=
2 a2 1
ab a2 2
tan < 0
2 a2 1
0
a2 2

a 2, 1 1, 2
6. 2s(2s 2a) = xbc
4s s a A
x = 4cos2
bc 2
x (0, 4)
2 2
7. x + x + 1 = ax + 1 and 1 x + x + 1 1
a<1
7
8. cos4 sin4 = cos2 sin2 = cos 2

2 2
(2b) 4b = (4) 4 2
b = 1, 2
9. Put x = 1
2 12
(2 + 3c + c ) = 0 (as the sum of coefficients vanishes)
2
c + 3c + 2 = 0
c = 1, 2
SECTION B
1
1. (A) Can take any value except , 3
3
A B C sec A sec B sec C C
(C) Centroid of ABC is , y = sec x
3 3
sec A secB sec C A BC
sec B
3 3
A
sec A sec B sec C
2 Least value of sec A = 6
3
2sin 20 cos 20
(D) 4
1
sin20 cos 20
2
2. R = 15
1
18 24

r = 2 =6
s 18 24 30
2
Circum-centre = (9, 12), orthocentre = (0, 0), in-centre = (6, 6), centroid = (6, 8)
SECTION C
1. x2 + y2 12x 2y + 28 = 0
C = (6, 1), r = 3
|z0 + 5 i|min = 8
2. |z 1| + |z 2| + |z 3| |3z 6| = 3|z 2| = 3|2ei 2| = 12

9
3. k=2
n n 1
na 29
2
10
n(2a + n 1) = 2
Which is only possible for n = 1
a = 512
8
11!
4. 6 boys and 5 girls in
6! 5!
Teachers are at remaining places in 12P3 ways
11!
12 P3
5! 6!
5. b ac
b3 abc
b3 4
b 41/3
[b] = 1
sin2
6. 6 cot = cot( ) + cot( + ) =
sin sin
3cos 2sin cos

sin cot 2 cos 2
4 sin2 = 6 sin2
2 sin2
3
sin2
7. x=y=z=1
2x + 3y + 4z = 9
8. 2zz 2 | z 3 || z 3 | 82
|z + 3| + |z 3| = 10
|z|max = 5

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FIITJEE JEE(Advanced), 2015

ALL INDIA INTEGRATED TEST SERIES ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICCS

(A) (p, q, r, s, t) (A) (p, q) (A) (r)

3. For vertical equilibrium T

4. If v be the velocity at mean position in two cases then

1. At point P slope is tan 150

6. While floating net force = zero

3. (i) use PV = nRT

(D) Three times protonation followed by ring expansion gives benzene.

6. In the option (b), the H atom is linked to an sp2 hybridised C atom.

1. The PV diagram for the given changes is as:

(P1, 300 K) (P1, T2)

3. 30 ml of N/50 HCl = 30 ml of N/50 Mg(HCO3)2

Mathematics PART III

1. Let the equation of the line L be y 2 = m(x 8), m < 0

2. Let centre C = (a, 0)

4. Equation of tangent y mx a 2m2 b 2

8. cos4 sin4 = cos2 sin2 = cos 2

2. |z 1| + |z 2| + |z 3| |3z 6| = 3|z 2| = 3|2ei 2| = 12

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